(Questions) Dated 14-4-2019

TM
S-Beta, S-Edison, S-Thomsan

This booklet contains 23 printed pages. Test ID : 92113001
Test Pattern : JEE Advance M.M : 264
Paper-2 Syllabus Time : 3 Hours
Physics Electrostatics Till Field Lines & SHM
Solutions Till Lec 6 Group 13 Coordination Compound, Till Nomenclature

Chemistry
Determinants, Functions
Mathematics
A. General: INSTRUCTIONS
1. This Question Paper contains 23 pages having 60 questions.
2. No additional sheets will be provided for rough work.
3. Blank papers, clipboards, log tables, slide rules, calculators, cellular phones, pagers and electronic gadgets
in any form are not allowed.
4. The answer sheet, a machine-gradable Objective Response Sheet (ORS), is provided separately.
5. Do not Tamper/mutilate the ORS or this booklet.
B. Filling the bottom-half of the ORS:
6. Write the Code on the ORS same as that given on this question booklet
7. Write your Enrollment Number, Name and Name of centre and sign with pen in appropriate boxes. Do not
write these anywhere else.
8. Darken the appropriate bubbles below your Enrollment number with HB Pencil.
C. Question paper format and Marking scheme :
9. This question paper consists of 3 parts Physics (88 Marks), Chemistry (88 Marks) and Mathematics
(88 Marks). Each part consists of three Sections.
10. For each question in Section-I, you will be awarded 4 marks if you darken only the bubbles corresponding
to the correct answer and zero mark if no bubbles are darkened. In all other cases, minus two (-2) mark will
be awarded.
11. For each question in Section II, there are 4 parts. For each parts you will be awarded 2 marks if you darken
the bubbles corresponding to the correct answer and zero mark if no bubbles are darkened. No negative
marks will be awarded in this Section.
12. For each question in Section-III, you will be awarded 4 marks if you darken only the bubbles corresponding
to the correct answer and zero mark if no bubbles are darkened. No negative marks will be awarded in this
Section.
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Physics Section_I (Multiple Type Answer) 40
1. The diagram shows part of an evacuated tube in which a stream of electrons from an electron gun passes 4
between a pair of large parallel deflecting plates. The electron gun accelerates the electrons in a field due to the
‘accelerating voltage’. The deflection of the electron beam as it leaves the parallel plates is x. (Neglect gravity and
the electron enters the deflecting region parallel to the plates)
Which of following will change the displacement x of the electron beam as it leaves the parallel plates?
a. increasing the accelerating voltage
b. increasing the deflecting voltage
c. increasing the distance between the electron gun and the deflecting plates
d. increasing the distance between the two deflecting plates
2. A particle of mass 2 kg and charge 1mC is projected vertically with a velocity 10 ms-1. There is a uniform 4
horizontal electric field of 104N/C.
[Neglect air resistance, g=10 ms-2]
a. the horizontal range of the particle is 10m
b. the time of flight of the particle is 2s
c. the maximum height reached is 5m
d. the horizontal range of the particle is 0
3. In the figure shown, initially the spring of negligible mass is at natural length and the block is released from rest. 4
E is a uniform electric field and the floor is smooth. Then
a. The maximum speed of the block will be QE
√mk
b. The maximum speed of the block will be 2QE
√mk
c. The maximum compression of the spring will be QE
d. The maximum compression of the spring will be 2QE
roboassess.robomateplus.com/PaperPreview.aspx?pid=122559&sa=0 1/14
4. Two point like charges a & b whose magnitudes are same are positioned at a certain distance from each other. a 4
is at the origin. Graph is drawn between electric field strength at points between a & b and distance x from a. E
is taken positive if it is along the line joining from a to b. From the graph it can be decided that
a. a is positive
b. b is positive
c. a is negative
d. b is negative
5. Electric field given by the vector E=x

⃗ ^
i +y j , is present in the XY plane. A small ring carrying charge +Q, which
^ 4
can freely slide on a smooth non conducting rod, is projected along the rod from the point (0, L) such that it can
reach the other end of the rod (L,0). What minimum speed should be given to the ring? (Assume zero gravity)
a. −
−−−
2
QL
√
m
b. −
−−−
2
QL
2√
m
c. −
−−−
2
QL
4√
m
d. −
−−−
2
QL
√
2m
6. Density of a liquid varies with depth as ρ = αh. A small ball of density ρ0 is released from the free surface of the 4
liquid. Then
a. The ball will execute S.H.M. of amplitude ρ0/α
b. The mean position of the ball will be at a depth ρ0/2 α
c. The ball will sink to a maximum depth of 2 ρ0/α
−−−
d. ρ
The time period of SHM is 2π√ α g
0
7. A block with mass M is connected by a massless spring with stiffness 4

constant k to a rigid wall and moves without friction on a horizontal surface.
The block oscillates with small amplitude A about an equilibrium position x0.
Consider two cases: (i) when the block is at x0; and (ii) when the block is at
x = x0 + A. In both the cases, a particle with
massm (< M) is softly place on the block after which they stick to each other.
Which of the following statements(s) is (are) true about the motion after the mass m is
placed on the mass M?
a. −− −−−
whereas in the
M
The amplitude of oscillation in the first case changes by a factor of√ ,
m + M
second case it remains unchanged

b. The final time period of oscillation in both the cases is same
c. The total energy decreases in both the cases
d. The instantaneous speed at x0 of the combined masses decreases in both the cases
8. A particle of mass m is attached to their identical springs A,B and C , each of force constant k as shown in the 4
figure. If the particle of mass m is pushed slightly against spring A and released, then the time period of
oscillation is :
−−
−
a. 2m
2π√
k
b. −−
−
k
2π√
2m
c. 2π √
−−
m
d. 2π√
−−
m
2k
9. The electric field intensity at the center of a uniformly charged hemispherical shell is E0. Now portions of the 4
hemisphere are cut from either side, and the remaining portion is shown in Fig. If α = β = π/3 , then the
electric field intensity at the center due to the remaining portion is

a. E0
b. E0
c. E0
d. Information insufficient
10. Find the force experienced by a semicircular wire having a charge q as shown in Fig. Radius of the wire is R, and 4
the line of charge with linear charge density λ passes through its center and is perpendicular to the plane of
wire.
a. λq
2
2π ε0 R
b. λq
2
π ε0 R
c. λq
2
4π ε0 R
d. λq
4πε0 R
Physics Section_II (Matrix Match) 16
1. Two charged particles of charges q1 and q2 are fixed on the x-axis at (a, 0) and (-a, 0) respectively and another 8
charged particle q3 is placed at the origin. q3 is slightly displaced along the direction mentioned.
Columns A Columns B
A) If q1 = q2 = +q and q3 = +Q and along x-axis P) Stable equilibrium
B) If q1 = q2 = –q and q3 = +Q and along y-axis Q) Unstable equilibrium
C) If q1 =q2 = +q and q3 = +Q and along y-axis R) Neutral equilibrium
D) If q1 = q2 = –q and q3 = +Q and along x-axis S) Execute oscillatory motion
2. A simple harmonic oscillator consists of a block attached to a spring with 8

k = 200 N/m. The block slides on a frictionless horizontal surface, with
equilibrium point x = 0. A graph of block’s velocity v as a function of time t is shown.
Correctly match the
2
required information in column I with the value given in column II (useπ = 10) :
Columns A Columns B
A) The block’s mass in kg P) -200
B) The block’s displacement at t = 0 in metres Q) 0.20
C) The block’s acceleration at t = 0 0.10 s in m/s2 R) 4.0
D) The block’s maximum kinetic energy in joules S) -0.20
Physics Section_III (Integer Type) 32
1. A non-conducting ring of radius 0.5m carries a total charge of 1.11×10

−10
C distributed non-uniformly on its 4
circumference producing an electric field E everywhere in space. The value of the line integral
⃗
l=0
∫
⃗
− E. d l (where l = 0 being centre of the ring) is _____V.
⃗
l=∞
2. A 1 μC charge is uniformly distributed on a thin spherical shell given by equationx2 + y 2 +z

2
= 25 . What 4
will be intensity of electric field (in SI unit) at a point (1,2,1)? (All the quantities are in S.I units)
3. An electron (of charge -e) revolves around a long wire with uniform charge density λin a circular path of radius r. 4
Its kinetic energy is given by . Find n.
λe
nπε0
4. A wire of linear charge density is bent in the form of quadrant of a circle of radius R and its center is O. A
λ 4
′
infinite wire of charge density λ is placed at 2R from O on the other side as shown. If O is null point, then =
′ λ

5. Two identical small charged spheres are suspended by strings of equal lengths. The strings make an angle of 4
300 with each other in air. When suspended in a liquid of density 0.8 g/cc, the angle remains same. If the density
of the material of the sphere is 1.6 g/cc, the dielectric constant of the liquid is _______.
6. A point charge having charge '-q' and mass 'm' is released at rest on the axis of a uniformly charged fix ring of 4
total charge 'Q' and radius 'R' from a distance √3 R. Its velocity when it reaches to centre of ring is
−−−−−−
N Qq
v=√ . Find the value of N
4π∈ mR
0
7. On a smooth table, a block of mass m=1 kg was attached as shown. The springs are both stretched in the 4
equilibrium position. The angular freuqency of small horizontal oscillations about the equilibrium position will
be ____ rad/sec.
−−
−
8. For given spring mass system, If the time period of small oscillations of block about its mean position is π√
nm
4
k
, then find n. Assume ideal conditions. The system is in vertical plane and take K1 =2K , K2 = K .
Chemistry Section_I (Multiple Type Answer) 40
1. Vapour pressure of solution containing 6g of a non-volatile solute in 180 g water is 20.0 torr. If 1 mole water is 4
further added, vapour pressure increases by 0.02 torr. Which of the following is true?
a. The molecular weight of solute is 54g mol-1
b. The vapour pressure of pure water is 20.22 torr
c. Addition of more water in the solution will further raise the vapour pressure of solution
d. The vapour pressure of pure water is 22.22 torr
2. For chloroform and acetone or for a solution of chloroform and acetone if Ps, (observed (actual)) is compared 4
with Ps (Theoretical (Raoult)), then which of the following is /are true ?
a. Ps(actual) <Ps(Raoult)
b. X limC hlorof orm → 0 (P
0
−Ps (actual)) =0
acetone
c. X limacetone
0
→ 0 (Pchlorof orm −P s (actual)) =0
d. P
0
>P
0
near room temperature
acetone chlorof orm
3. The incorrect statement is 4

a. Vapour pressure of a liquid always increases by increasing temperature.
b. Vapour pressure only depends on temperature and not on the nature of substance.
c. Vapour pressure does not depend on the quantity of the liquid taken and the surface area of the liquid.
d. Vapour pressure is not a colligative property & is independent of the concentration of the liquid.
4. An ideal mixture of liquids A and B with 2 moles of A and 2 moles of B has a total vapour pressure of 1 atm at a 4
certain temperature. Another mixture with 1 mole of A and 3 moles of B has a vapour pressure greater than 1
atm. But if 4 moles of C are added to the second mixture, the vapour pressure comes down to 1 atm. Vapour
pressure of C, PCo = 0.8 atm. Calculate the vapour pressures of pure A and pure B.
a. P
o
= 1.4 atm, PBo = 0.7 atm
A
b. P
o
= 1.2 atm, PBo = 0.6 atm
A
c. P
o
= 1.4 atm, PBo = 0.6 atm
A
d. P
o
= 0.6 atm, PBo = 1.4 atm
A
5. Select the correct statement(s). 4

a. KH (Henry’s law constant) is a function of nature of gases
b. Higher the value of KH at a given pressure, the lower is the solubility of the gas in the liquid.
c. KH increases with increase in temperature
d. KH increases with increase in partial pressure
6. In the following two graphs; temperature is plotted against mole fraction of the components of two different 4
azeotropic solutions.
Select the correct options.

a. Graph (I) represents maximum boiling point and minimum vapour pressure
b. Graph (II) represents minimum boiling point and maximum vapour pressure
c. Graph (I) represents minimum boiling point and maximum vapour pressure
d. Graph (II) represents maximum boiling point and minimum vapour pressure
7. Which of the following complexes have correct name? 4

a. K[Pt(NH3)Cl5] = potassium amminepentachloridoplatinate (IV)
b. [Ag(C N ) ]
−
= dicyanidoargentate (I) ion
2
c. K 3 [C r(C 2 O4 ) ] = tripotassium trioxalatochromate(III)

3
d. Na2[Ni(EDTA)] = sodium ethylenediaminetertraacetatonickel(II)
8. Which is/are the correctly named? 4

a. acac = Acetlacetonato, chelating, uninegative
b. bipy = 2,2′ bipyridine, bidentate, neutral
c. DMG = bidentate and neutral
d. gly = glycinato, bidentate, uninegative
9. Which statement(s) about anhydrous aluminium chloride is/are correct? 4

a. It exists as Al2Cl6 molecule in solid state
b. It is easily hydrolysed
c. It is sublimes at 1800 C
d. It reacts with air
10. Which of the following statements regarding beryllium and aluminium is/are correct? 4
a. They form covalent hydrides
b. Their oxides are amphoteric in nature
c. Their maximum covalency is always 4
d. They do not exhibit the same oxidation states
Chemistry Section_II (Matrix Match Type) 16
1. Match the Column I with Column II and mark the correct option from the codes given below. 8
Columns A Columns B
A) Sodium argentothiosulphate P) Neutral complex
B) P tC l4 ⋅ 5N H3 Q) Cationic complex
C) N a 2 Z nC l4 R) Anionic complex
D) [P t(N H3 ) 2 Br2 C l2 ] S) Heteroleptic complex
T) Homoleptic complex
2. Volatile component Vapour pressure at 350 K Molar mass 8

A 24 kPa 60 g mol-1
B 12 kPa 40 g mol-1
100 g of binary mixture of A and B contains 60% of A. Mixture is subjected to the following operation.
Distil Condense Distil
Original mixture I −−−→ II containing vapours of A and B −−−−−−→ III (liquid) −−−→ IV containing vapours of A
and B.
Match the content of Column I with their values in Column II.
Columns A Columns B
A) Mixture I P) 0.25
B) Mixture II Q) 0.50
C) Mixture III R) 0.67
D) Mixture IV S) 0.80
Chemistry Section_III (Integer Type) 32
1. The vapour pressure of a liquid solution containing A and B is 99 torr. Calculate mole percent of B in vapour 4
phase.
(Given : PA
o
= 100 torr; PBo = 80 torr)
2. Vapour pressure of a volatile liquid A is 60 torr at 270C. Vapour pressure of another volatile liquid B is 42 torr at 4
270C. How many moles of B should be added to 4 moles of A in order to bring down the vapour pressure of
solution by 20 percent at 270C ?
3. A solution of A(l) and B (l) with 30 mole percent of A is in equilibrium with its vapour which contain 60 mole 4
percent of A. Assuming ideality of the solution and its vapour calculate the ratio of vapour pressure of pure A to
that of pure B. (Report your answer as ratio ×2)
4. The concentration of O2 in water required to support aerobic aquatic life is about 3.856 mg dm-3. Minimum 4
partial pressure (in kPa) of oxygen in the atmosphere that can achieve this concentration is
(KH, Henry’s law constant of O2 = 74.68 kPa m3 mol-1)
5. Three moles of B2H6 are completely reacted with methanol. The number of moles of boron containing product 4
formed is :
6. In the complex P tC l4 ⋅ 5N H3 if coordination number of platinum is 6, number of chloride ions precipitated by 4

adding AgCl are
7. The number of B−O−B bond angles in a molecule of borax is ……… 4
8. The complex potassium dicyanodioxalatonickelate (II) in solution produce …… ions. 4
Mathematics Section_I (Multiple Type Answer) 40
1. ∣ a c c−a a+c ∣ 4
∣ ∣
∣ c b b−c b+c ∣
If Δ= , then which of the following can be true.
=0
∣ ∣
a−b b−c 0 a−c
∣ ∣
∣ x y z 1+x+y ∣
a. a, b, c are in A.P.
b. b, a, c are in A.P.
c. a, c, b are in G.P.
d. a, c, b are in H.P.
2. If x, y, satisfy the following system of equations x+y+z+w=1 ; x+2y+4z+8w=16;

z, w ∈ R 4
x+3y+9z+27w=81 and x+4y+16z+64w=256, then the pairs which has H.C.F. as 2 is
a. (|w| , |z|)
b. (|z| , |y|)
c. (|y| , |x|)
d. (|z| , |x|)
3. If f : R → R, f (x)=x3 −ax2 +(2a−3)x+5, a ∈ R is a bijective function, then : 4

{Note : [k] denotes greatest integer function less than or equal to k.}
a. The value of a is equal to 3.
b. The value of a is equal to -3.
c. limx→0 [
sin ax
] =2
x
d. limx→0 [
x
] =2
sin ax
4. Consider, f (x)=(x2 −1)

1/3
for x < 0, g(x)= −(x +1)
3
1/2
for x > -1. Identify which of the following 4
statement(s) is(are) correct?
a. The range of f (f (x)) is (−1, 0) .
b. The domain of g (g(x)) is (−1, 0) .
c. f
−1
og
−1
(x)=x∀x ∈ (−∞, 0)
d. g
−1
of
−1
(x)=x∀x ∈ (−1, ∞)
5. The maximum value of the function defined by f (x)= min (e

x 2
, 2+e −x, 8) is α , then integer value of x 4
x(x−[α])
satisfying the inequality 2
<0 , is :
x −[α]x+12
{Note : [k] denotes greatest integer function less than or equal to k.}
a. 1
b. 3
c. 5
d. 6
6. ∣ cos(θ+α) − sin(θ+α) cos 2α ∣ 4

∣ ∣
The value of the determinant sin θ cos θ sin α is
∣ ∣
∣ − cos θ sin θ λ cos α ∣
a. independent of θ for all λ ∈ R
b. independent of θ and α when λ=1

c. independent of θ and α when λ= −1
d. independent of λ for all θ
7. System of equation x + 3y + 2z = 6 4
x+λy+2z=7
x + 3y + 2z = μ has
a. Unique solution if λ=2, μ ≠ 6
b. infinitely many solution if λ=4, μ=6
c. no solution if λ=5, μ=7
d. no solution if λ=3, μ=5
8. Let a, b, c, be real number such that a 2 +b

2
+c =1
2
then 4
∣ ax−bx−c bx+ay cx+a ∣
∣ ∣
bx+ay −ax+by−c cy+b =0 is a
∣ ∣
∣ cx+a cy+b −ax−by+c ∣
a. Straight line
b. Point circle
c. Parabola
d. Ellipse
9. ∣ 3 3x
2
3x +2a
2
∣ 4
∣ ∣
3x 3x +2a
2 2 3
3x +6a x
2
then
∣ ∣
2 2 3 2 4 2 2 4
∣ 3x +2a 3x +6a x 3x +12a x +2a ∣
a. f (x)=0
′
b. f(x) is independent of x.
c. 1
6
∫ f (x)dx=4a
0
d. y
2
=f (x) represents a pair of lines
10. ∣ x −6 −1 ∣ 4
∣ ∣
Let f (x)= 2 −3x x−3 and α<β<γ be the roots of f(x) = 0. Then
∣ ∣
∣ −3 2x x+2 ∣
a. γ=2
b. f(x) < 0 for α<x<β

c. f(x) > 0 for β<x<γ
d. f(x) > 0 for α<x<β
Mathematics Section_II (Matrix Match Type) 16
1. ∣ −√2 sin θ cos θ ∣ ∣ sin 2θ −1 1 ∣ 8

∣ ∣ ∣ ∣
Let p(θ)= 1 cos θ sin θ , q(θ)= cos 2θ 4 −3 ,
∣ ∣ ∣ ∣
∣ −1 sin θ − cos θ ∣ ∣ 2 7 −5 ∣
∣ cos θ sin θ cos θ ∣ ∣ sec 2 θ 1 1 ∣

∣ ∣ ∣ 2 2 2
∣
r(θ)= − sin θ cos θ sin θ , and s(θ)= cos θ cos θ cosec θ
∣ ∣ ∣ ∣
2 2
∣ − cos θ − sin θ cos θ ∣ ∣ 1 cos θ cot θ ∣
Match the functions on the left their range on the right.

Columns A Columns B
A) p(θ) P) [0, 1]
B) q(θ) Q) [0, 2√2]
C) r(θ) R) [−2, 2]
D) s(θ) S) [−√5−2, √5−2]
2. Match the parameter on which the value of the determinant does not depend upon 8
Columns A Columns B
A) ∣ 1 x ∣ x
2
P) a
∣ ∣
∣ cos(a−b)y cos ay cos(a+b)y ∣
∣ ∣
∣ sin(a−b)y sin ay sin(a+b)y ∣
B) ∣ x2 +y 2 ax+by x+y ∣ Q) b
∣ 2
∣
2
ax+by a +b a+b
∣ ∣
∣ x+y a+b 2 ∣
C) ∣ 1 a
2
a +b ∣ R) x
∣ ∣
2
∣1 b b +a ∣
∣ ∣
∣1 1 1+ab ∣
D) ∣ a 2 +(b2 +x2 ) cos y S) y

∣
1
3
∣ ab(1− cos y)
2 2 2
(a +b +x ) ∣
∣ ax(1− cos y)
ab(1− cos y) ax(1− cos y) ∣

∣
2 2 2
b +(x +a ) cos y bx(1− cos y) ∣
∣
2 2 2
bx(1− cos y) x +(a +b ) cos y ∣
Mathematics Section_III (Integer Type) 32
1. Find the smallest value of (

−8p
) for which 4
7
2
|x −5x+7−p|=6+|x −5x+1−p| f or all x ∈ [−1, 3]
2
.
2. ∣ f (x+1) f (x+8) f (x+1) ∣ 4

∣ ∣
If f(x) satisfies the equation 1 2 −5 =0 for all real x. If f is periodic with period 7,
∣ ∣
∣ 2 3 λ ∣
then find the value of |λ|
3. ∣ cos x sin x sin x ∣ 4

∣ ∣
The number of distinct real roots of the equation sin x cos x sin x =0 which lies in the interval
∣ ∣
∣ sin x sin x cos x ∣
is _____
−π π
≤ x ≤
4 4
4. ∣ a1 a2 a3 ∣ 4
∣ ∣
If a 1 ,a 2 ,a 3 ,5,4,a 6 ,a 7 ,a 8 ,a 9 are in H.P., then the value of the determinant 5 4 a6 can be expressed
∣ ∣
∣ a7 a8 a9 ∣
p
in the lowest form as q
, find (p - 2q).
5. ∣ 1 3 cos q 1 ∣
3
4
∣ ∣ |maximum value of D - Minimum value of D|
If D= sin q 1 3 cos q , then the is equal to
∣ ∣ 250
∣ 1 sin q 1 ∣
6. The system of equation 2x+3y−z=0, 3x+2y+kz=0, 4x+y+z=0 have a set of nonzero integral 4
solution then the least positive value of z is ______
7. If a(5sin2 θ−11)= −sin

2
θ+8 sin θ−9 , where a, θ ∈ R, then find the maximum value of a. 4
8. If −2 ≤ [x]<2, −1 ≤ [y]<1, −3 ≤ [z]<3 , where [x] denotes greatest integer function and the minimum 4
∣ [x]+1 [y] [z] ∣
∣ ∣
value of ∣ [x] [y]+1 [z] ∣ is equals to K then |K | equals to
∣ ∣
∣ [x] [y] [z]+1 ∣

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TM

S-Beta, S-Edison, S-Thomsan

Physics Electrostatics Till Field Lines & SHM

Solutions Till Lec 6 Group 13 Coordination Compound, Till Nomenclature

Physics Section_I (Multiple Type Answer) 40

a. The maximum speed of the block will be QE

b. The maximum speed of the block will be 2QE

c. The maximum compression of the spring will be QE

d. The maximum compression of the spring will be 2QE

5. Electric ﬁeld given by the vector E=x

7. A block with mass M is connected by a massless spring with stiﬀness 4

second case it remains unchanged

Physics Section_II (Matrix Match) 16

B) If q1 = q2 = –q and q3 = +Q and along y-axis Q) Unstable equilibrium

C) If q1 =q2 = +q and q3 = +Q and along y-axis R) Neutral equilibrium

D) If q1 = q2 = –q and q3 = +Q and along x-axis S) Execute oscillatory motion

2. A simple harmonic oscillator consists of a block attached to a spring with 8

B) The block’s displacement at t = 0 in metres Q) 0.20

C) The block’s acceleration at t = 0 0.10 s in m/s2 R) 4.0

D) The block’s maximum kinetic energy in joules S) -0.20

Physics Section_III (Integer Type) 32

1. A non-conducting ring of radius 0.5m carries a total charge of 1.11×10

2. A 1 μC charge is uniformly distributed on a thin spherical shell given by equationx2 + y 2 +z

Chemistry Section_I (Multiple Type Answer) 40

3. The incorrect statement is 4

5. Select the correct statement(s). 4

Select the correct options.

7. Which of the following complexes have correct name? 4

c. K 3 [C r(C 2 O4 ) ] = tripotassium trioxalatochromate(III)

d. Na2[Ni(EDTA)] = sodium ethylenediaminetertraacetatonickel(II)

8. Which is/are the correctly named? 4

9. Which statement(s) about anhydrous aluminium chloride is/are correct? 4

Chemistry Section_II (Matrix Match Type) 16

D) [P t(N H3 ) 2 Br2 C l2 ] S) Heteroleptic complex

2. Volatile component Vapour pressure at 350 K Molar mass 8

C) Mixture III R) 0.67

Chemistry Section_III (Integer Type) 32

6. In the complex P tC l4 ⋅ 5N H3 if coordination number of platinum is 6, number of chloride ions precipitated by 4

7. The number of B−O−B bond angles in a molecule of borax is ……… 4

8. The complex potassium dicyanodioxalatonickelate (II) in solution produce …… ions. 4

Mathematics Section_I (Multiple Type Answer) 40

2. If x, y, satisfy the following system of equations x+y+z+w=1 ; x+2y+4z+8w=16;

3. If f : R → R, f (x)=x3 −ax2 +(2a−3)x+5, a ∈ R is a bijective function, then : 4

4. Consider, f (x)=(x2 −1)

5. The maximum value of the function deﬁned by f (x)= min (e

6. ∣ cos(θ+α) − sin(θ+α) cos 2α ∣ 4

a. independent of θ for all λ ∈ R

b. independent of θ and α when λ=1

d. independent of λ for all θ

b. inﬁnitely many solution if λ=4, μ=6

c. no solution if λ=5, μ=7

d. no solution if λ=3, μ=5

8. Let a, b, c, be real number such that a 2 +b

b. f(x) < 0 for α<x<β

Mathematics Section_II (Matrix Match Type) 16

1. ∣ −√2 sin θ cos θ ∣ ∣ sin 2θ −1 1 ∣ 8

∣ cos θ sin θ cos θ ∣ ∣ sec 2 θ 1 1 ∣

Match the functions on the left their range on the right.

B) q(θ) Q) [0, 2√2]

D) s(θ) S) [−√5−2, √5−2]

D) ∣ a 2 +(b2 +x2 ) cos y S) y

ab(1− cos y) ax(1− cos y) ∣

Mathematics Section_III (Integer Type) 32