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Article history: Sewage sludge contains significant amounts of resources, such as nutrients and organic matter. At the
Received 30 July 2017 same time, the organic contaminants (OC) found in sewage sludge are of growing concern. Consequently,
Received in revised form in many European countries incineration is currently favored over recycling in agriculture. This study
7 November 2017
presents a Multi-Attribute Value Theory (MAVT)-based decision support tool (DST) for facilitating sludge
Accepted 10 November 2017
Available online 13 November 2017
treatment decisions. Essential decision criteria were recognized and prioritized, i.e., weighted, by experts
from water utilities. Since the fate of organic contaminants was in focus, a simple scoring method was
Handling Editor: Prof. J. de Boer developed to take into account their environmental risks. The final DST assigns each sludge treatment
method a preference score expressing its superiority compared to alternative methods.
Keywords: The DST was validated by testing it with data from two Finnish municipal wastewater treatment plants
Sludge treatment (WWTP). The validation results of the first case study preferred sludge pyrolysis (preference score: 0.629)
Nutrient recycling to other alternatives: composting and incineration (score 0.580, and 0.484 respectively). The preference
Environmental risk scores were influenced by WWTP dependent factors, i.e., the operating environment and the weighting
MCDA
of the criteria. A lack of data emerged as the main practical limitation. Therefore, not all of the relevant
criteria could be included in the value tree. More data are needed on the effects of treatment methods on
the availability of nutrients, the quality of organic matter and sludge-borne OCs. Despite these short-
comings, the DST proved useful and adaptable in decision-making. It can also help achieve a more
transparent, understandable and comprehensive decision-making process.
© 2017 Elsevier Ltd. All rights reserved.
1. Introduction some of them have also increased the amount of sludge generated
in the process. At the same time, the traditional disposal routes of
Sewage sludge (SS) is a residue generated at centralized sludge, such as dumping in the sea and landfill disposal, are no
wastewater treatment plants (WWTPs) (Harrison et al., 2006). SS longer possible due to tightening environmental regulations.
treatment is one of the most controversial issues of modern Moreover, agricultural use faces increasing opposition because of
municipal wastewater treatment. Advanced wastewater treatment the potential harmful effects of organic contaminants (OC). As a
technologies have resulted in a higher quality of the effluent but result, incineration of sludge has become increasingly popular in
the European countries (Fytili and Zabaniotou, 2008; Kelessidis and
Stasinakis, 2012).
SS can be seen as a resource, the recycling of which is encour-
* Corresponding author.
E-mail address: ville.j.turunen@aalto.fi (V. Turunen).
aged in the European framework directive on waste (2008/98/EC).
https://doi.org/10.1016/j.chemosphere.2017.11.052
0045-6535/© 2017 Elsevier Ltd. All rights reserved.
522 V. Turunen et al. / Chemosphere 193 (2018) 521e529
SS contains significant amounts of phosphorus (P) (2e4% in dry The aim of our study was to build a DST in cooperation with
weight) and nitrogen (N) (2.8e3.8% in dry weight), which are wastewater utilities to facilitate the selection of a sludge treatment
essential for plant growth (Haynes et al., 2009; O’ Connor et al., method. Multi-attribute value theory (MAVT), a particular MCDA-
2004). In addition, SS contains organic matter (OM), potassium method, formed the theoretical basis for the DST. The DST was
and micronutrients, such as copper and zinc (Sternbeck, 2011). At validated by testing it with data from two Finnish WWTPs. Its us-
present, most of the phosphorus fertilizers are produced from ability in a wider context was also assessed. The ultimate goal was
phosphate rock, which is a nonrenewable and depleting natural to enable systematic decision-making and involve stakeholders in
resource (Childers et al., 2011). SS can offer an alternative, renew- the decision-making in order to promote justified sludge treatment
able phosphorus source for agriculture and also partly replace man- decisions.
made nitrogen fertilizers. However, the availability of P and N in the
SS has traditionally been considered lower compared to commer- 2. Materials and methods
cial fertilizers (Seyhan and Erdincler, 2003), although some studies
have reported that the availability of sludge P and N is close to or 2.1. Choosing the form of DST e theoretical framework
comparable to inorganic fertilizers (Kahiluoto et al., 2015; Rigby
et al., 2016). Unfortunately, SS also includes some contaminants The basis of MCDA is in so-called value-focused thinking, which
that may limit its use, such as pathogens, heavy metals and OCs, implies that the decision makers' and stakeholders’ underlying
originating from industrial and municipal wastewater (So € rme et al., objectives must be recognized and structured in all decision-
2003; Rogers, 1996). The potential risks related to land application making, contrary to the traditional way of thinking where the de-
of SS have fostered the development of different phosphorus re- cision is often based on the best available alternative (Mustajoki,
covery processes. At present, these processes are generally not yet 2015).
economically feasible (Egle et al., 2016). MAVT was chosen as the theoretical basis of the DST. In MAVT,
Before SS is used as a soil amendment or fertilizer, it needs to be the alternatives are ranked based on their performance in relation
treated to reduce its water content and odor, inactivate pathogenic to several objectives. MAVT is a compensatory approach, and good
organisms, and stop the biological degradation. The various treat- performance related to one objective can offset poor performance
ment methods include anaerobic digestion, composting, and sta- related to another objective. MAVT also enables the weighting of
bilization with alkaline material or other chemicals, thermal criteria and it supports both quantitative and qualitative data
treatment by heat drying, pyrolysis, incineration, and combinations (Keeney and Raiffa, 1976; Ferretti et al., 2014). A more in-depth
of these (Fytili and Zabaniotou, 2008). The treatment changes the explanation of MAVT and calculation of additive scores for deci-
physicochemical properties of the sludge, and may therefore affect sion alternatives can be found in Keeney and Raiffa (1976) and Von
the quality and feasibility of the final SS product. In the past, high Winterfeldt and Edwards (1986).
concentrations of heavy metals restricted the use of SS in agricul-
ture (So€ rme et al., 2003). Due to regulatory guidelines and other 2.2. Constructing the DST
source control measures, the concentrations of heavy metals in the
SS generated in Finland have declined substantially (Kasurinen In our case, the overall objective of the decision-making was to
et al., 2014). Presently, the OCs pose the highest risks, since the identify the optimal SS treatment solution, where the use of re-
use of synthetic organic chemicals both in industry and households sources is maximized and the adverse effects caused to the com-
has rapidly increased in the past 50 years. Many of the OCs are munity and the environment are minimized. The main objective
harmful to terrestrial and aquatic organisms and may disrupt their was divided into distinct sub-objectives, also called criteria, which
hormonal activity and/or have carcinogenic or mutagenic effects were further divided into attributes and their sub-attributes.
(Haynes et al., 2009). The ability of the common SS treatment Finally, indicators, which measure the goodness of an alternative
methods to degrade the OCs varies significantly (Smith, 2009). in terms of a specific criterion, were defined for the attributes at the
The costs of SS treatment can account for up to 50% of the total lowest level. The relation between the overall objective, the criteria
costs associated with wastewater treatment, making the selection and the attributes is shown by a value tree (Fig. 2), which is a
of the treatment method(s) also a significant financial issue. At the graphical representation of the problem hierarchy. The criteria
same time, the potential environmental problems caused by con- were chosen in a way that they are not overlapping and that it is
taminants and the direct environmental effects of SS treatment and possible to measure the value of the (sub-)attributes based on the
management, e.g. odors and increased traffic, may disturb the local indicators.
community (Campbell, 2000; Haynes et al., 2009). Hence, choosing The important decision criteria were recognized on the basis of
an optimal SS treatment method is a decision having diverse interviews and consultation with the representatives of the
environmental, economic and social consequences. WWTPs participating in our case studies. The process is described
The impacts of SS and sewage treatment systems and land in more detail in the supplementary material.
application of SS have been previously assessed in numerous life The system boundaries of the DST (Fig. 1) start from the SS
cycle assessment (LCA) studies (Hospido et al., 2004; Lundin et al., leaving the preliminary treatment and extend to the disposal or
2004; Yoshida et al., 2013; Alyaseri and Zhou, 2017; Harder et al., reuse of the sludge product generated in the treatment processes.
2017). In addition to LCA, some multi-criteria decision analysis The system does not cover the avoided emissions caused by the
(MCDA) based methods have been applied. MCDA provides a substitution of energy and material in production. It also excludes
framework that analyzes and evaluates the alternatives systemat- dewatering or conditioning processes, such as the addition of
ically (Kiker et al., 2005). For example, Pijuan et al. (2010) presented polymers to SS, because these are considered as a preliminary
a combined MCDA and fuzzy logic tool for assessing the suitability treatment even though they might be located after the main
of SS for land application and Garrido-Baserba et al. (2015) used a treatment.
MCDA for the evaluation of SS treatment technologies. However, In our DST, the final product from the SS treatment was assumed
many of the previous studies do not comprehensively compare the to be applied on land as a fertilizer (if it fulfills the Finnish fertilizer
effects and assess the trade-offs associated with different treatment regulations) or disposed of as waste (if the fertilizer regulations are
options but only consider the effects of one treatment method or not met). When assessing the environmental risks in land appli-
ignore stakeholders. cation, only OCs were considered, since the heavy metals and
V. Turunen et al. / Chemosphere 193 (2018) 521e529 523
Risk factor
Wastewater treatment plant
5
8
7
0
1
3
6
9
Sludge pre-
treatment
Risk factors of organic contaminants (OC); PNEC ¼ Predicted No Effect Concentration; the references for each parameter are presented in the supplementary data (Table S19; S20; S21).
2 ¼ possible risk
Disposal// Disposal/ Disposal/
0 ¼ no risk
recycling recycling recycling
0
0
0
0
0
1
0
2
ma terials/energy ma terials/energy ma terials/energy
1
2
2
0
0
0
2
2
drocarbons (PAH), polychlorinated biphenyls (PCB), poly-
chlorinated dibenzodioxins and furans (PCDD/F), linear
alkylbenzene sulphonates (LAS), nonylphenols and their etoxylates
2
3
3
0
1
2
1
2
PAHa
PFOS
PCB
LAS
a
b
changed (Qureshi et al., 1999). soil, the contaminant's half-life in soil, the potential to accumulate
in crops, the potential to accumulate in animals, and the potential
risks it poses to ground water and surface waters (Table 1).
2.4. Determination of risk values for organic contaminants
Public opinion
Dema nd for the
s l udge product Usability
Organic ma er
Phosphorus
Recoverable
Nutrients
res ources
Nitrogen
Energy
Net cos ts Wa s te
Fig. 2. The final value tree and its criteria/attributes/sub-attributes. The lighter color signifies that the attribute was not considered in decision-making in this study.
GHG ¼ Greenhouse gas. (For interpretation of the references to colour in this figure legend, the reader is referred to the web version of this article.)
V. Turunen et al. / Chemosphere 193 (2018) 521e529 525
Processes for nutrient recovery were not considered based on were rather evenly weighted but slightly emphasizing the criteria
the above-mentioned preconditions. In all the treatment alterna- “Demand for the sludge product” and “Contaminants in the sludge
tives in both cases, SS is anaerobically digested before additional product”.
treatment processes.
The decision alternatives in case A were: 3.2.2. Preferred treatment options
As expected, in the different decision alternatives, the contri-
A1: composting bution of the different criteria to the total preference score varied
A2: heat drying þ incineration (Fig. 3). Since the weighting in case A heavily favors destruction of
A3: pyrolysis OCs and utilization of recoverable resources, the treatment option
A3 (i.e. pyrolysis) receives the highest total score (0.629). However,
The decision alternatives in case B were: the difference between the total preference scores of option A1 and
option A3 is not substantial because option A1 (composting) re-
B1: stabilization with lime and acid ceives the highest score, for example, for the criteria “Direct
B2: composting adverse effects” and “Net costs” and reasonably good scores for the
B3: heat drying þ incineration rest of the criteria (total score of 0.580). Option A2 receives the
lowest score (0.484).
The criteria, attributes, and sub-attributes were weighted using In case B, the preference scores differ more significantly. The
direct weighting. The elicitation of weights was based on the lowest preference score (0.100) is attributed to option B3: heat
preferences of the WWTP representatives. drying þ incineration. This is mainly because the process in this
option is the most expensive, and it does not enable OM or nutri-
3. Results and discussion ents to be utilized. In fact, option B3 receives the lowest scores in all
of the criteria except the criterion “Contaminants in the sludge
3.1. Value tree product”. Option B1 (acid and lime treatment) receives the best
overall preference score (0.869), since it scores best with respect to
In our final value tree (Fig. 2).the main objective is divided into the criteria “Recoverable resources” and “Net costs,” among others.
seven (7) criteria, some of which are further divided into lower- In the validation of the model, the optimal treatment alternative
level attributes and sub-attributes. In the expert consultation pro- varied due to differences in the SS's properties, operational envi-
cess, the draft value tree was slightly modified, e.g., some criteria ronment of the WWTPs, and weighting. It can be noticed that the
were omitted and new ones were added. The criterion describing same treatment alternatives (e.g., A1 and B2) receive different
the mass of a SS product was originally expected to be an important preference scores in case A and in case B, depending on the local
decision criterion, but the interviews showed that it was rather a conditions. In case A, the WTTP's large size enables lower treatment
factor affecting the costs of sludge treatment. Thus, the criterion costs, whereas the direct adverse effects caused by the composting
“Mass of the sludge product” was omitted from our final value tree. process are expected to be more pronounced owing to the higher
The criterion “Demand for sludge product” and the attributes population number. Thus, the two different case studies demon-
“Organic matter” and “GHG emissions” were added to the value strate our DST's validity in a wide variety of different decision-
tree. In the preliminary value tree the attribute “Contaminants in making situations. The more intricate and abundant the input
the sludge product” was hierarchically below the criterion “Emis- data is, the easier it is to represent the idiosyncrasy of the specific
sions and residues”. In the final value tree it was included as a situation.
criterion of its own. In the DST, very different attributes are compared with each
We distinguished suitable indicators for each attribute and sub- other at the same level of hierarchy. For instance, it can be very
attribute to determine the values for the criteria (see Table 2). We difficult for stakeholders to assess the importance of GHG emis-
addressed qualitative (i.e., verbal) indicators for the attributes that sions against the importance of adverse effects caused by the OCs in
were not quantitatively measurable. These were further converted the SS product. Due to decision makers’ differing values and pref-
to numeric values. We defined the values for the attributes based erences, the weighting may also cause conflicts in the decision
on the literature, process data from the two studied WWTPs, and situation, which can complicate decision-making. Assigning
the expert judgment provided by the representatives of the weights to criteria/attributes may in fact be one of the most
WWTPs. Criteria that are time-dependent, such as operating costs, problematic issues of our DST.
were analyzed over the course of one year of WWTP's operation. Most previous decision support aids and LCAs assessing the
The aggregated risk value (ARV) (see Section 2.4) was used for effects of SS treatment include the three main criterion groups in
determining the risk caused by sludge-borne OCs following land environmental decision-making: economic, environmental and
application of SS. social criteria (Pijuan et al., 2010; Garrido-Baserba et al., 2015;
Alyaseri and Zhou, 2017). The differences rise from the division of
3.2. Validation of the DST these main criteria to smaller criterion groups and attributes.
A previous MCDA study by Garrido-Baserba et al. (2015)
3.2.1. Values of the criteria and attributes and their weighting included the global warming potential and annual cash flow,
For the validation of the DST, values were calculated for the whereas many LCA studies include numerous environmental
attributes and criteria in each decision alternative in both WWTP impact categories such as agricultural land occupation, climate
cases, and the criteria and attributes were weighted. The detailed change effects on the ecosystem and human health, eutrophication
calculation of the values can be found in the supplementary ma- and human toxicity. The criteria included in these LCA studies are
terial. In case A, heavy weights were given to the criteria “Recov- affected and limited by the methodology of the Life Cycle Impact
erable resources” (0.3) and “Contaminants in the sludge product” Assessment (LCIA) (Alyaseri and Zhou, 2017). Our DST has its focus
(0.3) with much less weight addressed to ”Net costs” and the “Se- on the recycling of resources and managing the risks caused by
curity of the process” (0.1 and 0.05 respectively). In case B, the sludge-borne OCs. It does not, however, consider, for example the
criteria “Net costs” and “Recoverable resources” received the land requirements for building treatment facilities nor exhibit a
highest weights (0.3, both). The rest of the criteria and attributes complicated financial analysis. Moreover, the value tree in this
526 V. Turunen et al. / Chemosphere 193 (2018) 521e529
Table 2
Indicators of the criteria/attributes/sub-attributes and their data sources. GHG ¼ Greenhouse gas; WWTP ¼ Wastewater treatment plant; ARV ¼ Aggregated risk value.
Demand for the sludge product (þ) The market for the sludge product for
beneficial reuse
Public opinion Perception and public acceptance of the qualitative (1e10): 1 ¼ very strong expert judgement
use of the sludge product in agriculture opposition; 5 ¼ average; 10 ¼ perceived
as safe and acceptable
Usability The physical characteristics and quality qualitative (1e10): 1 ¼ cannot be used; expert judgement
of the sludge product which affect the 5 ¼ can be used but the properties are
spreading, storing etc. not ideal; 10 ¼ ideal properties for use
Recoverable resources (þ) Resources which can be utilized in the
treatment operation
a, b
Energy produced Energy produced in treatment methods GWh/a the two WWTPs studied; literature
for example incineration of sludge or
biogas
Nutrients Nutriens that can be utilized in
agriculture in the final product of
sludge treatment
Phosphorus Amount of phosphorus utilizable in t/year the two WWTPs studied
agriculture
c, d, e, f
Nitrogen Amount of nitrogen utilizable in t/year the two WWTPs studied; literature
agriculture
d, e, g, h, i
Organic matter Amount of organic matter utilizable in t/year Data from the WWTP; literature
agriculture
Pollutants in the sludge product (¡) The pollutants in the sewage sludge
which may cause risks in sludge land-
application
Pathogens Pathogens present in the final product e
(not considered)
Metals Amount of metals in the final product e
(not considered)
Organic contaminants Amount of organic contaminants in the ARV calculated value, see chapter 2.4 for details
final product
Emissions and residues (¡) The emissions and non-utilizable
sidestreams of the sludgre treatment
process
GHG-emissions Greenhouse gases emitted directly or t/year the two WWTPs studied; literaturea, j, k, l
Bold was used to differentiate between the higher level criteria and the attributes/subattributes.
a
Myllymaa et al. (2008)
b
Inguanzo et al. (2002)
c
Hossain et al. (2011)
d
Solis et al. (2002)
e
Alvarez et al. (2002)
f
Mo€ller and Müller (2012)
g
Haynes et al. (2009)
h
Fonts et al. (2012)
i
Rigby et al. (2016)
j
Zupan ci
c and Ros (2003)
k
SYLVIS Environmental (2009)
l
Wang et al. (2013)
m €yry Environment (2007)
Po
study was built in cooperation with WWTP representatives. With structure of the DST, criteria, and the weighting of the criteria might
the contribution of different or additional stakeholders, the differ significantly. The hierarchical structure of the value tree can
V. Turunen et al. / Chemosphere 193 (2018) 521e529 527
3.3. Sensitivity to weights In this paper, we presented the construction and validation of an
MAVT-based DST, which provides a systematic and transparent
To test the sensitivity of our DST to changes in criteria weights, process for making a justified decision on a sewage sludge treat-
we conducted a sensitivity analysis for the case studies (Fig. 4). The ment. The final DST is a hierarchical value tree, which comprises
analysis for case A showed that if higher weights were attributed to criteria, attributes and sub-attributes that can be weighted. Each
“Direct adverse effects” (>0.15), “Security of the process” (>0.15), alternative receives a preference score based on its performance as
“Emission and residues” (>0.35)”or “Net costs” (>0.15) the optimal for the attributes and the weighting of the criteria.
treatment method would change from option A3 to option A1. The The DST offers a systematic framework for decision-making thus
optimal treatment method would only change to option A2 if the making it less likely for decisions to be made based on prejudices
criterion “Contaminants in the sludge product” was heavily and old habits. A structured, relatively simple and transparent
weighted (weight > 0.6). In case B, the optimal treatment option decision-making tool also enables an easier and wider involvement
(B1) is significantly less sensitive to the changes in criteria weights. of the stakeholders. However, in this study, the weighting was done
The optimal treatment alternative changes to B2 if “Demand” or only with the WWTP representatives. In a real-life situation, other
“Emissions and residues” are heavily weighted (>0.65 and > 0.5, stakeholders are usually involved in the decision process, which
respectively) or if “Contaminants in the sludge product” receives a may lead to different results.
528 V. Turunen et al. / Chemosphere 193 (2018) 521e529
Case A
Preference score
Preference score
Preference score
1 0.8 0.8 0.8
Preference score
0.8
0.6 0.6 0.6
0.6
0.4 0.4 0.4
0.4
0.2 0.2 0.2 0.2
0 0 0 0
0 0.5 1 0 0.5 1 0 0.5 1 0 0.5 1
Weight Weight Weight Weight
A1 A2 A3 A1 A2 A3 A1 A2 A3 A1 A2 A3
0.8
0.6
0.4
0.2
0
0 0.5 1
Weight
A1 A2 A3
Case B
Demand for sludge product Contaminants in the sludge Emissions and residues Security of the process
product
1 1 1
Preference score
Preference score
Preference score
0.8
0.6 0.6 0.6
0.6
0.4 0.4 0.4
0.4
0.2 0.2 0.2 0.2
0 0 0 0
0 0.5 1 0 0.5 1 0 0.5 1 0 0.5 1
Weight Weight Weight Weight
B1 B2 B3 B1 B2 B3 B1 B2 B3 B1 B2 B3
Fig. 4. Sensitivity of the results to criteria weights. Only those results where the change in the weighting of a single criterion caused changes in the preference order of the
treatment options are shown. Hence, the weighting of criteria “Demand for sludge product” and “Recoverable resources” (case A) and “Recoverable resources”, “Net costs” and
“Direct adverse effects” (case B) did not affect the priority order of the treatment alternatives. Case study A - A1: mesophilic anaerobic digestion þ composting; A2: mesophilic
anaerobic digestion þ heat drying þ incineration; A3: mesophilic anaerobic digestion þ pyrolysis. Case study B - B1: mesophilic anaerobic digestion þ stabilization with lime and
acid; B2: mesophilic anaerobic digestion þ composting; B3: mesophilic anaerobic digestion þ heat drying þ incineration; the horizontal line indicates the original weight of the
criterion in the case study.
The validation of the DST showed its usefulness for decision- also beneficial to study whether some characteristics of the
making in different situations. While weighting has a strong ef- WWTPs affect the stakeholders’ prioritization.
fect on the preferred treatment method, the outcome is also highly
affected by the values of the criteria/attributes, which in turn are Appendix A. Supplementary data
very dependent on the operational environment.
It is worth noting that any decision problem is almost inevitably Supplementary data related to this article can be found at
simplified when described by a value tree, and some important https://doi.org/10.1016/j.chemosphere.2017.11.052.
decision criteria may be left out. Real-life decision-making situa-
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