Chemistry Question Bank

Question Bank of Chemistry
Single Correct Questions 6. The lowering of vapour pressure in a saturated aq.

solution of salt AB is found to be 0.108 torr. If
1. Radiation corresponding to the transition n = 4 o
vapour pressure of pure solvent at the same
n = 2 in hydrogen atoms falls on a certain metal
temperature is 300 torr. Find the solubility product
(work function = 2.0 eV). The maximum kinetic
of salt AB
energy of the photoelectrons will be
(A) 0.55 eV (B) 2.55 eV (A) 10–8 (B) 10–6
(C) 4.45 eV (D) none (C) 10–4 (D) 10–5
2. Reaction A + B  C + D follow's following rate 7. Study the following figure and choose the correct
option.
1 1

law : rate = k  [A] 2 [B] 2 . Starting with initial
conc. of one mole of A and B each, what is the time
taken for amount of A of become 0.25 mole. Given
k = 2.31 × 10–3 sec–1.
(A) 300 sec. (B) 600 sec.
(C) 900 sec. (D) none of these (A) There will be no net moment of any substance
across the membrane
(B) CaCl2 will flow towards the NaCl solution.
3. For the equilibrium at 27°C.
(C) NaCl will flow towards the CaCl2 solution.
LiCl.3NH3 (s)  LiCl .NH3 (s) + 2NH3(g) ;
(D) The osmotic pressure of 0.2 M NaCl is lower
Kp = 9 atm2
than the osmotic pressure of 0.15 M CaCl2,
A 24.63 litre flask contain 1 mol LiCl.NH3. How assuming complete dissociation of electrolyte.
many moles of NH3 should be added to flask at
this temperature to drive the backward reaction for
compleletion.
8. Select the correct option if it is know that
(A) 0002 (B) 0005
Ksp (AgCl) > Ksp (AgBr) > Ksp (AgI)
(C) 0003 (D) 0004
(A) E oI  / AgI / Ag
 E oBr  / AgBr / Ag
 E oCl  / AgCl / Ag
4. The activation energies of two reactions I and II o o o

are Ea and 2Ea respectively. If the temperature of (B) E I / AgI / Ag  E Br  / AgBr / Ag  E Cl  / AgCl / Ag
the reacting systems is increased from T to T',
predict which of the following alternative is (C) E oAg / AgI / I ¯  E oAg / AgBr / Br ¯  E oAg / AgCl / Cl ¯
correct?(k represent rate constant)
(D) None of these
'
(A) k I / kI  k 'II / k II
9. What is [Ag+] in a solution made by dissolving
' '
(B) k I / k I  k II / k II both Ag2CrO4 and Ag2C2O4 until saturation is
reached with respect to both salts. KSP(Ag2C2O4)
' ' = 2 × 10–11, KSP(Ag2CrO4) = 2 × 10–12
(C) k I / k I  k II / k II
(A) 2.80 × 10–4 (B) 7.6 × 10–5
' ' (C) 6.63 × 10–6 (D) 3.52 × 10–4
(D) k I / k I  2 k II / k II
10. An aqueous solution of Na2SO4 was electrolysed

5. If molar internal energy change for a gas in a for 10 min. 82 ml of a gas was produced at anode
closed rigid vessel given by over water at 27°C at a total pressure of 580 torr.
U = a + bT + cT2 Determine the current that was used.
find the entropy change in J/K at constant (Vapour pressure of H2O at 27°C = 10 torr)
volume when 1 mol of gas are heated from 200
(R = 0.082 atm lit./ mol / K)
K to 400 K.
(A) 15 (B) 30 (A) 0.1 Amp (B) 1.25 Amp
(C) 60 (D) None of these (C) 2.23 Amp (D) 1.61 Amp
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11. (Si 2 O5 ) 2nn  anion is obtained when 15. pH of a saturated solution of silver salt of
monobasic acid HA is found to be 9.
4
(A) no oxygen of a Si O 4 tetrahedron is shared Find the Ksp of sparingly soluble salt Ag A(s).
Given : Ka (HA) = 10–10
4
with another Si O 4 tetrahedron. (A) 1.1 × 10–9 (B) 1.1 × 10–10
(C) 1.1 × 10–11 (D) 10–12
4
(B) one oxygen of a Si O 4 tetrahedron is shared
4 16. Give the correct order of initials T or F for following
with another Si O 4 tetrahedron. statements. Use T if statement is true and F if it is
4 false.
(C) two oxygen of a Si O 4 tetrahedron are shared
(I) Number of S–S bonds in H2SnO6 are (n+1)
4
with another Si O 4 tetrahedron. (II) When F2 reacts with water gives HF, O2 & O3
(III) LiNO3 & BaCl2 compounds are used in fire
4 works
(D) three oxygens of a Si O 4 tetrahedron are
(IV) Be and Mg hydrides are ionic and polymeric
4 (A) FTTF (B) FTTT
shared with another Si O 4 tetrahedron.
(C) TFTT (D) TTFF
12. Give the correct order of initials T or F for following
statements. Use T if statement is true and F if it is 17. The following complexes are given:
false. (1) Trans–[Co(NH3)4Cl2]+
(I) Sulphide ions react with Na2[Fe(NO)(CN)5] to (2) cis–[Co(NH3)2en2]3+
form a purple coloured compound
(3) Trans–[Co(NH3)2(en)2]3+
Na4[Fe(CN)5(NOS)]. In the reaction, the
2
oxidation state of iron changes (4) NiCl 4
(II) In B2H6 vacant orbital takes part in
hybridisation 2
(5) TiF6
(III) The welding of magnesium can be done in the
atmosphere of Helium 3
(6) CoF6
(IV) LiAlH4 on hydrolysis will give H2.
(A) FFTT (B) FTTT Choose the correct code.
(C) TFTF (D) TFTT (A) (1), (2) are optically active, (3) is optically
inactive
13. The enthalpy of neutralisation of 1M solution of (B) (2) is optically active, (1), (3) are optically
HCl with 1M solution of NaOH is –57.3 kJ/mole. inactive
The enthalpy of solution of a weak acid HA(1M) (C) (4), (5) are coloured and (6) is colourless
with same NaOH solution is –54.6 kJ/mole. If the (D) (4) is coloured and (5), (6) are colourless.
weak acid is 10% ionized in 1M solution, what is
Hionisation of HA (in kJ/mole)
18. Give the correct order of initials T or F for following
(A) +3 (B) +2.7 statements. Use T if statement is true and F if it is
(C) +2.43 (D) +2 false.
(I) Br–P–Br bond angle in PCl3Br2 is 180°.
14. Which is the correct sequence in the following
 
properties. For the correct order, mark (T), and for (II) NO 2 , NO2 & NO 2 species have O–N–O
the incorrect order mark (F) :
 
(a) Acidity order : SiF4 < SiCl4 < SiBr4 < SiI4 bond angle order, NO 2 < NO2 < NO 2 .
(b) Melting point : NH3 > SbH3 > AsH3 > PH3
(III) Oxy acid is not produced, when NCl 3
(c) Boiling point : NH3 > SbH3 > AsH3 > PH3 undergoes hydrolysis.
(d) Dipole moment order : NH3 > SbH3 > AsH3 > (IV) Silicones are very inert and water repellant.
PH3
(A) TTTF (B) TFTT
(A) FTFT (B) TFTF
(C) FFTT (D) FFTF (C) FTFF (D) FTFT
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19. Fe2+ and Fe3+ can be distinguished by 23. An ion M2+, forms the complexes [M(H2O)6]2+,
[M(en)3] and [MBr6]4–, match the complex with
2+
(A) K3[Fe(CN)6] (B) K4[Fe(CN)6]
the appropriate colour.
(C) KSCN (D) All
(A) Green, blue and red
(B) Blue, red and green
(C) Green, red and blue
20. on treatment with acid (D) Red, blue and green
followed by hydrolysis yields

(A) CH3CO2H + PhNH2
(B) PhCO2H + CH3CH2NH2 3H O
24.  
(C) PhCH2NH2 + HCO2H
(D) PhCH2CO2H + CH3NH2 (A) + (B) formed can be distinguished by
(A) Iodoform (B) Fehling

21. Use the following data to answer the questions (C) NaHSO3 (D) 2,4-DNP
below:
2H
 H = – 28.6 Kcal mol–1 25. An inorganic Red colour compound (A) on heating,
Ni
gives a compound (B) and a gas (C). (A) on
treatment with conc. HNO3, gives compound (D),
excess H brown colour substance (E) and a neutral oxide (F).
 2 
( Ni ) Compound (D) on warming gives off again gas (C).
Then, (E) will be:
H = – 116.2 Kcal mol–1
(A) Mn3O4 (B) PbO2
Calculate the resonance energy of anthracene,
(C) Pb3O4 (D) Fe2O3
26. Select reaction in which correct products are given:

(A) 84 kcal/mol (B) 100 kcal/mol
(C) 110 kcal/mol (D) 116 kcal/mol 14
(A) Ph  CH 2  COOH + NaHCO3  CO2 
22. Which among the following compounds will give 14 14

maximum enol content in solution: (B) Ph–OH + NaH C O3  C O 2 
O O
|| ||
(A) C 6 H 5  C  CH 2  C  C 6 H 5
(C) + NaHCO3  CO2 
O O
|| ||
(B) CH 3  C  CH 2  C  CH 3
(D) Me3CONa + H2O  Me3C – OH + NaOH
O
|| 27. Which one of the following reagent can be used
(C) CH 3  C  CH 2  CH 2  CH 3 for distinguishing the Cu2+, Cd2+ & Bi3+ ?
(A) H2S gas in presence of dil HCl
O (B) NH4OH (excess)
|| (C) K4[Fe(CN)6]
(D) CH 3  C  CH 2  COOC 2 H 5 (D) (B) and (C) both
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28. Correct order of basicity of marked N in following (A) S° can be obtained from the y-intercept
compound is (B) The slope of the line is equal to +(H°/R)
(C) The reaction is endothermic
(D) The standard free energy change of the reaction
is positive.
31. Select the correct statement:
N
(A) 1 > 2 > 3 (B) 2 > 1 > 3
(A) H Et is optically inactive while
(C) 2 > 3 > 1 (D) 3 > 2 > 1 CH3
N
Multiple Correct Answer is optically active
29. The order of reaction A  product can be given
by the expression
 
[where r = rate of reaction ; [A]1 = concentration at (B) CH 3  CH 2  CH 2  CH 3
time t1 ; [A]2 = concentration at time t2 ] ( I)
ln r2  ln r1
 
(A)
ln[ A]2  ln [A]1 CH 3  CH 2  CH 3
( II)
ln [A 0 ]2  ln [A 0 ]1
(B) About C() – C() bonds; (I) has more energy barrier
ln[ t1 / 2 ]2  ln [ t1/ 2 ]1
for rotation as compared to (II).
(C) The boat form of cyclohexane is less
  d[A]  stable than chair form due to torsional strain
(C) ln   / ln [A]
 k.dt  as well as flag pole interaction.
(D) In t-butyl substituted cyclohexane, most stable
ln (r / k ) chair conformer has – CMe3 group at equitorial
(D) position.
ln[ A]
32. Choose the incorrect option(s).

30. In the laboratory the equilibrium constant for a
particular reaction can be measured at different I
temperatures. Plotting the data yields the graph (A) Rate of SN2 >
shown. Which of the following statements is false?
(Note : The notation 4.40e – 4 is equivalent to I
4.40 × 10–4)
OH D
| |
HI
(B) Ph  CH — CH  Me  racemic
Optically pure SN 1
mixture
Moist
(C) Me–Cl  Me–O–Me (major)
Ag 2O
(D) MeI (excess) + NH3  Me3N
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33. Pb | PbSO4 | SO42– (0.1M) | | Pb+2 (0.01 M) | Pb
[Given : Ksp (PbSO4) = 10–16 M2 37. (X)
E oPb  2 / Pb  0.12 volt

(Y) (Z)
2.303 RT Identify X, Y, Z :
Use = 0.06 ]
F (A) Y is CH3  CH  CH2 C  CCH3
Select the correct option(s). |
O  CH3
o
(A) E is 0.36 volt
Pb / PbSO 4 / SO 4 2 (B) Y is CH3  CH2  CHC  CCH3
(B) Ecell is 0.39 volt |
OCH3
o
(C) E cell is zero
(C) Z is CH3  CH  CH2  CH  CH  CH3
|
(D) E oPb / PbSO / SO  2 is 0.60 volt
4 4 O  CH3
(D) X is
34. Find out the reactant P and RX for Williamson

synthesis
38. Which of the following statements is/are correct?
Na RX (A) B2H6 reacts with excess NH3 at low
 
P 
temperature to produce an ionic compound
(A) PhBr + NaOCH2 – O – CH3 (B) B2H6 reacts with excess of NH3 at higher
(B) CH3OH + PhCH2Br temperature to form boron nitride solid
(C) PhCH2OH + CH3Br (C) Boron nitride has polymeric layer structure
(D) Ph – CH2 – Br + CH2Br (D) In borazine there are -ve and +ve charges on B
and N respectively
35. Which of the following statements(s) is /are true

for XeF6 ? 39. Which of the following conditions satisfies the
(A) Its partial hydrolysis gives XeOF4. conditions belong to minimum boiling azeotropes?
(B) Its reaction with silica gives XeOF4 (A) Vmixing > 0
(C) It is prepared by the reaction of XeF4 and (B) Hmixing > 0
O2F2 (C) Smixing<0
(D) Its reaction with XeO3 gives XeOF4. (D) Solvent-solvent interaction forces and solute-
solute interaction forces are greater than that
of solvent-solute interaction forces.
36. In which of the following test(s)/reaction(s) a green
precipitate/mass is obtained as one of the reaction
products ? 40. The diagram given aside depicts the boiling point
(A) Reaction of chromium (iii) soluble salt with am- as the function of composition of the mixture of
monium hydroxide CCl4 and SiCl4. Which of the following statements
(B) Reaction of cobalt (II) soluble salt with sodium about the diagram is false?
carbonate and bromine water
(C) On heating zinc salt with cobalt nitrate and so-
dium carbonate in oxidising flame
(D) On fusing a mixture of manganese dioxide, po-
tassium nitrate and sodium hydroxide
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(A) The point a represents the composition of
solution and that point b that of the vapour in
equilibrium (A)
(B) The proportion of CCl4 in the solution is
smaller than that in the vapour in equilibrium
(C) Ba represents the condensation of the vapour
(B)
(D) The point c represents the composition of
solution and the point b that of the vapour is
equilibrium.
(C)
41. Which of the following expression(s) represent the
voltage of cell at 298 K : Ag (s) | AgI (saturated
solution) || Ag2C2O4 (saturated solution) | Ag(s)
(D)
44.
The correct matches are -

(A) Q = MeCONHMe
(B) Y = MeCH2CHO
(C) Q = MeCONHCH2Me
(D)
42. Consider the cell : Ag | AgCl (s) | KCl (1M) | Hg2Cl2(s)
| Hg () | Pt. The cell potential :
(A) increases on increasing concentration of Cl-
ions
(B) decreases or decreasing concentration of Cl- 45. Which of the following are possible products from
ions aldol condensation of 6-oxoheptanal ?
(C) is independent of concentration of Cl - ions
(D) is independent of amounts of AgCl (s) and
Hg2Cl2 (s)
(A) (B)
43. (C) (D)
Which of the following are possible products (in

significant amount) -
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46. (A)
Final product (s) is/are - (B)

(A) Alanine (B) Glycine
(C) Phthalic acid (D) Valine
(C)
(D)
47.
49. A transition metal M forms an Octahedral complex.

The calculated magnetic moment remains unaf-
fected by the nature of ligand i.e. whether strong or
weak. Select the correct statement -
(A) M forms coloured compounds only
The correct statement (s) is /are - (B) Metal ion can have d3 configuration
(C) Metal ion can have d2 or d8 configuration
(A) (D) Metal ion can have d1 or d9 configuration
50. Cu2+ form many complexes in the aqueous solu-

(B) tion-
(A) If colour of Cu(H2O)62+ is light blue the colour
of [Cu (NH3)4(OH2)2]2+ may be light green
(B) If colour of Cu(H2O)62+ is light blue the colour
(C) of [Cu(NH3)4(H2O)2]2+ may dark blue
(C) If colour of [Cu(H2O)6]2+ is light blue the colour
of [CuCl4]2- may light green
(D) (D) The geometry of [CuCl4]2- is either planar or
may be distorted tetrahedral
Integer Type Questions

48. 51. PCl5 dissociates according to the reaction,
PCl5 (g)  PCl3 (g) + Cl2 (g)
The density of equilibrium mixture at 1 atm & 5 °C is
6.25 gm/l, then calculate the value of KP for the
dissociation at this temperature.
Given : R = 0.08
[Fill your answer by multiplying it with 300]
[Q] The correct option (s) is/are (Assuming major

product is formed in each reaction) -
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52. For the reaction A(g)  B(g) + C(g), the value of measured is 100. Calculate elevation in boiling
G was –5154.3 Joules at partial pressures of 2,1,1 point of the 0.1 M CH3COOH solution, using
atm for A, B and C respectively, in a container of following information.
volume 'V' litres at Temperature 300 K. Find the
total pressure in the same container at equilibrium Kb = 0.5 K kg/mol ;   
m (H )
= 300 Scm2 mole–1
in atm.
USE: R = 8.3 J/K mole; ;   2
m (CH 3 COO ) = 100 Scm mole
–1
ln X Fill your answer by multiplying it with 800.

log 2 = 0.3  100.3 = 2; = 2.3
log X
58. The enthalpy of vapourisation of water
= 45.953 kJ/mol
53. In a sample of hydrogen atom in ground state
At 1 atm pressure the boiling point of water is 373
electrons make transition from ground state to a
particular excited state where path length is five K. What is the boiling point of water when pressure
times de-broglie wavelength, electrons make back equal to 1/2 atm in Kelvin in nearest possible
transition to the ground state producing all possible integers ? Given : log 2 = 0.3
photons. If photon having 2nd highest energy of
this sample can be used to excite the electron in a Comprehension Type Questions
particular excited state of Li2+ atom then find the
final excited state of Li2+ atom. Comprehension -1
A fuel cell is the device to convert the energy of a
fuel into electrical energy without the use of heat
54. Consider the following galvanic cell:
engine, where the fuel is burnt directly. Such con-
Pt | H2 (1 bar) | HX | | KCl (1 M) | Cl2 (g) versions are possible because the overall reaction
(1bar) | Pt are highly exothermic. Electrical energy can be
At 25° C, emf of the cell is 600 mV. When HX is obtained indefinitely from a fuel cell as along as the
replaced by a buffer solution at pH 6.80, the emf of outside supply of fuel is maintained. In hydrogen –
cell becomes 750 mV. Calculate the pH of HX oxygen fuel cell, the following reaction take place:
solution originally used. Anode reaction :
2.303 RT 2H2 (g) + 4OH–(aq) 4H2O(l) + 4e–
Given : = 0.06 V..
F Cathode reaction:
(Answer by multiplying the pH by 1000) O2(g) + 2H2O(l) + 4e–  4OH–(aq)
Overall reaction: 2H2(g) + O2(g)  2H2O(l)
O H ºf [H2O(l)] = – 285.8 kJ mol–1 and G ºf [H2O(l)]
||
55. (i) C  O  H NaHCO
 3  y (gas) = – 237.39 kJ mol–1 at 25C.
14 59. What is the standard EMF of the cell?
KH (A) 0.615 V (B) 1.23 V
(ii) OH 
 z (gas) (C) 2.46 V (D) 0.74 V
Sum of  (x) + molecular weight of gas (y) +

molecular weight of gas (z) is 60. How many litres of gaseous H2, when combined
with excess O2 in the fuel cell at 25C and 1.00 bar,
are needed to produce 23.739 KJ of useful work
56. On passing electricity through nitrobenzene under standard conditions?
solution, it is converted into azobenzene. Calculate
(A) 2.47 L (B) 4.94 L
the mass of azobenzene (in mg) if same quantity of
(C) 1.23 L (D) 2.26 L
electricity produces oxygen just sufficient to burn
96 mg of fullerene (C60).
61. The theoretical efficiency of the fuel cell is given
57. A solution of 0.1 M CH3COOH is placed between by
parallel electrodes of cross-section area 4cm 2, (A) 83.06 % (B) 100 %
(C) 67.53 % (D) 97.88 %
separated by 2cm. For this solution resistance
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Comprehension -2 Comprehension -4
For the reaction, A + C  B + P
K1
Mechanism is A R+B
K–1
k2
R + C  P
62. Rate of formation of P should be
k1 [ A ] [C] k1k 2 [ A ] [C]

(A) k (B) k [B]  k [C]
–1 [B] –1 2
66. When compound B undergoes in hydrolysis,
k1k 2 [ A ] [C] k1k 2 evolved gas is
(C) k (D) k [ A ] [C]
–1 [B]  [C] –1 Cl2
(A) (B) HCl
(C) H2 (D) O2
dp
63. depends on concentration of which reaction 67. Choose the correct statement
dt
component when concentration of [C] is very high. (A) compound A, B & C have same type of bond
(A) [A] only (B) [A] & [B] only (B) compound C & D have same type of bond
(C) [A], [B] & [C] (D) [A], [B], [C] & [P] (C) compound A & C have same type of bond
(D) compound A & D have same type of bond
Comprehension -3
A 0.5 L reaction vessel which is equipped with a
Comprehension -5
movable piston is filled completely with a 1M
aqueous solution of H2O2 .The H2O2 decomposes (i) P + C (carbon) + Cl2 — Q + CO 
to H2O and O2(g) in a first order process with half (ii) Q + H2O — R + HCl
life 10 hrs at 300 K. As gas decomposes, the piston (iii) BN + H2O — R + NH3 
moves up against constant external pressure of 750
(iv) Q + LiAlH4 — S + LiCl + AlCl3
mm Hg.
(v) S + H2O — R + H2
64. What is the net work done by the gas from the start
of sixth hour till the end of 10 hrs? (vi) S + NaH — T
(A) 100 J (B) 120 J (P, Q, R, S & T do not represent their chemical
symbols)
(C) 130 J (D) 150 J
68. Compound Q has
I. zero dipole moment
65. If H for decomposition of H2O2(aq.) is X K J/mole, II. A planar trigonal structure
how much heat has been exchanged with III. An electron deficient compound
surrounding to maintain temperature at 300 K (in
IV. A Lewis base
KJ) from the start of 6th hour till the end of 10th
hour. Choose the correct code :
(A) –0.1035 X (B) –0.2070 X (A) I, IV (B) I, III, IV
(C) I, II, III (D) I, II, III, IV
(C) –0.052 X (D) 0.026 X
69. Compound T is used as a/an

(A) Oxidising Agent (B) Complexing Agent
(C) Bleaching Agent (D) Reducing Agent
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70. Compound S is each other are called diastereomers. Enantiomers
I. An odd-e– compound are always chiral molecules whereas diastereomers
may or may not be chiral, configuration of the
II. (2c – 3e–) compound compound having no element of symmetry is
III. An electron deficient compound always chiral. Chiral molecule may or may not
IV. A sp2 hybridized compound contain chiral carbon.
Choose the correct code : 74. Which of the following compounds are chiral?
(A) III (B) I, III
(C) II, III, IV (D) I, II, IV
(A)
Comprehension -6
An element (X) having same chemical properties
as that of hydrogen atom. The diatomic molecule
(B)
X2 is gaseous in nature. The energy required to
remove an electron from the outermost shell of (X)
atom is 13.5 eV. It is also found that the time taken
for diffusion of equal volume of gaseous X2 & O2 (C)
at the same pressure is in the ratio 3 : 4 . The
(D) All of these
normal freezing point of pure X2O is 0°C. However
on adding 0.02 moles of a non-electrolyte solute to
0.8 moles of X2O, the freezing point of solution is
75. Which of the following pairs are diastereomers ?
found to be –1.25°C. X-atom also obey Bohr's model.
71. When 3 gm of a weak monoprotic acid (Mw = 60) is
added to 0.8 moles of X2O, the resulting solution (A) and
freeze at – 3.75°C. What is degree of dissociation
for weak acid.
(A) 0.10 (B) 0.20
(C) 0.30 (D) 0.40
(B) and
72. What amount of electricity is required to produce

3.3 gm of X2 gas by electrolysis of X2O.
(A) 0.1 F (B)1.1 F
(C) 0.3 F (D) 0.4 F (C) and
(D) All of these

73. What will be the energy required to excite 5 (X)
atoms to second excited state.
(A) 30 eV (B) 60 eV 76. Which one of the following pairs is correctly
matched?
(C) 120 eV (D) 15 eV
(A) enantiomers:
Comprehension -7
Isomers which are nonsuper-imposable mirror
images of each other are called enantiomers. All and
optically active compounds exhibit enantiomerism.
The stereoisomers which are not mirror images of
Rajasthan
(B) Diastereomers: 79. The compound (E) responds to following
properties
(A) It giveswhiteppt with (CH3COO)2 Pb solution
soluble in ammonium acetate
and (B) It gives dirty white ppt with K
(C) Its hydrated salt effloresces
(D) All of these
80. When a piece of iron or zinc is added to the solution

of compound (F) in dil HNO3
(C) meso form
(A) a reddish brown ppt is formed
(B) a white ppt is formed
(C) a black ppt is formed
(D) Enantiomer (D) none of these
Comprehension - 9
and
Complex compounds which have same molecular
formula but have different structural arrangements
of ligands around central metal atom or ion are called
structural isomers and phenomenon is named as
structural isomerism.
81. Which of the following compounds is/are poly-
Comprehension 8 merisation isomer of [Fe(NO2)3(NH3)3].
A black coloured compound (A) on reaction with (I) [Fe(NO2)(NH3)5] [Fe(NO2)5(NH3)]
dil. H2SO4 gives a gas (B) which on passing in a (II) [Fe(NO2)2(NH3)4]2 [Fe(NO2)5(NH3)]
solution of an acid (C) gives a white turbidity (D). (III) [Fe(NO2)(NH3)5] [Fe(NO2)4(NH3)2]2
Gas (B) when passed in an acidified solution of a
compound (E) gives a black ppt (F) which is soluble (IV) [Fe(NO2)2(NH3)4] [Fe(NO2)4(NH3)2]
in dil. HNO3. After boiling this solution when excess Choose the correct code :
of NH4OH is added, a blue coloured compound (G) (A) II, III (B) II, III, IV
is formed. To this solution on addition of acetic (C) I, IV (D) I, II, III, IV
acid and aqueous potassium ferrocyanide, a
chocolate brown ppt (H) is formed. On addition of
an aqueous solution of BaCl 2 to an aqueous 82. How many more coordination isomers are possible
solution of (E) white ppt. insoluble in HNO3 is of the following complex compound.
obtained.
[PtCl2 (NH3)4] [Pt (SCN)4]
77. Black colourd compound (A) is
(A) 5 (B) 6
(A) PbS (B) CuS
(C) 8 (D) 9
(C) FeS (D) All of these
78. The gas (B) on passing through an acid (C) gives a 83. Select incorrect match
white turbidity (D) because (A) [Co(NO2)(H2O)(en)2)]Cl2, [CoCl(NO2)(en)2] Cl .
(A) Gas (B) acts as an oxidising agent H2O - Hydrate isomerism
(B) Gas (B) acts as an reducing agent (B) [Cu(NH3)4][PtCl4],[CuCl2(NH3)2]
(C) Acid (C) acts as an oxidising agent [PtCl2(NH3)2] - Coordination isomerism
(D) (B) and (C) both (C) [Ni(CN)(H2O)(NH3)4]Cl,
[NiCl(H2O)(NH3)4]CN - Ionization isomerism
(D) [Cr(NCS)(NH3)5] [ZnCl4], [Cr(SCN)(NH3)5]
[ZnCl4] - Linkage isomerism
Rajasthan
Comprehension -10
84. Type of hybridization of complex (M) is

(A) sp3d2 (B) d2sp3 (C) dsp2 (D) sp3
85. Water of crystallization in salt (A)

(A) 5 (B) 6 (C) 7 (D) 10
86. Compound (H) + X + FeCl3 — Blood Red Colouration.

The unknown compound X is?
(A) NaOCN (B) NaCN (C) NaNC (D) Na2S2O3
Matrix Match
87. Column A Column B
(A) Caprolactum formation take place in (P) HN

3 

H 2SO 4

(B) Beckmann rearrangement is (Q) H

( i ) CHCl / HO 
3
(C) Schmidt reaction is (R)    
( ii ) H 
Rajasthan
(D) Reaction in which number of (S) PCl

5 
carbon increases
88. Column I Column II
HCN LiAlH 4 NaNO

(A)  (A)   2  (C)
 (B)   (P) Formation of six member ring takes
traces of KOH HCl
place
NH OH LAHH
(B)  (A)  (B)  (C)
 2 (Q) Final product is Ketone

O O
|| || HO 
(C) CH 3  C  CH 2  CH 2  CH 2  C  H  (A) (R) Final product formed will give

positive Tollen's test
(S) Final product formed will react

H

(D)  (A) with 2,4-DNP.
(2,4-Di-nitrophenyl hydrazine)
89. Column I Column II

(A) 2s (P) Number of radial node = 1
2
r
(B) (Q) Number of maxima in radial probability

distribution curve = 2
r
r
(C) (R) Number of angular node = 0
(D) 4d (S) angular depends upon 
Rajasthan
90. Column-I (Carbanions) Column -II (Half lives)
(a) (P) 4.3 × 10–8 s
(b) (Q) 2.5 × 10–5 s
(c) (R) 8.7 × 10–7 s
(d) (S) 1.4 × 10–4 s
91. Column – I Column – II

(A) FeSO4 (P) Green ppt with NaOH.
(B) Bi(NO3)3 (Q) White ppt. with Pb(NO3)2 .
(C) Ni(NO3)2 (R) Yellow ppt with (NH4) (NO2) + CH3COOH on warming
(D) CoCl2 (S) Black ppt. with H2S
92. 2 mol of an ideal gas (= 1.5) at 600 K is expanded adiabatically against a constant pressure of 8.21 atm from 2L to 8L.
The change in entropy of gas is (in cal/K).
[Given : ln2 = 0.7, ln(1.5) = 0.4, R = 2 cal/mol-K]
(A) 1.6 (B) 3.2 (C) 5.8 (D) 6.4
93. When 100 ml 0.8 M CH3COOH(aq) was mixed with 100 ml 0.4 M NaOH in an insulated calorimeter at constant
pressure, a temperature rise of 1.6 K was observed.
Given : Heat capacity of solution = 4.2 J g–1, Density of solution = 1 g/ml.
Heat capacity c' calorimeter = 0.5 kJ K–1 pKa (CH3COOH) = 5
(1H) H2 O(  )  286kJ mol1
( 1H) OH (aq)  229kJ mol 1
Rajasthan
(A) Enthalpy of neutralisation of HCl and NaOH is –57 kJ/mol
(B) Enthalpy of neutralisation of CH3COOH and KOH is –53.6 kJ/mol
(C) Enthalpy of dissociation of CH3COOH is 3.4 kJ/mol
(D) Final pH of solution in calorimeter is 5.
Subjective Type Questions

94. Give structures/configurations of the products (T) to (Z) of the following reactions :
C2H5 O
(i) N3H, Heat
(a) H3C H + D2 
Pd
 (T) + (U) (b) R C Cl (V)
(ii) H2O
CH CH2
D
(i) Mg, Ether
(c) I– + CH3 –– CH2 –– CH2 I — (W) (d) Br CH2 CH3 (X)
(ii) D2O
H
2+
(i) BH3, THF Cu
(e) H2C C COOH –
(Y) (f) 2HC C H (Y)
(ii) H2O2, OH O2
CH3
95. Predict the major products in the following reactions :

(i) C6H6 + (CH3)2CHCH2OH 
H 2SO 4

1. CH 3 MgBr(excess)
(ii) C6H5CH2COOCH3
2. H +
1. Br2, Heat, Light
(iii) C6H5C2H5
2. NaCN
CH3CH2 1. KCN/H2SO4
(iv) C O (D)
H 2. LiAlH4
(v) Predict the structure of the product in the following reaction.

Br
H Ph NaI
(C)
MeO H Acetone
Ph
(vi) Suggest the appropriate structure of the missing compounds.
(The number of carbon atoms remains the same throughout the reactions.)
CH3
Dil.KMnO 4 HIO 4 
HO
  (A)   (B)   (C)
CH3
96. Complete the following :
CH3 CH2CN
(A) Cl2 (C) 
(a) (B)  H3O
  (D)
AlCl3 (anhy.) hv
Rajasthan
NO2
Br2 / Fe Sn/HCl
NaNO2 Cu 2Cl2
(b)   (A)  (B) HCl 0-5° C (C)   (D)
NH3
(c) CH3CH2CH2OH 
P  Br2
 (A) 
KOH alc.
 (B) 
HBr
 (C) (D)
(d) C6H5COOC6H5 

Mononitration
 (A)
+
P2O 5 H
(e) C6H5CONH2   (A) (B)
H2O,
CHO
(g) C 6H 4 + HCHO 
KOH
 (A) + (B)
(P–) OCH 3
(i) NaNH2 (3.0 equiv.)
(v) C6H5 CH = CH2 
Br2
(A) (ii) CH 3I
(B)
O
(i) LiAlH4
O CHC6H5 (D)
[C] (ii) H+, Heat
(w)
97. Identify (X), (Y) and (Z) in the following synthetic scheme and write their structures.
(i) NaNH2 H 2 /Pd  BaSO 4 Alkaline KMnO 4
CH3CH2 C  CH (X)   (Y)  (Z)
(ii) CH3 CH2Br
Is the compound (Z) optically active ?
98. The major product P and Q in the reaction
AlCl3 H 3O
+ ClCH2CH2  CH3   P   Q + phenol are :
(A) + CH3CH2CHO (B) + CH3CHO
(C) + CH3COCH3 (D) + CH3CH2CHO
99. A light bluish green crystalline solid responds the following tests :
(i) Its aqueous solution gives brown precipitate or colour with alkaline K2HgI4 solution
(ii) Its aqueous solution gives blue colour with K3Fe(CN)6 solution
(iii) Its solution in HCl gives white ppt. with BaCl2 solution
Identify the ions present and suggest formula of compound.
Rajasthan
100. (i) A powdered substance (A) on treatment with fusion mixture gives a green coloured compound (B).
(ii) The solution of (B) in boiling water on acidification with dilute H2SO4 gives a pink coloured compound (C).
(iii) The aqueous solution of (A) on treatment with excess of NaOH and bromine water gives a compound (D).
(iv) A solution of (D) in conc. HNO3 on treatment with lead peroxide at boiling temperature produced a compound (E)
which was of the same colour as that of (C).
(v) A solution of (A) in dilute HCl on treatment with a solution of barium chloride gave a white precipitate of
compound (F) which was insoluble in conc. HNO3 and conc. HCl.
Rajasthan
1. A 2. B 3. B 4. C 5. A 6. C 7. D
8. B 9. D 10. D 11. D 12. B 13. A 14. A
15. C 16. A 17. B 18. D 19. D 20. A 21. A
22. A 23. B 24. A 25. B 26. ACD 27. D 28. B
29. ACD 30. BD 31. ABCD 32. ABCD 33. BD 34. BC 35. ABD
36. ACD 37. ACD 38. ABCD 39. ABD 40. ABC 41. BD 42. CD
43. BC 44. AD 45. AC 46. BC 47. AD 48. BD 49. BCD
50. ACD 51. 100 52. 5 atm 53. 12 54. 4300 55. 50 56. 0728
57. 0045 58. 356 59. B 60. A 61. A 62. B 63. A
64. C 66. C 67. B 68. C 69. D 70. A 71. B
72. B 73. B 74. D 75. C 76. B 77. D 78. D
79. D 80. A 81. D 82. C 83. B 84. D 85. C

86. B
87. (A) P, Q, (B) Q, S, (C) P, (D) R 88. (A) P, Q, S; (B) P; (C) P, Q, S; (D) P, Q, S
89. (A) P,Q,R ; (B) P,Q,S ; (C)  R ; (D) P,Q,R 90. (A) R, (B) S, (C) Q, (D) P
91. A P, Q, S; BS; C P , S; DR, S 92. B
93. AB 98. C
Rajasthan

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Question Bank of Chemistry

Single Correct Questions 6. The lowering of vapour pressure in a saturated aq.

4. The activation energies of two reactions I and II o o o

10. An aqueous solution of Na2SO4 was electrolysed

followed by hydrolysis yields

(A) Iodoform (B) Fehling

26. Select reaction in which correct products are given:

22. Which among the following compounds will give 14 14

31. Select the correct statement:

32. Choose the incorrect option(s).

(D) MeI (excess) + NH3  Me3N

E oPb  2 / Pb  0.12 volt

34. Find out the reactant P and RX for Williamson

35. Which of the following statements(s) is /are true

The correct matches are -

43. (C) (D)

Which of the following are possible products (in

Final product (s) is/are - (B)

49. A transition metal M forms an Octahedral complex.

50. Cu2+ form many complexes in the aqueous solu-

Integer Type Questions

[Q] The correct option (s) is/are (Assuming major

ln X Fill your answer by multiplying it with 800.

Sum of  (x) + molecular weight of gas (y) +

k1 [ A ] [C] k1k 2 [ A ] [C]

69. Compound T is used as a/an

72. What amount of electricity is required to produce

(D) All of these

80. When a piece of iron or zinc is added to the solution

84. Type of hybridization of complex (M) is

85. Water of crystallization in salt (A)

86. Compound (H) + X + FeCl3 — Blood Red Colouration.

(A) Caprolactum formation take place in (P) HN

(D) Reaction in which number of (S) PCl

88. Column I Column II

HCN LiAlH 4 NaNO

89. Column I Column II

(B) (Q) Number of maxima in radial probability

(C) (R) Number of angular node = 0

(D) 4d (S) angular depends upon 

(a) (P) 4.3 × 10–8 s

(b) (Q) 2.5 × 10–5 s

(c) (R) 8.7 × 10–7 s

(d) (S) 1.4 × 10–4 s

91. Column – I Column – II

( 1H) OH (aq)  229kJ mol 1

Subjective Type Questions

95. Predict the major products in the following reactions :

(v) Predict the structure of the product in the following reaction.

(d) C6H5COOC6H5 

98. The major product P and Q in the reaction

(A) + CH3CH2CHO (B) + CH3CHO

(C) + CH3COCH3 (D) + CH3CH2CHO

79. D 80. A 81. D 82. C 83. B 84. D 85. C

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