0 Stimmen dafür0 Stimmen dagegen

18 Aufrufe105 SeitenJun 21, 2019

© © All Rights Reserved

PDF, TXT oder online auf Scribd lesen

© All Rights Reserved

Als PDF, TXT **herunterladen** oder online auf Scribd lesen

18 Aufrufe

© All Rights Reserved

Als PDF, TXT **herunterladen** oder online auf Scribd lesen

- Midnight in Chernobyl: The Untold Story of the World's Greatest Nuclear Disaster
- The Field Updated Ed: The Quest for the Secret Force of the Universe
- The Final Day: A John Matherson Novel
- Bloody Sunday: A Thriller
- WomanCode: Perfect Your Cycle, Amplify Your Fertility, Supercharge Your Sex Drive, and Become a Power Source
- The Hormone Reset Diet: The 21-day Diet That Resets Your Metabolism
- The Making of the Atomic Bomb
- Blackfish City: A Novel
- Blackfish City: A Novel
- Wheels of Life: A User's Guide to the Chakra System
- Clinton Cash: The Untold Story of How and Why Foreign Governments and Businesses Helped Make Bill and Hillary Rich
- Chernobyl 01:23:40: The Incredible True Story of the World's Worst Nuclear Disaster
- The Prize: The Epic Quest for Oil, Money & Power
- Multipliers, Revised and Updated: How the Best Leaders Make Everyone Smarter
- Zero Hour
- The Energy Bus: 10 Rules to Fuel Your Life, Work, and Team With Positive Energy
- The Keto Reset Diet: Reboot Your Metabolism in 21 Days and Burn Fat Forever
- The Power of Full Engagement: Managing Energy, Not Time, is the Key to High Performance and Personal Renewal
- Midnight in Chernobyl: The Story of the World's Greatest Nuclear Disaster
- Positive Energy: 10 Extraordinary Prescriptions for Transforming Fatigue, Stress, and Fear into Vibrance, Strength, and Love

Sie sind auf Seite 1von 105

PART TEST – I

Pl ea s e r ea d t h e i n s t r u c t i o n s c a r ef u l l y. Yo u a r e a l l o t t ed 5 m i n ut es

s p ec i f i c a ll y f o r t h i s p u r p o s e.

Yo u a r e n o t a ll o wed t o l ea v e t h e E xa m i n at i o n Ha ll b ef o r e t h e en d o f

t h e t es t .

ALL INDIA TEST SERIES

INSTRUCTIONS

A. General Instructions

1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.

2. This question paper contains Three Parts.

3. Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.

4. Each part has only one section: Section-A.

5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be

provided for rough work.

6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic

devices, in any form, are not allowed.

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers

on OMR sheet.

2. On the OMR sheet, darken the appropriate bubble with black pen for each character of your

Enrolment No. and write your Name, Test Centre and other details at the designated places.

3. OMR sheet contains alphabets, numerals & special characters for marking answers.

1. Section-A (01 – 30, 31 – 60, 61 – 90) contains 90 multiple choice questions which have only one

correct answer. Each question carries +4 marks for correct answer and –1 mark for wrong

answer.

Enrolment No.

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I-PCM-JEE(Main)/18 2

Useful Data

PHYSICS

Acceleration due to gravity g = 10 m/s2

CHEMISTRY

= 0.0821 Lit atm K1 mol1

= 1.987 2 Cal K1 mol1

Avogadro's Number Na = 6.023 1023

Planck’s constant h = 6.625 1034 Js

= 6.625 10–27 ergs

1 Faraday = 96500 coulomb

1 calorie = 4.2 joule

1 amu = 1.66 10–27 kg

1 eV = 1.6 10–19 J

N=9, Na=11, Mg=12, Si=14, Al=13, P=15, S=16,

Cl=17, Ar=18, K =19, Ca=20, Cr=24, Mn=25,

Fe=26, Co=27, Ni=28, Cu = 29, Zn=30, As=33,

Br=35, Ag=47, Sn=50, I=53, Xe=54, Ba=56,

Pb=82, U=92.

Atomic masses: H=1, He=4, Li=7, Be=9, B=11, C=12, N=14, O=16,

F=19, Na=23, Mg=24, Al = 27, Si=28, P=31, S=32,

Cl=35.5, K=39, Ca=40, Cr=52, Mn=55, Fe=56, Co=59,

Ni=58.7, Cu=63.5, Zn=65.4, As=75, Br=80, Ag=108,

Sn=118.7, I=127, Xe=131, Ba=137, Pb=207, U=238.

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

3 AITS-PT-I-PCM-JEE(Main)/18

Physics PART – I

SECTION – A

(One Options Correct Type)

This section contains 30 multiple choice questions. Each question has four choices (A), (B), (C) and

(D), out of which ONLY ONE option is correct.

1. A point mass performs straight line motion along positive x-axis. At t = 0 point mass is at point

a

A(x1, 0). It moves such that its velocity is given by v , where a is positive constant and x is the

x

x-coordinate of position vector of point mass at a certain time t. Find the time required to move

from A to B (x 2, 0)

x 2 x12 x 2 x12

(A) 2 (B) 2

2a a

2x 22 x12 2x 22 x12

(C) (D)

2a a

speed 3v 0 as shown in figure. When the particle is at

point P, it explodes in three identical particles. P

3v0 v0

Choose the INCORRECT statement regarding the H

H/2

physical quantities just before and just after 60

explosion. A

(A) The linear momentum of system can be conserved just before and just after explosion.

(B) The centre of mass of the system will trace same path as it will follow without explosion.

(C) The mechanical energy of the system remains conserved just before and just after explosion.

(D) The impulse given by the weight of particle during explosion is negligible as compared to that

by the explosive forces.

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I-PCM-JEE(Main)/18 4

(either + or , consistent with the co-ordinate R1

system shown in the figure). FBD of the pulley is 2

also shown in the figure. The symbol a1y and a2x

=0 R2

represent y and x components of magnitude of F1

y g

acceleration of block-1 and block-2 respectively z 1 F2

For Pulley : Mg

x

CM ICM kˆ : [A] F1r [B] F2r ICM z

Constraint :

a1y [C]a2x [D] z r

Choose correct option.

A B C D

(A) + +

(B) + +

(C) +

(D) + + +

4. Two identical discs of mass m and of radius R touch each other and v

move with the same velocity perpendicularly to the line segment m R

which joins their centres of mass, along the surface of a horizontal R M

smooth tabletop. There is a third disc of mass M and of radius R at m

rest, at a point on the perpendicular bisector of the line segment R

j oi ni ng t he centres of m ass of t he t wo m ov ing di scs as v

shown in the figure. The two moving discs collide elastically with the third one, which is at rest.

There is no friction between the rims of the discs. What should the ratio of M/m be in order that

after the collision the two discs of mass m move perpendicularly to their initial velocity?

(A) 3 (B) 2

(C) 3 (D) 2

Its velocity versus time graph is shown in the

figure. Which one of the following choices

best gives the proper intervals(s) of time for

which the object is moving away from the Velocity (m/s) 0

origin?

(A) Only for times 0 s < t < 3s

–5

(B) Only for times 0 s < t < 5 s 0 2 4 6 8 10

Time(s)

(C) Only for times 3 s < t < 5s

(D) Only for times 0 s < t < 7 s

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

5 AITS-PT-I-PCM-JEE(Main)/18

wheel of radius R is (constant), in the clockwise sense. (O is

A v

fixed point)

xR sin x 2 sin

(A) (B)

R cos x R cos x

L

xR sin R2 sin

(C) (D)

R cos x R cos x

x

B

R

O

frictionless surface with horizontal force F. The force that

block-1 exerts at block-2 has magnitude F21 and the force

F

that block-7 exerts on the block-8 is F87. Find 21

F87

(A) 3 (B) 5

(C) 7 (D) 9

0

of inclination =37 is at rest at horizontal surface. h=3m

There is a small point –like object (mass m =0.5kg) M m

next to the slope as shown in the figure. At what

acceleration must wedge be moved in order that the

point like object reaches its top in a time t = 5s (Neglect the friction between point like object and

wedge)

(A) 2m/s2 (B) 4m/s2

2

(C) 8m/s (D) 10 m/s2

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I-PCM-JEE(Main)/18 6

particle moving along a straight line

is shown. What is the total distance

Position (m)

travelled by the particle from t = 0 s

to t = 10s?

(A) 2m 0

(B) 18 m

(C) 26m

(D) 34m

-10

0 1 2 3 4 5 6 7 8 9 10

Time (s)

bottom of a fixed incline of height H. A

person decides to push the object up the

incline in one of two ways with an applied H H

F2

force shown in the diagram. In each of the

trials, the object reaches the top of the F1

incline with speed V. How would the work Trial 1 Trial 2

done by the person on the block compare Force parallel to floor Force parallel to incline

for the two trials? Assume the same constant non-zero coefficient of kinetic friction between the

incline and the object for both trials.

(A) More work would be done in Trial 1

(B) More work would be done in Trial 2

(C) It is impossible to determine for which trial there would be more work done without knowing

the value of the speed V.

(D) It is impossible to determine for which trial there would be more work done without knowing

the value of the coefficient of kinetic friction.

by a horizontal force F acting through the center as shown. The F

cylinder rolls to the right without slipping. What is the

magnitude of the force of friction between the cylinder and the

ground?

(A) F/4 (B) F/3

(C) F/2 (D) 2F/3

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

7 AITS-PT-I-PCM-JEE(Main)/18

12. A particle is moving along straight line such that dot product of its acceleration a and velocity v

is negative. How many times particle can be found at a distance d from the origin?

(A) One (B) Three

(C) Two (D) Can’t be determined with given data

rough horizontal surface with angular acceleration . Centre of mass

R 45 ,

of sphere lies at a distance from the centre of sphere. Find the CM

2

normal force applied by sphere on the surface at an instant when line O

joining centre of mass of sphere and centre of sphere makes an

angle 45° with the vertical and angular velocity of sphere at this

instant is .

mR mR

(A) mg

2

2 (B) mg

2

2

mR mR

(C) mg

2

2 (D) mg

2

2

14. A block of mass m = 5 kg is being whirled in a horizontal circle with the help of a string of length

–1

= 1m with constant speed v = 5 ms . One end of the string is held fixed at a point O above the

centre of the horizontal circle. Gravity exists vertically downwards. The force of tension exerted by

the string on bob is T . For this given situation, choose INCORRECT statement:

mv 2 ˆ

(A) Total force acting on mass is mg T T

(B) Total force acting on mass is mg T

(C) Net force on the particle is in the horizontal direction.

(D) Horizontal component of tension provides required centripetal force.

and length . It rests upright on a horizontal smooth surface with its F

lower right corner against a stop about which the frame could pivot. A

horizontal force of magnitude F is applied to the upper corner of the

frame as shown in the figure. What is the largest value of F may have

without causing the frame to pivot upward about the stop? B C

(A) 3 mg (B) 3 mg

mg 3

(C) (D) mg

3 2

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I-PCM-JEE(Main)/18 8

fastened at left end to a vertical wall as shown 0.5m

in the figure I. Initially block C of mass 2 kg and

block D of mass 5 kg rest on horizontal surface

with block C in contact with spring (But not

compressing it.) and the block D in contact with K=400 N/m

block C. Block C is moved leftward,

C D

compressing spring by a distance of 0.5 m and

held in place while block D remains at rest as

shown in the figure. Now Block C is released Figure-I

and it accelerates to the right towards block D.

The surface is rough and the coefficient of

friction between each block and surface is 0.1.

The block collide instantaneously stick together

and move right. Find the velocity of combined

system just after collision.

(A) 2 m/s

(B) 3 m/s C D

(C) 4 m/s

(D) 6 m/s

Figure-II

17. All the blocks are attached to an ideal rope which passes over an ideal pulley. If accelerations of

blocks m1, m2, m3, and m4 are a1, a2, a3 and a4 respectively then choose the correct option.

m1 m2 m4

F = 2mg F = 2mg

F = 2mg m3 F = 2mg

m1 = m

m3 = m

m2 = 3m

m4 = 2m

a1 a2 a3 a4

(A) g 2g 3g g/2

(B) g 2g/3 3g g/2

(C) 2g/3 2g 3g g

(D) g g/2 3g 2g/3

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

9 AITS-PT-I-PCM-JEE(Main)/18

suspended through two points which are not in same

horizontal level. Tension in the string at the end points are T1

T1 and T2 and at the lowest point is T3. Mass of string in

terms of T1, T2 and T3 can be represented a {uniform

gravity ‘g’ exists downwards)

T3

T12 T32 T22 T32 T1 T2 2T3

(A) (B)

g g

T12 T22 T12 T32 T22 T32

(C) (D)

g g

free body diagram of the object is shown with the gravitational force

represented by W, the friction force by f, the applied external push

parallel to the incline by F, and the normal force with surface by N. f

Which one of the following choices represents correct relationships

between the forces?

W

(A) N > W and F < f (B) N < W and F > f

(C) N < W and F < f (D) N = W and F > f

frictionless pivot located L/3 from one end. The rod is released from

rest incrementally away from being perfectly vertical, resulting in the

rod rotating clockwise about the pivot. When the rod is horizontal,

what is the magnitude of the tangential acceleration of its center of pivot

mass?

L/3

(A) g/6 (B) g/2

(C) g/4 (D) 2g/3

placed with its curved surface on the smooth horizontal surface

and a string AB of length 4m is attached to point A on its rim as

shown in the figure. Find the tension in the string if hemisphere

A

is in equilibrium.

(A) 320 N (B) 640 N

(C) 180 N (D) 360 N

B

=0

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I-PCM-JEE(Main)/18 10

which itself suspended from an ideal string-pulley system as shown in the

figure. The string AB can bear maximum 900 N. Choose correct

statement.

(A) The man is never ever able to read his correct weight in the spring

balance.

(B) If man is able to manage himself at rest, the spring balance reads his A

true weight.

(C) The maximum magnitude of acceleration, man can manage is 12.5 B

2

m/s while moving upward.

(D) When man moves downward with acceleration 5 m/s2, the spring

balance will read 40 kg.

23. One end of a heavy uniform rod AB can slide along rough C

E

ring

horizontal guiding surface CD with the help of massless ring D

as shown in the figure. The dimension of ring is negligible. BE A

is the ideal string. If EBA is right angle and is the angle

90

between rod AB and horizontal when the rod is on the verge

of sliding. Find the coefficient of friction between ring and

horizontal guiding surface CD. B

tan tan

(A) 2

(B)

2 tan 1 2 tan2

tan tan

(C) (D)

2 tan 1 tan2

upward from rest with acceleration as

shown in a-t graphs. After 15 sec, the a(in m/s )

2

ignites. Choose the INCORRECT 30

statement regarding motion of rocket in

the time interval 0 t 40 s. Motion of 20

rocket

15 20 30 40 t(sec)

O

(A) At t = 15 sec, the speed of rocket is 15 0 m/s.

(B) At t = 20 sec, the speed of rocket is 300 m/s.

(C) In time interval t = 0 sec to t = 15 sec, the distance travelled by rocket is 750 m.

(D) In time interval t = 0 sec to t = 20 sec, the distance travelled by rocket is 1500 m.

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

11 AITS-PT-I-PCM-JEE(Main)/18

25. A particle whose velocity is given as v ˆi 6tjˆ m/s is moving in x-y plane. At t = 0, particle is at

2 2

origin. Find the radius of curvature of path at point m, m

3 3

(A) 1.5 m (B) 3.0 m

(C) 4.5 m (D) 6.0 m

figure and system is released from rest. Choose 2m

correct option.

(A) When mass B moves with speed 4 m/s, the =0

speed of mass A is 1 m/s.

(B) When mass B moves with speed 1 m/s, the

speed of mass A is 4 m/s. g

(C) In the time interval in which the mass A

covers distance 8 m, in the same time m B

interval, mass B travels a distance 1 m.

(D) In the time interval in which the mass A

covers distance 1 m, in the same time

interval, mass B travels a distance 8 m.

8r

a tunnel of width d as shown in the figure. (in the

5

figure, the sphere rolls perpendicular to the plane of the A C

page). The velocity of centre of mass of sphere is v directed

into the plane of the page. The maximum speed of a point

on the sphere is

D

4v 8v

(A) (B)

3 3

6v 3v

(C) (D)

3 2

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I-PCM-JEE(Main)/18 12

placed on frictionless surface. Two blocks of 4m F

masses 4m and m (where m = 10 kg) are placed on Movable

m

the platform. For both blocks, the coefficient of massless

static friction with platform equal to 0.16 and the m stand

coefficient of kinetic friction equal to 0.10. The

blocks are connected by

a light ideal string through a light pulley (mounted at a movable massless stand), which is acted

2

upon by an unknown horizontal force F. If the acceleration of the platform is 2 m/s , find the value

of unknown force F and acceleration of blocks 4m and m on a1 and a2 respectively.

2 2

F(N) a1(m/s ) a2(m/s )

2 2

(A) 180 N 2 m/s 8 m/s

2 2

(B) 180 N 8 m/s 2 m/s

2 2

(C) 90 N 2 m/s 8 m/s

2

(D) 90 N 8 m/s 2 m/s2

A

and rotating about an axis AB, which is perpendicular to rod M

as shown in the figure. The rod has linear mass density that O

varies with the distance x from left end of the rod according x= x

x

x3 B

to 0 3

L

Where unit of 0 is kg/m. What is the value of x so that

moment of inertia of rod about axis AB (IAB) is minimum?

7 2

(A) (B)

15 5

8 4

(C) (D)

15 5

30. Identical constant forces push two identical cars A and B continuously from a starting line to a

finish line. The cars move on a frictionless horizontal surface. If car A is initially at rest and car-B

is initially moving right with speed v 0. Choose the correct statement.

(A) Car-A has the larger change in momentum.

(B) Car-B has the larger change in momentum.

(C) Both cars have the same change in momentum.

(D) Not enough information is given to decide.

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

13 AITS-PT-I-PCM-JEE(Main)/18

Chemistry PART – II

SECTION – A

(One Options Correct Type)

This section contains 30 multiple choice questions. Each question has four choices (A), (B), (C) and

(D), out of which ONLY ONE option is correct.

3/2

1 1

3s

a 3 a0

6 6 2 / 2 ,

2rZ

Where

3ao

What is the maximum radial distance of node from nucleus?

(A)

3 3 a o

(B)

ao

Z Z

(C)

3 3 3 ao (D)

2ao

2 Z Z

32. Calculate the minimum and maximum number of electrons which may have magnetic quantum

1

number, m = +1 and spin quantum number s in chromium(Cr):

2

(A) 0, 1 (B) 1, 2

(C) 4, 6 (D) 2, 3

33. The orbital diagram in which both the Pauli’s exclusion principle and Hund’s rule violated is:

(A) (B)

(C) (D)

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I-PCM-JEE(Main)/18 14

34. Listed in the table are forward and reverse rate constant for the reaction:

2NO g

N2 g O 2 g

1400 1.1 × 10-6

0.29

-5

1500 1.3

1.4 × 10

Select the correct statement:

(A) Reaction is exothermic and value of equilibrium constant (Keq) at 1400 K is 3.79 × 10-6.

(B) Reaction is endothermic and value of equilibrium constant (Keq) at 1400 K is 2.63 × 105.

(C) Reaction is exothermic and value of Keq at 1400 K is 2.63 × 105.

(D) Reaction is endothermic and value of Keq) at 1500 K is 9.28 × 104.

A 2B C

If the total pressure after time t was Pt and after long time t was P then K in terms of Pt,

P and t is

2.303 P 2.303 2P

(A) K log (B) K log

t P Pt t P Pt

2.303 2P

(C) K log (D) None of these

t 3 P Pt

(A) Stoichiometry of a reaction tells about the order of the elementary reactions.

(B) For a zero order reaction, rate and the rate constant are identical.

(C) A zero order is controlled by factors other than concentration of reactants.

(D) A zero order reaction is an elementary reaction.

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

15 AITS-PT-I-PCM-JEE(Main)/18

37. What will be the effect on the equilibrium constant on increasing temperature, if the reaction

neither absorbs heat nor releases heat?

(A) Equilibrium constant will remain constant. (B) Equilibrium constant will decrease

(C) Equilibrium constant will increase. (D) Can not be predicted.

38. The conversion of ozone into oxygen is exothermic under what conditions is ozone is most

stable?

2O3 g

3O2 g

(A) At low pressure and low temperature. (B) At high pressure and high temperature.

(C) At high pressure and low temperature. (D) At low pressure and high temperature.

2A g

2B g C g

At equilibrium 700 ml gaseous mixture contains 100 ml of gas C at 10 atm and 300 K. What is the

value of KP for the reaction?

40 1

(A) (B)

7 28

10 28

(C) (D)

28 10

N2 O 4 g

2NO2 g is 4.5

What would be the average molar mass (in g/mol) of an equilibrium mixture of N2O4 and NO2

formed by the dissociation of pure N2O4 at a total pressure of 2 atm?

(A) 69 (B) 57.5

(C) 80.5 (D) 85.5

41. What is the hydronium ion concentration of a 0.25 M HA solution (Ka = 4 × 10-8)

(A) 10-4 (B) 10-5

-7

(C) 10 (D) 10-10

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I-PCM-JEE(Main)/18 16

42. In a saturated solution of AgCl, NaCl is added gradually. The concentration of Ag+ is plotted

against the concentration of Cl , the graph appears as:

(A) (B)

Ag Ag

Cl Cl

(C) (D)

Ag

Ag

Cl

Cl

43. A solution is 0.01 M KI and 0.1 M KCl. If solid AgNO3 is added to the solution, what is the

I when AgCl begins to precipitate?

K SP AgI 1.5 10 16 ;K SP AgCI 1.8 10 10

(A) 3.5 107 (B) 6.1 10 8

7

(C) 2.2 10 (D) 8.3 108

44. Solubility of AgCl in 0.2 M NaCl is x and that in 0.1 M AgNO3 is y. Then which of the following is

correct?

(A) x = y (B) x > y

(C) x < y (D) we cannot predict

(A) CO 2 CO32 CF2 Cl2 (B) NO2 NO3 NO2

(C) XeF2 XeF4 XeCl4 (D) PH3 AsH3 SbH3

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

17 AITS-PT-I-PCM-JEE(Main)/18

(A) CHF3 (B) ClF3

(C) XeOF4 (D) All of these

(A) s-orbital of another atom produce bond when y is the bond formation axis.

(B) Py - orbital of another produce bond when x is the bond formation axis.

(C) Pz - orbital of another atom produce bond when x is the bond formation axis.

(D) dxy – orbital of another atom produce bond when x is the bond formation axis.

48. The set of d-orbitals which do not contain any d-orbital which is involved in hybridization of central

atom in ICl4

(A) dz2 ,dx2 y2 (B) dx2 y2 ,dxy ,dyz ,dzx

(C) dz2 ,dxy ,dyz ,dzx (D) dxy ,dzx ,dyz

(A) Li Na K (B) Li K Na

(C) Cs Rb K (D) Li Cs K

decompose below 900oC?

(A) BeCO3, MgCO3 (B) SrCO3, BaCO3

(C) BeCO3, BaCO3 (D) MgCO3, SrCO3

(A) KOH > Mg(OH)2 > Al(OH)3 (B) Al(OH)3 > Mg(OH)2 > KOH

(C) Mg(OH)2 > KOH > Al(OH)3 (D) KOH > Al(OH)3 > Mg(OH)2

(A) Be and Mg have [He]2s2 and [Ne]3s2 configuration respectively.

(B) 2s and 3s orbital are filled to their capacity.

(C) Be and Mg are unable to accept electron.

(D) All the above are correct.

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I-PCM-JEE(Main)/18 18

53. Out of N, O, Ne, Na, Na+, select the species which have maximum and minimum ionization

energy

+

(A) Na , Na (B) NO, Na

(C) Na+, O (D) Ne, N

(A) N3 O 2 F Na (B) N3 Na O2 F

(C) Na O2 N3 F (D) O 2 F Na N3

(A) Acidic nature (B) Covalent nature

(C) Ionic nature (D) Vacant orbital

56. H3BO3 is

(A) Mono basic and weak Lewis acid

(B) Mono basic and weak Bronsted acid

(C) Mono basic acid and strong Lewis acid

(D) Tri basic acid and weak Bronsted acid

57. Graphite is a soft solid lubricant extremely difficult to smelt. The reason for this anomalous

behaviour is that graphite:

(A) Has molecules of variable molecular masses like polymer

(B) Has carbon atom arranged in large plated of rings of strongly bonded carbon atoms with

weak interplate bonds

(C) Is a non-crystalline substance

(D) Is an allotropic form of diamond

5H2 O2 xClO 2 2OH xCl yO2 6H2 O

(A) x = 5, y = 2 (B) x = 2, y = 5

(C) x = 4, y = 10 (D) x = 5, y = 5

z

xMnO 4 yC2 O24 2H xMn2 2yCO2 H2O

2

The values of x, y, z in the reaction are respectively:

(A) 2, 5 and 16 (B) 5, 2 and 8

(C) 5, 2 and 16 (D) 2, 5 and 8

60. Metal hydrides are ionic, covalent or molecular in nature. Among LiH, NaH, KH, RbH, CsH the

correct order of increasing ionic character is

(A) LiH > NaH > CsH > KH > RbH (B) LiH < NaH < KH < RbH < CsH

(C) RbH > CsH > NaH > KH > LiH (D) NaH > CsH > RbH > LiH > KH

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

19 AITS-PT-I-PCM-JEE(Main)/18

SECTION – A

(One Options Correct Type)

This section contains 30 multiple choice questions. Each question has four choices (A), (B), (C) and

(D), out of which ONLY ONE option is correct.

2

dy x y 1

61. The solution to the differential equation is

dx xy y 2x 2

(A) e2y/ x cx 4 cx3 y (B) e y/ x cx 3 cx 4 y

2y 2

(C) e x 1 cx 4 cx 2 y (D) none of these

62. Let a continuous function f(x) on R R be defined such that it satisfies the relation

f(x) + f(x + 2y) + 3xy = 2f(2y – x) + 2y2 x, y R. Then which of the following is true

(A) f(x) is an odd function (B) f(x) is one-one

(C) f(x) is into (D) f(x) is invertible

n

1 n 2 n 1 ..... n 1

63. lim 1 is equal to

n

13 23 ..... n3

2

(A) (B) e2

3

1 2

(C) e 2 (D) e 3

64. Which of the following statements is NOT true (where [.] denote the greatest integer function and

{.} denote fractional part function)

(A) {x2} is continuous as well as differentiable at x = 0

(B) [x2] is continuous as well as differentiable at x = 0

(C) x2 is continuous as well as differentiable at x = 0

(D) none of the above

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I-PCM-JEE(Main)/18 20

5 2

d3 x dy d2 y dy d3 y

65. If P then value of ‘P’ is equal to

dy 3 dx 2

dx dx dx 3

(A) 1 (B) 2

(C) 3 (D) none of these

2/5

x 1 x

9 5

66. dx is equal to

5 12/5 1 7/5 1 12/ 5 1 7/5

(A)

12

1 x5

14

1 x5

C (B)

12

1 x5

7

1 x5 C

5 12/5 5 7/5

(C)

12

1 x5

1 x5

7

C (D) none of these

5 3f x f x

67. If f(x) = x(x – 1)(x – 2)(x – 3)(x – 4)(x – 5) then value of 3f x f x dx (where [.] denotes the

0

greatest integer function) is equal to

(A) 10 (B) 15

(C) 6 (D) 9

68. If f(x) = cos( sin2 x) and g(x) = cos( cos2 x) then which of the following statements is true

(A) f(x) is aperiodic

(B) g(x) is aperiodic

(C) f(x) + g(x) is periodic with fundamental period

(D) none of these

k k

n

tan1 n 1

tan1

n and T n

69. Let Sn

n

n n for n N, then which of the following statements is

k 1 k 0

false

ln 4 ln 4

(A) Sn (B) Tn

4 4

(C) lim Sn lim Tn (D) none of these

n n

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

21 AITS-PT-I-PCM-JEE(Main)/18

9

70. Let if f x ai x i be a real valued function, ai R–, where f(x) = 0 has two distinct negative

i0

roots. Then minimum number of distinct real roots of f(x) = 0 are

(A) 3 (B) 2

(C) 9 (D) not enough information

71. Area bounded by curve y = 1 and y in x [0, ] is

2

3 1 3 1

(A) 1 (B)

4 2 4 2

(C) 2 3 (D) 2 1

x

72. Number of points where function f x 1 sin x cos x sgn x 2 is discontinuous is

2

(A) 0 (B) 1

(C) 2 (D) 3

1 1 x2

73. If f x and g x cos ln , then domain of (fog)(x) is

x x ex

(A) (–, 0) (B) (–1, 0)

(C) (–1, 1) (D) (0, 1)

74. The curve for which square of sub tangent varies as subnormal is

(A) (x + 2)2 = y3 (B) (x – 2)3 = y2

2 3

(C) x = (y – 2) (D) x3 = (y + 2)2

75. Let f(x) be a ‘n’ degree polynomial function having ‘n’ real and distinct roots.

If g(x) = f(x) + 100f(x), then minimum number of roots that g(x) must possesses is

(A) n (B) n + 1

(C) n – 1 (D) information is insufficient

(A) e < e (B) 3 > 3

(C) 2e > e2 (D) 10 > 10

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I-PCM-JEE(Main)/18 22

2

4

77. x d ln x is equal to

2

e 8 e 8 64

(A) (B)

4 5

(C) 0 (D) none of these

1 3

78. Area bounded by the curve f x 2

and x-axis between x and

2

x x 2 x 1 2x x 2

5

x is equal to (where [.] denote the greatest integer function and {.} denote fractional part

2

function)

1

(A) (B) 1

2

(C) 2 (D) 4

4 4

(A) 4

0

36 x2 5x dx (B) 2

0

36 x2 5x dx

20

y2 20

y2

2

(C) 4 dy (D) 4 9 36 y dy

5 5

0 0

6x 23 9x 8

80. 2

dx is equal to

x15 x 9 1

9

x 3x 9 2x 3

(A) c (B) c

x15 x9 1 x 15

x9 1

3

x 15

x9 1

2

x15 x6

(C) c (D) none of these

x x9 1

15

x

t

sin x

e dt 1/ x2

81. Which of the following limits vanish? (i) lim (ii) lim 0 2 (iii) lim sin x

x x x

e x x 0

(C) (i), (iii) (D) (i), (ii), (iii)

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

23 AITS-PT-I-PCM-JEE(Main)/18

(A) ~(p q ~r) (B) (p ~q) r

(C) ~(~p q ~r) (D) ~(~p ~q r)

3x2 1

83. x 6 2x 4 2x 3 x2 2x 2 is equal to

x 5 2x 2

(A) 3 c (B) –cot–1(x3 + x + 1) + c

x x 1

x3 x

(C) 2

(D) none of these

x 6 2x 4 2x 3 x 2 2x 2

dy

84. If 2y x 2y x = constant then is equal to

dx

x x

(A) (B)

2 2

4y 4y x 4y 4y2 x 2

x x

(C) (D)

4y 2 4y2 x 2 4y 2 4y 2 x2

85. Consider the functions f(x) = |x|5; g(x) = {cos x}; h(x) = [|sin x|] (where [.] denote the greatest

integer function and {.} denote fractional part function) then which of these functions is

differentiable at x = 0?

(A) f(x) and g(x) (B) g(x) and h(x)

(C) f(x), g(x) and h(x) (D) f(x) and h(x)

86. If the line segment y = 2x, –1 x 1 is rotated about y-axis, then which of the following

statements hold true for the solid so formed

2 4

(A) volume = , surface area = 5 (B) volume = , surface area = 5 2

3 3

2 4

(C) volume = , surface area = 5 (D) volume = , surface area = 2 5

3 3

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I-PCM-JEE(Main)/18 24

87. Let a relation be defined on a set of functions defined on R R such that R = {(f, g)|f – g is an

even function} then, relation R is

(A) reflexive, symmetric (B) reflexive, transitive

(C) symmetric, transitive (D) equivalence relation

1

2

88. If area bound by the curves y eax , y e 8 between x = 0 and x = 1 is minimum, then the value

of ‘a’ is

(A) 1 (B) 2

1

(C) (D) none of these

2

dy dy

89. Order and degree of the differential equation sin 2xy 3 cos respectively are

dx dx

(A) order 1, degree 1 (B) order 1, degree not defined

(C) order 2, degree not defined (D) none of these

90. Let the number of elements in a set A be ‘n’. A set ‘C’ is defined such the

C = {(x, y)| x, y P(A) and x y = }, where P(A) is power set of A, then cardinal number of C is

equal to

(A) 22n (B) 3n

n

(C) 2.3 (D) none of these

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

1 AITS-PT-I-PCM-JEE(Main)/18

FIITJEE JEE(Main)-2018

ANSWERS, HINTS & SOLUTIONS

PART TEST – I

(Main)

ALL INDIA TEST SERIES

1. A 31. C 61. D

2. C 32. D 62. C

3. C 33. D 63. D

4. A 34. C 64. C

5. D 35. C 65. C

6. C 36. D 66. B

7. C 37. A 67. C

8. C 38. B 68. D

9. D 39. C 69. C

10. A 40. B 70. A

11. B 41. A 71. D

12. D 42. C 72. A

13. A 43. D 73. B

14. A 44. C 74. B

15. A 45. C 75. C

16. A 46. D 76. D

17. B 47. D 77. A

18. A 48. D 78. C

19. B 49. A 79. D

20. C 50. A 80. A

21. C 51. A 81. D

22. C 52. D 82. D

23. B 53. A 83. B

24. D 54. A 84. C

25. C 55. D 85. D

26. C 56. A 86. D

27. B 57. B 87. D

28. A 58. B 88. C

29. D 59. A 89. A

30. A 60. B 90. B

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I-PCM-Sol-JEE(Main)/18 2

Physics PART – I

SECTION – A

dx

1. v

dt

dx xdx

dt

v a

t x2

1

dt

0

a xdx

x1

x 22 x12

t

2a

0 0

60

2mv0 = Mv1 …(i)

Newton’s second law : 0

v

M

30

v0 cos 30 = v1 cos 30 + v2 cos 60 m,R vcos30

0

0

v1

3v0 3v1 v 2 …(ii) 30

Before collision After collision

For ‘m’: v0 sin 30 = v2 sin 60 …(iii)

v0 2

v2 , v1 v 0

3 3

2mv 0 2v 0

from (i)

M 3

m 1 M

3

M 3 m

x 2 R 2 L2 2 2 2

6. cos 2xR cos = x + R L

2xR

d dx dx

2R x sin cos 2x

dt dt dt

xv = Rv cos Rx sin

xR sin

v

Rcos x

7. F81 = ma F 1 2 3 4 5 6 7 8

F21 = 7 ma

F21

7

F87

8. Let Wedge is moving rightward with acceleration a and mass m has an acceleration A with

respect to wedge along the surface of the wedge in upward direction, so

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

3 AITS-PT-I-PCM-Sol-JEE(Main)/18

h 1 2h

At 2 A 2 …..( 1)

sin 2 t sin

With the help of FBD of mass m in the frame of wedge, we can write

2h

A a cos gsin 2 acos gsin

t sin

2h 3 5 5 1

a g tan 2 10 2 3 8m / s2

t sin cos 4 3 4 5 5

[W g + W friction]1 = [W g + W friction]2

Since, |f 1| > |f 2| [W ext]1 > [W ext]2

MaR

11. F f = Ma, fR

2

f = F/3

cos 45

R 2R 2

R

2 2

N mg macm, y 2

m CM acm

N mg

2

2 R

2R 2R

2 2

14. F.B.D. of torque

about C is zero’s F

3 F1

Fmax 3mg 0

2 2

Fmax 3mg

B F2 C

3mg

1 K 2

2

mc vc2

2

x f xi2 m0 gd

kxi2 2mc gd

vc

me

mc v c

v sys 2m/s

me mD

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I-PCM-Sol-JEE(Main)/18 4

17. Case I:

T1 = 2mg

ma1 = 2mg T1

a1 = g

Case II:

T2 = mg

3ma2 = 3mg T2

a2 = 2g/3

Case III:

T3 = 4mg

ma3 = T3 mg

a3 = 3g

Case IV:

T4 = mg

2ma4 = 2mg T4

a4 = g/2

T1 sin T2 sin mg

2 2

T T

mg T1 1 3 T2 1 3

T

1 T2

T12 T32 T22 T32

m

g

M2 P

Mg

6 9 Mg

3g

2

g

at

6 4

hemisphere we can write

3R

OC and ON R L 6 m O

8

C

A

AN R2 (R L)2 8 m N

T

3R mg D

T R cos mg sin 0

8 B C

3mg tan 3 64 10 6

T 180 N

8 88

2T = kx

M(g a)

T

3

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

5 AITS-PT-I-PCM-Sol-JEE(Main)/18

2M(g a)

(when moving upward)

kx 2T 3g

Reading of spring balance =

g g 2M(g a) (when moving downward)

3g

three forces only so they must be concurrent. Using

y

Lami’s theorem we can write

L L B

tan and tan

2x x 90

tan tan

tan ( + ) = 2 tan 2 tan A mg

1 tan tan

tan + tan = 2 tan 2tan2 tan

tan

tan

1 2 tan2

2t 2

if 0 t 15 sec

24. v 9

150 30(t 15) if 15 s t 40 s

at t = 15 sec

3 15 15

v 150 m/s

3

2t 3

ĵ if 0 t 15 sec

r 3

150 150(t 15) 15(t 15) ˆj

2

if 15 s t 40 s

at t = 15

2 15 15 15

r 750 m

33

dy d2 y dy

6x , 2

6 2 2

dx dx dx x 2

3

As we know that

3/2

dy 2

1

dx (1 8)3/2

R 4.5 m

d2 y 6

dx2

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I-PCM-Sol-JEE(Main)/18 6

3r 5v

27. v

5 3r

8r 5v 8r 8v

vB

5 3r 5 3 r 3r/5

37

4r/5

Instantaneous

axis of rotation

motion towards rightwards, so friction N2

forces (F1 and F2) will act on both blocks

leftward, hence on the platform rightward,

4m m

so F/2 F/2

F F F 2

a 1 2 2 m/s F mg

m 1

F1 + F2 = 20 N 4mg

F1 64 N1 F2 16 N

Case I: Suppose block of mass 4m has a relative motion with respect to platform

So, F1k = 40 N

F2 = 20 N (not possible)

Case II: Suppose block of mass m has a relative motion with respect to platform, so

F2k = 10 N F1s = 10 N (possible)

F F

F1s 4m 2 1) 4 10 2 90

2 2

F

F = 180 N F2k ma 90 10 = 10a a = 8 m/s2

2

x

0

IAB y 2 dm

3 2

(y x) y dy

3 x

(y x)4 1

(y x)3 y 2 dy y 2 y(y x)4 dy

4 2

y 2 (y x)2 y 1

= (y x)5 (y x)5 dy

4 10 10

y 2 (y x)2 y(x y)5 (y x)2

4 10 60

( x)

(L x)2 ( )4 ( x)5 6

y 2 (y x)3 dx

4 10 60

x0

( x)2 1 1 3 ( x)2 1 1 2

IAB 0 ( x)2 0 ( x)

4 10 60 4 10 60

dIAB ( x) 4

0 0 5 5x 5x = 4 x =

dx 2 10 5

Second Method:

As we know that moment of inertia is minimum among all set of parallel axis, if axis is passing

through centre of mass, so x must be distance of centre of mass.

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

7 AITS-PT-I-PCM-Sol-JEE(Main)/18

L

1

x CM

M

xdm 0

….(i)

0 0 0 0 2

M dm x 3 dx , and xdx x 4 dx

3 0

4

0

3 0

5

4

Putting these values in equation (i) we have x cm

5

Third Method:

From given function it is clear that centre of

mass of system must be at distance grater

8

than /2. We have only two option, and

15

4

. For graph it is clear that maximum mass

5 O x= x

existence is nearer to other end, so it can’t be

8 4

, so right answer will be .

15 5

30. Time taken by Car-A to reach the finish line is greater than that of Car-B, So

tA tB

Fdt Fdt p

0 0

A pB

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I-PCM-Sol-JEE(Main)/18 8

Chemistry PART – II

SECTION – A

31. 3s 0

6 6 2 0

6 36 4 1 6

21

6 12

2

62 3

2

3 3 or 3 3

2rZ

3 3

3ao

3 a

r

2

3 3 o

Z

32. Cr 1s2 2s2 2p6 3s2 3p6 4s13d5

For p 1

m = +1, 0, -1

1

For 2p of 3p there are 2e with s

2

For d 2

1 1

m = +1 may have e with or

2 2

So minimum 2 and maximum 3.

33.

Same value of spin quantum number.

0.29

34. Keq at 1400 K 0.26 106

1.1 10 6

26 104

1.3

Keq at 1500 K 0.92 105

1.4 105

92 103

Since Keq decreases on increasing temperature. So reaction is exothermic.

A 2B C

35.

t0 PA

tt PA P 2P P

t 0 2PA PA

PA P 2P P Pt

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

9 AITS-PT-I-PCM-Sol-JEE(Main)/18

PA 2P Pt

2PA PA P

P

PA

3

P

2P Pt

3

P 1

P Pt

3 2

PA P

Kt n n

PA P P P P

3 t

3 2 6

P

Kt n

2P 3Pt P

3

6

2P

Kt n

3P 3Pt

2.303 2 P

K log

t 3 P Pt

K2 H 1 1

37. log

K1 R 2.303 T1 T2

If H 0

Then K 2 K1

Means no effect.

38. For exothermic reaction high temperature favour backward reaction and with increase in pressure

reaction goes where number of moles are less.

39.

2A g

2B g C g

v

v 2v 2v v

v 100

v 2v 2v v 700

v 600

2A g

2B g C g

400 200 100

400 200 100

10 10 10

700 700 700

40 20 10

7 7 7

2

20 10

20 20 10 10

7 7

KP 2

40 40 40 7 28

7

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I-PCM-Sol-JEE(Main)/18 10

40.

N2 O 4 g

2NO2 g is 4.5

P

P P 2P

P P 2P 2

P P 2

4P2 2

4.5

P 1

4P 2

4.5

1

4.5 1 4P2

4.5 1

P

4 2

P 1 2

4.5 1 1

2

4 2

4.5 1 2 8 2

4.5 4.5 2 8 2

4.5 12.5 2

4.5

12.5

0.6

M EMM

EMM n 1

92 EMM

0.6

EMM 2 1

0.6EMM 92 EMM

1.6EMM 92

92

EMM

1.6

= 57.5

41.

HA H A

0.25

0.25 x x x

0.25

x2

4 10 8

0.25

25

x2 4 108

100

x 104

x H 10 4

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

11 AITS-PT-I-PCM-Sol-JEE(Main)/18

K 1.8 10 10 10

Ag spAgCl

Cl 0.1

Ag 1.8 10 9

K spAgI Ag I

1.5 10 16 1.8 10 9 I

1.5 10 16

I 0.833 107

1.8 10 9

8.3 10 8

46. Fact

47. y y

Py

x x

52. Conceptual.

53. Na+ have maximum ionization energy because of noble gas configuration and Na have lowest

ionization energy because electron have to remove from 3rd shell.

56. Fact.

2Cl 5O2 6H2 O

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I-PCM-Sol-JEE(Main)/18 12

SECTION – A

61. Use substitution

x–1X

y+2Y

To make it homogenous differential equation

2

dY X Y

dX XY

Y = vX

dv 1 2v

X

dX v

1 1

v ln 1 2v = ln|X| + c

2 22

x

62. x = 0, y

2

x2

f(x) + f(0) = 2f(x) +

2

x2

f(0) – = f(x)

2

f(x) is into, many-one, non-invertible

r n r 1 2

1/21/3 2

n2 n 1 /4

63. lim 1 2

= e = e 1/ 4 e3

2

n n 1 / 4

n

2

(a) {x2} (b) [x2] (c) x

1

–1 0 1 –1 0 1

–1 0 1

d2 y

2 1

d x d 1 dx d dy 2

65. 2

= dx 3

dy dy dy dy dx dx dy

dx dx

3 3 4 5 2 2

d3 x d d2 x dx d d2 y dy d y dy dy d y

. = 3 2

dy 3 dy dy 2 dy dx dx 2 dx dx3 dx dx dx

2

d3 x dy 5 d2 y dy d3 y

3 3 2

dy dx dx dx dx3

x

9

66. x4 x 4 1 x5 dx = x 4 x5 1 dx x 4 1 x 5 dx

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

13 AITS-PT-I-PCM-Sol-JEE(Main)/18

12/5 7/5

1 x 5

1 x 5

C

12 7

3f x f x 0 if f x 0

67.

3f x f x 2 if f x 0

1 3 5

2dx 2dx 2dx 6

0 2 4

68.

f x cos sin2 x f x

g x cos cos 2

x g x

h x f x g x 2cos .cos cos 2 x 0

2

h(x) periodic without any fundamental period

T n < Sn

1

ln 4

lim Sn lim Tn tan1 xdx

n n

0

4

ln 4 ln 4

Sn ,Tn

4 4

sin x cos x sin x cos x cos x x 0,

1

4

71.

2 sin x

x ,

4

/4 /2

Required Area = 1 cos x dx 1 sin x dx 2 1 /4 /2

0 /4

=– 2 –1

x

72. Sgn x2 is discontinuous at x = 0 and x = and (1 – sin x – cos x) 0

2 2

As x 0 and x . So f(x) is continuous x.

2

Range of g(x) = [–1, 1]

Domain of (fog) (x) = (–1, 0)

2

y y2

74. ym 2 kym

m m

y

y = 0 or m3

k

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I-PCM-Sol-JEE(Main)/18 14

dy dx 3 2/3 x

1/3

1/3

y 1/3 C

y k 2 k

2 3

y 2 1/3 x Ck 1/3

3k

2

If = 1 and Ck1/3 = –2

3k1/3

y2 = (x – 2)3

C1' x e100x g x

If C' x 0 g(x) = 0

If f(x) has roots 1, 2, ....., n then applying Rolle’s theorem in (1, 2), (2, 3) ..... (n – 1, n), we

get g(x) has atleast n – 1 roots

c/x

76. Let f(x) = x where c is a constant then f(x) has maxima at x = e

e

(a) use function f(x) = x x f(e) > f() e > e

3

(b) f(x) = x x f(3) > f() 3 > 3

2e

(c) f(x) = xx f(e) > f(2) e2 > 2e

10

(d) f(x) = x x f() > f(10) 10 > 10

2

4

77. x d ln x

2

Let ln x = t d (ln x) = dt

2 2

4t

4t e e8 e 8

e dt 4

4

2 2

1

78. f(x) = –1

2

x 1

5/2 1

1

f x dx 4 2

dx

3/2 0 x 1

O 1

1 1 –3/2 –1 2 5/2

1 1

= 4 dx = 4 =2

0 1 x 2 1 x 0

20

2 y2

Where x 36 y dy

5 x

0

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

15 AITS-PT-I-PCM-Sol-JEE(Main)/18

6x 23 9x8 6x 5 9x 10

80. 2

dx 2

dx

x 15

x9 1 x 6

1 x 9

1 x9

C C

x 6 x 9 1 x15 x 9 1

sin x

81. lim 0

x x

x

lim e t dt 0

x

0

2

0

ex

1/x 2

lim sin x 0

x

3x 2

1 dx

83. 2

tan1 x3 x 1 C = –cot (x + x – 1) + C

–1 3

x x 1

3

1

84. 2y x 2y x C

2y 1 2y 1

0

2 2y x 2y x

Rearrange and rationalize to get

x

y

4y 2 4y 2 x 2

85. Shown in the figure f(x) = |x|5 f(x) = {cos x} h(x) = [|sin x|]

O

– /2 O /2 – /2 O /2

2

86. V=2 rh

3 5

2

4

= 2. . 1. 2 = 1

3 3

S = 2 rl

=2 5

87. Reflexive f R, f – f = 0 R

(f, f) R

Symmetric (f, g) R

f – g is even

g – f is even

(g, f) R

Transitive (f, g) R, (g, h) R

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I-PCM-Sol-JEE(Main)/18 16

f – g is even, g – h is even

f – h is even

(f, h) R

So, R is equivalence relation

2

For area to be minimum y e1/8 e

a 1/2

88.

1

a

2

89. sin(y) + 3 cosy = 2xy

10 sin y 2xy

2xy

y sin1

10

90. Number of possible pairs of (x, y) = n C0 2n nC1 2n1 ..... nCn 2nn

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

FIITJEE JEE (Advanced)-2018

PART TEST – I

Paper 1

Pl ea s e r ea d t h e i n s t r u c t i o n s c a r ef u ll y . Yo u a r e a l l o t t ed 5 m i n u t es

s p ec i f i c a ll y f o r t h i s p u r p o s e.

Yo u a r e n o t a l l o wed t o l ea v e t h e E xa m i n at i o n Ha l l b ef o r e t h e en d o f

ALL INDIA TEST SERIES

t h e t es t .

INSTRUCTIONS

A. General Instructions

1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.

2. This question paper contains Three Parts.

3. Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.

4. Each part is further divided into Two sections: Section-A & Section-C

5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be

provided for rough work.

6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic

devices, in any form, are not allowed.

B. Filling of OMR Sheet

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers

on OMR sheet.

2. On the OMR sheet, darken the appropriate bubble with black pen for each character of your

Enrolment No. and write your Name, Test Centre and other details at the designated places.

3. OMR sheet contains alphabets, numerals & special characters for marking answers.

1. Section-A (01– 07, 19 – 25, 37 - 43) contains 21 multiple choice questions which have one or

more than one correct answer. Each question carries +4 marks for correct answer and –2

marks for wrong answer

Partial Marks +1 for each correct option provided no incorrect options is selected.

Section-A (08 – 13, 26 – 31, 44 - 49) contains 18 questions. Each of 2 Tables with 3 Columns

and 4 Rows has three questions. Column 1 will be with 4 rows designated (I), (II), (III) and (IV).

Column 2 will be with 4 rows designated (i), (ii), (iii) and (iv). Column 3 will be with 4 rows

designated (P), (Q), (R) and (S).

Each question has only one correct answer and carries +3 marks for correct answer and –1

mark for wrong answer.

2. Section-C (14 – 18, 32 – 36, 50 - 54) contains 15 Numerical based questions with answer as

numerical value from 0 to 9 and each question carries +3 marks for correct answer. There is no

negative marking.

Enrolment No.

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I (Paper-1)-PCM-JEE(Advanced)/18 2

Useful Data

PHYSICS

Acceleration due to gravity g = 10 m/s2

CHEMISTRY

= 0.0821 Lit atm K1 mol1

= 1.987 2 Cal K1 mol1

Avogadro's Number Na = 6.023 1023

Planck’s constant h = 6.625 1034 Js

= 6.625 10–27 ergs

1 Faraday = 96500 coulomb

1 calorie = 4.2 joule

1 amu = 1.66 10–27 kg

1 eV = 1.6 10–19 J

N=9, Na=11, Mg=12, Si=14, Al=13, P=15, S=16,

Cl=17, Ar=18, K =19, Ca=20, Cr=24, Mn=25,

Fe=26, Co=27, Ni=28, Cu = 29, Zn=30, As=33,

Br=35, Ag=47, Sn=50, I=53, Xe=54, Ba=56,

Pb=82, U=92.

Atomic masses: H=1, He=4, Li=7, Be=9, B=11, C=12, N=14, O=16,

F=19, Na=23, Mg=24, Al = 27, Si=28, P=31, S=32,

Cl=35.5, K=39, Ca=40, Cr=52, Mn=55, Fe=56, Co=59,

Ni=58.7, Cu=63.5, Zn=65.4, As=75, Br=80, Ag=108,

Sn=118.7, I=127, Xe=131, Ba=137, Pb=207, U=238.

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

3 AITS-PT-I (Paper-1)-PCM-JEE(Advanced)/18

Physics PART – I

SECTION – A

(One or More than one correct type)

This section contains 7 questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR

MORE THAN ONE of these four options is(are) correct.

are rigidly fixed to the ends of a thin shaft S, which is B

supported in horizontal position with the help of two A

S

smooth bearings at points P1 and P2. Two blocks of

masses 2 kg and 1 kg are connected to the light cords P2

wrapped around the discs as shown in the figure. There P1

is no slipping between the cord and the discs. If the

P1

system is released from rest from the position shown, 2 kg 1 kg

2

then mark the correct statement(s). (Take g = 10 m/s )

(A) Power developed by tension in cord connected to 2 kg block is, negative.

(B) Acceleration of each block is 2 m/s2.

(C) Total work done by tension on the discs is zero during the motion.

(D) Acceleration of each block is 1 m/s2.

2. A uniform ball of radius R rolls without slipping between the rails such that the horizontal distance

is 3 R between the two contact points of the rails of the ball. Figure (a) shows the front view of

the ball and figure (b) shows the side view of the ball. vCM is the velocity of centre of mass of the

ball and is the angular velocity of the ball after rolling down a distance 2h along the incline then

ball

ball

rail

2h

R R

3 R rail 30

rail

(velocity into the plane)

figure (a) figure (b)

R

(A) v CM R (B) vCM

2

10gh 10gh

(C) v CM (D) v CM

13 7

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I (Paper-1)-PCM-JEE(Advanced)/18 4

3. A worker wishes to pile up sand on to a circular area of radius R. No sand is to spill on to the

surrounding area. If s is the coefficient of static friction between sand particles, then choose the

correct statement(s).

(A) The greatest height of sand pile that can be created is sR.

(B) The greatest height of sand pile that can be created is R/s.

2 4

(C) Minimum work required to create greatest height sand pile is s R g . Where is the

12

density of sand volume.

(D) Sand pile will be in stable equilibrium.

4. A solid spherical ball is released from rest on an incline of inclination angle (which can be

varied) but through a fixed vertical height h. The coefficient of static and kinetic friction are both

equal to . If E represents the total kinetic energy of the ball at the bottom of the incline as a

function of the angle of inclination . W represents the work done by friction for the whole time of

motion as a function of the angle of inclination . Choose the correct graph(s).

(A) E (B) E

/2 /2

(C) W (D) W

/2 /2

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

5 AITS-PT-I (Paper-1)-PCM-JEE(Advanced)/18

respectively placed in a vertical plane. A particle is thrown up in the W3

Multi-storey

vertical plane. Let t1, t2 and t3 are the time taken to cross the window

tower

W 1, W 2 and W 3 respectively and V1, V2 and V3 are the change in W2

speed after respective window cross.

(A) Average speed of the particle passing the windows may be equal W1

if W 1 < W 2 < W 3

(B) Average speed of the particle passing the windows may be equal

if W 1 > W 2 > W 3.

(C) If W 1 = W 2 = W 3, the change in speed of the particle while crossing the windows will satisfy

V1 < V2 < V3.

(D) If W 1 = W 2 = W 3, the time taken by particle to cross the windows will satisfy t1 < t2 < t3.

B A

6. The potential energy function of a particle is given by U(r) , where A and B are

2

2r 3r

constants and r is the radial distance from the centre of the force. Choose the correct option(s).

2A

(A) The equilibrium distance will be r0

B

3A

(B) The equilibrium distance will be r0

B

B2 r

(C) If the total energy of the particle is , then its radial velocity will vanish at 0 , where r0 is

6A 3

the equilibrium distance.

B2 r

(D) If the total energy of the particle is , then its radial velocity will vanish at 0 , where r0 is

6A 2

the equilibrium distance.

7. Velocity of a particle of mass 2 kg changes from v1 2iˆ 2ˆj m/s to v 2 (iˆ ˆj) m/s after colliding

with a smooth plane surface.

1

(A) The angle made by the plane surface with the positive x-axis is 90 + tan1

3

1

(B) The angle made by the plane surface with the positive x-axis is tan1

3

1

(C) The direction of change in momentum makes an angle tan1 with the positive x-axis.

3

1

(D) The direction of charge in momentum makes an angel 90 tan1 with the plane surface.

3

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I (Paper-1)-PCM-JEE(Advanced)/18 6

This section contains SIX questions of matching type. The section contains TWO tables (each having 3

columns and 4 rows). Based on each table, there are THREE questions. Each question has FOUR

options (A), (B), (C), and (D). ONLY ONE of these four options is correct.

Answer questions 8, 9 and 10 by appropriately matching the information given in the three

columns of the following table.

Match the following

(Body) (Axis and reference level) (magnitude of

physical

quantity in S.I.

Unit)

(I) (i) (P) 1

R

axis

Uniform hollow Reference

hemispherical shell of level (U = 0)

M = 3 kg and R = 2 m

(II) (ii) axis (Q) 2

R

Reference

Uniform solid hemisphere

level (U = 0)

of

5

M= kg and R = 3 m

7

(III) (iii) (R) 3

h

axis

Uniform triangular plate of Reference

M = 9 kg and h = 3 m level (U = 0)

Reference

Uniform hollow cone of M = level (U = 0)

2 kg, R = 1m and h = 3 m

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

7 AITS-PT-I (Paper-1)-PCM-JEE(Advanced)/18

8. Distance of centre of mass (in m) of the body (shown in column-1) from the axis (shown in

column-2)

(A) (I) (i) (Q) (B) (II) (ii) (S)

(C) (III) (iii) (P) (D) (IV) (iv) (R)

9. Moment of inertia of body (in kg-m2) (shown in column –1) about the axis (shown in column –2)

(A) (I) (i) (S) (B) (II) (ii) (S)

(C) (III) (iii) (Q) (D) (IV) (iv) (R)

10. (in J-s /m) of the body (shown in

g

column-1) with respect to the reference level (shown in column-2), where g is gravitation

acceleration.

(A) (I) (i) (S) (B) (II)(ii) (R)

(C) (III) (iii) (P) (D) (IV) (iv) (Q)

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I (Paper-1)-PCM-JEE(Advanced)/18 8

Answer questions 11, 12 and 13 by appropriately matching the information given in the

three columns of the following table.

A block of mass m = 15 kg is suspended in an elevator with

Cord 1

the help of three identical light elastic cords (spring constant k

Elevator

= 100 N/m each) attached vertically. One of them, cord 1 is

tied to the ceiling of the elevator and the other two cords 2 and 15 kg

3 are tied to the elevator floor as shown in the figure. When

Cord 2

Cord 3

the elevator is stationary the tension force in each of the lower

cords is T = 7.5 N. Take g = 10 m/s2. Now the elevator starts

moving with given four accelerations shown in column I.

Column II given the displacement of the block with respect to

elevator when it is accelerating. Column III gives tension in the

cords when elevator is accelerating.

Column 1 Column 2 Column 3

(acceleration of the elevator in (displacement of the block (Tension in the cord)

different cases) with respect to the elevator

upto new equilibrium position)

(I) 1 m/s2 upward (i) 7.5 cm downward (P) 2.5 N

(II) 1.5 m/s2 upward (ii) 2.5 cm downward (Q) 5N

(III) 2 m/s2 upward (iii) 15 cm downward (R) 172.5 N

(IV) 33 m/s2 downward (iv) 5 cm downward (S) 0N

(A) (I) (i) (S) (B) (II)(i) (R)

(C) (III) (ii) (P) (D) (IV) (iii) (Q)

(A) (I) (iv) (P) (B) (II)(i) (Q)

(C) (III) (iii) (R) (D) (IV) (ii) (S)

(A) (I) (i) (P) (B) (II)(ii) (P)

(C) (III) (iii) (S) (D) (IV) (iii) (R)

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

9 AITS-PT-I (Paper-1)-PCM-JEE(Advanced)/18

SECTION – C

(Single digit integer type)

This section contains FIVE questions. The answer to each question is a single Digit integer ranging from

0 to 9, both inclusive.

as shown in the figure. The coefficient of friction between the left part

of the ring and left part of the horizontal surface is 1 = 0.6 and

between right half and the surface is 2 = 0.2. At the instant shown, O

now the ring has been imparted an angular velocity in clockwise sense

in the figure shown. At this moment magnitude of acceleration of

2 2

centre O of the ring (in m/s ) is (take g = 10 m/s )

15. A power output from a certain experimental car design to be shaped like a cube is proportional to

the mass m of the car. The force of air friction on the car is proportional to Av 2, where v is the

speed of the car and A is the cross-sectional area. On a level surface the car has a maximum

speed v max. Assume that all versions of this design have the same density. Then v max is

proportional to m1/C . Find C.

16. A solid cylinder rolls from the back of a large truck travelling at 10

m/s to the right. The cylinder is travelling horizontally at 8 m/s to

the left relative to an observer in the truck. The ball lands on the v

roadway 1.25 m below its starting level. How far behind the truck

does it land (in m)?

figure. The pulley is rotating freely about the vertical axis

T

passing through the centre O of the pulley. The vertical axis is

fixed on the horizontal smooth surface. The mass per unit O

length of the drive belt is 1 kg/m and the tension in the drive

belt 8 N. The speed of the drive belt is 2 m/s. Find the net

normal force applied by the belt on the pulley in newton. T

beam of gas particles from both sides as shown in the figure. The v F

solid dots are representing the molecules hitting from left side and the

faint dots are the molecules hitting from right side. The mass of these

gas particles is m = 1026 kg and velocity before hitting is v 0 = 5 m/s.

Volume density of the gas particles on both sides is n = 1025 per m3.

Each beam has an area A = 1 m2 and the collisions are perfectly

elastic. What is the external force F (in newton) required to move the

plate with a constant velocity v = 2 m/s.

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I (Paper-1)-PCM-JEE(Advanced)/18 10

Chemistry PART – II

SECTION – A

(One or More than one correct type)

This section contains 7 questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR

MORE THAN ONE of these four options is(are) correct.

o

19. Pure PCl5(g) was introduced into an evacuated vessel and comes to equilibrium at 247 C and 2

atm pressure. At equilibrium the equilibrium mixture contains 40% by volume of Cl2(g)

PCl5 g

PCl3 g Cl2 g

Which of the following statement(s) regarding the above equilibrium is/are correct?

(A) KP for the equilibrium is 1.6 atm.

(B) KC for the equilibrium is 0.071.

(C) Addition of inert gas to the equilibrium mixture at constant pressure increase the number of

moles of PCl3.

(D) Increase in pressure increases the number of moles of Cl2.

o

20. If 0.53 A is the Bohr’s radius for the 1st orbit of hydrogen atom, the correct statement(s) in the

light of wave mechanical model is/are

o

(A) The product of 2 and 4r 2 increases till it reaches at the distance of 0.53 A .

o

(B) 2 goes on increasing till it reaches at the distance of 0.53 A .

o

(C) goes on decreasing till it reaches at the distance of 0.53 A .

o

(D) The nodal point for the 1s orbital is at 0.53 A .

(A) 2NO2 g 2OH NO2 aq NO3 aq H2 O

(B) P4 s 3OH aq 3H2 O PH3 g 3H2PO2 aq

Cl aq ClO aq H2 O

(C) Cl2 g 2OH aq

(D) CN2 2OH aq CN aq OCN aq H2 O

(A) Calcium carbide on hydrolysis produces acetylene

(B) Calcium carbide when heated with N2 at 1100oC forms calcium cyanamide

(C) Cyanamide ion is isoelectronic with CO2

(D) Beryllium carbide on hydrolysis forms CH4

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

11 AITS-PT-I (Paper-1)-PCM-JEE(Advanced)/18

NO g NO2 g

N2 O3 g K P 1

2NO2 g

N2 O4 g K P2 8 atm

1

Initially only NO(g) and NO2(g) are present in 3 : 5 mole ratio. The total pressure at equilibrium is

5.5 atm and the partial pressure of NO2 at equilibrium is 0.5 atm.

The incorrect statement(s) regarding the above equilibria is/are

(A) K P1 for the equilibrium is 0.4 atm-1.

(B) Partial pressure of N2O4 at equilibrium is 1.6 atm.

(C) Partial pressure of N2O3 at equilibrium is 2 atm.

(D) Partial pressure of NO at equilibrium is 2.5 atm.

(A) The B – F bond length of BF3 is smaller than the B – F bond length of BF4 .

(B) Diborane on hydrolysis forms H3BO3.

(C) Borazine on hydrolysis produces N3H.

(D) In TI3 oxidation state of T is +3.

25. 60 ml of 0.1 M NH4OH is mixed with 40 ml of 0.1 M HCl. Which of the following statement(s)

is/are INCORRECT about the resulting solution/mixture? (Given pK b NH4 OH 4.74 , log2 = 0.3)

(A) The pH of the resulting solution is 5.04.

(B) The resulting solution is a basic buffer.

(C) The pOH of the resulting solution is 9.26.

(D) The resulting solution is acidic due to hydrolysis of NH4Cl.

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I (Paper-1)-PCM-JEE(Advanced)/18 12

This section contains SIX questions of matching type. The section contains TWO tables (each having 3

columns and 4 rows). Based on each table, there are THREE questions. Each question has FOUR

options (A), (B), (C), and (D). ONLY ONE of these four options is correct.

Answer questions 26, 27 and 28 by appropriately matching the information given in the

three columns of the following table.

Columns 1 contains integrated rate equation, Column 2 contains half-life and Column 3

contain graph corresponding to different order reactions, ‘a’ is initial concentration of

reactant and a – x is the concentration at time ‘t’.

Column 1 Column 2 Column 3

(I) 1 1 1 (i) a (P)

k t1/2

tax a 2k t 1/ 2

k t1/2

t k t1/ 2

k log t1/2

t ax ka t1/2

1

a

1 1 1 t1/2

k 2

2 2ka2

2t a x a t 1/ 2

1

a2

26. For the decomposition of HI on the surface of gold the only correct combination is

(A) (III) (ii) (R) (B) (II)(i) (P)

(C) (IV) (i) (P) (D) (I) (iii) (z)

1

27. For the reaction N2 O5 2NO2 O2 , the only correct combination is

2

(A) (III) (ii) (Q) (B) (I)(iii) (P)

(C) (II) (i) (S) (D) (IV) (i) (P)

2

r k A

Which of the following is the only correct combination for the reaction?

(A) (II) (iii) (P) (B) (II)(iii) (S)

(C) (III) (i) (S) (D) (I) (iii) (R)

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

13 AITS-PT-I (Paper-1)-PCM-JEE(Advanced)/18

Answer 29, 30 and 31 by appropriately matching the information given in the three

columns of the following table.

Hybridisation of central atom Shape of molecule/ion No of lone pair in the

central atom

(I) sp2 (i) Linear (P) 0

(II) sp3 (ii) Square pyramidal (Q) 1

(III) sp3d (iii) T-shaped (R) 2

(IV) sp3d2 (iv) See-saw (S) 3

(A) (III) (ii) (Q) (B) (IV)(ii) (Q)

(C) (III) (iv) (P) (D) (IV) (iv) (R)

30. For the ion ICl2 , the only correct combination is

(A) (III) (i) (S) (B) (II)(iii) (Q)

(C) (IV) (iv) (R) (D) (IV) (i) (R)

(A) (IV) (ii) (Q) (B) (IV)(iii) (Q)

(C) (III) (iv) (P) (D) (III) (iii) (R)

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I (Paper-1)-PCM-JEE(Advanced)/18 14

SECTION – C

(Single digit integer type)

This section contains FIVE questions. The answer to each question is a single Digit integer ranging from

0 to 9, both inclusive.

32. 4 mol of a mixture containing one mol each of LiNO3, NaNO3, Ca(NO3)2 and Mg(NO3)2 is

decomposed by strongly heating. The total number of moles of NO2(g) evolved is (assuming

complete decomposition of all the salts)

5

33. The velocity of an electron in the orbit of hydrogen atom is 5.47 × 10 m/sec. Total number of

waves formed by the electron in one complete revolution is

N2 , O2 , B 2 , C2 , CN , NO , CO, H2 , He2

35. 6 ml of 0.1 M CH3COOH when mixed with x ml of 0.1 M NaOH, the pH of the resulting buffer

solution was found to be 5.04. The value of x is (log2 = 0.3) pK a CH3 COOH 4.74 .

A g B g C g

At 300 K, the average molecular weight of the equilibrium mixture is 83 g/mol. If atomic weight of

A, B and C are 100, 60 and 40 gram/mol respectively, then the number of moles of ‘C’ present at

equilibrium in a reaction starting with 10 moles of A is

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

15 AITS-PT-I (Paper-1)-PCM-JEE(Advanced)/18

SECTION – A

(One or More than one correct type)

This section contains 7 questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR

MORE THAN ONE of these four options is(are) correct.

3

37. If is the root of the equation x – tan x = 3 where , ; then which of the following is/are

2 2

correct?, (where [.] denotes the greatest integer function and {.} fractional part function)

max tan x,x min tan x,x

(A) lim 1 (B) lim 1

x

x3 x

x 3

min tan x,x max tan x,x

(C) lim 0 (D) lim 1

x

x3

x

tan x

x x2 1

1

x sin x cos x then (where [.]

4 x4 x2 1 8

denotes the greatest integer function) f is one-one onto

x 3 2x2

(B) let f: R R, such that f x then f is one-one onto

sin x 2

2

x 1

(C) let f: R [1, ) such that f x 2 then f(x) is one-one into

(D) let f: R – {0} R such that f(x) = |x|ln|x| then f(x) is one-one onto

n r 4 r 3n r 2n2 2n4 n 1 4

r r 3n r 2n2 2n4

39. Let Sn n5

and Tn

n5

, n = 1, 2, 3, ..... then

r 1 r 0

167 167

(A) Tn (B) Tn

60 60

167 167

(C) Sn (D) Sn

60 60

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I (Paper-1)-PCM-JEE(Advanced)/18 16

/8

sin 8nx cos 8nx 2 2 1 1 1

(A) dx 1 2 3 ..... n

0

x

1 1

2 1/3 1/ 3

(B) 3 x dx 4x dx

ln3 0 0

/6

8

(C)

sin x 8 3 sin x dx 9

0

/3

1 tan x 1

(D) dx

4 / 4 x 3

dy

3 xy

dx 2y sin2 x 2 y 2

41. The most general solution of the differential equation

dx x 5 is

xy

dy

4 4

1 2 y / x 1 2y / x

(A) cot x 2 y 2

2

4

c 0

2

(B) cot x 2 y 2 4

ec 0

4

1 2y / x 1 2y 3

(C) cot x 2 y 2

2

4

tanc 0 (D)

4

tan x2 y 4

x

c 0

3

42. Let f(x) = 2x3 – 3x2 – x + then which of the following is/are incorrect?

2

7/8

3

(A) f f x dx 4

1/8

3/5

(B) y f x is not differentiable at exactly 1 point

(C) y = [f(x) + ], ( prime number) is discontinuous at 3 points if x [0, 1]

(D) f(f(x)) = 0 has minimum 6 real roots

x sec 2 x tan x sin2x f x

43. If e x tan x dx e g x c then which of the following is/are incorrect?

2

(A) f(0) is equal to = 1

3/2 1 3

(B) number of solution(s) of the equation g x x is 3

2 2

3/2 1 3

(C) number of solution(s) of the equation g x x is 1

2 2

(D) f(x) is an even function

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

17 AITS-PT-I (Paper-1)-PCM-JEE(Advanced)/18

This section contains SIX questions of matching type. The section contains TWO tables (each having 3

columns and 4 rows). Based on each table, there are THREE questions. Each question has FOUR

options (A), (B), (C), and (D). ONLY ONE of these four options is correct.

Answer questions 44, 45 and 46 by appropriately matching the information given in the three

columns of the following table.

Column-1: real valued function; Column-2: continuity of the function; Column-3: differentiability of the

function; Match the following Column(s)

(i) continuous (P) not differentiable

(I) f(x) = ||x – 6| – |x – 8|| – |x2 – 4| + 3x – |x – 7|3

xR at 3 points

(II) f(x) = (x2 – 9)|x2 + 11x + 24| + sin|x – 7| (ii) discontinuous at a (Q) not differentiable

3/5

+ cos|x – 4| + (x – 1) sin(x – 1) single point only at 4 points

3 /5 3

x 1 2 : x 1

1 (iii) discontinuous at 2 (R) not differentiable

2

(III) f x x cos 1 4x 3 3x : 1 x 1

points at 2 point

5/3

x 1 : 1 x 2

(iv) discontinuous at 3 (S) not differentiable

(IV) f(x) = {sin x}{cos x} + (sin3{x})([x]), x [–1, 2]

points at 5 points

(Where [.] denotes the greatest integer function and {.} fractional part function)

(A) (I) (i) (R) (B) (III) (ii) (R)

(C) (IV) (iv) (P) (D) (I) (i) (Q)

(A) (II) (iii) (S) (B) (III) (i) (P)

(C) (II) (iii) (R) (D) (III) (i) (R)

(A) (I) (i) (S) (B) (IV) (i) (S)

(C) (II) (ii) (S) (D) (II) (ii) (P)

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I (Paper-1)-PCM-JEE(Advanced)/18 18

Answer 47, 48 and 49 by appropriately matching the information given in the three

columns of the following table.

Column-1: real valued function; Column-2: domain of the function; Column-3: range of the function.

Match the following Column(s) (where [.] denotes the greatest integer function and {.} denotes fractional

part function)

3 3 (i) number of (P) set of all non

(I) f1 x log 2

x 1 x 3 integers in the positive

domain of f(x) is 2 integers {1}

4 x2 4 x2 (ii) number of (Q) set of all non

(II) f2 x log sin ln cos ln integers not in the negative

2

1 x 1 x domain of f(x) is 2 integers

x 5 2 (iii) number of (R) set of all

(III) f3 x 2 integers in the positive

x 10x 21 domain of f(x) is 3 integers

(iv) number of 1

1 integers in the (S) 0,

(IV) f4 x

2

domain of f(x) is

1

ln cos x infinite

(A) (I) (iv) (P) (B) (I) (iv) (R)

(C) (II) (ii) (R) (D) (III) (i) (S)

(A) (IV) (i) (P) (B) (III) (ii) (S)

(C) (IV) (i) (Q) (D) (II) (iii) (S)

(A) (II) (iv) (P) (B) (IV) (i) (P)

(C) (II) (i) (P) (D) (IV) (i) (R)

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

19 AITS-PT-I (Paper-1)-PCM-JEE(Advanced)/18

SECTION – C

(Single digit integer type)

This section contains FIVE questions. The answer to each question is a single Digit integer ranging from

0 to 9, both inclusive.

50. If the value of A for which the equation cot3 A + cot2 A |cot A + x| + |cot2 Ax + 1| = 1 has not less

–1 –1 –1

than 6 different solutions which are integers are [cot , ) [cot , cot ], then

2

| + 30() | is equal to _____ (where A (0, ))

51. Let f(x) be a differentiable and g(x) be a twice differentiable function such that |f(x) – 1| 1 and

2 2

f(x) = g(x). If f (3) + g (3) = 20 then number of value(s) of c (0, 4) such that g(c)g(c) > 0 is/are

_____

52. Let f(x) be a non-constant thrice differential function defined on (–, ) such that

x 13 3 x 1 9

f f and f 0 f f 2 f 3 f 0 then the minimum number of

2 2 2 2

2

zeroes of h(x) = (f(x)) + f(x)f(x) in the interval [0, 9] is 2k then k is equal to _____

53. If h R – {0}, two distinct tangents can be drawn from the points (2 + h, 3h – 1) to the curve

a

y = x3 – 6x2 – a + bx then is equal to _____

b

n

k 4 2k 3 k 2 k 1 1

54. Let lim

n

5 2

3n n n 5k

3

then is equal to _____

k 1

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

1 AITS-PT-I (Paper-1)-PCM-JEE(Advanced)/18

FIITJEE JEE(Advanced)-2018

ANSWERS, HINTS & SOLUTIONS

PART TEST – I

PAPER-1

ANSWERS KEY

1. A, B 19. A, C 37. A, B, C, D

ALL INDIA TEST SERIES

2. B, C 20. A, C 38. A, B, C, D

3. A, C 21. A, B, C, D 39. B, C

4. B, C 22. A, B, C, D 40. A, C

5. A, C, D 23. B, C 41. A, C

6. B, C 24. A, B 42. A, B, C

7. A, C 25. A, C, D 43. A, B, D

8. C 26. B 44. C

9. B 27. A 45. D

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I (Paper-1)-PCM (Sol)-JEE(Advanced)/18 2

Physics PART – I

SECTION – A

T2 10 = 1a (for 1 kg block) ….(ii)

2

1 1 1 1 a

T1 T2 (2) (2) (for the shaft + disc system)

2 2 2 2 1/ 2

So, T1 T2 = 2a ….(iii)

After solving these three equation

2

a = 2 m/s

3R2 R

2. vCM R2 (from pure rolling)

4 2

1 1 2

mgh mv 2cm mR 2 2 (from conservation of energy)

2 25

10gh

v CM

13

tan = S = h/R

1 h

work required = R2hg .

3 4 h

The system is in unstable equilibrium.

4. For small angle of inclinations, ball rolls without slipping. So there is no work done by friction. At

some critical angle C, the ball starts slipping. For > C, energy would be lost due to work done

by kinetic friction. But again for ( = /2), friction would be zero.

5. As going up, speed of the particle is decreasing and hence the time taken in crossing the

windows will be t1 < t2 < t3 (If W 1 = W 2 = W 3)

Simultaneously V t

V1 < V2 < V3

For unequal windows t1 = t2 = t3 may be if W 3 < W 2 < W1

dU A B

6. F 3 2

dr r 3r

3A

For equilibrium F = 0, r =

B

B2 A B r

(for r0 )

6A 2r02 3r0 3

7. P 2(iˆ ˆj) 2( 2iˆ 2ˆj)

= 6iˆ 2ˆj kg-m/s

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

3 AITS-PT-I (Paper-1)-PCM (Sol)-JEE(Advanced)/18

1

So, P makes angle tan1 with positive x-axis which is also the direction of normal force

3

1

exerted on the ball. So the plane surface makes an angle tan1 with positive x-axis.

2 3

h

8. Center of mass of a triangular uniform plate from its base is 1m

3

2 7 7 5 2

9. Iaxis = MR2 MR2 MR2 9 9 kg-m

5 5 5 7

U 3

10. MhCM (2) 2 m

g 3

11. For elevator acceleration 1.5 m/s2, tension in cord 2 and cord 3 is zero

So, T1 150 = (15) (1.5)

Tension in cord 1, T1 = 172.5 N

12. For elevator acceleration 1 m/s2, tension in cord 2 and cord 3 decreases.

So, 165 + T 2 (7.5 T) 150 = (15) (1)

T = 5 N

Tension in cord 2, T2 = 2.5 N

13. For elevator acceleration 2 m/s2, tension in cord 2 and cord 3 is zero.

So, T1 150 = (15) (2)

Tension in cord 1, T1 = 180 N

So, displacement of block = 15 cm downward.

SECTION – C

2Rdg

/2

14.

0

2 (1 2 )Rg cos d 2(1 2 )R g

d d

2( 1 2 )R g 1Rdg

a 4 O R

2R

15. At vmax

2 km

Av max F (where k is a proportionalty constant)

v max

m

m2/3 v max

2

v max

1/9

vmax m

1

16. 1.25 = (10)t 2

2

t = 0.5 sec

Distance of the cylinder from the truck = 8 0.5 = 4 m

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I (Paper-1)-PCM (Sol)-JEE(Advanced)/18 4

d v2

17. 2T sin dN Rd ( is linear mass density of belt)

2 R

2

Td dN = v d O

2 2 2

T

so total normal = dNcos T cos d v 2 cos d

d

2 2 2

N = 8 newton dN T

= 0.2 40 = 8 N

Chemistry PART – II

SECTION – A

19. Vn

40

PPCl3 PCl2 2 0.8 atm

100

0.8 0.8

KP 1.6 atm

0.40

KP 1.6

KC n

0.037

RT 0.0821 520

Increase in pressure increases the number of moles PCl5(g).

20.

1s 1s

2

r r

1s

4 r 2 2

o

0.53 A

r

CaC2 N2 Ca NCN C

Be2 C 4H2 O 2Be OH 2 CH4

Cyanamide ion [N = C = N]2- is isoelectronic with CO2.

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

5 AITS-PT-I (Paper-1)-PCM (Sol)-JEE(Advanced)/18

NO g NO2 g

N2 O3 g

23. 3P 5P 0

3P x 5P x 2y x

2NO2 g N2 O4 g

5P x 2y y

PN2 O4 PN2 O4

KP2 2

, 8 2

P NO2

0.5

PN2O4 2 atm

y 2 atm

Ptotal PNO PNO2 PN2O3 PN2O4

5.5 3P x 0.5 x 2

3P = 3, P = 1

5P – x – 2y = 0.5

5 × 1 – x – 2 × 2 = 0.5, x = 0.5 atm.

PN2 O3

K P1

PNO PNO2

0.5

0.4 atm

2.5 0.5

PNO 2.5 atm PNO2 0.5 atm PN2O3 0.5 atm,PN2O4 2atm

B3N3H6 9H2O 3NH3 3H3BO3 3H2

In T I3 oxidation state of T is +1.

NH4 Cl H2 O

600.1 6 400.1 4 0

2 0 4

The resulting solution is a basic buffer.

NH4

pOH pK b log

NH4OH

4

pOH 4.74 log 5.04

2

pH 14 5.04 8.96

st 2.303 a

27. For a 1 order reaction k log .

t ax

nd 1 1 1

28. For 2 order reaction k .

t a x a

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I (Paper-1)-PCM (Sol)-JEE(Advanced)/18 6

F

F F

Br

F F

Hybridisation sp3 d2

Shape – square pyramidal

Lone pair in central atom = 1

Cl

ICl2 I

Cl

Hybridisation sp3 d

Shape – Linear

Lone pair in the central atom = 3

XeOF2 Xe O

F

Hybridisation sp3 d

Shape – T-shaped

Lone pair in the central atom = 2

SECTION – C

1

32. 2LiNO3 Li2O 2NO2 O2

2

1 mol of LiNO3 will produce NO2 = 1

2Mg NO3 2

2MgO 4NO2 O2

1 mol of Mg NO3 2 will produce NO2 = 2

2Ca NO3 2

2CaO 4NO2 O2

1 mol of Ca NO3 2 will produce NO2 = 2

2NaNO3 2NaNO2 O2

Total number of moles of NO2 produced = 5

Z

33. V 2.188 10 6 m / sec.

n

2.188 106 1

n 4

5.47 105

According to de-Broglie, total number of waves made by an electron in one complete revolution

=n=4

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

7 AITS-PT-I (Paper-1)-PCM (Sol)-JEE(Advanced)/18

N2 , O2 , B 2 , H2 , He 2

60.10.6 x0.1 0

0.6 0.x 0.x

The resulting solution is a buffer solution.

CH3 COO 0.x

pH pK a log 0.3 log

0.6 0.x

CH3COOH

0.x

0.x log2 log

pH pK a log 0.6 0.x

0.6 0.x

0.x

0.x 2

5.04 4.74 log 0.6 0.x

0.6 0.x x =4

36.

A g

B g C g

10 1 10 10

100 83

D 50, d 41.5

2 2

Dd

d n 1

50 41.5

0.2

41.5 2 1

Number of moles of ‘C’ at equilibrium 10 10 0.2 2

SECTION – A

37. Shown in the figure y-axis

y = {x}

x-axis

0 3 4

3

x x

2 2

1 1

x x

38. (A) x x

2 1

4 x 2 1

x

4 x 1/ x 2 1

1

x

1 x 1

So, 2

8 1 8

4 x 1

x

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I (Paper-1)-PCM (Sol)-JEE(Advanced)/18 8

x x2 1

1

0

4 x 4 x2 1 8

1

So: f x 2x x sin2x injective but not onto

2

(B) f(x) = –x3 cos x + x2 (3 sin x + 2 cos x) + 4x(sin x + 2)

Many one onto

1 n1 r 4 3 2

39. Tn f where f(x) = x + x + x + 2, f(x) is an increasing function for x > 0.

n r 0 n

1 1 n 1

Tn f 0 f ..... f

n n

n

1

167

x

4

Tn x3 x2 2 dx

0

60

1 n r 1 1 r 167

Sn f > f ..... f n = 60

n r 1 n n n

n

sin t cos t

40. (A) Let dt An

0

t

2

1 sin t cos t dt

An sin t cos t dt .....

0

2

1 1 1 1

> 1 ..... sin t cos t dt

2 3

n 0

2 2 1 1 1

> 1 .....

2 3 n

3 sin x 8 3 sin x

(C)

2

3 sin x 8 3 sin x

3 1 4

(D) 1 tan x 3 and

x

3 tan x 4 3

So;

x

3

1 y y

41.

2

cosec 2 x2 y 2 d x 2 y 2 2 d

x x

4

1 2 y / x

cot x 2 y 2

2

4

c 0

7/8

42. I f f x dx ..... (1)

1/8

7/8 7/8

I f f 1 x dx f 1 f x dx ..... (2)

1/8 1/8

3

So, 2I

4

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

9 AITS-PT-I (Paper-1)-PCM (Sol)-JEE(Advanced)/18

2 2

2 sin2x x sec 2 x tan x cos x cos x

43. e

x sec x tan x

x tan x

2

dx = e

2

x sec 2

x tan

x

2

2 cos2 x

= e x sec x tan x c

2

44.-46. (I) f(x) = ||x – 6| – |x – 8|| – |x2 – 4| + 3x – |x – 7|3 is continuous x R and not differentiable at

x = –2, 2, 6, 7 & 8

(II) f(x) = (x2 – 9)|x2 + 11x + 24| + sin|x – 7| + cos|x – 4| + (x – 1)3/5 sin(x – 1) is continuous

x R and not differentiable at x = –8 & 7

3 /5 3

x 1 2 : x 1

1

(III) f x x cos 1 4x 3 3x : 1 x 1 is discontinuous at x = –1 & 1 not differentiable

2

5/3

x 1 : 1 x 2

1

at x = –1, & 1

2

(IV) f(x) = {sin x}{cos x} + (sin3{x})([x]), x [–1, 2]

Let g x sin x x sin2 x

cont. at x I

3

Doubtful points for non differentiability are x = 0, , ,

2 2

{sin x}·{cos x} is discontinuous at x = 0, , 2

2

So not differentiable at x = 2n, 2n +

2

47.-49. (I)

3 1 3 3

x 1 x 3

4

4 x2 4 x2

(II) u sin ln cos ln

1 x 1 x

4 x2

0

1 x

4 x2

ln

1 x

So; 2 u 2

1 1

(III) Let |x + 5| = t; g(t) 0,

2 4

gt

t 2

t 2 t 2

(IV) cos–1 x

– < ln(cos–1 x) ln < 2

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I (Paper-1)-PCM (Sol)-JEE(Advanced)/18 10

SECTION – C

3 2 2

50. Let cot A = a then a + a |a + x| + |a x + 1| = 1

3 2 2 2 2 3

|a + a x| + |a x + 1| = (a x + 1) – (a x + a )

|| + || = –

So, 0 and 0

Now take cases: a –1 and –1 < a 0 & 0 < a 1

1 1

Finally we get, a ( , 5] ,

5 6

51. 0 f(x) 2

and g(3) 2 5, 4 4, 2 5

4 4

Also g x dx f x dx f 4 f 0 2, 2 2 5

0 0

Case-I: Let g(x) > 0 and g(x) > 0 S K

4

4

Clearly g x dx Area MDKS = 4

0 O M D

Which is a contradiction x=3 x=4

Thus, there is no such C

Similarly case-II: Let g(x) < 0 and g(x) < 0

x 13 3x

52. f f 1 7 9 15

2 2 0 2 3 5 6 8 9

2 2 2 2

f(x) = f(8 – x)

f(x) = –f(8 – x)

1 15

f f 0

2 2

f(2) = –f(6) = 0

f(3) = –f(5) = 0

9 7

f f 0

2

2

d

f x f x

f(0) = –f(8); h x

dx

Clearly: h(x) has minimum 18 zeroes

53. y = 0 x = 2 Y

Let P be the point of inflection

So; P (2, 2b – a – 16)

Equation of tangent line passing through inflection

P

Point: y = (b – 12)x – a + 8 .....(1)

Let Q (2 + h, 3h – 1)

Locus of Q: 3x – y = 7 ..... (2)

X

From equation (1) and (2), we get ! x=2

So; a = 15 and b = 15

k 4

2k 3 k 2 k 1 1 1

n

n 5 x 4 dx x 5

54. lim

n

k 1 3n5 n2 n 5k 0

3 3 5 0 15

5

n

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

FIITJEE JEE (Advanced)-2018

PART TEST – I

Paper 2

Pl ea s e r ea d t h e i n s t r u c t i o n s c a r ef u ll y . Yo u a r e a l l o t t ed 5 m i n u t es

s p ec i f i c a ll y f o r t h i s p u r p o s e.

Yo u a r e n o t a l l o wed t o l ea v e t h e E xa m i n at i o n Ha l l b ef o r e t h e en d o f

ALL INDIA TEST SERIES

t h e t es t .

INSTRUCTIONS

A. General Instructions

1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.

2. This question paper contains Three Parts.

3. Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.

4. Each part is further divided into three sections: Section-A, Section-C & Section-D.

5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be

provided for rough work.

6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic

devices, in any form, are not allowed.

B. Filling of OMR Sheet

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers

on OMR sheet.

2. On the OMR sheet, darken the appropriate bubble with black pen for each character of your

Enrolment No. and write your Name, Test Centre and other details at the designated places.

3. OMR sheet contains alphabets, numerals & special characters for marking answers.

1. Section-A (01 – 03, 24 – 26, 47 – 49) contains 9 multiple choice questions which have only one

correct answer. Each question carries +3 marks for correct answer and –1 mark for wrong

answer.

Section-A (04 – 08, 27 – 31, 50 – 54) contains 15 multiple choice questions which have one or

more than one correct answer. Each question carries +4 marks for correct answer and –2

marks for wrong answer.

Partial Marks +1 for each correct option provided no incorrect options is selected.

Section-A (09 – 10, 32 – 33, 55 – 56) contains 3 paragraphs. Based upon paragraph, 2 multiple

choice questions have to be answered. Each question has only one correct answer and carries

+3 marks for correct answer. There is no negative marking.

2. Section-C (11 – 20, 34 – 43, 57 – 66) contains 30 Numerical based questions with answer as

numerical value from 0 to 9 and each question carries +3 marks for correct answer. There is no

negative marking.

3. Section-D (21 – 23, 44 – 46, 67 – 69) contains 9 Numerical answer type questions with answer

XXXXX.XX and each question carries +4 marks for correct answer and –1 mark for wrong

answer.

Enrolment No.

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I (Paper-2)-PCM-JEE(Advanced)/18 2

Useful Data

PHYSICS

Acceleration due to gravity g = 10 m/s2

Planck constant h = 6.6 1034 J-s

Charge of electron e = 1.6 1019 C

Mass of electron me = 9.1 1031 kg

Permittivity of free space 0 = 8.85 1012 C2/N-m2

Density of water water = 103 kg/m3

5 2

Atmospheric pressure Pa = 10 N/m

Gas constant R = 8.314 J K1 mol1

CHEMISTRY

= 0.0821 Lit atm K1 mol1

= 1.987 2 Cal K1 mol1

Avogadro's Number Na = 6.023 1023

Planck’s constant h = 6.625 1034 Js

= 6.625 10–27 ergs

1 Faraday = 96500 coulomb

1 calorie = 4.2 joule

1 amu = 1.66 10–27 kg

1 eV = 1.6 10–19 J

N=9, Na=11, Mg=12, Si=14, Al=13, P=15, S=16,

Cl=17, Ar=18, K =19, Ca=20, Cr=24, Mn=25,

Fe=26, Co=27, Ni=28, Cu = 29, Zn=30, As=33,

Br=35, Ag=47, Sn=50, I=53, Xe=54, Ba=56,

Pb=82, U=92.

Atomic masses: H=1, He=4, Li=7, Be=9, B=11, C=12, N=14, O=16,

F=19, Na=23, Mg=24, Al = 27, Si=28, P=31, S=32,

Cl=35.5, K=39, Ca=40, Cr=52, Mn=55, Fe=56, Co=59,

Ni=58.7, Cu=63.5, Zn=65.4, As=75, Br=80, Ag=108,

Sn=118.7, I=127, Xe=131, Ba=137, Pb=207, U=238.

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

3 AITS-PT-I (Paper-2)-PCM-JEE(Advanced)/18

(SECTION – D)

Numerical answer type questions with answer XXXXX. XX

If answer is 348.4 / 251.37 / 213

Correct Method :

3 4 8 . 4 0

2 5 1 . 3 7

2 1 3 . 0 0

Wrong Method :

3 4 8 . 4

3 4 8 . 4

3 4 8 . 4

3 4 8 . 4

2 5 1 . 3 7

2 1 3 .

2 1 3 . 0

2 1 3 . 0

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I (Paper-2)-PCM-JEE(Advanced)/18 4

Physics PART – I

SECTION – A

(One Options Correct Type)

This section contains 3 multiple choice questions. Each question has four choices (A), (B), (C) and

(D), out of which ONLY ONE option is correct.

released from rest from the top of the wire. It slides without friction

under the influence of gravity to the bottom, where it then leaves the

wire horizontally and falls distance H to the ground. The bead lands R

a horizontal distance D away from where it was launched. Which of

2

the following is correct graph of RH versus D ?

H

ground

D

(A) RH (B) RH

2 2

D D

(C) RH (D) RH

2 2

D D

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

5 AITS-PT-I (Paper-2)-PCM-JEE(Advanced)/18

materials such that part OABO (say part(i)),

B

BCDOB (say part(ii)) and DEFOD (say

part(iii)) has mass 4m, m and m

respectively. Part (i) is a uniform

semicircular plate of radius R/2 and is on C R

the xy plane. Part (ii) and (iii) each is a A

uniform quarter circular plate of radius R on

xy and xz plane respectively. The whole D R

system is free to rotate about y-axis. A

R/2 O x

particle P of mass m moving with velocity R

v0 hits to a point located at the P v0 E

circumference of the part (iii) and sticks to

F

it. The point is at a distance R/2 from x-axis z

as shown in the figure. Angular velocity of

the combined system just after the collision

is

v 2v 0

(A) 0 (B)

4R 5R

3v 0 v

(C) (D) 0

5R 2R

ˆ P

moved with velocity v 0 i under application of an external

force (not shown in figure). Simultaneously a block B of B

x v0

mass m placed on the plank is also moving with velocity z v0

v0kˆ . All these velocities are with respect to ground

frame and at t = 0. Coefficient of friction between the

plank and the block is . Choose the correct option(s).

(A) Kinetic friction force acting on the block, at t = 0 is mgkˆ .

(B) At t = 0, power developed (with respect to ground frame) by kinetic friction force on the block

mgv 0

B is

2

(C) At t = 0, power developed (with respect to ground frame) by kinetic friction force on the block

B is mg 2v 0

(D) At t = 0, heat dissipation per sec in the system is 2 2 mgv0.

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I (Paper-2)-PCM-JEE(Advanced)/18 6

This section contains FIVE questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR

MORE THAN ONE of these four options is(are) correct.

disc of radius R as shown in the figure. The surface between the disc

and rope is rough such that the rope is just in equilibrium. Gravitational

acceleration is g. Choose the correct option(s). R

(A) Coefficient of static friction between rope and disc is = 1.

1

(B) Coefficient of static friction between rope and disc is = .

2

(C) Maximum tension in the rope is at the top most point A of the rope. R B

(D) Maximum tension in the rope is Rg( 2 1) .

P

smooth inclined plane as shown in the figure simultaneously

another particle Q is released on the smooth inclined plane Q

from the same position. P and Q collide after t = 4 seconds.

Then choose the correct Option(s).

(A) Trajectory of particle P in the frame of Q is parabola during

the flight of particle P.

(B) Speed of projection of P is 20 m/s. 60

(C) Relative velocity of Particle P in the frame of Q changes

linearly with time during the flight of P.

(D) Acceleration of particle P in the frame of Q is zero during the flight of P.

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

7 AITS-PT-I (Paper-2)-PCM-JEE(Advanced)/18

6. A disc is free to rotate about an axis passing through its centre and d

perpendicular to its plane. The moment of inertia of the disc about its

u

rotation axis is I. A light ribbon is tightly wrapped over it in multiple

layers. The end of the ribbon is pulled out at a constant speed of u. Let

the radius of the ribboned disc be R at any time and thickness of the

R

ribbon be d(<<R).

1

(A) Angular acceleration of the disc at any instant is proportional to 3 , where R is radius of the

R

ribboned disc.

1

(B) Angular acceleration of the disc at any instant is proportional to 2 , where R is the radius of

R

the ribboned disc.

Iu2 d

(C) Force required to pull the ribbon at constant speed u is F .

2R 4

Iu2d

(D) Force required to pull the ribbon at constant speed u is F = .

R 4

rests on a smooth horizontal plane. The

plank is pulled to right by a constant force

F. If the sphere does not slip over the

plank, then

Plank F

(B) Acceleration of the center of sphere is less than that of the plank.

(C) Work done by friction acting on the sphere is equal to its total kinetic energy.

(D) Total kinetic energy of the system is equal to work done by force F.

x

end is pulled up by an external agent with

constant vertical velocity v. Choose the correct

option(s).

2

(B) Power developed by external agent as a function of x is P = (v + xg)v

(C) Energy lost during the complete lift of the rope is zero.

v 2

(D) Energy lost during the complete lift of the rope is .

2

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I (Paper-2)-PCM-JEE(Advanced)/18 8

(Paragraph Type)

This section contains ONE paragraph. Based on the paragraph, there are TWO questions. Each question

has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct.

A block A of mass m moving with a uniform velocity v 0 strikes another identical block B kept at rest on a

horizontal smooth surface as shown in the figure-(i). We can conserve linear momentum.

v0 vB

A B

v0

Smooth horizontal surface

y

figure-(i)

v0

x vA

figure-(ii)

So, mv0 = mvA + mvB (vA and vB are the velocities of the blocks after collision)

v0 = vA + vB …(i)

If the collision is perfectly elastic

1 1 1

mv 02 mv 2A mv B2

2 2 2

v 20 v 2A vB2 …(ii)

Both the above equations (i) and (ii) are plotted on v A v B plane as shown in figure (ii). This plot can be

used to find the unknowns v A and vB.

For example, the solution of the situation in figure (i) is vA = 0, vB = v0 (point y in the plot)

Because v A = v0, vB = 0 (point x in the plot) is not physically possible.

Now answer the following questions based on the above comprehension.

(A) vB (B) vB

vA vA

(C) vB (D) vB

vA vA

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

9 AITS-PT-I (Paper-2)-PCM-JEE(Advanced)/18

10. In a situation, block A is moving with velocity 2 m/s and strikes vB (m/s)

another identical block B kept at rest. The vA vB plot for the m (2/3, 4/3)

situation is shown. m and are the intersection points whose v A,

vB coordinates are given in the figure. The coefficient of restitution (4/3, 2/3)

of the collision is vA (m/s)

(A) 1/2

(B) 1/3

(C) 1

(D) Collision not possible

SECTION – C

(Single digit integer type)

This section contains TEN questions. The answer to each question is a single Digit integer ranging from 0

to 9, both inclusive.

11. A table has a heavy circular top of radius 1 m and mass 2 kg. It has four light legs of length 1 m

fixed symmetrically on its circumference. Find the maximum mass (in kg) which may be placed

anywhere on this table without toppling it. (take 2 1.4 )

is slowly extracted from the neck of a bottom opened bottle. If the r

normal pressure between the bottle and un-extracted part of the

105

cork at any instant is constant and equal to P N/m2, find the x

work done (in Joule) in extracting it completely. The coefficient of

friction between the cork and bottle is = 0.3.

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I (Paper-2)-PCM-JEE(Advanced)/18 10

13. A bead under the influence of gravity, sides down a frictionless wire O

x

whose y coordinate is changing with x co-ordinate as shown in the figure.

Assume that at position O the wire is vertical and the bead passes this bead

point with a given speed v0 downward. If the shape of the wire is such

that the vertical component of velocity remains v 0 at all time, find

b y

(agv 0 x)c

(a + b + c) in the shape function of wire given by y = , where g

2g

is gravitational acceleration.

on a horizontal table. The width of the block is L = 4 m.

There is an insect A at distance d = 3 m from the block as u

shown in the figure. The insect wants to cross to the Table

opposite side of the table. It begins to crawl at a constant

velocity v at the instant shown in the figure. Find the least L

value of v (in m/s) for which the insect can cross to the

other side without getting hit by the block.

B

d A

(Top view, slightly skewed)

15. A body is projected vertically upwards with a velocity u = 5 m/s. After time t another body is

projected vertically upward from the same point with a velocity v = 3 m/s. If they meet in minimum

k

time duration measured from the projection of first body, then t sec, find k. (where g is

g

gravitation acceleration)

16. A car can pull a trailer of twice its mass up a certain slope at a maximum speed v = 1 m/s.

Without the trailer the maximum speed of the car up the same slope is 2v. The resistance to the

motion is proportional to mass and square of speed. If the car (without trailer) starts to move

down the same slope, with its engine shut off, eventually it will acquire a constant speed v t, then

find v 2t (in m2/s2).

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

11 AITS-PT-I (Paper-2)-PCM-JEE(Advanced)/18

of mass m = 1 kg and connected by a spring. v0

The whole system is placed on a smooth /4

horizontal surface as shown in the figure.

Initially the spring is at its natural length, the ball A B

8

B is imparted a velocity v 0 m/s in the

7

direction shown. The spring constant of the

spring is adjusted so that the length of the spring at maximum elongation is twice that of the

natural length of the spring. Find the maximum potential energy stored (in Joule) in the spring

during the motion.

18. A disc shaped body (having a hole as shown in the figure) of mass

10

m = 10 kg and radius R = m is performing pure rolling motion

9

R/2

on a rough horizontal surface. In the figure point O is geometrical

center of the disc and at this instant the centre of mass C of the C O

disc is at same horizontal level with O. The radius of gyration of the

disc about an axis passing through C and perpendicular to the

R

plane of the disc is and at the instant shown the angular velocity

2

g

of the disc is rad/sec in clockwise sense. g is gravitation

R

acceleration = 10 m/s2. Find angular acceleration (in rad/s2) of the

disc at this instant.

19. A long plank begins to move at t = 0 and accelerates along a straight track with a speed given by

v = 2t2 for 0 t 2 (where v is in m/s and t is in second). After 2 sec the plank continues to move

at the constant speed acquired. A small block initially at rest on the plank begins to slip at

t = 1 sec and stops sliding at t = 3 sec. If the coefficient of static friction and kinetic friction

between the plank and the block is 0.s and 0.k (where s and k are digits) respectively, find s + k.

(take g = 10m/s2)

m A /4

20. Three blocks A, B and C of mass m, and m of different

2 B /2

L/4

densities and dimensions are placed over each other as C

L/2

shown in the figure. The coefficients of friction are shown.

Blocks placed in a vertical line are made to move towards L

right with same velocity at the same instant. Find the time (in sec) taken by the upper block A to

topple from the middle block B. Assume that blocks B and C don’t stop sliding before A topples

2

from B. (given L = 36 m, = 0.4 and g = 10 m/s )

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I (Paper-2)-PCM-JEE(Advanced)/18 12

SECTION – D

(Numerical Based XXXXX.XX answer Type)

This section contains 3 questions. Each question, when worked out will result in numerical answer Type

with answer xxxxx.xx.

21. In the system shown in the figure, a bead of mass m can slide on the

string. There is friction between the bead and the string. Block B has

mass equal to twice that of the bead. The system is released from

rest with length = 18.75 m of the string hanging below the bead.

bead

Assuming the pulley and string to be massless. Find the distance (in

meter) moved by the block B before the bead slips out of the thread. m

= 18.75 m

20 cm as shown in the figure. The stick makes an angle = 37

with the horizontal and is tangent to the disc at its upper end.

Friction exists at all points of contact and assume that it is large

enough to keep the system at rest. Find the friction force (in R

Newton) between the ground and the disc. (take g = 10 m/s2) 37

23. A bead moves along straight horizontal wire of length L, starting from the left end with a velocity

v0. Its retardation is proportional to the distance from the right end of the wire. Find the initial

retardation (in m/s2) (at left end of the wire) if the bead reaches the right end of the wire with a

v

velocity 0 . (given v0 = 5 m/s and L = 1 m)

2

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

13 AITS-PT-I (Paper-2)-PCM-JEE(Advanced)/18

Chemistry PART – II

SECTION – A

(One Options Correct Type)

This section contains 3 multiple choice questions. Each question has four choices (A), (B), (C) and

(D), out of which ONLY ONE option is correct.

M M

24. 10 ml of NH4OH is mixed with 4 ml of H2SO4 solution. The pH of the resulting solution is

10 10

(pKb NH4OH = 4.76), (log2 = 0.3).

(A) 5.36 (B) 8.64

(C) 9.26 (D) 4.74

25. A catalyst lower the activation energy of a reaction from 200 KJ mol-1 to 100 KJ mol-1. The

temperature at which the rate of uncatalysed reaction will be same as the rate of catalysed

reaction at 25o C is (assuming Arrheneous constant A to be same in both the cases)

(A) 50oC (B) 225oC

o

(C) 323 C (D) 596oC

(A) 2B2O3 P4 O10 4BPO 4 (B) BCl3 3H2 O H3BO3 3HCl

180o C

(C) 2BF3 6NaH

2B 6NaF 3H2 (D) B3N3H6 3HCl

B3N3H9 Cl3

This section contains FIVE questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR

MORE THAN ONE of these four options is(are) correct.

(A) In PCl3F2 the P – F bond length is greater than P – Cl bond length.

(B) N – N bond length in N2H4 is greater than N – N bond length in N2F4.

(C) In PCl5 the P – Cl axial bond length is greater than P – Cl equatorial bond length.

(D) In SF6 all S – F bonds have equal bond length.

(A) In aqueous solution Na has stronger reducing character than Li.

(B) LiH is thermally more stable than NaH.

(C) Li2CO3 is thermally more stable than Na2CO3.

(D) KO2 is paramagnetic in nature.

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I (Paper-2)-PCM-JEE(Advanced)/18 14

(A) Sc2Si2O7 (B) MgSiO3

(C) Ca3Si3O9 (D) Zn2SiO4

(A) Borax on strong heating produces a glassy mass of sodium metaborate and boric anhydride.

(B) The formula of borax is Na2[B4O5(OH)2].8H2O.

(C) Aqueous solution of borax is weakly acidic in nature.

(D) The number of B – O – B bonds in borax is 5.

31. Which of the following statement(s) is/are correct for the following equilibrium?

NH4HS s NH3 g H2 S g

(A) Addition of NH4HS(s) at equilibrium increases the concentration of NH3(g).

(B) Addition of NH3(g) at equilibrium decreases the concentration of H2S(g).

(C) KP is independent of the amount of NH4HS(s).

(D) Increase in temperature changes the KP of this reaction.

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

15 AITS-PT-I (Paper-2)-PCM-JEE(Advanced)/18

(Paragraph Type)

This section contains ONE paragraph. Based on the paragraph, there are TWO questions. Each question

has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct.

Solid AgNO3 is gradually added to a solution which is 0.01 M in Cl and 0.01 M in CO23 .

K sp AgCl 1.8 10 10 and K sp Ag2CO3 4 1012 .

+

32. The minimum concentration of Ag required to start the precipitation of Ag2CO3 is

-5 -10

(A) 2 × 10 M (B) 4 × 10 M

-5

(C) 4 × 10 M (D) 2 × 10-10 M

-9 -5

(A) 1.8 × 10 M (B) 1.8 × 10 M

-4 -6

(C) 1.2 × 10 M (D) 9 × 10 M

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I (Paper-2)-PCM-JEE(Advanced)/18 16

SECTION – C

(Single digit integer type)

This section contains TEN questions. The answer to each question is a single Digit integer ranging from 0

to 9, both inclusive.

34. In a hydrogen atom the de-Broglie wavelength of an electron is 1.67 nm. The value of principal

quantum number of the electron is

xCr OH3 yIO3 zOH xCrO42 yI 5H2 O

the sum of the stoichiometric coefficient (x + y + z) is equal to

A g 3B g

4C g

initial concentration of A(g) is equal to that of B(g). The equilibrium concentration of A(g) and C(g)

are equal. Kc for the reaction is

37. A vessel at 1000 K contains CO2(g) at 2 atm pressure. When graphite is added the following

equilibrium is established

CO 2 g C s

2CO g

the total pressure at equilibrium is 3 atm. The value of Kp is

38. The half-lie period for the decomposition of AB2(g) at 100 mm pressure is 10 min and at 200 mm

pressure is 5 min, the order of reaction is

Boron Nitride, Boric acid, Borazole, Borax, Beryllium hydride, Gypsum, Graphite.

40. Total number of solutions from the following which has pH < 7 at 25oC.

K aCH3COOH 1.8 105 , K bNH4OH 1.8 105

(i) 10-8 M HCl

(ii) 0.01 M solution of NH4Cl

(iii) 0.01 M solution of CH3COONa

(iv) 0.01 M solutin of B(OH)3

(v) 0.01 M solution of CH3COONH4

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

17 AITS-PT-I (Paper-2)-PCM-JEE(Advanced)/18

41. 200 ml of 1 M CH3COOH (Ka = 10-6) is mixed with 200 ml of 0.1 M HCOOH (Ka = 10-5). The pH of

the resulting mixture is

CO32 ,NO3 , XeF4 , XeO4 ,SF4 ,I3 ,COCl2 ,SO3 ,ClO3 ,I2Cl6 (solid)

43. How many of the following hydroxides are soluble in excess NaOH solution?

Fe(OH)3, Al(OH)3, Zn(OH)2, Ni(OH)2, Mn(OH)2, Sn(OH)2, Cu(OH)2

SECTION – D

(Numerical Based XXXXX.XX answer Type)

This section contains 3 questions. Each question, when worked out will result in numerical answer Type

with answer xxxxx.xx.

44. The shortest wavelength of transition in Paschen series of He+ ion in nanometer(nm) is

1

91.12nm

RH

45. 4 mole of S2Cl4(g) is introduced into a 10 L vessel. The following equilibrium was establised

S 2 Cl4 g

2SCl2 g

at equilibrium 0.2 mol of S2Cl4 was present in the vessel. The value of equilibrium constant is.

1

46. A weak base MOH was titrated against a strong acid. The pH at th equivalence point was 9.3.

4

3

What will be the pH at th equivalence point in the same titration? (log3 = 0.48)

4

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I (Paper-2)-PCM-JEE(Advanced)/18 18

SECTION – A

(One Options Correct Type)

This section contains 3 multiple choice questions. Each question has four choices (A), (B), (C) and

(D), out of which ONLY ONE option is correct.

1 11

10 2 2 2

x2 x 11

x2 x 10

x2 x 420

47. If 3 dx 3 dx 3 dx then is equal to

20 x 3x 1 1 x 3x 1 21 x 3x 1 7939

21 20

110 110

(A) (B)

939 969

110 120

(C) (D)

739 759

x2 y 2 x2 y 2

(A) y kx 2 e 2 (B) y ky 2 e 2

3x 2 y 2 2

k y xy 2

(C) y 2 e 2 (D) ln 2 ec

x x 4

1

49. If f(x) = k3x + k3 – 2 cuts the curve g(x) = lnx2 at exactly one point then ‘k’ may lie in the interval

2

1 1 1

(A) , e (B) ,

e e e

1 1

(C) 2 , (D) none of these

e e

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

19 AITS-PT-I (Paper-2)-PCM-JEE(Advanced)/18

This section contains FIVE questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR

MORE THAN ONE of these four options is(are) correct.

3y 2 x 15

50. Let y = f(x) be the solution of the differential equation y 2

where y 0 then which

4y 5 4

of the following is/are correct?

27/4

3 15 27

(A) y x

4 4

(B) f x dx 8

15/4

27/4

27

(C) f x dx 8 (D) f(x) 0 x 0

15/4

51. The solution of the differential equation (x2 + 4y2 – 5)xdx = (4x 2 – 3y2 – 1)ydy is

2

2 1

y 2 1 1 y2 1

(A) tan 3 2

ln 6 2 2 ln x2 1 c = 0

3 x 1 4 x 1

2

2 y2 1 1 y2 1

(B) tan1 3 2 ln 6 2 2 ln x 2 1 tanc = 0

3 x 1 4 x 1

2

2 2

x 1 1 2

y 1

(C) tan1 3 2 ln 6 2 2 ln x 2 1 ec = 0

3 y 1 4 x 1

2

2 2

x 1 1 2

x 1

(D) tan1 3 2 ln 6 2 2 ln x 2 1 ec = 0

3 y 1 4 y 2

52. Let functions are defined from set A to set B where B = {, } and & are the roots of the

equation t 2 2 t 0 , then the number of functions which are

(A) discontinuous only at each even integers if A = [0, 11] is 682

(B) discontinuous only at each odd integer if A = [0, 11] is 243

(C) discontinuous only at prime numbers if A = [0, 11] is 81

(D) discontinuous only at x = 5k(k I+) if A = [0, 11] is 27

53. If f(x) is a twice differentiable function and given that f(1) = 2, f(2) = 5 and f(3) = 10 then

(A) f(x) = 2 x (1, 3) (B) f(x) = f(x) = 2 for some x (2, 3)

(C) f(x) = 3 x (2, 3) (D) f(x) = 2 for some x (1, 3)

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I (Paper-2)-PCM-JEE(Advanced)/18 20

0 ; x is irrational

54. Let f x 2 p and f(x)

2q3 q2 q sin2 q 5 ; if x q (rational) where HCF p, q = 1; p, q > 0

is defined x > 0 then which of the following is/are incorrect?

(A) f(x) is continuous at each irrational in (0, )

(B) f(x) is continuous at each rational in (0, )

(C) f(x) is discontinuous at each rational in (0, )

(D) f(x) is discontinuous for all x in (0, )

(Paragraph Type)

This section contains ONE paragraph. Based on the paragraph, there are TWO questions. Each question

has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct.

Read the following write up carefully and answer the following questions:

dy k

Let y = f(x) be the solution of the differential equation x tan x 1 x tan x sin x , where f(0) = 1 and

dx 7

193 1

let k be the minimum value of g(x) where g x max cos y cos y x where y R, then

2 3

7

55. Area bounded by y = f(x) and its inverse between x and x is

2 2

(A) 12 (B) 6

(C) 9 (D) 8

(A) 3 (B) 1

(C) 2 (D) 4

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

21 AITS-PT-I (Paper-2)-PCM-JEE(Advanced)/18

SECTION – C

(Single digit integer type)

This section contains TEN questions. The answer to each question is a single Digit integer ranging from 0

to 9, both inclusive.

x 1 x 2 ; x 1 max f t : x 1 t x : 0 x 2

57. Let f x and g x then number

x ; x 1 x 3 : 2 x3

of points in [0, 3] where g(x) is not differentiable is/are _____

3 6

58. Let Q(x) be a function defined for x [e , e ] be a real valued differentiable function such that

2

Q(e3) = 1 and Q(x) = then maximum value of Q can’t exceed a number

3

x ln ln x e 4

ln x

( N), then minimum value of is _____

xn

1 xn 1 1

59. If lim n

= then is equal to _____

x 1 n 0

1 x

60. If the least area bounded by the curves y = x 2 – 4 and y = x + 12 is equal to , then is

20

equal to _____ (where [.] denotes the greatest integer function)

61. The range of real constant ‘t’ for which (1 – tan2 t)sin 2 + tan2 t·tan 2 2; always holds

0, is [, ) then is equal to _____

2

62. The complete set of non-zero values of ‘k’ such that the equation |x 2 – 7x + 6| = kx is satisfies by

at least one and at most three real value(s) of x is (–, 1 ] [ 2 , ) then 1 2 is equal to

2

_____

x

3

63. Let f be the real valued differentiable function on R such that e x f x 4e x 2t 2 6t 5 dt

e2 2

x R and let g(x) = f –1(x) then [g(3)] + [|g(3)|] is equal to _____ (where [.] denote the greatest

integer function)

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I (Paper-2)-PCM-JEE(Advanced)/18 22

64. Let f(x) = [x] + {x}3 then the area of the figure bounded by y = f –1(x), y = 0 between the ordinates

9 3 1

x = 2 and x is , then 10/3 is equal to _____ (where [.] denotes the greatest integer

2 2 2

function)

x

t8 1

65. Total number of distinct x [0, 1] for which t8 t 2 1 dt 3x 2 is _____

0

66. Let

ex e x

f(x) = ax17 + b sin x·sin 2x·sin3x + cx 2 sgn(sin x) + d log x 1 x2 x x 1 x 1 x

e e

x

be defined on the set of real numbers, (a > 0, b, c, d R) if f(–7) = 7, f(–5) = –5, f(–2) = 3, then

the minimum number of zeroes of the equation f(x) = 0 is equal to _____

SECTION – D

(Numerical Based XXXXX.XX answer Type)

This section contains 3 questions. Each question, when worked out will result in numerical answer Type

with answer xxxxx.xx.

I1 3 1

1 3 1 3 1 0.2

2 2 2 I 2 2

67.

If I1 1 1 x 3

x dx and I2 1 1 x

3

2

x dx , then 2

10

is equal to

0 0

_____

68. If f(x) = 2x3 – 3x2 + 1 then number of distinct real solution(s) of the equation f(f(x)) = 0 is/(are)

7k

k then is equal to _____

102

5

69. Number of points of inflexion on the curve f(x) = (x – 1)7(x + 2)8 is equal to then is equal to

102

_____

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

1 AITS-PT-I (Paper-2)-PCM-JEE(Advanced)/18

FIITJEE JEE(Advanced)-2018

ANSWERS, HINTS & SOLUTIONS

PART TEST – I

PAPER-2

ANSWERS KEY

1. D 24. B 47. B

ALL INDIA TEST SERIES

2. A 25. C 48. A

3. B 26. C 49. A

4. A, D 27. B, C, D 50. A, B, D

5. C 28. A, C 51. A, B

6. A, C 29. A 52. B, C

7. B, C, D 30. A, D 53. D

8. B, D 31. B, C, D 54. B, D

9. B 32. A 55. A

11. 5 34. 5 57. 2

13. 8 36. 8 59. 1

14. 4 37. 4 60. 4

16. 5 39. 4 62. 7

17. 2 40. 3 63. 0

19. 7 42. 7 65. 1

20. 3 43. 3 66. 7

22. 00006.40 45. 28.88 68. 00000.21

23. 00018.75 46. 8.34 69. 00000.15

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I (Paper-2)-PCM (Sol)-JEE(Advanced)/18 2

Physics PART – I

SECTION – A

2H

1. D 2g(2R)

g

2

R

4m 2 2

2 mR mR mR2 2mR2

4 4 2

Conservation of angular momentum along y-axis

R

mv0 2mR2

2

v0

4R

1 ˆ 1 ˆ

3. fk on the block B = mg i k

2 2

ˆi kˆ

Pfk mg ˆ

(v 0k)

2 2

mgv 0

2

dQ 2

mgv0 2mgv 0

dt 2

4. For equilibrium T + dT

2 2

0

Rg cos d Rg sin d

0 d

dN

=1

At the position of maximum tension in the rope

Rdgcos (Rdgsin )

= 45

At any , Rdg

dT Rdgcos Rdgsin

Tmax 4

0

dT Rg (cos sin )d

0

1 1

Tmax Rg sin cos 04 Rg

2

2

1 Rg

2 1

5. Acceleration of particle P and Q along the incline is same.

Acceleration of particle P perpendicular to the incline plane is 10 cos 60 = 5 m/s2

So, v P 5(2) = 0

v P = 10 m/s

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

3 AITS-PT-I (Paper-2)-PCM (Sol)-JEE(Advanced)/18

6. R = u = constant

dR d

R 0

dt dt

d dR

dt R dt

In time dt radius decreases by dR

2RdR = uddt

dR ud

dt 2R

d ud

dt R 2R

u2 d

2 R 3

Iu2 d

2R 3

Iu2 d

F

2R 4

7. For pure rolling motion, static friction would act in the forward direction on the sphere. Work done

by static friction is change in the kinetic energy of the sphere. Work done by static friction on the

complete sphere + Plank system is zero.

v 2

Energy lost in the complete lift = W F K.E. U =

2

9. For perfectly in elastic collision both blocks have same velocity after collision.

4 2

1

10. e 3 3

2 3

SECTION – C

1 R

11. 2g R mg R

2 2

2

m 5 kg

2 1

12.

W 2rxdxP

0

= rP2

105

= (0.3)(3 102) 102 = 9 J

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I (Paper-2)-PCM (Sol)-JEE(Advanced)/18 4

y

and v sin = v0 (as given in question)

bead

v0

sin

v 20 2gy v

y

v0

tan =

2gy

dy v0

dx 2gy

(3gv0 x)2/3

y

2g

a+b+c=8

L D C

14. Time to cross, t =

v cos u

uL

ut = d L tan

v cos u

uL L B

v v

dcos L sin

uL

vmin 4 m/s B

d2 L2

d A

15. If they meet a height h after time T of the projection of the second.

1 1

Then, h = u(T) g(T)2 v(T t) g(T t)2 …(i)

2 2

5t 2 3t

T

10t 2

dT

For minimum T, 0

dt

50t2 20t 6 = 0

6

t = 0.6 =

g

Pmax = (3mg sin + 3kmv 2)v

For car only

Pmax = (mg sin + 4kmv2)2v

(3mg sin + 3kmv2)v = (mg sin + 4kmv2)2v

gsin

k

5v 2

For down the incline kmv 2t = mg sin

v2t = 5v2

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

5 AITS-PT-I (Paper-2)-PCM (Sol)-JEE(Advanced)/18

17. At the starting (with respect to COM frame) At the instant of maximum elongation (with

respect to the COM frame)

v0 v

2 2

v0 v0 2

v

2 2 2 2

v0

2 2

Conservation of angular momentum with respect to centre of mass (COM) frame

v

2m 0 2mv

2 22

v

v 0

4 2

From conservation of energy with respect to centre of mass frame

1 v2 v2 1 v2

2 m 0 0 2 m 0 = Uspring

2 8 8 2 32

2

1 1 7mv 0

Uspring mv 02 = 2 Joule

4 32 32

R R

mg m 2R

2 2

R g R

mg m R mgR C O

2 R 2

2

R

R2 3 mg

IP m m R2 mR

2

N

2 4 2

2mgR 2g 2 P fs

6 rad/s

3mR 2 3R

dv

19. sg at t = 1 sec

dt

s 0.4

At t = 3 sec velocities of plank and block are equal.

2 k g(2) v at t = 3 sec = 8

k 0.3

s+k=4+3=7

A

20. Since , the upper block will move faster than the

4 2 f

middle block and hence force of friction on upper block is

B f

towards left

f

f mg

4

g

aA leftward

4

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I (Paper-2)-PCM (Sol)-JEE(Advanced)/18 6

m 3

f m g mg

2 2 4

aB g (leftward)

3

a A /B g (rightward)

4

3L

For sliding down the block B, A has to move a distance

8

relative to block B.

3L 1 3

gt 2

8 24

L

t 3 sec.

g

SECTION – D

2mg 2T = 2ma2

So, a1 = a2

a1 a2

Relative acceleration of bead with respect to end = 3a

1

displacement of block x = at 2 = 6.25 m

2 3 mg 2mg

22. A = 0 f N

Mg N N

N cos

2

2

For disc, N sin = f + f cos

Nsin Mgsin cos N

f f

1 cos 2(1 cos ) Mg W

R

M = L and L A f

f

tan

2

1

f gR cos

2

1 2 4

8 10

2 10 5

32

6.40 N

5

dv

23. v k(L x) , where k is a constant.

dx v0 v

v 0 /2 L x (L x)

v0

vdv k (L x)dx

0

3

v02 KL2

4

3 v 02 3

So initial retardation = KL = 25 18.75 m/s2

4 L 4

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

7 AITS-PT-I (Paper-2)-PCM (Sol)-JEE(Advanced)/18

Chemistry PART – II

SECTION – A

24. Initial 1 m mol 0.4 m mol 0

0.2m mol 0 0.4 m mol

2 0.4 0.2

NH4 , NH4 OH

14 14

0.8 / 14

pOH pK b log

0.2 / 14

= 4.76 + log4 = 4.76 + 0.6

= 5.36

pH = 14 - 5.36 = 8.64

Ea1 Ea 2

25.

T1 T2

200 100

T1 298

T1 = 596 K = 323oC

o

180 C

26. 2BF3 6NaH B2H6 6NaF

P – F 159.6 pm P – Cl 200.5 pm.

28. (i) Li has stronger reducing character than Na in aqueous solution.

(ii) Li2CO3 is thermally less stable than Na2CO3.

6

29. Pyrosilicates have general formula Si2 O7 .

31. K P PNH3 PH2S

Addition of NH4HS(s) at equilibrium does not change the concentration of NH3(g).

K sp Ag2CO3 4 10 12

32. Ag 2 105 M

2

CO

3

102

33. Cl sp

Ag 2 105

= 9 × 10-6 M.

SECTION – C

2rn

34.

n

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I (Paper-2)-PCM (Sol)-JEE(Advanced)/18 8

n

1.67 10 9 2 3.14 0.529 10 10 n

n 5

x = 2, y = 1, z = 4

x y z 2 1 4 7

36. A g 3B g

4C g

ax a 3x 4x

ax 4x a 5x

[A] = a – x = 5x – x = 4x

[B] = a – 3x = 5x – 3x = 2x

[C] = 4x

4

Kc

C

3

A B

4

4x

3

4x 2x

=8

37. CO 2 g C s

2CO g

2x 2x

2 x 2x 3

x=1

PCO2 2 1 1 atm, PCO 2x 2 1 2 atm

2 2

PCO 2

Kp 4

PCO2 1

n 1

t1/ 2 1 P

38. 2 n–1=1

t1/2 2 P1

n 1

10 200

n=2

5 100

n–1

2=2

-8

40. (i) 10 M HCl

(ii) 0.01 M solution of NH4Cl

(iii) 0.01 M solutin of B(OH)3

200 1

41. CH3 COOH C1 0.5

400

200 0.1

HCOOH C2 0.05

400

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

9 AITS-PT-I (Paper-2)-PCM (Sol)-JEE(Advanced)/18

H K a1 C1 K a2 C2

10 6

0.5 10 5 0.05

-3

= 10

pH = - log 10-3 = 3

CO32 ,NO3 , XeF4 ,I3 ,COCl2 ,SO3 ,I2 Cl6 (solid)

Soluble

Zn OH 2 2NaOH Na2 ZnO2 2H2 O

Soluble

Sn OH2 2NaOH

Na2 SnO 2 2H2 O

Soluble

SECTION – D

1 1 1

4 RH 2 2

min 3

1 4

RH

min 9

9 1

min nm

4 RH

= 205.02 nm

45.

S 2Cl4 g

2SCl2 g

Initial 4 0

At equilibrium 0.2 7.6

0.2 7.6

S 2Cl4 SCl2

10 10

2

Kc

SCl2

S2Cl4

7.6 7.6

10 10

0.2

10

= 28.88

1

46. pOH at th equivalence point = 14 – 9.3 = 4.7

4

1

At th equivalence point

4

pOH pK b log

Salt

Base

0.25x

4.7 pK b log

0.75x

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I (Paper-2)-PCM (Sol)-JEE(Advanced)/18 10

1

4.7 pK b log

3

pK b 4.7 log3

3

At th equivalence point

4

pOH pK b log

Salt

Base

0.75x

pOH 4.7 log3 log

0.25x

pOH 4.7 log3 log3

pOH 4.7 2 log3

pOH 4.7 2 0.48

pOH 5.66

pH = 14 – 5.66 = 8.34

SECTION – A

1 1

47. Put x in I2 and x 1 in I3

1 t t

2

10

x2 x 1 1

We get 3 1 2 dx

20 x 3x 1

x 1 x 2

x3 3x 1 du

Let u then 2

x x 1 u

48.

x4 x4

y

d 2

x xyd xy

y

x2

2

y xy

ln 2 c

x 2

3lnk 2

49. k3

1

1

k3 1

3 P 3 , 3lnk

So, f(k) = k + 3lnk – 1 k

1

f f e 0

e

(–1, –2)

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

11 AITS-PT-I (Paper-2)-PCM (Sol)-JEE(Advanced)/18

2 4x

4y 5 5

3 3 3 1 4x 15

50. y 2

4 2

4y 5 4 4 4y 5 27 9

,

4 4

3

y for 4x – 15 0

4

27/4

1 12 9 15 27

f x dx 2 4 4 x=

4

x=

4

15/4

51.

x 1 4 y 1 x dy

2 2

4 x 1 3 y 1 y dx

2 2

2 2

Let y – 1 = v(x – 1)

6v 2 2 x2 1 dv

4 3v x dx

4 3v x

6v 2 2 dv x 2 1 dx

2

2 y 2 1 1 y2 1

1

tan 3 2

ln 6 2 2 ln x2 1 c = 0

3 x 1 4 x 1

(B) (2 2 – 1)5 1

(C) (2 2 – 1)4 1

(D) (2 2 – 1)2 = 9

g(1) = g(2) = 0

So; g(C1) = 0 for at least one C1 (1, 2)

Similarly g(C2) = 0 for at least one C2 (2, 3)

Using LMVT on x (C1, C2)

g C2 g C1

g(C) = 0

C2 C1

f(C3) = 2

54. Let x 3

f 3 0

3 1.732050807.....

p

As the decimal part increases then in the expression , q becomes very large

q

2

So, 0

2q q q sin2 q 5

3 2

Hence, lim f x 0

x 3

Thus, f(x) is continuous at each irrational

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I (Paper-2)-PCM (Sol)-JEE(Advanced)/18 12

55.-56. 7

193 1 cos y cos y 7

2 3

x 7 ; x0

So; g x

x 7 ; x0

So; g(x)min = 7

So; f(x) = x + cos x

3 /2

55. A 32 x x cos x dx –1

y = f (x)

/2

3 y = f(x)

3 /2

= 3 2 sin x /2 2 2

= –6(–1 – 1) = 12 3

2 2

SECTION – C

x : 0 x 1

57. g x 1 : 1 x 2

x 3 : x 2

e6 e6

2

So, Q x dx x dx

e3 e3

6

Q(e ) 7

1 x n 1 xn x 1

59. 1

1 xn 1 xn

N n xn

x x 1 N xn x 1

So, ln 1

x n

ln 1

n0 1 xn n0

1 x n

n

1 1 1 n x n 1

So, x 1 ..... x

1 x

2

1 x3 1 x2k n0 1 xn

1 1 1

x 1 2

3

..... 2k 1

1 x 1 x 1 x

2

So, limit =

e

4

256

So; Amin = 2 12 x 2 4 dx

0

3

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

13 AITS-PT-I (Paper-2)-PCM (Sol)-JEE(Advanced)/18

2 sin 2

61. tan2 t 0,

2 2

tan sin 2

2 2

sin

So; tan2 t 2 2

0,

tan sin max 2

Since; in 0, : tan 2 > 2 and the same is subtracted from N–r and D–r both

2

So; maximum value occurs at O+

2 1

Therefore tan t ; t ,

3 6 2

7 k 7k 7k y = kx : k > 0

x ,

2 2 2

7 k 2

7 k 7k

Also 7 6 k

4 2 2

k 7 24 , 7 24 (Rejected) 1 6

Similarly: consider case-II if k < 0 then k , 7 24

Second Method

Clearly: m1 < k < k2 m2

For slope of ON

m1

–(x2 – 7x + 6) = kx M

Must have equal roots

For slope of OM

x2 – 7x + 6 = kx N

Must have equal roots

O

63. g(f(x)) = x

So; g(f(x))·f(x) = 1

f x

g f x 3

f x

1 43

So; g 3 and g 3 3

23 5 23

–1 1/3

64. f (x) = [x] + {x}

9/2 9/2

1/3 17 3

So, x dx x dx = 10/3

2 2

2 2

x

t8 1

65. Let f x 8 2

dt 3x 2

0 t t 1

f(0) = 2, f(1) = negative

So; f(x) has one root in [0, 1]

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

AITS-PT-I (Paper-2)-PCM (Sol)-JEE(Advanced)/18 14

So; f(7) = –7, f(5) = 5, f(2) = 3

x –, f(x) –7 –5 –2 02 5 7

x , f(x)

SECTION – D

3

67. Let 1 – x = t

1 3 1 3 1

1 t

2 2

3I1 1 t dt and 3I2 1 dt

0 0

1 3

= 3 1 2 1 t 1 t 1 dt (Using integration by parts)

2 2

3I2 3 1 2 3I 3 1 2 3I

2 1

I1 3 1 3 1 3 1

So, 0.2 1 0.2 1.2

I2 2 2 2 2 2 2

then f(f(x)) = 0 (where f(x) = t)

f(t) = 0 t = , 1

So; total number of distinct real solutions = 2 + 1 = 3

1

f(x) = 0 if x = 1, –2, x1, x2

Clearly: there are 3 inflexion points

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

- CRE Assignment - 1Hochgeladen vonRishikesh
- Exam Set 04Hochgeladen vonallovid
- Statics of Rigid BodiesHochgeladen vonJoanne-chan Mingi
- Assignment1 KineticsHochgeladen vonVishal H
- Easy ProblemsHochgeladen vonChennaiSuperkings
- KineticsHochgeladen vonpaoloasequia
- Equilibrium Constant Report Example 2Hochgeladen vonjim gorman
- 5th- Lesson Overview-Forces and MotionHochgeladen vonlchambless
- PanpsychIsm and Thermodynamics, ExploredHochgeladen vonTed Erikson
- Chemical Equilibrium 2Hochgeladen vonMahesh
- Center1Hochgeladen vonfoster
- Momentum FR Exam ReviewHochgeladen vonIsaiah Everett
- 11 Chemistry NcertSolutions Chapter 7 Exercises 1Hochgeladen vonHarish
- Integer LOMHochgeladen vonAyushBhatt
- 10. Equilibrium and ReversibleHochgeladen vonRosaElizabethValentePereira
- UntitledHochgeladen vonapi-256504985
- gendalll edr318obl2Hochgeladen vonapi-439275227
- 46.docxHochgeladen vonLeanna Peter
- +2 Model q PapersHochgeladen vonSunny Siluvai Pichai
- LampA&B Rekod PrestasiHochgeladen vonAna Hidayah Syuhada
- webassign_102Hochgeladen vonapi-3726069
- Solubility Product Constan1Hochgeladen vonraj
- CHE102FF03PHochgeladen vonDhrumilParikh
- BITSAt 2017 BrochureHochgeladen vonChristopher Brown
- ThermodynamicsHochgeladen vonHumbulani
- U4 Review.docHochgeladen vonmagiclcj
- JSI MID YR T5 2018Hochgeladen vonAisha Chunsha Cassiopeia
- KineticsOverview.pptHochgeladen vonAlbert Daniel Garcia
- Test PhysicsHochgeladen vonShams Shams
- ch04.pdfHochgeladen vonRodrigo Silva Quirino

- S.S SteelsHochgeladen vonSelva Raj
- Akai Apiflo File_461c9a72a4fa6APIFLO M Series BrochureHochgeladen von2009tamer6138
- M-ller Et Al-2008-Macromolecular Reaction EngineeringHochgeladen vonFaisal Sahul Hameed
- Assignment 4Hochgeladen vonShripad Pachpute
- FMHochgeladen vonRuby Smith
- Chiller Maintenance - CopyHochgeladen vonvineeth8624
- The Essential Guide Flow MeasurementHochgeladen vonpertejo157
- Heimo Walter, Bernd Epple (Eds.)-Numerical Simulation of Power Plants and Firing Systems-Springer-Verlag Wien (2017)Hochgeladen vonmolodme380
- Class 22Hochgeladen vonEli S. Alves Jr.
- HANSEN Et Al-1953-Journal of the American Ceramic Society (1)Hochgeladen vonBilly Drees
- NNANO.2011Hochgeladen vonLuca Rebuffi
- FAACHS Series 20 to 104KWHochgeladen vonمحمودجلال
- Literature Review on Retrofitting of Existing Reinforced Concrete Building Using Steel PlateHochgeladen vonjagannath
- Jochen Bartels- Small-x physics and QCD reggeon field theoryHochgeladen vonKlim00
- ArticlesHochgeladen vonMj Makilan
- lab_5Hochgeladen vonKaren Palacios
- Stress Analysis of GRPHochgeladen vonRomner Cordova
- Cold Storage SheetHochgeladen vonamitbslpawar
- S.nelson Physical GeologyHochgeladen vonsatyam mehta
- Act 8 - Growth Inhibition and Death of MicroorganismsHochgeladen vonAnonymous Xlpj86la
- specification 2.pdfHochgeladen vonHsaam Hsaam
- Question for Exam in BUETHochgeladen vonShaibal Ahmed
- York Air Conditioner User Manual for York Eco2 Ypal 060 Air ConditionerHochgeladen vonDanny Valerio
- Weather LectureHochgeladen vonnagtipunan
- diapositivas_full scale test-Dr.ZAVALA.pdfHochgeladen vonOscar Ccama
- inverse heat conductionHochgeladen vonhsemarg
- hw-rotarykiln-8-105-07eHochgeladen vonmareymorsy2822
- ub mae 311Hochgeladen vonDeepak Kumar
- Tugas Makalah Las ListrikHochgeladen vonEniey MuEt MUet
- solar car Innovation ReportHochgeladen vonpankaj

## Viel mehr als nur Dokumente.

Entdecken, was Scribd alles zu bieten hat, inklusive Bücher und Hörbücher von großen Verlagen.

Jederzeit kündbar.