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PHYSICS MCQ’s with Full Explanations
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VOL-4
Ray Optics| Wave Optics| Dual Nature Of Matter & Photo Electric Effect| Atoms X-rays|
VOL-3
Nuclear Physics| Electronic
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Properties Of Matter| Thermal Properties Of
VOL-2
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Simple
& Hormonic Motion| Waves On A String| Sound Waves| Kinetic Motion
Theory Of
VOL-1
Dimensions| Basic Mathematics| Motion In One Dimension| In Two Dimension|
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VOL-3
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& Absorption plants|Anatomy
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|Biological Classification |Animal Kingdom|Structural Organisation in Animals
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Chemistry Times July 18
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Chemistry Times July 18
Little more: If the substance under examination contains sulphur also, the gases evolved are first passed
through an acidified solution of potassium dichromate which absorbs all the sulphur dioxide and then
through lime water and which turns milky.
S 2CuO
2Cu SO2
K 2 Cr2 O7 H 2 SO4 3SO2
K 2 SO4 Cr2 ( SO4 )3 H 2 O
SO2 like CO2 turns lime water milky due to formation of CaSO3 .
Organic compounds (suppose to contain P) are heated with oxidizing agents (like Na2 O2 ). The phosphorus
present in the organic compound is oxidized to phosphate.
Little more
Lithium is not used in Lassaigne’s test as it reacts slowly moreover its compounds are covalent. Potassium
cannot be used in this test as its reaction is violent.
Instead of sodium metal, mixture of sodium carbonate and zinc can be used. It is called Middleton’s fusion
method.
3
Chemistry Times July 18
Sometimes when the amount of nitrogen present is Na2 S Cd (CH 3COO) 2 CdS (Yellow ppt)
small, the prussian blue is present in colloidal form 2CH 3COONa
and the solution looks green. Oxidation test: The organic compound is fused
When the alkaline solution is acidified with HCl, with fusion mixture (a mixture of sodium carbonate
the yellow color of ferric chloride produced by the and potassium nitrate). The sulphur, is present in
acid with ferric ions makes the blue color to appear the organic compound, is oxidised to sodium
as green. sulphate.
When the organic substance contains both N and
S, sodium thiocyanate is formed which gives a Na2 CO3 S 3O Na2 SO4 CO2
blood red coloration of ferric sulphocyanide (or The fused mass is dissolved in water and the
ferric thiocyanate) with ferric ions. solution is acidified with HCl. BaCl2 solution is
3 NaCNS FeCl3
Fe(CNS )3 3 NaCl then added. The formation of a white ppt. indicates
Blood red
the presence of sulphur.
If sodium fusion is carried out with excess of
sodium, the thiocyanate decomposes to give Na2 SO4 BaCl2 BaSO4 (white ppt) 2NaCl
cyanide and sulphide. These ions give usual tests (3) Detection of Halogens
The sodium fusion extract is acidified with nitric
NaSCN 2 Na NaCN Na2 S
acid and then treated with silver nitrate. A white
This test is not given by compounds which do not precipitate, soluble in ammonium hydroxide
contain C atoms but contain N atoms, (aqueous ammonia) shows the presence of
for example, NH 2 NH 2 , NH 2 OH . Since these chlorine, a yellowish precipitate, sparingly soluble
compounds do not contain C atoms, so in sodium in ammonium hydroxide shows the presence of
bromine and a yellow precipitate, insoluble in
fusion extract, CN ion is not formed and Prussian
ammonium hydroxide shows the presence of iodine.
blue color is not observed.
This test is not given by diazonium salt also, AgNO3 NaCl
AgCl (White ppt) NaNO3
although they contain both C and N elements, AgNO3 NaBr
AgBr (Pale yellow ppt)
because they decompose and loses N 2 on heating
NaNO3
much before they have a chance to react with the
fused sodium metal. AgNO3 NaI
AgI (Yellow ppt) NaNO3
If nitrogen or sulphur is also present in the
(2) Detection of sulphur compound, the sodium fusion extract is first boiled
Sulphur is present in the sodium extract in the form with concentrated nitric acid to decompose cyanide
of sodium sulphide ( Na2 S ) . Sulphur is tested in or sulphide of sodium formed during Lassaigne’s
the sodium extract in the following manner: test. These ions would otherwise interfere with
The sodium fusion extract is acidified with acetic silver nitrate test for halogens. If these ions are not
acid and lead acetate is added to it. A black removed, they would give a white precipitate of
precipitate of lead sulphide indicates the presence AgCN or Ag 2 S with AgNO3 and will confuse it
of sulphur. for AgCl.
Na2 S Pb(CH 3COO ) 2 PbS (Black ppt)
Little More
2CH 3COONa
On treating sodium fusion extract with sodium Chlorine water test (layer test) for Br2 and I 2 :
nitroprusside, appearance of a violet color further From the color of AgBr and AgI, it is difficult to
indicates the presence of sulphur. judge whether the organic compound contains Br
or I. A small portion of Na extract is acidified with
Na2 S Na2 [ Fe( NO)(CN )5 ] Na4 [ Fe( NOS )(CN )5 ]
Sodium nitroprusside Sodium thionitroprusside dilute HNO3 or H 2 SO4 and add CS2 Cl3 or CCl4 .
4
Chemistry Times July 18
Now shake with excess of Cl2 water. If the color of the CCl4 layer becomes yellow or brown ‘Br’ is present.
2 NaBr Cl2
2 NaCl Br2
(turns CS2 layer orange)
If the color of the CCl4 layer turns violet ‘iodine’ is present.
2 NaI Cl2
2 NaCl I 2
(turns CS2 layer violet)
5
Chemistry Times July 18
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Chemistry Times July 18
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Chemistry Times July 18
Weight of RCOOAg = W gm
W w W 195
Weight of Ag = w gm E 205
1 equivalent of RCOOAg = 1 equivalent of Ag 2 E 410 195 w 2
(c) Volumetric method for organic acids and bases
W w
i. A known mass of organic acid is dissolved in water
E 107 108 or alcohol and titrated against a standard NaOH or
W 108 KOH solution. From the volume of alkali used, the
E 107 equivalent weight of organic acid can be calculated.
w
V mL of ‘N’ NaOH = w gm of organic acid
(MW of an acid = E x x – factor)
(b) Chloroplatinate or Platinichloride method for w 1000
1000 mL of ‘N’ NaOH 1gm
organic bases V
Organic bases form salts with HCl and the chlorides equivalent of the base EW of the base
give double salts with platinum chloride. Organic
Equivalent of acid = EW of the organic acid
bases react with dibasic chloroplatinic acid
Where ‘V’ is volume of ‘N’ NaOH used for
( H 2 PtCl6 ) and form double salts and are called neutralizing ‘w’ gm of acid.
chloroplatinates or platinichlorides. These salts ii. Organic bases: A known mass of organic base is
leave a residue of metallic platinum on ignition. titrated against a standard acid (e.g., HCl or oxalic
Equivalent weight of organic base = E acid). From the volume of the acid used, the
Mass or weight of chloroplatinate salt = W gm equivalent weight of organic base can be calculated.
Mass or weight of platinum = w gm V mL of ‘N’ HCl = w gm of the organic base
Equivalent weight of platinum = 195 w1000
1000 mL of ‘N’ HCl 1gm equivalent of
2E H 2 PtCl6
E2 H 2 PtCl6 Pt V N
Equivalent weight of E2 H 2 PtCl6 2 E 2 195 the base EW of the base
(6 35.5) 2E 410 Where ‘V’ is volume of ‘N’ HCl used for neutralizing
‘w’ gm of base.
1 equivalent of E2 H 2 PtCl6 1 equivalent of Pt
Calculation of Empirical Formula and Molecular Formula
An empirical formula represents the simplest whole number ratio of various atoms present in a compound
whereas the molecular formula shows the exact number of different types of atoms present in a molecule of
a compound.
If the mass percent of various elements present in a compound is known, its empirical formula can be
determined. Molecular formula can further obtained if the molar mass is known. The following steps illustrates
this sequence:
9
Chemistry Times July 18
Temperature 15 C
Atmospheric pressure = 750 mm
Vapor pressure of water at 15 C 13 mm 1.Sol: It is test for the organic compound containing
The vapor density of the compound is N and S.
(a) 120 (b) 60 (c) 45 (d) 30
16. 40 g of a substance were dissolved in 450 g of 3 NaCNS FeCl3
Fe(CNS )3 3 NaCl
Blood red
water to give a solution which boils at 100.2C . If sodium fusion is carried out with excess of
Calculate molecular weight of substance. K b for sodium, the thiocyanate decomposes to give
cyanide and sulphide. These ions gives usual tests
water 0.51K kg mol 1 .
NaSCN 2 Na
NaCN Na2 S
(a) 227 (b) 40 (c) 250 (d) 100
17. 0.76 g of the silver salt of a dibasic acid was ignited. 2.Sol: Diazonium salts are stable only at 0 5 C . At
It gave 0.54 g of pure silver. The molecular mass of high temperature, it releases N 2 gas.
the acid is
(a) 45 (b) 90 (c) 60 (d) 85 3.Sol: Conc. HNO3 decomposes Na2 S and NaCN, if
18. An aromatic mono basic acid contains 68.87% C formed.
and 4.9 % H. 0.610 g of the acid required 25 mL of 4.Sol:
M/10 diacidic base for neutralization. What is
80 Mass of AgBr formed
molecular formula of acid? % of Br 100
188 Mass of substance taken
(a) C7 H 6 O2 (b) CH 3O (c) C3 H 6 O (d) CHO
19. An organic compound gave the following data: 80 141
100 24%
0.236 g yielded 0.528 g CO2 and 0.324 g H 2 O on 188 240
combustion. 0.295 g of the compound gave 56 mL 5.Sol: It is an example of Beilstein test
7.Sol:
of N 2 at STP. The compound is a monoacidic base.
12 Mass of CO2
It’s platinic chloride salt contains 36.93% platinum. % of C 100
44 Mass of organic compound
Calculate the molecular formula of the compound.
12 0.198
(a) CH 3 N (b) C3 H 9 N (c) CHN (d) C4 H 8 N % of C 100 23.01%
44 0.246
20. The freezing point constant of C6 H 6 is 4.9 K 2 Mass of H 2 O
% of H 100
kg mol 1 and its melting point is 5.51C . A 18 Mass of organic compound
solution of 0.816 g of compound (A) when 2 0.1014
% of H 100 4.58%
dissolved in 7.5 g of C6 H 6 freezes at 1.59C . The 18 0.246
8.Sol: Increase in mass of U - tube = Mass of water
compound (A) has C = 70.58% and H = 5.88%. formed = 1.08 g
Determine the molecular formula of (A).
2 Mass of H 2 O
(a) CHO (b) C4 H 4 O2 (c) CHO2 (d) C8 H 8O2 % of H 100
18 Mass of organic compound
2 1.08
% of H 100 13.04%
18 0.92
Increase in mass of Potash bulbs = Mass of CO2
1. a 2. b 3. a 4. c 5. d formed = 1.76 g
6. c 7. a 8. b 9. b 10. c 12 Mass of CO2
1. b
11. 12. a 13. d 14. a 15. b % of C 100
44 Mass of organic compound
16. a 17. b 18. a 19. b 20. d
12 1.76
% of C 100 52.17%
44 0.92
10
Chemistry Times July 18
% of O 100 [% of C % of H ] 13.Sol:
11
Chemistry Times July 18
2 Mass of H 2 O
% of H 100 12 0.324 100 15.25%
18 Mass of organic compound 18 0.236
28 V2
% of N 100 28 56 100 23.73%
22400 Massof organiccompound 22400 0.295
12
Chemistry Times July 18
13
Chemistry Times July 18
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Chemistry Times July 18
1 r0 r
(c) k t ln r r
t
15
Chemistry Times July 18
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Chemistry Times July 18
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Chemistry Times July 18
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Chemistry Times July 18
PAPER-1
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Chemistry Times July 18
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Chemistry Times July 18
(c) (d)
(c) (d)
16. The compound Z is
(a) (b)
22
Chemistry Times July 18
4.Sol:
5.Sol:
6.Sol:
AB Isothermal process, E or U 0
AC Isochoric process, v U
BC Isobaric process, p H
7.Sol: K 2 CrO4 i.e. Cr 6 d 0 (diamagnetic)
Paramagnetic H-atom, NO2 (monomer), O2 (superoxide), S2 (vap), Mn3O4 , ( NH 4 ) 2 [ FeCl4 ] ,
( NH 4 ) 2 [ NiCl4 ], K 2 MnO4 .
23
Chemistry Times July 18
11.Sol: [n ]
13.Sol: Solubility K sp 1
Ka
24
Chemistry Times July 18
103
Y 103 2 1010 1 8 2 105
10
X
1 2 ( K B ) X m (0.65) ( K b )Y m
X 0.05
15, 16.Sol:
25
Chemistry Times July 18
17, 18.Sol:
[O ] ethylene glycol
Organic Acid (C11 H12 O2 ) dibasic acid polymer (dacron)
O3
( P)
Zn / H 2O
aliphatic ketone other products.
alkene
Mg|Et2 O
CO2 ( dryice)
H 3O
26
Chemistry Times July 18
ATOMIC STRUCTURE
Introduction
The belief of John Dalton that atom is indivisible In 1897, J.J.Thomson determined e/m value (or
was disapproved by experimental evidences of charge/mass value) as -1.7588x108 C/g and
different isotopes of elements with different masses proved that whatever gas be taken in the
which ultimately led for the discovery of the discharge tube and whatever be the material of
fundamental particles such as electron, proton and the electrodes, the value of e/m is always the
neutron. same.
Electrons are, thus, common universal
Sub-atomic particles constituents of all atoms.
(1) Electron: The charge (e) on electrons was determined
The nature and existence of electron was (Millikan Oil drop experiment) to be -1.602 x 10-19
established by experiments on conduction C or -4.803 x 10-10 esu or unit negative charge.
electricity through gases i.e., discovery of
cathode rays. e
Rest Mass of electron : m e = e/m
e
1.60×10-19
= kg =9.1094×10 -31kg
1.758820×1011
Some of the characteristics of cathode rays are
given below: = 0.000548 amu (or) 1/1837 times of proton
Cathode rays travel with high speed of the order of
107 m/s, in straight lines and produce shadows of
the objects placed in their path.
Cathode rays can penetrate through thin layers of
matter. Mass of electron in motion
Cathode rays possess high kinetic energy and
Rest mass of electron
therefore m'
(i) they exert mechanical pressure on the object on 1 u c 2
which they fall
(ii) they produce heat when stopped by matter u = Velocity of electron
(iii) they can ionise a gas c = Velocity of light
Cathode rays are deflected by electric and magnetic if u = c then mass of moving electron
field both
Cathode rays produce fluorescence when they fall Lorentz named “a subatomic particle i.e., a
on certain substances like ZnS. The colour of fundamental constituent of all matter, having a
fluorescence depends upon the chemical nature of mass of 9.08 10-31 kg and charge equal to -1.602
substance. 10-19 C” as electron (usually represented as
o
Cathode rays on striking metal target of high atomic e-1).
number such as tungsten, produce highly The Radius of electron = 4.28 10-14 cm
penetrating X - rays. 1 mole of electrons have 1 Faraday (96500 C)
charge.
27
Chemistry Times July 18
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Chemistry Times July 18
The scattering i.e., number of scattered (3)If the motion of an electron in orbits is leading
particles (N) is proportional to the square to the instability of the atom. Considering
of the atomic number (Z) of both the incident electrons as stationary around the nucleus
particles (i.e., Z ) and the target scatterer (Zt). electrostatic attraction between the dense
The number of particles showing scattering nucleus and the electrons would pull the
is inversely proportional to the fourth power of electrons toward the nucleus to form a miniature
sin / 2 where is the scattering angle i.e., version of Thomson’s model of atom which was
already rejected.
sin 4 ( / 2). Rutherford model says nothing about the
The number of particles showing scattering electronic structure of atoms i.e., how the
is minimum when / 2 = 900 i.e., = 180o electrons are distributed around the nucleus and
Rutherford model or Planetry model what are the energies of these electrons.
Nucleus is small portion of atom where the Atomic number and Mass number
positive charge and most of the mass of the A neutral atom contains equal number of
atom is concentrated. electrons and protons.
Electrons move around the nucleus with a very Atomic number(Z) : The number of protons or
high speed in circular paths called orbits. electrons(in neutral atoms)
These observation led Rutherford to propose Moseley discovered the relationship between
the concept of nucleus in an atom. The size of frequencies of the characteristic X-rays of an
the various nuclei can be calculated from the element and its atomic number. v=a(Z-b), v is
relation,
the frequency of characteristic x-rays, ‘a’ and
r = (1.33 10-13)A1/3
‘b’ are constants having definite values for that
where r is the radius of the nucelus (in cm) with
element.
mass number A.
Electrons and the nucleus are held together by
electrostatic forces of attraction. The centrifugal
force arising due to fast moving electrons
balances the coulombic force of attraction of
the nucleus and the electrons.
q1q 2
Coulombic force = k
r2
q1 and q2 are charges, r is the distance of
separation of the charges and
k is proportionality constant between electron
and the nucleus.
Defects of Rutherford’s atomic model
(1) It cannot explain Stability of Atom. These values are different for different elements.
According to the electromagnetic theory of Thus it became evident that Atomic number is
Maxwell, charged particles when accelerated responsible for chemical reactivity of elements.
should emit electromagnetic radiation (This Mass Number(A) : The sum of protons and
feature does not exist for planets since they are neutrons in the atom of an element. Mass
uncharged). Therefore, an electron in an orbit number is always a whole number.
will emit radiation, the energy carried by radiation Number of neutrons(n) = A - Z.
comes from electronic motion. The orbit will thus Isotopes : Same Z but different A or A - Z
continue to shrink. Calculations show that it Isobars : Different Z but Same A
should take an electron only 10–8 s to spiral into Hydrogen : 1H1, (1D2 or 1H2), (1T3 or 1H3). C14 and
the nucleus. But this does not happen. 7
N14
(2) It fails to explain the atomic spectrum or line Carbon : 6C12, 6C13, 6C14
spectrum. Isotones : Different Z, A but same A-Z
29
Chemistry Times July 18
Chlorine :17Cl35, 17Cl37, 9F19, 10Ne20 These fields are transmitted in the forms of
Isoelectronic: Different Z,A and A-Z but same waves called electromagnetic waves or
no. of electrons CO and N2 electromagnetic radiation.
Maxwell revealed that light waves are
associated with oscillating electric and magnetic
Developments leading to the Bohr’s character which are perpendicular to each other
model of atom and perpendicular to the direction of
The developments played a major role in the propagation of the wave.
formulation of Bohr’s model of atom were: Electromagnetic waves do not require medium
Dual character of the electromagnetic radiation for propagation and can move in vacuum.
(EMR) i.e., wave and particle nature. There are many types of electromagnetic
Experimental results of atomic spectra can be radiations, which differ from one another in
explained only by assuming quantised electronic wavelength (or frequency). These constitute
energy levels in atoms. what is called electromagnetic spectrum.
(1) Wave nature of Electromagnetic (I) Electromagnetic spectrum:
radiation (Maxwell) The arrangements of the various types of
When electrically charged particle moves under electromagnetic radiation in order of their
acceleration, alternating electrical and magnetic increasing (or decreasing) wavelengths or
fields are produced and transmitted. frequencies is known as electromagnetic
spectrum.
Sources of EMR:
Gamma rays: Produced from nuclei of radioactive atoms through the process of radioactive disintegration
going on spontaneously in nature.
X - rays: Produced by placing a metal obstacle in the path of a fast moving stream of electrons.
UV radiation: Present in sun’s rays. The laboratory sources of UV radiation are arc lamps containing Hg
vapour, Xe or hydrogen gas.
Visible radiation: Produced from stars, arc lamps, hot filaments as of tungsten in an electric bulb, etc. It is
important to note that our eye is sensitive only to radiation lying between wavelengths of 3800-7600 Ao i.e.,
visible radiation
IR radiation: Emitted by incandescent objects.
Microwaves: Generated by special generators, e.g., Klystron tube. These waves are used in telephone
circuits.
Radiowaves: Generated from alternating electric currents of high frequencies.
30
Chemistry Times July 18
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Chemistry Times July 18
With this theory, Planck was able to explain the the phenomena of interference and diffraction.
distribution of intensity in the radiation from The particle nature of light was explained by the
black body as a function of frequency or Black Body Radiation and photoelectric effect.
wavelength at different temperatures. Whenever radiation interacts with matter, it
displays particle like properties and whenever
radiation propagates it displays wave like
properties.
Some microscopic particles like electrons also
One quantum is packet of energy not necessarily exhibit this wave-particle duality.
light. Photon is not a material body but it is a packet
(4) Evidence for the quantised electronic
of light energy.
Intensity of light (number of photons falling per energy levels (Spectra):
unit area per sec) depends upon the number of A ray of white light is spread out into a series of
these photons and if intensity of light is referred coloured bands called spectrum.
as amount of energy falling per unit area per sec; E.g:White light consists of waves with all the
then it also depends upon the wavelength of wavelengths in the visible range - Rainbow
photons used. When electromagnetic radiation interacts with
The rest mass of photon is zero. matter, atoms and molecules may absorb energy
and reach to a higher energy state.
With higher energy these are in an unstable
(III) Photoelectric effect:
state and to return back normal (more stable,
Ejection of the electrons from metal surface when
lower energy states) energy state, the atoms and
exposed to a beam of light is called as
molecules emit radiations in various regions of
Photoelectric Effect.
the electromagnetic spectrum.
E.g:Potassium, Rubidium, Caesium etc.
Emission spectrum: The spectrum of radiation
Einstein (1905) was able to explain the
emitted by a substance that has absorbed energy
photoelectric effect using Planck’s quantum
is known as emission spectrum
theory
Absorption spectrum : It is like the photographic
(A) Light particles are referred as the photons.
negative of an emission spectrum. A continuum
When a photon of sufficient energy strikes
of radiation is passed through a sample which
an electron in the atom of the metal, it
absorbs radiation of certain wavelengths. The
transfers its energy instantaneously to the
missing wavelength which corresponds to the
electron during the collision and the electron
radiation absorbed by the matter, leave dark
is ejected without any time lag or delay.
spaces in the bright continuous spectrum.
(B) Kinetic energy of the ejected electron is
The spectrum of the visible light is continuous
proportional to the frequency of the EMR
as all wavelengths (red to violet) are represented
(C) Since the striking photon has energy equal
in the spectra.
to hv and the minimum energy required to
The emission spectra of atoms in the gas phase
eject the electron is hv0 (also called work
is called line spectra or atomic spectra. Each
function, W0 )
element has a unique line emission spectrum.
(D) The difference in energy (hv – hv0 ) is
Elements like Helium (He), Rubidium (Rb),
transferred as the kinetic energy of the
Caesium (Cs), Thallium (Tl), Indium (In), Gallium
photoelectron.
(Ga) and Scandium (Sc) were discovered by
K.E of ejected electron =1/2meV2 = hv – hv0
spectroscopic methods.
(me = mass of electron)
(V = Velocity of ejected electron.) Hydrogen spectrum
(E) A more intense beam of light consists of The hydrogen spectrum is the simplest of all the
larger number of photons, consequently the atomic spectra.
number of electrons ejected is also larger. Although H - atom has only one electron, yet its
(3) Dual nature of EMR spectrum consists of several lines. A sample of H2
The wave behaviour of light could account for
gas, contains infinite number of molecules.
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Chemistry Times July 18
The hydrogen spectrum consists of several series Line spectrum becomes more and more complex
of lines named after their discoverers. for heavier atom but certain features which are
The wavelength or wave number of various lines in
common to all line spectra are
the visible region can be expressed by Rydberg’s i) Line spectrum of element is unique and
equation. ii) There is regularity in the line spectrum of each
element.
1 1 1
= = RH 2- 2
λ n1 n 2
The value of RH = 1,09,678 cm-1 is valid only for the
lines in the hydrogen spectrum.
For one electron species like He+, Li2+ .... etc, the
value of R = RH x Z2
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Chemistry Times July 18
= Frequency of radiation En = 2
ergs/atom
n
The line spectrum is obtained due to the
electronic transition from one orbit to another
-18
orbit -2.179 ×10
= Joules/atom
(2) Some important results of Bohr’s n
2
equation:
The force of attraction between the nucleus and -13.6
= eV/atom
the electron = -Ze 2 r 2 n
2
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Chemistry Times July 18
This confirms that as the photon has momentum
2π Ze 2 2.188×108
V= = cm/sec as well as wavelength, electrons should also
nh n have momentum as well as wavelength.
For hydrogen atom Vn = V1 n h h
For H atom like ions Vn = ZV1 n de-Broglie’s equation is λ = mν = p
Ionisation potential Bohr’s theory and de Broglie’s concept:
For hydrogen atom, I.P= -E1 n 2 According to de Broglie, an electron behaves
as a standing or stationary wave which extends
For H atom like ions, I.P= -Z 2 E1 n 2 round the nucleus in a circular orbit when it
(3) Merits of Bohr’s model: revolves in those orbits.
It successfully explained the hydrogen spectrum There is constructive interference of electron
and spectra of ions having one electron. waves and the electron motion has a character
Energies, radii of possible orbits, Ionisation of standing wave or non-energy radiating
enthalpy and Rydberg constant of hydrogen motion.
atom are in good agreement with experimental An electron wave to be in phase, the
values circumference of the Bohr’s orbit should be an
(4) Limitations of Bohr’s model: integral multiple of the wavelength of the
It failed to explain - the spectra of atoms or ions electron wave.
having more than one electron, fine structure of nλ = 2πr
spectral lines, Zeeman effect and Stark effect.
nh h nh
=2πr(λ= ) on rearranging mvr= (Bohr concept)
mv mv 2π
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Chemistry Times July 18
36
Chemistry Times July 18
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Chemistry Times July 18
px 1 YZ Energies of orbitals:
The energy of an electron in a hydrogen atom is
py 1 ZX determined solely by the principal quantum number.
pz 1 XY Thus the energy of the orbitals increases as
follows:1s < 2s = 2p < 3s = 3p = 3d <4s = 4p = 4d=
d xy 2 YZ, ZX 4f < ......
d yz 2 ZX, XY The energy of an electron in a multielectron atom,
depends not only on its principal quantum number
d zx 2 XY, YZ (shell), but also on its azimuthal quantum number
d x 2 y2 (subshell) i.e., for a given principal quantum
2 YZ, ZX
number, s, p, d, f ... of same energy level have
Two planes parallel to Z - axis and making angle of different energies.
45o relative to X or Y - axes. Effective nuclear charge(Zeff) : The net positive
charge experienced by the outer electrons is known
Orbit, orbital and its Importance as effective nuclear charge. For a given value of ‘n’
Orbit and orbital are not synonymous. the Zeff experienced by the electron decreases with
Orbit : An orbit, as proposed by Bohr, is a circular increase of azimuthal quantum number (l),
path around the nucleus in which an electron Shielding effect : The attractive effect will be
moves. A precise description of this path of the lowered due to the partial screening of positive
electron is impossible according to Heisenberg charge on the nucleus by the inner shell electrons.
uncertainty principle. Bohr orbits, therefore, have Effective sheilding order is s > p > d > f even if all
no real meaning and their existence can never be are present in same ‘n’
demonstrated experimentally. (n+l)rule : Mathematically, the dependence of
Orbital : Shape of the orbital which encloses a energies of the orbitals on n and l are quite
region or volume in which the probability of complicated but one simple rule is that,
finding the electron is very high, say, 90%. Enclosed a)The lower the value of (n + l) for an orbital, the
region is referred as Boundary surface diagram or lower is its energy.
contour surface diagram. An atomic orbital, on the b)If two orbitals have the same value of (n + l), the
other hand, is a quantum mechanical concept and orbital with lower value of ‘n’ will have the lower
energy.
refers to the one electron wave function in an
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Chemistry Times July 18
Filling of electrons in Orbitals of an 2. An oil drop has 6.39 1019 C charge. The number
Atom of electrons in this drop is
The filling of electrons into the orbitals of different (a) 2 (b) 3 (c) 4 (d) 5
atoms takes place according to the aufbau principle 3. Which of the following statements is wrong about
which is based on the Pauli’s exclusion principle, cathode rays?
the Hund’s rule of maximum multiplicity and the (a) They travel in straight line towards cathode.
relative energies of the orbitals. (b) They produce heating effect.
(c) They are carrying negative charge.
(1) Aufbau principle:
(d) They produce X - rays when strike with material
Electron filling follows energy ranking. The
having high atomic masses.
orbitals are successively filled in the order of
4. Rutherford’s experiment which establishes the
their increasing energy.The energy value of an
nuclear atom model of the atom, used a beam of
orbital increases as its (n + l) value increases.
(a) particles, which impinged on a metal foil
(2) Pauli’s exclusion principle:
(I) No two electrons in the same atom can have the and got absorbed
same values for all the four quantum numbers. (b) particles which impinged on a metal foil
(II) Maximum number of electrons in an orbital is and ejected electrons
two. (c) particles which impinged on a metal foil
(3) Hund’s rule: and got scattered
Pairing does not take place unless degenerate (d) Helium atoms which impinged on a metal foil
(same energy containing) orbitals are occupied and got scattered
singly. Unpaired electrons have parallel spin and 5. According to Bohr’s atomic theory, the correct
are paramagnetic in behaviour. statement is
Extra Stability of Half and fully Filled Orbitals Z2
due to maximum exchange energy. (a) Potential energy of electron
n2
E.C of Cr - atom is1s2 2s2 2p6 3s2 3p6 3d5 4s1 but not
1s2 2s2 2p6 3s2 3p6 3d4 4s2. (b) The product of velocity of electron and principal
E.C of Cu - atom is 1s2 2s2 2p6 3s2 3p6 3d10 4s1 but quantum number (n) Z 2
not 1s2 2s2 2p6 3s2 3p6 3d9 4s2 (c) Frequency of revolution of electron in an orbit
(4) Electronic configuration of an Z2
element is represented by the notation 3
n
(nlx)
x : number of electrons present in an orbital, (d) Coulombic force of attraction on the electron
l : denotes the sub-shell
Z2
n : principal quantum number.
n2
6. The ionisation energy of He is 19.6 1018 J
atom1 . The energy of the first stationary state of
Li 2 will be
(a) 21.2 1018 J/atom (b) 44.10 1018 J/atom
1. When beryllium is bombarded with particles
(Chadwick’s experiment) extremely penetrating (c) 63.2 1018 J/atom (d) 84.2 1018 J/atom
radiations which cannot be deflected by electric 7. The energy of electron in first Bohr’s orbit of H-
or magnetic field are given out. These are atom is -13.6 eV. What will be its potential energy
(a) A beam of protons in 4th orbit ?
(b) Alpha rays (a) -13.6 eV (b) -3.4 eV
(c) A beam of neutrons (c) -0.85 eV (d) -1.70 eV
(d) A beam of neutrons and protons
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Chemistry Times July 18
8. The frequency of line spectrum of sodium is 15. The photoelectric effect supports quantum nature
14 1
5.09 10 sec . Its wavelength (in nm) will be of light because
(a) there is a minimum frequency of light below
c 3 108 m / sec which no photoelectrons are emitted
(a) 510 nm (b) 420nm (c) 589 nm (d) 622 nm (b) the maximum kinetic energy of photoelectrons
9. The correct expression derived for the energy of an depends only on the frequency of light and not on
electron in the nth energy level is for H-atom its intensity
(c) even when metal surface is faintly illuminated
2 2 me 4 2 2 me 4 thephotoelectrons leave the surface immediately
(a) En (b) En
n2 h2 nh 2 (d) electric charge of photoelectrons is quantised
16. Which transition of the hydrogen spectrum would
2 2 me 2 2 2 me 4 have the same wavelength as the Balmer transition,
(c) En 2 2 (d) En 2 2
nh nh n=4 to n=2 of He spectrum?
10. For H-atom, the energy required for the removal of
(a) n2 2 to n1 1 (b) n2 3 to n1 1
electron from various sub-shells is given as under.
(c) n2 4 to n1 2 (d) n1 2 to n1 3
17. The shortest wavelength in H spectrum of Lyman
series when RH 109678cm 1 is
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Chemistry Times July 18
1 (c) 2(2l 1)
l 0
(d) 2(2l 1)
l 0
(d) n 3, l 2, m 2, s
2 28. Which is the correct order of increasing energy of
the listed orbitals in the atom of titanium?
(At. no. Z = 22)
(a) 4s 3s 3p 3d (b) 3s 3p 3d 4s
23. The above (c) 3s 3p 4s 3d (d) 3s 4s 3p 3d
29. Which of the following is responsible to rule out
configuration is not correct as it violates the existence of definite paths or trajectories of
(a) Only Hund’s rule electrons?
(b) Only Pauli’s exclusion principle (a) Pauli’s exclusion principle.
(c) (n + l)rule (b) Heisenberg’s uncertainty principle.
(d) (Hund + Pauli) rule (c) Hund’s rule of maximum multiplicity.
24. The orbital diagram in which ‘Aufbau principle’ is (d) Aufbau principle.
violated is 30. The energy of an electron moving in nth Bohr’ss
13.6 2
(a) orbit of an element is given by En Z eV/
n2
(d)
25. An electron of velocity ‘v’ is found to have a certain
value of de Broglie wavelength. The velocity (a) (b)
possessed by neutron to have the same de Broglie
wavelength is
v
(a) 1840 v (b)
1840
1840
(c) 3 v (d)
v
26. An electron, a proton and an alpha particle have (c) (d)
kinetic energies of 16E, 4E and E respectively. What
is the qualitative order of their de broglie
wavelengths?
(a) e p (b) p e (a) 1 106 cm s 1 (b) 1 105 cm s 1
(c) p e (d) e p (c) 1 1011 cm s 1 (d) 1.1 109 cm s 1
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Chemistry Times July 18
c 3 108 ms 1
8.Sol:
v 5.09 1014 s 1
1. c 2. c 3. a 4. c 5. c 0.589 106 m 589nm
6. b 7. c 8. c 9. d 10. c 9.Sol: Conceptual
11. c 12. a 13. b 14. b 15. a 10.Sol: In case of H atom, energy of 3s, 3p, 3d is as
16. a 17. b 18. a 19. d 20. d follows 3s=3p=3d
21. d 22. c 23. d 24. b 25. b 11.Sol: Increasing order of wavelength of EMR: X -
26. a 27. d 28. c 29. b 30. a rays < UV < Visible < IR < Radiowaves
Wavelength is inversely proportional to wave
number
Decreasing order of wave number of EMR: X - rays
> UV > Visible > IR > Radiowaves
1.Sol: Neutron carrying no electrical charge
hc
2.Sol: Charge on oil drop 6.39 1019 C 12.Sol: Energy of a photon hv
Now we know that
1.602 1019 C is the charge on one electron (6.63 1034 J .s )(3 108 m / s )
(4000 10 10 m)
6.39 1019 C will be charge on
4.97 1019 J .
6.39 1019
Number of photons required
1.602 1019
1J
4 electrons 2.01 1018
3.Sol: They travel in straight lines towards anode as 4.97 10 19 J
they carry negative charge. E1 v1 x
4.Sol: particles which impinged on a metal foil 13.Sol: E v E v y
2 2
and got scattered.
Z n2 hc
5.Sol: v ;r 14.Sol: Energy absorbed
n Z
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Chemistry Times July 18
1 1 h
RH [2]2 2 2 18.Sol:
2 4 mv
3 h
RH ...(A) 19.Sol: x p
4 4
Now for H atom
2 h h
1 1 1
p p
4 4
RH 2 2 ...(B)
n1 n2
h 1 h
Equating (A) and (B) we have mv v
4 2m
1 1 3
2 h h
x
2
n1 n2 4 20.Sol: x.P
4 p
Obviously n1 1 and n1 2. Hence the transition
h h P v 1
n 2 to n 1 in hydrogen atom, will have the P
p
4 P v 4
same wavelength as the transition n 4 to n 2
in He species. v 1
% Uncertainty 100 8%
17.Sol: For Lyman series n1 1 v 4
21.Sol: dz2 contains only two lobes
For shortest ' ' of Lyman series is the energy
25.Sol: Since the mass of the neutron is 1840 times the
difference in two levels showing transition should
mass of an electron.
be maximum (i.e., n2 ).
h
1 1 1 26.Sol:
RH 2 2 2m( K .E.)
1
28.Sol: Ti (22) :1s 2 2 s 2 2 p 6 3s 2 3 p 6 3d 2 4 s 2
109678
Order of increasing energy is 3s,3 p, 4 s,3d .
911.7 108
29.Sol: According to Heisenberg’s uncertainty
0
911.7 A principle.
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Chemistry Times July 18
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Chemistry Times July 18
(a) NH 2 (b) N 3 H 9V V
160 239 V 316
(c) NH 3 (d) N 2 H 4 20 5
3.Sol: Since the compound undergoing combustion
12. The amount of BaSO4 formed upon mixing 100
is an alkane, hence the combustion reaction can
mL of 20.8% BaCl2 solution with 50 mL of 9.8% be written as
H 2 SO4 solution with 50 mL of 9.8% 3n 1
Cn H 2 n 2 O2
nCO2 (n 1) H 2 O
H 2 SO4 solution will be: [2014] 5L 2
25 L
(a) 23.3 g (b) 1.65 g (c) 30.6 g (d) 33.2 g Since volumes are measured at constant T&P,
13. The density of 3M solution of sodium chloride is hence According to Avogadro’s law
1.252 g mL1 . The molarity of the solution will be: C3 H 8 5O2 3CO2 4 H 2 O
1
(molar mass, NaCl 585 g mol ) [2013] Conc . HCl
4.Sol: 2 H 3 AsO4 5 H 2 S As2 S5 8H 2O
(a) 260 m (b) 2.18 m (c) 2.79 m (d) 3.00 m 2 moles
1 mole
1 mole
1/2 mole
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Chemistry Times July 18
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Chemistry Times July 18
PAPER-2
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Chemistry Times July 18
(a) (b)
(a) (b)
(c) (d)
(c) (d)
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Chemistry Times July 18
-.30, 30.27, -127.30) using the mouse and the undergo self-reduction. The weight (in kg) of Pb
onscreen virtual numeric keypad in the place produced per kg of O consumed is ______ .
2
designated to enter the answer.
Answer to each question will be evaluated (Atomic weights in g mol 1 : O 16, S 32, Pb 207 )
according to the following marking scheme. 9. To measure the quantity of MnCl2 dissolved in
Full Marks: + 3 If ONLY the correct numerical an aqueous solution, it was completely converted
value is entered as answer.
Zero Marks: 0 In all other cases. to KMnO4 using the reaction,
MnCl2 K2S2O8 H2O KMnO4 H2 SO4 HCl
7. The total number of compounds having atleast one
(equation not balanced).
bridging oxo group among the molecules given
Few drops of concentrated HCl were added to this
below is ______ .
solution and gently warmed. Further, oxalic acid
N 2 O3 , N 2 O5 , P4 O6 , P4 O7 , H 4 P2 O5 , H 4 P3O10 , (225 mg) was added in portions till the colour of
H 2 S 2 O3 , H 2 S 2 O5 the permanganate ion disappered. The quantity of
8. Galena (an ore) is partially oxidized by passing MnCl2 (in mg) present in the initial solution is
air through it at high temperature. After some time, ______ . (Atomic weights in
the passage of air is stopped, but the heating is g mol 1 : Mn 55, Cl 35.5 )
continued in a closed furnace such that the contents
10. For the given compound X, the total number of optically active stereoisomers is ______ .
11. In the following reaction sequence, the amount of D (in g) formed from 10 moles of acetophenone is
______ . (Atomic weights in g mol 1 : H = 1, C = 12, N = 14, O = 16, Br = 80. The yield (%) corresponding
to the product in each step is given in the parenthesis)
12. The surface of copper gets tarnished by the formation of copper oxide. N 2 gas was passed to prevent the
oxide formation during heating of copper at 1250 K. However, the N 2 gas contains 1 mole % of water
vapour as impurity. The water vapour oxidises copper as per the reaction given below.
2Cu ( s ) H 2 O ( g )
Cu2 O ( s ) H 2 ( g )
PH 2 is the minimum partial pressure of H 2 (in bar) needed to prevent the oxidation at 1250 K. The value
of ln ( pH 2 ) is ______ .
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Chemistry Times July 18
(Given: total pressure = 1 bar, R (universal gas corresponding to the correct matching is chosen
1 1
constant) 8 JK mol , ln(10) 2.3 . Zero Marks: 0 If none of the options is chosen
(i.e. the question is unanswered).
Cu(s) and Cu2 O ( s ) are mutually immiscible. Negative Marks: - 1 In all other cases.
15. Match each set of hybrid orbitals from List-I with
At 1250K: 2Cu ( s ) 1/ 2 O2 ( g )
Cu2 O ( s );
complex (es) given in List-II.
G 78, 000 J mol 1 List - I List - II
H 2 ( g ) 1/ 2 O2 ( g )
H 2 O ( g ); P. dsp 2 1. [ FeF6 ]4
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Chemistry Times July 18
Match each reaction in List-I with one or more products in List-II and choose the correct option.
(a) P 1,5; Q 2; R 3; S 4 (b) P 1, 4; Q 2; R 4; S 3
(c) P 1, 4; Q 1, 2; R 3, 4; S 4 (d) P 4,5; Q 4; R 4; S 3, 4
18. Dilution processes of different aqueous, with water, are given in List-I. The effects of dilution of the
solutions on [ H ] are given in List-II. (Note: Degree of dissociation ( ) of weak acid and weak base is <
< 1; degree of hydrolysis of salt < < 1; [ H ] represents the concentration of H ions)
List - I List - II
P. (10 mL of 0.1M NaOH + 20 mL of 1. The value of [ H ] does not change
0.1 M acetic acid) diluted to 60 mL on dilution
Q. (20 mL of 0.1 M NaOH + 20 mL of 2. The value of [ H ] changes to half of its initial
0.1 M acetic acid) diluted to 80 mL value on dilution
R. (20 mL of 0.1 M HCl + 20 mL of 3. The value of [ H ] charges to two times of its initial
0.1 M ammonia solution) diluted to value on dilution
80 mL
S. 10 mL saturated solution of 4. The value of [ H ] charges to 1/ 2 times of its initial
Ni (OH ) 2 in equilibrium with excess value on dilution
solid Ni (OH ) 2 is diluted to 20 mL
(solid Ni (OH ) 2 is still present after
dilution). 5. The value of [ H ] changes to 2 times of its
initial value on dilution
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Chemistry Times July 18
Match each process given in List - I with one or more effect(s) in List-II. The correct option is
(a) P 4; Q 2; R 3; S 1 (b) P 4; Q 3; R 2; S 3
(c) P 1; Q 4; R 5; S 3 (d) P 1; Q 5; R 4; S 1
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Chemistry Times July 18
hc
0
1
0
[Co (en) ( NH 3 )3 ( H 2 O )]3 absorbs light at longer wavelength as compared to [Co (en) ( NH 3 ) 4 ]3
2.Sol: Both Cu+2 and Mn+2 gives green colour in the flame test.
K sp (CuS ) K sp ( MnS )
4.Sol:
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Chemistry Times July 18
5.Sol: A( g ) 2 B( g ) C( g ) 6.Sol: From the graph (1) and (2), we get H ve
i.e. exothermic.
1 2 P0
k ln e ln K1 T2
t 3P0 Pt Given : ln K T
2 1
kt ln (2 P0 ) ln (3 P0 Pt )
ln (3P0 Pt ) ln(2 P0 ) kt S H 1
R R T1 T2
S H 1 T1
R R T2
S
(T2 T1 ) 0
R
At t t1/3 S 0
7.Sol:
ln 3
t1/3
k
N 2 O3 :
t1/3 is independent of [ A]0
N 2 O5 :
P4 O6 :
For 1st order reaction, rate constant is independent
of initial concentration of reaction.
P7 O7 :
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Chemistry Times July 18
207
w pb 6.47 kg
32
H 4 P2 O5 :
9.Sol:
H 2 P3O10 :
H 2 S2 O3 :
w 225
8.Sol: PbS O2 Pb SO2 5 2
126 90
nO2 nPb [Equal moles]
2 225 126
w 126 mg
wo2 wpb wo2 wpb 90 5
10.Sol: Total number of stereomers of compound - X
M O2 M pb 32 207
=8
Let, wo2 1 kg X has 7 optically active stereisomers
X has 1 optically inactive
11.Sol:
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Chemistry Times July 18
2Cu( s ) H 2 O( g )
Cu2 O( s ) H 2( g )
1
At 1250 K 2Cu( S ) O2( g ) Cu2 O( s ) G 78000 J/mol 78 kJ/mol
2
1
H 2 O( g ) H 2( g ) O2( g ) G 17800 J/mol= 178 kJ/mol
2
2Cu( s ) H2O( g )
Cu2O( s ) H2 ( g ) ; G 100 kJ/mol
G G RT ln K G RT ln 4e2
( pH 2 ) 2500 ln 4e 2
0 100 RT ln
( pH 2 O ) 2500 (ln 4 ln e 2 )
8 pH 2 2500 (2 ln 2 2)
100 1250 ln
1000 pH 2 O 2500 (2(0.7) 2)
Given : pH 2 O 1% of total pressure (1 bar) 2500 3.4
1 8500
1 Absolute value of G 8500.00
100
2 n
n
8 pH 14.Sol: A( s ) A( aq, 2 M ) B( aq ,1M ) B( s )
100 1250 ln 22
1000 10 Oxidation
10 ln pH 2 ln102 A An ne ....(1)
10 ln pH 2 2 ln10 Reduction
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Chemistry Times July 18
RT ln 4 Ti 3 3d 1
2 R ln 2
T
8.3 0.7 2
11.62 J K -1 mol 1 Weak ligands H 2 O, Cl
2
15.Sol: P : dsp - (6) d 2 sp 3 - octahedral
[ Ni (CN ) 4 ]2 (3) [Cr ( NH 3 )3 ]36
Ni 4 S 2 3d 8 Cr : 4 s1 3d 5 ; Cr 3 4 s 0 3d 3
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Chemistry Times July 18
(S)
(Q)
(R) (S)
R - (4)
18.Sol:
P: [ H1 ] C2 0.025
CH 3COOH NaOH
CH 3COONa H 2 O [ H 2 ] C1 0.05
20 ml of 0.1 M 10 ml of 0.1 M
[ H 2 ] 0.05
The value of H does not change on dilution for 2
[ H1 ] 0.025
buffer solution P - (1)
Q: [ H 2 ] 2 H1
NaOH CH 3COOH
CH 3COONa H 2 O R :
20 ml of 0.1M 20 ml of 0.1M
C1 0.05M NH 4 OH HCl NH 4 Cl H 2 O
20 ml of 0.1M 20 ml of 0.1M
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Chemistry Times July 18
SOLUTIONS
1. If molality of the dilute solutions is doubled the (a) 0.177 (b) 0.0354
value of molal depression constant (K f ) will be:- (c) 0.0177 (d) 1.770
[2017] 6. The boiling point of 0.2mol kg 1 solution of X in
(a) Halved (b) Tripled water is greater than equimolal solution of Y in
(c) Unchanged (d) Doubled water. Which one of the following statements is
2. Which of the following is dependent on true in the case?
temperature ? [2017] [2015]
(a) Molarity (b) Mole fraction (a) X is undergoing dissociation in water.
(c) Weight percentage (d) Molality (b) Molecular mass of X is greater than the molecu-
3. Which of the following statements about the lar mass of Y.
composition of the vapour over an ideal 1:1 molar (c) Molecular mass of X is less than the molecular
mixture of benzene and toluene is correct? Assume mass of Y.
that the temperature is constant at 250 C . (Given, (d) Y is undergoing dissociation in water while X
undergoes no change
vapour pressure data at 250 C , benzene = 12.8 kPa, 7. Which one of the following electrolyte has the same
toluene = 3.85 kPa)
value of van’t Hoff factor (i) as that of Al2 ( SO4 )3
[2016]
(a) The vapour will contain a higher percentage of (if all are 100% ionised)?
toluene. [2015]
(b) The vapour will contain equal amounts of (a) K 2 SO4 (b) K3 [ Fe(CN )6 ]
benzene and toluene.
(c) Al ( NO3 )3 (d) K 4 [ Fe(CN )6 ]
(c) The vapour will contain a higher percentage of
benzene. 8. Of the following 0.10 m aqueous solutions, which
(d) Not enough information is given to make a one will exhibit the largest freezing point
prediction. depression?
[2014]
4. At 1000 C the vapour pressure of a solution of 6.5
(a) C6 H12 O6 (b) KCl
g of a solute in 100 g water is 732 mm. If
Kb 0.52 , the boiling point of this solution will (c) K 2 SO4 (d) Al2 ( SO4 )3
be: [2016] 20
9. 6.02 10 molecules of urea are present in 100
(a) 103 C (b) 102 C (c) 100 C (d) 1010 C
0 0 0 mL of its solution. The concentration of solution
5. What is the mole fraction of the solute in a 1.00 m is: [2013]
aqueous solution? [2015] (a) 0.01 M (b) 0.02 M (c) 0.1 M (d) 0.001 M
59
Chemistry Times July 18
10. Which of the following compounds can be used as (a) 0.56 K (b) -1.12 K (c) 1.12 K (d) -0.56 K
antifreeze in automobile radiators? [2012] 17. 1.0 g of a non-electrolyte solute (molar mass 250
(a) Methyl alcohol (b) Nitrophenol g mol 1 ) was dissolved in 51.2 g of benzene. If the
(c) Ethylene glycol (d) Ethyl alcohol
freezing point depression constant of benzene is
11. p A and pB are the vapour pressure of pure liquid 1
5.12 K kg mol , the lowering in freezing point
components, A and B, respectively of an ideal will be [2006]
binary solution. If X A represents the mole fraction (a) 0.2 K (b) 0.3 K (c) 0.5 K (d) 0.4 K
of component A, the total pressure of the solution 18. A solution containing 10 g per dm3 of urea (molar
will be [2012] mass = 60) is isotonic with a 5 g per 100cm3 of
(a) pB xA ( pB p A ) (b) pB xA ( p A pB ) non-volatile solute. The molecular mass of non
volatile solute is [2006]
(c) p A x A ( pB pA ) (d) p A x A ( p A pB )
(a) 250 (b) 200 (c) 350 (d) 300
12. The freezing point depression constant for water 19. During osmosis, flow of water through a semi
is 1.860 C m 1 . If 5.00 g Na2 SO4 is dissolved in permeable membrane, [2006]
(a) from solution having higher concentration only
45.0 g H 2O, the freezing point is changed by
(b) from both sides of semipermeable membrane
3.820 C , Calculate the van’t Hoff factor for with equal flow rates
(c) from the sides of semipermeable membrane with
Na2 SO4 . [2011]
unequal flow rates.
(a) 2.05 (b) 3.11 (c) 0.381 (d) 2.63 (d) from solution having lower concentration only
13. The van’t Hoff factor i for a compound which 20. The vapour pressure of two liquids P and Q are 80
undergoes dissociation in one solvent and torr and 60 torr respectively. The total vapour
association in other solvent is respectively pressure obtained by mixing 3 mole of P and 2 of
[2011] Q would be [2005]
(a) less than one and less than one (a) 140 torr (b) 72 torr (c) 68 torr (d) 20 torr
(b) greater than one and less than one 21. A solution of urea (molar mass 60) boils at
(c) greater than one and greater than one
(d) less than one and greater than one 100.180 C at atmospheric pressure. If K f and K b
14. A solution of sucrose (molar mass 342 g mol 1 ) for water are 1.86 and 0.512 K molality 1
has been produced by dissolving 68.5 g sucrose in respectively, the above solution will freeze at
1000 g water. The freezing point of the solution [2005]
obtained will be ( K f for H 2 O 1.86 kg / mol ) (a) 0.6540 C (b) 0.6540 C
[2010] (c) 6.540 C (d) 6.540 C
(a) 0.3720 C (b) 0.5700 C 22. A solution has a 1:4 mole ratio of pentane to hexane.
The vapour pressures of pure hydrocarbons at
(c) 0.3720 C (d) 0.5200 C
15. A 0.0020 m aqueous solution in an ionic compound 200 C are 440 mmHg for pentane and 120 mmHg
for hexane. The mole fraction of pentane in vapour
Co( NH 3 )5 ( NO2 )Cl freezes at 0.007320 C .
phase would be [2005]
Number of moles of ions which 1 mol of ionic (a) 0.549 (b) 0.200 (c) 0.786 (d) 0.478
compound produces on being dissolved in water
will be
( K f 1.860 C / m) [2009]
(a) 3 (b) 2 (c) 1 (d) 4
16. A 0.5 molal aqueous solution of a weak acid (HX) 1. c 2. a 3. c 4. d 5. c
is 20 percent ionised. The lowering in freezing point 6. a 7. d 8. d 9. a 10. c
11. b 12. d 13. b 14. c 15. b
of this solution is (K f 1.86 K / m for water) 16. c 17. d 18. d 19. c 20. b
[2007] 21. a 22. d
60
Chemistry Times July 18
T 0 (3.82) 3.82 K
4.Sol: At. B.P., P0 760 torr for elevation of B.P 1000 1.86 5 i i 2.63
3.82
142 45
P 0 Ps WB / M B 760 732 6.5 / M
14.Sol: T f molality K f
Ps WA / M A 732 100 /18
On solving M = 30.6 68.5 1000
1.86 0.372
342 1000
6.5
Tb 1K b m 1 0.52
30.6
1000 1.1
T f 0 0.372 0.3720 C
100
15.Sol: T f i K f ' molality
Tb TbS Tbo so TbS Tb TbO
0.00732 i 1.86 0.002
TbS 1.1 100C 101.10 C
i 1.96 2
5.Sol: 1.00 m solution means 1 mole solute is present
in 1000 g of water. [Co( NH 3 )5 ( NO2 )]Cl [Co( NH 3 )5 NO2 ] Cl
1000 16.Sol: T f iK f m
nwater 55.5 mol
18
i 1
nsolute 1 we know, ( dissociation)
X solute 0.0177 n 1
nsolute nwater 1 55.5
i 1
6.Sol: Tb ikb m i 1
2 1
For equilibrium solutions, elevation in boiling
point will be higher if solution undergoes so, T f ( 1) K f m
dissociation i.e., i 1 . Given 0.2, molality 0.5, K 'f 1.86
2 Al 3 3SO42 , i 5
7.Sol: Al2 ( SO4 )3
T f 0.5 1.2 1.86 1.116 K
Al 3 3 NO3 , i 4
Al ( NO3 )3 17.Sol:
4
K 4 [ Fe(CN ) 6 ]
4 K [ Fe(CN ) 6 ] , i 5 1000 K f w
1000 5.12 1
Tf 0.4 K
K 2 SO4
2 K SO , i 3 2 mw 250 51.2
4
18.Sol: For isotonic solutions of two non-electrolytes
3K [ Fe(CN ) 6 ]3 , i 4
K 3 [ Fe(CN ) 6 ]
C1 C2
6.02 1020
9.Sol: Number of moles of urea 0.001 10 5
6.02 1023 (1 dm3 103 cm3 )
60 1000 mw 100
Molarity of solution of urea
Number of moles of urea mw 300 g mol 1
1000
Volume in mL 20.Sol: PT PP PQ PPo X P PQO X Q
0.001 3 2
1000 0.01M
PT 80 60 48 24 72
100 5 5
10.Sol: Ethylene glycol is used as antifreeze
compound in automobile radiators. Tb Kb
21.Sol: T K
11.Sol: pM p ' A p ' B f f
p A x A pB xB ( p ' A p A x A ) Kf 1.86
T f Tb 0.18 0.654
pB x A ( p A pB ) Kb 0.512
100 K f w f.pt. 0 0.654 0.6540 C
12.Sol: T f i
mw
61
Chemistry Times July 18
INORGANIC STRUCTURES
Questions based on structures of inorganic species(molecules/ions) are most common in all competitive
exams. One can learn them systematically by knowing CHEMISTRICK
“E.C. Lewis covered
cov hybrid love
l apple plants,
p s, B plantss behind dat
Bo p date palm trees for double bon
bonanza”.
1. Electronic Configuration (E.C.): Write E.C. of Xe = 2, 4, 6, 8 (1st, 2nd , 3rd, 4th E.S.)
central atom of the species, if needed go for excited (G.S. = Ground state, E.S.= Excited state)
E.C.s. For example write 4. Hybridisation:
Hybrid If the sum of the powers of s, p, d is
1st excited E.C. for Be in BeCl2 (Be = 2s12px1) equal to no. of surrounded atoms/no. of B.P.s/ no.
or B in BCl3 (B= 2s12px12py1) of covalent bonds, then the species get regular
or C in CH4 (C= 2s12px12py12pz1) shapes.
or P in PCl5 (P= 3s13px13py13pz13d1)
2nd excited E.C.
for S in SF6 (S= 3s13px13py13pz13d13d1)
3rd excited E.C.
for I in IF7 (I= 3s13px13py13pz13d13d13d1)
4th excited E.C.
for Xe in XeO4 (Xe=5s15px15py15pz15d15d15d15d1)
2. Lewis dot Structure: Write Lewis dot structure for
central atom
3. Covalency: One can get an idea of covalency(no. Even hybridisation of different species
of covalent bonds formed by central atom) by is same, their geometry may not be same when L.P.s
observing E.C. and Lewis dot structures. Covalency are present.
of any group element upto IV group is equal to its eg: NH4+, CH4 (sp3, tetrahedral),
group number(G). For atoms of V group onwards NH3 & H3O+ (sp3, pyramidal, 1 L.P.),
(except 1st member of the group, as it does not H2O(sp3, Angular, 2L.P.s)
contain d orbitals, could not expand its octet) If you compare CH4, NH3, H2O, with
minimum covalency is 8-G and maximum covalency the increase of one lone pair, one covalent bond
is G. decreases i.e. shape from tetrahedral to pyramidal
Valency of P = 3, 5 (G.S., 1st E.S.) to angular. Same logic must be applied for unknown
S = 1, 4, 6 (G.S., 1st, 2nd E.S.) species also.
Cl = 1, 3, 5, 7 (G.S., 1st, 2nd , 3rd E.S.)
62
Chemistry Times July 18
6 s1 p3 d 2 , octahedral eg: N= 1L.P. + 3B.P. 1 2 31
PO43- SO2
3. ClF3 No. of H.O.S
1
7 3
2
5 s1 p3 d 1 , Bent ' T '
SO3 SO3-2
63
Chemistry Times July 18
64
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