MSDS - Formalin 45 LM - US - Usa-1996

Safety data sheet
Issue Date 21-Mar-2018 Revision Date 21-Mar-2018 Version 2
1. IDENTIFICATION
Product identifier
Product Name
Formalin 45 LM - US
Chemical Name CAS No
Formaldehyde 50-00-0
Other means of identification

Synonyms Formaldehyde solution
Pure substance/mixture Substance
Recommended use of the chemical and restrictions on use

Application Chemical intermediate
Uses advised against Consumer use
Details of the supplier of the safety data sheet

Manufacturer Address
Perstorp Polyols, Inc.

600 Matzinger Road
Toledo, Ohio 43612
Phone: 419-729-5448
800-537-0280
Fax: 419-729-3291
www.perstorp.com
E-mail address productinfo@perstorp.com
Emergency telephone number

USA (+)1 866 519 4752 (contract no: 334101)
2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200):
Acute toxicity - Oral - Category 3
Acute toxicity - Dermal - Category 3
Acute toxicity - Inhalation (Vapors) - Category 2
Skin corrosion/irritation - Category 1 Sub-category B
Serious eye damage/eye irritation - Category 1
Skin sensitization - Category 1A
Germ cell mutagenicity - Category 2
Carcinogenicity - Category 1A
Specific target organ toxicity (single exposure) Category 1; optic nerve, - central nervous system
Specific target organ toxicity (single exposure) - Category 3
Flammable liquids - Category 4
Label elements
Symbols/Pictograms
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Page 1 / 12 AGHS - EN
Formalin 45 LM - US Revision Date 21-Mar-2018
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Signal word
Danger
Hazard statements
Fatal if inhaled
Toxic if swallowed
Toxic in contact with skin
Causes severe skin burns and eye damage
May cause cancer
Suspected of causing genetic defects
May cause an allergic skin reaction
Causes damage to organs
Causes damage to organs if swallowed; optic nerve, central nervous system
May cause respiratory irritation
Combustible liquid
Precautionary Statements
Obtain special instructions before use
Do not breathe mist/vapors/spray
Wear protective gloves/protective clothing/eye protection/face protection
IF SWALLOWED: Immediately call a POISON CENTER or doctor
IF INHALED: Remove person to fresh air and keep comfortable for breathing
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing
Immediately call a POISON CENTER or doctor
Store in a well-ventilated place. Keep container tightly closed
Contains: Formaldehyde 45-46%, Methanol 1-2%
Supplemental information
No information available
Hazards not otherwise classified (HNOC)

Toxic to aquatic life
Unknown Acute Toxicity

47.2 % of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance
Chemical Name CAS No Weight-%
Formaldehyde 50-00-0 45-46
Methanol 67-56-1 1-2
4. FIRST AID MEASURES

Description of first aid measures
General advice First aid personnel should pay attention to their own safety. If unconscious place in
recovery position and seek medical advice. Remove/Take off immediately all
contaminated clothing. Remove breathing equipment only after contaminated clothing
have been completely removed. If breathing is irregular or stopped, administer artificial
respiration.
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Inhalation Remove to fresh air. Call a physician or poison control center immediately. Oxygen or
artificial respiration if needed. If unconscious place in recovery position and seek medical
advice.
Skin contact Important! Immediately flush skin with water for at least 15 minutes. Use lukewarm water
if possible. Remove contaminated clothing and shoes. Get medical attention
immediately. Cover wound with a sterile dressing.
Eye contact Important! Immediately flush eyes, also under eyelids, with water for at least 15 minutes.
Use lukewarm water if possible. Get medical attention immediately.
Ingestion Rinse mouth then drink plenty of water. Do NOT induce vomiting. Seek immediate
medical attention/advice.
Self-protection of the first aider Do not breathe gas/fumes/vapor/spray. Avoid contact with skin, eyes or clothing. Use
personal protective equipment as required.
Most important symptoms and effects, both acute and delayed

Exposure may cause watery eyes, nausea, coughing, chest tightness, wheezing, skin rashes, allergenic reactions, and burning
sensations in the eyes, nose, and throat. Formaldehyde is corrosive on skin and may cause permanent clouding of the cornea
after only one exposure. Subsequent exposures can produce symptoms more quickly and at lower concentrations. Symptoms
of exposure may include coughing, eye or skin irritation, allergic reactions, vomiting, and diarrhoea. Formaldehyde has been
shown to cause cancer in laboratory animals and may cause cancer in humans. It is toxic if swallowed, inhaled, or absorbed
though skin or mucous membranes. Contains: Methanol. Methanol poisoning has a number of symptoms. These include
bizarre behavior, extreme dizziness, severe headaches, and coma. Methanol poisoning can cause permanent damage to the
optic nerve and central and peripheral nervous system with just a single acute exposure. The digestive system starts to
immediately reject methanol and symptoms may include severe stomach pain, nausea, and diarrhea. Methanol also disrupts
liver and pancreatic function. Even with treatment, methanol poisoning can cause permanent liver damage. Signs of systemic
poisoning may be delayed 8-36 hours after initial exposure. The substance is as well a mild eye, respiratory tract, and mucous
membrane irritant and acts defattening on skin which cauese the skin to become dry and cracked.
Indication of any immediate medical attention and special treatment needed

Note: Contains 1-2% Methanol
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Carbon dioxide (CO2). Extinguishing powder. Water spray (fog).
Unsuitable extinguishing media

Do not use a solid water stream as it may scatter and spread fire.
Specific hazards arising from the chemical

Vapors may form explosive mixtures with air. Thermal decomposition can lead to release of irritating and toxic gases and
vapors. In the event of fire and/or explosion do not breathe fumes.
Protective equipment and precautions for firefighters

Wear self-contained breathing apparatus and protective suit. Use personal protective equipment as required.
Additional information
Cool containers with flooding quantities of water until well after fire is out. Prevent fire extinguishing water from contaminating
surface water or the ground water system.
6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Personal precautions
Keep unprotected persons away. Wear full protective clothing and self contained breathing apparatus. Remove all sources of
ignition. Ensure adequate ventilation, especially in confined areas.
Environmental precautions
Do not allow into any sewer, on the ground or into any body of water. Local authorities should be advised if significant spillages
cannot be contained. See Section 12 for additional ecological information.
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Methods and material for containment and cleaning up

Methods for containment
Prevent further leakage or spillage if safe to do so.
Small spill Dilute with water and wipe up or absorb with inert material.
Large spill Contact the rescue service.
Methods for cleaning up

Clean contaminated surface thoroughly. Flush area with flooding quantities of water.
Reference to other sections

See Section 7,8,13 for more information.
7. HANDLING AND STORAGE

Precautions for safe handling
Use only with adequate ventilation and in closed systems. Obtain special instructions before use. Do not handle until all safety
precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Not to be
used by pregnant workers and workers who have recently given birth or who are breastfeeding.
General Hygiene Considerations

When using do not eat, drink or smoke. Regular cleaning of equipment, work area and clothing is recommended.
Conditions for safe storage, including any incompatibilities

Store in a locked area. Storage at low temperatures (below 20°C) will lead to the formation of a paraformaldehyde as a white
precipitate, and this polymerization reaction is enhanced as the temperature reduces. Storage facilities should be equipped
with ventilation at high level.
Suitable container/equipment material

Suitable container/equipment material: Stainless steel 304 or 316, High density polyethylene (HDPE), Low density
polyethylene (LDPE), aluminum.
Unsuitable container/equipment material

Unsuitable container/equipment material: Paper, Board, Glass.
Additional information Keep container tightly closed
8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters
Exposure Guidelines
Users are advised to consider national Occupational Exposure Limits or other equivalent values.
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH

Formaldehyde STEL: 0.3 ppm TWA: 0.75 ppm IDLH: 20 ppm
50-00-0 TWA: 0.1 ppm (vacated) TWA: 3 ppm unless Ceiling: 0.1 ppm 15 min
specified in 1910.1048 TWA: 0.016 ppm
(vacated) STEL: 10 ppm 30 min
unless specified in 1910.1048
(vacated) Ceiling: 5 ppm unless
specified in 1910.1048
STEL: 2 ppm see 29 CFR
1910.1048
Methanol STEL: 250 ppm TWA: 200 ppm IDLH: 6000 ppm
67-56-1 TWA: 200 ppm TWA: 260 mg/m3 TWA: 200 ppm
S* (vacated) TWA: 200 ppm TWA: 260 mg/m3
(vacated) TWA: 260 mg/m3 STEL: 250 ppm
(vacated) STEL: 250 ppm STEL: 325 mg/m3
(vacated) STEL: 325 mg/m3
(vacated) S*
NIOSH IDLH Immediately Dangerous to Life or Health
Appropriate engineering controls

Showers
Eyewash stations
Ventilation systems
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Individual protection measures, such as personal protective equipment

Eye/face protection Tight sealing safety goggles.
Hand Protection Ensure that the breakthrough time of the glove material is not exceeded. Refer to glove
supplier for information on breakthrough time for specific gloves.
Duration of contact material Glove thickness Break through time Remarks
Suitable materials also with Nitrile rubber, NBR Butyl >480 min
prolonged, direct contact rubber
(corresponding > 480 minutes of
permeation time):
Skin and body protection Body protection must be chosen depending on activity and possible exposure, e.g.
apron, chemical resistant boots, chemical-protection suit.
Respiratory protection Wear positive pressure self-contained breathing apparatus (SCBA).
9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Appearance
liquid
colorless
Odor Pungent
Odor threshold 0.2-1 ppm
Property Value Remar ks •Met hod

pH 2 - 4 @ 20°C (68 °F)
Melting point / freezing point Not determined
Boiling point / boiling range 94 - 100 °C / 202 - 212 °F (@ 760 mmHg)
Flash point 80 °C / 176 °F
Evaporation rate Not determined
Flammability (solid, gas) Not applicable
Explosive limits
Upper explosive limits 73 Vol-% No information available
Lower explosive limits 7 Vol-% (100% FA)
Vapor pressure 39-42 mmHg @ 37.8°C (100 °F)
Vapor density Not applicable
Relative density No information available
Water solubility Fully miscible.
Solubility(ies) No information available
Partition coefficient -1 log POW
Autoignition temperature ca 430 °C / ca 806 °F
Decomposition temperature Not determined
Kinematic viscosity No information available
Dynamic viscosity No information available
Explosive properties Not explosive. No information available
Oxidizing properties Not oxidizing. No information available
Density 1.08–1. 13g/ cm³(
9.013–9.
43 No information available
lbs/gal)
Bulk density No information available
Other Information
The flashpoint data apply to Formalin 45 LM - US. The rest of the physical data apply to 37% concentration of FA.
10. STABILITY AND REACTIVITY

Reactivity
The substance is a strong reducing agent, especially in the presence of alkalis. The substance reacts violently with nitrous
oxides at about 356°F, performic acid, nitromethane, manganese carbonate and hydrogen peroxide. The substance reacts with
strong oxidizers and acids.
Chemical stability
The product is stable under normal conditions of use and storage. However, it is normal for formaldehyde solutions to form
paraformaldehyde (white precipitate or cloudy solutions) at temperatures below 68°F. Formaldehyde will sIowly oxidize in
contact with air to give formic acid.
Possibility of Hazardous Reactions
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The substance reacts violently with nitrous oxides at about 356°F, performic acid, nitromethane, manganese carbonate and
hydrogen peroxide. Risk of run-away reactions between formaldehyde and phenol. Reaction with hydrochloric acid may form
bis-chloromethyl ether (carcinogenic).
Conditions to avoid
Keep away from heat and sources of ignition.
Incompatible materials
See above.
Hazardous decomposition products

Thermal decomposition may release noxious, toxic or corrosive gases or vapours.
11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure
Inhalation. Dermal. Oral.
Symptoms related to the physical, chemical and toxicological characteristics

See Section 4 for more information.
Numerical measures of toxicity

ATEmix (oral) 212.00
ATEmix (dermal) 636.00
ATEmix (inhalation-vapor) 1.00
Unknown Acute Toxicity 47.2 % of the mixture consists of ingredient(s) of unknown toxicity
Acute toxicity
Fatal if inhaled. Toxic in contact with skin and if swallowed.
Formaldehyde (50-00-0)
Method Species Exposure route Effective dose Remarks
OECD Test No. 401: Acute Rat Oral 640 LD50 (lethal dose)
Oral Toxicity mg/kg
OECD Test No. 403: Acute Rat Inhalation Vapor <463 LD50 (lethal dose) 4h,
Inhalation Toxicity ppm
Methanol (67-56-1)
Not defined Rat Oral 7000-9000 LD50 (lethal dose)
mg/kg
Not defined Rabbit Dermal 17100 LD50 (lethal dose)
mg/kg
Not defined Rat Inhalation 128.2 LC50 4h mg/l
Skin corrosion/irritation
Causes burns.
Method Species Exposure route Results:
OECD Test No. 404: Acute Dermal Rabbit Dermal Corrosive
Irritation/Corrosion
Methanol (67-56-1)
Not defined Rabbit Dermal Non-irritant
Serious eye damage/eye irritation

Causes burns. Risk of serious damage to eyes.
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Unknown Rat Eye Corrosive
Methanol (67-56-1)
Not defined Rabbit Eye Non-irritant
Respiratory or skin sensitization

May cause sensitization by skin contact.
OECD Test No. 429: Skin Mouse Skin Sensitizing
Sensitization: Local Lymph Node
Assay
Unknown Mouse Inhalation Not sensitizing.
Not defined human data Inhalation Not sensitizing.
Methanol (67-56-1)
OECD Test No. 406: Skin Guinea pig Skin Not sensitizing.
Sensitization
Germ cell mutagenicity

May cause heritable genetic damage.
Method Species Results:
OECD Test No. 471: Bacterial Reverse in vitro Positive
Mutation Test
OECD Test No. 476: In vitro Mammalian Cell in vitro Positive
Gene Mutation Test
OECD Test No. 479: Genetic Toxicology: In in vitro Positive
vitro Sister Chromatid Exchange Assay in
Mammalian Cells
OECD Test No. 484: Genetic Toxicology: in vivo Negative
Mouse Spot Test
OECD Test No. 474: Mammalian Erythrocyte in vivo Negative
Micronucleus Test
Other in vivo Positive
Methanol (67-56-1)
Method Species Results:
OECD Test No. 471: Bacterial Reverse in vitro Negative
Mutation Test
OECD Test No. 476: In vitro Mammalian Cell in vitro Negative
Gene Mutation Test
OECD Test No. 474: Mammalian Erythrocyte in vivo Negative
Micronucleus Test
Carcinogenicity
The table below indicates whether each agency has listed any ingredient as a carcinogen.
Chemical Name IARC NTP

Formaldehyde Group 1 Monograph 100F [2012] Known (Twelfth ed.)
Group 1 Monograph 88 [2006]
Group 1 Monograph 62 [1995]
Group 1 Supplement 7 [1987]
IARC (International Agency for Research on Cancer)
Group 1 - Carcinogenic to Humans
NTP (National Toxicology Program)
Known - Known Carcinogen
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OECD Test No. 453: Mouse Inhalation 15 NOAEC ppm May
Combined Chronic cause cancer by
Toxicity/Carcinogenicity inhalation
Studies
OECD Test No. 453: Rat Oral 82-109 NOAEL mg/kg bw/day
Combined Chronic No carcinogenic effects
Toxicity/Carcinogenicity have been observed.
Studies
OECD Test No. 451: Rat Oral - No carcinogenic effects
Carcinogenicity Studies have been observed.
Methanol (67-56-1)
OECD Test No. 453: Mouse Inhalation >1.3 NOAEC mg/l Not
Combined Chronic considered to be
Toxicity/Carcinogenicity carcinogen.
Studies
Reproductive toxicity
This product does not contain any known or suspected reproductive hazards.
Effects on fertility Not applicable
Toxicokinetics,
metabolism and
distribution To Formic
acid
OECD Test No. 414: Prenatal Mouse Oral 185 NOAEL mg/kg bw/day
Development Toxicity Study Developmental Toxicity
OECD Test No. 414: Prenatal Rat Inhalation 10 NOAEC ppm
Development Toxicity Study Developmental Toxicity
Methanol (67-56-1)
OECD Test No. 416: Rat Inhalation 1.3 NOAEC mg/l P
Two-Generation
Reproduction Toxicity
OECD Test No. 416: Rat Inhalation 0.13 NOAEC mg/l F1
Two-Generation
OECD Test No. 416: Rat Inhalation 0.13 NOAEC mg/l F2
Two-Generation
STOT - single exposure Methanol; May cause damage to the following organs if swallowed: Eyes, central
nervous system
Unknown Inhalation - Irritating to respiratory
system
Methanol (67-56-1)
Unknown human data Oral - Causes damage to the
following organs if
swallowed: Eyes
central nervous system
STOT - repeated exposure
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OECD Test No. 453: Rat Oral 15 NOAEL mg/kg bw/day
Combined Chronic
Toxicity/Carcinogenicity
Studies
Methanol (67-56-1)
Unknown Monkey Oral 2340 LOAEL mg/kg bw/day
3d
OECD Test No. 412: Rat Inhalation 6.66 NOAEC mg/l
Subacute Inhalation Toxicity:
28-Day Study
OECD Test No. 453: Mouse Inhalation 1.3 NOAEC mg/l
Combined Chronic
Toxicity/Carcinogenicity
Studies
Aspiration hazard
No information available.
12. ECOLOGICAL INFORMATION

Toxicity
Toxic to aquatic life.
0% of the mixture consists of components(s) of unknown hazards to the aquatic environment
Method Species Exposure route Effective dose Exposure time Remarks
Unknown Morone saxatilis Freshwater 6.7 96h LC50 (lethal
concentration) mg/l
OECD Test No. 202: Daphnia pulex Freshwater 5.8 48h EC50 (effective
Daphnia sp. Acute concentration) mg/l
Immobilization Test
OECD Test No. 201: Scenedesmus Freshwater 4.9 72h EC50 (effective
Freshwater Alga and subspicatus concentration) mg/l
Cyanobacteria, Growth
Inhibition Test
OECD Test No. 215: Fish, Oryzias latipes Freshwater >48 28d NOEC mg/l
Juvenile Growth Test (Ricefish)
OECD Test No. 212: Fish, Brachydanio rerio Freshwater 6.9 144h LC50 (lethal
Short-term Toxicity Test concentration) mg/l
on Embryo and Sac-Fry
Stages
OECD Test No. 209: Freshwater 19 3h EC50 (effective
Activated Sludge, concentration) mg/l
Respiration Inhibition Test
(Carbon and Ammonium
Oxidation)
Methanol (67-56-1)
Method Species Exposure route Effective dose Exposure time Remarks
EPA-660/3-75-009 Lepomis Freshwater 15400 96h LC50 (lethal
macrochirus concentration) mg/l
OECD Test No. 202: Daphnia magna Freshwater 18260 96h EC50 (effective
Daphnia sp. Acute concentration) mg/l
Immobilization Test
OECD Test No. 201: Pseudokirchneriell Freshwater 22000 96h EC50 (effective
Freshwater Alga and a subcapitata concentration) mg/l
Cyanobacteria, Growth
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Inhibition Test
OECD Test No. 209: Bacteria toxicity Freshwater >1000 3h IC50 mg/l
Activated Sludge,
Respiration Inhibition Test
(Carbon and Ammonium
Oxidation)
OECD Test No. 207: Eisenia fetida >1 48h LC50 (lethal
Earthworm, Acute Toxicity concentration)
Tests
Persistence and degradability

Readily biodegradable
Method Value Exposure time Results:
OECD Test No. 301D: Ready 90% 28d Readily biodegradable
Biodegradability: Closed Bottle Test
(TG 301 D)
Methanol (67-56-1)
Method Value Exposure time Results:
Unknown 95% 20d Readily biodegradable
Unknown 97% 20d Readily biodegradable
Bioaccumulative potential
Based on the partition coefficients of the ingredients the product is not expected to bioaccumulate in organisms.
Chemical Name Partition coefficient Bioconcentration factor (BCF)

Formaldehyde 0.35
Methanol -0.77
Mobility in soil
The substance is not expected to adsorb to a high degree to suspended solids and sediment based upon the log Pow.
Chemical Name Log Koc

Formaldehyde 1.202
Other adverse effects
Emissions to water lowers the pH. This may cause local damage to fish and aquatic organisms in the discharge area.
13. DISPOSAL CONSIDERATIONS

Disposal methods
Disposal should be in accordance with applicable regional, national and local laws and regulations.
US EPA Waste Number U122

U154
Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes
Formaldehyde - 50-00-0 U122 Included in waste streams: Not available U122
K009, K010, K038, K040,
K156, K157
Methanol - 67-56-1 Not available Included in waste stream: Not available U154
F039
This product contains one or more substances that are listed with the State of California as a hazardous waste.
Chemical Name California Hazardous Waste Status

Formaldehyde Toxic
Ignitable
Methanol Toxic
Ignitable
Contaminated packaging
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Not applicable.
14. TRANSPORT INFORMATION
DOT Road transport

UN/ID no UN2209
UN proper shipping name Formaldehyde solution
Proper Shipping Description UN2209 FORMALDEHYDE SOLUTION , 8, III
Transport hazard class(es) 8
Packing Group III
RID Rail transport

UN number UN2209
Packing Group III
ADR Hazard Id (Kemmler 80
Number)
IMDG Sea transport

UN number UN2209
Packing Group III
EmS-No F-A, S-B
Limited quantity (LQ) 5L
Transport in bulk according to No information available
Annex II of MARPOL 73/78 and
the IBC Code
IATA Air transport

UN number UN2209
Packing Group III
ERG Code 8i
Limited quantity (LQ) 1L
15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
International Regulations
IARC (International Agency for Research on Cancer): Group 1 - Carcinogenic to Humans.
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a
chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal
Regulations, Part 372
Chemical Name SARA 313 - Threshold Values %
Formaldehyde - 50-00-0 0.1
Methanol - 67-56-1 1.0
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CWA (Clean Water Act)

This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21
and 40 CFR 122.42)
Chemical Name CWA - Reportable CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous
Quantities Substances
Formaldehyde 100 lb Not available Not available X
50-00-0
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)
Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ)

Formaldehyde 100 lb 100 lb RQ 100 lb final RQ
50-00-0 RQ 45.4 kg final RQ
Methanol 5000 lb Not available RQ 5000 lb final RQ
67-56-1 RQ 2270 kg final RQ
TSCA Inventory
Listed and active in the TSCA registry.
US State Regulations
California Proposition 65
This product contains the following Proposition 65 chemicals
Chemical Name California Proposition 65

Formaldehyde - 50-00-0 Carcinogen
Methanol - 67-56-1 Developmental
U.S. State Right-to-Know Regulations
Chemical Name New Jersey Massachusetts Pennsylvania

Formaldehyde X X X
50-00-0
Methanol X X X
67-56-1
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST

REVISION
NFPA Health hazards 3 Flammability 2 Instability 0 Physical and Chemical
Properties Not
available
HMIS Health hazards 3 Flammability 2 Physical hazards 0 Personal protection X
Key or legend to abbreviations and acronyms used in the safety data sheet
Not applicable
Issue Date 21-Mar-2018

Revision Date 21-Mar-2018
Revision Note SDS sections updated; 1 Uses advised against, 2 Classification, 11 Toxicity data, 15
TSCA
This safety data sheet complies with the requirements of: OSHA Hazard Communication Standard (29 CFR 1910.1200).
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication.
The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid
for such material used in combination with any other materials or in any process, unless specified in the text.
End of Safety Data Sheet
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MSDS - Formalin 45 LM - US - Usa-1996

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Safety data sheet

Issue Date 21-Mar-2018 Revision Date 21-Mar-2018 Version 2

Other means of identification

Pure substance/mixture Substance

Recommended use of the chemical and restrictions on use

Uses advised against Consumer use

Details of the supplier of the safety data sheet

Perstorp Polyols, Inc.

E-mail address productinfo@perstorp.com

Emergency telephone number

Contains: Formaldehyde 45-46%, Methanol 1-2%

Hazards not otherwise classified (HNOC)

Unknown Acute Toxicity

4. FIRST AID MEASURES

Most important symptoms and effects, both acute and delayed

Indication of any immediate medical attention and special treatment needed

Unsuitable extinguishing media

Specific hazards arising from the chemical

Protective equipment and precautions for firefighters

6. ACCIDENTAL RELEASE MEASURES

Methods and material for containment and cleaning up

Methods for cleaning up

Reference to other sections

7. HANDLING AND STORAGE

General Hygiene Considerations

Conditions for safe storage, including any incompatibilities

Suitable container/equipment material

Unsuitable container/equipment material

Additional information Keep container tightly closed

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH

NIOSH IDLH Immediately Dangerous to Life or Health

Appropriate engineering controls

Individual protection measures, such as personal protective equipment

9. PHYSICAL AND CHEMICAL PROPERTIES

Property Value Remar ks •Met hod

10. STABILITY AND REACTIVITY

Possibility of Hazardous Reactions

Hazardous decomposition products

11. TOXICOLOGICAL INFORMATION

Symptoms related to the physical, chemical and toxicological characteristics

Numerical measures of toxicity

Serious eye damage/eye irritation

Method Species Exposure route Results:

Respiratory or skin sensitization

Germ cell mutagenicity

Chemical Name IARC NTP

STOT - repeated exposure

12. ECOLOGICAL INFORMATION

0% of the mixture consists of components(s) of unknown hazards to the aquatic environment

Persistence and degradability

Chemical Name Partition coefficient Bioconcentration factor (BCF)

Chemical Name Log Koc

13. DISPOSAL CONSIDERATIONS

US EPA Waste Number U122

Chemical Name California Hazardous Waste Status

14. TRANSPORT INFORMATION

DOT Road transport

RID Rail transport

IMDG Sea transport

IATA Air transport

15. REGULATORY INFORMATION

CWA (Clean Water Act)