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Final JEE -Main Exam April,2019/10-04-2019/Morning Session   FINAL JEE–MAIN EXAMINATION – APRIL,2019  

Final JEE -Main Exam April,2019/10-04-2019/Morning Session

 

FINAL JEE–MAIN EXAMINATION – APRIL,2019

 

(Held On Wednesday 10 th APRIL, 2019)

TIME : 9 : 30 AM

To 12 : 30 PM

 

CHEMISTRY

 

TEST PAPER WITH ANSWER

 

1. \pm(uirwz(xzwl}k|(wn(|pm(nwttwqvo(zmik|qwv(q{(B

3. \pm(kwzzmk|(wzlmz(wn(ki|mvi|qwv(q{(B

 
 

OH

091(K(F([q(F(Om(»( [v

0:1(K(F([v(F([q(»(Om

CH CHCH CH NH

3

22

2

(

¾¾¾¾¾¾¾®

|zqm|ptiuqvm

m|pt(nwzui|m( 9my}q~6

)

 

0;1(Om(F([v(F([q(F(K

Official Ans. by NTA (1)

0<1([q(F([v(F(K(F(Om

 

OH

4. \pm(w€wikql(wn({}txp}z(|pi|(lwm{(vw|(kwv|iqv

091 CH CHCH CH NHCHO

3

22

 

jwvl(jm|mmv({}txp}z(i|wu{(q{(B

 

0:1 KP ; KPEKPžKP : VP :

091(P : [ < W > 0;1(P : [ : W ;

0:1(P : [ : W ? 0<1(P : [ : W <

 

O

 
    Official Ans. by NTA (2)  
 

Official Ans. by NTA (2)

 

O

H

5. Kwv{qlmz(|pm({|i|mumv|{([9(ivl([:(B

 

0;1 CH CHCH CH NH

3

22

2

[9(B(Kwvl}k|q~q|(iti{(qvkzmi{m{(q|p

 

lmkzmi{m(qv(|pm(kwvkmv|zi|qwv(wn(mtmk|zwt|m6

 

OH

 

[:(B(Uwtiz(kwvl}k|q~q|(iti{(qvkz|mi{m{(q|p

0<1 CH –CH CH=CH

3

lmkzmi{m(qv(|pm(kwvkmv|zi|qwv(wn(mtmk|zwt|m6

2

\pm(kwzzmk|(wx|qwv(iuwvo(|pm(nwttwqvo(q{(B

Official Ans. by NTA (1)

2. I(jik|mzqit(qvnmk|qwv(qv(iv(qv|mzvit(w}vl

ozw{(i{(V/0|1(E(V (m€x0|14(pmzm(|pm(|qum(|(q{

8

091 Jw|p([9(ivl([:(izm(kwzzmk|

0:1 [9(q{(zwvo(ivl([:(q{(kwzzmk|

 

qv(pw}z{6(I(lw{m(wn(iv|qjqw|qk4(|ismv(wzitt4

vmml{(9(pw}z(|w(zmikp(|pm(w}vl6(Wvkm(q|

0;1 [9(q{(kwzzmk|(ivl([:(q{(zwvo

0<1 Jw|p([9(ivl([:(izm(zwvo

zmikpm{(|pmzm4(|pm(jik|mzqit(xwx}ti|qwv(owm{

Official Ans. by NTA (2)

 

6. _pqkp(wn(|pm(nwttwqvo(q{(i(kwvlmv{i|qwv

lwv(i{( lV (E(ž=V

l|

:

6(_pi|(qtt(jm(|pm(xtw|(wn

xwtumz(G

091(J}vi(5([ 0:1(Vtwv(>4(>

 

V

8

 

0;1(\mntwv

0<1(Vmwxzmvm

V

(~{6(|(in|mz(9(pw}z(G

Official Ans. by NTA (2)

 
 

7. I|(;88(S(ivl(9(i|uw{xpmzqk(xzm{{}zm4(98(uT

 
N 0 N
N
0
N

0:1(

N 0 N
N
0
N

wn(i(plzwkizjwv(zmy}qzml(==(uT(wn(W : (nwz

kwuxtm|m(kwuj}{|qwv(ivl(<8(uT(wn(KW : (q{

091(

nwzuml6(\pm(nwzu}ti(wn(|pm(plzwkizjwv(q{(B

091(K P

<

@

0:1(K <

P ? Kt

 
 

t(h)

t(h)

0;1(K < P 98 0<1(K < P >

 

Official Ans. by NTA (4)

 
 
N 0 N
N
0
N

t(h)

0<1(

N 0 N
N
0
N

t(h)

8. M|ptiuqvm(0K : P = VP : 1(kiv(jm(wj|iqvml(nzwu

V5m|ptxp|pitquqlm(wv(|zmi|umv|(q|p(B

 

0;1(

091(ViJP < 0:1(KiP :

0;1(P : W

0<1(VP : VP :

 

Official Ans. by NTA (4)

 

Official Ans. by NTA (1)

   
   

1

Final JEE -Main Exam April,2019/10-04-2019/Morning Session

Final JEE -Main Exam April,2019/10-04-2019/Morning Session 9. \pm(q{wmtmk|zwvqk({m|(wn(qwv{(q{(B 091(V ;ž 4(Tq 3

9. \pm(q{wmtmk|zwvqk({m|(wn(qwv{(q{(B 091(V 4(Tq 3 4(Uo :3 (ivl(W

0:1

 

13. Uirwz(xzwl}k|{(wn(|pm(nwttwqvo(zmik|qwv(izm(B

CHO 3(PKPW ( ) ¾¾¾¾¾® q =8- ViWP

CHO

3(PKPW

(

)

¾¾¾¾¾®

q

=8- ViWP

 

0;1

Tq 3 4(Vi 3 4(W (ivl(N ž N ž 4(Tq 3 4(Vi 3 (ivl(Uo :3 V 4(W 4(N ž (ivl(Vi 3

   

(

qq

)

P

;

W

+

0<1

091

KP

; WP(ivl(PKW : P

Official Ans. by NTA (4)

CH OH

2

Official Ans. by NTA (4) CH OH 2 COOH

COOH

10. \pm({xmkqm{(|pi|(kiv(pi~m(i(|ziv{5q{wumz(q{(B

0:1

10. \pm({xmkqm{(|pi|(kiv(pi~m(i(|ziv{5q{wumz(q{(B 0:1 (ivl(

(ivl(

 

0mv(E(m|pivm594(:5lqiuqvm4(w€(E(w€iti|m1

091(cX|0mv1Kt : e 0:1(cKz0mv1 : 0w€1e 3 0;1(cbv0mv1Kt : e 0<1(cX|0mv1 : Kt : e :3

0;1 KP ; WP(ivl(

0;1 KP ; WP(ivl( COOH

COOH

 

Official Ans. by NTA (4)

   

11. Ui|kp(|pm(zmnqvqvo(um|pwl{(0Kwt}uv(Q1(q|p

 

CH OH

2

 

um|it{(0Kwt}uv(QQ16

 

0<1 PKWWP(ivl(

0<1 PKWWP(ivl(

Kwt}uv(Q

Kwt}uv(QQ

   

0Zmnqvqvo(um|pwl{1

0Um|it{1

 

Official Ans. by NTA (4)

 

0Q1

Tqy}i|qwv

0i1(bz

14. \pm(xzqvkqxtm(wn(kwt}uv(kpzwui|wozixp(q{(B

0QQ1 bwvm(Zmnqvqvo

0j1(Vq

091

Kixqttiz(ik|qwv6

 

0QQQ1 Uwvl(Xzwkm{{

0k1([v

0:1 Ozi~q|i|qwvit(nwzkm6

0Q^1 ^iv(Izsmt(Um|pwl

0l1(Oi

0;1 Lqnnmzmv|qit(il{wzx|qwv(wn(|pm({}j{|ivkm{(wv

091 0Q1(ž(0j1C(0QQ1(ž(0k1C(0QQQ1(ž(0l1C(0Q^1(ž(0i1

 

|pm({wtql(xpi{m6

 

0:1 0Q1(ž(0j1C(0QQ1(ž(0l1C(0QQQ1(ž(0i1C(0Q^1(ž(0k1

0<1 Lqnnmzmv|qit(ij{wzx|qwv(wn(|pm({}j{|ivkm{(wv

0;1 0Q1(ž(0k1C(0QQ1(ž(0i1C(0QQQ1(ž(0j1C(0Q^1(ž(0l1

 

|pm({wtql(xpi{m6

 

0<1 0Q1(ž(0k1C(0QQ1(ž(0l1C(0QQQ1(ž(0j1C(0Q^1(ž(0i1

Official Ans. by NTA (3)

 

Official Ans. by NTA (4)

 

15. \pm(uirwz(xzwl}k|(wn(|pm(nwttwqvo(zmik|qwv(q{(B

12. Kwv{qlmz(|pm(nwttwqvo({|i|mumv|{

   

O

O O

O

O O
O O
 
 

0i1 \pm(xP(wn(i(uq€|}zm(kwv|iqvqvo(<88(uT(wn

869(U(P [W (ivl(<88(uT(wn(869(U(ViWP

:

<

qtt(jm(ixxzw€qui|mt(96;6

0j1 Qwvqk(xzwl}k|(wn(i|mz(q{(|muxmzi|}zm

NC

(

)

¾¾¾¾®

D

PQ m€km{{

 
 

lmxmvlmv|6

I NC

I

NC

OH

I

I OH

OH

 

0k1 I(uwvwji{qk(ikql(q|p(S (E(98

i

ž=

( pi{ (i

 

xP(E(=6(\pm(lmozmm(wn(lq{{wkqi|qwv(wn(|pq{

091(

 

0:1(

 

ikql(q{(=8-6

0l1 \pm(Tm(Kpi|mtqmz/{(xzqvkqxtm(q{(vw|(ixxtqkijtm

 

NC

 

|w(kwuuwv5qwv(mnnmk|6

 
OH NC

OH

NC

OH

I I

I

I

 

|pm(kwzzmk|({|i|mumv|(izm(B

091(0i14(0j1(ivl(0l1

0:1(0i14(0j1(ivl(0k1

0;1(

 

0<1(

0;1(0i1(ivl(0j1

0<1(0j1(ivl(0k1

   

NC

Official Ans. by NTA (2)

 

Official Ans. by NTA (3)

 
 

16. Iutwxmk|qv(q{(kwuxw{ml(wn(B

091

a5L5ot}kw{m4(K 9 žK < (ivl(K 9 žK > (tqvsiom{ a5L5ot}kw{m4(K 9 žK < (ivl(K : žK > (tqvsiom{ b5L5ot}kw{m4(K 9 žK < (ivl(K : žK > (tqvsiom{ b5L5Ot}kw{m4(K 9 žK < (ivl(K 9 žK > (tqvsiom{

0:1

0;1

0<1

Official Ans. by NTA (1)

 

2

 
Final JEE -Main Exam April,2019/10-04-2019/Morning Session 17.   091 18.   091 19.   ;

Final JEE -Main Exam April,2019/10-04-2019/Morning Session

17.

 

091

18.

 

091

19.

 

;

 

cKw0VP

; 1

=

cKw0VP

; 1 > e

|pmu(q{(B

 

20.

 

091(s2( : X ‚ 0;1( p2( : X €

cKwKt0VP 1

:3 (D(^ :3 € 86= = sx u = e :3 (0Q14 P We ;3
:3
(D(^
:3
€
86=
= sx
u
= e :3
(0Q14
P We
;3
(0QQ1(ivl
:
;3
(0QQQ1
ž
4(|pm(qvkwuqvo
:
:
0:1( p
:
X

0<1( p(
:
X
€

21.

I

I

MeO
MeO

MeO

MeO

(A)

(B)

I

I

22.

H C

3

21. I I MeO (A) (B) I I 22. H C 3 (C) H CO 3

(C)

H CO

3

I MeO (A) (B) I I 22. H C 3 (C) H CO 3 (D) 091

(D)

091 0I1(D(0J1(D(0K1(D(0L1

0:1 0J1(D(0I1(D(0L1(D(0K1

0;1 0J1(D(0I1(D(0K1(D(0L1

0<1 0I1(D(0J1(D(0L1(D(0K1

Official Ans. by NTA (3)

Kwv{qlmz(|pm(nwttwqvo(|ijtm(B

Oi{(

>

i70s(Xi(lu (uwt

ž9

1(

j70lu ; (uwt ž9 1(

I(

><:6;:(

868=9A>(

J(

9==6:9(

868<9;>(

K(

<;96A9(

868=9A>(

L(

9==6:9(

86<;@:(

(

{|i|mumv|(ijw}|(|pm(oi{m{(q{(B

091

Official Ans. by NTA (3)

091 Official Ans. by NTA (3) 3 Kwv{qlmz(|pm(plzi|m{(qwv{(wn(\q :3 4(^ :3 4(\q ;3

3

091 Official Ans. by NTA (3) 3 Kwv{qlmz(|pm(plzi|m{(qwv{(wn(\q :3 4(^ :3 4(\q ;3

Kwv{qlmz(|pm(plzi|m{(qwv{(wn(\q :3 4(^ :3 4(\q ;3 (ivl [k ;3 6(\pm(kwzzmk|(wzlmz(wn(|pmqz({xqv5wvt uiovm|qk(uwumv|{(q{(B

Qvkzmi{qvo(zi|m(wn([ V 9(zmik|qwv(qv(|pm(nwttwqvo kwuxw}vl{(q{(B

[k ;3 (D(\q ;3 (D(\q

0:1 \q ;3 (D(\q :3 (D([k ;3 (D(^ :3 0;1 [k ;3 (D(\q ;3 (D(^ :3 (D(\q :3 0<1 ^ :3 (D(\q :3 (D(\q ;3 (D([k ;3

Official Ans. by NTA (1)

I(oi{(}vlmzowm{(xp{qkit(il{wzx|qwv(wv(i {}znikm(ivl(nwttw{(|pm(oq~mv(Nzm}vltqkp il{wzx|qwv(q{w|pmzu(my}i|qwv

Il{wzx|qwv(wn(|pm(oi{(qvkzmi{m{(q|p(B

Lmkzmi{m(qv(x(ivl(lmkzmi{m(qv(\

0:1 Qvkzmi{m(qv(x(ivl(qvkzmi{m(qv(\

0;1 Qvkzmi{m(qv(x(ivl(lmkzmi{m(qv(\

0<1 Lmkzmi{m(qv(x(ivl(qvkzmi{m(qv(\

Official Ans. by NTA (3)

\pzmm(kwuxtm€m{4

ij{wzj(tqop|(qv(|pm(~q{qjtm(zmoqwv6(\pm(kwzzmk|

wzlmz(wn(|pm(i~mtmvo|p(wn(tqop|(ij{wzjml(j

091(0QQQ1(F(0Q1(F(0QQ1 0:1(0Q1(F(0QQ1(F(0QQQ1

i(ivl(j(izm(~ivlmz(iit{(kwv{|iv|6(\pm(kwzzmk|

Oi{(K(qtt(wkk}x(tm{{mz(~wt}um(|piv(oi{(IC

oi{(J(qtt(jm(tm{{mz(kwuxzm{{qjtm(|piv(oi{(L

0:1 Oi{(K(qtt(wkk}x(uwzm(~wt}um(|piv(oi{(IC

oi{(J(qtt(jm(tm{{mz(kwuxzm{{qjtm(|piv(oi{(L

0;1 Oi{(K(qtt(wkk}x(uwzm(~wt}um(|piv(oi{(IC

oi{(J(qtt(jm(uwzm(kwuxzm{{qjtm(|piv(oi{(L 0<1 Oi{(K(qtt(wkk}x(tm{{mz(~wt}um(|piv(oi{(IC oi{(J(qtt(jm(uwzm(kwuxzm{{qjtm(|piv(oi{(L

0;1(0QQ1(F(0Q1(F(0QQQ1 0<1(0QQQ1(F(0QQ1(F(0Q1

Official Ans. by NTA (2)

L}zqvo(|pm(kpivom(wn(W (|w(W

mtmk|zwv(owm{(|w(|pm(wzjq|it(B

Official Ans. by NTA (3)

Final JEE -Main Exam April,2019/10-04-2019/Morning Session

Final JEE -Main Exam April,2019/10-04-2019/Morning Session 23. \pm(qvkzmi{qvo(wzlmz(wn(|pm(zmik|q~q|(wn(|pm

23. \pm(qvkzmi{qvo(wzlmz(wn(|pm(zmik|q~q|(wn(|pm nwttwqvo(kwuxw}vl{(|wizl{(mtmk|zwxpqtqk

28. \pm(uirwz(xzwl}k|(wn(|pm(nwttwqvo(zmik|qwv

q{(B5

 
 

izwui|qk({}j{|q|}|qwv(zmik|qwv{(q{(B5

 

CH

3

Cl

Cl

CH 3

COCH 3

CH –C–CH CH

3

3

KP WP

;

¾¾¾¾®

 
    H Br
    H Br
   

H

Br

 

CH

3

(I)

(II)

(III)

091 CH –C–CH CH

3

3

 

091(Q(D(QQQ(D(QQ

 

0:1(QQ(D(Q(D(QQQ

 

H

OCH 3

0;1(QQQ(D(Q(D(QQ

0<1(QQQ(D(QQ(D(Q

 

Official Ans. by NTA (3)

   

CH 3

 

24. \pm(ozixp(jm|mmmv(„y„ : (ivl(z0zilqit(lq{|ivkm1

0:1( CH –C–CH = CH

3

2

 
 

q{({pwv(jmtw6(\pq{(zmxzm{mv|{(B5

   

H

 
2
2

r

 

CH

3

 

|y|

0;1

CH –C–CH CH

3

23

 
   

OCH

3

CH

3

 

091(;{(wzjq|it

0;1(:x(wzjq|it

 

0:1(9{(wzjq|it

0<1(:{(wzjq|it

0<1(

CH –C = CH CH

3

3

 

Official Ans. by NTA (4)

 

Official Ans. by NTA (3)

25. I|(zwwu(|muxmzi|}zm4(i(lqt}|m({wt}|wv(wn(}zmi

29. \pm(zmoqwv{(wn(|pm(i|uw{xpmzm4(pmzm(ktw}l{

 

q{(xzmxizml(j(lq{{wt~qvo(86>8(o(wn(}zmi(qv

nwzu(ivl(pmzm(m(tqvm(zm{xmk|q~mt4(izm(B5

;>8(o(wn(i|mz6(Qn(|pm(~ixw}z(xzm{{}zm(wn(x}zm

091([|zi|w{xpmzm(ivl(\zwxw{xpmzm

i|mz(i|(|pq{(|muxmzi|}zm(q{(;=(uuPo4

0:1(\zwxw{xpmzm(ivl([|zi|w{xpmzm

twmzqvo(wn(~ixw}z(xzm{{}zm(qtt(jm

0;1(\zwxw{xpmzm(ivl(\zwxw{xpmzm

0uwtiz(ui{{(wn(}zmi(E(>8(o(uwt

ž9

1B5

0<1([|zi|w{xpmzm(ivl([|zi|w{xpmzm

091 868:?(uuPo

 

0:1(868:@(uuPo

Official Ans. by NTA (3)

 

0;1(8689?(uuPo

0<1(868;9(uuPo

30. \pm(ittw(}{ml(qv(|pm(kwv{|z}k|qwv(wn(iqzkzin|{

Official Ans. by NTA (3)

 

q{(B5

 

26. \pm({vwvu(nwz(i|mz(oi{(pmv(}{ml(qv(|pm

091(Uo(ž([v 0:1(Uo(ž(Uv

 

xzwl}k|qwv(wn(um|pivwt(q{(B5

 

0;1(Uo(ž(It 0<1(Uo(ž(bv

091(vi|}zit(oi{ 0:1(ti}opqvo(oi{

Official Ans. by NTA (3)

 

0;1({v(oi{

0<1(n}mt(oi{

 

Official Ans. by NTA (3)

 

27. I(xzwkm{{(qtt(jm({xwv|ivmw}{(i|(itt

 

|muxmzi|}zm{(qn(B5

 

091(DP(F(8(ivl( D[ (D (8 0:1(DP(D(8(ivl( D[ (F (8 0;1 DP(F(8(ivl( D[ (F (8 0<1(DP(D(8(ivl( D[ (D (8

 

Official Ans. by NTA (2)

 

4