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11 Main product cooler

komponenmasuk keluar
fraksi mas flowrate (kg/jamfraksi massa flowrate
H2O 0.004279 9.0869002295 0.004278842 9.0869002295
C2H5OH 0.993747 2110.4015527 0.993746533 2110.40155271
CH3COOH 0.001975 4.1934735899 0.001974624 4.1934735899
Total 1 2123.6819265 1 2123.68192653

10 nermas komponen ethanol dehydrator d-430


komponenmasuk 35 keluar 37 keluar
fraksi mas flowrate (kg/jamfraksi massa flowrate fraksi massa
H2O 0.052673 120.43319917 0.004278842 9.0869002295 0.6842352748
C2H5OH 0.923019 2110.4015527 0.993746533 2110.40155271 0
CH3COOH 0.024308 55.5781869828 0.001974624 4.1934735899 0.3157647252
Total 1 2286.4129389 1 2123.68192653 1
2286.413 2286.412938857

9 mixing tee
komponenmasuk 30 masuk 33 keluar
fraksi mas flowrate (kg/jamfraksi massa flowrate fraksi massa
H2O 0.035365 48.3672868743 0.078440278 72.0659122914 0.0526734244
C2H5OH 0.923999 1263.7314001 0.921559722 846.67015264 0.9230185488
CH3COOH 0.040637 55.5781869828 0 0 0.0243080268
Total 1 1367.6768739 1 918.736064932 1
2286.4129389

8 side product cooler


komponenmasuk 32 keluar 34
fraksi mas flowrate (kg/jamfraksi massa flowrate
H2O 0.000157 0.0632803418 0.000156567 0.0632803418
C2H5OH 0.001839 0.7434524169 0.001839441 0.7434524169
CH3COOH 0.998004 403.36637935 0.998003992 403.366379349
Total 1 404.17311211 1 404.173112108

7 Acetic acid dehydrator


komponenmasuk 31 keluar 32 keluar
fraksi mas flowrate (kg/jamfraksi massa flowrate fraksi massa
H2O 0.054523 72.1291926332 0.000156567 0.0632803418 0.0784402779
C2H5OH 0.640568 847.41360506 0.001839441 0.7434524169 0.9215597221
CH3COOH 0.304909 403.36637935 0.998003992 403.366379349 0
Total 1 1322.909177 1 404.173112108 1
1322.909177 1322.909177039

6 Distillation Column
komponenfeed 24 distillate 30 bottom
fraksi mas flowrate (kg/jamfraksi massa flowrate fraksi massa
H2O 0.044784 120.49647951 0.035364557 48.3672868743 0.054523163
C2H5OH 0.784641 2111.1450051 0.923998515 1263.73140007 0.6405682414
CH3COOH 0.170574 458.94456633 0.040636928 55.5781869828 0.3049085957
Total 1 2690.586051 1 1367.67687393 1
2690.586051 2690.586050965
5 Distillation feed preheater
komponenmasuk 23 keluar 24
fraksi mas flowrate (kg/jamfraksi massa flowrate
H2O 0.044784 120.49647951 0.044784473 120.496479508
C2H5OH 0.784641 2111.1450051 0.784641325 2111.14500513
CH3COOH 0.170574 458.94456633 0.170574201 458.944566332
Total 1 2690.586051 1 2690.58605096

4 Fermentation broth pump


komponenmasuk 22 keluar 23
fraksi mas flowrate (kg/jamfraksi massa flowrate
H2O 0.044784 120.49647951 0.044784473 120.496479508
C2H5OH 0.784641 2111.1450051 0.784641325 2111.14500513
CH3COOH 0.170574 458.94456633 0.170574201 458.944566332
Total 1 2690.586051 1 2690.58605096

3 Fermentation broth tank


komponenmasuk 21 keluar 22
fraksi mas flowrate (kg/jamfraksi massa flowrate
H2O 0.044784 120.49647951 0.044784473 120.496479508
C2H5OH 0.784641 2111.1450051 0.784641325 2111.14500513
CH3COOH 0.170574 458.94456633 0.170574201 458.944566332
Total 1 2690.586051 1 2690.58605096

2 Filtrate pump
komponenmasuk 21 keluar 22
fraksi mas flowrate (kg/jamfraksi massa flowrate
H2O 0.044784 120.49647951 0.044784473 120.496479508
C2H5OH 0.784641 2111.1450051 0.784641325 2111.14500513
CH3COOH 0.170574 458.94456633 0.170574201 458.944566332
Total 1 2690.586051 1 2690.58605096

Rotary vacuum filter


komponenmasuk 15 keluar 16 keluar
fraksi mas flowrate (kg/jamfraksi massa flowrate fraksi massa
H2O 0.035544 121.12624131 0.000878127 0.6297618011 0.0447844734
C2H5OH 0.622751 2122.1786759 0.015385124 11.0336707441 0.7846413254
CH3COOH 0.135381 461.34319041 0.003344592 2.3986240748 0.1705742012
Media ATC 0.157302 536.04561703 0.747451006 536.045617027 0
C. ljungdah0.049023 167.057213972 0.23294115 167.057213972 0
Total 1 3407.7509386 1 717.164887619 1
3407.7509386 3407.75093858

Fermentation tank
komponenmasuk 10 Reaksi keluar
fraksi mas flowrate (kg/jamgeneration consumption fraksi massa
CO 0.665866 4118.0429465 0 4118.04294647 0
CO2 0.27117 1677.0494109 4206.286724 2471.53313428 0
CH4 0.000876 5.4176072235 0 0 0
H2 0.051901 320.97832913 0 320.978329127 0
H2O 6.15E-05 0.3804216023 1444.402481 1323.65666137 0.0355443351
H2S 0.000344 2.125 0 0 0
N2 0.009783 60.5 0 0 0
C2H5OH 0 2122.178676 0 0.622750522
CH3COOH 0 461.3431904 0 0.1353805483
Total 1 6184.4937154 0
komponenmasuk 13 0
fraksi mas flowrate (kg/jam) 0
Media ATC 0.7624 536.04561703 0.1573018764
C. ljungdah 0.2376 167.057213972 0.0490227182
Total 1 703.102831 1
komponen keluar
fraksi massa
CO2 0.9804466592
CH4 0.0015568528
H2S 0.0006106593
N2 0.0173858288
Total 1
6887.5965464

propagation tank
komponenmasuk 11 masuk 12 keluar
fraksi mas flowrate (kg/jamfraksi massa flowrate fraksi massa
Media ATC 0 0 1 617.160625386 0.7624000266
C. ljungdah 1 85.9422056126 0 0.2375999734
total 1 85.9422056126 1 617.160625386 1
703.102831
7.1811122485
syngas cooler
komponenmasuk 9 keluar 10
fraksi mas flowrate (kg/jamfraksi massa flowrate
CO 0.665866 4118.0429465 0.665865815 4118.04294647
CO2 0.27117 1677.0494109 0.27117004 1677.04941093
CH4 0.000876 5.4176072235 0.000875999 5.4176072235
H2 0.051901 320.97832913 0.051900502 320.978329127
H2O 6.15E-05 0.3804216023 6.151217E-05 0.3804216023
H2S 0.000344 2.125 0.000343601 2.125
N2 0.009783 60.5 0.009782531 60.5
TOTAL 1 6184.4937154 1 6184.49371536

syngas expander
komponenmasuk 7 keluar 9
fraksi mas flowrate (kg/jamfraksi massa flowrate
CO 0.665866 4118.0429465 0.665865815 4118.04294647
CO2 0.27117 1677.0494109 0.27117004 1677.04941093
CH4 0.000876 5.4176072235 0.000875999 5.4176072235
H2 0.051901 320.97832913 0.051900502 320.978329127
H2O 6.15E-05 0.3804216023 6.151217E-05 0.3804216023
H2S 0.000344 2.125 0.000343601 2.125
N2 0.009783 60.5 0.009782531 60.5
TOTAL 1 6184.4937154 1 6184.49371536

Gassifier
Masuk keluar
5 7
komponenfraksi mas flowrate (kg/jamkomponen fraksi massa flowrate (kg/jam)
TJ 1 5000 CO 0.6658658147 4118.042946472
total 1 5000 CO2 0.2711700404 1677.049410934
CH4 0.0008759985 5.4176072235
6 H2 0.0519005021 320.9783291272
O2 1 1290 H2O 6.1512166E-05 0.3804216023
total 1 1290 H2S 0.0003436013 2.125
N2 0.0097825308 60.5
total 1 6184.49371536

keluar 8
C 1 105.1809348495
total 1 105.1809348495

total 6289.6746502 total 6289.6747

zona reduction
komponenmasuk zona reduction reaksi keluar 7
fraksi mas flowrate (kg/jamgeneration consumption fraksi massa
TJ 0 0
C 0.200674 1262.1712182 1156.99028 0
CO 0.347521 2185.7956085 2999.059056 1066.81172 0.6658658147
CO2 0.074907 471.14037923 1676.418414 470.50938 0.2711700404
CH4 0.000861 5.4176072235 0.0008759985
H2 0.011659 73.3325683409 247.6457608 0.0519005021
H2O 0.354421 2229.1922687 2228.81185 6.151216571E-05
H2S 0.000338 2.125 0.0003436013
N2 0.009619 60.5 0.0097825308
Total 1 6289.6746502 1
keluar 8
Komponen fraksi massa
C 1
Total 1
Total 1 6289.6746502 1
zona combustion
komponenmasuk zona reduction reaksi keluar, masuk reduction
fraksi mas flowrate (kg/jamgeneration consumption fraksi massa
TJ 0 0 0
C 0.420724 2103.618697 841.447478796 0.2006735306
CO 0.044876 224.37923251 1963.377451 1.9610744921 0.3475212519
CO2 0.093612 468.05869074 3.081688488 0 0.0749069555
CH4 0.001084 5.4176072235 0.0008613494
H2 0.018832 94.160976298 20.8284079571 0.011659199
H2O 0.408348 2041.7365971 187.4556716 0 0.3544209188
H2S 0.000425 2.125 0.0003378553
N2 0.0121 60.5 0.0096189395
Total 1 5000 0
Masuk 5 0
Komponenfraksi mas flowrate (kg/jam) 0
O2 1 1289.6778494 0
Total 1 1289.6778494 1
Total 1 6289.6746502

zona pyrolysis
masuk 5 reaksi keluar ke combustion
fraksi mas flowrate (kg/jamgeneration consumption fraksi massa
TJ 1 5000 5000 0
C 0 2103.618697 0.4207240086
CO 0 224.3792325 0.0448758752
CO2 0 468.0586907 0.093611798
CH4 0 5.417607223 0.0010835221
H2 0 94.1609763 0.0188322073
H2O 0 2041.736597 0.4083475807
H2S 0 2.125 0.0004250003
N2 0 60.5 0.0121000077
Total 1 5000 5000 5000 1

rumus molekul TJ dengan Berat molekul = 886


KomponenFraksi MasBM Mol (basis 100Mol (basis C) BM (Basis C)
C 0.4663 12 3.885833333 1 12
H 0.0645 1 6.45 1.6598756166 1.6598756166
O 0.4567 16 2.854375 0.7345592966 11.7529487454
N 0.0121 14 0.086428571 0.0222419656 0.3113875188
S 0.0004 32 0.00125 0.0003216813 0.0102938023
total 1 25.734505683
a
k 1
eq6 0
eq7 0
eq8 0
0.0897 C (s)

0.0009 H2S

Overall-%C(s)-%H2S
0.9094
0.0906

a=1 h=
>> I=

b
eq1 1
eq2 0
eq3 0
eq4 0
eq5 0
eq6 -121.779264214
eq7 11.9892
eq8 -10.9128
densitas v m3/j m3/d kl/yr kl/day
969.6597 0.009371 0.224909 67.47282748 0.204463114
789.3 2.673764 64.17032 19251.0974 58.33665879
1049 0.003998 0.095942 28.78265953 0.08722018
2.687132 64.49118 19347.35289 58.62834209

Neraca komponen
36 KomponenCampuran 35
flowrate Massa (kg/densitas (kg/m3)
111.34629894 0.075452 92.45482119 H2O 120.4332 969.6597
0 C2H5OH 2110.402 789.3
51.384713393 0.075452 92.45482119 CH3COOH 55.57819 1049
162.73101233 Total 2286.413

35
flowrate
120.43319917
2110.4015527
55.578186983
2286.4129389

33
flowrate asam asetat 99.8% H2O 72.1291926332
72.065912291 0.002 H2O +C2H5OH C2H5OH 847.4136050574
846.67015264 0.806732759 919.5427976906
0
918.73606493

Feed masuk dist col


31 KomponenFraksi Massa Flowrate (kg/j BM Fraksi mol Mole (kmole)
flowrate H2O 0.044784473 120.4964795 18 0.11113 6.6942488615
72.129192633 C2H5OH 0.784641325 2111.145005 46 0.761888 45.8944566332
847.41360506 CH3COOH 0.170574201 458.9445663 60 0.126981 7.6490761055
403.36637935 TOTAL 1 2690.586051 1 60.2377816002
1322.909177
C wt% ethanol diinginkan = 92.4%
Tb H2O 100 P= 101.325 kPa
Tb C2H5O 78.37 x1 0.11113
Tb CH3CO 118.1 x2 0.761888
Feed temp 95 x3 0.126981

untuk 92.4 % wt ethanol, diperlukan KomponenFeed 24


o mol H2O 0.4014 Fraksi mol mole (Kmole)
o mol C2H5 0.5986 H2O 0.11113 6.6942488615
- C2H5OH 0.761888 45.8944566332
CH3COOH 0.126981 7.6490761055
1 60.2377816002
60.2377816002

17
flowrate
120.49647951
2111.1450051
458.94456633
0 dry cake 703.102831 H2O 121.1262413086
0 2% filtrat H2O + C2H5OH +CH3COOH C2H5OH 2122.1786758696
2690.586051 14.06205662 CH3COOH 461.3431904064
2704.6481075846
15
flowrate
6H2 2CO2 = C2H5OH 3H2O
m 288.8804962 2118.456972 1107.375 1299.9622329652
n 144.4402481 48.14674937 24.07337 72.2201240536
2407.337468 2407.3374684541
121.12624131 6CO 3H2O = C2H5OH 4CO2
m 3706.238652 1191.290995 1014.803 3882.726206674
n 132.3656661 66.18283307 22.06094 88.2437774244
2122.1786759 4897.529647 4897.5296470547
461.34319041 4CO 2H2O = CH3COOH 2CO2
m 411.8042946 132.3656661 220.6094 323.5605172228
n 14.70729624 7.353648119 3.676824 7.3536481187
544.1699608 544.1699607839
536.04561703 2CO2 4H2 = CH3COOH 2H2O
167.05721397 m 353.076162 32.09783291 240.7337 144.4402481072
3407.7509386 n 8.024458228 16.04891646 4.012229 8.0244582282
14 385.173995 385.1739949527
flowrate
3411.8030006
5.4176072235
2.125
60.5
3479.8456078
6887.5965464

Volume yg akan di fermentasi (syngas)


13 Komponen Flowrate (kg/j Massa jen volume (m3/jam)
flowrate CO 4118.042946 1.1 4529.847
536.04561703 CO2 1677.049411 1.729 2899.618
167.05721397 CH4 5.417607223 0.6302 3.414176
703.102831 H2 320.9783291 0.0792 25.42148
703.102831 H2O 0.380421602 998.2 379.7368
H2S 2.125 1.339 2.845375
N2 60.5 0.03928 2.37644
Total 6184.493715 7843.26
81.115008359
X0 0.04448 g/L X=
Xm 0.15089 g/L densitas mikroba
μm 0.196 /jam
k 0.033 /jam
t 48 jam

Vtotal starter = Vlar + Vmik


= V lar + Juml mik/X
= V lar + mikroba diinokulasi x V lar/X
V mik diinokula10% V lar
massa mik diinokulasi = 10% vlar x X
v total starter V lar + mik diinokulasi x X x V lar/X
v total starter V lar + 0.1 Vlar^2
784.3259991 = V lar +0.1 Vlar^2

V lar 0.1 V lar ^2


83.70322592 700.623003 784.3262

V lar = 83.70322592 m3/jam 83703.23 L/jam


V mik = V total starter - V lar
784.3259991 83.70323
V mik = 700.6227731 m3/jam
massa mik diinokulasi = 1.026749

flowrate (kg/jam) rx 1 XC= 0.061


komponenkoef consumption MR n
0 C 1 128.3207405 12 10.6934
4118.0429465 CO2 1 470.5093819 44 10.6934
1677.0494109 CO gen 2 598.8301224 28 21.38679
5.4176072235 rx 2 XC= 0.489
320.97832913 komponenkoef consumption MR n
0.3804216023 C 1 1028.669543 12 85.72246
2.125 H2O 1 1543.004314 18 85.72246
60.5 CO gen 1 2400.228933 28 85.72246
6184.4937154 H2 gen 1 171.4449238 2 85.72246
rx 3 X CO "=" 0.488065633
flowrate (kg/jam) komponenkoef consumption MR n
105.18093 CO 1 1066.811718 28 38.10042
105.18093485 H2O 1 685.8075328 18 38.10042
6289.6746502 CO2 gen 1 1676.418414 44 38.10042
H2 gen 1 76.20083698 2 38.10042
masuk reduction
flowrate (kg/jam)
0 KomponenX Consumption MR n
1262.1712182 C 0.4 841.4474788 12 70.12062
2185.7956085 CO 0.00874 1.961074492 28 0.070038
471.14037923 H2 0.2212 20.82840796 2 10.4142
5.4176072235
73.332568341 Komponenkoefisien mole O2 need m O2 mi
2229.1922687 CO 0.5 35.06031162 1121.93 1963.377
2.125 CO2 0.5 0.035019187 1.120614 3.081688
60.5 H2O 0.5 5.207101989 166.6273 187.4557
1289.678

0.999999491362
0 6289.678 6289.675
6289.6746502
6289.67465
31.063 1.42

ke combustion C%
flowrate (kg/jam) C(s) CH4
0 886 0.90226 0.001742743
2103.618697 31.06344 2103.618697 a 1
224.37923251 1.42 224.3792325 C b 31.0634360922
468.05869074 1.885 468.0586907 CH4 c 0.06
5.4176072235 0.06 5.417607223 CO d 1.42
94.160976298 8.342663 94.1609763 CO2 e 1.885
2041.7365971 20.09976 2041.736597 H2 f 8.3426625
2.125 0.011075 2.125 H2O g 20.0997625
60.5 0.382879 60.5 H2S h 0.011075
5000 N2 i 0.3828785714
C
kg/kmol C 34.428 a = b
Rasio mol H 57.147 a =
34.428483333 m O 25.29 a =
57.147 n N 0.766 a =
25.2897625 o S 0.011 a =
0.7657571429 p 0a= -121.779b
0.011075 q 0a= 12b
117.64207798

259.29188568 C H
34.42848 eq 1 a 34.428 eq 2
=
57.147 b 1
25.28976 c 1
0.765757 d 1
0.011075 e 1
f
g
h
i

a = b c
eq1 34.428 1 1
eq2 57.147 4
eq3 25.290
eq4 0.766
eq5 0.011
b = c d
0.0897 C (s) eq6 121.7792642 16 28
h = b c
0.0009 H2S eq7 37743.77778 12 16

Overall-%C(s)-%H2S b h = c
0.9094 12 34 16
0.0906 eq8 10.9128 30.9196 1.4496

a=1 h= 0.382878571
>> I= 0.011075

b c d e f g h i
31.063 0.06 1.42 1.885 8.3425 20.1 0.011075 0.3828785714
-121.7792642 16 28 44 2 18 34 28
12 16 28 44 2 18 -37743.8 28
-10.9128 1.4496 2.5368 3.9864 0.1812 1.6308 -30.9196 2.5368

-3782.829284 0.96 39.76 82.94 16.685 361.8 0.37655 10.7206


372.756 0.96 39.76 82.94 16.685 361.8 -418.012 10.7206
-338.9843064 0.086976 3.602256 7.514364 1.511661 32.77908 -0.34243 0.97128636
a = b c d e f
eq1 34.428 1 1 1 1
eq2 57.147 4 2
eq3 25.290 1 2
eq4 0.766
eq5 0.011
b = c d e f g
eq6 121.7793 14.5648 25.4884 40.0532 1.8206 16.3854
h = b c d e f
eq7 37743.78 11.9892 15.9856 27.9748 43.9604 1.9982

b h = c d e f
12 34 16 28 44 2
eq8 10.9128 30.9196 1.4496 2.5368 3.9864 0.1812

0.3828785714
0.011075

c d e f g h i =
1 1 1 0 0 0 0 34.428
4 0 0 2 2 2 0 57.147
0 1 2 0 1 0 0 25.290
0 0 0 0 0 0 2 0.766
0 0 0 0 0 1 0 0.011
14.5648 25.4884 40.0532 1.8206 16.3854 30.9502 25.4884 0.000
15.9856 27.9748 43.9604 1.9982 17.9838 -37743.8 27.9748 0.000
1.4496 2.5368 3.9864 0.1812 1.6308 -30.9196 2.5368 0
Produk bioetanol 37 Terserap absorber 36
Volume (m3) %V Volume (m3) %V Volume (m3)
0.1242015102 0.003487445 0.009371226 0.700976 0.11483
2.6737635281 0.995024876 2.6737635281 0 0
0.0529820658 0.001487679 0.0039975916 0.299024 0.048984
2.8509471041 1 2.6871323457 1 0.163815
2.8509471041 2.850947

H2O 0.1242015102 0.700976 0.009371


CH3COOH 0.0529820658 0.299024 0.003998
0.177183576
0.005 0.013368818

0.0784402779 0.063280342
0.9215597221 0.743452417

Konstanta Antoine
Komponen A B C
H2O 16.262 3799.89 226.35
C2H5OH 16.6758 3674.49 226.45
CH3COOH 7.8152 1800.03 246.894
goalseek
BUBL T = 83.339005508 P= 101.325
Komponen xi ln Psat Psat ki αi log αi
H2O 0.1111304016 3.991981 54.16208 0.5345381202 1 0
C2H5OH 0.7618882272 4.814533 123.2893 1.2167704493 2.276302 0.35723
CH3COOH 0.1269813712 2.364412 10.63779 0.1049867782 0.196407 -0.706844
Total 1

Distillate 30 Bottom 31
Fraksi mol mole (Kmole) Fraksi mol mole (Kmole)
0.0864404908 2.687071493 0.1374581297 4.007177
0.883761234 27.47242174 0.6319307153 18.42203
0.0297982753 0.926303116 0.230611155 6.722773
1 31.08579635 1 29.15199
60.2377816

filtrate
0.0447844734 0.629761801
0.7846413254 11.03367074
0.1705742012 2.398624075
generation consumption
CO 0 4118.043
CO2 4206.2867239 2471.533
CH4
H2 320.9783
H2O 1444.4024811 1323.657
H2S
N2
C2H5OH 2122.1786759
CH3COOH 461.34319041
8234.2110712 8234.211

rasio Laju Pertumbuhan


volume substrat dif volume substrat memfermentasi X= 1.026749 kg/m3
10 1 k0 = 0.196 /jam
7843.2599907367 784.3259991 Km = 0.68 kg/m3
S 7.3732 kg/m3

dx/dt = 0.18425
Massa ditambah 85.94221
Vr = 0.020189
Pertumbuhan 48 jam
Mikroba tumbuh81.11501 kg
0.1226654067 g/L
0.1226654067 kg/m3
2185.7716
1066.8
0.488060272 0.4880656332

C 1156.990283

H2O 2228.811847
0.000000508638

1.885 0.06

CO CO2
0.0412449188 0.054751177

O 404.6362
O left= 321.5962
20.09976
H 57.147
H left= 16.68533
8.342663

CH4 CO CO2 H2 H2O H2S N2


c d e
4c 2f 2g 2h
d 2e 2g
2i
h
16c 28d 44e 2f 18g 34h 28i
16c 28d 44e 2f 18g -37742.778h 28i

O N
a 57.147 eq 3 a 25.290 eq 4
= =
b b
c 4 c
d d 1
e e 2
f 2 f
g 2 g 2
h 2 h
i i

d e f g h i
1 1
2 2 2
1 2 1
2
1
e f g h i
44 2 18 34 28
d e f g i
28 44 2 18 28

d e f g i
28 44 2 18 28
2.5368 3.9864 0.1812 1.6308 2.5368

-3269.58713 513.24215
467.6092611 885.6216
-292.861118 46.46562336

886
12 372.75785 31.06315
34 0.3784 0.011129
g h i

2 2
1
2
1
h i
30.9502 25.4884
g i
17.9838 27.9748

g i
18 28
1.6308 2.5368
yi
0.0594034
0.9270431
0.0133314
0.9997779
goalseek to 1
Media per 1L
Komponen massa (gram)
NH4CL 1
KCL 0.1
MgSO4.7H2O 0.2
NaCl 0.8
KH2PO4 0.1
CaCl2.2H2O 0.02
Yeast extract 1
10 ml trace element solution (mL): 10
Nitrilotriacetic acid 2
MnSO4.H2O 1
Fe(SO4)2(NH4)2.6H2O 0.8
CoCl2.6H2O 0.2
ZnSO4.7H2O 0.0002
CuCl2.2H2O 0.02
NiCl2.6H2O 0.02
Na2MoO4.2H2O 0.02
Na2SeO4 0.02
Na2WO4 0.02
10 Vitamin solutions (mL) 10
Biotin 0.002
Folic acid 0.002
Pyridoxine-HCl 0.01
Thiamine-HCl 0.005
Riboflavin 0.005
Nicotinic acid 0.005
Calcium D(+) panthotnate 0.005
Vitamin B12 0.0001
P-aminobenzoic acid 0.005
Thiotic acid 0.005
100 Reacting agent solution (mL): 100
NaOH 0.0009
L-Cysteine-HCl 0.004
Na2S.9H2O 0.004
S
a 0.766 eq 5 a
= =
b b
c c
d d
e e
f f
g g
h h
i 2 i
media per 83703.23 L
Komponen massa (gram)
NH4CL 83703.23
KCL 8370.323
MgSO4.7H2O 16740.65
NaCl 66962.58
KH2PO4 8370.323
CaCl2.2H2O 1674.065
Yeast extract 83703.23
trace element solution (mL): 837032.3
Nitrilotriacetic acid 167406.5
MnSO4.H2O 83703.23
Fe(SO4)2(NH4)2.6H2O 66962.58
CoCl2.6H2O 16740.65
ZnSO4.7H2O 16.74065
CuCl2.2H2O 1674.065
NiCl2.6H2O 1674.065
Na2MoO4.2H2O 1674.065
Na2SeO4 1674.065
Na2WO4 1674.065
Vitamin solutions (mL) 837032.3
Biotin 167.4065
Folic acid 167.4065
Pyridoxine-HCl 837.0323
Thiamine-HCl 418.5161
Riboflavin 418.5161
Nicotinic acid 418.5161
Calcium D(+) panthotnate 418.5161
Vitamin B12 8.370323
P-aminobenzoic acid 418.5161
Thiotic acid 418.5161
Reacting agent solution (mL): 8370323
NaOH 75.3329
L-Cysteine-HCl 334.8129
Na2S.9H2O 334.8129
617160.6 g
7.3732 kg/m3
C (s) 0.0897 H2S 0.0009
0.011 eq 6 b 121.779 eq 7 h
= =
b
c 16 c
d 28 d
e 44 e
f 2 f
g 18 g
1 h 34
i 28 i
37743.778

16
16
28
44
2
18

28
11 Main product cooler
masuk keluar
komponen
fraksi massa flowrate (kg/jam) fraksi massa
H2O 0.006075189 10.0086755496 0.006075189
C2H5OH 0.9931319108 1636.1524039375 0.9931319108
CH3COOH 0.0007929002 1.3062771783 0.0007929002
Total 1 1647.4673566654 1

10 nermas komponen ethanol dehydrator d-430


masuk 35 keluar
komponen
fraksi massa flowrate (kg/jam) fraksi massa
H2O 0.151179908 291.6411323228 0.006075189
C2H5OH 0.8481429486 1636.1524039375 0.9931319108
CH3COOH 0.0006771434 1.3062771783 0.0007929002
1 1929.0998134386 1
Total
1929.0998134386

9 mixing tee
komponen masuk 30 masuk
fraksi massa flowrate (kg/jam) fraksi massa
H2O 0.0747680013 79.2768577095 0.244435372
C2H5OH 0.9240000158 979.7214921295 0.755564628
CH3COOH 0.0012319829 1.3062771783 0
Total 1 1060.3046270173 1
1929.0998134386

8 side product cooler


masuk 32 keluar
komponen
fraksi massa flowrate (kg/jam) fraksi massa
H2O 0.000487895 0.1733024701 0.000487895
C2H5OH 0.001508113 0.535688494 0.001508113
CH3COOH 0.998003992 354.495482046 0.998003992
Total 1 355.20447301 1

7 Acetic acid dehydrator


masuk 31 keluar
komponen
fraksi massa flowrate (kg/jam) fraksi massa
H2O 0.1736418597 212.5375770834 0.000487895
C2H5OH 0.5367375679 656.966600302 0.001508113
CH3COOH 0.2896205725 354.495482046 0.998003992
1 1223.9996594314 1
Total
1223.9996594314

6 Distillation Column
feed 24 distillate
komponen
fraksi massa flowrate (kg/jam) fraksi massa
H2O 0.1277476195 291.8144347929 0.0747680171
C2H5OH 0.7164930268 1636.6880924315 0.924
CH3COOH 0.1557593537 355.8017592242 0.0012319829
1 2284.3042864486 1
Total
2284.3042864486
5 Distillation feed preheater
masuk 23 keluar
komponen
fraksi massa flowrate (kg/jam) fraksi massa
H2O 0.1277476195 291.8144347929 0.1277476195
C2H5OH 0.7164930268 1636.6880924315 0.7164930268
CH3COOH 0.1557593537 355.8017592242 0.1557593537
Total 1 2284.3042864486 1

4 Fermentation broth pump


masuk 22 keluar
komponen
fraksi massa flowrate (kg/jam) fraksi massa
H2O 0.1277476195 291.8144347929 0.1277476195
C2H5OH 0.7164930268 1636.6880924315 0.7164930268
CH3COOH 0.1557593537 355.8017592242 0.1557593537
Total 1 2284.3042864486 1

3 Fermentation broth tank


masuk 21 keluar
komponen
fraksi massa flowrate (kg/jam) fraksi massa
H2O 0.1277476195 291.8144347929 0.1277476195
C2H5OH 0.7164930268 1636.6880924315 0.7164930268
CH3COOH 0.1557593537 355.8017592242 0.1557593537
Total 1 2284.3042864486 1

2 Filtrate pump
masuk 21 keluar
komponen
fraksi massa flowrate (kg/jam) fraksi massa
H2O 0.1277476195 291.8144347929 0.1277476195
C2H5OH 0.7164930268 1636.6880924315 0.7164930268
CH3COOH 0.1557593537 355.8017592242 0.1557593537
Total 1 2284.3042864486 1

Rotary vacuum filter


masuk 15 keluar
komponen
fraksi massa flowrate (kg/jam) fraksi massa
H2O 0.0978223703 293.6108290513 0.0025048553
C2H5OH 0.548652464 1646.7634579428 0.0140488829
CH3COOH 0.1192722748 357.9920560745 0.003054105
Media ATCC 1754 PETC 0.2047231036 614.4700846678 0.8568044745
C. ljungdahlii 0.0295297873 88.6327463309 0.1235876824
1 3001.4691740673 1
Total
3001.4691740673

Fermentation tank
masuk 10 Reaksi
komponen
fraksi massa flowrate (kg/jam) generation
CO 0.6349585686 3243.8011836396 0
CO2 0.2585832414 1321.0194587384 3313.3112090033
CH4 0.0008353376 4.2674738832 0
H2 0.0480794604 245.622656887 0
H2O 0.0452091693 230.9592535153 1105.3019559916
H2S 0.0060158183 30.7329006849 0
N2 0.0063184043 32.2787158089 0
C2H5OH 0 1646.7634579428
CH3COOH 0 357.9920560745
Total 1 5108.6816431572
masuk 13
komponen
fraksi massa flowrate (kg/jam)
Media ATCC 1754 PETC 0.873940564 614.4700846678
C. ljungdahlii 0.126059436 88.6327463309
Total 1 703.1028309987

komponen

CO2
CH4
H2S
N2

Total
5811.7844741559

propagation tank
masuk 11 masuk
komponen
fraksi massa flowrate (kg/jam) fraksi massa
Media ATCC 1754 PETC 0 0 1
C. ljungdahlii 1 85.9422056126 0
1 85.9422056126 1
total
703.1028309987

syngas cooler
masuk 9 keluar
komponen
fraksi massa flowrate (kg/jam) fraksi massa
CO 0.6349585686 3243.8011836396 0.6349585686
CO2 0.2585832414 1321.0194587384 0.2585832414
CH4 0.0008353376 4.2674738832 0.0008353376
H2 0.0480794604 245.622656887 0.0480794604
H2O 0.0452091693 230.9592535153 0.0452091693
H2S 0.0060158183 30.7329006849 0.0060158183
N2 0.0063184043 32.2787158089 0.0063184043
TOTAL 1 5108.6816431572 1

syngas expander
masuk 7 keluar
komponen
komponen
fraksi massa flowrate (kg/jam) fraksi massa
CO 0.6349585686 3243.8011836396 0.6349585686
CO2 0.2585832414 1321.0194587384 0.2585832414
CH4 0.0008353376 4.2674738832 0.0008353376
H2 0.0480794604 245.622656887 0.0480794604
H2O 0.0452091693 230.9592535153 0.0452091693
H2S 0.0060158183 30.7329006849 0.0060158183
N2 0.0063184043 32.2787158089 0.0063184043
TOTAL 1 5108.6816431572 1

Gassifier
Masuk keluar
5 7
komponen fraksi massa flowrate (kg/jam) komponen
TJ 1 4192 CO
total 1 4192 CO2
6 CH4
komponen fraksi massa flowrate (kg/jam) H2
O2 1 999 H2O
total 1 999 H2S
N2
total
keluar 8
komponen
C
total

total 5191.5331445611 total

zona reduction
masuk zona reduction reaksi
komponen
fraksi massa flowrate (kg/jam) generation
TJ 0
C 0.1915075931 994.2180168476
CO 0.3316479174 1721.7611555616 2362.3724766984
CO2 0.0714855154 371.1194224247 1320.5224192608
CH4 0.0008220065 4.2674738832
H2 0.0097371936 50.5509632685 195.0716936185
H2O 0.3826623929 1986.6044960818
H2S 0.0059198121 30.7329006849
N2 0.0062175691 32.2787158089
Total 1 5191.5331445611

Komponen
C
Total
Total 1 5191.5331445611
zona combustion
komponen masuk zona reduction reaksi
fraksi massa flowrate (kg/jam) generation
TJ 0 0
C 0.395280251 1657.0300280793
CO 0.0421619562 176.7445433296 1546.5613595407
CO2 0.0879505193 368.6919623681 2.4274600565
CH4 0.0010179949 4.2674738832
H2 0.0154838242 64.9087869395
H2O 0.4430741954 1857.3840830425 129.2204130392
H2S 0.0073312544 30.7329006849
N2 0.0077000046 32.2787158089
Total 1 4192
Masuk 5
Komponen fraksi massa flowrate (kg/jam)
O2 1 999.494650425
Total 1 999.494650425
Total 1 5191.5331445611

zona pyrolysis
masuk 5 reaksi
Komponen
fraksi massa flowrate (kg/jam) generation
TJ 1 4192.0410141382
C 0 1657.0300280793
CO 0 176.7445433296
CO2 0 368.6919623681
CH4 0 4.2674738832
H2 0 64.9087869395
H2O 0 1857.3840830425
H2S 0 30.7329006849
N2 0 32.2787158089
Total 1 4192.0410141382 4192

rumus molekul TJ dengan Berat molekul =


Komponen Fraksi Massa BM Mol (basis 100gr)
C 0.4381 12 3.6508333333
H 0.0654 1 6.54
O 0.4819 16 3.011875
N 0.0077 14 0.055
S 0.0069 32 0.0215625
total 1
keluar
flowrate densitas v m3/j m3/d kl/yr
10.0086755496 969.6597 0.0103218 0.2477242 74.3172722938
1636.15240394 789.3 2.0729158 49.749978 14924.99342246
1.3062771783 1049 0.0012453 0.0298862 8.9658681446
1647.46735667 2.0844829 50.027589 15008.2765629

37 keluar 36
flowrate (kg/jamfraksi massa flowrate
10.0086755496 1 281.6324567732 0.0343185 96.5681536518
1636.15240394 0 0
1.3062771783 1 0
1647.46735667 1 281.6324567732
1929.099813439
10.0086755496

33 keluar 35
flowrate fraksi massa flowrate
212.364274613 0.151179908 291.6411323228
656.430911808 0.8481429486 1636.1524039375
0 0.0006771434 1.3062771783
868.795186421 1 1929.0998134386
1929.0998134386

34
flowrate
0.1733024701
0.535688494
354.495482046
355.20447301

32 keluar 33
flowrate (kg/jam) fraksi massa flowrate asam asetat 99.8%
0.1733024701 0.244435372 212.3642746134 Fraksi Komponen
0.535688494 0.755564628 656.430911808 0.002 H2O + C2H5OH
354.495482046 0 0
355.20447301 1 868.7951864213
1223.999659431

Feed masuk dist col


30 bottom 31 Komponen Fraksi Massa
flowrate fraksi massa flowrate H2O 0.1277476195
79.2768577095 0.1526442599 212.5375770834 C2H5OH 0.7164930268
979.72149213 0.5740904007 656.966600302 CH3COOH 0.1557593537
1.3062771783 0.2732653394 354.495482046 TOTAL 1
1060.30462702 1 1223.9996594314
2284.304286449
Tb H2O 100
24 Tb C2H5OH 78.37
flowrate Tb CH3COO 118.1
291.814434793 Feed temp 95
1636.68809243
355.801759224 untuk 92.4 % wt ethanol, diperlukan
2284.30428645 o %mol H2O 0.4014
o %mol C2H5 0.5986
-
23
flowrate
291.814434793
1636.68809243
355.801759224
2284.30428645

22
flowrate
291.814434793
1636.68809243
355.801759224
2284.30428645

22
flowrate
291.814434793
1636.68809243
355.801759224
2284.30428645

16 keluar 17
flowrate fraksi massa flowrate
1.7963942584 0.1277476195 291.8144347929
10.0753655113 0.7164930268 1636.6880924315
2.1902968503 0.1557593537 355.8017592242
614.470084668 0 0 dry cake 703.1028309987
88.6327463309 0 0 2% filtrat H2O + C2H5OH +CH3COOH
717.164887619 1 2284.3042864486 14.06205662
3001.46917407
keluar 15
consumption fraksi massa flowrate
3243.80118364 0 6H2
1891.29445803 0 m 221.0603911983
0 0 n 110.5301955992
245.622656887 0
1042.65038046 0.0978223703 293.6108290513 6CO
0 0 m 2919.421065276
0 0 n 104.2650380456
0 0.548652464 1646.7634579428
0 0.1192722748 357.9920560745 4CO
0 m 324.380118364
0 n 11.5850042273
0
0.2047231036 614.4700846678 2CO2
0.0295297873 88.6327463309 m 270.1849225757
1 3001.4691740673 n 6.1405664222
keluar 14
fraksi massa flowrate
0.9760599494 2743.0362097116
0.0015185036 4.2674738832
0.0109357483 30.7329006849
0.0114857987 32.2787158089
1 2810.3153000886
5811.7844741559

Volume yg akan di fermentasi (syngas)


12 keluar 13 Komponen
flowrate fraksi massa flowrate CO
617.160625386 0.873940564 614.4700846678 CO2
0.126059436 88.6327463309 CH4
617.160625386 1 703.1028309987 H2
703.1028309987 H2O
H2S
N2
10 Total
flowrate
3243.80118364 X0
1321.01945874 Xm
4.2674738832 μm
245.622656887 k
230.959253515 t
30.7329006849
32.2787158089 Vtotal starter
5108.68164316

9 massa mik diinokulasi = 10% vlar x X


flowrate v total starter =
3243.80118364 v total starter =
1321.01945874 23646.03127435
4.2674738832
245.622656887 V lar
230.959253515 83.7032259245
30.7329006849
32.2787158089 V lar =
5108.68164316 V mik =

V mik =
keluar massa mik diinokulasi =
7
fraksi massa flowrate (kg/jam)
0.6349585686 3243.80118364
0.2585832414 1321.019458738
0.0008353376 4.2674738832
0.0480794604 245.622656887
0.0452091693 230.9592535153
0.0060158183 30.7329006849
0.0063184043 32.2787158089
1 5108.681643157
keluar 8
fraksi massa flowrate (kg/jam)
1 82.851501404
1 82.851501404

5191.5331

reaksi keluar 7
consumption fraksi massa flowrate (kg/jam) rx 1 XC=
0 komponen koef
911.36652 0 0 C 1
840.33245 0.6349585686 3243.8011836396 CO2 1
370.62238 0.2585832414 1321.0194587384 CO gen 2
0.0008353376 4.2674738832 rx 2 XC=
0.0480794604 245.622656887 komponen koef
1755.64524 0.0452091693 230.9592535153 C 1
0.0060158183 30.7329006849 H2O 1
0.0063184043 32.2787158089 CO gen 1
1 5108.6816431572 H2 gen 1
keluar 8 rx 3 X CO "="
fraksi massa flowrate (kg/jam) komponen koef
1 82.85150 CO 1
1 82.851501404 H2O 1
1 5191.5331445611 CO2 gen 1
H2 gen 1
reaksi keluar, masuk reduction
consumption fraksi massa flowrate (kg/jam)
0 0 Komponen X
662.812011232 0.1915075931 994.2180168476 C 0.4
1.5447473087 0.3316479174 1721.7611555616 CO 0.00874
0 0.0714855154 371.1194224247 H2 0.2212
0.0008220065 4.2674738832
14.357823671 0.0097371936 50.5509632685 Komponen koefisien
0 0.3826623929 1986.6044960818 CO 0.5
0.0059198121 30.7329006849 CO2 0.5
0.0062175691 32.2787158089 H2O 0.5

0 0
1 5191.5331445611
5191.53314

reaksi keluar ke combustion


consumption fraksi massa flowrate (kg/jam)
4192.04101414 0 0 301.6368
0.395280251 1657.0300280793 9.9359165 1657.030028079
0.0421619562 176.7445433296 0.4541996 176.7445433296
0.0879505193 368.6919623681 0.602934 368.6919623681
0.0010179949 4.2674738832 0.0191915 4.2674738832
0.0154838242 64.9087869395 2.3352442 64.9087869395
0.4430741954 1857.3840830425 7.4248557 1857.384083043
0.0073312544 30.7329006849 0.0650404 30.7329006849
0.0077000046 32.2787158089 0.0829501 32.2787158089
4192.04101414 1 4192

301.6368 kg/kmol
Mol (basis C) BM (Basis C) Rasio mol
1 12 11.01225684
1.7913718329 1.7913718329 19.72704672
0.8249828806 13.1997260899 9.08492337
0.0150650536 0.210910751 0.16590024
0.0059061858 0.1889979457 0.065040435
27.3910066195 40.055167605
kl/day
0.247724241
49.7499780749
0.0298862271
50.027588543

Neraca komponen
Komponen Campuran 35 Produk bioetanol 37
Massa (kg/jadensitas (kg/m3) Volume (m3) %V
H2O 291.641132 969.6597 0.3007664775 0.004954611
C2H5OH 1636.1524 789.3 2.0729157531 0.995024876
CH3COOH 1.30627718 1049 0.0012452595 2.05135E-05
Total 1929.09981 2.3749274901 1
2.3749274901

H2O
CH3COOH

0.005 0.010364579

Komponen Flowrate (31) Fraksi Flowrate (32)


asetat 99.8% H2O 212.5375770834 0.244435372 0.17330247
Flowrate (kg/jam) C2H5OH 656.966600302 0.755564628 0.535688494
0.7089909641 869.5041773854

Konstanta Antoine
Flowrate (kg/jam) BM Fraksi mol Mole (kmole) Komponen
291.8144347929 18 0.28086137 16.211913044 H2O
1636.6880924315 46 0.61640454 35.5801759224 C2H5OH
355.8017592242 60 0.10273409 5.9300293204 CH3COOH
2284.3042864486 1 57.7221182869
BUBL T =
wt% ethanol diinginkan = 92.4% Komponen
C P= 101.325 kPa H2O
C x1 0.28086137 C2H5OH
C x2 0.61640454 CH3COOH
C x3 0.10273409 Total

Feed 24 Distillate 30
Komponen
Fraksi mol mole (Kmole) Fraksi mol mole (Kmole)
H2O 0.28086137 16.211913044 0.2281408243 6.507461896
C2H5OH 0.61640454 35.5801759224 0.7466828495 21.29829331
CH3COOH 0.10273409 5.9300293204 0.0251763262 0.718126551
1 57.7221182869 1 28.52388175
Total
57.7221182869

filtrate
H2O 293.6108290513 0.1277476195 1.796394258
C2H5OH +CH3COOH C2H5OH 1646.7634579428 0.7164930268 10.07536551
CH3COOH 357.9920560745 0.1557593537 2.19029685
2298.3663430686
2CO2 = C2H5OH 3H2O CO
1621.1095354543 847.398166 994.7717603924 CO2
36.8433985331 18.4216993 55.2650977996 CH4
1842.1699266526 1842.1699266526 H2
3H2O = C2H5OH 4CO2 H2O
938.38534241 799.365292 3058.441116003 H2S
52.1325190228 17.3775063 69.5100253637 N2
3857.8064076856 3857.8064076856 C2H5OH
2H2O = CH3COOH 2CO2 CH3COOH
104.2650380456 173.775063 254.8700930003
5.7925021136 2.89625106 5.7925021136
428.6451564095 428.6451564095
4H2 = CH3COOH 2H2O
24.5622656887 184.216993 110.5301955992
12.2811328444 3.07028321 6.1405664222
294.7471882644 294.7471882644

e yg akan di fermentasi (syngas) rasio


Flowrate (kg/jam) Massa jenis (mg/ volume (m3/jam) volume substrat dif volume substrat memfermen
3243.8011836396 1.1 3568.1813 10 1
1321.0194587384 1.729 2284.04264 236460.31274355 23646.03127
4.2674738832 0.6302 2.68936204
245.622656887 0.0792 19.4533144
230.9592535153 998.2 230543.527
30.7329006849 1.339 41.151354
32.2787158089 0.03928 1.26790796
5108.6816431572 236460.313

0.04448 g/L X= 0.1226654067 g/L


0.15089 g/L densitas mikroba 0.1226654067 kg/m3
0.196 /jam
0.033 /jam
48 jam

= Vlar + Vmik
= V lar + Juml mik/X
= V lar + mikroba diinokulasi x V lar/X
V mik diinokulasi = 10% V lar
mik diinokulasi = 10% vlar x X
V lar + mik diinokulasi x X x V lar/X
V lar + 0.1 Vlar^2
= V lar +0.1 Vlar^2

0.1 V lar ^2
700.623003016 784.3262289404

83.7032259245 m3/jam 83703.2259 L/jam


V total starter - V lar
23646.0312743546 83.7032259245
23562.3280484301 m3/jam
mik diinokulasi = 1.0267490251

0.061
consumption MR n
101.0788317128 12 8.42323598 2185.7716
370.6223829471 44 8.42323598 1066.8
471.7012146599 28 16.846472 X CO 0.619598134
0.489
consumption MR n C 911.3665154
810.2876837308 12 67.5239736 H2O 1755.645243
1215.4315255962 18 67.5239736
1890.6712620385 28 67.5239736
135.0479472885 2 67.5239736
0.4880656332
consumption MR n
840.3324486205 28 30.0118732
540.2137169703 18 30.0118732
1320.5224192608 44 30.0118732
60.02374633 2 30.0118732
Consumption MR n
662.8120112317 12 55.2343343
1.5447473087 28 0.05516955
14.357823671 2 7.17891184

mole O2 needed m O2 mi
27.6171671347 883.749348309 1546.56136
0.0275847734 0.8827127478 2.42746006
3.5894559178 114.8625893682 129.220413
999.494650425

C%
C(s) CH4 CO CO2
0.90225979 0.001742743 0.0412449188 0.054751177
a 1
C b 9.9359165279
CH4 c 0.0191915341
CO d 0.4541996393
CO2 e 0.6029340283
H2 f 2.3352441828
H2O g 7.4248556741
H2S h 0.065040435
N2 i 0.08295012
oduk bioetanol 37 Terserap absorber 36
Volume (m3) %V Volume (m3)
0.0103218434 0.9958768 0.2904446
2.0729157531 0 0
4.273539E-05 0.0041232 0.0012025
2.0832803319 1 0.2916472
2.3749275

0.3007664775 0.9958768 0.0103218


0.0012452595 0.0041232 4.274E-05
0.3020117369

onstanta Antoine
A B C
16.262 3799.89 226.35
16.6758 3674.49 226.45
7.8152 1800.03 246.894
goalseek
85.794887948 P= 101.325
xi ln Psat Psat ki αi log αi yi
0.2808613669 4.0885186 59.651456 0.5887140998 1 0 0.165347
0.6164045426 4.9078251 135.34473 1.3357486757 2.2689259 0.3558203 0.8233616
0.1027340904 2.4046496 11.074549 0.1092973002 0.1856543 -0.731295 0.0112286
1 0.9999372
goalseek to 1
Bottom 31
Fraksi mol mole (Kmole)
0.3323642898 9.7044511
0.4891351092 14.281883
0.178500601 5.2119028
1 29.198237
57.722118287
generation consumption
0 3243.8012
3313.311209 1891.2945

245.62266
1105.301956 1042.6504

1646.7634579
357.99205607
6423.368679 6423.3687

Laju Pertumbuhan
olume substrat memfermentasi X= 1.026749 kg/m3
k0 = 0.196 /jam
Km = 0.68 kg/m3
S 7.3732 kg/m3

dx/dt = 0.1842502
Massa ditambah85.942206
Vr = 0.0006697
Pertumbuhan 48 jam 10 ml
Mikroba tumbuh2.6905407 kg

10
100

0.4880656332
O 145.35877
O left= 118.79769
7.4248557
H 19.727047
H left= 4.6704884
2.3352442
Media per 1L media per
Komponen massa (gram) Komponen
NH4CL 1 NH4CL
KCL 0.1 KCL
MgSO4.7H2O 0.2 MgSO4.7H2O
NaCl 0.8 NaCl
KH2PO4 0.1 KH2PO4
CaCl2.2H2O 0.02 CaCl2.2H2O
Yeast extract 1 Yeast extract
trace element solution 10 mL trace element solution
Nitrilotriacetic acid 2 Nitrilotriacetic acid
MnSO4.H2O 1 MnSO4.H2O
Fe(SO4)2(NH4)2.6H2O 0.8 Fe(SO4)2(NH4)2.6H2O
CoCl2.6H2O 0.2 CoCl2.6H2O
ZnSO4.7H2O 0.0002 ZnSO4.7H2O
CuCl2.2H2O 0.02 CuCl2.2H2O
NiCl2.6H2O 0.02 NiCl2.6H2O
Na2MoO4.2H2O 0.02 Na2MoO4.2H2O
Na2SeO4 0.02 Na2SeO4
Na2WO4 0.02 Na2WO4
Vitamin solutions 10 mL Vitamin solutions
Biotin 0.002 Biotin
Folic acid 0.002 Folic acid
Pyridoxine-HCl 0.01 Pyridoxine-HCl
Thiamine-HCl 0.005 Thiamine-HCl
Riboflavin 0.005 Riboflavin
Nicotinic acid 0.005 Nicotinic acid
Calcium D(+) panthotnate 0.005 Calcium D(+) panthotnate
Vitamin B12 0.0001 Vitamin B12
P-aminobenzoic acid 0.005 P-aminobenzoic acid
Thiotic acid 0.005 Thiotic acid
Reacting agent solution 100 mL Reacting agent solution
NaOH 0.0009 NaOH
L-Cysteine-HCl 0.004 L-Cysteine-HCl
Na2S.9H2O 0.004 Na2S.9H2O
83703.226 L
massa (gram)
83703.226
8370.3226
16740.645
66962.581
8370.3226
1674.0645
83703.226
837032.26 mL
167406.45
83703.226
66962.581
16740.645
16.740645
1674.0645
1674.0645
1674.0645
1674.0645
1674.0645
837032.26 mL
167.40645
167.40645
837.03226
418.51613
418.51613
418.51613
418.51613
8.3703226
418.51613
418.51613
8370323 mL
75.332903
334.8129
334.8129
617160.63 g
7.3732 kg/m3
6 Distillation Column
komponenarus 24 komponenarus 25
fraksi mas flowrate (kg/jam) fraksi mas flowrate (kg/jam)
H2O 0.127748 291.8144 H2O 0.159899 504.1787
C2H5OH 0.716493 1636.688 C2H5OH 0.727259 2293.119
CH3COOH 0.155759 355.8018 CH3COOH 0.112842 355.8018
Total 1 2284.304 Total 1 3153.099

komponenarus 29 komponenarus 32
fraksi mas flowrate (kg/jam) fraksi mas flowrate (kg/jam)
H2O 0.006075 10.00868 H2O 0.328214 494.17
C2H5OH 0.993132 1636.152 C2H5OH 0.436339 656.9666
CH3COOH 0.000793 1.306277 CH3COOH 0.235446 354.4955
Total 1 1647.467 Total 1 1505.632

komponenarus 33 komponenarus 34
fraksi mas flowrate (kg/jam) fraksi mas flowrate (kg/jam)
H2O 0.244435 212.3643 H2O 0.442509 281.8058
C2H5OH 0.755565 656.4309 C2H5OH 0.000841 0.535688
CH3COOH 0 0 CH3COOH 0.55665 354.4955
Total 1 868.7952 Total 1 636.8369
29

24 25
dist

33

32

ast dehyd

34

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