Beruflich Dokumente
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2 Hazards identification
· Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008
GHS02 flame
GHS07
Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects.
· Classification according to Directive 67/548/EEC or Directive 1999/45/EC
T; Toxic
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Xn; Harmful
R20/21-65: Harmful by inhalation and in contact with skin. Harmful: may cause lung damage if swallowed.
Xi; Irritant
F; Highly flammable
R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
· Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification guideline for
preparations of the EU" in the latest valid version.
· Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and literature
data.
· Label elements
· Labelling according to EU guidelines:
The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous
Materials.
· Code letter and hazard designation of product:
T Toxic
F Highly flammable
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· Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
3 Composition/information on ingredients
· Chemical characterization: Mixtures
· Description: Mixture of substances listed below with nonhazardous additions.
· Dangerous components:
CAS: 1330-20-7 xylene 25-50%
EINECS: 215-535-7 Xn R20/21; Xi R38
R10
Flam. Liq. 3, H226; Acute Tox. 4, H312; Acute Tox. 4, H332; Skin Irrit.
2, H315
CAS: 64742-95-6 Solvent naphtha (petroleum), light arom. 10-25%
EINECS: 265-199-0 T Carc. Cat. 2, Muta. Cat. 2 R45-46; Xn R65
Carc. 1B, H350; Asp. Tox. 1, H304
CAS: 95-63-6 1,2,4-trimethylbenzene 2.5-10%
EINECS: 202-436-9 Xn R20; Xi R36/37/38; N R51/53
R10
Flam. Liq. 3, H226; Aquatic Chronic 2, H411; Acute Tox. 4, H332;
Skin Irrit. 2, H315; Eye Irrit. 2, H319; STOT SE 3, H335
CAS: 64742-88-7 Solvent naphtha (petroleum), medium aliph. 2.5-10%
EINECS: 265-191-7 Xn R65
R10
Asp. Tox. 1, H304
CAS: 108-67-8 mesitylene 2.5-10%
EINECS: 203-604-4 Xi R37; N R51/53
R10
Flam. Liq. 3, H226; Aquatic Chronic 2, H411; STOT SE 3, H335
CAS: 98-82-8 cumene ≤ 2.5%
EINECS: 202-704-5 Xn R65; Xi R37; N R51/53
R10
Flam. Liq. 3, H226; Asp. Tox. 1, H304; Aquatic Chronic 2, H411;
STOT SE 3, H335
· Additional information:
For the wording of the listed risk phrases refer to section 16.
CAS: 7429-90-5 aluminium powder (pyrophoric) 2.5-10%
EINECS: 231-072-3 F R11-15
Pyr. Sol. 1, H250; Water-react. 2, H261
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· After inhalation:
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms
persist.
In case of unconsciousness place patient stably in side position for transportation.
· After skin contact: Immediately wash with water and soap and rinse thoroughly.
· After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.
· After swallowing: If symptoms persist consult doctor.
· Information for doctor:
· Most important symptoms and effects, both acute and delayed No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Firefighting measures
· Extinguishing media
· Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· Special hazards arising from the substance or mixture No further relevant information available.
· Advice for firefighters
· Protective equipment: Mouth respiratory protective device.
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Avoid contact with the skin.
Avoid contact with the eyes and skin.
· Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure
use self-contained respiratory protective device.
· Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
application.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection:
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11 Toxicological information
· Information on toxicological effects
· Acute toxicity:
· LD/LC50 values relevant for classification:
1330-20-7 xylene
Oral LD50 4300 mg/kg (rat)
Dermal LD50 2000 mg/kg (rabbit)
64742-95-6 Solvent naphtha (petroleum), light arom.
Oral LD50 >6800 mg/kg (rat)
Dermal LD50 >3400 mg/kg (rab)
(Contd. on page 8)
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Inhalative LC50/4 h >10.2 mg/l (rat)
95-63-6 1,2,4-trimethylbenzene
Oral LD50 5000 mg/kg (rat)
98-82-8 cumene
Oral LD50 1400 mg/kg (rat)
Dermal LD50 12300 mg/kg (rabbit)
Inhalative LC50/4 h 24.7 mg/l (mouse)
· Primary irritant effect:
· on the skin: Irritant to skin and mucous membranes.
· on the eye: No irritating effect.
· Sensitization: No sensitizing effects known.
· Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EU Classification
Guidelines for Preparations as issued in the latest version:
Harmful
Irritant
Carcinogenic.
The product can cause inheritable damage.
12 Ecological information
· Toxicity
· Aquatic toxicity: No further relevant information available.
· Persistence and degradability No further relevant information available.
· Behaviour in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Ecotoxical effects:
· Remark: Harmful to fish
· Additional ecological information:
· General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Harmful to aquatic organisms
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.
13 Disposal considerations
· Waste treatment methods
· Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
(Contd. on page 9)
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· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.
14 Transport information
· UN-Number
· ADR, IMDG, IATA UN1263
· UN proper shipping name
· ADR 1263 PAINT, special provision 640E
· IMDG, IATA PAINT
· Transport hazard class(es)
· ADR
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15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the substance or mixture
· Philippines Inventory of Chemicals and Chemical Substances
All ingredients are listed.
· National regulations:
· Information about limitation of use:
Workers are not allowed to be exposed to the hazardous carcinogenic materials contained in this preparation.
Exceptions can be made by the authorities in certain cases.
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
* 16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
· Relevant phrases
H226 Flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H350 May cause cancer.
H411 Toxic to aquatic life with long lasting effects.
R10 Flammable.
R20 Harmful by inhalation.
R20/21 Harmful by inhalation and in contact with skin.
R36/37/38 Irritating to eyes, respiratory system and skin.
R37 Irritating to respiratory system.
R38 Irritating to skin.
R45 May cause cancer.
R46 May cause heritable genetic damage.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R65 Harmful: may cause lung damage if swallowed.
· Department issuing MSDS:
Safety, Health and Environment Department
Gretchen A. Fontejon - g_fontejon@boysen.com.ph
· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the
International Transport of Dangerous Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
ICAO: International Civil Aviation Organization
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
· * Data compared to the previous version altered.
25.02.2012
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