Beruflich Dokumente
Kultur Dokumente
and Calculations
By
Assist. Prof. Dr. Wipada Sanongraj
Chapter I : Introduction to
Chemical Engineering
Calculations
Rules of operation
Only same units can be added or subtracted
For example, 10 lbs + 5 grams
5 kgs + 3 Joules
1 ft + 3 sec
1 horsepower + 30 watts
Example of SI units
Physical Quantity Name of Unit Symbol Definition of Unit
Basic SI Units
Length meter m
Mass kilogram kg
Temperature kelvin K
Time second s
Amount of substance mole mol
Derived SI Units
Energy Joule J Kg.m2.s-2
Force Newton N Kg.m.s-2 J.m-1
Power watt W Kg.m2.s-3 J.s-1
Density Kilogram per cubic meter Kg.m-3
Acceleration Meter per second squared m.s-2
Velocity Meter per second m.s-1
Pressure Newton per square N.m-2, Pa
meter, pascal
Heat Capacity Joule per J.kg-1.K-1
(kilogram.kelvin)
Alternative Units
Time minute, hour, day, year min, h, d, y
o
Temperature Degree Celsius C
Volume liter L
Mass ton, gram t, g
Example of American
Engineering System Units
SI Prefixes
2 1100 ft 1 mi 60 s 60 min
s 5280 ft 1 min 1 hr
= 4.56 cm3/min
Solution
= 155 (ft)(lbf)
Dimensional Consistency
The equations must be dimensionally consistent in
order to be able to operate.
Each term must have the same net dimensions and
units in the equation.
For example, van der Waals equation
atm.cm6
cm3
a
(P + )(V - b ) = RT
V2
atm cm3
= 22.7 g mol
(b) 2.00 lb NaOH 1 lb mol NaOH 454 g mol
40 lb NaOH 1 lb mol
Density
Or
m3
Be Cautious!!!!!
Solution
First, we need to transform the mass
fraction of 0.412 into mass per liter of the
drug. Take 1.00 kg of the exit solution as a
basis
Basis: 1.00 kg solution
0.412 kg Drug
Reactor
0.588 kg Water
= 0.0226 kg mol/min
1.3.4 Concentrations
Concentration is the quantity of some solute
per specified amount of solvent, or solution,
in a mixture of two or more components
(1) mass per unit volume (lbm of solute/ft3, g of
solute/L, lbm of solute/bbl, kg of solute/m3)
(2) mole per unit volume (lb mol of solute/ft3, g
mol of solute/L, g mol of solute/cm3)
(3) Parts per million (ppm), parts per billion
(ppb)
(4) Other methods of expressing concentration
e.g., molarity (g mol/L) and normality
(equivalents/L)
10 g mol HCN 27.03 g HCN 1 g mol air 103 mg HCN 103 g air
106 g mol air 1 g mol HCN 29 g air 1 g HCN 1 kg air
1.4 Basis
To chose the basis, ask yourself these
questions
What do I have to start with?
What answer is called for?
What is the most convenient basis to use?
O 1 0.5 16 16 0.1
Solution
Basis: 100 kg Coal
The sum of S+N+O+ash+water is 2+1+6+11+3=23
kg
Hence the C and H must be 100-23=77 kg
To determine the kilograms of C and H, we have to
select a new basis. Because C/H is molar ratio
Basis: 100 kg mol of C and H
Component Mole kg mol Mol. Wt kg
Fraction
H 9/10 0.9 90 1.008 90.7
H: 77 kg 90.7 kg H
210.7 kg total = 33.15 kg H
C: 77 kg120 kg C
210.7 kg total = 43.85 kg C
Summarized table
Component kg Wt. Fraction
C 43.85 0.51
H 33.15 0.39
S 2 0.02
N 1 0.01
O 6 0.07
Total 86.0 1.00
1.5 Temperature
The temperature is a measure of thermal
state considered in reference surrounding
Units of temperature: Fahrenheit (F),
Celsius (C), Rankine (R), Kelvin (K)
Absolute temperature scales have their
zero point at the lowest possible
temperature that can exist.
Temperature measuring
instruments span the range
from near absolute zero to
beyond 3000 K.
Temperature scales
= 211 Btu/(hr)(ft2)(K/ft)
Conversion
The heat capacity of sulfuric acid in a handbook has
the units J/(g mol)(°C) and is given by the relation
heat capacity = 139.1 + 1.56 ×10-1T
Where T is expressed in °C. Modify the formula so
that the resulting expression has the associated units
of Btu/(lb mol)(°R) and T is in ° R
1.6 Pressure
Pressure is normal force
per unit area Pressure at the bottom of the
static column of water is
p = F/A = rgh + p0
p = pressure at the bottom of the
column of the fluid
F = force
A = area
r = density of fluid
g = acceleration of gravity
h = height of the fluid column
p0 = pressure at the top of the
column of fluid
Open-end manometer
Barometer
Standard atmosphere:
760 mm Hg, 29.92 in Hg
33.91 ft H2O
1 atm
1.013 bars
14.7 psia
1.013*105 Pa or N/m2 or 101.3 kPa
Solution
The pressure gauge is reading psig
Absolute pressure = gauge pressure +
atmospheric pressure
Basis: barometric pressure = 28 in Hg
Atmospheric pressure = 28 in Hg 14.7 psia
29.92 in Hg
= 13.76 psia
Absolute pressure in the tank
51.0 + 13.76 = 64.8 psia
Solution
We can ignore the gas density above the
manometer fluid.
Basis: 730 mm Hg
Atmospheric pressure = 730 mm Hg 29.92 in Hg
760 mm Hg
= 28.7 in Hg
Basis: 4 cm H2O draft (under atmospheric)
4 cm H2O 1 in 1 ft 29.92 in Hg = 0.12 inHg
2.54 cm 12 in 33.91 ft H2O
The reading is 4 cm H2O draft, the absolute reading
in uniform units is
28.7-0.12 = 28.6 in Hg
Example 1.20:Vacuum
Pressure
Small animals can live at reduced air
pressure down to 20 kPa. In a test a
mercury manometer attached to a tank
reads 64.5 cm Hg and the barometer
reads 100 kPa. Will the mice survive?
Solution
Basis: 64.5 cm Hg below atmospheric
the absolute pressure in the tank is
100 kPa – 64.5 cm Hg 101.3 kPa
76 cm Hg
= 100 – 86 = 14 kPa absolute
The mice will not survive
Solution
p1-p2 = (rf-r)gd
= (1.1-1)103 kg 9.807 m 22*10-3 m 1 Ns2 1 Pa*m2
m3 s2 kg*m 1 N
= 21.6 Pa
= 30.8 kg CO2
Example1.23: Chemical
Equation
In the combustion of heptane, CO2 is
produced. Assume that you want to
produce 500 kg of dry ice per hour and that
50% of the CO2 can be converted into dry
ice, as shown in Figure. How many kg of
heptane must be burned per hour
Other products CO2 gas 50%
Solution
Basis: 500 kg of dry ice (equivalent to 1 hr)
C7H16 + 11 O2 7 CO2 + 8 H2O
500 kg dry ice 1 kg CO2 1 kg mol CO2 1 kg mol C7H16 100 kg C7H16
0.5 kg dry ice 44 kg CO2 7 kg mol CO2 1 kg mol C7H16
= 325 kg C7H16
Example 1.24:
Stoichiometry
A limestone analysis
CaCO3 92.89%
MgCO3 5.41%
Insoluble 1.70%
(a) How many pounds of calcium oxide can
be made from 5 tons of this limestone?
(b) How many pounds of CO2 can be
recovered per pound of limestone?
(c) How many pounds of limestone are
needed to make 1 ton of lime?
Solution
Basis: 100 lb of limestone
CO2
Limestone
CaO
Heat MgO Lime
Insoluble
CaCO3 CaO + CO2
Limestone Products
Component lb = % lb mol Solid lb CO2 (lb)
Component
CaCO3 92.89 0.9280 CaO 52.04 40.83
100 lb stone
Things to realize !!
In industrial reactors you will rarely find exact
stoichiometric amounts of materials used.
Limiting reactant is the reactant that is present in
the smallest stoichiometric amount.
For example
A + 3B + 2C = P
1.1 mol of A, 3.2 mol of B, and 2.4 mol of C are fed
as reactants in the reactor, we choose A as the
reference substance and calculate
Ratio in feed Ratio in chemical equation
B/A 3.2/1.1 = 2.91 3/1 = 3
C/A 2.4/1.1 = 2.18 2/1 = 2
Solution
Component kg MW g mol
Sb2S3 0.6 339.7 1.77
Fe 0.25 55.85 4.48
Sb 0.2 121.8 1.64
FeS 87.91
1.64 g mol Sb
Chapter 2
Material Balance
Closed system
System boundary
Open system
System boundary
100 kg 70 kg
Thickener
Wet sludge Dehydrated sludge
Water = ?
100 kg = 70 kg + kg of water
kg of water = 30 kg
Tank
Accumulation = Vtank(dC/dt)
é Accumulation ù dC
ê within the system ú = Vtan k dt = [QinCin ] - [Qout Cout ] + [ 0] - [ 0]
ë û
Problems
a) Tea kettle
b) Fireplace
c) Swimming pool
21% O2
25% O2
Input
Flow Output
79% N2 75% N2
O2 N2
waste stream
solution
This is a steady state process without chemical
reaction so that the accumulation term and the
generation and consumption terms are zero. The
system is the membrane. Let xO2 be the mole
fraction of oxygen and xN2 be the mole fraction of
nitrogen, and let nO2 and nN2 be the respective
moles.
F (g mol) P (g mol)
Membrane Mol fr.
Mol fr. O2 0.25
O2 0.21 W (g mol) N2 0.75
N2 0.79 Mol fr. Mol 1.00
1.00 O2 xO2 nO2
N2 xN2 nN2
1.00 W
Or
In Out
O2: 0.21(100) = 0.25(P) + nO2
N2: 0.79(100) = 0.75(P) + nN2
80 = nO2 + nN2
H2SO4 77.7%
H2O 22.3%
System
Accumulation = In - Out
Basis : 200 kg of A
Final Initial
Total P - F = 200 - 0
Because the equations are linear and only two occur, you
can take the total mass balance, solve it for F, and
substituting for F in the H2SO4 balance to calculate P.
P = 2110 kg acid
F = 1910 kg acid
A in F in P out
Total A + F = P
W = 100 kg H2O
0 kg H2O
A kg
Rotary dryer
Wet fish Cake = ?
B kg
0.8 H2O Dry fish Cake = ?
0.2 BDC
0.4 H2O
0.6 BDC
Tie component
We will use total mass balance plus the BDC balance rather
than the water balance. Because the BDC balance is
slightly easier to use. The water balance can be used as a
check on the calculations.
In Out
Saturated solution at ? oC
Saturated solution at 30 oC
Na2CO3 Na2CO3
H2O
H2O
System boundary
Na2CO3.10H2O
3000 kg
Solution
We need solubility data for Na2CO3 as a function of
temperature
10,000 kg
Na2CO3 = 0.280 Na2CO3 P = ? Kg
Na2CO3
H2O = 0.720 mNa2CO3
mH2O
H2O
H2O
System 3,000 kg
Na2CO3.10H2O Na CO = 0.371
boundary 2 3
H2O = 0.629
CO2
CO Flue gas
on SO2 Flue gas
Stack Gas O2
free basis or Orsat analysis
N2
or dry basis
SO2
H2O
1 C 1 CO2
Combustion
1 O2
C + O2 CO2
The material balance for O2 in moles
Acc. In Out Gen. Cons.
O2 0 = 1 - 0 + 0 - 1
C
O2
excess O2
% excess air = 100
O2 entering - excess O2
Solution
This is a problem involving the following reaction
C3H8 + 5O2 3CO2 + 4H2O
The required O2 is
20 kg C3H8 1 kg mol C3H8 5 kg mol O2
44 kg C3H8 1 kg mol C3H8
= 2.27 kg mol O2
The entering O2 is
= 28%
Example 2.9
Suppose a gas containing 80% C2H6 and 20%
O2 is burned in an engine with 200%
excess air. Eighty percent of the ethane
goes to CO2, 10% goes to CO, and 10%
remained unburned. What is the amount
of excess air per 100 moles of the gas?
2Na2SO3 + O2 2Na2SO4
= 886 lb Na2SO3
nPCO2 = 1
nPH2O = 2
nPN2 = 8.18
nPO2 = 2.17 - 0.5(2) – 1 = 0.17
P = 1 + 2 + 8.18 + 0.17 = 11.35
From xiP = (niP)/P
xPCO2 = 0.09 xPN2 = 0.72
xPH2O = 0.18 xPO2 = 0.01
W
H2O
kg mol
mass fr.
F Catalytic G
C 0.88
Test liquid oxidation unit kg mol
H2 0.12
kg
1.00
mol fr.
mol fr. A CO2 0.134
N2 0.79 Air (dry) N2 0.830
O2 0.21 kg mol O2 0.036
1.00 1.00
C: 0.88F + 0 - 0 - 0.134(100) = 0
12
H2: 0.12F + 0 - W - 0 = 0
2.016
excess O2
% excess air = 100
O2 entering - excess O2
or excess O2
% excess air = 100
required O2
The required O2 is
C + O2 CO2 182.73*(0.88) = 13.40 kgmol
12
Component Percent
C 83.05
H 4.45
O 3.36
N 1.08
S 0.70
Ash 7.36
Total 100.0
Component Percent
CO2 + SO2 15.4
CO 0.0
O2 4.0
N2 80.6
Total 100.0
Moisture in the fuel was 3.9%, and the air on the average
contained 0.0048 lb H2O/lb dry air. The refuse showed
14.0% unburned coal, with the remainder being ash. You are
asked to check the consistency of the data before they are
stored in a data base. Is the consistency satisfactory? What
was the average percent excess air used?
Basis : F = 100 lb
7.36 = R(0.86)
R = 8.56 lbs
8.56(0.14) = 1.20 lb
N - - - -
9.524 - 7.942
% excess air = 100 = 19.9%
7.942
4.00
% excess air = 100 = 23.8%
15.4 + 2.746 / 2
Recycle, R
2 4
3
1
1. About the entire process
2. About the junction point at which the fresh feed
is combined with the recycle stream
3. About the process only
4. About the function point at which the gross
product is separated into recycle and net product
R=?
0.286V
0.714 H2O
F
98 lb/hr Continuous
20% V Centrifuge
80% H2O Filter
C=?
60% V
40% H2O
P=?
W=? 4% H2O
H2O 100% 96 % V
Basis : 1 hr (F = 98 lb)
Overall mass balances
In Out
V: 0.20(98) = 0 + 0.96P
H2O : 0.80(98) = (1.0)W + 0.04P
Total : 98 = W + P
Solving for P and W
P = 20.4 lb W = 98 – 20.4 = 77.6 lb
Recycle
Gross product
Fresh Feed Process feed
Net product
Basis : S = 100 kg
f = 0.93
R
xs,R
xI,R
Xw,R
C P
F = 100 lb Separator
Sucrose 30% xs,C Reactor xs,R
H2O 70% xI,C = 0.05 xI,R
xw,C Xw,R
Solution
Basis: 100 lb = F
Overall balance: F = P = 100 lb
Balance at mixing point:
Total 100 + R = C (a)
Sucrose 100(0.3) + R(xs,R) = C(xs,C) (b)
Inversion 0 + R(xI,R) = C(0.05) (c)
In Out Consumed
Water Cxw,C - (R+100)xw,R - Cxs,C(0.9)(0.0526) (e)
Xs,R + xI,R + xw,R = 1 (f)
Xs,C + xI,C + xw,C = 1 (h)
Solve equations (a-h), we get R = 20.9 lb and xI,R = 0.313
Iso-
De-
pentane
butanizer X kg Y kg
tower
n-C5H12 100%
F = 100 kg
n-C5H12 80% To natural gasoline plant, P kg
i-C5H12 20% n-C5H12 = 90%
i-C5H12 = 10%
We get, x = 55.5 kg
F mol
67.3% H2 E mol
32.5% CO Reactor Separator 100% CH3OH
0.2% CH4
Chapter 3
Energy Balance
Introduction
System: 304 12 1 Chemi cal Engineering Principles
Closed system: lucose: 100(0.40) + 12 (
I00 = S + P
Open system: otal m ta er ila ba l ance: (100 / nerts
E y)
Property: Šr o perty:/a t er : 100(0.60) =
pen system:
Extensive Property: olve these equa t ions we get
utane fr e e ga s pas sed through
Intensive Property: olve these equt a ions we get
Šroperty:
State: Entroduction
Solution
s2 v2
F
W = - ò Ads = - ò pdV
s1
A v1
Path A:
W = -p(V2-V1) = - (200*103 Pa)(0.1 m3) = -20 kJ
Path B:
v2 v2
nRT V
W = - ò pdv = - ò dV = -nRT ln( 2 )
v1 v1
V V1
n = (200 kPa)(0.1 m3)/(300 K)(8.314 kPa m3) = 0.00802 kg mol
Heat
Part of total energy flow across a system boundary that
is caused by a temperature difference between the
system and the surrounding
Heat is positive when transferred to the system
Heat maybe transfer by conduction, convection, or
radiation
Q = UADT ; A is area for heat transfer, U is an empirical
.
coefficient, DT is the effective temperature difference
between the system and its surroundings, and is the
rate of heat transfer. Q&
0.001 m3/s
Solution
Basis: 0.001 m3/s of water
Assume that r = 1000 kg/m3
r = ½(3.00) = 1.50 cm
v = 0.001 m3 (100 cm)2
s p(1.50)2 cm2 (1 m)2
= 1.415 m/s
k = 1 (1.415)2 1 N 1J
2 (s/m)2 (1 kg m/s2) 1 Nm
= 1.0 J/kg
Solution
300 ft
40 ft
Let the water level in the first reservoir be the reference plane, then h = 40 ft
u = u (T , V )
æ ¶u ö æ ¶u ö ˆ
du = ç ÷ dT + ç ÷ dV
è ¶T øVˆ è ¶V ø T
ˆ
u 2 - u1 = ò C v dT
T1
Enthalpy (H)
H = U + pV where p is the pressure and V is
the volume.
æ ¶Hˆ ö æ ¶Hˆ ö
dHˆ = çç ÷ dT + ç
÷
÷
ç ¶P ÷ dP
Ĥ = enthalpy per unit mass
è ¶T ø p è øT
T2
Hˆ 2 - Hˆ 1 = ò C p dT
(neglect second term of above
T1 eq. and (¶Hˆ / ¶T ) is the heat
p
Calculation of Enthalpy
Changes
Phase transition enthalpy change latent heat
Enthalpy changes in a single phase: sensible heat
Enthalpy changes for the phase transition: heat of fusion
and heat of vaporization
Heat of condensation is the negative of the heat of
vaporization.
Solid changes directly to vapor: heat of sublimation
Enthalpy Computing
DH = ò C p dT
T1
Solution
The heat capacity equations are ( in Btu/lb mol F)
N2: Cp = 6.895 + 0.7624*10-3T – 0.7009*10-7T2
O2: Cp = 7.104 + 0.7851*10-3T – 0.5528*10-7T2
CO2: Cp = 8.448 + 5.757*10-3T – 21.59*10-7T2 + 3.059*10-10T3
CO: Cp = 6.865 + 0.8024*10-3T – 0.7367*10-7T2
Basis: 1 lb mol of gas
Multiplying these equations by the respective mole fraction of
each component and adding them together can save time in
integration.
200
DH = ò Cpnet dT
550
Example 3.6
Calculate the enthalpy change for 1 kg
mol of N2 gas that is heated at constant
pressure of 100 kPa from 18 to 1100 oC
Solution
For 1 kg mol of N2
DH = 34,715 – 524 = 34,191 kJ/kg mol
Example 3.7
Steam is cooled from 640 oF and 92 psia to
480 oF and 52 psia. What is DH in Btu/lb?
Solution
Use steam table and do the double interpolation first
between pressures at fixed temperature, and then
between temperatures at fixed pressures.
Steps:
1st: Get DH at P = 50, 55, 90, and 95 psia at each
temperatures of 600 and 700 oF.
2nd: Interpolate between P = 50 and 55 psia and temp 600
oF to get DH at P = 52 psia and T = 600 oF
2*(1328.7-1328.4)/5 = 0.12
So, at p = 92 psia and T = 600 oF , DH = 1328.7-0.12 = 1328.6
The enthalpy change is
DH = 1272.8 – 1348.4 = -75.6 Btu/lb
Example 3.8
Four kilograms of water at 27 oC and 200
kPa are heated at constant pressure until
the volume of the water becomes 1000
times the original value. What is the final
temperature of the water?
Solution
The initial specific volume is the saturated liquid water
volume at 300 K = 0.001004 m3/kg.
The final volume is = 0.001004*1000 = 1.004 m3/kg
At 200 kPa, using interpolation between 400 and 450 K
which covers the range of the specific volume of 1.004
m3/kg, we find T by solving;
(T2-T1)(DV)/(V2-V1) = DT
0.9024 + (1.025-0.9024)/(450-400)*(T-400) = 1.004 m3/kg
T = 400 + 41 = 441 K
U1 h2
h1
P1
Q=+ Q=-
Solution
Closed system without reaction
Use CO2 chart in Appendix J to get properties
Specific volume of CO2 is 4/10 = 0.4 ft3/lb, hence CO2 is a
gas at the start, pressure is 300 psia and Dh = 160 Btu/lb
Basis: 10 lb CO2
In the energy balance: DE = Q + W
W = 0 (volume of the system is fixed, DK =DP = 0), Q = DU
= Dh – D(pv)
Find Dhfinal from the CO2 chart by following the constant-
volume line of 0.4 ft3/lb to the spot where the quality is
0.6.
Dhfinal = 81 Btu/lb, pfinal = 140 psia
Q = (81-160)-{[(140)(144)(0.4)/778.2] –
[(300)(144)(0.4)/778.2]} = -67.2 Btu/lb (heat is removed)
Example 3.10
Argon gas in an insulated plasma deposition
chamber with a volume of 2 L is to be heated by
an electric resistance heater. Initially the gas,
which can be treated as an ideal gas, is at 1.5 Pa
and 300 K. The 1000-ohm heater draws current
at 40 V for 5 minutes (480 J of work is done by
the surrounding). What is the final gas
temperature and pressure at equilibrium? The
mass of the heater is 12 g and its heat capacity is
0.35 J/gK. Assume that the heat transfer to the
chamber from the gas at this low pressure and in
the short time period is negligible.
Solution
Closed system: DK=DP = 0
DE=Q + W = DU
Q = 0 so DE = W = DU
Basis: 5 minutes
Calculate mass of the gas: n = pV/RT
n = 1.5 Pa 2L 10-3 m3 1 gmol K
1L 8.314 Pa m3 300 K
= 1.203*10-6 gmol
Cv = Cp – R and since Cp = 5/2R, so Cv = 3/2R
DU = nCv(T-300)
480 J = (12g)(0.35 J/g K)(T-300) + (1.203*10-6) (3/2)(8.214)(T-
300)
T = 414.3 K
Final pressure is p2 = p1(T2/T1) = 1.5(414.3/300) = 2.07 Pa
Example 3.11
Air is being compressed from 100 kPa and 255 K
(where it has an enthalpy of 489 kJ/kg) to 1000
kPa and 278 K (where it has an enthalpy of 509
kJ/kg). The exit velocity of the air from the
compressor is 60 m/s. What is the power
required (in kW) for the compressor if the load is
100 kg/hr of air?
225 K 278 K
Dh = 489 kJ/kg Dh = 509 kJ/kg
v1 = 0 v1 = 60
100 kPa 1000 kPa
Solution
Basis: 100 kg of air = 1 hr
Simplify energy balance: DE = Q + W – D[(h+k+p)m]
The process is in steady state: DE = 0
m1=m2 = m
D(pm) = 0
Q = 0 by assumption
W = DH + DK
DH = (509-489)kJ/kg*100 kg = 2000 kJ
DK = 1/2m(v22-v12) = ½(100 kg)(602 m2/s2) = 180 kJ
W = 2180 kJ
Convert to power
kW = 2180 kJ/1 hr (=3600 sec) = 0.61 kW
Example 3.12
Water is being pumped from the bottom of a well 15 feet
deep at the rate of 200 gal/hr into a vented storage tank
to maintain a level of water in a tank 165 ft above the
ground. To prevent freezing in the winter a small heater
puts 30,000 Btu/hr into the water during its transfer
from the well to the storage tank. Heat is lost from the
whole system at the constant rate of 25,000 Btu/hr. What
is the temperature of the water as it enters the storage
tank, assuming that the well water is at 35 F? A 2-hp
pump is being used to pump the water. About 55% of
the rated horsepower goes into the work of pumping
and the rest is dissipated as heat to the atmosphere.
Solution
Open system with flow in and out
Material balance is 200 gal enter and 200 gal leave in an
hour
Energy balance is : DE = Q + W – D(h+k+p)m
Process is in the steady state, DE = 0
m2 = m1 = m
DK = 0 because will assume that v1 = v2 = 0, then 0 = Q + W
– D(h + p)m
At the top of the tank, DH = mDh = mCp(T2-35)
Total mass of water pumped is (200 gal/hr)(8.33 lb/1gal) =
1666 lb/hr
Potential energy change = (1666 lb/hr)(32.2
ft/s2)(180ft)/(32.2 ft lbm/s2 lbf)/(778 ft lbf) = 385.5 Btu
T
DHA = DH ofA + òC
Tref
dT
pA
s s T
DHmixture = åni DH of i + å ò nC
i pi dT
i =1 i =1 Tref
DH rxn = ( å
products
ni DH f i - å n DH
reac tan ts
i fi )
Example 3.13
Calculate DHrxno for the following reaction of 4 g mol of NH3
4NH3(g) + 5O2(g) 4NO(g) + 6H2O(g)
Example 3.14
If the standard heat of formation for H2O(l)
is -285.838 kJ/g mol and the heat of
evaporation is 44.012 kJ/g mol at 25 OC
and 1 atm, what is the standard heat of
formation of H2O(g)?
Solution
DHrxn=SDHf,product-SDHf,reactants
A: H2(g) + 1/2O2(g) H2O(l)
DHrxno=-285.838 kJ/g mol
B: H2O(l) H2O(g)
DHvap = 44.012 kJ/g mol
A+B: H2(g) + 1/2O2(g) H2O(l)
DHrxn + DHvap = DHrxn H2O(g) = DHfoH2O(g)
o o
Example 3.15
An iron pyrite containing 85% FeS2 and 15%
gangue (inert dirt, rock) is roasted with an
amount of air equal to 200% excess air according
to the reaction
4FeS2 + 11O2 2Fe2O3 + 8SO2
Solution
Basis: 100 kg of pyrite ore
MW of Fe(55.85), Fe2O3(159.7), FeS2(120)
Product:P
Mol%
SO2 x4
O2 x5
200% xs air N2 x6 Cinder:C
Wt%
Mol%
Gangue x1
N2 79
Fe2O3 x2
O2 21
FeS2 x3
Total 100
Total x1+x2+x3
Ore:F
Wt%
FeS2 85
Gangue 15
Comp 10-3 g mol DHfo (kJ/g niDH fi o(kJ) 10-3 g DHfo (kJ/g niDH fio
mol) mol mol) (kJ)
FeS2 0.0242 -177.9 -4.305 0.7083 -177.9 -126.007
Fe2O3 0.342 -822.156 -281.177 0 -822.156 0
N2 21.9983 0 0 21.983 0 0
O2 3.938 0 0 5.8437 0 0
SO2 1.368 -296.9 -406.159 0 -296.9 0
-691.641 -126.007
pVˆ = RT
Vˆ = specific volume of the gas (vol. per mole)
pVˆ = RT
p 1V 1 n RT
= 1 1
p 2V 2 n 2 RT 2
or
æ p1 öæ V1 ö æ n1 öæ T1 ö
ç ÷ç ÷ = ç ÷ç ÷
çp ÷çè V ÷ø çè n ÷øçè T ÷ø
è 2 ø 2 2 2
piVtotal n RT
= i total
or ptotalVtotal ntotal RTtotal
ni
p i = p total = p total y i
n total
yi is the mole fraction of component i
1
CO + O 2 ® CO 2
2
1
H 2 + O2 ® H 2 O
2
CH4 + 2O2 ®CO2 + 2H2O
The excess is
Excess O2 : 0.4(46.5) = 18.6 lb mol
Total O2 : 46.5 + 18.6 = 65.10 lb mol
ft 3 of gas
100 lbmol entering gas (359 ft 3 at S .C.)(550 o R)(29.92 in.Hg )
=
1 lbmol (492 o R)(35.0 in. Hg )
= 343 *102
ft 3 of air
310 lbmol air (359 ft 3 at S .C.)(530 o R)(29.92 in.Hg )
=
1 lbmol (492 o R)(29.4 in. Hg )
= 1220 *102
ft 3 of product
366.55 lbmol P (359 ft 3 at S .C.)(860 o R)(29.92 in.Hg )
=
1 lbmol (492 o R)(29.4 in. Hg )
= 2340 *102
Tr = T/Tc
Pr = P/Pc
Vˆ
V r
=
Vˆ c
Figure 3 (f)
Tc' = Tc + 8 K
Pc' = Pc + 8 atm
Vˆ
V ri =
Vˆci
Where Vci is the ideal critical volume (not the
experimental value of the critical volume), or
RT
V ci =
c
Pc
Basis: 1 lb of NH3
Apparently, your boss used the ideal gas law in
getting his figure of 1.2 ft3/lb of NH3 gas.
( psia)( ft 3 )
R = 10.73 P = 292 + 14.7 = 306.7 psia
(lbmol )( o R)
1lb
T = 125 oF + 460 = 585 oR n=
17lb / lbmol
1
(10 . 73 )( 585 )
RT 17
V =
ˆ = = 1 . 20 ft 3 / lb
P 306 . 7
Tc = 405.5 K = 729.9 R
Pc = 111.3 atm = 1636 psia
T 585 o R
Tr = = = 0 . 801 Pr =
P
=
306 . 7 psia
= 0 . 187
T c 729 . 9 o R Pc 1636 psia
Vˆ = 1 . 2 ( ft 3 / lb ) ideal ( 0 .855 )
= 1 .03 ft 3 / lbNH 3
Equation of State
Another way to predict p, V, n, and T for real gases
nRT n 2a
p = -
V - nb V 2
However, if you want to solve for V (or n), you can see
that the equation becomes cubic in V (or n):
æ nRT ö 2 n 2 a n 3 ab
f (V ) = V 3 - ç nb + ÷ V + V - =0
è p ø p p
( c m 3 )( a tm )
R = 8 2 .0 6
( g m o l )( K )
22.7 kg
n= = 0.516 kgmol propane
44 kg / kgmol
é ( 0 .5 1 6 ´ 1 0 3 ) 2 ( 9 .2 4 ´ 1 0 6 ) ù
ê 4 8 .3 + ú [ 0 .1 5 0 ´ 1 0
6
ë ( 0 .1 5 ´ 1 0 6 ) 2 û
- ( 0 .5 1 6 ´ 1 0 3 ) ( 9 0 .7 ) ] = ( 0 .5 1 6 ´ 1 0 3 ) (8 2 .0 6 ) ( T K )
T = 384 K
æ pnb + nRT ö 2 n 2 a n 3 ab
f (V ) = V 3 - ç ÷V + V- =0
è p ø p p
(679.7)(1.137)(1.45) + (1.137)(10.73)(683)
f (Vo ) = (12.26)3 - (12.26)2
679.7
(1.137)2 (3.49 ´104 ) (1.137)3 (3.49 ´104 )(1.45)
+ (12.26) - = 738.3
679.7 679.7
2[(679.7)(1.137)(1.45) + (1.137)(10.73)(683)]
f '(Vo ) = 3(12.26)2 - (12.26)
679.7
(1.137)2 (3.49 ´104 )
+ = 216.7
679.7
The final solution is 5.0 ft3 at 679.7 psia and 683 oR.
Gaseous Mixtures
Methane 20
Ethylene 30
Nitrogen 50
R = 82.06 (cm3-atm)/(gmol-K)
P 90
Pr' = = = 2.18
Pc' 41.2
T 373
Tr' = '
= = 2.01
Tc 186
znRT 0.965(1)(82.06)(373)
Vˆ = =
P 90
= 328 cm 3 at 90 atm and 373 K
Target
Vacuum
chamber
To pump
electrode electrode
Solution
We have to calculate P* for Al at 972 oC. The Antoine
equation is suitable if data are known for the vapor
pressure of Al. Considerable variation exists in the
data for Al at high temperature, but we will use A =
8.779, B = 1.615*104, and C = 0 with P* in mm Hg
and T in K.
1.615*104
*
ln P972 = 8.799 -
972 + 273
o
C
-4
= 1 .3 * 1 0 g /(c m 2
)( s )
Saturation
Saturate : method, ew first calculate the .779, B = 1.615*10
E 1996).•n volume containing .2 7 kg of
Saturated Air : RaaodDr o
PairV nairRT
=
PH2OV nH2O RT
Solution
Assuming that the process is isothermal
20 oC 100 kPa
100 kPa Saturated
Air air-alcohol
mixture
Alcohol
6 kg
*
Palcohol n
= alcohol
Pair nair
Solution
Methane contains 2 kg mol of H2 per kgmol of C,
while coal contains 71 kg of C per 5.6 kg of H2 in
100 kg o coal. The coal analysis is equivalent to
1 kgmol C
71 kg C ´ = 5.92 kgmol C
12 kg C
1 kgmol H 2
5.6 kg H 2 ´ = 2.78 kgmol H 2
12 kg H 2
O2 0.21
N2 0.79
1.00
Basis : 1 kg mol C
Natural Gas
CH 4 + 2O2 ® CO2 + 2 H 2 O
C 1.0 1.0
H2 2.0 2.0
Air 0.8 10.5
Total 1.0 2.0 0.80 10.5
C 1.0 1.0
H2 0.47 0.47
Air 0.49 6.5
Total 1.0 0.47 0.49 6.5
Req. O2: 1+0.47(1/2) = 1.24 Excess O2: (1.24)(0.4) = 0.49
N2: 1.40(79/21)[1+0.47(1/2)] = 6.5
Pi = Pi * xi
FxFi xFi
yi = =
L L 1
+ (F - L) 1- (1- )
Ki F Ki
where L/F is the fraction of liquid formed on
vaporization. Consequently, since ∑yi = 1 , after
summing the yi’s we want to solve the following
equation:
n
x Fi
1= å L 1
i =1
1- (1 - )
F Ki
Solution
A B C
n-hexane (C6) 15.8737 2697.55 -48.784
n-octane (C8) 15.9798 3127.60 -63.633
æ 2697 . 55 ö æ 3127 . 60 ö
760 = exp ç 15 . 8737 - ÷ 0 . 040 + exp ç 15 .9787 - ÷ 0 . 960
è - 48 .784 + T ø è - 63 . 633 + T ø
PC*6 3114
yC6 = xC6 = (0.040) = 0.164
Ptot 760
Stage L/F
1 1.0
2 0.8565
3 0.6567
4 0.5102
5 0.4573
6 0.4511
F=C–P+2
pVˆ = RT
Solution F=C–P+2
a) C = 1, P = 1, hence F = 1 – 1 + 2 = 2. The
temperature and pressure might be specified in the
range in which benzene remains a liquid.
b) C = 1, P = 2, hence F = 1 – 2 + 2 = 1. Once either
the temperature or the pressure is specified, the
other intensive variables are fixed.
c) C = 2, P = 2, hence F = 2 – 2 + 2 = 2. A pair from
temperature, pressure, or mole fraction can be
specified.
d) C = 2, P = 2, hence F = 2 – 2 + 2 = 2. Since a
particular pressure is to be achieved, you would
adjust the salt concentration and temperature of
the solution.
When the vapor is water vapor and the gas is air, the
special term humidity applies. For other gases or
vapors, the term saturation is used.
Pl Pl / Pt Vl / Vt nt massi
RS = = = = =
Pl* Pl* / Pt Vsatd / Vt nsat d masssatd
PH 2 O
(100 ) = % R H = 60 %
PH* 2 O
PH 2 O
100 = 100% or PH 2 O = PH* 2 O
PH* 2 O
nvapor
= molal saturation
n vapor - free gas
æ P1 ö
çç ÷÷
è total
P - P1 ø P1 æ Ptotal - P1* ö
% AS = 100 = * çç ÷100
æ P1* ö P1 è Ptotal - P1 ÷ø
çç * ÷
÷
è total
P - P1 ø
æP - P1* ö
% AS = ( relative saturation ) çç total ÷÷100
è Ptotal - P1 ø
Solution
Data from the steam tables are
P*H2O at 86 oF = 1.253 in Hg = 31.8 mm Hg = 4.242 kPa
c) PH2O = 6.58 mm Hg
a) %RH = 100(6.58/31.8) = 20.7%
b) H = [(MWH2O)(nH2O)]/[(MWair)(nair)]