Final JEE - Main Exam April,2019/10-04-2019/Morning Session

FINAL JEE–MAIN EXAMINATION – APRIL,2019

(Held On Wednesday 10th APRIL, 2019) TIME : 9 : 30 AM To 12 : 30 PM
CHEMISTRY TEST PAPER WITH ANSWER
1. The major product of the following reaction is : 3. The correct order of catenation is :
OH (1) C > Si > Ge » Sn (2) C > Sn > Si » Ge
( )
ethyl formate 1equiv. (3) Ge > Sn > Si > C (4) Si > Sn > C > Ge
CH3CHCH2CH2NH2 ¾¾¾¾¾¾¾
triethylamine
®
Official Ans. by NTA (1)
OH 4. The oxoacid of sulphur that does not contain
(1) CH3CHCH 2CH2NHCHO bond between sulphur atoms is :
(2) CH3CH=CH–CH2NH2 (1) H2S 4O6 (2) H2S 2O7
(3) H2S 2O3 (4) H2S 2O4
O
Official Ans. by NTA (2)
O H 5. Consider the statements S1 and S2 :
(3) CH3CHCH2CH2NH2 S1 : Conductivity always increases with
decrease in the concentration of electrolyte.

2.
OH
(4) CH3–CH –CH=CH 2
Official Ans. by NTA (1)
A bacterial infection in an internal wound
EN
grows as N'(t) = N0 exp(t), where the time t is
in hours. A dose of antibiotic, taken orally,
needs 1 hour to reach the wound. Once it
S2 : Molar conductivity always incrteases with
decrease in the concentration of electrolyte.
The correct option among the following is :
(1) Both S1 and S2 are correct
(2) S1 is wrong and S2 is correct
(3) S1 is correct and S2 is wrong
(4) Both S1 and S2 are wrong
Official Ans. by NTA (2)
LL
reaches there, the bacterial population goes
6. Which of the following is a condensation
dN polymer ?
down as = –5N2. What will be the plot of
dt (1) Buna - S (2) Nylon 6, 6
(3) Teflon (4) Neoprene
N0
vs. t after 1 hour ? Official Ans. by NTA (2)
N
7. At 300 K and 1 atmospheric pressure, 10 mL
A

of a hydrocarbon required 55 mL of O 2 for

N0 N0 complete combustion and 40 mL of CO 2 is
N N formed. The formula of the hydrocarbon is :
(1) (2)
(1) C4H8 (2) C4H7Cl
t(h) t(h) (3) C4H10 (4) C4H6
Official Ans. by NTA (4)
8. Ethylamine (C2H5NH2) can be obtained from
N-ethylphthalimide on treatment with :
N0 N0
N N (1) NaBH4 (2) CaH2
(3) (4)
(3) H2O (4) NH2NH2
t(h) t(h) Official Ans. by NTA (4)

Official Ans. by NTA (1)

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Final JEE - Main Exam April,2019/10-04-2019/Morning Session

9. The isoelectronic set of ions is : 13. Major products of the following reaction are :
(1) N3–, Li +, Mg 2+ and O2– CHO
( i ) 50% NaOH
(2) Li+, Na+, O2– and F– + HCHO ¾¾¾¾¾
( ii ) H3O+
®
(3) F–, Li +, Na+ and Mg2+
(4) N3–, O2–, F – and Na+ (1) CH3OH and HCO2H
Official Ans. by NTA (4) CH2OH COOH
10. The species that can have a trans-isomer is : (2) and
(en = ethane-1, 2-diamine, ox = oxalate)
(1) [Pt(en)Cl2] (2) [Cr(en)2(ox)]+ COOH
(3) [Zn(en)Cl 2] (4) [Pt(en)2Cl2]2+ (3) CH3OH and
Official Ans. by NTA (4)
11. Match the refining methods (Column I) with CH2OH
metals (Column II). (4) HCOOH and
Column I Column II
(Refining methods) (Metals) Official Ans. by NTA (4)
(I) Liquation (a) Zr 14. The principle of column chromatography is :
(II) Zone Refining (b) Ni (1) Capillary action.
(III) Mond Process
(IV) Van Arkel Method (d) Ga
EN
(c) Sn

(1) (I) – (b); (II) – (c); (III) – (d); (IV) – (a)

(2) (I) – (b); (II) – (d); (III) – (a); (IV) – (c)
(3) (I) – (c); (II) – (a); (III) – (b); (IV) – (d)
(4) (I) – (c); (II) – (d); (III) – (b); (IV) – (a)
15.
(2) Gravitational force.
(3) Differential adsorption of the substances on
the solid phase.
(4) Differential absorption of the substances on
the solid phase.
Official Ans. by NTA (3)
The major product of the following reaction is :
Official Ans. by NTA (4)
LL
12. Consider the following statements O
(a) The pH of a mixture containing 400 mL of
( )
0.1 M H2SO4 and 400 mL of 0.1 M NaOH ¾¾¾¾
HI excess
D
®
will be approximately 1.3. NC O
(b) Ionic product of water is temperature
dependent.
OH I
A

(c) A monobasic acid with K a = 10 –5 has a

pH = 5. The degree of dissociation of this (1) (2)
acid is 50%. NC I NC OH
(d) The Le Chatelier's principle is not applicable
to common-ion effect. OH I
the correct statement are :
(3) (4)
(1) (a), (b) and (d) (2) (a), (b) and (c)
(3) (a) and (b) (4) (b) and (c) NC OH NC I
Official Ans. by NTA (2) Official Ans. by NTA (3)
16. Amylopectin is composed of :
(1) a-D-glucose, C1–C4 and C1–C6 linkages
(2) a-D-glucose, C1–C4 and C2–C6 linkages
(3) b-D-glucose, C 1–C4 and C2–C6 linkages
(4) b-D-Glucose, C 1–C4 and C1–C6 linkages
Official Ans. by NTA (1)

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 Final JEE - Main Exam April,2019/10-04-2019/Morning Session

17. Consider the hydrates ions of Ti2+, V2+, Ti3+ and 21. Increasing rate of SN1 reaction in the following
Sc 3+ . The correct order of their spin-only compounds is :
magnetic moments is :
I I
(1) Sc3+ < Ti3+ < Ti2+ < V2+ MeO
(2) Ti3+ < Ti2+ < Sc3+ < V2+
(3) Sc3+ < Ti3+ < V2+ < Ti2+
(4) V2+ < Ti2+ < Ti3+ < Sc3+
(A) (B)
Official Ans. by NTA (1)
18. A gas undergoes physical adsorption on a I I
surface and follows the given Freundlich
adsorption isotherm equation
H 3C H3CO
x
= kp0.5 (C) (D)
m
Adsorption of the gas increases with : (1) (A) < (B) < (C) < (D)
(1) Decrease in p and decrease in T (2) (B) < (A) < (D) < (C)
(2) Increase in p and increase in T (3) (B) < (A) < (C) < (D)

19.
(3) Increase in p and decrease in T
(4) Decrease in p and increase in T
Official Ans. by NTA (3)
Three complexes,
[CoCl(NH3)5]2+ (I),
[Co(NH3)5H2O]3+ (II) and
[Co(NH3)6]3+ (III)
EN 22.
(4) (A) < (B) <
Official Ans. by NTA (3)
(D)

Consider the following table :

< (C)

Gas a/(k Pa dm6 mol–1) b/(dm3 mol–1)

A
B
642.32
155.21
0.05196
0.04136
absorb light in the visible region. The correct
LL
C 431.91 0.05196
order of the wavelength of light absorbed by
D 155.21 0.4382
them is :
(1) (III) > (I) > (II) (2) (I) > (II) > (III) a and b are vander waals constant. The correct
(3) (II) > (I) > (III) (4) (III) > (II) > (I) statement about the gases is :
Official Ans. by NTA (2) (1) Gas C will occupy lesser volume than gas A;
–
20. During the change of O2 to O2 , the incoming gas B will be lesser compressible than gas D
A

electron goes to the orbital : (2) Gas C will occupy more volume than gas A;
(1) s* 2P z (2) p 2P y gas B will be lesser compressible than gas D
(3) p* 2P x (4) p 2P x (3) Gas C will occupy more volume than gas A;
Official Ans. by NTA (3) gas B will be more compressible than gas D
(4) Gas C will occupy lesser volume than gas A;
gas B will be more compressible than gas D
Official Ans. by NTA (3)

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Final JEE - Main Exam April,2019/10-04-2019/Morning Session

23. The increasing order of the reactivity of the 28. The major product of the following reaction
following compounds towards electrophilic is :-
aromatic substitution reactions is :- CH3
CH OH
Cl CH3 COCH3 CH3–C–CH CH3 ¾¾¾
3
¾
®
H Br
CH3
(I) (II) (III) (1) CH3–C–CH CH3
(1) I < III < II (2) II < I < III H OCH3
(3) III < I < II (4) III < II < I
Official Ans. by NTA (3) CH3
24. The graph betweeen |y|2 and r(radial distance) (2) CH3–C–CH = CH2
is shown below. This represents :-
H

CH3

|y|
2 (3) CH3–C–CH2CH3

25.
(1) 3s orbital
(3) 2p orbital
Official Ans. by NTA (4)
r
EN
(2) 1s orbital
(4) 2s orbital

At room temperature, a dilute soluton of urea 29.

OCH3

CH 3
(4) CH3–C = CH CH3

Official Ans. by NTA (3)

The regions of the atmosphere, where clouds
is prepared by dissolving 0.60 g of urea in form and where we line respectively, are :-
LL
360 g of water. If the vapour pressure of pure (1) Stratosphere and Troposphere
water at this temperature is 35 mmHg, (2) Troposphere and Stratosphere
lowering of vapour pressure will be (3) Troposphere and Troposphere
(molar mass of urea = 60 g mol–1):- (4) Stratosphere and Stratosphere
(1) 0.027 mmHg (2) 0.028 mmHg Official Ans. by NTA (3)
(3) 0.017 mmHg (4) 0.031 mmHg 30. The alloy used in the construction of aircrafts
A

Official Ans. by NTA (3) is :-

26. The synonym for water gas when used in the (1) Mg – Sn (2) Mg – Mn
production of methanol is :- (3) Mg – Al (4) Mg – Zn
(1) natural gas (2) laughing gas Official Ans. by NTA (3)
(3) syn gas (4) fuel gas
Official Ans. by NTA (3)
27. A process will be spontaneous at all
temperatures if :-
(1) DH > 0 and DS < 0
(2) DH < 0 and DS > 0
(3) DH > 0 and DS > 0
(4) DH < 0 and DS < 0
Official Ans. by NTA (2)