ANDHERI / BORIVALI / DADAR / CHEMBUR / THANE / MULUND/ NERUL / POWAI

IIT – JEE: 2019 NCERT based Test DATE: 31/08/17

TIME: 0.5 hours TOPIC: Periodic Properties MARKS: 80

1. Which of the following predictions were as per Mendeleev’s periodic table?

(I) eka – boron ⇒ Gallium (II) eka – silicon ⇒ Germanium
(III) eka – Aluminium ⇒ Gallium (IV) eka – Technetium ⇒ Manganese
(A) I, II, IV (B) I, II (C) II only (D) II, III

2. Which of the following is the nomenclature for Mendelevium? (Atomic Number = 101)
(A) Unnilunium (B) Unnilnilium (C) Uninilunium (D) Uninilniliumn

3. The first inner – transition series begins with atomic number ________

4. Which of the following is not correct?

(A) Oxides of alkali metals are basic
(B) Oxides of halogens are acidic
(C) Oxides of some elements around the center of periodic table are amphoteric
(D) CO, NO, H2O etc. may act acidic or basic

5. Despite being present in d – block, group __________ elements do not show most of the properties
like coloured ions, variable valency, paramagnetism etc of transition elements.

6. Which of the following is transuranic element?

(A) z = 90 (B) z = 92 (C) z = 93 (D) None of these

7. Arrange the following in increasing order of atomic size.

Mg, Mg2+, Al, Al3+

8. I.E. vs. Z graph - Identify the elements at Peaks and Valleys (Write symbols only)

0 z
10 20 40

PEAKS VALLEYS

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9. What is Zeff for the He as per Slater's rule ?

10. What is the relationship between electron affinity (EA) and electron gain enthalpy (∆HEG)

11. Compare EA between P, S, Cl and F.

12. The electronegativity of element is a constant value. (True / False)

13. Identify the nature of following oxides:

Acidic (A), Basic (B), Amphoteric (Ap), Neutral (N)

Li2O – Tl2O3 – As2O3 –

Na2O – CO – As2O5 –
K2 O – CO2 – Sb2O3 –
BeO – SiO2 – Sb2O5 –
MgO – GeO – Bi2O3 –
CaO – GeO2 – SO2 –
SrO – SnO – SO3 –
BaO – SnO2 – SeO2 –
B2O3 – PbO – TeO2 –
Al2O3 – PbO2 – Cl2O7 –
GaO – NO – H2 O –
Ga2O3 – N2 O –
In2O3 – N2 O5 –
N2 O3 –
P4 O6 –
P4O10 –

14. Compare the following in terms of size.

(A) Li+, Be2+, Na+, Mg2+
(B) Li+, Li, Na, Na+, Mg, Mg2+

15. Locate the group and period of the element ununquadium.

16.
Element ΔH IE ΔH IE 2 ΔH EG
(All values in kJ / mole)
A 520 7300 – 60
B 419 3051 – 48
C 1618 3374 – 328
D 1008 1846 –295
E 2372 5251 +48
F 738 1451 +50

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 i) Least reactive element is ________
ii) Most reactive metal is _________
iii) Most reactive non metal is _________
iv) Least reactive non metal is __________
v) Element that can forms a stable binary halide of the formula MX2 is _______

17. Mark (True /False) for the following:

i) Tc43 is an artificial element
ii) Elements after z = 92 are transuranic elements
iii) Liquid non – metal Br
iv) Liquid metal – Hg, Ga, Cs
v) Solid non – metal (Volatile) – Iodide
vi) Lightest metal – Li
vii) Heaviest metal – Ir
viii) Hardest metal – W
ix) Lowest electro negativity – Cs
x) Highest electro negativity – F
xi) Highest ionization energy – He
xii) Lowest ionization energy – Cs
xiii) Highest electron Affinity – Cl
xiv) Least electropositive element – F
xv) Most electropositive element – Cs

18. Write the electronic configuration of the following elements. Eg., Fez6 ⇒ [Ar ] 4s2 3d6
i) Cr –
ii) Cu –
iii) Pd –
iv) Ag –
v) Pt –
vi) Au –
vii) La –
viii) Ac –

19. For the electrons of oxygen atom, which of the following statements is correct?
(A) Zeff for an electron in a 2s orbital is the same as Zeff for an electron in a 2p orbital.
(B) An electron in the 2s orbital has the same energy as an electron in the 2p orbital.
(C) Zeff for an electron in 1s orbital is the same as Zeff for an electron in a 2s orbital.
(D) The two electrons present in the 2s orbital have spin quantum numbers ms but of opposite sign.

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ANSWER KEY

1. C
2. A
3. 58
4. D. The mentioned examples are neutral oxides
5. 12 or IIB
6. C
7. Al3+ <Mg2+ <Al <Mg
8.
PEAKS VALLEYS
He Li
Ne Na
Ar K
Kr Rb
Xe Cs

9. 1.7

10. ∆HEG = – EA – 5/2 RT

11. Cl > F > S > P

12. False
13. Li2O – B Tl2O3 –B As2O3 –Ap
Na2O –B CO – N As2O5 –Ap
K2 O – B CO2 – A Sb2O3 –Ap
BeO – Ap SiO2 – A Sb2O5 –Ap
MgO – B GeO – A Bi2O3 –B
CaO – B GeO2 –A SO2 –A
SrO – B SnO – Ap SO3 –A
BaO – B SnO2 – Ap SeO2 – A
B2O3 – Ap PbO – Ap TeO2 –A
Al2O3 –Ap PbO2 – Ap Cl2O7 –A
GaO – Ap NO – N H2O –N
Ga2O3 –Ap N2 O – N
In2O3 – B N2 O5 – A
N2 O3 – A
P4 O6 – A
P4O10 –A
14. Be2+<Mg2+<Li+< Na+
Mg2+<Li+<Na+<Li<Na<Mg
15. Group = 14, period = 7
16. i) E
ii) B

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 iii) C
iv) E
v) F
17. All true
18. i) Cr – [Ar ] 4s1 3d5
ii) Cu – [Ar ] 4s1 3d10
iii) Pd – [Kr ]5s0 4d10or [Kr ] 4d10
iv) Ag – [Kr ] 5s1 4d10
v) Pt – [Xe] 6s1 5d9
vi) Au – [Xe] 6s1 5d10
vii) La – [Xe] 6s2 5d1
viii) Ac – [Rn ] 7s 2 6d1

19. D

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