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1) Question code & Id : EM0458576 (458576) (Single Choice) (Chemistry / Amines and
Diazonium salts) (4) (50) (Analysis)
Question Info

Benzene diazonium chloride on reaction with aniline in the presence of dilute hydrochloric acid gives:
Answers

Answer
# Answer Unit Answer Explanation Correct
1 In case on mild acidic medium (5-7 pH) Correct
coupling reaction takes place

2 Wrong

3 Wrong

4 Wrong

Concepts

Concept
# ID Code Name
1 16240 KTNG13 Coupling reaction of amines

2) Question code & Id : EM0458577 (458577) (Single Choice) (Chemistry / Solutions and
Colligative Properties) (4) (60) (Application)
Question Info

A solution is prepared by dissolving 0.6 g of urea (molar mass = 60 g mol−1 ) and 1.8 g of glucose (molar
mass = 180 g mol−1 ) in 100 mL of water at 27o C. The osmotic pressure of the solution is:
( R = 0.08206 L atm K−1  mol−1 )
Answers

Answer
# Answer Unit Answer Explanation Correct
1 8.2 atm Wrong
2 2.46 atm Wrong

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17/05/2019 Answer Embibe
# Answer Unit Answer Explanation Correct
3 4.92 atm i factor of glucose and urea are 1 : 1 Correct
respectively.
w
Moles of glucose = Mw = 180 1.8
t
= 10
−2

Moles of urea = 0.6

60
= 10
−2

Total mole of solute

−2 −2 −2
= 10 + 10 = 2 × 10
−2

Concentration of solution = 2×10

−3
= 0.2
100×10

Osmotic pressure (π) = CRT

= 0.2 × 0.0821 × 300 = 4.926 atm

4 1.64 atm Wrong

Concepts

Concept
# ID Code Name
1 7829 KTSL07 Osmosis and Osmotic pressure
2 7847 KTSL12 Van't Hoff's factor (i) = Observed colligative property calculated colligative
property

3) Question code & Id : EM0458578 (458578) (Single Choice) (Chemistry / s Block elements
(Alkali and Alkaline earth Metals) and Hydrogen) (3) (50) (Analysis)
Question Info

The temporary hardness of a water sample is due to compound X. Boiling this sample convertrs X to
compound Y. X and Y, respectively, are:

Answers

Answer
# Answer Unit Answer Explanation Correct
1 Mg(HCO3 )2 and MgCO3 Wrong

2 Ca(HCO3 )
2
and Ca(OH)2 Wrong

3 Mg(HCO3 )
2
and Mg(OH)2 Both Mg(HCO3 )2 and Ca(HCO3 )2 are Correct
responsible for temporary hardness.
Boiling ⏐ ↑
Mg(HCO3 ) −−− → 2MgCO3 ⏐ +CO2 ⏐ +H O
2 ⏐ ⏐ 2

(X)
⏐ ⏐
↓ ⏐
−2 − −
CO + H2 O → HCO + OH
3 3
+2 −
Mg + 2OH → Mg(OH)
2

(Y)

4 Ca(HCO3 )
2
and CaO Wrong

Concepts

Concept
# ID Code Name
1 7423 KTML17 Hardness of water expressed as calcium carbonate content (ppm).
2 9055 KTSB07 Hard & Soft Water

4) Question code & Id : EM0458579 (458579) (Single Choice) (Chemistry / d and f Block
elements) (3) (60) (Analysis)
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 Question Info
17/05/2019 Embibe

The pair that has similar atomic radii is:

Answers

Answer
# Answer Unit Answer Explanation Correct
1 Mo and W Among the given pairs Mo and W have Correct
the same atomic radius of 139 pm and
this is due to Lanthanoid contraction.
This happens due to the poor screening
ability of 4f electrons. The radius of other
pairs are:
Sc (162 pm) and Ni (124 pm)

Mo (139 pm) and W (139 pm)

Mn (140 pm)and Re (135 pm)

Ti(170 pm) and Hf  (159 pm).

2 Sc and Ni Wrong
3 Mn and Re Wrong
4 Ti and Hf Wrong
Concepts

Concept
# ID Code Name
1 8816 KTPP03 Atomic radius trends

5) Question code & Id : EM0458580 (458580) (Single Choice) (Chemistry / Alkanes, Alkenes and
Alkynes (Hydrocarbons)) (5) (75) (Analysis)
Question Info

Consider the following reactions:

‘A’ is:
Answers

Answer
# Answer Unit Answer Explanation Correct
1 CH2 = CH2 Wrong
2 CH ≡ CH Wrong
3 CH3 − C ≡ C − CH3 Wrong
4 CH3 − C ≡ CH A reacts with Ag2 O , so it should have Correct
acidic hydrogen. This implies that the
compound will be terminal alkyne.

Concepts

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17/05/2019 Concept Embibe
# ID Code Name
1 12685 KTAA98 Oxymercuration - Demercuration mechanism: Alkynes
2 12940 KTIS74 Concept of Tautomerism

3 13211 KTAAK21 Reduction Reactions of aldehydes and ketones

4 13163 KTAAE30 Lucas Test

6) Question code & Id : EM0458581 (458581) (Single Choice) (Chemistry / Chemical Kinetics) (3)
(60) (Application)
Question Info

NO2 required for a reaction is produced by the decomposition of N2 O5 in CCl4 as per the equation,
2N2 O5 (g)→ 4NO2 (g)+O2 (g).

The initial concentration of N2 O5 is 3.00 mol L−1 and it is 2.75 mol L−1 after 30 minutes. The rate of
formation of NO2 is:

Answers

Answer
# Answer Unit Answer Explanation Correc
1 1.667 × 10−2 mol L
−1
min
−1
Rate of reaction in terms of rate of disappearance of Correct
N2 O5 (s)
d [ N2 O 5 ] 1 d [ NO2 ] 2d [ O2 ]
− = = = rate of  Reaction
dt 2 dt dt
(−2+1.75)
− = rate of  reaction
30
0.25 −3 −1 −1
−(− )= 8.3 × 10 Mol L min
30

=
25

3000
= 8.3 × 10
−3
=
1

2
× rate of formation of O2
d [ NO2 ]
−3 1
8.3 × 10 =
2 dt
d[NO2 ]
−3
1.66 × 10 m/min  =
dt

2 8.333 × 10
−3
mol L
−1
min
−1
Wrong
3 4.167 × 10
−3
mol L
−1
min
−1
Wrong
4 2.083 × 10
−3
mol L
−1
min
−1
Wrong
Concepts

Concept
# ID Code Name
1 6914 KTCK17 Rate law expression
2 6904 KTCK03 Average and Instantaneous Reaction Rate

7) Question code & Id : EM0458582 (458582) (Single Choice) (Chemistry / General Principles
and Processes of Isolation of Metals (Metallurgy)) (4) (75) (Comprehension)
Question Info

The correct statement is:

Answers

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17/05/2019 Answer Embibe
# Answer Unit Answer Explanation Correct
1 Pig iron is obtained from cast iron. The Wrong
Hall-Heroult process is used for
2 the production of aluminium and iron. Wrong
3 leaching of bauxite using (1) During leaching when bauxite is Correct
concentrated NaOH solution gives treated with concentrated NaOH, then
sodium aluminate and sodium silicate. sodium aluminate and sodium silicate is
formed in the soluble form, whereas
Fe2 O3 is precipitated
(2) The blistered appearance of copper
during the metallurgical process is due
to evolution of SO2 .
(3) Cast iron is obtained from pig iron.
(4) Hall-Heroult process is used for
production of only aluminium.
4 the blistered appearance of copper Wrong
during the metallurgical process is due
to the evolution of CO2 .
Concepts

Concept
# ID Code Name
1 16924 KTMG38 Extraction of Iron
2 8728 KTMG04 Concentration of ores: Leaching
3 8789 KTDF31 Properties of Iron and corrosion of iron
4 8796 KTDF34 Properties of copper

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