D. G.

Ruparel College, Mumbai

Question Papers
University of Mumbai

M.SC. Part I
SEM - II

Apr - 2016
 QP Code : 25684

Duration:[2i Hours] [Marks: 60]

N.B. 1) All questions are compulsory and carry equal marks.
2) Solve any TWO subquestions from each questions. Cam,

1. (a) Each coefficient in the equation axe + bx + c = 0 is determined by throwing an ordinatj' (6)
die. Find the probability that the given equation will have real roots. C.)
ev.)
(b) Let -V; : i E I} be a collection of sigma-fields of subsets of Q. Prove or disprove 0 (6)
(i) nn.FI is a sigma-field. \.„,
<€./
(ii)Uiti Y is a sigma field. ‘...S:'
(c) State and prove inclusion-exclusion principle for 71 events. 00\-4 (6)

• 2. (a) State and prove First Borel-Cantelli lemma.

(b) Urn A contains 3 white, 1 black and 4 red balls. Urn B contains 4
red balls. Urn C contains 4 white, 3 black and 2 red balls . One
0
te, 3 black and 4
is chosen at random
(6)
(6)
and 2 balls are drawn. They happen to be red and black. is the probability that
both the balls come from urn B? (y.
(c) Let An be an infinite sequence of events such that Anti C eilf,ior every n and A= ni-,. A,,. (6)
Show that P(A)= limn, P(An). A\
'S'"
3. (a) If X has the normal distribution with mean p an lance e2 and Y = aX + b, where a (6)
and b are given constants with a # 0 then show Y has normal distribution with mean
ay+ b and variance a2o-2. ‘<.,
(b) Prove that if random variables X and Y a&ndependent'‘.N, and EaX1) 5 oo, BOYD < oo (6)
and BOXY') < oo then CI
(i) E(XY) = E(X)E(Y) (Z71
(ii)Var(X +Y) = V ar(X) + Var(Y*9--
(c) Show that Binomial distribution C'ds to a Poisson distribution when n -4 co and p -4 0, (6)
where n is the number of indee; ent trials, p is the probability of success.
4. (a) Let (X„) be a sequence of rfiedorn variable. Show that X„ —> X almost surely if and only
(6)
if P(sup,n>„ IX„, — XI >444 0 as n --i oo for all e > 0.
(b) The joint density fun‘ of X and Y is given as (6)
2(1 — x),6c0--\, < x ._.. 1, 0 < y < 1
f (x) = 0,
CJ t otherwise
(i)Find the itional expectation of X given Y.
(ii)Find nditional expectation of Y given X.
(c) Suppos;& the average, the dailly demand for an item is 28 with variance 16. How many (6)
ite Vould you make so that the supply meets the demand within
east 90% of the time.
4 t most 90% of the time.

[TURN OVER
bN OC-Con. 9737-16.
 QP Code : 25684

5. (a) Show that (6)

(i) The Cantor set
(ii) Singleton set {a}, 0 < a 5_ 1
are Borel set.
(b) Suppose C2 = {1, 2,3} and F is a collection of all subsets of 12. State and prove nesessarO' (6)
and sufficient conditions on the real numbers x, y and z such that there exist a count
additive probability measure P on F with x = P(1, 2), y = P(2, 3) and z = P(1, 3).c
(c) Let X be a continuous random variable with probability density function
SE
(x) = ke Uzi, jx1 > oo.

(i)Determine the characteristic function of X.

(ii)Find E(X).
(iii)Find V(X).

ej<>
4ct
C,..

J49

0*<,
0
0

O
4-4JC-Con. 9737-16.
n)
 OP Code : 25670
(3 hours)
Total marks: 60
N.B.
1) Attempt any TWO questions among question numbers 1, 2 and 3 and
any TWO questions among question numbers 4, 5 and 6.
2) Figures to the right indicate full marks.
3) Simple non-programmable calculator is allowed.

1. (a) A population consists of N animals of which M have been marked. Let Y

denote the sample size required to recapture exactly k marked animals.
Assuming the sampling scheme to be without replacement, derive the
probability distribution of Y, its mean and Variance. State the
distribution, mean and variance of Y if sampling scheme is wit
replacement. , 0
(b) Let X and Y be iid random variables taking value k with probabil' (04)
pk > 0 V k = 0,1,2,3..... Show that X and Y are geometric rand
variables if,
P(X =ti X+Y= t) = P(X = t — 1IX + Y = t) = 1/(t + 1) for a on
negative integer t.

(c) Let X1,X2,...Xr, be independent Poisson random v bles where Xi is (04)

Poisson with parameter hi. Let Y = ifLiXt.
I. Obtain probability distribution of Y. ,C)N
ii. Show that the conditional probabilqdistribution of (X1, X2,- .Xn)
given Y = t is multinomial. N,

2. (a) Define Standard Cauchy distributiooS enve its distribution function. (05)
Find mean, median and mode if .ttey exist

(b) Let Xi, X2, Xn be indepenrIt and identically distributed random (06)
variables. wv
• I, Show that X1— eerential if and only if.Y1 = X2,... Xn)
follows expon ial distribution.
ii. Obtain the p f the sample range if Xi's — exponential .

onal distribution of Y given X = x, is U(0, x) and

(c) Suppose the cpiOti (04)
X — G(n=2,
i. Finc f of Y.
5G+ Y < 2).
ii.
3. (a) If YISNY2< <Y, denote order statistics based on a random sample of (06)
Nn from U(0, 1), derive:
JQ oint pdf of (Yr, Ys) ii) Cov(Yr, Ys) where 1 < s n.
/X1
Page 1 ea

[TURN OVER
L.) OC-Con. 9740-16.

0
 2 QP Code : 25670

(b) Explain Acceptance-Rejection method of simulating a random variable (04)

from density function f(x).

(c) Consider a random sample from population with pdf,

f(x) = c/x6 V x > 5
= 0 otherwise
where c is a constant. Obtain the pdf and mean of the eh order statistic
based on a random sample of size n.

4. (a) Let Xi, X2,....Xn be iid rvs from Poisson distribution P(A). Find CRLB for
an unbiased estimator of e- A .
\C
N"

• (b) Give an unbiased estimator of r' in 4(a) above. Compute its varittd
and compare it with CRLB.

(c) Let Xi, X2,....Xn be a random sample from N(µ, 1). Obtain B atacharya (05)
(05)

Bound, L.2 for variance of any unbiased estimator of /2 2 . 0

_÷
5. (a) X1, X2 Xn are iid rvs from exponential distribution wiVflean O. Obtain (05)
CRK lower bound for an unbiased estimator of 0. 5

(b) Define a maximal invariant statistic. Derive an eOlicit expression for (05)
Minimum Risk Equivariant (MRE) estimator f5.0 location parameter.

(c) Let Xi, X2 Xn be iid N(0,1) random v<dks. (05)

(i) Find Pitman Estimator of 0.
(ii) Under the location group and steed error loss function, find MRE
estimator of 0.
•
6. (a) Let Xi, X2,....X„, be iid rvs wi vat n,p),0 < p < 1. Obtain consistent (05)
•
estimator of p and the mini el sample size i e mnfor given e and S.

(b) State and obtain CRK ISer bound. (05)

O•
(c) Let Xi, be f rvs with U(0, 0). Show that it does not satisfy the (05)
regularity condi '
A•

C.>

******************

QJ
Page 2 of 2

,C 0C-Con. 9740-16.

O)
 QP Code : 19977

( 21/2 Hours) [ Total Marks : 60

N.B. : (1) All questions are—compulsory. ___

------------4—
(2) Figures to the right indicate maximum marks. ,-,,c`
/,k..2
(3) Symbols have usual meanings unless stated otherwise. N.,
(4) Use of non-programmable calculator is allowed. rici>
Li
1. (A) Attempt any one :-
g-
08
(0 What are Clebsch-Gordan coefficients in relation to addition of an
momenta? Obtain the recursion relation for Clebsch-G ord an coeffici
,0
(ii) Show that Lis a generator of infinitesimal rotation 34 about thLt-axis;
viz, -''
i— rO-
,
R.,,(t)= exp E 4)1, z . ,..,
h ) 5cy. ,
(B) Attempt any one :- 4
cn.
CO Show that Pauli spin matrices antic,ommute.Alsqpirove, [ a X' ay ] = 2io
(ii) Show that ( U•A) ( T-Y•13) = A • 171 + its- • (64c1), where A and 73 are
constant vectors and -cs is Pauli spin ma,

?. (TA) Attempt any one :- 0 8

0
(i) Explain time independentpertur on theory for non-degenerate stationary
cares. Obtain/he-trig order p rbation corrections to the eigenvalues and
eigen-frinctions. .\§
g-
0 ______„-----(11) A system is subject to cym e dependent perturbation H'( r,t ) = V(r)f (t) .
....------- Show that the proObility of transition from an initial state yt ( r, t) to the
io
state NiK 6; c l,ia time t is PIK = I CK 0) e , where,
A<••
Vice 1 e (E k -E t W/h
,cD CK 0) = f (t')dt'
in j
l..)
'•

,..,
c7
,
,.\.)
,0,-- [ TURN OVER
AO
,Li
1
\'' -
v.) OR C n • 11710-16.
 QP Code : 19977

-2-

lDl Attempt any one :- 4 NZ

(i) Find the energy eigenvalues and eigen functions of Hamiltonian H corrected
(1 + e e
V
EN
upto first order. H = ., where E c< 1
E • +E),
-1.
,
0
(ii) Consider a one-dimensional harmonic oscillator with linear perturbation 2.,X. 1
r/4,
Calculate the perturbation corrections to the grounds state up to second orde L'i
- iii h
Given . Cc
2m co
(a+at )

‘.
‹)
- \---
G
\-\%\-\
•
3. (A) Attempt any one :- P
(I) Using variation method, obtain ground state energy of hyd en atom when 8
the trial function is ui(r)=Aear , cc is a variation param
. - CD
n!
Given : iT...
x -ax
e dx - (c )n+I 47'
SI-
G Fr-
(ii). Dia_ -- the turning points and connection f.irslalas in WKB approximation.
i;•,."
c
NN,
-0) 4:17L-- 2.131y one :- . r.,,
CD S7-nvithat variation method giv,- beer bound to ground state energy.
(“1 Diwass the conditions of validiVo WK-i-,•-„_:rincimation.

(A) Athemot any one :- ,..§r - -_____

Q--
(1) Analyse the scatterinqy an incident beam of particles with momentum-- -

hk and energy from a scattering centre, using the method of partial

',bast shit. Show that the scattering amplitude f (0) is given in terms
co
ia
of ph hifts St as f (0) = — E (2/ + 1)e I .sin St ye, (cos 0).
K t=r,

k".•

••••

[ TURN OVER

NJOR-Con. : 11710-16.
 QP Cock 7 ..-

-3-
(ii) Derive the expression for scattering dinplir.ude ai Boxii cyproximafion and
7e2
ate it for a screened coulomb pcvnitip.1 V(*) = ---=' — le', where 'a' is C'
C"
a positive constant.
ON'
0
Attempt any one questions :- 04
do-(0,$) t
Define scattering cross-section and show that : ''S"
d2
0
da( 0,4) 0
O =1 f(0.,$) 12 where f(0, +) theccAtterinz nr ___v_litildp .4)
d
Explain the validity criterion of Born approximation.
c/Y
5. Attempt any four :-
(i) Show that: [Jr, =n 4.Dt
(ii) Prove that :

J±1 ±t1J+ ; [.1 ] = 2hiz

(iii) Show that there is no first order s effect in ground state of an atom_
Given : Unperturbed ground st \Stavefiniction is
2 — Zr/ao
4100kr) = 3/2 o is Bohr radius
ao
(iv) Consider a particle igy one dimensional potential well :
00 L
V(x) = 'otherwise

( Ll
%1Ste is subject to perturbation of the form 1-1"(x) = LV0 5(.3( —
2

re Vo is a constant. Calculate the first order correction to the energy

vel of the particle.

— sin
Given : Energy eigen functions, 1ln (x) = L
F nax

[ TURN OVER

<)OR-Con.: 11710-16.
QOM
 QP Code : 19_91_7

(v) Obtain Bohr Sarnmerfeld quantization condition from WICB approximation.

(vi) Use WKB approximation to find the energy eigen values of a particle in an
infinite poteatial well.
(vii) State the .conditions under which the method of partial wave analysis is (DN'
applicabitfor solving a scattering problem. C)
C.)<<"
(viii) Consider the schrodinger equation for the scattering of a two particle systerpe
Express :he wave function in the form of an integral equation.
(D
•

cp,

GP

mow.
AK:

VR-Can. : 1171046.

0
Z
 OP Code : 19916

(2'% Hours ) [ Total Marks : 60

All questions are compulsory.

Figures to the right indicate full marks.
Symbols have usual meanings.
Use of log-table/ non prOgrammable calculator is allowed.

1. (a) Attempt any one :-

(i) Obtain the equation,
d
j (we, + com )dv = j.Edv + f S .fida
dt v v surface

representing energy conservation law in electrodynam Give the

physical significance of each term. OA
P
(i The field intensities E and B are defined as.
3A
E---=---V(k-1 ; = VXA
c at
Write the components of E & TEi (i.e components) of the above
equations. Define Field Tensor F µ, express it in the form of 4 x 4
matrix.
GO
(b) Attempt any one :- <<>, 4
(i) Obtain continuity equati in terms of current four vector.
(ii) The Maxwellian stre ensor with components is given by
1 ( 0 1
Ti, = — Ei E./CB; B • - -8- (E kEk + BkB k ) ; (i, j,k -= 1,2,3)
41T $.C1 j 2
r1
\
Write it Ole matrix form

2. (a) Attempt one :- 8

causs the frequency dependence of conductivity, hence obtain the
(i) lis
0
Go
ci expression (7(0)) =
— Rot
C)
01_÷

[ TURN OVER
0
OR-Con. 11518-16.
 QP Code : 19916

-2-
(ii) For cylindrical wave guide show that the transverse components of
field vectors are entirely determined by the longitudinal components.

(b) Attempt any one :-

(i) With the help of suitable diagram explain in brief anornalus dispersion. c Li
(ii) If a plane wave is contained in volume V and if according to Einstein, (-\\,
one requires that this plane wave represents an energy quantum with 01/4-i
energy hco , then show that electrodynomics yeilds the de-Broglie&
relation p = Pik • t

3. (a) Attempt any one :- 00 8

(i) Consider a charge q moving with a costant velocity S is that the
scalar potential 4. and vector potential A for this charge e given by:.

q .&7--
(1)(1-,
V 5
R 1- —sin- 0
C2 <--)‘

qv c0
A t)
and
cR 1 c2c)
where R = r -- V t is theiector from the actual position of the charge
to the point of obser on and his the angle between R and V
(ii) Show that the toteiower radiated from a charge moving with non-
•
2e' a'
relativistic ‘tOocity is given by : P =
3c3
A•

(b) AttemptCny one :- 4

(i) What
What are gauge transformation? Explain coulomb gauge and Lorentz
-,Ceauge.
or) An electron is released from rest and falls under the influnence of
gravity. What fraction of its potential.energy is radiated away when it
falls by 1cm?

[ TURN OVER

OR-Con. 11518-16.
 QP Code : 19916

-3-

4. (a) Attempt any one :- 8

(i) Write down Lorentz transformation equations. Show that the interval
ds2 =c'dt2 -1dxr is invariant under Lorentz transformations.
(ii) Derive an expression for the Lagrangian of a particle moving with
relativistic velocities.

(b) Attempt any one :- X00

(i) Discuss time like interval in special relativity.
(ii) Show that the field strength tensor is antisymmetnic.
0 12
5. Attempt any four:- C.)

(a) Explain why the tails of the comets are always directed awayfs.?Yin
F"-
the Sun.

(b) Ifs is a Poynting vector then explain the physical si ficance of the
terms -§/c2 , also express -s- in terms of E and H .
If electric field corresponding to certain plane,eonochromatic wave is
(c)
( —wt) + E2ei(k—rrot+n/ 2
• )
E(r,t) = i El -k
then comment on state of polarization. ok,'
(d) Explain in brief the terms phase veloc0 and group velocity.
Find the scalar and vector potenti it an infinite straight wire carrying a
(e)
current I(t) = 0 for t < o and IV, 0 for t > 0
'gauge function.'
(0 Obtain the wave equation for
rmation equations.
(g) Write down Galilean tra
(h) What are the componefOg of the 4-momentum?
„O.
Ac
41/4/

0
OP

Q_÷

.4-(9<<1 OR-Con. 11518-16.

 QP Code : 19860

( 2% Hours ) Total Marks : 60

N.B.: (1) All questions are compulsory.

(2) Figures to right indicate full marks.
(3) Use of non-programmable scientific calculator is allowed.

Useful constants 0
c = 2.998 x 1 Ogrns-' e = 1.602 x 10-'9 C .oic<iti
\<Ci
.,
R = 8.3147K-Imor' k 1.3811 x 10-23.1K-1 \,\-.'
h = 6.626 x 10-"Js 1J = 6.24 x 10" eV . e
• 0
me = 9.110 x 10-31 kg leV = 8.06 x 103 cm-1
•\.-s
NA = 6.022 x 10"mol-' lamu = 1.66 x 10'-'kg'Sr
.X.)41
,.N<K>
1. (A) Attempt any two of the following:- Li
cp
(i) Obtain the time independent Schrodinger wavKespation for a particle 4
7<Z--
in two dimensional box, z, IS
(ii) What are the characteristics of a well behAttcl function? Indicate which 4
- of the following wave functions areAa6ptable.
,v
(i) W= e (ii) oNqv = tan x
(iii) What do you mean by deget#y of energy levels? Determine the 4
1,2-- 38h'
degree of degeneracy ola energy level 8ma.2
4(Z--
• (iv) For Hermite's diffeeatial equation 4
S'
cl2F
2y dF +z- —1) F= 0
dy2 — dyz p,
A•
Obtain t ecursion formula.
0
9
(B) AttemptW one of the following :
(i) *hsider an electron moving in a one dimensional box of 3A° width. 4
cyCalculate the transition in energy when an electron jumps from second
• orbit to first orbit. Also calculate the wavelength of the emitted
<Th
< radiation.
.0,7s
c<i
,0
y
\--\ [TURN OVER
N<0
rb
oNb OR-Con. 11128-16.
Q
s-v
-
 QP Code : 19860

-2-
(ii) The Hermite polynomials are derived from the generating functions. 4

}In (y) = eY2 cl "(e 3? )

y
0
where in' is vibrational quantum number and also the degree of
polynomial. Calculate the polynomial for n = 2 and n = 3 .
0
(<,
2. (A) Attempt any two of the following :
(i) Explain the application of Schrodinger wave equation to two elect") 4

• system.
(ii) Sketch qualitativelythe probability density curve for Is, 2s Gild 3s
orbitals. Also mention the number of nodes in each case. ÷
4

4
(iii) Write the Schrodinger wave equation in terms cespherical
coordinates. Why is it necessary to convert Sc Inger wave
equation from cartesian coordinates to spherical(c>o dinates? Give
the limits of variation for x, y, z, r, 0, 4)
(iv) What are quantum numbers? Explain the i ificance of magnetic 4
quantum number.
<63C
0
(B) Attempt any one of the following :
(i) The energy expression for atkflectron in a rigid rotator is given by 4

the expression E M = :4, where M is rotational quantum

• number. Calculaeke first three energy levels using the above
equation for th.lectron rotating in a circular orbit of radius 0.5A° .
4
(ii) Calculate thSost probable distance of an electron from the nucleus
..ck•
in grouptate. The function is
0 1 —r/a0

3/2
1 7c ao

3. (A) CA. -tempt any two of the following :

4
(i) Give a brief account of the Lindemann-Hinshelwoods theory of
OQ~unimolecular reactions in gas phase.
0
[ TURN OVER
bn)
QN OR-Con. 11128-16.
N.1
 QP Code : 19860

-3-
(ii) Show that the rate of polymerization reaction is proportional to the 4
square root of its initial concentration of the monomer.
(iii) H, reacts with Br, to give HBr according to the reaction 4 <Q,
205-302° C > 2HBr . Using the chain reaction mechanism, <<.9
H2 + Br2
0
obtain the rate equation for the above thermal reaction. C)
0,04
(iv) Using the following reaction mechanism for the decomposition o
‘‘,
C.
acetaldehyde:

• CH3 CH0—> •CH, + • CHO

• CH, +CH,CHO--k-> •CH 4 + • CH,CHO
0
\-‘

<C) 0

• CH,CHO • CH, + CO
`4 > CH3CH3 A<>
• CH, +• CH, --J--
(.6°'
d [CH 4 ]= k [ CH3CHO
Show that — Nr-7
dt
0

(B) Attempt any one of the following: \;/

4
(i) Consider a bimolecular gaseouUeaction between like molecules with
collision diameter d = 20 ; massM = 100 g mol-' and a steric
factor p = 1.00 . Calcula ePtheArrhenius pre-exponential factor A in
dm3 mob's-' at (1) 6100°C and (2) 200°C if it is related to the other
four parameters ihe constant 3.893 x 1029 .What is the percentage
increase tween this range of temperature?
ofIct 4
(ii) The foll -ng process follows the first order kinetics
x 220 > y 33 " >z' where the times are the half lives of the
reeon in days. At what stage of time will the concentration of y
,`come maximum?

4. (A)5-Attempt any two of the following :

e
c (1) Derive an expression to show the influence of ionic strength on rate
of the reaction between ions in solution.
4

N [ TURN OVER
\g)
OR-Con. 11128-16.
 QP Code : 19860
-4-

(ii) Discuss the effect of substituent on reaction rates using Hammet 4

relationship.
\-\R-
(iii) Derive Michaelis -Menten equation for reactions catalysed by 4 dc,
enzymes. .\,\.
(iv) Discuss the kinetics of enzyme inhibition by noncompetitive 64
inhibition method. &
<<.'(--

• (B) Attempt any one of the following : Ot

(i) Derive an expression for the parabolic rate law for react" id in the
solid state.
4
'R-
(ii) Derive kinetic expression for the rate law of the rea of spherical 4
particles.
S
5. Attempt any four of the following : 12
\t"
(a) Show that the eigen value of a Hermit operator is real.
(b) Which of the following are eigen ction of the operator d2 /dx2 ?
(i) cos 4x (ii)
(c) Write the expression for ra 'aciwave function for 2p and 3d orbitals.
(d) Explain the statement ' h#e is an equal chance of finding is electron
in any direction with pect to nucleus.'
(e) Explain the three osion limits of a non-stationary chain reaction.
(0 Explain the to
(i) collisi equency factor
(ii) reaAn cross section.
cc./
(g) Disouss the factors which affect the reactions in solid state.
(h) Pict the effect of increase in ionic strength on the rate constant
4or each of the following reactions :

(i) H2 02 + 2Br + 2H+ ---> Products

<K9
(ii) CH2 ICO0H+ CNS ---> Products

0 (iii) S2 Ct + 21 --> Products

<z\) OR-Con. 11128-16.

 QP Code : 25663
(3 hours)
Total marks: 60
N.B.
1) Attempt any TWO questions among question numbers 1, 2 and 3 and any \.•
TWO questions among question numbers 4, 5 and 6. .ems
vS2-
2) Figures to the right indicate full marks. \-s.
3) Simple non-programmable calculator is allowed. Ai.:
l.)

O
N'
1. (a) Explain the concept of Bonferroni t-intervals. Write Bonferroni t- (-#)
intervals for all possible elementary contrasts of cr i's for the model g_:--
\„
<K.
yij = p+ a1 + E.ii ,1 = 1,2,3 ,1 = 1,2 and sir/N(0,0-2). \,
.C4
C'

• (b) Consider a linear model:

iii + a+ .13J ± Yu + Eij
ro
Li
-s--
(10)

and eij—IN(0,52). F---

= 1,7, _ -;" , j = 1,2, ..., q , c
Derive T!_ikevis test of nonadditivity to test for signific of the
int=r.rtiorl --feet c>
c-D
.A.c-,'
2. (a) Consider a two way ANOVA model with uneqL .c.t observations per cell (07)
•
and without interaction. For this model obtailhe reduced normal
=r ”firms, if this model is connected, sh o hat every contrast of row
=ffects ic e=tirnia.
Y

(b) Consider a two way ANOVA rtel yii = p + af + + eij (08)

= 1,2,...,n : = q agu—IN(0, o'2). Write normal equations
and determine which of tlie, parametric functions are estimable. Also
derive test statistic toe-61710:th. = 102 = = fig.
4.(/
3. (a) Consider a two ANOVA model with r observations per cell and (07)
without interaC s on:
yijk = y + Eta = 1,2, ...p , j = 1,2, ..., q and
k = 1,2, cy, eijk —IN(0, a2).
Deriv 'est statistic to test Ho:fli. = 162 = = flq.

[TURN OVER

nt 0C-Con.9755-16.
,Nb
 2 QP Code : 25663

(b) Consider a model yuk = p + a1 + Rij + auk, i = 1,2, ...,p , (08)

j = 1,2, , q , k = 1,2,...,r and Eijk -IN (0, az ). Obtain normal equations
and least square solutions of parameters in the model. Is fu -P is ]
s estimable? If so obtain its BLUE and variance of the BLUE. Derive
test statistic to test the hypothesis Ho: pia = $12 = ••• = igf q ,

4. Describe analysis of covariance model. Explain how it differs from (15) Ae,,,
&C.9
analysis of variance model. Consider the ANOCOVA model:
N:"
Ynxi = Xnxp• flpx2. + Znxm• Yrnx2. + enx1 ON1
Let $ = $ + (X'X)-X'Zy.
<OC)
(i) Obtain least square estimates of fl.and y. oc)
Obtain vary) \.<C7
.,
(H)
v\
.,-'
(Hi) Obtain cov(P.,1%) ,-,\'
,-c)
(iv) Obtain Error sum of squares li
(v) Derive a test for Ho: y = 0 '-'-
,-c
5. (a) Obtain Maximum Likelihood estimates of category pr*aabilities (08)
(rri) i = 1, ...,N given the observed data {ni) i = 1,e
), assuming
multinomial sampling. Explain how will you test the null hypothesis
Ho:Tr ' = Trio for i = 1, ..., N 4"
k-
\i''
c<
(b) Justify that Pearson's statistic used for teng the above hypothesis (07)
has a limiting chi-square distribution. z,C9
NY

6. (a) Define prediction matrix P. State&KI prove its properties. (08)

(<>

(b) State with assumptions tht-way random effect model with two and (07)
three factor interactions ‘rite
. down the ANOVA table with expected
mean sum of squares ive estimate of any one component of
variance. ,O'

N.)

*********************
0
c-D

OP
OJ

cs
c
p
00
t\-0C-Con.9755-16.
n \
 Q.P. Code : 19857

( 2% Hours) [ Total Marks : 60

N.B. : (1) All questions are compulsory C`

(2) Figures to the right indicate full marks
(3) Symbols have their usual meanings unless otherwise stated ON'
0
(4) Use of log tables / non-programmable calculator is allowed

1 (a) Attempt any one:- \-1 8

(i) With help of neat diagram, explain the architecture 8085
• microprocessor.
(ii) Explain the operation of PORT 0 of 8051 microcon ler. Which
are quasi-bi-directional and true bi-directional p th reference
to 8051?
(b) Attempt any one :- SO 4
(i) With reference to the 8085 microproce , explain the functions
of the following pins: IO/M , SID k
0
(ii) Explain the Register Indirect Ad ssing mode in case of 8051.
‘<,
2. (a) Attempt any one : - 0ON' 8
(i) With the help of neat bWk diagram, explain the working of
(Z-
SMPS.
(ii) Discuss the, working 4 bit Digital to analog converter with
R-2R ladder netwerk.
(b) Attempt any one :- <SY 4
(i) Draw neat k diagrams of the three basic configurations of
square we inverter.
Discu e working of voltage to current converter with
grained load.

3. (a) AttemOany one:- 8

Discuss and distinguish between pulse amplitude modulation and
‘<, pulse width modulation.
e- (ii) With the help of neat diagram explain types of optical fiber and
0 hence discuss different modes of propagation of light through
the fiber.

[TURNOVER
Q' OR-Con. 11127-16.
 Q.P. Code : 19857
2

(b) Attempt any one :- 4

(i) A fiber optic cable has a maximum acceptance angle of 35°
and a core of refractive index 1.46. Calculate the refractive CC9
index of cladding of the fiber. ON/
(ii) Explain dispersion in Optical fiber and state how it can be <c0
reduced.
‘,C`
4. (a) Attempt any one :- 04N\-1 8
• (i) With the help of schematic diagram, explain how to i 3ife'rface
DC motor to microprocessor 8085.
(ii) With help of a neat diagram, explain how you 41 interface
optical sensor to a Microcontroller for r itoring light
intensity. c-D
(b) Attempt any one :- 4
- ntroller.
(i) Mention any four applications of mivliYco
(ii) Explain the working of load cell. <<S)
0
5. Attempt any four :- 0\/ 12
(a) Explain the concept of Stack1i reference to microprocessor 8085.
(b) Draw a generalized block agram of a Microcontroller.
(c) Draw the block diagra of uninterrupted power supply.
(d) Draw a neat diagr S-of Op-Amp based second order High
Pass Butterwort alter. State an expression for its cut-off
frequency. 4(/
(e) Write a noteStime Division Multiplexing used in modulation.
(f) Draw a n diagram showing Pulse amplitude modulation.
(g) Draw t circuit diagram of electronic weighing single pan
balakE.ca using strain gauge.
(h) Da a block diagram of a microprocessor based temperature
(cintrolled heater.

0L÷
<<.

OR-Con. 11127-16.
Q't

\-\N'
 QP Code : 25648

Time: 22 Hours [Total Marks: 60]

N.B. 1) All questions are compulsory and carry equal marks. kr

2) Solve any two subquestions out of three in each of questions one, two, three and four. \''
(3) Solve any four subquestions out of six in question five. ,-,<<"
L.)
N.,
Q. 1. (a) Let Gi, G2 be finite groups. Prove that GI x 02 is cyclic if and only if gcdaGil, 1021) 11,
where IGi l denotes the order of the group Gi. 0(6)
(b) (i) Let G be an infinite cyclic group and let Aut(G) denote the set of all autoi~iuhisms
of G. Determine Aut(G) with correct justification. 1.,<< -- (4)
•
10 9 k...1N'
(ii) In M2(Z11) determine the inverse of 8 7 if it exists. ,44 (2)
,L..)
• (c) (i) State the structure theorem for finite abelian groups. Determine uptddSomorphism all
finite abelian groups of order 104. (4)
4)
(ii) Let GI, G2 be finite groups and let q; : GI —> 02 be a group isomorphism. Prove that
if a E Gi, then order of cp(a) equals order of a. ii-ev (2)
Li
Q. 2. (a) Let G be a finite abelian group. Let p be a prime such that p des order of G. Prove that
G has an element of order p. 5 (6)
(b) (i) Let p be a prime. Prove that every group of order p2C]. abelian. (4)
(ii) Prove that the center of a group G is a normal sub oup of G. (2)
(c) (i) Let G be a group of order pq, where p, q are pries, p < q and p does not divide q— 1.
Prove that G is isomorphic to ZI,,. 4, (4)
(ii) Let G be a group acting on a set X. Defin abilizer of x E X and prove that it is a
subgroup of G. N, (2)
&
0
Q. 3. (a) Let R be an integral domain. Define qu t field of R and prove its existence. (6)
(b) (i) Let R be a commutative ring witpnity. Prove that R is a field if and only if R has
exactly two ideals. (4)
(ii) Define characteristic of a ring #,:§Prove or disprove the statement: There exists a field
• F whose characteristic is 1e' (2)
(c) (i) Let R, S be commutativegyigs with unity. Let ;a : R —> 5 be a ring homomorphism. If
J is an ideal of S, proOthat co-1(.7) ---- {r E R I co(r) E J} is an ideal of S. Further
show that if J is a e ideal in S, then co-1(J) is a prime ideal in R. (4)
(ii) Prove with correstification that the ideal generated by X in the polynomial ring
Q[X] is maxima& (2)
Q. 4. (a) Prove that the A/W of Gaussian integers Z[i] is an Euclidean domain. (6)
(b) (i) Let R b principal ideal domain and let 10 C .4 C /2 C • - • be an ascending chain of
ideals its . Prove that there exists k > 0 such that Ii = ./k for all j > k. (4)
(ii) D prime element and irreducible element in an integral domain R. (2)
(c) (i) v) an example, with correct justification, of a polynomial which is irreducible over
] but reducible over Q[X]. (4)
tate (without proof) Eisenstein's criterion. (2)
° —TURN OVER—
0
\N
.-.
Ncp
brb
,...,N OC-Con. 9762-16.
<Z(N)
-,..‘
 2 QP Code : 25648

Q. 5. Attempt any four out of six:

(i) Prove that every Euclidean domain is a principal ideal domain. (3)
(ii) Prove or disprove: if G is a group with subgroups H and K such that K is a normal in 4-
H and H is normal in G, then K is normal in G. (3) (--,Y
(iii) Let SL2 (C) be the group of all 2 x 2 invertible matrices over C of determinant one()--'
a b z+b
Suppose SL2(C) acts on C by ( z —a Determine the stabilizer o
cd cz+d .
SL2(C). C (3)
(iv) Prove or disprove the following statement: if two groups GI and 02 have the sg 1e class
equation, then they are isomorphic. \'`. (3)
(v) Let F be a field and let f (X) = a„,XTh + + • • • + a0 E F[X]. Pr4e that X —1

• is a factor of f (X) if and only if an + + - + ao = O.

(vi) Determine the number of ring homomorphisms from 42 to Z15. Q
O (3)
(3)
•R"."

.643/
CD

(e9
60

S)<S)./

`§•\;"."

(:) •
k/

AA •

cp

GP
_,_k,
vc-Con. 9762-16.
 QP Code : 25654

(3 hours)
Total marks: 60
N.B.
1) Attempt any TWO questions among question numbers 1, 2 and 3 and any TWO
questions among question numbers 4, 5 and 6. ,4
2) Figures to the right indicate full marks. •
3) Simple non-programmable calculator is allowed.
<<"

1. (a) State and prove the C,...inequality. Hence or otherwise prove or disprove
0 (05)
E(X 2 + Y2)312 E(IXI + WI).

(b) For a random variable with mean zero and variance a 2 , prove that (05)
(7 2
P(X > x) <
2 if x > 0. Further verify it for discrete uniform rand
•
variable
taking values -1 and 1.

(c) Prove convergence in probability implies convergence in disrtion. (05)

2. (a) Let X1,X2 ...X„ , be lid U(0,8) random variables. Prothat 2, converges in (06)
distribution to B. Does it converge in probability to 9? Iify.
/\c)‘
(b) State and prove Khintchines' Weak Law of Large rmbers for i.i.d. random (06)
variables.
<C,

(c) State Liapunouv's condition for CLT. Exarrrd if it is satisfied for i.i.d. exponential
(03)
random variables.
(Ye
3. (a) Define a Markov Chain. Let X3.,X2 . ,.....be i.i.d. random variables taking (05)
values -1 and 1 with probability h. Let Y, = X1+ ••• +X,. Show that {ic} is
a Markov Chain. JQ

(b) Let {X,:n = 0,1,2, ..... ) be r' Markov Chain with states space {1, 2, 3) and (05)
0• 0.3 0.4 0.3\
transition probability mJ\ (tpm), P = 0.4 0.3 0.3 .
0.3 0.3 0.4
(i) Find the stationley distribution.
(ii) If the initial ribution of X0 is uniform then find marginal distribution of X
i
and P{Xi — fXo = 2).

o+c,
(c) 0
Prove tlkal'a state j is persistent or transient according as E;;...,o pil)= to or < 00. (05)

.ate
40

[TURN OVER
OC-Con. 9764-16.
rb
\n
 QP Code : 25654

4. (a) For populations with linear trend and N = nk, show that, (10)
1 nk -F 1
Vst : Vs), : Vr„ • . - 1 -
n k +1
where Vs r,V_ V.anst andrespectivelyfor sampling variances of the sample 1*-‘
unbiased estimator of the population mean for stratified random sampling,
systematic random sampling and simple random sampling without replacement.
0<<"
(b) Consider the probability proportional to size sampling without replacement wAs.:(05)
inclusion probabilities n-i and rcip Let U and S represent set of population itit's
and sample units respectively. Consider the following estimator: C.)
1 k 1

•
0
N2 7rk N 2 \-4
keS k e S,I e S,k *1 71- kl 0

For what function of interest is this estimator unbiased?

t t-
5 (a) Suppose a population is divided into N clusters each ofarg`fv1 elementary units. (07)
Show that, the proportion of elements belonging to the ss 'A' in entire sample
is an unbiased estimator of proportion of element4elonging to class 'A' in
population. Derive the variance Of this estimator. 4\cD‘

(b) - In two-stage sampling, suppose a sample of e n first-stage units is selected (08)

from N units and a sample of size m se stage units is selected from each
selected first-stage units by simple om sampling without replacement.
Determine optimum values of m and thich will minimize the variance of the
sample mean for a fixed cost of the ey or alternatively will minimize the cost
of sample survey for given variano‘<of sample mean. State required assumptions
for determining values of mane.

C9
6. (a) In case of double samplinecs how that Rstd is an unbiased estimator of population (08)
mean. Also show that,aance is given by,
,RN r2 (1, 1\ ± w c2
viz 1.)
A a N
h=1 77- (- 9h

(b) What do you canby non-sampling error? Explain the main sources of non- (07)
sampling 6.3ors. Also describe traditional approach to minimize non-sampling
errors. S
r
Nt
Th
******M********

,1,1)0
0C-Con. 976446,,
\c,
 QP Code 25674

Duration:[2 Hours] [Marks: 60]

N.B. 1) All questions are compulsory and carry equal marks.
2) Solve any TWO sub-questions from each question.
NV
1. (a) Suppose the function f c C on the rectangle R : it - 71 Lc. a, Ix - El _< b (a, b > (6)
Let M = max I fit, 0)1, (t, x) E R and a = min (a, b/M). Prove that there exisq/ a
dx
solution 0 E Cr of the first order differential equation — = f (t, x) on It - TI < a fber ich
dt
0(7.)
(b) Do the following functions satisfy Lipschitz condition with respect to the6Variable on (6)
the sets indicated? Explain.
(i)f (x, = x2 cos2 + Sin2 on I xi < 1, < co N.9
(ii)f (x, y) = y213 on R : 101 < 1, lyl < 1
(c) Using Picard's method compute the first four successive approx.i bns Oho, 01, $2,03 for (6)
dy
the initial value problem — = x 4 y, y(0) = 1.
dx
CD
2. (a) Let xi, x2, ... 0, be a set of n functions defined on a real tci,ffterval I and let each function (6)
be differentiable (7/ - 1) times on I. If these functions linearly dependent on I, then
prove that the Wronskian W(xl, x2, ,x,)(t) = 0, Orle I. Is the converse true? Justify
your answer. („9
(b) Find the general solution of y" +4y = tan 2x 11,21"Na; method of variation of parameters. (6)
(c) (i) Let al , , at, be continuous functions dean interval I containing the point xe. If (3)
..,a„ are any it constants, provedat there exists a solution (;() of
L(y) = y(") + 2\e, y(n-1) + an(x)y = 0
on I satisfying 0(x0) = al, Or= a2, 0-1) (x0) = an :
1
(ii) Solve: y' + y e2x

3. (a) Let y(x) and z(x) be nontehl solutions of y" --I- q(x)y = 0 and z"+ r(z)z = 0 where q(x)
and r (x) are positive fu 'ons such that q(x) > r(x). Then prove that y(x) vanishes at
least once between tv hccessive zeros of z(x).
A' / 2 )2"4-p
(b) The Bessel functc J„(x) for any real number p is given by Jp(x) (
nx..0
Prove that 0
c-D
ExP Jp(x)1 9Jp_. (x)

4+1(x)
CY-
hence deduce that 24(4 = JP -1(M) - JP-hl(X)*

•
\P
,\<o CM-Con. 9729-16. [TURN OVER
np
 2 QP Code : 25674

(c) Find the eigen values an and eigen functions yn (x) for the boundary value problem (6)
+ Ay = 0, y(0) --= 0, y(ir/2) = 0,

4. (a) Derive the characteristic equations of the general first order quasilinear equation *6)
a(x , y,u)ux + b(x , y, u)uy = c(x , y, \

If co (x , y, u) = C1 and IP(x,y,u) = C2 be two independent first integrals of these cha

istic equations and 02y -1- '0! 0 0, then prove that the general solution of the abov ial
differential equation equation is given by
hogx, y, •0(x, y, u)) = 0, GO
where h is an arbitrary function.
(b) Solve the Cauchy problem: uz + 2uy = u2, with u(x, 0) = h(x), whe%h(x) is an arbitrary (6)
function of x.
C)
(c) Find the integral surface generated by the partial differential ration (6)
x(y2 + z) zx — y ( x2 + z) = (x2 et.?
1\-1
which contains the straight line x +y = 0, z = 1.
5. (a) Let An and an be distinct eigen values and y,n k and yn(x) the corresponding eigen
(6)
functions of the following Sturm Liouville probldal)
:C51
d dyl
[Aq(z)()] y = 0, a < x < b

with the boundary conditions c y (a) 4 (a) = 0, do(b) + d2y1(b) = 0, where either ci or
c2 0 0 and either d1 or d2 0 0. .AleQp(x), .71 (x), q(x) and r(x) are continuous functions
rb „.3"•
on [a, b]. Then show that q(4-,„(x)y,i(x)dx = 0 form # n.
a CY
(b) Find the linearly independV solutions of y'" — 4y' = 0 and compute their wronskian. (6)
Compute the solution $ h that q5(0) = 0, 91/(0) = 1, "(0) = 0.
(c) Find a general solutigl the following system: (6)
A• dx
x + 3y
dl
CO dy
= 3x + y

GP
9
c<2
0
0
<o OC-Con. 9729-16.
 QP Code : 25680

(3 hours)
Total marks: 60
N.B.
1) Attempt any TWO questions among question numbers 1, 2 and 3 and any X"
TWO questions among question numbers 4, 5 and 6.
2) Figures to the right indicate full marks. c
3) Simple non-programmable calculator is allowed. 00

1. (a) For the row column design, obtain the reduced normal equations (10)_D
Q = F2 for estimating treatment effects.

(b) Under usual notations for PBIBD(m), prove that c3(05)

0.4N
Sx[Sx(TO1= rixTi PLSi(ri)
1=1
<C)
7-1
2. (a) Define Graeco Latin Square design. State its mathematical odel. Also (10)
obtain normal equations for estimating parameters of thiXmodel.

(b) Write a short note on split plot design. Also state its lahematical (05)
model. i\c")‘

3. (a) Consider the set of jth associates of all ith a s iates of treatment O. Let (05)
4) be the hth associate of 0. Then prove t 4 reatment (I) occurs in this
set PO times and treatment 0 occurs intiis set zero or n, times
according as i j or i = j respectiveW

(b) For any weighing design matr prove that, variance of estimated (05)
weight of one particular ob cannot be less than 62/n.

(c) 1 1 1 0 (05)
1 1 0
Let X =
I 0 ,c \
0 1z"1 1
N<
denote w ring des'gn matrix. Obtain the variance of the estimated
weight. ero is replaced by -1 find variance of individual weight. Is the
low ound attained?

4. (a) tain four independent treatment combination of 215.11 resolution III (05)
ractional factorial design. Explain how you will obtain the remaining
NC treatment combination of the fraction.

Page 1 of 2
OD

<D
OC-Con. 9731-16. [TURN OVER
 2 QP Code : 25680

(b) Construct principal block of 27-2 FFD with defining contrast F=ABCD (05)
and G=ABDE. Give the treatment combination of this design which may
be divided into two blocks of 16 observations each confounding ACE
with the blocks.

(c) Write the defining relation using the defining contrast F=ABCD, (05)
G=ABDE, E=±AC of any one of the fraction given in 4(b) above. Give
the alias effect relation involving two factor interaction assuming three
or higher factor interactions are suppressed. What is resolution of this
design?

5. (a) For 33 factorial experiment in r replicates, explain the method of (05)

computing sum of squares due to components P(111),P(112),P(121
and P(122). Also give the procedure to compute sum of squares ¢¢ua o
interaction ABC. How are these two types of sum of squares rel teel

(b) Consider 35 design in nine blocks of having 27 treatment con'Onations (05)

each with P(11100) and P(00111) as independent interacgn chosen to
be confounded with the blocks. Give three inciependen. atmont
combination of the key block using Das method. Expl6 how to obtain
the remaining treatment combinations. Find the Gehcelalised interaction
components confounded with blocks and explairzpw to obtain the
remaining blocks of this design. \r-
(c) Consider 35-2 fractional factorial design o 0 ned using the key block of (05)
design given in 5(b). For this design obt the defining relation. Give
the alias effect relation involving mai ects and interaction
component of two factors assumin tree or higher factor interactions
are suppressed.

6. (a) The following data were coil td by a chemical engineer. The

(10)
response y is filtration tirnc4Rxiis temperature, x2 is pressure. Fit a
second order response (place model. Also obtain ANOVA table.
x1 x2 y Xy x2 Y
-1 -1 ÷ C 0 y5 . 0 0
Y9
-1 1 he Ni5 0 Y6 0 0 Y10
1 -1 -Y 0 —V/ Y7 0 0 Y1.1
1 1 0 y,/, 0 if 0 0
Ye Y12
cc
(b) ConsidOthe fitted second order response surface model
0 (05)
2 = BO + 2x/ '+ 3x2 — 1.54 — 24 — xix2
D(etermine the stationary point and comment on the same.

OJ
c,
‘
******************

Page 2 of 2
0
0
OC-Con. 9731-16.
b)
ON
 QP Code : 20037

( 21/2 Hours) [ Total Marks : 60

N.B. : (1) All questions are compulsory.
(2) Figures to the right indicate full marks.
(3) Symbols have their usual meanings unless otherwise stated.
(4) Use of log tables / non-programmable calculator is allowed. <<"
0
1. (a) Attempt any one: -
(i) Show that the set of reciprocal lattice vectors G determines the possible c
x-ray reflections.
<
(ii) Monochromatic plane waves are elastically scattered from a crysta0.he
\
sample. State the expression for the scattered wave. Dedwei the
expression for intensity of these scattered waves.
(b) Attempt any one : - 4
(i) Obtain the reciprocal lattice of: simple cubic lattice Ot1 face centred
cubic lattice.
(ii) Write a short note on Low Energy Electron Difqation (LEER).
\CD
2. (a) Attempt any one: -
e, P
(i) Derive the dispersion relation for trOliatomic lattice. Hence or
otherwise explain the significance 2</fl'
ni st Brillouin zone.
(H) What is harmonic theory? State Cttig consequences. Explain thermal
expansion in solids using anhanic interactions.
(b) Attempt any one : - <</ 4
(Z--
(i) Explain thermal conductety of a solid using kinetic theory of gases.
(H) Show that phonon moSntum in a crystal is zero except for uniform
mode K 0 . 0
0•
3. (a) Attempt any ones 8
(i) Derive ark-Qpression for paramagnetic susceptibility of conduction
el ectro4</
(ii) State jeid explain the Hund's rules with suitable examples.
(b) Atte any one : - 4
(i) xplain the process of adiabatic demagnetization.
.
4.1) Estimate the susceptibility of solidArgon. At 4K Ar" has concentration
,c0 as 2.66 x 1028 atoms/m'. The root mean square distance of an electron
from the nearest Argon nucleus is 0.62 AU. Also calculate the
O magnetization of solid Argon in a 2.0 T induction field.
'r\‘‘ [TURN OVER
\c) OR-Con. 11999-16.
 OP Code : 20037

-2-

4. (a) Attempt any one:-

(i) Give brief account of Heisenberg Exchange theory to illustrate the
Origin of ferromagnetism. Obtain the expression of Heisenberg
Exchange coefficient J.
(ii) Derive the expression for Bloch Fa law.
(b). Attempt any one : -
(i) With the help of Band model, show that the effective number of
magnetons of ferromagnetic material is non-integer.
(ii) Write a short note on Bloch Wall.

5. Attempt any four: -

(a) Find the structure factor for an fro crystal structure when scatting peaks
are indexed to a simple cubic lattice. Take atomic form facto' to be f
(b) Write a short note on Ewald constructions.
(c) Write a note on Quantization of elastic waves.
otta
(d) How imperfections in a crystal affect thermal conducctivity of solid?
(e) Cobalt has 7 electrons in its 3d shell. Compute effective number of
Bohr magnetons of a Cobalt ion without consic&ing the quenching effect
of its orbital angular momentum.
Write a note on magnetic properties of, earth elements.
Describe Spinel structure. r 0NY
The susceptibility of an antiferrotatnet is 2. 53 at its. Neel temperature
(TN = 116K). Determine its Ctreonstan .

c o
cp

OJ

,C5C)

rb OR-Con 11999-16.
 QP Code : 29040

(2% Hours) [ Total Marks ; 60

N.B. 1) All questions are compulsory.

2) Figures to the right indicate full marks.
3) Use of logarithmic table/non programmable calculator is allowed.

Q.1 A Attempt any two of the following:

a) Draw a labeled schematic diagram of Michelson's interferometer. Explain its 4
working in FTIR.,
b) What are the different types of IR Sources? Describe any one in detail. OC4
c) The observed 2 ...values for phenol and phenolate ion are 211nm and 235 me 4
respectively while in case aniline and anilinium ion 2. „,,,,, values arc 230 ri4‘and
203nm respectively. Explain. 0
d) With respect to spectroscopic analysis, explain the use of wavelen 4
selectors. Describe prism monochromators in detail.
t."
B Attempt any one of the following:
O<C#
a) What are thermal transducers? Describe any one therm <CYsducer in detail. 4
b) A simultaneous determination for cobalt and nickel 1,0is based upon 4
absorption by their respective 8- hydroxygninolino& - inplexe,s. Calculate the
molar concentration of nickel and cobalt ions inSilution of nickel and cobalt
ions on the basis following data.
Thickness of absorbing medium is 1 cm)
Solution Molar absorptivi.. Absorbance
a mole-I dm3cri&t
365nm (j 700nm 365nm •700nm
Cobalt 65 <>1 5493 ---
Nickel 3235 `R-- 'C. 15 ---
Mixture of cobalt 9..--- ---- 0.553 0.346
and nickel %
re, •

Q.2 A. Attempt any two~o e following:

a) With the help olabeled diagram, describe lithium drifted silicon detector used 4
in X-ray spe oscopy.
b) With refer re to mass spectrometry, discuss the purpose and types of inlet 4
systernQ
e) Descripe wavelength dispersive instrument used in X-ray fluorescence 4
sp; escopy
the help of suitable diagram , describe the construction and working of 4
adrupole mass analyzer.
<c
‹)
•\-B. Attempt any one of the following:
<C/l a) Name ion sources used in molecular mass spectroscopy. Discuss any one in
detail.

TURN OVER
(I)

OR-Con. 12000-16.
 2 QP Code 20040

b) Describe following technique with respect to compensation of matrix effect in 4

X-ray spectroscopy
i) External standard calibration
ii) Use of internal standard.

Q.3 A. Attempt any two of the following:

a) Describe the enzyme electrodes that can be used to measure blood urea
nitrogen. 4 0
b) What are gas sensing probes?With the help of schematic diagram, describe a 40
gas sensing probe used for determination of dissolved CO2 in sample solution.
What are the applications of coulometric titrations?
d) Explain controlled cathode potential electrogravimetry <<,- 4
B. Attempt any one of the following: \-4
a) A cell consisting of a saturated calomel electrode and nickel electrode 0
4
developed a potential of -0.483V when immersed in 40.0cm3 of s. ,41e
solution .When 5.0 cm3 of standard 1.75x10-2M nickel ion soluti9ft was added
to the sample solution the potential of the cell shifted to -0.442 2. Calculate the
concentration of nickel ions in sample solution in terms ofz >.:Vi.
b) A 0.1895g sample of a purified organic acid was neutraleiVi by the hydroxide 4
ions produced, in 8 min 12 seconds by a constant curreab of 380 mA. Calculate
gram equivalent weight of the acid. (1 Faraday = 96nEVC)

Q.4 A) Attempt any tvvo of the following:

0 types? Discuss its
a) What is pulse polarography? What are its dg rent
advantages over normal polarography.
b) Discuss the basic principle of cyclic v +\11aetry with respect to
(i) the triangular waveform of the aped potential.
(ii) the peaks produced in the cyc
c) Give the advantages and limita s of the dropping mercury electrode as 4
compared with platinum or c n microelectrode.
d) What is bi-amperometric tifta on? Explain the nature of amperometric 4
titration curve. 0.
B) Attempt any one e following:
a) State the Randlee evick equations for the peak current used in cyclic 4
voltametry angive the significance of each term involved in it. How is the
peak pote lid/ p) for a reversible process related to half wave potential Ein?
b) Calculat e concentration of Ccr2 ions in a solution which gave a diffusion 4
currezt,c6f 67pA.
Giv\e. Diffusion coefficient for Cd' = 5.7 x 10-scm2s1, Rate of flow of
nylircury drops = 3.4mg 5-1, drop time = 3.5 s
C.)
N.)
Q.5 ic, Attempt any four of the following: 12
Describe the methods of sample preparation in recording IR spectra.
<<3.-
' b) Give a brief account of fiber optics in optical instruments.
\,
10
•K"-' [ TURN OVER
rb
OR-Con. 12000-16.
NU
JQ
 Cir Cods ;

c) Describe rotating crystal method used in X-ray diffraction analysis.

d) Explain basic principle of mass spectrometry.
e) Explain the factors affecting the nature of deposit in clectrogravimetry.
0 How ion Selective field effect transistors are useful in determination of pH?
g) Give an account of anodic stripping voltametry.
h) Discuss the principle of Karl Fisher titrati on

xx

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0.

0
cp

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4€ _÷

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rb
OR-Con. 12000-16.
O~b
 QP Code : 25657

(21/2 Hours 77 ' ' 1.110;'!-cri GO

Total ivlorks:. 60
N.B. (1) All questions are compulsory and carry equal marks.
(2) Figures at the right indicate marks for each sub-question.
(.3 Attempt any two sub-questions from all questions.
Q.1 (a) i. Let X be a set. Define a basis for a topology on X. Give an example of a
• basis for standard topology on R. Justify.
ii. Let aq, and 72 be two topologies 011 X such that aq, C 7-2. Let A be any
subset of X. Then show that every limit point of A with respect to (X, 72)
is also a limit point of (X, TO.
(b) i. State and prove pasting lemma (or gluing lemma ).
C/C
ii. Consider finite complement topology on R. Determine K if /..SE
K={ e
\ „\-4
(c) Let X be a topological space, Y be a set and f : X Y a functie\—from X
onto Y. Define quotient topology determined by f. Show that (be quotient
topology determined by f : X Y is a tupology for Y.
Q.2 (a) i. Prove or disprove: R2 \ Q2 is path connected in usual o ology.
ii. Let A{ E R21 3:2- v2 < 1} and B {(1, 0), (g1-3, (-1,0), (0,-1)}.
Prove or disprove: AU B is connected in H2 witeRandard topology.
(b) i. Define a connected component of a topologicaifipace. Show that if C is
connected component of X then there does n&l exist a connected subspace
D of X such that C C D
X- (3)
Let (X, r) be a topological space. Slactlint each connected subset of X
i_, ;;of X.
is contained in exactly one comport .1(( (3)
Let X be locally path connected., tow that every connected open set in
X is path connected.
6\/ (3)
Show that if X is locally paiwconnected, then the components and path
components of X are the tie.
Q.3 (s.) i. Show that finite unio4ccompact subspaces of X is compact.
ii. Show that every coSact subspace of Hausdorff space is closed.
(b) i. Using Tube lem4-aslow that the product of finitely many compact spaces
is compact. ef) •
ii. Let f : X 't be continuous, where R is topological space with standard
topology ow that if X is compact, then there exist points c, d G X such
that 0'5 f (x) .5_ 1(d) for every x E X.
(3)
(c) Let X kcsi a locally compact Hausdorff space. Construct a space Y which
satisgpfollowing conditions:
is a subspace of Y.
41i. The set Y — X consist of a single point.
O (C) -17 is a compact Hausdorff space.
(6)
[TURN OVER
Atit
N.)
QC-Con-9753-16.
 2 QP Code : 25657

Q.4 (a) Let (X, d) be a metric space. Show that there is an isometric embedding of
X into a complete metric space. (6)
(b) Let (X, dx) and (Y, dy) be metric spaces; let Y be complete. Let A C X.
Show that if f : A -# Y is uniformly continuous, then f can be uniquely
extended to a continuous function g : A ---> Y, and g is uniformly continuous. \Y-
(6) \-4
(c) Show that the metric space (X, dx ) is complete if and only if for every nested /5'
sequence Al D A2 D • of non empty cloend sots of X such that Metymi,, a

the intersection of the sets An is non-empty.

/f C?)
Q.5 (a) i.Define Tg, Tj and T, spaces. ov (3)
ii. Let :r„.} be a sequence in a metric space (X, d) which converges toC
X. Prove that the set A = {x7, : n E U {x0} is compact. rtS (3)
(b) Define locally compact space and show that Iku with product topcOgy is not
locally compact, where Rw is a countable cartesian product of topcCielgical space
H with standard topology. k'v) (6)
-7.
(c) Let A and B be disjoint compact subspaces of the Haus If space X. Show
that there exists open sets U and V containing A and spectively. (6)

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< OC-Con.9753-16.
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