TRANSFORMASI DIAGRAM FASA

Dosen Pengampu:
Gusti Umindya Nur Tajalla, S.T., M.T.

Program Studi Teknik Material dan Metalurgi

Jurusan Ilmu Kebumian dan Lingkungan
Institut Teknologi Kalimantan
2019
 Lecture 7
EQUILIBRIUM DIAGRAMS HAVING
INTERMEDIATE PHASES OR
COMPOUNDS

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 TERMINAL SOLID SOLUTION

The eutectic copper–silver

and lead–tin phase
diagrams have only two
solid phases,  and ; these
are sometimes termed
terminal solid solutions
because they exist over
composition ranges near
the concentration
extremes of the phase
diagram.

TERMINAL SOLID SOLUTION

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INTERMEDIATE SOLID
SOLUTION

The isomorphous and eutectic phase diagrams

discussed thus far are relatively simple, but
those for many binary alloy systems are much
more complex.

For other alloy systems, intermediate solid

solutions (or intermediate phases) may be found
at other than the two composition extremes.

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Cu-Zn BINARY SYSTEM

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COMMERCIAL BRASS

CARTRIDGE BRASS

70 wt% Cu – 30 wt% Zn
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INTERMETALLIC
COMPOUND
For some systems, discrete intermediate compounds rather than solid
solutions may be found on the phase diagram, and these compounds
have distinct chemical formulas; for metal–metal systems, they are
called intermetallic compounds. For example, consider the
magnesium–lead system. The compound Mg2Pb has a composition of
19 wt% Mg–81 wt% Pb (33 at% Pb) and is represented as a vertical line
on the diagram, rather than as a phase region of finite width; hence,
Mg2Pb can exist by itself only at this precise composition.

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Mg-Pb BINARY SYSTEM

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 Lecture 7
EUTECTOID AND PERITECTIC
REACTION

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EUTECTOID AND PERITECTIC
REACTION

EUTECTOID
REACTION

PERITECTIC
REACTION

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 Lecture 7
CONGRUENT PHASE
TRANSFORMATION

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CONGRUENT PHASE
TRANSFORMATION

Phase transformations may be classified according to whether

there is any change in composition for the phases involved.
Those for which there are no compositional alterations are said
to be congruent transformations. Conversely, for incongruent
transformations, at least one of the phases experiences a
change in composition.

Examples of congruent transformations include allotropic

transformations and melting of pure materials. Eutectic and
eutectoid reactions, as well as the melting of an alloy that
belongs to an isomorphous system, all represent incongruent
transformations.

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CONGRUENT PHASE
TRANSFORMATION (2)

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