Page # 50 BIOMOLECULES & POLYMERS

EXERCISE-I
1. Given structure is ?
Br2
HC O 5. D-Glucose  
H O
| 2

H  C  OH (A) Aldonic acid (B) Adaric acid

|
(C) Alditol (D) Tartaric acid
H  C  OH
|
H  C  OH 6. D-Glucose will form same osazone with -
| (A) D-Mannose (B) D-Fructose
CH2OH (C) D-Allose (D) Both (B) and (C)
D  ribose
(A) Aldopentose (B) Aldohexose 7. Relation between D-Glucose & D-Fructose is -
(C) Ketopentose (D) Aldotetrose (A) C2-epimer (B) C3-epimer
2. Given structure ? (C) Functional isomer (D) Positional isomers
CH 2 OH
| 8. Which of following is Oligosaccharides ?
C  O
| (A) Glucose (B) Fructose
HO  C  H
| (C) Sucrose (D) Starch
H  C  OH
|
H  C  OH 9. Which of the following is D-Glyceraldehyde ?
|
H  C  OH CH2OH
| CHO
CH 2 OH
(A) H OH (B) H OH
D  sedoheptul ose
CH CH2  OH
(A) Aldopentose (B) Ketohexose
(C) Ketoheptose (D) Ketohexose
3. Given structure is ? CHO CHO
(C) H OH (D) HO H
HC  O
| CH3 CH3
HO  C  H
|
HO  C  H
| 10. C2-epimer of D-Glucose is -
H  C  OH (A) D-Glucose (B) D-Allose
|
H  C  OH (C) D-Altrose (D) D-Mannose
|
CH2OH 11. C3-epimer of D-Glucose is -
D  mannose (A) D-Glucose (B) D-Allose
(A) Aldopentose (B) Ketohexose (C) D-Altrose (D) D-Mannose
(C) Ketoheptose (D) Aldohexose
12. Which of following Carbohydrate is Aldohexose ?
4. Which of the following is D-glyceraldehyde ? (A) D-Mannose (B) D-Glucose
HC=O H (C) D-Fructose (D) Both (A) and (B)
(A) HOCH2 OH (B) HO CH2OH
H Br2
HC=O 13. D-Glucose   Product in known as -
H O 2
CH2OH
(A) D-Glucitol (B) D-Gluconic acid
(C) HO H (D) A and B both
(C) D-Glucaric acid (D) Tartaric acid
HC=O

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BIOMOLECULES & POLYMERS Page # 51
O
HO  HO  OH OCH3
14. D-Glucose D-Fructose (X)

(A) D-Allose (B) D-Altrose

(C) D-Mannose (D) D-Glucose
H OH H CH2  OH
(C)
15. 5HIO4
D-Glucose   Product is -
(A) 4HCO2H1CO2, HCHO (B) 5HCO2H, HCHO
(C) 4HCO2H1CO2, HCHO (D) 5HCHO, HCO2H H OH

O
HO  CH2 OH
16. Which of following pair give same Osazone -
(A) D-Glucose, Fructose (B) D-Glucose, D-Mannose
(C) D-Allose, D-Altrose (D) All
H OH H H

Comprehension (Q.17 to Q.20) (D)

H OH
CH2  OH
17. Relation between (A) and (B) is -
H H (A) Anomers (B) Positional isomer
O
(C) Functional isomer (D) Enantiomer
18. Structure of B-D-Gluco pyronose is -
H
(A) A (B) B
(A) (C) C (D) D
OH H
19. Which of compound not undergo mutarotation -
(A) A (B) B
HO HO (C) C (D) D
20. How many mole of acetic anhydride will
H OH consumed when it reacts with compound (A)
(A) 3 (B) 4
(C) 5 (D) 6
21.
CH2OH
CH2  OH
C=O
H O HO
H OH
(i) NaBH4
H HO H (P)
(B) (ii) H , H2O
OH H H OH

CH2OH
HO H D-sorbose
Number of stereioisomer of product (P) is -
H OH (A) 4 (B) 10
(C) 12 (D) 16

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 Page # 52 BIOMOLECULES & POLYMERS
22. The main structural features of proteins is - 31. Zieglar-Natta catalyst is -
(A) Ester linkage (B) Ether linkage (A) R3Al (B) TiCl4
(C) Peptide linkage (D) All of these (C) R3Al + TiCl4 (D) R3B + TiCl2

23. Which compound can exist in a dipolar 32. Monomer of Teflon is -

(Zwitterion) structure ? (A) Monochloroethene
(A) C6H5CH2CH(N=CH2)COOH (B) 1,2-Difluoroethene
(B) (CH3)2CHCH(NH2)COOH (C) 1, 1, 2-Trifluoroethene
(C) C6H5CONHCH2COOH (D) Tetrafluoroethene
(D) HOOCCH2CH2COCOOH
33. Orion is polymer of -
24. Vitamins C is chemically - (A) Styrene (B) CF2=CF2
(A) Ascorbic acid (B) Citric acid (C) Vinyl chloride (D) Acrylonitrile
(C) Aspirin (D) Aspartic acid
34. Intermolecular force present in nylon-66 is -
25. In an amino acid, the carboxylic group ionises (A) vander Waal
(B) Hydrogen bond
ka1
at p = 2.34 and ammonium ion at pka2 = 9.60. (C) Dipole-Dipole interactions
The iso electric point of the amino acid is at pH - (D) Sulphide linkage
(A) 5.97 (B) 2.34
(C) 9.60 (D) 6.97 35. Nylon-66 is made by using -
(A) Phenol (B) Benzaldehyde
26. Which statement is incorrect about peptide (C) Adipic acid (D) Succnic acid
bond ?
(A) C–N bond length in proteins is loger than usual 36. Polymer which has amide linkage is -
(A) Nylon-66 (B) Terylene
bond length of C–N bond
(C) Teflon (D) Bakelite
(B) Spectroscopic analysis shows planer structure
of C  NH  bond 37. Bekelite is prepared by the reaction between -
|| (A) Phenol and formaldehyde
O (B) Ethylene glycol and dimethylphthalate
(C) C–N bond length in proteins is smaller than usual (C) Urea and formaldehyde
bond length of C–N bond (D) Tetramethylene glycol and hexamethylene diamine
(D) None of these
38. Natural rubber is a polymer of -
27. A triglyceride can have how many different (A) Butadiene (B) Ethyne
acyl groups ? (C) Styrene (D) Isoprene
(A) 3 (B) 2
39. Terylene is a condensation polymer of ethylene
(C) 1 (D) 4
glycol and
(A) Benzoic acid (B) Phthalic acid
28. Which one of the following is natural polymer -
(C) Salicylic acid (D) Terephthalic acid
(A) Starch (B) Nylon-6
(C) Kodel (D) Buna-S, SBR 40. Cellulose acetate is a -
(A) Natural polymer
29. Which of the following is homopolymer ? (B) Semisynthetic polymer
(A) Starch (B) Polystyrene (C) Synthetic polymer
(C) Orion (D) All of these (D) Plasticiser

30. Which of the following monomers can undergoes 41. A condenation polymer among the following
radical, cationic as well as anionic polymerisation polymers is -
with equal ease ? (A) Teflon (B) Polystyrene
(C) PVC (D) Dacron
(A) CH3  C  CH2 (B) C6H5–CH=CH2
| 42. In elastomer, intermolecular forces are -
CH3
(A) Nil (B) Weak
(C) CH2=CH–CN (D) CH2=CH2 (C) Strong (D) Very strong

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43. Which one of the following is a polyamide ?
(A) Teflon (B) Nylon-66
(C) Terylene (D) Bakelite CH2  OH

44. Glycosidic linkage is present in - H HO

O
(A) Sucrose (B) Maltose
(C) Lactose (D) All H
(B)
OH H
45. Which of the following amino acid has lowest
is electric paint ?
(A) Lysine (B) Aspastic acid HO H
(C) glycine acid (D) Alanire
H OH
46. Protein on hydrolysis give - O
HOCH2 OH
(A) -amino acid (B) -amino acid
(C) -amino acid (D) All
(C)
47. Which of the following aminoacid is optically
is actue - H H H H
(A) Glycire (B) Alanire
(C) Valire (D) Leucire

48. Peptide linkase is present is - OH OH

(A) Protein (B) Nylon-6, 6
(C) Sucrose (D) both (A) & (B)
CH2  HO O
CH2  HO
49. Product obtained by hyrolysis of lactose are -
(A) Glucose & fructose (B) Glucose, mannose (D)
(C) Mannose & fructose (D) Galactose, Glucose
H OH H OH
50. Which of following is amino acid ?
(A) NH2–CH2–CO2H
(B) NH2–CH2–CH2–CO2H
(C) NH2–CH2–CH2–CH2–CO2H H OH
(D) All

51. Which of following is structure of -D- 52. Which of the following is fully fluorinated polymer ?
(A) Neoprene (B) Teflon
Glucopyranose ?
(C) Thiokol (D) PVC

CH2  OH 53. The monomer of the polymer

CH3 CH3
H H 
O CH2 C CH2 C
is
H CH3 CH3
(A)
OH H CH3

(A) CH2  C (B) CH3–CH=CH–CH3

HO HO CH3

H OH (C) CH3–CH=CH2 (D) CH3– C  C  CH3

| |
CH3CH3

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 Page # 54 BIOMOLECULES & POLYMERS
54. Buna-S is a polymer of -
(A) butadiene only CHO CHO
(B) Butadiene and styrene
(C) Styrene only H C OH H C OH
(D) Butadiene and nitryl (C) H C OH and HO C H

55. Maximum number of monosaccharide units H C OH H C OH

present in oligosaccharides is
CH2OH CH2OH
(A) 8 (B) 15
(C) 10 (D) 40
CHO CHO
56. Which one of the following is non-reducing sugar
? H C OH HO C H
(A) Glucose (B) Arabinose
(D) H C OH and HO C H
(C) Fructose (D) Sucrose
HO C H H C OH
57. Which one of the following is reducing sugar ?
(A) Starch (B) Cellulose CH2OH CH2OH
(C) Glycogen (D) Fructose
63. Glucose molecule reacts withX number of
58. In solution glucose exist in how many isomeric
forms ? molecule of phenylhydrazine to yield osaxone. The
(A) Two (B) Sixteen value of X is
(C) Three (D) Four (A) Three (B) Two
(C) One (D) Four
59. Reducing property of monosaccharide is due
to the presence of 64. Which of the following reagents cannot
(A) -OH group (B) Keto group
distinguish between glucose and fructose ?
(C) Acetal group
(D) Anomeric hydroxyl group (A) Tollens reagent (B) Fehling solution
(C) Bendict solution (D) All of these
60. Which one of the following carbohydrates will
show mutarotation ? 65. Cellulose is a polymer of
(A) Sucrose (B) Maltose (A) Glucose (B) Fructose
(C) Lactose (D) Both (B) & (C)
(C) Ribose (D) Sucrose
61. Glucose and mannose are
66. Which of the following is an example of
(A) Anomers (B) Positional isomers
(C) Functional isomers (D) Epimers Ketohexose ?
(A) Mannose (B) Galactose
62. Which of the following pairs are epimers (C) Maltose (D) Fructose
CHO CHO
67. When glucose reacts with bromine water, the
H C OH HO C H
main product is
H C OH and HO C H (A) Acetic acid (B) Saccharic acid
(A) (C) Glyceraldehyde (D) Gluconic acid
H C OH HO C H

CH2OH CH2OH 68. All monosaccharide ........ Tollens reagent

CH2OH CHO (A) oxidises (B) reduces
C=O (C) condense with (D) add to
H C OH
HO C H HO C H 69. The number of chiral centres in (+) glucose is
H C OH and H C OH (A) 4 (B) 3
(B)
(C) 2 (D) 1
H C OH HO C H
CH2OH CH2OH

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70. Protein is polymer of 79. Identify the pair of Epimers
(A) Amino acid (B) -Amino acid (A) D-Glucose & D-Fructose
(C) -Amino acid (D) -Amino acid (B) D-Glucose & L-Glucose
(C) D-Glucose & D-Mannose
(D) D-Glucose & D-Glucose
71. Amino acid may be
(A) Neutral (B) Basic 80. The number of Stereogenic centres in -D-
(C) Acid (D) Any one of these Glucose are
(A) 4 (B) 5
72. The given structure of -amino acid will exist (C) 3 (D) 2
at which pH ?
81. -D-Glucose and -D-Glucose are
COOH (A) Epimers (B) Anomers
(C) Enantiomers (D) Acetals
NH3 C H
82. Identify the non reducing sugar
R OH
O
OH
(A) 7 (B) 14 H
H
(C) 0 (D) 12 H
(A) HO
OH OH
73. Peptide linkage is H
OCH3
O
O O H3CO
(A) (B) H
C O C NH2 (B)
H3CO OH
O O H3CO
(C) (D) CH2OH
C NH NH 2 C NH
H O OH
H
74. Complete hydrolysis of cellulose gives OH H
(C)
(A) L-glucose (B) D-fructose OH H
(C) D-ribose (D) D-glucose H OH

75. Number of chiral carbons in -D-(+)-glucose is OH

(A) six (B) three O
OH
(C) four (D) five
H
(D) HO OCH3
76. The pair of compounds in which both the compounds
give positive test with Tollen’s reagent is OH
(A) glucose and sucrose
(B) fructose and sucrose 83. Write the names of monomers of the following
(C) acetophenone and hexanal polymers :
(D) glucose and fructose H H O O
(i) | | || ||
77. Among cellulose, polyvinyl chloride, nylon, and [
—N–(CH2)6—N—C—(CH2)4–C—n ]
natural rubber, the polymer in which the intermolecular
force of attraction is the weakest is O H
|| |
(A) polyvinyl chloride (B) natural rubber
(ii)
—C–(CH 2)5—N—n
[ 2–CF2—
(iii) —CF ]n
(C) nylone (D) cellulose
84. Clas sify the follow ing as addition and
78. D-Glucose & L-Glucose are condensation polymers: Terylene, Bakelite, Polyvinyl
(A) Enantiomers (B) Diastereomers chloride, Polythene.
(C) Epimers (D) Anomers

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