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Simulation: -model-12

• Cooling 100 lbmol of Methanol from 150°F to 100°F using 1000 lbmol of Water at 50°F in a heat exchanger.
• Draw the simulation and review results

1
3
methanol
1

2
water

FLOWSHEET SUMMARY
ID Type Label Stream Numbers
1 HTXR 2 3 -1 -4
Stream Connections
Stream Equipment
From To
1 1
2 1
3 1
4 1
Calculation mode : Sequential
Flash algorithm : Normal
Equipment Calculation Sequence
1
No recycle loops in the flowsheet.
Overall Mass Balance lbmol/h lb/h
Input Output Input Output
Methanol 100.000 100.000 3204.200 3204.200
Water 1000.000 1000.000 18015.000 18015.000
Total 1100.000 1100.000 21219.199 21219.199
Overall Energy Balance MMBtu/h
Input Output
Feed Streams -131.923
Product Streams -131.923
Total Heating 0
Total Cooling 0
Power Added 0
Power Generated 0
Total -131.923 -131.923
COMPONENTS
ID # Name Formula
1 117 Methanol CH4O
2 62 Water H2O
THERMODYNAMICS
K-value model : NRTL
No correction for vapor fugacity
Enthalpy model : Latent Heat
Liquid density : Library

CHEMCAD 7.1.2 Page 1 of 3 31/03/2019 2:44 PM


Simulation: -model-12

Std vapor rate reference temperature is 60 F.


Atmospheric pressure is 14.6959 psi.
NRTL Parameters: Tij = Aij + Bij/T + Cij * Ln(T) + Dij * T (T Deg K)

I J Bij Bji Alpha Aij Aji Cij Cji Dij Dji


1 2 -24.49 307.17 0.300 0.00 0.00 0.00 0.00 0.00 0.00
EQUIPMENT SUMMARIES
Heat Exchanger Summary
Equip. No. 1
Name
2nd Stream T Out F 100.0000
Calc Ht Duty MMBtu/h 1.6184
LMTD (End points) F 24.9309
LMTD Corr Factor 1.0000
1st Stream Pout psia 14.7000
2nd Stream Pout psia 14.7000
P1 out specifed psia 14.7000
P2 out specifed psia 14.7000
STREAM PROPERTIES
Stream No. 1 2 3 4
Name water methanol
- - Overall - -
Molar flow lbmol/h 1000.0000 1000.0000 100.0000 100.0000
Mass flow lb/h 18015.0000 18015.0000 3204.2000 3204.2000
Temp F 139.9159 50.0000 150.0000 100.0000
Pres psia 14.7000 14.7000 14.7000 14.7000
Vapor mole fraction 0.0000 0.0000 1.000 0.0000
Enth MMBtu/h -121.70 -123.31 -8.6094 -10.228
Tc F 705.5600 705.5600 463.0820 463.0820
Pc psia 3207.9768 3207.9768 1174.3701 1174.3701
Std. sp gr. wtr = 1 1.000 1.000 0.801 0.801
Std. sp gr. air = 1 0.622 0.622 1.106 1.106
Degree API 10.0000 10.0000 45.2429 45.2429
Average mol wt 18.0150 18.0150 32.0420 32.0420
Actual dens lb/ft3 61.3642 62.3884 0.0733 48.5153
Actual vol ft3/hr 293.5751 288.7556 43716.2617 66.0452
Std liq ft3/hr 288.5730 288.5730 64.1101 64.1101
Std vap 60F scfh 379478.6250 379478.6250 37947.8633 37947.8633
- - Vapor only - -
Molar flow lbmol/h 100.0000
Mass flow lb/h 3204.2000
Average mol wt 32.0420
Actual dens lb/ft3 0.0733
Actual vol ft3/hr 43716.2617
Std liq ft3/hr 64.1101
Std vap 60F scfh 37947.8633
Cp Btu/lbmol-F 11.1975
Z factor 0.9823
Visc cP 0.01105
Th cond Btu/hr-ft-F 0.0112
- - Liquid only - -
Molar flow lbmol/h 1000.0000 1000.0000 100.0000
Mass flow lb/h 18015.0000 18015.0000 3204.2000
Average mol wt 18.0150 18.0150 32.0420
Actual dens lb/ft3 61.3642 62.3884 48.5153
Actual vol ft3/hr 293.5751 288.7556 66.0452
Std liq ft3/hr 288.5730 288.5730 64.1101
Std vap 60F scfh 379478.6250 379478.6250 37947.8633

CHEMCAD 7.1.2 Page 2 of 3 31/03/2019 2:44 PM


Simulation: -model-12

Cp Btu/lbmol-F 17.9844 18.0938 20.0156


Z factor 0.0009 0.0010 0.0021
Visc cP 0.4784 1.318 0.4585
Th cond Btu/hr-ft-F 0.3740 0.3373 0.1134
Surf. tens. dyne/cm 65.9723 74.6858 21.1853
FLOW SUMMARIES:
Stream No. 1 2 3 4
Stream Name water methanol
Temp F 139.9159 50.0000 150.0000 100.0000
Pres psia 14.7000 14.7000 14.7000 14.7000
Enth MMBtu/h -121.70 -123.31 -8.6094 -10.228
Vapor mass frac. 0.00000 0.00000 1.0000 0.00000
Total lbmol/h 1000.0000 1000.0000 100.0000 100.0000
Total lb/h 18015.0000 18015.0000 3204.2000 3204.2000
Total std L ft3/hr 288.5730 288.5730 64.1101 64.1101
Total std V scfh 379478.63 379478.63 37947.86 37947.86
Flow rates in lb/h
Methanol 0.0000 0.0000 3204.2000 3204.2000
Water 18015.0000 18015.0000 0.0000 0.0000
Heating Curves Summary
Eqp # 1 Unit type : HTXR Unit name:
Stream 2
NP Temp Pres Del H Vapor Liquid Vap mole Vap mass
F psia MMBtu/h lb/h lb/h frac. frac.
1 50.0 14.7 0.000 0 18015 0.0000 0.0000
2 55.5 14.7 0.0999 0 18015 0.0000 0.0000
3 61.2 14.7 0.202 0 18015 0.0000 0.0000
4 72.4 14.7 0.405 0 18015 0.0000 0.0000
5 83.7 14.7 0.607 0 18015 0.0000 0.0000
6 94.9 14.7 0.809 0 18015 0.0000 0.0000
7 106.2 14.7 1.01 0 18015 0.0000 0.0000
8 117.4 14.7 1.21 0 18015 0.0000 0.0000
9 128.7 14.7 1.42 0 18015 0.0000 0.0000
10 139.8 14.7 1.62 0 18015 0.0000 0.0000
11 139.9 14.7 1.62 0 18015 0.0000 0.0000
Stream 3
NP Temp Pres Del H Vapor Liquid Vap mole Vap mass
F psia MMBtu/h lb/h lb/h frac. frac.
1 100.0 14.7 0.000 0 3204 0.0000 0.0000
2 148.1 14.7 0.0999 0 3204 0.0000 0.0000 Bub
3 148.1 14.7 0.202 216 2988 0.0675 0.0675
4 148.1 14.7 0.405 644 2560 0.2009 0.2009
5 148.1 14.7 0.607 1071 2133 0.3343 0.3343
6 148.1 14.7 0.809 1499 1705 0.4678 0.4678
7 148.1 14.7 1.01 1926 1278 0.6012 0.6012
8 148.1 14.7 1.21 2354 850 0.7346 0.7346
9 148.1 14.7 1.42 2781 423 0.8680 0.8680
10 148.1 14.7 1.62 3204 0 1.0000 1.0000 Dew
11 150.0 14.7 1.62 3204 0 1.0000 1.0000

CHEMCAD 7.1.2 Page 3 of 3 31/03/2019 2:44 PM

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