SUMMER INTERNSHIP PROJECT REPORT

MAY – JUNE 2018

“Energy Balance of Distillation Column”
BY
Deep Shah
3rd Year, Chemical Engineering

Shri S’ad Vidya Mandal Institute Of technology

Mentored by: Place of Internship:

Mr. Lalan Pandey Jubilant Infrastructure Limited
Manager of FC Plant Vilayat, Bharuch
 Certificate
This is to certify that Mr. Deep Shah, 3rd year Undergraduate from Shri S’ad
Vidya Mandal of Technology in the Chemical engineering has successfully
completed his summer training from Jubilant Infrastructure Limited,
Vilayat, under the mentorship of Mr. Lalan Pandey, Manager of FC Plant.
The duration of this training / internship was from 15/05/2018 to
04/06/2018.
As part of this internship, he was assigned a project, titled “Energy Balance
of Distillation Column”, and he has successfully completed this project and
submitted the report to the concerned department.

Mentor: DGM:

Mr. Lalan Pandey Mr. Kashyap Mapara

Manager of FC Plant Deputy General Manager
Jubilant Infrastructure limited Jubilant Infrastructure limited
 Acknowledgement
The project would not have been possible without the help and support of
the following key people.
I am deeply grateful to Mr. Chirag Shah (GM Safety Department) for
providing me with this wonderful learning opportunity at Jubilant
Infrastructure Limited, Villayat. And also thanks to Mr. Tosif Patel (HR) for
providing FC plant for training.
I am deeply indebted to Mr. Rabi Mohanty (Deputy Manager) for being an
extremely helpful, deeply insightful and generously supportive mentor. His
guidance during the various stages of my training and internship at Jubilant
Infrastructure Limited and I believe that I have learnt a lot of invaluable
lessons from his able mentorship.
My thanks are due to Mr. P. C. Padaliya (Assistant Manager) and Mr.
Vishvas Pandya (Assistant Manager) for the help they provided at various
stages of the internship at Jubilant Infrastructure Limited, Villayat.
Last but not the least; I thank all the co-trainees, executives, technicians,
plant in- charges, DCS operators, and mess & housekeeping staff for all the
direct and indirect help they provided me with. Again thank to all plant
member for teaching me and helping me to complete my training safely
Summer Training / Internship (May - June 2018)
Jubilant Infrastructure Limited, Villayat

3rd Year UG,

Chemical Engineering, SVMIT
 INDEX
Sr. No Topic Page no
1 Jubilant Overview 5
2 Process Overview 6
3 Energy Balance of Distillation Column 7
4 About Ejector 9
5 Calibration Of Tank / Vessel 10
6 About MSDS 11
7 Conclusion 13
8 References 14
 Brief Overview Of The Factory Premises
Jubilant Life Science Limited is an integrated pharmaceutical & Life Science
Company. As Indian’s largest custom research and manufacturing services
(CRAMS) player and leading Drug Discovery and Development Solution
provider out of India, it is constantly engaged in delivering value to its
global customers through innovative technologies, products and services.
The company’s focus is to innovate, collaborate and accelerate the process
of delivering products to the market for its customer. Today it is well
recognized as a ‘Partner of Choice’ by leading global pharm and Life Science
Companies. The company through its presence in India, Canada, Europe,
and China constantly serves its customers in over 65 countries across the
globe.

Objective Of The Plant

The emergency Response plan defines the organization for the organization
for the co-ordinate response necessary in the event of a major disaster. The
organization plant shows the structure of the organization and a brief
overview the tasks of personnel in the key roles. Role descriptions are
provided foe all key personnel.
First and foremost objective of Employee Management is to maintain
healthy Employee Management relation and meticulously planned and
execute all emergency situation.
The Emergency Response Plan was written to provide response procedure
to protect people and property during an emergency or disaster situation.
This plan identifies and assigns personnel to various emergency tasks and
responsibilities, thus cresting the Site Emergency Team. This plan provides
coordination between the Site Emergency Team response and
governmental authorities to ensure an effective response.
 Process Overview
 In Fine Chemical Plant main product is 2,3,5 Collidine. Process in two
step 1st is reaction and 2nd is distillation. The flow diagram of process is
under:

Catalyst

Row Material 1 Slurry Preparation Water circulation

Row Material 1

High Pressure Gas cooler &

Row Material 2 scrubber set
Reaction in Reactor

Catalyst for reuse

Reaction Mass Effluent to ETP

Cooling Catalyst Aq layer recycled
Separation

Recovered RM for use

Distillation and
Product Purification Solvent Residue in incinerator

Pure Product
 Energy Balance of Distillation Column
I. LBS (Low Boiling Substance)
II. 1st By Product Inter Cut
III. 1st By Product Pure State
IV. 2nd Product 1st Inter Cut
V. 2nd Product 2nd Inter Cut
VI. 2nd Product Pure State
VII. HBS (High Boiling Substance)
VIII. Residue

 These are the difference component to be collect from Distillation

Column at difference temperature and it collect in difference tank.
 Now Energy Balance for the Distillation Column is under:

Basic formula for Energy Balance:

Input = Output + Accumulation + Loss
 Required Energy for Input
𝑄 = 𝑚𝐶𝑝 ∆𝑇 = 30000 ∗ 0.05 ∗ 40 = 𝟔𝟎𝟎𝟎𝟎 𝑱
 Required Energy for Product (Output)

I. LBS (Low Boling Substance)

102 − 89
∆𝑇𝑚 = = 95.35
𝐼𝑛 102⁄89
𝑄 = 𝑚𝐶𝑝 ∆𝑇 = 2973 ∗ 0.05 ∗ 95.35 = 𝟏𝟒𝟏𝟕𝟑. 𝟕𝟕𝟓 𝑱

II. 1st By Product Inter Cut

54 − 19
∆𝑇𝑚 = = 33.51
𝐼𝑛 54⁄19
𝑄 = 𝑚𝐶𝑝 ∆𝑇 = 1250 ∗ 0.05 ∗ 33.51 = 𝟐𝟎𝟗𝟒. 𝟏𝟖 𝑱

III. 1st By Product Pure State

 19 − 13
∆𝑇𝑚 = = 15.81
𝐼𝑛 19⁄13
𝑄 = 𝑚𝐶𝑝 ∆𝑇 = 7946 ∗ 0.05 ∗ 15.81 = 𝟔𝟐𝟖𝟏. 𝟑𝟏𝟑 𝑱

IV. 2nd Product 1st Inter Cut

13 − 4
∆𝑇𝑚 = = 7.63
𝐼𝑛 13⁄4
𝑄 = 𝑚𝐶𝑝 ∆𝑇 = 5208.5 ∗ 0.05 ∗ 7.63 = 𝟏𝟗𝟖𝟔. 𝟗𝟑 𝑱

V. 2nd Product 2nd Inter Cut

6−4
∆𝑇𝑚 = = 4.93
𝐼𝑛 6⁄4
𝑄 = 𝑚𝐶𝑝 ∆𝑇 = 7652 ∗ 0.05 ∗ 4.93 = 𝟏𝟖𝟖𝟔. 𝟐𝟐 𝑱

VI. 2nd Product Pure State

14 − 6
∆𝑇𝑚 = = 9.44
𝐼𝑛 14⁄6
𝑄 = 𝑚𝐶𝑝 ∆𝑇 = 4065 ∗ 0.05 ∗ 9.44 = 𝟏𝟗𝟏𝟖. 𝟔𝟖 𝑱

VII. HBS (High Boiling Substance)

22 − 15
∆𝑇𝑚 = = 18.277
𝐼𝑛 22⁄15
𝑄 = 𝑚𝐶𝑝 ∆𝑇 = 989 ∗ 0.05 ∗ 18.277 = 𝟗𝟎𝟑. 𝟕𝟗𝟕 𝑱
Sum of all above energy.
We get. Output Energy =29244.895 J
 Accumulation (Residue)

𝑄 = 𝑚𝐶𝑝 ∆𝑇 = 1012.5 ∗ 0.05 ∗ 60 = 𝟐𝟎𝟗𝟑𝟎. 𝟗𝟗 𝑱

So put all value in Basic Equation and get Loss
Input = Output + Accumulation + Loss
60000 = 29244.895 + 20930.99 + Loss
Loss = 9825.12 J
 Column having 5 segment, column is pack column it’s having structure
packing, each segment having around 20-24 packing, flow of liquid and
vapour is Zik-zak flow. During my training I was see whole column
packing transferring and cleaning of packing.
 Here some data are official and some data are randomly. So this loss is
not accurate but for learning purpose this information is sufficient.

Ejector
 What is Ejector? : An ejector is a device used to suck the gas or
vapour from the desired vessel or system. An ejector is similar to of
vacuum pump or compressor. The major difference between the
ejector and the vacuum pump or compressor is it had no moving
parts. Hence it is relatively low-cost and easy to operate and
maintenance free equipment.
 Principle of Ejector: The operating principle of the ejector is the
pressure energy in the motive fluid is converted to velocity energy by
an adiabatic expansion in the Converging/Diverging Nozzle. Due to
the pressure drop of the motive fluid, it will create a low-pressure
zone before the mixing chamber. Due to the low-pressure zone, the
suction fluid will start to move to toward it and mix with motive fluid
in the mixing chamber. In mixed fluid enter the diverging portion of
the ejector where its velocity energy is converted into Pressure
energy.
  Benefits of Ejector

o Ejectors can be operated with many different motive fluids:

steam, air, organic vapour and other gases.
o No moving parts, no lubrication, no vibration. Hence low
maintenance cost when to compare with other peer equipment.
o Ejectors can be installed indoors or outdoors without
restriction.
o Can be installed at any orientation. Hence space requirement
will be very low.
o Initial cost is very less and no spares required.
o Easy to handle corrosive and slugging liquids.

Calibration Of Tank/Vessel

 Calibration in measurement technology and metrology is the

comparison of measurement values delivered by a device under
test with those of a calibration standard of known accuracy. Such a
standard could be another measurement device of known accuracy, a
device generating the quantity to be measured such as a voltage, or a
physical artefact, such as a metre ruler.
 Calibration may be required for the following reasons:
o A new instrument
o After an instrument has been repaired or modified
o When a specified time period has elapsed
o When a specified usage (operating hours) has elapsed
o Before and/or after a critical measurement
o After an event, for example
 After an instrument has been exposed to a shock, vibration,
or physical damage, which might potentially have
compromised the integrity of its calibration
 Sudden changes in weather
o Whenever observations appear questionable or instrument
indications do not match the output of surrogate instruments
o As specified by a requirement, e.g., customer specification,
instrument manufacturer recommendation.
 How to measure level of Tank in term of Litter?
o First find that in 1 CM how much quantity of liquid is tank.
o Than every tank heaving its Dead Level find that.
o Now tank one example:

 Liquid level in tank is 15 CM and its Dead volume is 1400 Litter and its
LPC is 73.1 Litter. Fine out quantity of liquid.
o Quantity = (15* 73.1) + 1400 = 2496.5 Litter

MSDS
 A safety data sheet (SDS), material safety data sheet (MSDS), or
product safety data sheet (PSDS) is an important component of
product stewardship, occupational safety and health, and spill-handling
procedures. SDS formats can vary from source to source within a
country depending on national requirements.

 Some of those chemicals are perfectly safe, some of them may or may
not be safe, and some have known risks. ... A material safety data sheet
(or MSDS) is a document that provides workers with procedures for
safely handling or working with a particular substance.

 The Globally Harmonized System of Classification and Labelling of

Chemicals contains a standard specification for safety data sheets. The
SDS follows a 16 section format which is internationally agreed and for
substances especially, the SDS should be followed with an Annex which
contains the exposure scenarios of this particular substance. The 16
sections are:

 Chemical product and company identification

 Composition and information on ingredients
 Hazards Identification
 First aid measures
 Fire and explosion data
 Accidental release measures
 Handling and storage
 Exposure control / personal protection
 Physical and chemical properties
 Stability and reactivity data
 Toxicological information
 Ecological information
 Disposal Consideration
 Transport information
 Other regulatory information
 Other information
 Conclusion
Energy balance of the distillation column has been successfully performed
and verified with minor differences in the practical and theoretical values.
Calibration of tank is important for measuring level of liquid and it is
derived properly. Ejector is the most important equipment in industry.
How to create vacuum in tank was learned. In this industry steam ejector is
use. About MSDS of product and which thinks are provide in MSDS are
learning. Official work is notice and what is the work system of company is
know very well.
 References
 https://en.wikipedia.org
 Unit Operations, McGraw Hill
 http://www.mechanicalengineeringsite.com