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Chemosphere 193 (2018) 521e529

Contents lists available at ScienceDirect

Chemosphere
journal homepage: www.elsevier.com/locate/chemosphere

A decision support tool for selecting the optimal sewage sludge


treatment
Ville Turunen*, Jaana Sorvari, Anna Mikola
Aalto University, School of Engineering, P.O. Box 15200, 00076 Aalto, Finland

h i g h l i g h t s

 A decision support tool was constructed to facilitate sludge treatment decisions.


 The tool considers the benefits and drawbacks of alternative methods.
 Testing with data from two wastewater plants showed the applicability of the tool.
 The superiority of the treatment options was dependent on the local conditions.
 The quality and lack of input data emerged as the main practical limitations.

a r t i c l e i n f o a b s t r a c t

Article history: Sewage sludge contains significant amounts of resources, such as nutrients and organic matter. At the
Received 30 July 2017 same time, the organic contaminants (OC) found in sewage sludge are of growing concern. Consequently,
Received in revised form in many European countries incineration is currently favored over recycling in agriculture. This study
7 November 2017
presents a Multi-Attribute Value Theory (MAVT)-based decision support tool (DST) for facilitating sludge
Accepted 10 November 2017
Available online 13 November 2017
treatment decisions. Essential decision criteria were recognized and prioritized, i.e., weighted, by experts
from water utilities. Since the fate of organic contaminants was in focus, a simple scoring method was
Handling Editor: Prof. J. de Boer developed to take into account their environmental risks. The final DST assigns each sludge treatment
method a preference score expressing its superiority compared to alternative methods.
Keywords: The DST was validated by testing it with data from two Finnish municipal wastewater treatment plants
Sludge treatment (WWTP). The validation results of the first case study preferred sludge pyrolysis (preference score: 0.629)
Nutrient recycling to other alternatives: composting and incineration (score 0.580, and 0.484 respectively). The preference
Environmental risk scores were influenced by WWTP dependent factors, i.e., the operating environment and the weighting
MCDA
of the criteria. A lack of data emerged as the main practical limitation. Therefore, not all of the relevant
criteria could be included in the value tree. More data are needed on the effects of treatment methods on
the availability of nutrients, the quality of organic matter and sludge-borne OCs. Despite these short-
comings, the DST proved useful and adaptable in decision-making. It can also help achieve a more
transparent, understandable and comprehensive decision-making process.
© 2017 Elsevier Ltd. All rights reserved.

1. Introduction some of them have also increased the amount of sludge generated
in the process. At the same time, the traditional disposal routes of
Sewage sludge (SS) is a residue generated at centralized sludge, such as dumping in the sea and landfill disposal, are no
wastewater treatment plants (WWTPs) (Harrison et al., 2006). SS longer possible due to tightening environmental regulations.
treatment is one of the most controversial issues of modern Moreover, agricultural use faces increasing opposition because of
municipal wastewater treatment. Advanced wastewater treatment the potential harmful effects of organic contaminants (OC). As a
technologies have resulted in a higher quality of the effluent but result, incineration of sludge has become increasingly popular in
the European countries (Fytili and Zabaniotou, 2008; Kelessidis and
Stasinakis, 2012).
SS can be seen as a resource, the recycling of which is encour-
* Corresponding author.
E-mail address: ville.j.turunen@aalto.fi (V. Turunen).
aged in the European framework directive on waste (2008/98/EC).

https://doi.org/10.1016/j.chemosphere.2017.11.052
0045-6535/© 2017 Elsevier Ltd. All rights reserved.
522 V. Turunen et al. / Chemosphere 193 (2018) 521e529

SS contains significant amounts of phosphorus (P) (2e4% in dry The aim of our study was to build a DST in cooperation with
weight) and nitrogen (N) (2.8e3.8% in dry weight), which are wastewater utilities to facilitate the selection of a sludge treatment
essential for plant growth (Haynes et al., 2009; O’ Connor et al., method. Multi-attribute value theory (MAVT), a particular MCDA-
2004). In addition, SS contains organic matter (OM), potassium method, formed the theoretical basis for the DST. The DST was
and micronutrients, such as copper and zinc (Sternbeck, 2011). At validated by testing it with data from two Finnish WWTPs. Its us-
present, most of the phosphorus fertilizers are produced from ability in a wider context was also assessed. The ultimate goal was
phosphate rock, which is a nonrenewable and depleting natural to enable systematic decision-making and involve stakeholders in
resource (Childers et al., 2011). SS can offer an alternative, renew- the decision-making in order to promote justified sludge treatment
able phosphorus source for agriculture and also partly replace man- decisions.
made nitrogen fertilizers. However, the availability of P and N in the
SS has traditionally been considered lower compared to commer- 2. Materials and methods
cial fertilizers (Seyhan and Erdincler, 2003), although some studies
have reported that the availability of sludge P and N is close to or 2.1. Choosing the form of DST e theoretical framework
comparable to inorganic fertilizers (Kahiluoto et al., 2015; Rigby
et al., 2016). Unfortunately, SS also includes some contaminants The basis of MCDA is in so-called value-focused thinking, which
that may limit its use, such as pathogens, heavy metals and OCs, implies that the decision makers' and stakeholders’ underlying
originating from industrial and municipal wastewater (So € rme et al., objectives must be recognized and structured in all decision-
2003; Rogers, 1996). The potential risks related to land application making, contrary to the traditional way of thinking where the de-
of SS have fostered the development of different phosphorus re- cision is often based on the best available alternative (Mustajoki,
covery processes. At present, these processes are generally not yet 2015).
economically feasible (Egle et al., 2016). MAVT was chosen as the theoretical basis of the DST. In MAVT,
Before SS is used as a soil amendment or fertilizer, it needs to be the alternatives are ranked based on their performance in relation
treated to reduce its water content and odor, inactivate pathogenic to several objectives. MAVT is a compensatory approach, and good
organisms, and stop the biological degradation. The various treat- performance related to one objective can offset poor performance
ment methods include anaerobic digestion, composting, and sta- related to another objective. MAVT also enables the weighting of
bilization with alkaline material or other chemicals, thermal criteria and it supports both quantitative and qualitative data
treatment by heat drying, pyrolysis, incineration, and combinations (Keeney and Raiffa, 1976; Ferretti et al., 2014). A more in-depth
of these (Fytili and Zabaniotou, 2008). The treatment changes the explanation of MAVT and calculation of additive scores for deci-
physicochemical properties of the sludge, and may therefore affect sion alternatives can be found in Keeney and Raiffa (1976) and Von
the quality and feasibility of the final SS product. In the past, high Winterfeldt and Edwards (1986).
concentrations of heavy metals restricted the use of SS in agricul-
ture (So€ rme et al., 2003). Due to regulatory guidelines and other 2.2. Constructing the DST
source control measures, the concentrations of heavy metals in the
SS generated in Finland have declined substantially (Kasurinen In our case, the overall objective of the decision-making was to
et al., 2014). Presently, the OCs pose the highest risks, since the identify the optimal SS treatment solution, where the use of re-
use of synthetic organic chemicals both in industry and households sources is maximized and the adverse effects caused to the com-
has rapidly increased in the past 50 years. Many of the OCs are munity and the environment are minimized. The main objective
harmful to terrestrial and aquatic organisms and may disrupt their was divided into distinct sub-objectives, also called criteria, which
hormonal activity and/or have carcinogenic or mutagenic effects were further divided into attributes and their sub-attributes.
(Haynes et al., 2009). The ability of the common SS treatment Finally, indicators, which measure the goodness of an alternative
methods to degrade the OCs varies significantly (Smith, 2009). in terms of a specific criterion, were defined for the attributes at the
The costs of SS treatment can account for up to 50% of the total lowest level. The relation between the overall objective, the criteria
costs associated with wastewater treatment, making the selection and the attributes is shown by a value tree (Fig. 2), which is a
of the treatment method(s) also a significant financial issue. At the graphical representation of the problem hierarchy. The criteria
same time, the potential environmental problems caused by con- were chosen in a way that they are not overlapping and that it is
taminants and the direct environmental effects of SS treatment and possible to measure the value of the (sub-)attributes based on the
management, e.g. odors and increased traffic, may disturb the local indicators.
community (Campbell, 2000; Haynes et al., 2009). Hence, choosing The important decision criteria were recognized on the basis of
an optimal SS treatment method is a decision having diverse interviews and consultation with the representatives of the
environmental, economic and social consequences. WWTPs participating in our case studies. The process is described
The impacts of SS and sewage treatment systems and land in more detail in the supplementary material.
application of SS have been previously assessed in numerous life The system boundaries of the DST (Fig. 1) start from the SS
cycle assessment (LCA) studies (Hospido et al., 2004; Lundin et al., leaving the preliminary treatment and extend to the disposal or
2004; Yoshida et al., 2013; Alyaseri and Zhou, 2017; Harder et al., reuse of the sludge product generated in the treatment processes.
2017). In addition to LCA, some multi-criteria decision analysis The system does not cover the avoided emissions caused by the
(MCDA) based methods have been applied. MCDA provides a substitution of energy and material in production. It also excludes
framework that analyzes and evaluates the alternatives systemat- dewatering or conditioning processes, such as the addition of
ically (Kiker et al., 2005). For example, Pijuan et al. (2010) presented polymers to SS, because these are considered as a preliminary
a combined MCDA and fuzzy logic tool for assessing the suitability treatment even though they might be located after the main
of SS for land application and Garrido-Baserba et al. (2015) used a treatment.
MCDA for the evaluation of SS treatment technologies. However, In our DST, the final product from the SS treatment was assumed
many of the previous studies do not comprehensively compare the to be applied on land as a fertilizer (if it fulfills the Finnish fertilizer
effects and assess the trade-offs associated with different treatment regulations) or disposed of as waste (if the fertilizer regulations are
options but only consider the effects of one treatment method or not met). When assessing the environmental risks in land appli-
ignore stakeholders. cation, only OCs were considered, since the heavy metals and
V. Turunen et al. / Chemosphere 193 (2018) 521e529 523

Risk factor
Wastewater treatment plant

5
8
7
0
1
3
6
9
Sludge pre-
treatment

Risk to groundwater and surface water


Treatment Treatment Treatment
system boundaries

method 1 method 2 method n

Product of Product of trea tment Product of trea tment

1 ¼ risks are uncertain


trea tment method 1 method 2 method n

Risk factors of organic contaminants (OC); PNEC ¼ Predicted No Effect Concentration; the references for each parameter are presented in the supplementary data (Table S19; S20; S21).

2 ¼ possible risk
Disposal// Disposal/ Disposal/

0 ¼ no risk
recycling recycling recycling

Avoi ded use of Avoi ded use of Avoi ded use of

0
0
0
0
0
1
0
2
ma terials/energy ma terials/energy ma terials/energy

1 ¼ risk of accumulation uncertain


Fig. 1. The system boundaries of the DST for choosing a sludge treatment method.

2 ¼ possible accumulation risk


pathogens in the SS products were not expected to cause envi-

0 ¼ does not accumulate


Accumulation in animals
ronmental hazards if their corresponding national limit values
were not exceeded. Some treatment methods decrease the OM
content of SS, thus increasing the concentration of heavy metals in
the product and may prevent its land application if the limit values
for metals are exceeded (Supplementary material:Table S2).
The OCs/OC groups considered were: polycyclic aromatic hy-

1
2
2
0
0
0
2
2
drocarbons (PAH), polychlorinated biphenyls (PCB), poly-
chlorinated dibenzodioxins and furans (PCDD/F), linear
alkylbenzene sulphonates (LAS), nonylphenols and their etoxylates

1 ¼ risk of accumulation uncertain


(NP/NPE), di-2-ethylhexyl phthalate (DEHP), polybrominated

2 ¼ possible accumulation risk


diphenyl ethers (PBDE), perfluorooctanesulfonic acid (PFOS), and
perfluorooctanoic acid (PFOA). This list includes different types of
0 ¼ does not accumulate
Accumulation in plants

contaminants, i.e., traditional recalcitrant persistent organic pol-


lutants (POP) as well as less recalcitrant bulk chemicals and
emerging problematic compounds such as perfluorinated com-
pounds (PFC) and PBDEs (Smith, 2009; Sternbeck, 2011; Clarke and
Smith, 2011). In addition, a significant amount of data was available
in the literature concerning the environmental fate and effects of
0
1
0
0
0
0
1
these compounds. 1
0 ¼ half life < 6 months

2 ¼ half life > 6 months

2.3. Calculation of preference scores


1 ¼ half life uncertain
Accumulation in soil

In MAVT, the superiority of each decision alternative is based on


its performance with respect to the decision criteria. The total
Average PNEC of naphthalene and phenanthrene was used.

preference score thus represents the superiority of a particular


alternative in relation to other decision alternatives. The higher is
the total preference score, the more desired is the decision alter-
Average PNEC of BDE-99 and BDE-209 was used.
2
2
2
0
0
0
2
2

native. Preference scores were calculated, as per Von Winterfeldt


and Edwards (1986), on the basis of attribute and sub-attribute
¼ 0,001 - 1 mg/kg

values and weights addressed to them and the criteria. The


Toxicity (soil PNEC mg/kg)

< 0,001 mg/kg

weights indicate the relative importance of each criterion or attri-


1e15 mg/kg
> 15 mg/kg

bute. The sum of the weights is normalized to 1 before calculating


the preference scores. In our DST, the value functions of the attri-
butes are assumed to be linear, and the values of the attributes’
value functions are normalized between 0 and 1.
PNEC
PNEC
PNEC
PNEC

We used Web-HIPRE, Java-based decision-making software


¼
¼
¼
¼

available from the internet, for calculating the preference scores of


0
1
2
3

2
3
3
0
1
2
1
2

the treatment alternatives (Mustajoki and Ha €ma€la


€inen, 2000).
Web-HIPRE was also used for conducting a sensitivity analysis to
NP/NPE
PCDD/F

test the sensitivity of our DST to changes in the weights. Sensitivity


PBDEb
DEHP
Table 1

PAHa

PFOS
PCB
LAS

analysis examines the stability of the model by checking the extent


OC

a
b

of variation in the output when the parameters of the model are


524 V. Turunen et al. / Chemosphere 193 (2018) 521e529

changed (Qureshi et al., 1999). soil, the contaminant's half-life in soil, the potential to accumulate
in crops, the potential to accumulate in animals, and the potential
risks it poses to ground water and surface waters (Table 1).
2.4. Determination of risk values for organic contaminants

In the determination of the environmental risks arising from


land application, the potential additive toxic effect of OCs present in 2.5. Testing of the DST
SS was taken into account by first calculating a risk value for each
individual key contaminant (Eq. (1)) and then summing up the 2.5.1. Case studies
values to produce an aggregated risk value (ARV) (Eq. (3)). The validity of the DST was tested using data from two (2)
Finnish WWTPs representative of Finnish WWTPs with different
Risk valueoc ¼ Ci  Rfi (1) scales and operational environments. Case A is a large-scale WWTP
located in Southern Finland in an urban environment. The capacity
of the WWTP is approximately 1,000,000 inhabitants based on the
Ci ¼ ð1  Di Þ  C0 (2)
incoming wastewater load, and the plant produces 64,000 metric
Xn tons of SS per year, which is digested anaerobically and dewatered
ARV ¼ i¼1
Riskvalueoci (3) to ca. 30% of total solids. Case B is a substantially smaller plant
(capacity for 47,000 inhabitants) located in Eastern Finland, in a
where Ci is the concentration of an organic contaminant “i” in the more rural setting. It produces 4773 metric tons of sludge annually,
SS product, Rfi is the risk factor of that OC, Di is the degradation rate which is digested anaerobically and dewatered to ca.30% of total
of that OC related to a specific treatment process, C0 is the initial solids. The treatment methods we studied were identified on the
concentration of that OC in the SS and ARV is the aggregated risk basis of discussions with the WWTP representatives, i.e., an
value of the SS product. Data on the concentrations (Ci) were employee in an operational role (case A) and the WWTP manager
compiled partly from the analyses made by the WWTPs and partly (case B), and considering the following conditions:
calculated by using Eq (2) and degradation data documented in the
literature.  The implementation of the SS treatment option is feasible in the
The calculation of the risk factor (Rfi) is based on the procedure particular case
presented by Clarke and Smith (2011). It considers five parameters:  The available data on the effects of the SS treatment for calcu-
the predicted no-effect concentration (PNEC) of a contaminant in lating the needed DST input data are sufficient.

Public opinion
Dema nd for the
s l udge product Usability

Organic ma er
Phosphorus
Recoverable
Nutrients
res ources
Nitrogen
Energy

Conta minants i n Metals


the s ludge product
Pathogens
Op mal treatment op on
Emi s sions and Organic contaminants
res i dues
GHG-emissions

Net cos ts Wa s te

Di rect a dverse effects

Securi ty of the Availability


process
Reliability

Fig. 2. The final value tree and its criteria/attributes/sub-attributes. The lighter color signifies that the attribute was not considered in decision-making in this study.
GHG ¼ Greenhouse gas. (For interpretation of the references to colour in this figure legend, the reader is referred to the web version of this article.)
V. Turunen et al. / Chemosphere 193 (2018) 521e529 525

Processes for nutrient recovery were not considered based on were rather evenly weighted but slightly emphasizing the criteria
the above-mentioned preconditions. In all the treatment alterna- “Demand for the sludge product” and “Contaminants in the sludge
tives in both cases, SS is anaerobically digested before additional product”.
treatment processes.
The decision alternatives in case A were: 3.2.2. Preferred treatment options
As expected, in the different decision alternatives, the contri-
 A1: composting bution of the different criteria to the total preference score varied
 A2: heat drying þ incineration (Fig. 3). Since the weighting in case A heavily favors destruction of
 A3: pyrolysis OCs and utilization of recoverable resources, the treatment option
A3 (i.e. pyrolysis) receives the highest total score (0.629). However,
The decision alternatives in case B were: the difference between the total preference scores of option A1 and
option A3 is not substantial because option A1 (composting) re-
 B1: stabilization with lime and acid ceives the highest score, for example, for the criteria “Direct
 B2: composting adverse effects” and “Net costs” and reasonably good scores for the
 B3: heat drying þ incineration rest of the criteria (total score of 0.580). Option A2 receives the
lowest score (0.484).
The criteria, attributes, and sub-attributes were weighted using In case B, the preference scores differ more significantly. The
direct weighting. The elicitation of weights was based on the lowest preference score (0.100) is attributed to option B3: heat
preferences of the WWTP representatives. drying þ incineration. This is mainly because the process in this
option is the most expensive, and it does not enable OM or nutri-
3. Results and discussion ents to be utilized. In fact, option B3 receives the lowest scores in all
of the criteria except the criterion “Contaminants in the sludge
3.1. Value tree product”. Option B1 (acid and lime treatment) receives the best
overall preference score (0.869), since it scores best with respect to
In our final value tree (Fig. 2).the main objective is divided into the criteria “Recoverable resources” and “Net costs,” among others.
seven (7) criteria, some of which are further divided into lower- In the validation of the model, the optimal treatment alternative
level attributes and sub-attributes. In the expert consultation pro- varied due to differences in the SS's properties, operational envi-
cess, the draft value tree was slightly modified, e.g., some criteria ronment of the WWTPs, and weighting. It can be noticed that the
were omitted and new ones were added. The criterion describing same treatment alternatives (e.g., A1 and B2) receive different
the mass of a SS product was originally expected to be an important preference scores in case A and in case B, depending on the local
decision criterion, but the interviews showed that it was rather a conditions. In case A, the WTTP's large size enables lower treatment
factor affecting the costs of sludge treatment. Thus, the criterion costs, whereas the direct adverse effects caused by the composting
“Mass of the sludge product” was omitted from our final value tree. process are expected to be more pronounced owing to the higher
The criterion “Demand for sludge product” and the attributes population number. Thus, the two different case studies demon-
“Organic matter” and “GHG emissions” were added to the value strate our DST's validity in a wide variety of different decision-
tree. In the preliminary value tree the attribute “Contaminants in making situations. The more intricate and abundant the input
the sludge product” was hierarchically below the criterion “Emis- data is, the easier it is to represent the idiosyncrasy of the specific
sions and residues”. In the final value tree it was included as a situation.
criterion of its own. In the DST, very different attributes are compared with each
We distinguished suitable indicators for each attribute and sub- other at the same level of hierarchy. For instance, it can be very
attribute to determine the values for the criteria (see Table 2). We difficult for stakeholders to assess the importance of GHG emis-
addressed qualitative (i.e., verbal) indicators for the attributes that sions against the importance of adverse effects caused by the OCs in
were not quantitatively measurable. These were further converted the SS product. Due to decision makers’ differing values and pref-
to numeric values. We defined the values for the attributes based erences, the weighting may also cause conflicts in the decision
on the literature, process data from the two studied WWTPs, and situation, which can complicate decision-making. Assigning
the expert judgment provided by the representatives of the weights to criteria/attributes may in fact be one of the most
WWTPs. Criteria that are time-dependent, such as operating costs, problematic issues of our DST.
were analyzed over the course of one year of WWTP's operation. Most previous decision support aids and LCAs assessing the
The aggregated risk value (ARV) (see Section 2.4) was used for effects of SS treatment include the three main criterion groups in
determining the risk caused by sludge-borne OCs following land environmental decision-making: economic, environmental and
application of SS. social criteria (Pijuan et al., 2010; Garrido-Baserba et al., 2015;
Alyaseri and Zhou, 2017). The differences rise from the division of
3.2. Validation of the DST these main criteria to smaller criterion groups and attributes.
A previous MCDA study by Garrido-Baserba et al. (2015)
3.2.1. Values of the criteria and attributes and their weighting included the global warming potential and annual cash flow,
For the validation of the DST, values were calculated for the whereas many LCA studies include numerous environmental
attributes and criteria in each decision alternative in both WWTP impact categories such as agricultural land occupation, climate
cases, and the criteria and attributes were weighted. The detailed change effects on the ecosystem and human health, eutrophication
calculation of the values can be found in the supplementary ma- and human toxicity. The criteria included in these LCA studies are
terial. In case A, heavy weights were given to the criteria “Recov- affected and limited by the methodology of the Life Cycle Impact
erable resources” (0.3) and “Contaminants in the sludge product” Assessment (LCIA) (Alyaseri and Zhou, 2017). Our DST has its focus
(0.3) with much less weight addressed to ”Net costs” and the “Se- on the recycling of resources and managing the risks caused by
curity of the process” (0.1 and 0.05 respectively). In case B, the sludge-borne OCs. It does not, however, consider, for example the
criteria “Net costs” and “Recoverable resources” received the land requirements for building treatment facilities nor exhibit a
highest weights (0.3, both). The rest of the criteria and attributes complicated financial analysis. Moreover, the value tree in this
526 V. Turunen et al. / Chemosphere 193 (2018) 521e529

Table 2
Indicators of the criteria/attributes/sub-attributes and their data sources. GHG ¼ Greenhouse gas; WWTP ¼ Wastewater treatment plant; ARV ¼ Aggregated risk value.

Criterion/attribute Explanation Measure Data source

Demand for the sludge product (þ) The market for the sludge product for
beneficial reuse
Public opinion Perception and public acceptance of the qualitative (1e10): 1 ¼ very strong expert judgement
use of the sludge product in agriculture opposition; 5 ¼ average; 10 ¼ perceived
as safe and acceptable
Usability The physical characteristics and quality qualitative (1e10): 1 ¼ cannot be used; expert judgement
of the sludge product which affect the 5 ¼ can be used but the properties are
spreading, storing etc. not ideal; 10 ¼ ideal properties for use
Recoverable resources (þ) Resources which can be utilized in the
treatment operation
a, b
Energy produced Energy produced in treatment methods GWh/a the two WWTPs studied; literature
for example incineration of sludge or
biogas
Nutrients Nutriens that can be utilized in
agriculture in the final product of
sludge treatment
Phosphorus Amount of phosphorus utilizable in t/year the two WWTPs studied
agriculture
c, d, e, f
Nitrogen Amount of nitrogen utilizable in t/year the two WWTPs studied; literature
agriculture
d, e, g, h, i
Organic matter Amount of organic matter utilizable in t/year Data from the WWTP; literature
agriculture
Pollutants in the sludge product (¡) The pollutants in the sewage sludge
which may cause risks in sludge land-
application
Pathogens Pathogens present in the final product e
(not considered)
Metals Amount of metals in the final product e
(not considered)
Organic contaminants Amount of organic contaminants in the ARV calculated value, see chapter 2.4 for details
final product
Emissions and residues (¡) The emissions and non-utilizable
sidestreams of the sludgre treatment
process
GHG-emissions Greenhouse gases emitted directly or t/year the two WWTPs studied; literaturea, j, k, l

indirectly by the treatment processes


Waste Waste generated in the treatment e
processes
a, m
Net costs (¡) The cost of running sludge treatment MV/year the two WWTPs studied; literature
operation (the possible revenue of
selling the final product was not
included)
Security of the process (þ) The ease-of-use and maintanance of the
treatment process
Reliability The frequency of malfunctions or qualitative (0e2): 0 ¼ unreliable; expert judgement
breakages of the process equipment 1 ¼ semi reliable; 2 ¼ very reliable
Availability The availability of the process qualitative (0e2): 0 ¼ novelty process, expert judgement
equipment and/or spare parts for poor availability; 1 ¼ used on a sizable
maintanance or breakage situations scale, moderately available; 2 ¼ used
extensively, commonly available
Direct adverse effects (¡) Local adverse effects caused by the qualitative (0e3):0 ¼ adverse effects expert judgement
treatment methods are very rate; 1 ¼ occasional adverse
effects; 2 ¼ significant or frequent
adverse effects; 3 ¼ severe adverse
effects or risk of accident

Bold was used to differentiate between the higher level criteria and the attributes/subattributes.
a
Myllymaa et al. (2008)
b
Inguanzo et al. (2002)
c
Hossain et al. (2011)
d
Solis et al. (2002)
e
Alvarez et al. (2002)
f
Mo€ller and Müller (2012)
g
Haynes et al. (2009)
h
Fonts et al. (2012)
i
Rigby et al. (2016)
j
Zupan ci
c and Ros (2003)
k
SYLVIS Environmental (2009)
l
Wang et al. (2013)
m €yry Environment (2007)
Po

study was built in cooperation with WWTP representatives. With structure of the DST, criteria, and the weighting of the criteria might
the contribution of different or additional stakeholders, the differ significantly. The hierarchical structure of the value tree can
V. Turunen et al. / Chemosphere 193 (2018) 521e529 527

weight higher than 0.3. If “Contaminants in the sludge product” is


very heavily weighted (>0.7) the optimal treatment method
changes to option B3. Both the overall distribution of criteria
weights and the case-specific values of the criteria/attributes affect
the sensitivity of the preferred treatment method to the weights.

3.4. Uncertainties involved

The validation of the DST includes many uncertainties caused by


a lack or low quality of the input data and data gaps concerning SS.
The most important knowledge gaps are related to the fate of OCs
and the availability of nutrients in the SS product. The effect of SS
treatment on the availability of phosphorus is still unknown, and
the documented studies show controversial results (Kahiluoto
et al., 2015; Seyhan and Erdincler, 2003; Haynes et al., 2009;
Jardin and Po € pel, 1994) while the effect of SS treatment processes
on nitrogen is known better (Hossain et al., 2011; Mo €ller and
Müller, 2012). In our study, the potential availability of P and N
was not considered due to the controversial data. In addition, we
did not consider the quality of the OM in the DST. The quality and
properties of the OM of the products from different SS treatment
processes are highly variable, but choosing a suitable single indi-
cator for OM was challenging. Furthermore, potassium and other
micronutrients present in SS were not considered in the DST, even
though they may increase the fertilizing properties of the SS
product.
Because of the unknown environmental fate and risks of sludge-
borne OCs, our risk assessment based on using ARV includes un-
certainty. The data needed for deriving the ARVs, such as the con-
centration of OCs and degradation rate, vary significantly in
different literature sources. It should also be noted that our risk
calculation method produces a risk factor of zero (0) for LAS. This
means that LAS would not contribute to the potential adverse ef-
Fig. 3. The total preference scores of the decision alternatives: Case study A - A1:
mesophilic anaerobic digestion þ composting; A2: mesophilic anaerobic fects in the land application of SS. However, in reality, high con-
digestion þ heat drying þ incineration; A3: mesophilic anaerobic centrations of LAS may cause environmental risks. Moreover, due to
digestion þ pyrolysis. Case study B - B1: mesophilic anaerobic digestion þ stabilization the lack of data, the calculated ARV assumes additivity of the OCs’
with lime and acid; B2: mesophilic anaerobic digestion þ composting; B3: mesophilic toxic responses and hence, ignores any combined effects, e.g.,
anaerobic digestion þ heat drying þ incineration.
antagonism or synergism.
Finally, it is worth noting that other factors, such as the prop-
erties of soil, climate, weather conditions, and plant species, and
affect the outcome of the decision process because the attributes
not only the SS treatment process, also determine the final
that are low in the hierarchy have a smaller effect on the total
bioavailability of nutrients and OCs to organisms. Moreover, the
preference score. The low-level attributes may also receive less
costs of SS treatment depend on the demand and supply of the
emphasis from the decision-makers (Borcherding and von
treatment technologies and are therefore highly variable. Finally,
Winterfeldt, 1988), which is why the value tree should have
the reliability of the values of the qualitative indicators depends on
approximately the same number of criteria/attributes on each hi-
their assessor's expertise and perceptions.
erarchy level (Mustajoki, 2015). Our value tree had a slightly un-
even distribution of criteria/attributes.
4. Conclusions and future perspectives

3.3. Sensitivity to weights In this paper, we presented the construction and validation of an
MAVT-based DST, which provides a systematic and transparent
To test the sensitivity of our DST to changes in criteria weights, process for making a justified decision on a sewage sludge treat-
we conducted a sensitivity analysis for the case studies (Fig. 4). The ment. The final DST is a hierarchical value tree, which comprises
analysis for case A showed that if higher weights were attributed to criteria, attributes and sub-attributes that can be weighted. Each
“Direct adverse effects” (>0.15), “Security of the process” (>0.15), alternative receives a preference score based on its performance as
“Emission and residues” (>0.35)”or “Net costs” (>0.15) the optimal for the attributes and the weighting of the criteria.
treatment method would change from option A3 to option A1. The The DST offers a systematic framework for decision-making thus
optimal treatment method would only change to option A2 if the making it less likely for decisions to be made based on prejudices
criterion “Contaminants in the sludge product” was heavily and old habits. A structured, relatively simple and transparent
weighted (weight > 0.6). In case B, the optimal treatment option decision-making tool also enables an easier and wider involvement
(B1) is significantly less sensitive to the changes in criteria weights. of the stakeholders. However, in this study, the weighting was done
The optimal treatment alternative changes to B2 if “Demand” or only with the WWTP representatives. In a real-life situation, other
“Emissions and residues” are heavily weighted (>0.65 and > 0.5, stakeholders are usually involved in the decision process, which
respectively) or if “Contaminants in the sludge product” receives a may lead to different results.
528 V. Turunen et al. / Chemosphere 193 (2018) 521e529

Case A

Direct adverse effects


Contaminants in the sludge Emissions and residues Netcosts
product
1 1 1

Preference score

Preference score

Preference score
1 0.8 0.8 0.8
Preference score

0.8
0.6 0.6 0.6
0.6
0.4 0.4 0.4
0.4
0.2 0.2 0.2 0.2
0 0 0 0
0 0.5 1 0 0.5 1 0 0.5 1 0 0.5 1
Weight Weight Weight Weight

A1 A2 A3 A1 A2 A3 A1 A2 A3 A1 A2 A3

Security of the process


1
Preference score

0.8
0.6
0.4
0.2
0
0 0.5 1
Weight

A1 A2 A3

Case B

Demand for sludge product Contaminants in the sludge Emissions and residues Security of the process
product
1 1 1
Preference score

Preference score
Preference score

0.8 1 0.8 0.8


Preference score

0.8
0.6 0.6 0.6
0.6
0.4 0.4 0.4
0.4
0.2 0.2 0.2 0.2
0 0 0 0
0 0.5 1 0 0.5 1 0 0.5 1 0 0.5 1
Weight Weight Weight Weight

B1 B2 B3 B1 B2 B3 B1 B2 B3 B1 B2 B3

Fig. 4. Sensitivity of the results to criteria weights. Only those results where the change in the weighting of a single criterion caused changes in the preference order of the
treatment options are shown. Hence, the weighting of criteria “Demand for sludge product” and “Recoverable resources” (case A) and “Recoverable resources”, “Net costs” and
“Direct adverse effects” (case B) did not affect the priority order of the treatment alternatives. Case study A - A1: mesophilic anaerobic digestion þ composting; A2: mesophilic
anaerobic digestion þ heat drying þ incineration; A3: mesophilic anaerobic digestion þ pyrolysis. Case study B - B1: mesophilic anaerobic digestion þ stabilization with lime and
acid; B2: mesophilic anaerobic digestion þ composting; B3: mesophilic anaerobic digestion þ heat drying þ incineration; the horizontal line indicates the original weight of the
criterion in the case study.

The validation of the DST showed its usefulness for decision- also beneficial to study whether some characteristics of the
making in different situations. While weighting has a strong ef- WWTPs affect the stakeholders’ prioritization.
fect on the preferred treatment method, the outcome is also highly
affected by the values of the criteria/attributes, which in turn are Appendix A. Supplementary data
very dependent on the operational environment.
It is worth noting that any decision problem is almost inevitably Supplementary data related to this article can be found at
simplified when described by a value tree, and some important https://doi.org/10.1016/j.chemosphere.2017.11.052.
decision criteria may be left out. Real-life decision-making situa-
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