Exercise

STOICHIOMETRY - 1 Page # 21
Class Room Problems

Problem.1 From the following reaction sequence Problem.3 A polystyrene, having formula Br3C6H3
(C 8H8 )n was prepared by heating styrene with
Cl2 + 2KOH → KCl + KClO + H2O
tribromobenzoyl peroxide in the absence of air. If it
3KClO → 2KCl + KClO3 was found to contain 10.46% bromine be weight, find
4KClO3 → 3KClO4 + KCl the value of n.
Calculate the mass of chlorine needed to produce Sol.
100 g of KClO4.
Sol.
Problem.4 5 mL of a gaseous hydrocarbon was

exposed to 30 mL of O2. The resultant gas, on cooling
is found to measure 25 mL of which 10 mL are absorbed
by NaOH and the remainder by pyrogallol. Determine
molecular formula of hydrocarbon. All measurements
Problem.2 Calculate the weight of FeO produced from are made at constant pressure and temperature.
2 g VO and 5.75 g of Fe2O3. Also report the limiting
Sol.
reagent. VO + Fe2O3 → FeO + V2O5
Sol.
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Page # 22 STOICHIOMETRY - 1
Problem.5 A gaseous alkane is exploded with oxygen. Problem.7 16 mL of a gaseous aliphatic compound
The volume of O2 for complete combustion to CO2 CnH3nOm was mixed with 60 mL O2 and sparked. The
formed is in the ratio of 7 : 4. Deduce molecular gas mixture on cooling occupied 44 mL. After treatment
formula of alkane. with KOH solution, the volume of gas remaining was
Sol. 12 mL. Deduce the formul a of compound. All
measurements are made at constant pressure and
room temperature.
Sol.
Problem.6 A sample of gaseous hydrocarbon

occupying 1.12 litre at NTP, when completely burnt in
air produced 2.2 g CO2 and 1.8 g H2O. Calculate the
weight of hydrocarbon taken and the volume of O2 at
NTP required for its combustion. Problem.8 In what ratio should you mix 0.2M NaNO3
Sol. and 0.1M Ca(MO3)2 solution so that in resulting
solution, the concentration of –ve ion is 50% greater
than the concentration of +ve ion ?
Sol.
Problem.9 How much BaCl2 would be needed to make Problem.11 A sample of H2SO4 (density 1.787 g mL–1) is
250 mL of a solution having same concentration of labelled as 86% by weight. What is molarity of acid ?
Cl– as the one containing 3.78 g of NaCl per 100 mL ? What volume of acid has to be used to make 1 litre of
Sol. 0.2 M H2SO4 ?
Sol.
Problem.10 What is the purity of conc. H2SO 4

solution (specific gravity 1.8 g/mL), if 5.0 mL of this Problem.12 Mole fraction of I2 in C6H6 is 0.2.
solution is neutralized by 84.6 mL of 2.0 N NaOH ? Calculate molality of I2 in C6H6.
Sol. Sol.
Problem.13 A drop (0.05 mL) of 12 M HCl is spread Problem.15 A mixture of Al and Zn weighing 1.67 g
over a thin sheet of aluminium foil (thickness 0.10 mm was completley dissolved in acid and evolved 1.69
and density of Al = 2.70 g/mL). Assuming whole of litre of H2 at NTP. What was the weight of Al in original
the HCl is used to dissolve Al, what will be the maximum mixture ?
area of hole produced in foil ? Sol.
Sol.
Problem.14 What would be the molarity of solution Problem.16 A mixture of FeO and Fe3O4 when heated
obtained by mixing equal volumes of 30% by weight in air to constant weight, gains 5% in its weight. Find
H2SO4 (d = 1.218 g mL–1) and 70% by weight H2SO4 out composition of mixture.
(d = 1.610g mL–1) ? If the resulting solution has density
Sol.
1.425 g/mL, calculate its molality.
Sol.
Problem.17 25.4 g of I2 and 14.2 g of Cl2 are made

to react completely to yield a mixture of ICl and ICl3.
Calculate mole of ICl and ICl3 formed.
Sol.
Problem.19 For the reaction, N2O5(g) 2NO2(g)

+ 0.5O2(g), calculate the mole fraction of N2O5(g)
decomposed at a constant volume and temperature,
if the initial pressure is 600 mm Hg and the pressure
at any time is 960 mm Hg. Assume ideal gas behaviour.
Sol.
Problem.18 A mixture of HCOOH and H2C2O4 is

heated with conc. H 2SO 4. The gas produced is
collected and on treating with KOH solution the volume
1
of the gas decreases by th. Calculate molar ratio
6
of two acids in original mixture.
Sol.
Problem.20 0.22 g sample of volatile compound,

containing C, H and Cl only on combustion in O2 gave
0.195 g CO2 and 0.0804 g H2O. If 0.120 g of the
compound occupied a volume of 37.24 mL at 105º
and 768 mm of pressure, calculate molecular formula
of compound.
Sol.
Problem.22 10 mL of a solution of KCl containing
NaCl gave on evaporation 0.93 g of the mixed salt
which gave 1.865 g of AgCl by the reaction with
AgNO3. Calculate the quantity of NaCl in 10 mL of
solution.
Sol.
Problem.21 2.0 g sample containing Na2CO3 and Problem.23 A sample of CaCO3 and MgCO3 weighed
NaHCO3 loses 0.248 g when heated to 300ºC, the 2.21 g is ignited to constant weight of 1.152 g. What
temperature at which NaHCO3 decomposes to Na2CO3, is the composition of mixture ? Also calculale the
and H2O. What is % of Na2CO3 in mixture ? volume of CO2 evolved at 0ºC and 76 cm of pressure.
Sol. Sol.
Problem.24 2.0 g of a mixture of carbonate,

bicarbonate and chloride of sodium on heating
produced 56 mL of CO2 at NTP. 1.6 g of the same
mixture required 25 mL of N HCl solution for
neutral i zat i on. Cal cul ate percent age of each
component present in mixture.
Sol.
Problem.26 A solid mixture 5 g consits of lead nitrate

and sodium nitrate was heated below 600ºC until
weight of residue was constant. If the loss in weight
is 28%, find the amount of lead nitrate and sodium
nitrate in mixture.
Sol.
Problem.25 Igni ting MnO 2 i n ai r converts i t

quantitatively to Mn3O4. A sample of pyrolusite has
MnO2 80%, SiO2 15% and rest having water. The
sample is heated in air to constant mass. What is
the % of Mn in ignited sample ?
Sol.
Problem.27 Determine the formula of ammonia form

the folloiwng data :
(i) Volume of ammonia = 25 mL.
(ii) Volume on addition of O2 after explosion = 71.2 mL.
(iii) Volume after explosion and reaction with O2 on
cooling = 14.95 mL.
(i v) Vol ume after bei ng absorbed by al kali ne
pyrogallol = 12.5 mL.
Sol. Sol.
Problem.30 A mixture in which the mole ratio of H2

and O2 is 2 : 1 is used to prepare water by the
Problem.28 A mixture of ethane (C2H6) and ethene
reaction,
(C2H4) occupies 40 litre at 1.00 atm and at 400 K.
The mixture reacts completely with 130 g of O2 to 2H2(g) + O2(g) → 2H2O(g)
produce CO2 and H2O. Assuming ideal gas behaviour, The total pressure in the container is 0.8 atm at
calculate the mole fractions of C2H4 and C2H6 in the 20ºC before the reaction. Determine the final pressure
mixture. at 120ºC after reaction assuming 80% yield of water.
Sol.
Problem. 29 0.50 g of a mixture of K2CO3 and Li2CO3

required 30 mL of 0.25 N HCl solution for neturalization.
What is % composition of mixture ?
Exercise - I Objective Type
Sol.
Fill in the blank :
1. For the reaction
2x + 3y + 4z → 5w
Initially if 1 mole of x, 3 mole of y and 4 mole of z is
taken. If 1.25 mole of w is obtained then % yield of
this reaction is __________________.
Sol.
4. Ratio of masses of H2SO4 and Al2 (SO4)3 is grams

each containing 32 grams of S is __________.
Sol.
2. A solution of A (MM = 20) and B (MM = 10), [Mole

fraction XB = 0.6] having density 0.7 gm/ml then molarity
and m ol al i t y of B i n thi s s ol ut i on wi l l b e
________________ and ______________ respectively.
Sol.
5. The vapour density of a mixture of gas A (Molecular

mass = 40) and gas B (Molecular mass = 80) is 25.
Then mole % of gas B in the mixture would be
_________
Sol.
3. 125 ml of 8% w/w NaOH solution (sp. gravity 1) is

added to 125 ml of 10% w/v HCl solution. The nature
of resultant solution would be _________
6. For the reaction

2A + 3B + 5C → 3D
Initially if 2 mole of A, 4 mole of B and 6 mole of C is
taken, With 25% yield, moles of D which can be
produced are _____________.
Sol.
Single Correct :
8. Equal volumes of 10% (v/v) of HCl is mixed with

10% (v/v) NaOH solution. If density of pure NaOH is
1.5 times that of pure HCl then the resultant solution
be :
(A) basic (B) neutral
(C) acidic (D) can’t be predicted.
Sol.
7. Fill in the blanks in the following table.

Compound Grams Grams Molality Mole Fraction
Compd Water of Compd of Compd

Na2CO3 ______ 250 0.0125 ________
CH3OH 13.5 150 _____ ________
KNO3 ______ 555 ______ 0.0934 9. A definite amount of gaseous hydrocarbon was burnt
Sol. with just sufficient amount of O2. The volume of all
reactants was 600 ml, after the explosion the volume
of the products [CO2(g) and H2O(g)] was found to be
700 ml under the similar conditions. The molecular
formula of the compound is :
(A) C3H8 (B) C3H6 (C) C3H4 (D) C4H10
Sol.
10. One gram of the silver salt of an organic dibasic Sol.

acid yields, on strong heating, 0.5934 g of silver. If
the weight percentage of carbon in it 8 times the
weight percentage of hydrogen and half the weight
percentage of oxygen, determine the molecular formula
of the acid. [Atomic weight of Ag = 108]
(A) C4H6O4 (B) C4H6O6 (C) C2H6O2 (D) C5H10O5
Sol.
12. C6H5OH(g) + O2(g) → CO2(g) + H2O(l)

Magnitude of volume change if 30 ml of C6H5OH (g) is
burnt with excess amount of oxygen, is
(A) 30 ml (B) 60 ml (C) 20 ml (D) 10 ml
Sol.
11. One mole mixture of CH4 & air (containing 80% N2
20% O2 by volume) of a composition such that when
underwent combustion gave maximum heat (assume
combustion of only CH4). Then which of the statements
are correct, regarding composition of initial mixture.
(X presents mole fraction)
1 2 8
(A) X CH4 = , X O2 = , X N2 =
11 11 11
3 1 1
(B) X CH4 = , X O 2 = , XN2 =
8 8 2
1 1 2
(C) X CH4 = , X O 2 = , XN2 =
6 6 3
(D) Data insufficient
13. 10 ml of a compound containing ‘N’ and ‘O’ is

mixed with 30 ml of H2 to produce H2O (l) and 10 ml of
N2(g). Molecular formula of compound if both reactants
reacts completely, is
(A) N2O (B) NO2 (C) N2O3 (D) N2O5
Sol.
15. Mass of sucrose C12H22O11 produced by mixing 84

gm of carbon, 12 gm of hydrogen and 56 lit. O2 at 1
atm & 273 K according to given reaction, is
C(s) + H2(g) + O2(g) → C12H22O11(s)
(A) 138.5 (B) 155.5 (C) 172.5 (D) 199.5
Sol.
14. Similar to the % labelling of oleum, a mixture of

H3PO4 and P4O10 is labelled as (100 + x) % where x is
the maximum mass of water which can react with
P4O10 present in 100 gm mixture of H3PO4 and P4O10. If
such a mixture is labelled as 127% Mass of P4O10 is
100 gm of mixture, is
(A) 71 gm(B) 47 gm (C) 83gm (D) 35 gm
Sol.
Sol.
16. If 50 gm oleum sample rated as 118% is mixed
with 18 gm water, then the correct option is
(A) The resulting solution contains 18 gm of water
and 118 gm H2SO4
(B) The resulting solution contains 9 gm of water and
59 gm H2SO4
(C) The resulting solution contains only 118 gm pure
H2SO4
(D) The resulting solution contains 68 gm of pure H2SO4
Sol.
18. 40 gm of a carbonate of an alkali metal or alkaline

earth metal containing some inert impurities was
made to react with excess HCl solution. The liberated
CO2 occupied 12.315 lit. at 1 atm & 300 K. The correct
option is
(A) Mass of impurity is 1 gm and metal is Be
(B) Mass of impurity is 3 gm and metal is Li
(C) Mass of impurity is 5 gm and metal is Be
(D) Mass of impurity is 2 gm and metal is Mg
Sol.
17. In the quantitative determination of nitrogen using

Duma’s method, N2 gas liberated from 0.42 gm of a
sample of organic compound was collected over water.
100
If the volume of N2 gas collected was ml at total
11
pressure 860 mm Hg at 250 K, % by mass of nitrogen
in the organic compound is
[Aq. tension at 250K is 24 mm Hg and R = 0.08 L atm
mol–1 K–1]
10 5 20 100
(A) % (B) % (C) % (D) %
3 3 3 3
Sol.
19. The percentage by mole of NO2 in a mixture NO2(g)

and NO(g) having average molecular mass 34 is :
(A) 25% (B) 20% (C) 40% (D) 75%
Sol.
21. The mass of CO2 produced from 620 gm mixture of

C2H4O2 & O2, prepared to produce maximum energy is
(A) 413.33 gm (B) 593.04 gm (C) 440 gm (D) 320 gm
Sol.
20. The minimum mass of mixture of A2 and B4 required

to produce at least 1 kg of each product is :
(Given At. mass of ‘A’ = 10; At mass of ‘B’ = 120)
5A2 + 2B4 → 2AB2 + 4A2B
(A) 2120 gm (B) 1060 gm (C) 560 gm (D) 1660 gm
22. Assuming complete precipitation of AgCl, calculate

the sum of the molar concentration of all the ions if 2
lit of 2M Ag2SO4 is mixed with 4 lit of 1 M NaCl solution
is :
(A) 4M (B) 2M (C) 3M (D) 2.5 M
Sol.
24. 74 gm of sample on complete combustion gives

132 gm CO2 and 54 gm of H2O. The molecular formula
of the compound may be
(A) C5H12 (B) C4H10O (C) C3H6O2 (D) C3H7O2
23. 12.5 gm of fuming H2SO4 (labelled as 112%) is

m i x e d w i t h 1 0 0
+
in
l i t w a t e r. M o l a r c o n c e n t r a t i o n o f H
resultant solution is :
[Note : Assume that H2SO4 dissociate completely and
there is no change in volume on mixing]
2 2 3 3
(A) (B) (C) (D)
700 350 350 700
Sol.
25. The % by volume of C4H10 in a gaseous mixture of

C4H10, CH4 and CO is 40. When 200 ml of the mixture is
burnt in excess of O2. Find volume (in ml) of CO2
produced.
(A) 220 (B) 340 (C) 440 (D) 560
Sol.
27. An iodized salt contains 0.5% of Nal. A person

consumes 3 gm of salt everyday. The number of iodide
ions going into his body everyday is
(A) 10–4 (B) 6.02 × 10–4 (C) 6.02 × 1019 (D) 6.02 × 1023
Sol.
26. What volumes should you mix of 0.2 M NaCl arid

0.1 M CaCl2 solution so that in resulting solution the
concentration of positive ion is 40% lesser than
concentration of negative ion. Assuming total volume
of solution 1000 ml.
(A) 400 ml NaCl, 600 ml CaCl2 (B) 600 ml NaCl, 400 ml
CaCl2
28. The pair of species having same percentage (mass)
(C) 800 ml NaCl, 200 ml CaCl2 (D) None of these
of carbon is :
Sol.
(A) CH3COOH and C6H12O6
(B) CH3COOH and C2H5OH
(C) HCOOCH3 and C12H22 O11
(D) C6H12O6 and C12H22O11
Sol.
29. 200 ml of a gaseous mixture containing CO, CO2

and N2 on complete combustion in just sufficient amount
of O2 showed contraction of 40 ml. When the resulting
gase s we re pass ed t hroug h KOH s ol ut i on i t
reduces by 50 % then calculate the volume ratio of
VCO2 : VCO : VN2 in original mixture.
(A) 4 : 1 : 5 (B) 2 : 3 : 5 (C) 1 : 4 : 5(D) 1 : 3 : 5

Sol. More than one correct :
Q.31 Two gases A and B which react according to the
equation
aA ( g) + bB ( g) → cC( g) + dD ( g)
to give two gases C and D are taken (amount not
known) in an Eudiometer tube (operating at a constant
Pressure and temperature) to cause the above.
If on causing the reaction there is no volume change
observed then which of the following statement is/
are correct.
(A) (a + b) = (c + d)
(B) average molecular mass may increase or decrease
if either of A or B is present in limited amount.
(C) Vapour Density of the mixture will remain same
throughout the course of reaction.
(D) Total moles of all the component of mixture will
change.
Sol.
30. Density of a gas relative to air is 1.17. Find the

mol. mass of the gas. [Mair = 29 g/mol]
(A) 33.9 (B) 24.7 (C) 29 (D) 22.3
Sol.
32. A mixture of C3H8 (g) O2 having total volume 100

ml in an Eudiometry tube is sparked & it is observed
that a contraction of 45 ml is observed what can be
the composition of reacting mixture.
(A) 15 ml C3H8 & 85 ml O2 (B) 25 ml C3H8 & 75 ml O2
(C) 45 ml C3H8 & 55 ml O2 (D) 55 ml C3H8 & 45 ml O2
Sol.
34. A mixture of 100 ml of CO, CO2 and O2 was sparked.

When the resulting gaseous mixture was passed through
KOH solution, contraction in volume was found to be
80 ml, the composition of initial mixture may be (in the
same order)
(A) 30 ml, 60 ml, 10 ml (B) 30 ml, 50 ml, 20 ml
(C) 50 ml, 30 ml, 20 ml (D) 30 ml, 40 ml, 30 ml
Sol.
33. An aqueous solution consisting of 5 M BaCl2, 58.8%

w/v NaCl solution & 2m Na2 X has a density of 1.949
gm/ml. Mark the option(s) which represent correct
molarity (M) of the specified ion.
[Assume 100% dissociation of each salt and molecular
mass of X2– is 96]
(A) [Cl–] = 20 M (B) [Na+] = 11 M
(C) [Total anions] = 20.5 M (D) [Total cations]=15 M
Sol.
35. Given following series of reactions :

(I) NH3 + O2 → NO + H2O
(II) NO + O2 → NO2
(III) NO2 + H2O → HNO3 + HNO2
(IV) HNO2 → HNO3 + NO + H2O
Select the correct option (s) :
(A) Moles of HNO3 obtained is half of moles of Ammonia
used if HNO2 is not used to produce HNO3 by reaction
(IV)
100
(B) % more HNO3 will be produced if HNO2 is used
6
to produce HNO3 by reaction (IV) than if HNO2 is not
used to produce HNO3 by reaction (IV)
1
(C) If HNO2 is used to produce HNO3 then th of total
4
HNO3 is produced by reaction (IV)
(D) Moles of NO produced in reaction (IV) is 50% of
moles of total HNO3 produced.
Sol.
37. The incorrect statement(s) regarding 2M MgCl2

aqueous solution is/are (dsolution = 1.09 gm/ml)
(A) Molality of Cl is 4.44 m
(B) Mole fraction of MgCl2 is exactly 0.035
(C) The conc. of MgCl2 is 19% w/v
(D) The conc. of MgCl2 is 19 × 104 ppm
Sol.
36. Solution(s) containing 40 gm NaOH is/are

(A) 50 gm of 80% (w/w) NaOH
(B) 50 gm of 80% (w/v) NaOH [dsoln = 1.2 gm/ml]
(C) 50 gm of 20 M NaOH [dsoln = 1 gm/ml]
(D) 50 gm of 5m NaOH
Sol.
38. An organic compound is burnt with excess of O2

to produce CO2 (g) and H2O(l), which results in 25%
volume contraction. Which of the following option(s)
satisfy the given conditions.
(A) 10 ml C3H8 + 110 ml O2
(B) 20 ml C2H6O + 80 ml O2
(C) 10 ml C3H6O2 + 50 ml O2
(D) 40 ml C2H2O4 + 60 ml O2
Sol.
40. Solution(s) containing 30 gm CH3COOH is/are

(A) 50 gm of 70% (w/v) CH3COOH [dsol = 1.4 gm/ml]
(B) 50 gm of 10 M CH3COOH [dsol = 1 gm/ml]
(C) 50 gm of 60% (w/w) CH3COOH
(D) 50 gm of 10 m CH3COOH
Sol.
39. A sample of H2O2 solution labelled as 56 volume

has density of 530 gm/L. Mark the correct option(s)
representing concentration of same solution in other
units. (Solution contains only H2O and H2O2)
w
(A) MH2O2 = 6 (B) % = 17
v
1000
(C) Mole fraction of H2O2 = 0.25 (D) mH2O 2 =
72
Sol.
41. ‘2V’ ml of 1 M Na2SO4 is mixed with ‘V’ ml of 2M Sol.

Ba(NO3)2 solution.
(A) Molarity of Na+ ion in final solution can’t be
calculated as V is not known.
2
(B) Molarity of BaSO4 in final solution is M
3
4
(C) Molarity of NO3– in final solution is M
3
2
(D) Molarity of NO3– in final solution is M
3
Sol.
Q.43 The recommended daily dose is 17.6 milligrams

of vitamin C (ascorbic acid) having formula C6H8O6.
Match the following. Given : NA = 6 × 1023
Column I Column II
(A) O-atoms present (P) 10–4 mole
(B) Moles of vitamin C in 1gm (Q) 5.68 × 10–3
of vitamin C
(C) Moles of vitamin C in 1gm (R) 3.6 × 1020
should be consumed daily
Sol.
Match the Column :

42. One type of artifical diamond (commonly called
YAG for yttrium aluminium garnet) can be represented
by the formula Y3Al5O12 [Y = 89, Al = 27]
Column I Column II
Element Weight percentage
(A) Y (P) 22.73 %
(B) Al (Q) 32.32 %
(C) O (R) 44.95 %
44. Column I Column II 45. Bunty & Bubbly have two separate containers one
(A) 10 M MgO (P) Wsolvent = 120 gm having N2 gas & other H2 gas : It is known that N2 & H2
(dsol = 1.20 gm/ml) per 100 ml of solution. react to give N2H2(l) and/or N2H4 (g) depending upon
the ratio in which N2 & H2 are taken & that N2H2 reacts
Solute: MgO, Solvent:H2O
with H2 to give N2H4. Formation of 1 mole of N2H4
(B) 40% w/v NaOH (Q) Wsol = 150 gm requires 30 units of energy & formation of 1 mole of
(dsol. = 1.6 gm/ml) per 100 gm solvent N2H2(l) release 30 units of energy. From this information
Solute:NaOH,Solvent:H2O match Column I (representing composition of gases
(C) 8 m CaCO3 (R) Wsolute = 120 gm per taken) with Column II (representing the observation)
Solute:CaCO3,Solvent:H2O 100 gm of solvent Column I Column II
(D) 0.6 mol fraction of ‘X’ (S) Wsolvent = 125 gm (Composition of gases)(Observation)
(molecular mass = 20) per 100 gm of solute (A) 40 lit N2 & 30 lit H2 (P) Contraction by 22.4 lit
in ‘Y’ (molecular mass 25) (same tem perature &
pressure)
Solute : X, Solvent : Y
(B) 11.2 lit of N2 & H2 (Q) Contraction by 20 lit.
Sol. taken at 1 atm & 273 K
in a ratio such that max.
release of energy
is observed
(C) 11.2 lit of N2 & 30 lit (R) Contraction by 60 lit
of H2 (same temperature
& pressure)
(D) 10 lit of N2 & more
than 22.4 lit of H2 (S) Contraction by 11.2 lit
(same temperature &
pressure)
Sol.
46. Br2 reacts with O2 in either of the following ways COMPREHENSION

depending upon supply of O2. 47. A 4.925 g sample of a mixture of CuCl2 and CuBr2
was dissolved in water and mixed thoroughly with a
1
Br2 + O 2 → Br2O 5.74 g portion of AgCl. After the reaction the solid, a
2 mixture of AgCl, and AgBr, was filtered, washed, and
dried. Its mass was found to be 6.63 g.
3
Br2 + O 2 → Br2O 3 (a) % By mass of CuBr2 in original mixture is
2
(A) 2.24 (B) 74.5 (C) 45.3 (D) None
Match composition of the final mixture for initial amount
of reactants. (b) % By mass of Cu in original mixture is
Column I Column II (A) 38.68 (B) 19.05 (C) 3.86 (D) None
(Initial reactants) (Final product) (c) % by mole of AgBr in dried precipitate is
(A) 320 gm Br2 is mixed (P) 1 mole Br2O3 (A) 25 (B) 50 (C) 75 (D) 60
with 64 gm of O2 –
(d) No. of moles of Cl ion present in the solution
after precipitation are
1
(B) 160 gm Br2 is mixed (Q) mole (Br2O), (A) 0.06 (B) 0.02 (C) 0.04 (D) None
2
Sol.
1
with 8 gm of O2 mole (Br2 )
2
(C) 80 gm Br2 is mixed with (R) 1 mole (Br2O), 1 32
gm of O2 mole (Br2O3)
1
(D) 160 gm Br2 is mixed with (S) mole (Br2O3),
2
1
48 gm of O2 mole (O2)
4
Sol.
48. NaBr, used to produce AgBr for use in photography 49. N2O5 and H2O can react to form HNO3, according
can be self prepared as follows : to given reaction
Fe + Br2 → FeBr2 ...(i) N2O5 + H2O → 2HNO3
FeBr2 + Br2 → Fe3Br8 ...(ii) (not balanced) the concentration of a mixture of HNO3 and N2O5(g)
Fe3Br8 + Na2CO3 → NaBr + CO2 + Fe3O4 ...(iii) can be expressed similar to oleum. Then answer the
following question.
(not balanced)
(a) Find the percentage labelling of a mixture containing
(a) Mass of iron required to produce 2.06 × 103 kg
23 gm HNO3 and 27 gm N2O5.
NaBr
(A) 104.5% (B) 109% (C) 113.5% (D) 118%
(A) 420 gm (B) 420 kg
(b) Find the maximum and minimum value of percentage
(C) 4.2 × 105 kg (D) 4.2 × 108 gm
labelling :
(b) If the yield of (ii) is 60% & (iii) reaction is 70%
(A) 133.3% (B) 116.66%, 0%
then mass of iron required to produce 2.06 × 103 kg
NaBr (C) 116.66%, 100% (D) None
(A) 105kg (B) 105 gm (C) 103 kg (D) None (c) Find the new labelling if 100 gm of this mixture
(original) is mixed with 4.5 gm water
(c) If yield of (iii) reaction is 90% then mole of CO2
formed when 2.06 × 103 gm NaBr is formed : 4.5 4.5
(A) 20 (B) 10 (C) 40 (D) None (A) 100 + (B) 100 +
1 1.045
Sol.
4.5 4 .5
(C) 100 + (D) 100 +
104.5 1.09
Sol.
50. For a gaseous reaction, 51. A 10 ml mixture of N2, a alkane & O2 undergo
2A(g) → 3B(g) + C(g) combustion in Eudiometry tube. There was contraction
Whose extent of dissociation depends on temperature of 2 ml, when residual gases are passed through KOH.
is performed in a closed container, it is known that To the remaining mixture comprising of only one gas
extent of dissociation of A is different in different excess H2 was added & after combustion the gas
temperature range. With in a temperature range it is produced is absorbed by water, causing a reduction in
constant. (Temperature range T0 – T1, T1 – T2, T2 – T∞). volume of 8 ml.
A plot of P v/s T is drawn under the given condition. (a) Gas produced after introduction of H2 in the mixture ?
Given : tan 55 = 1.42, tan 50 = 1.19, tan 60 = 1.73 (A) H2O (B) CH4 (C) CO2 (D) NH3
60° (b) Volume of N2 present in the mixture ?
(A) 2 ml (B) 4 ml (C) 6 ml (D) 8 ml
P(atm)
(c) Volume of O2 remained after the first combustion ?

(A) 4 ml (B) 2 ml (C) 0 (D) 8 ml
(d) Identify the hydrocarbon.
(A) CH4 (B) C2H6 (C) C3H8 (D) C4H10
55° Sol.
50°
T0 T1 T2 T(k)
(a) If α
Ti – Ti+1 is the degree of dissociation of A then
in the temperature range Ti → Ti + 1
(A) α T0 – Ti is lowest (B) α T0 – Ti is highest
(C) α T2 – T∞ = 1 (D) α T2 – T∞ = 0
(b) If initially 1 mole of A is taken in a 0.0821 l container
then [R = 0.0821 atm lit/k]
(A) α T0 – Ti = 0.19 (B) α T0 – T1 = 0.095
(C) α T1 – T2 = 0.42 (D) α T1 – T2 = 0.73

Sol.
Exercise - II (Subjective Level-1)
1. The average mass of one gold atom in a sample of

naturally occuring gold is 3.257 × 10–22 g. Use this to
calculate the molar mass of gold.
Sol.
2. A plant virus is found to consist of uniform cylindrical

particles of 150 Å in diameter and 5000 Å long. The
specific volume of the virus is 0.75 cm3/g. If the virus
is considered to be a single particle, find its molecular
weight. [V = πr2l]
4. A chemical compound “dioxin” has been very much
Sol.
in the news in the past few years. (it is the by-product
of herbicide manufacture and is through to be quite
toxic.) Its formula is C12H4Cl4O2. If you have a sample
of dirt (28.3 g) that contains 8.78 × 10–8 moles of
dioxin, calculate the percentage of dioxin in the dirt
sample ?
Sol.
MOLE
3. Calculate
(a) Number of nitrogen atoms in 160 amu of NH4NO3
(b) Number of gram-atoms of S in 490 kg H2SO4
(c) Grams of Al2(SO4)3 containing 32 amu of S.
Sol.
5. Nitrogen (N), phosporus (P), and potassium (K) are 7. Given the following empirical formulae and molecular
the main nutrients in plant fertilizers. According to an weights, compute the true molecular formulae :
industry convention, the numbers on the label refer Empirical Formula Molecular weight
to the mass % of N, P2O5, and K2 O, in the order.
(a) CH2 84
Calculate the N : P : K ratio of a 30 : 10 : 10 fertilizer
in terms of moles of each elements, and express it as (b) CH2O 150
x : y : 1.0. (c) HO 34
Sol. (d) HgCl 472
(e) HF 80
Sol.
8. What is the empirical formula of a compound 0.2801

gm of which gave on complete combustion 0.9482 gm
of carbon dioxide and 0.1939 gm of water ?
Sol.
EMPIRICAL & MOLECULAR FORMULA

6. Polychlorinated biphenyls, PCBs, known to be
dangerous environmental pollutants, are a group of
compounds with the general empirical formula C12HmCl10–m,
where m is an integer. What is the value of m, and
hence the empirical formula of the PCB that contains
58.9% chlorine by mass ?
Sol.
9. A 5.5 gm sample of an organic compound gave on

quantitative analysis 1.4 gm of N and 3.6 gm of C and
0.5 gm of H. If Molecular mass of the compound is 55
then calculate E.F. and M.F.
Sol.
11. A sample containing only CaCO3 and MaCO3 is

ignited to CaO and MgO. The mixture of oxides produced
weight exactly half as much as the original sample.
Calculate the percentages of CaCO3 and MgCo3 in the
sample.
Sol.
PROBLEMS RELATED WITH MIXTURE

10. One gram of an alloy of aluminium and magnesium
when heated with excess of dil. HCl forms magnesium
chloride, aluminium chloride and hydrogen. The evolved
hydrogen collected over mercury at 0ºC has a volume
of 1.12 liters at 1 atm pressure. Calculate the
composition of the alloy.
Sol.
12. Determine the percentage composition of a mixture

of anhydrous sodium carbonate and sodium bicarbonate
from the following data :
wt of the mixture taken = 2g
Loss in weight on heating = 0.11 gm
Sol.
14. A mixture of Ferric oxide (Fe2O3) and Al is used as

a solid rocket fuel which reacts to give Al2O3 and Fe.
No other reactants and products are involved. On
complete reaction of 1 mole of Fe2O3, 200 units of
energy is released.
(i) Write a balance reaction representing the above
change.
(ii) What should be the ratio of masses of Fe2O3 and
Al taken so that maximum energy per unit mass of fuel
is released.
(iii) What would be energy released if 16 kg of Fe2O3
reacts with 2.7 kg of Al.
13. A 10 g sample of a mixture of calcium chloride and Sol.

sodium chloride is treated with Na2CO3 to precipitate
calcium as calcium carbonate. This CaCO3 is heated
to convert all the calcium to CaO and the final mass
of CaO is 1.12gm. Calculate % by mass of NaCl in the
original mixture.
Sol.
17. Carbon reacts with chlorine to form CCl4. 36 gm of

carbon was mixed with 142 g of Cl2. Calculate mass of
CCl4 produced and the remaining mass of reactant.
Sol.
LIMITING REACTANT
15. Titanium, which is used to make air plane engines

and fr am es , ca n be ob ta i ned f rom ti ta ni um
tetrachloride, which in turn is obtained from titanium
oxide by the following process :
3 TiO2 (s) + 4C(s) + 6Cl2 (g) → 3TiCl4(g) + 2CO2(g) + 2Co(g)
A vessel contains 4.32 g TiO2, 5.76 g C and; 6.82 g
Cl 2 , suppose the reaction goes to completion as
written, how many gram of TiCl4 and be produced ?
(Ti = 48)
Sol.
16. A chemist wants to prepare diborane by the

reaction
6LiH + 8BF3 → 6LiBF4 + B2H6
If he starts with 2.0 moles each of LiH & BF3. How
many moles of B2H6 can be prepared.
Sol.
MISCELLANEOUS PROBLEM
18. P4S3 + 8O2 → P4O10 + 3SO2

Calculate minimum mass of P4S3 is required to produce
atleast 1 gm of each product.
Sol.
20. The chief ore of Zn is the sulphide, ZnS. The ore

is concentrated by froth floatation process and then
heated in air to convert ZnS to ZnO.
75%
2ZnS + 3O 2 → 2ZnO + 2SO 2
100%
ZnO + H2SO 4  → ZnSO 4 + H2O
80%
2ZnSO 4 + 2H2O → 2Zn + 2H2SO 4 + O 2
(a) What mass of Zn will be obtained from a sample of
ore containing 291 kg of ZnS.
(b) Calculate the volume of O2 produced at 1 atm &
273 K in part (a).
Sol.
19. By the reaction of carbon and oxygen, a mixture

of CO and CO2 is obtained. What is the composition
by mass of the mixture obtained when 20 grams of O2
reacts with 12 grams of carbon ?
Sol.
22. A mixture of nitrogen and hydrogen. In the ratio

of one mole of nitrogen to three moles of hydrogen,
was partially converted into NH3 so that the final
product was a mixture of all these three gases. The
mixture was to have a density of 0.497 g per litre at
25ºC and 1.00 atm. What would be the mass of gas in
22.4 liters at 1atm and 273 K ? Calculate the %
composition of this gaseous mixture by volume.
Sol.
21. In a determination of P an aqueous solution of

NaH2PO4 is treated with a mixture of ammonium and
magnesium ions to precipitate magnesium ammonium
phosphate Mg(NH4)PO4 , 6H2O. This is heated and
decomposed to magnesium pyrophosphate, Mg2P2O7
which is weighed. A solution of NaH2PO4 yielded 1.054
g of Mg2P2O7. What weight of NaH2PO4 was present
originally ?
Sol.
23. 1gm sample of KClO3 was heated under such 24. In one process for waterproofing, a fabric is exposed
conditions that a part of it decomposed according to to (CH3)2SiCl2 vapour. The vapour reacts with hydroxyl
the equation (1) 2KClO3 ––→ 2 KCl + 3O2 groups on the surface of the fabric or with traces of
and remaining underwent change according to the water to form the waterproofing film [(CH3)2SiO]n, by
equation. (2) 4KClO3 ––→ 3 KClO4 + KCl the reaction
If the amount of O2 evolved was 112 ml at 1 atm and n(CH3 )2 SiCl2 + 2nOH − → 2nCl − + nH2O + [(CH3 )2 SiO] n
273 K., calculate the % by weight of KClO4 in the
residue. where n stands for a large integer. The waterproofing
film is deposited on the fabric layer upon layer. Each
Sol.
layer is 6.0 Å thick [the thickness of the (CH3)2SiO
group]. How much (CH3)2 SiCl2 is needed to waterproof
one side of a piece of fabric, 1.00 m by 3.00 m, with a
film 300 layers thick ? The density of the film is
1.0 g/cm3.
Sol.
CONCENTRATION TERMS
25. Calculate the molarity of the following solutions :
(a) 4g of caustic soda is dissolved in 200 mL of the
solution.
(b) 5.3 g of anhydrous sodium carbonate is dissolved
in 100 mL of solution
(c) 0.365 g of pure HCl gas is dissolved in 50 mL of
solution.
Sol.
27. The density of a solution containing 40% by mass

of HCl is 1.2 g/mL. Calculate the molarity of the
solution.
Sol.
28. 15g of methyl alcohol is present in 100 mL of

solution. If density of solution is 0.90 g mL–1. Calculate
the mass percentage of methyl alcohol in solution
Sol.
26. Density of a solution containing 13% by mass of

sulphuric acid is 1.09 g/mL. Then molarity of solution
will be.
Sol. 29. Units of parts per million (ppm) or per billion (ppb)
are often used to describe the concentrations of
solutes in very dilute solutions. The units are defined
as the number of grams of solute per million or per
billion grams of solvent. Bay of Bengal has 1.9 ppm of
lithium ions. What is the molality of Li+ in this water ?
Sol.
30. A 6.90 M solution of KOH in water contains 30%

by mass of KOH. What is density of solution in gm/ml.
Sol.
32. Find out the volume of 98% w/w H2SO4 (density =

1.8 gm/ml) must be diluted to prepare 12.5 litres of
2.5 M sulphuric acid solution.
Sol.
31. A solution of specific gravity 1.6 is 67% by weight.

What will be % by weight of the solution of same acid
if it is diluted to specific gravity 1.2 ?
Sol.
33. Determine the volume of diluted nitric acid (d =

1.11 gmL–1, 19% w/v HNO3) That can be prepared by
diluting with water 50 mL of conc. HNO3 (d = 1.42 g
ML–1, 69.8 % w/v).
Sol.
35. Calculate molality (m) of each ion present in the

aqueous solution of 2M NH4 Cl assuming 100%
dissociation according to reaction.
NH4 Cl (aq) → NH+4 (aq) + Cl − (aq)
Given : Density of solution = 3.107 gm/ml.

Sol.
34. (a) Find molarity of Ca2+ and NO3– in 2 M Ca(NO3)2

aqueous solution of density 1.328 g/mL.
(b) Also find mole fraction of solvent in solution.
Sol.
36. 500 ml of 2 M NaCl solution was mixed with 200 ml

of 2 M NaCl solution. Calculate the final volume and
molarity of NaCl in final solution if final solution has
density 1.5 gm/ml.
Sol.
38. 0.20 gm of an organic compound was treated by

Kjeldahl’s method and the resulting ammonia was
passed into 50 cc of M/4 H2 SO4. The residual acid
was then found to require 40 cc of M/2 NaOH for
neutralisation. What is the percentage of nitrogen in
the compound ?
Sol.
EXPERIMENTAL METHODS
37. What is the percentage of nitrogen in an organic

compound 0.14 gm of which gave by Dumas method
82.1 c.c. of nitrogen collected over water at 27ºC
and at a barometric pressure of 774.5 mm ? (aqueous
tension of water at 27ºC is 14.5 mm)
Sol.
40. 0.6872 gm of an organic compound gave on

complete combustion 1.466 gm of carbon dioxide and
0.4283 gm of water. A given weight of the compound
when heated with nitric acid and silver nitrate gave
an equal weight of silver chloride. 0.3178 gm of the
compound gave 26.0 cc of nitrogen at 15ºC and 765
mm pressure. Deduce the empirical formula of the
39. 0.252 gm of an organic compound gave on
compound ?
complete combustion 0.22 gm of carbon dioxide and
0.135 gm of water. 0.252 gm of the same compound Sol.
gave by Carius method 0.7175 gm of silver chloride.
What is the empirical formula of the compound ?
Sol.
41. 0.80 g of the chloroplatinate of a mono acid base

on ignition gave 0.262 g of Pt. Calculate the mol wt of
the base.
Sol.
SOME TYPICAL CONCENTRATION TERMS
43. Calculate composition of the final solution if 100

gm oleum labelled as 109% is added with
(a) 9 gm water (b) 18 gm water (c) 120 gm water
Sol.
42. The molecular mass of an organic acid was

determined by the study of its barium salt. 2.562 g of
salt was quantitatively converted to free acid by the
reaction 30 ml of 0.2 M H2 SO4, the barium salt was
found to have two moles of water of hydration per
Ba+2 ion and the acid is mono basic. What is molecular
weight of anhydrous acid ? (At mass of Ba = 137)
Sol.
44. For ‘44.8 V’ H2O2 solution having d = 1.136 gm/ml 45. An oleum sample is labelled as 118%, Calculate
calculate (i) Mass of H2SO4 in 100 gm oleum sample.
(i) Molarity of H2O2 solution. (ii) Maximum mass of H2SO4 that can be obtained if 30
(ii) Mole fraction of H2O2 solution. gm sample is taken.
Sol. (iii) Composition of mixture (mass of components) if
40 gm water is added to 30 gm given oleum sample.
Sol.
EUDIOMETRY
46. 10ml of a mixture of CO, CH4 and N2 exploded with

excess of oxygen gave a contraction of 6.5 ml. There
was a further contraction of 7 ml, when the residual
gas treated with KOH. Volume of CO, CH4 and N2
respectively is
Sol.
48. 60 ml of a mixture of nitrous oxide and nitric oxide

was exploded with excess of hydrogen. If 38 ml of N2
was formed, calculate the volume of each gas in the
mixture.
Sol.
47. When 100 ml of a O2 – O3 mixture was passed

through turpentine, there was reduction of volume by
20 ml. If 100 ml of such a mixture is heated, what will
be the increase in volume ?
Sol.
50. 10 ml of ammonia were enclosed in an eudiometer

and subjected to electric sparks. The sparks were
continued till there was no further increase in volume.
The volume after sparking measured 20 ml. Now 30
ml of O2 were added and sparking was continued again.
The new volume then measured 27.5 ml. All volume
were measured under i denti cal conditi ons of
temperature and pressure. V.D. of ammonia is 8.5.
Calculate the molecular formula of ammonia. Nitrogen
and Hydrogen are diatomic.
49. When a certain quantity of oxygen was ozonised Sol.
in a suitable apparatus, the volume decreased by 4
ml. On addition of turpentine the volume further
decreased by 8 ml. All volumes were measured at the
same temperature and pressure. From these data,
establish the formula of ozone.
Sol.
Exercise - III (Subjective Level-II)

under identical conditions and then cooled. The volume
1. A 2 + 2B 2 → A 2B 4 and
3
A 2 + 2B 2 → A 3B 4 left after cooling was 90 mL. On treatment with KOH a
2 contraction of 20 Ml was observed. If vapour density
Two substance A2 & B2 react in the above manner of compound is 23, derive molecular formula of the
when A2 is limited it gives A2B4, when in excess gives compound.
A3B4. A2B4 can be converted to A3B4 when reacted
with A2. Using this information calculate the composition 7. For a hypothetical chemical reaction represented
of the final mixture when mentioned amount of A2 & B2 by
are taken
(i) If 4 moles of A2 & 4 moles of B2 is taken in reaction 3 A( g) → C( g) + D( g) , the following informations are
container known.
Information
1
(ii) If moles of A2 & 2 moles of B2 is taken in reaction (i) At t = 0, only 1 mole of A is present and the gas
2
has V.D. = 60.
container
(ii) At t = 30 min, the gaseous mixture consist of all
5 three gases and has a vapour density = 75.
(iii) If moles of A2 & 2 moles of B2 is taken
4 (iii) Molecular Mass of C = 200
Calculate
2. How much minimum volume of 0.1 M aluminium (a) Molecular weight of A and D.
sulphate solution should be added to excess calcium (b) Moles of each specie at t = 30 min.
nitrate to obtain atleast 1 gm of each salt in the
reaction.
8. PCl3 + Cl2 → PCl5
Al 2 (SO 4 )3 + 3Ca(NO 3 )2 → 2Al(NO 3 )3 + 3CaSO 4
PCl3 + 3H2O → H3PO 3 + 3HCl
3. A sample of fuming sulphuric acid containing H2SO4, A sample containing very large amount of PCl3 was
SO3 and SO2 weighing 1.00 g is found to require 23.47 exposed to a sample of “Chlorinated water” having Cl2
ml of 1.00 M alkali (NaOH) for neutralisation. A separate dissolved in H2O so that the above two reactions
sample shows the presence of 1.50% SO2. Find the occurred. It was observed that ration of mass of PCl5
percentage of “free” SO3, H2SO4 and “combined” SO3 to mass of H3PO3 was 417 : 246. From this information
in the sample. calculate.
(i) ratio of moles of PCl5 to moles of H3PO3.
4. Chloride samples are prepared for analysis by using (ii) ratio of moles of Cl2 : H2O present in chlorinated
NaCl, KCl and NH4Cl separately or as mixture. What water
minimum volume of 5% by weight AgNO3 solution (sp
(iii) Molality (m) of Chlorine in Chlorinated water.
gr., 1.04 g ml–1) must be added to a sample of 0.3 g in
order to ensure complete precipitation of chloride in
every possible case ? 9. A mixture of H2, N2 & O2 occupying 100 ml underwent
reaction so as to from H2O2(l) and N2H2(g) as the only
products, causing the volume to contract by 60 ml.
5. One litre of milk weighs 1.035 kg. The butter fat is
The remaining mixture was passed through pyrogallol
10% (v/v) of milk has density of 875 kg/m3. The
causing a contraction of 10ml. To the remaining mixture
density of fat free skimed milk is ?
excess H2 was added and the above reaction was
repeated, causing a reduction in volume of 10 ml.
6. 10 mL of gaseous organic compound contain C, H Identify the composition of the initial mixture in mol
and O only was mixed with 100 mL of O2 and exploded %. (No other products are formed)
10. Consider the following set reactions 40% yield

13. H2O 2 + 2KI   
→ I 2 + 2KOH
CH3
O
|| 50% yield
CH − C − O − H H2O2 + 2KMnO4 + 3H2SO4  →
O K2SO4 + 2MnSO4 + 3O2 + 4H2O
||
CH − C − O − H
100 ml of H2O sample was divided into two parts. First
O part was treated with KI. And KOH formed required
||
CH − C − O − H 200 ml of M/2 H2SO4 for complete neutralisation. Other
n times
part was treated with just sufficient KMnO4 yielding
CH3 6.74 lit. of O2 at 1 atm & 273 K. Calculate
+ AgNO 3 → Silver Salt → White resideu (a) Moles of KOH produced
( excess)
(b) Moles of KMnO4 used
If 0.1 moles of silver salt is taken & wt. of residue
obtained is 54 gms then what will be the molecular (c) Total moles of H2O2 used in both reaction
mass of (d) Volume strength of H2O2 used.
 CH− CH ....... CH  14. The vapours of organic compound was burnt in
CH3  | | |  − CH
 Br Br Br  3
oxygen. Equal volume of both gaseous substance were
 n
taken at same pressure and temperature. After the
11. 124 gm of mixture containing NaHCO3, AlCl3 & KNO3 reaction, the system was returned to the original
requires 500 ml, 8% w/w NaOH solution [dNaOH = 1.8 condition and it turn out that its volume has not
gm/ml] for complete neutralisation. On heating same changed. The product of combustion contain 50% CO2
amount of mixture, it shows loss in weight of 18.6 gm. (g) and 50% H2O(g) by volume and no other gas. Find
Calculate % composition of mixture by moles. Weak
the molecular weight of organic compound (in gram/
base formed doesn’t interfere in reaction. Assume KNO3
does not decompose under given conditions. mol) in question.
12. A mixture of three gases an alkane (general formula 15. “Prussian blue” can be prepared by the following
Cn H2n + 2), an alkene (general formula CxH2x) and O2 reactions.
was subjected to sparking to cause combustion of
both the hydrocarbon at 127ºC. After the reaction I. Fe + H2SO 4 → FeSO 4 + H2
three gases were present and none of the hydrocarbon
remained. On passing the gases through KOH (absorb
CO2), an increment in mass of KOH solution by 132 gm II. FeSO 4 + H2SO 4 +
1
O 2 → Fe 2 (SO 4 )3 + H2O
was observed. The remaining gases were passed over 2
white anhydrous CuSO4 and the weight of blue
hydrated CuSO4 crystals was found to be 72 gm more III. Fe 2 (SO 4 )3 + K 4 [Fe(CN)6 ] → Fe 4 [Fe(CN)6 ]3 + K 2SO 4
than that of white anhydrous CuSo4. Given that initially
total 10 moles of the three gases were taken and Calculate number of moles of Fe4 [Fe(CN)6]3 produced,
moles of alkane and alkene were equal and if if
molecular mass of alkene molecular mass of alkane =
12 i.e. (Malkene – Malkane = 12), then answer the following (i) 50 moles of Fe and 30 moles of H2SO4 are used
questions. (Show calculations) with sufficient amount of other reactants.
(a) Which three gases are remained after the (ii) 50 moles of Fe, 70 moles of H2SO4 and 30 moles of
combustion reactions. K4[Fe(CN)6] are used with sufficient amount of other
(b) What are the number of moles of product gases. reactants.
(c) What i s the molecular formula of the two
(iii) 400 moles of Fe are used with sufficient amount
hydrocarbon.
of other reactants (assuming the yield of I, II & III
(d) What is the number of moles of each of the two
hydrocarbons and O2 gas taken initially. reactions are 50%, 40% and 60% respectively).
Exercise - IV JEE PROBLEMS

3. How many moles of e– weigh one Kg
1. An evacuated glass vessel weighs 50 gm when
empty, 148.0 g when completely filled with liquid of 1
density 0.98 gml–1 and 50.5 g when filled with an ideal (A) 6.023 × 1023 (B) × 1031
9.108
gas at 760 mm at 300 K. Determine the molecular
weight of the gas. [JEE ‘98,3] 6.023 1
(C) × 10 54 (D) × 10 8
Sol. 9.108 9.108 × 6.023
[JEE ‘2002 (Scr), 1]
Sol.
4. Calculate the molarity of pure water using its density

to be 1000 kg m–3. [JEE’ 2003]
Sol.
2. At 100° C and 1 atmp, if the density of liquid water

is 1.0 g cm–3 and that of water vapour is 0.0006 g cm–
3
, then the volume occupied by water molecules 1 L
of steam at that temperature is :
(A) 6 cm3 (B) 60 cm3
(C) 0.6 cm 3
(D) 0.06 cm3
[JEE ‘2001 (Scr), 1]
Sol.
5. One gm of charcoal absorbs 100 ml 0.5 M CH3COOH
to form a monolayer, and there by the molarity of
CH3COOH reduces to 0.49. Calculate the surface area
of the charcoal adsorbed by each molecule of acetic
acid. Surface area of charcoal = 3.01 × 102 m2/gm.
Sol. [JEE’ 2003]
6. Calculate the amount of Calcium oxide required when Sol.

it reacts with 852 gm of P4O10. [JEE 2005]
Sol.
9. Reaction of Br2 with Na2CO3 in aqueous solu-

tion gives sodium bromide and sodium bromate
with evolution of CO2 gas. The number of so-
dium bromide molecules involved in the bal-
anced chemical equation is : [JEE 2011]
Sol.
7. 20% surface sites have adsorbed N2. On heating N2

gas evolved from sites and were collected at 0.001
atm and 298 K in a container or volume is 2.46 cm3.
Density of surface sites is 6.023 × 1014/cm2 and surface
area is 1000 cm2, find out the no. of surface sites
occupied per molecule of N2. [JEE 2005]
Sol.
10. A decapeptide (Mol. wt. 796) on complete hy-
drolysis gives glycine (Mol. Wt. 75), alanine
and phenylalanine. Glycine contributes 47.0%
to the total weight tto the hydrolysed prod-
ucts. The number of glycine units present in
the decapeptide is : [JEE 2011]
Sol.
8. Dissolving 120 g of urea (mol. wt. 60) in 1000

g of water gave a solution of density 1.15 g/
mL. The molarity of the solution is:
(A) 1.78 M (B) 2.00 M [JEE 2011]
(C) 2.05 M (D) 2.22 M
ANSWER-KEY
Exercise-I
1. 50% 2. 30M, 75 m 3. Acidic 4. 0.86 5. 25% 6. 0.75
7. 0.331, 2.25 × 10–4, 2.81, 0.0482, 321, 5.72 8. A 9. A 10. B 11. A
12. B 13. C 14. A 15. B 16. B 17. A 18. B
19. A 20. A 21. C 22. B 23. A 24. C 25. C
26. D 27. C 28. C 29. C 30. A 31. A,C 32. A, B
33. A,B,C 34. A,B 35. A,C,D 36. A,C 37. B,D 38. A,C 39. B,D
40. B,C 41. C 42. (A) R, (B) P, (C) Q 43. (A) R, (B) Q, (C) P
44. (A) Q; (B) P; (C) S; (D) R 45. (A) R; (B) S; (C) P; (D) Q 46. (A) R, (B) Q, (C) S, (D) P
47. (a) C; (b) A; (c) B (d) A 48. (a) B; (b) C; (c) B 49. (a) B; (b) C; (c) B 50. (a) A; (b) A
51. (a) D; (b) B; (c) C; (d) A
Exercise-II
1. 196.169 gm 2. 7.092 × 107 3. (a) 4 ; (b) 5000 moles; (c) 1.89 × 10–22gm 4. 1.0 × 10–4%
5. 10 : 0.66 : 1 6. m = 4, C6H2Cl3 7. (a) C6H12, (b) C5H10O5, (c) H2O2, (d) Hg2 Cl2, (e) H4F4
8. CH 9. C3H5N, C3H5N 10. Al = 60%; Mg = 40%
11. CaCO3 = 28.4%; MgCO3 = 71.6% 12. NaHCO3 = 14.9%; Na2CO3 = 85.1%
13. %NaCl = 77.8% 14. (i) Fe2O3 + 2Al → Al2O3 + 2Fe; (ii) 80 : 27 ; (iii) 10,000 units
15. 9.12 16. 0.25 mole 17. wc = 24gm ; WCCl4 = 154 gm 18. 1.1458 19. 21 : 11
20. (a) 117 kg; (b) 20.16 × 103 lit. 21. 1.14 gm 22. 12.15 gm, N2 = 14.28% H2 = 42.86 %, NH3 = 42.86%
23. 59.72% 24. 0.9413 gram 25. (a) 0.5 M, (b) 0.5 M, (c) o.2 M 26. 1.445 27. 13.15
28. 16.66% 29. 2.7 × 10–4 30. 1.288 31. 29.77 32. 1.736 litre 33. 183.68 ml
34. (a) [Ca2+] = 2 molar [NO3–] = 4 molar; (b) 0.965 35. 0.6667, 0.6667 36. 2M
37. 66.67% 38. 35% 39. CH3Cl 40. C7H10NCl 41. 92.70 42. 128
43. (a) pure H2SO4 (109 gm); (b) 109 gm H2SO4, 9 gm H2O; (c) 109 gm H2SO4, 111 gm H2O
44. (i) 4M; (ii) 0.06 45. (i) 20 gm H2SO4; (ii) 35.4 gm H2SO4; (iii) H2SO4 = 35.4 gm, H2O = 34.6 gm
46. 5 ml, 2ml, 3ml 47. 10 ml 48. NO = 44 ml; N2O = 16 ml 49. O3 50. NH3
Exercise-III
1. (i) A2 = 1, A3B4 =2; (ii) B2 =1 A2B4=1/2; (iii) A3B4 = 0.5 A2B4 = 0.5 2. 24.51 ml
3. H2SO4 = 35.38%, Free SO3 = 63.1%, combined SO3 = 28.89% 4. 18.38 ml
2 1
5. 1.052 gm/ml 6. C2H6O 7. (a) mA = 120, mD = 160; (b) n A = , n C = 1 , nD =
5 5 5
m 2
8. (i) 2/3 ; (ii) 2/9; (iii) Cl 2 = × 1000 mol / kg 9. N2 = 30 ml, H2 = 40 ml 10. 495
9 × 18
11. AlCl3 = 33.33 ; NaHCO3 = 50 ; KNO3 = 16.67 12.(a) CO2, H2O and O2 ; (b) nCO2 = 3, nH2O = 4 ;
(c) C2H4 and CH4 are the H.C; (d) nO2 = 8
13. (a) 0.2; (b) 0.4 moles ; (c) 0.45 ; (d) 50.4 ‘V’ 14. 30 15. (a) 5, (b) 10, (c) 12
Exercise-IV
1. 123 g/mol 2. C 3. D 4. 55.5 mol L–1 5. 5 × 10–19 m2 6. 1008 gm
7. 0002 8. C 9. 0005 10. 0006

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STOICHIOMETRY - 1 Page # 21

Class Room Problems

Problem.4 5 mL of a gaseous hydrocarbon was

Problem.6 A sample of gaseous hydrocarbon

Problem.10 What is the purity of conc. H2SO 4

Problem.17 25.4 g of I2 and 14.2 g of Cl2 are made

Problem.19 For the reaction, N2O5(g) 2NO2(g)

Problem.18 A mixture of HCOOH and H2C2O4 is

Problem.20 0.22 g sample of volatile compound,

Problem.24 2.0 g of a mixture of carbonate,

Problem.26 A solid mixture 5 g consits of lead nitrate

Problem.25 Igni ting MnO 2 i n ai r converts i t

Problem.27 Determine the formula of ammonia form

Problem.30 A mixture in which the mole ratio of H2

Problem. 29 0.50 g of a mixture of K2CO3 and Li2CO3

Exercise - I Objective Type

4. Ratio of masses of H2SO4 and Al2 (SO4)3 is grams

2. A solution of A (MM = 20) and B (MM = 10), [Mole

5. The vapour density of a mixture of gas A (Molecular

3. 125 ml of 8% w/w NaOH solution (sp. gravity 1) is

6. For the reaction

8. Equal volumes of 10% (v/v) of HCl is mixed with

7. Fill in the blanks in the following table.

Compd Water of Compd of Compd

10. One gram of the silver salt of an organic dibasic Sol.

12. C6H5OH(g) + O2(g) → CO2(g) + H2O(l)

13. 10 ml of a compound containing ‘N’ and ‘O’ is

15. Mass of sucrose C12H22O11 produced by mixing 84

14. Similar to the % labelling of oleum, a mixture of

18. 40 gm of a carbonate of an alkali metal or alkaline

17. In the quantitative determination of nitrogen using

19. The percentage by mole of NO2 in a mixture NO2(g)

21. The mass of CO2 produced from 620 gm mixture of

20. The minimum mass of mixture of A2 and B4 required

22. Assuming complete precipitation of AgCl, calculate

24. 74 gm of sample on complete combustion gives

23. 12.5 gm of fuming H2SO4 (labelled as 112%) is

25. The % by volume of C4H10 in a gaseous mixture of

27. An iodized salt contains 0.5% of Nal. A person

26. What volumes should you mix of 0.2 M NaCl arid

29. 200 ml of a gaseous mixture containing CO, CO2

(A) 4 : 1 : 5 (B) 2 : 3 : 5 (C) 1 : 4 : 5(D) 1 : 3 : 5

30. Density of a gas relative to air is 1.17. Find the

32. A mixture of C3H8 (g) O2 having total volume 100

34. A mixture of 100 ml of CO, CO2 and O2 was sparked.

33. An aqueous solution consisting of 5 M BaCl2, 58.8%

35. Given following series of reactions :

37. The incorrect statement(s) regarding 2M MgCl2

36. Solution(s) containing 40 gm NaOH is/are

38. An organic compound is burnt with excess of O2

40. Solution(s) containing 30 gm CH3COOH is/are

39. A sample of H2O2 solution labelled as 56 volume

41. ‘2V’ ml of 1 M Na2SO4 is mixed with ‘V’ ml of 2M Sol.

Q.43 The recommended daily dose is 17.6 milligrams

Match the Column :

46. Br2 reacts with O2 in either of the following ways COMPREHENSION

(c) Volume of O2 remained after the first combustion ?

(C) α T1 – T2 = 0.42 (D) α T1 – T2 = 0.73

Exercise - II (Subjective Level-1)

1. The average mass of one gold atom in a sample of

2. A plant virus is found to consist of uniform cylindrical

8. What is the empirical formula of a compound 0.2801

EMPIRICAL & MOLECULAR FORMULA