SBA15

Micromeritics Instrument Corporation
Gemini VII 2390 V1.02 (V1.02 t) Unit 1 Serial #: 188 Page 1
Sample: SBA15-120
Operator: Quan
Submitter: SV Co Nam
File: D:\HUNGDO\BETFIL~1\002-460.SMP
Started: 4/27/2018 4:37:27PM Analysis Adsorptive: N2

Completed: 4/28/2018 3:03:12AM Equilibration Time: 5s
Report Time: 3/21/2019 4:54:32PM Sat. Pressure: 770.873 mmHg
Free Space Diff.: -0.2067 cm³ Sample Mass: 0.0465 g
Free Space Type: Measured Sample Density: 1.000 g/cm³
Evac. Rate: 1000.0 mmHg/min Gemini Model: 2390 t
Summary Report
Surface Area
Single point surface area at P/Po = 0.300137970: 619.7909 m²/g
BET Surface Area: 631.6035 m²/g
BJH Adsorption cumulative surface area of pores

between 17.000 Å and 3000.000 Å width: 575.110 m²/g
Pore Volume
BJH Adsorption cumulative volume of pores
between 17.000 Å and 3000.000 Å width: 1.259470 cm³/g
BJH Desorption cumulative volume of pores

between 17.000 Å and 3000.000 Å width: 1.437835 cm³/g
Pore Size
BJH Adsorption average pore width (4V/A): 87.599 Å
BJH Desorption average pore width (4V/A): 85.969 Å

Sample: SBA15-120
Operator: Quan

Isotherm Tabular Report

Relative Absolute Quantity Elapsed Time Saturation
Pressure (P/Po) Pressure Adsorbed (h:min) Pressure
(mmHg) (cm³/g STP) (mmHg)
00:41 770.178955
0.049897424 38.419552 142.3388 00:48 769.970642
0.074659390 57.488888 152.2146 00:52 770.015503
0.099631741 76.733650 160.1650 00:55 770.172729
0.124618061 95.962357 167.0097 00:59 770.051758
0.149700038 115.303421 173.1557 01:02 770.229736
0.174886872 134.683472 178.8545 01:05 770.117676
0.199824582 153.894760 184.2019 01:09 770.149292
0.249806715 192.376877 194.0912 01:12 770.102905
0.300137970 231.108032 203.4343 01:16 770.005981
0.350364983 269.845062 212.5711 01:20 770.182739
0.400874941 308.738861 221.7188 01:24 770.162537
0.450347880 346.827240 231.0051 01:28 770.131836
0.500357095 385.232239 240.9980 01:32 769.914612
0.550032624 423.658936 251.9959 01:37 770.243286
0.600427962 462.489532 264.4366 01:42 770.266479
0.650529409 501.012665 278.9159 01:48 770.161438
0.700113700 539.350220 296.6272 01:54 770.375183
0.750569152 578.301758 322.1326 02:04 770.484314
0.800653139 617.117432 458.4248 02:51 770.767517
0.826324679 636.771729 523.0736 03:14 770.607178
0.850710592 655.865051 540.7209 03:20 770.961426
0.876330908 675.425415 557.4541 03:26 770.742432
0.900861760 694.513062 574.9280 03:32 770.942993
0.920998241 710.127869 592.4883 03:39 771.041504
0.941113075 725.599731 614.7952 03:47 771.001648
0.950885940 733.260742 630.3126 03:54 771.134277
0.960928320 741.060425 651.8431 04:04 771.192200
0.970522139 748.834778 681.0745 04:16 771.579285
0.980924209 757.018799 729.5338 04:30 771.740356
0.985720414 760.973633 776.3653 04:51 771.997437
0.990971970 765.120361 819.4071 05:08 772.090820
1.001332385 773.322266 1337.1101 05:22 772.293274
0.991638470 765.853394 914.9366 06:23 772.311096
0.985999043 761.529236 873.0466 06:40 772.342773
0.981521182 757.794739 851.3495 06:52 772.061523
0.971353460 749.712524 820.5927 07:04 771.822571
0.965549490 745.410217 809.9091 07:10 772.006226
0.961450995 741.952332 803.3056 07:14 771.700623
0.950983906 734.021606 790.1068 07:20 771.854919
0.941039377 726.348572 780.6149 07:24 771.857788
0.931293189 718.733704 772.5708 07:28 771.758789
0.921225029 710.950806 763.8081 07:32 771.744995
0.901502860 695.541260 748.4804 07:37 771.535278
0.875944203 676.104248 730.0166 07:43 771.857666
Sample: SBA15-120
Operator: Quan

Isotherm Tabular Report

Relative Absolute Quantity Elapsed Time Saturation
Pressure (P/Po) Pressure Adsorbed (h:min) Pressure
(mmHg) (cm³/g STP) (mmHg)
0.851821790 657.123840 710.7955 07:50 771.433472

0.826933450 637.599304 687.8972 07:58 771.040649
0.800964621 617.809326 661.0091 08:07 771.331604
0.750943405 579.370850 599.5743 08:20 771.523987
0.701736393 540.724854 343.5315 09:23 770.552673
0.650991638 501.704681 314.3333 09:33 770.677612
0.601752756 463.305328 293.5011 09:40 769.926392
0.550644856 424.306580 274.2588 09:46 770.563049
0.501228912 386.168793 255.3791 09:53 770.443970
0.451486816 347.750610 233.7983 09:59 770.234253
0.400509823 308.562286 223.7293 10:03 770.423767
0.351805257 270.938232 214.7282 10:07 770.136963
0.301323820 232.141754 205.5701 10:11 770.406250
0.251281056 193.541504 196.2634 10:15 770.219238
0.201324997 155.108414 186.3581 10:18 770.437927
0.100086346 77.072205 162.1474 10:24 770.057129
Sample: SBA15-120
Operator: Quan

Isotherm Linear Plot

SBA15-120 - Adsorption
SBA15-120 - Desorption
1,200
1,000
Quantity Adsorbed (cm³/g STP)
800
600
400
200
0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
Relative Pressure (P/Po)
Sample: SBA15-120
Operator: Quan

BET Surface Area Report

BET Surface Area: 631.6035 ± 9.0861 m²/g
Slope: 0.006890 ± 0.000098 g/cm³ STP
Y-Intercept: 0.000002 ± 0.000017 g/cm³ STP
C: 3554.559849
Qm: 145.0895 cm³/g STP
Correlation Coefficient: 0.9992978
Molecular Cross-Sectional Area: 0.1620 nm²
Relative Quantity 1/[Q(Po/P - 1)]
Pressure Adsorbed
(P/Po) (cm³/g STP)
0.049897424 142.3388 0.000369

0.074659390 152.2146 0.000530
0.099631741 160.1650 0.000691
0.124618061 167.0097 0.000852
0.149700038 173.1557 0.001017
0.174886872 178.8545 0.001185
0.199824582 184.2019 0.001356
0.249806715 194.0912 0.001716
0.300137970 203.4343 0.002108
Sample: SBA15-120
Operator: Quan

BET Surface Area Plot

SBA15-120
0.0020
0.0018
0.0016
0.0014
1/[Q(Po/P - 1)]
0.0012
0.0010
0.0008
0.0006
0.0004
0.0002
0.0000
0.00 0.05 0.10 0.15 0.20 0.25 0.30
Relative Pressure (P/Po)
Sample: SBA15-120
Operator: Quan

BJH Adsorption Pore Distribution Report

Faas Correction
Halsey
t = 3.54 [ -5 / ln(P/Po) ] ^ 0.333
Width Range: 17.000 Å to 3000.000 Å
Adsorbate Property Factor: 9.53000 Å
Density Conversion Factor: 0.0015468
Fraction of Pores Open at Both Ends: 0.00
Pore Width Average Width Incremental Cumulative Incremental Cumulative
Range (Å) (Å) Pore Volume Pore Volume Pore Area Pore Area
(cm³/g) (cm³/g) (m²/g) (m²/g)
2159.9 - 1375.2 1598.7 0.070940 0.070940 1.775 1.775

1375.2 - 1035.0 1156.9 0.078040 0.148980 2.698 4.473
1035.0 - 676.2 781.5 0.081605 0.230585 4.177 8.650
676.2 - 513.9 572.5 0.049742 0.280327 3.476 12.126
513.9 - 411.5 450.9 0.036976 0.317303 3.280 15.406
411.5 - 345.1 372.2 0.026841 0.344144 2.885 18.290
345.1 - 259.7 289.8 0.039132 0.383276 5.401 23.691
259.7 - 208.5 228.1 0.031561 0.414837 5.534 29.225
208.5 - 168.4 183.9 0.032258 0.447095 7.018 36.243
168.4 - 140.3 151.6 0.032072 0.479167 8.463 44.706
140.3 - 121.2 129.2 0.035613 0.514781 11.025 55.731
121.2 - 106.0 112.4 0.144757 0.659538 51.505 107.236
106.0 - 85.0 92.9 0.317665 0.977202 136.762 243.999
85.0 - 70.8 76.4 0.044063 1.021265 23.069 267.067
70.8 - 60.6 64.8 0.028148 1.049413 17.382 284.450
60.6 - 52.8 56.0 0.022283 1.071696 15.906 300.356
52.8 - 46.5 49.2 0.018887 1.090583 15.370 315.726
46.5 - 41.5 43.6 0.016887 1.107470 15.484 331.210
41.5 - 37.2 39.0 0.015229 1.122699 15.605 346.815
37.2 - 33.6 35.1 0.014448 1.137147 16.442 363.257
33.6 - 30.3 31.7 0.014744 1.151891 18.577 381.834
30.3 - 27.5 28.7 0.015785 1.167676 21.987 403.821
27.5 - 24.9 26.0 0.017140 1.184816 26.386 430.207
24.9 - 22.4 23.5 0.019784 1.204600 33.728 463.935
22.4 - 21.2 21.8 0.011512 1.216112 21.134 485.070
21.2 - 20.1 20.6 0.012588 1.228700 24.433 509.503
20.1 - 18.9 19.4 0.014141 1.242841 29.116 538.619
18.9 - 17.7 18.2 0.016629 1.259470 36.491 575.110
Sample: SBA15-120
Operator: Quan

BJH Adsorption Cumulative Pore Volume (Larger)

Halsey : Faas Correction
SBA15-120
1.2
1.0
0.8
Pore Volume (cm³/g)
0.6
0.4
0.2
0.0
10 50 100 500 1,000
Pore Width (Å)
Sample: SBA15-120
Operator: Quan

BJH Adsorption dV/dlog(w) Pore Volume

SBA15-120
3.0
2.5
dV/dlog(w) Pore Volume (cm³/g·Å)
2.0
1.5
1.0
0.5
0.0
10 50 100 500 1,000
Pore Width (Å)
Sample: SBA15-120
Operator: Quan

BJH Adsorption Cumulative Pore Area (Larger)

SBA15-120
550
500
450
400
350
Pore Area (m²/g)
300
250
200
150
100
50
0
10 50 100 500 1,000
Pore Width (Å)
Sample: SBA15-120
Operator: Quan

BJH Adsorption dA/dlog(w) Pore Area

SBA15-120
1,200
1,000
dA/dlog(w) Pore Area (m²/g·Å)
800
600
400
200
0
10 50 100 500 1,000
Pore Width (Å)
Sample: SBA15-120
Operator: Quan

BJH Desorption Pore Distribution Report

Faas Correction
Halsey
t = 3.54 [ -5 / ln(P/Po) ] ^ 0.333
Width Range: 17.000 Å to 3000.000 Å
Adsorbate Property Factor: 9.53000 Å
Density Conversion Factor: 0.0015468
Fraction of Pores Open at Both Ends: 0.00
Pore Width Average Width Incremental Cumulative Incremental Cumulative
Range (Å) (Å) Pore Volume Pore Volume Pore Area Pore Area
(cm³/g) (cm³/g) (m²/g) (m²/g)
2329.1 - 1401.5 1644.7 0.068896 0.068896 1.676 1.676

1401.5 - 1067.1 1188.8 0.035878 0.104775 1.207 2.883
1067.1 - 694.8 803.6 0.051584 0.156359 2.568 5.451
694.8 - 580.3 627.0 0.017934 0.174293 1.144 6.595
580.3 - 520.1 546.8 0.011169 0.185462 0.817 7.412
520.1 - 411.7 452.9 0.022534 0.207996 1.990 9.402
411.7 - 344.1 371.6 0.016347 0.224343 1.760 11.162
344.1 - 296.6 316.6 0.014047 0.238390 1.774 12.936
296.6 - 259.8 275.6 0.015704 0.254094 2.279 15.215
259.8 - 209.2 228.7 0.028109 0.282203 4.915 20.131
209.2 - 167.3 183.3 0.035040 0.317244 7.648 27.778
167.3 - 140.8 151.6 0.038083 0.355326 10.051 37.829
140.8 - 121.0 129.3 0.047249 0.402576 14.622 52.451
121.0 - 105.5 112.1 0.057505 0.460081 20.519 72.970
105.5 - 84.6 92.5 0.138562 0.598644 59.936 132.907
84.6 - 70.6 76.1 0.639857 1.238501 336.141 469.047
70.6 - 60.1 64.4 0.043865 1.282366 27.254 496.302
60.1 - 52.4 55.6 0.027002 1.309367 19.421 515.723
52.4 - 46.0 48.7 0.025587 1.334954 21.022 536.745
46.0 - 41.0 43.1 0.029432 1.364386 27.299 564.044
41.0 - 36.7 38.5 0.041729 1.406115 43.301 607.345
36.7 - 33.0 34.6 0.001459 1.407573 1.687 609.032
33.0 - 29.9 31.2 0.000669 1.408243 0.858 609.890
29.9 - 27.0 28.2 0.001101 1.409344 1.561 611.451
27.0 - 24.3 25.5 0.002502 1.411846 3.929 615.379
24.3 - 21.9 23.0 0.004800 1.416646 8.363 623.743
21.9 - 17.1 18.7 0.021189 1.437835 45.263 669.005
Sample: SBA15-120
Operator: Quan

BJH Desorption dV/dw Pore Volume

SBA15-120
0.045
0.040
0.035
0.030
Pore Volume (cm³/g·Å)
0.025
0.020
0.015
0.010
0.005
0.000
10 50 100 500 1,000
Pore Width (Å)
Sample: SBA15-120
Operator: Quan

BJH Desorption dV/dlog(w) Pore Volume

SBA15-120
8
6
dV/dlog(w) Pore Volume (cm³/g·Å)
0
10 50 100 500 1,000
Pore Width (Å)
Sample: SBA15-120
Operator: Quan

BJH Desorption dA/dw Pore Area

SBA15-120
25
20
15
Pore Area (m²/g·Å)
10
0
10 50 100 500 1,000
Pore Width (Å)
Sample: SBA15-120
Operator: Quan

BJH Desorption dA/dlog(w) Pore Area

SBA15-120
4,000
3,500
3,000
dA/dlog(w) Pore Area (m²/g·Å)
2,500
2,000
1,500
1,000
500
0
10 50 100 500 1,000
Pore Width (Å)
Sample: SBA15-120
Operator: Quan

Options Report
Analysis Conditions
Preparation
Evacuation rate: 1000.0 mmHg/min
Evacuation time: 10.00 min
Free Space
Free-space type: Measured
Po and Temperature
Po and T type: Measure Po in the Po tube for each isotherm point. Enter
the Analysis Bath Temperature below.
Temperature: -195.850 °C
Analysis Method
Analysis Mode: Equilibration
Equilibration time: 5 s
Degas Conditions
Sample Prep: Temperature Ramp Rate Time (min)
Stage (%s) (%s/min)
1 80 10 10
2 120 10 60
3 200 10 10
4 300 10 240
Adsorptive Properties
Adsorptive: Nitrogen
Maximum manifold pressure: 1050.00 mmHg
Non-ideality factor: 0.0000620
Density conversion factor: 0.0015468
Molecular cross-sectional area: 0.162 nm²

SBA15

Hochgeladen von

Dokumentinformationen

Copyright

Verfügbare Formate

Dieses Dokument teilen

Dokument teilen oder einbetten

Freigabeoptionen

Stufen Sie dieses Dokument als nützlich ein?

Sind diese Inhalte unangemessen?

Copyright:

Verfügbare Formate

SBA15

Hochgeladen von

Copyright:

Verfügbare Formate

Micromeritics Instrument Corporation

Gemini VII 2390 V1.02 (V1.02 t) Unit 1 Serial #: 188 Page 1

Started: 4/27/2018 4:37:27PM Analysis Adsorptive: N2

BET Surface Area: 631.6035 m²/g

BJH Adsorption cumulative surface area of pores

BJH Desorption cumulative volume of pores

BJH Desorption average pore width (4V/A): 85.969 Å

Started: 4/27/2018 4:37:27PM Analysis Adsorptive: N2

Isotherm Tabular Report

Started: 4/27/2018 4:37:27PM Analysis Adsorptive: N2

Isotherm Tabular Report

0.851821790 657.123840 710.7955 07:50 771.433472

Started: 4/27/2018 4:37:27PM Analysis Adsorptive: N2

Isotherm Linear Plot

Started: 4/27/2018 4:37:27PM Analysis Adsorptive: N2

BET Surface Area Report

0.049897424 142.3388 0.000369

Started: 4/27/2018 4:37:27PM Analysis Adsorptive: N2

BET Surface Area Plot

Started: 4/27/2018 4:37:27PM Analysis Adsorptive: N2

BJH Adsorption Pore Distribution Report

2159.9 - 1375.2 1598.7 0.070940 0.070940 1.775 1.775

Started: 4/27/2018 4:37:27PM Analysis Adsorptive: N2

BJH Adsorption Cumulative Pore Volume (Larger)

Started: 4/27/2018 4:37:27PM Analysis Adsorptive: N2

BJH Adsorption dV/dlog(w) Pore Volume

Started: 4/27/2018 4:37:27PM Analysis Adsorptive: N2

BJH Adsorption Cumulative Pore Area (Larger)

Started: 4/27/2018 4:37:27PM Analysis Adsorptive: N2

BJH Adsorption dA/dlog(w) Pore Area

Started: 4/27/2018 4:37:27PM Analysis Adsorptive: N2

BJH Desorption Pore Distribution Report

2329.1 - 1401.5 1644.7 0.068896 0.068896 1.676 1.676

Started: 4/27/2018 4:37:27PM Analysis Adsorptive: N2

BJH Desorption dV/dw Pore Volume

Started: 4/27/2018 4:37:27PM Analysis Adsorptive: N2

BJH Desorption dV/dlog(w) Pore Volume

Started: 4/27/2018 4:37:27PM Analysis Adsorptive: N2

BJH Desorption dA/dw Pore Area

Started: 4/27/2018 4:37:27PM Analysis Adsorptive: N2

BJH Desorption dA/dlog(w) Pore Area

Started: 4/27/2018 4:37:27PM Analysis Adsorptive: N2

Das könnte Ihnen auch gefallen