Methods of Lime (CaO) generation

Decomposition / Chemical reaction

Conventional heating system Solar Thermal concept for electrolysis method

CaCO3 = CaO (Lime)+ CO2 (Carbon Dioxide) i) CaCO3 = CaO(Lime) + C(Carbon)+ O2 (Oxygen) below 800°C
(Harmful) ii) CaCO3 = CaO(Lime) + CO+ ½O2 (Oxygen) above 800°C

Solar Thermal electrolysis method for lime

Electrolysis is the passage of a direct electric current through an ionic substance that is either molten or dissolved in a
suitable solvent, resulting in chemical reactions at the electrodes and separation of materials.

When separated through electrolysis method to decompose the CaCO3, the resultant carbon and oxygen atoms no longer
pose the threat to the atmosphere that they do as CO2.

Also at higher temperature (above 800°C), the by- products of electrolysis CO or C can be used for other industrial process
such as plastics, purify nickel etc , thereby reducing the cost of lime generation used for the cement.

Aanalysis :

Based on temperature requirement for electrolysis, Solar thermal can assist process and below Solar Thermal
technology can be used :

A. below 800°C ( CO2 shall not be produced)

Current Solar Thermal options:
- Power Tower (upto 535°C) with molten salt
- Parabolic trough ( upto 393°C) with HTF ; HTF has limitation of 393°C)
 Conclusion : Power tower with Molten salt storage can gain above 500°C and 24 x 7 production , Molten
salt has limitation of 535°C. Advanced research ongoing.

B. Above 800°C(CO2 shall not be produced, further production of sellable by-product CO can drastically bring down
the cost of lime production ; even negative)
Current Solar Thermal Option: None
- Research ongoing