15.

Neraca Energi Compressor (C-01)

Q 5 out (10 atm,

Q 5 in (2
190,2426946°C)
atm, 75°C) C-01

Fungsi : Untuk menaikkan tekanan produk samping sebelum menuju flash drum

Kondisi operasi : T in = 75°C (348,15 K)

T out = 190,2426946°C (463,3926946 K)

T reff = 25°C (298,15 K)

P in = 2 atm

P out = 10 atm

Energi Masuk Q5
Massa bahan :
laju alir BM laju alir
Komponen
masuk (kg/jam) (kg/kmol) masuk (kmol/jam)
Cl2 465,163 70,9 6,56
NOCl 429,472 65,46 6,56

Entalpi bahan masuk pada suhu 75°C (348,15 K)

B C D
Q Cl2 = n [(A(T − Tref)) + ( 2 ) (T 2 − Tref 2 ) + (3) (T 3 − Tref 3 ) + ( 4 ) (T 4 −
E
Tref 4 + (5) (T 5 − Tref 5 )]
0,030426
= 6,56 [(27,213 (348,15 − 298,15)) + ( ) (348,152 −
2
−0,000033353
298,152 ) + ( ) (348,153 − 298,153 ) +
3
1,5961 × 10−8 −2,7021 × 10−12
( ) (348,154 − 298,154 ) + ( ) (348,155 −
3 5

298,155 )]
 kj
= 11175,4948
jam
B C
Q NOCl = n [(A(T − Tref)) + (2 ) (T 2 − Tref 2 ) + (3) (T 3 − Tref 3 ) +
D E
( 4 ) (T 4 − Tref 4 + (5) (T 5 − Tref 5 )]
0,075899
= 6,56 [(28,551 (348,15 − 298,15)) + ( ) (348,152 −
2
−0,00009441
298,152 ) + ( ) (348,153 − 298,153 ) +
3
6,0476 × 10−8 −1,5054 × 10−11
( ) (348,154 − 298,154 ) + ( ) (348,155 −
3 5

298,155 )]
kj
= 14790,1191 jam

Q5 in total = 11175,4948 + 14790,1191

kj
= 25965,6138 jam

Energi Keluar Q5
Massa bahan :
laju alir BM laju alir
Komponen
keluar (kg/jam) (kg/kmol) keluar (kmol/jam)
Cl2 465,163 70,9 6,56
NOCl 429,472 65,46 6,56

Entalpi bahan keluar pada suhu 190,2426946°C (463,3926946 K)

B C D
Q Cl2 = n [(A(T − Tref)) + ( 2 ) (T 2 − Tref 2 ) + (3) (T 3 − Tref 3 ) + ( 4 ) (T 4 −
E
Tref 4 + (5) (T 5 − Tref 5 )]

= 6,56 [(27,213 (463,3926946 − 298,15)) +

0,030426
( ) (463,39269462 − 298,152 ) +
2
−0,000033353
( ) (463,39269463 − 298,153 ) +
3
 1,5961 × 10−8
( ) (463,39269464 − 298,154 ) +
3
−2,7021 × 10−12
( ) (463,39269465 − 298,155 )]
5
kj
= 37670,4453 jam

B C
Q NOCl = n [(A(T − Tref)) + (2 ) (T 2 − Tref 2 ) + (3) (T 3 − Tref 3 ) +
D E
( 4 ) (T 4 − Tref 4 + (5) (T 5 − Tref 5 )]

= 6,56 [(28,551 (463,3926946 − 298,15)) +

0,075899
( ) (463,39269462 − 298,152 ) +
2
−0,00009441
( ) (463,39269463 − 298,153 ) +
3
6,0476 × 10−8
( ) (463,39269464 − 298,154 ) +
3
−1,5054 × 10−11
( ) (463,39269465 − 298,155 )]
5
kj
= 50626,2772 jam

Q5 out total = 37670,4453 + 50626,2772

kj
= 88296,7225 jam

Panas yang dibutuhkan

Qs = Q output − Q input
= 88296,7225 − 25965,6138
kj
= 62331,1087
jam

Menentukan Daya Kompresor

Data yang diketahui

kj
R = 8,314 kmol.K
T in = 75°C + 273,15 = 348,15 K
2 atm
P in = 0,9869 = 2,0265 𝑏𝑎𝑟
10 atm
P out = = 10,1327 𝑏𝑎𝑟
0,9869

Critical Properties and Acentric Factor (Sumber:Yaws,1999)

Komponen BM wt (%) kg/jam kmol/jam

Cl₂ 70.9 0.5 465.163008 6.560832271
NOCl 65.46 0.5 429.4720804 6.560832271
Total 1 894.6350884 13.12166454

Data Cl₂ NOCl

Tf (K) 172.12 213.55
239.12 267.77
Tb (K)
417.15 440.65
Tc (K)
77.11 91.19
Pc (bar)
123,75 139,30
Vc (cm3/mol)
0,573 0,4699
ρ (gr/cm3)
0,275 0,347
Zc
0,069 0,307
Ω
Menghitung nilai n dengan metode pitzer hal 97

Menghitung Nilai Tr
Tin 348,15
Tr Cl2 = = 417,15 = 0,8346
T𝑐
Tin 348,15
Tr NOCl = = 440,65 = 0,79
T𝑐

Menghitung Nilai Pr
Pin 2,0265
Pr Cl2 = = = 0,0263
P𝑐 77,11
Pin 2,0265
Pr NOCl = = = 0,222
P𝑐 91,19

Menghitung Nilai w
W = -log(Pr) – 1
w Cl2 = − log(0,0263) − 1 = 0,58
w NOCl = − log(0,222) − 1 = 0,65

Menghitung Nilai B°
0,422 1,6
Bº = 0.083 – (( ) )
Tr
0,422
B° Cl2 = 0.083 − ((0,8346)1,6 )

= 0,0266
0,422
B° NOCl = 0.083 − (( 0,79 )1,6 )

= 0,0215

Menghitung Nilai B’
0,172 4,2
B΄ = 0.139 − (( ) )
Tr
0,172
B’ Cl2 = 0.139 − ((0,8346)4,2 )

= −0,229
 0,172 4,2
B’ NOCl = 0.139 − (( ) )
Tr
0,172
= 0.139 − (( 0,79 )4,2 )

= −0,324

Pr 0,0263
𝐶𝑙₂ = 0,8346 = 0,0315
T𝑟
Pr 0,0222
𝑁𝑂𝐶𝑙 = = 0,028
T𝑟 0,79

BPc
 B 0  wB ,
Rtc
BPc
𝐶𝑙₂ = B° + (w × B′ )
R𝑇𝑐

= 0,0266 + (0,58 × −0,229)

= −0,106
BPc
𝑁𝑂𝐶𝑙 = B° + (w × B′ )
R𝑇𝑐

= 0,0215 + (0,65 × −0,324)

= −0,19

z 1 BPc / RTc  x Pr / Tr 

BPc Pr
𝑧 = 1 + (R𝑇𝑐 × T𝑟)

z Cl₂ = 1 + (−0,106 × 0,0315)

= 0,9967
z NOCl = 1 + (−0,19 × 0,028)
= 0,9947
z total = 0,9967 + 0,9947
= 1,991
Cp T Reff = 𝐴 + 𝐵𝑇 + 𝐶𝑇 2 + 𝐷𝑇 3 + 𝐸𝑇 4
Cp Cl2 = 27,213 + (0,030426 × 298,15) + (−0,000033353 × 298,152 ) +
(1,5961 × 10−8 × 298,153 ) + (−2,7021 × 10−12 × 298,154 )
kJ
= 33,7213 kmol.K

Cp NOCl = 28,551 + (0,075899 × 298,15) + (−0,00009441 × 298,152 ) +

(6,0476 × 10−8 × 298,153 ) + (−1,5054 × 10−11 × 298,154 )
kJ
= 44,2717 kmol.K

Cp campuran = 33,7213 + 44,2717

kJ
= 77,993 kmol.K

z x n x R xT
V
P
0,9967×6,56×8,314×348,15
V Cl2 = 2,0265

= 9339,6 𝑐𝑚³
0,9947×6,56×8,314×348,15
V NOCl = 2,0265

= 9320,8 𝑐𝑚³
V total = 18660,327 c𝑚³
18660,327×1000
= 1.000.000×3600

dm³
= 0,00518342
s
 dm³
Dari fig 3.6 coulson hal 83 dengan volume 0,00518342 didapat efisiensi
s

kompresor sebesar :
ɳ = 60%

Menghitung nilai y, m dan n

Cp
y=
C𝑝−𝑅
77,993
y = 77,993−8,314

= 1,1193

y−1
m = y×ɳ
1,1193−1
m = 1,1193×60%

= 0,1777

1
n = 1−𝑚
1
n = 1−0,1777

= 1,216
n−1 1,216−1
=
n 1,216

= 0,1777
Menghitung jumlah stage
𝑃21/𝑛
𝑅𝑐 = P1
101/1,216
𝑅𝑐 = 2

= 3,7565

Menghitung BM Campuran Gas

M = 𝑤𝑡𝑖 × 𝐵𝑀𝑖
M Cl2 = 0,5 × 70,9
kg
= 35,45 kmol

M NOCl = 0,5 × 65,46

kg
= 32,73 kmol

M total = 35,45 + 32,73

kg
= 68,18 kmol

Menghitung Power Kompresor

 w
z x R xT1 n
M
x
n 1

x P2 / P1  1
n1/ n


1,991×8,314×348,15 1,216 10
-w = × 1,216−1 × (( 2 )0,1777 − 1)
68,18
kj
= 157,5086 kg

−w
Kerja aktual kompresor = efisiensi

157,5086
= 60%

kj
= 262,5144 kmol
Kebutuhan tenaga kompresor

kmol
Umpan masuk = 13,1217 jam

Tenaga Kompresor = 𝑢𝑚𝑝𝑎𝑛 𝑚𝑎𝑠𝑢𝑘 × 𝑘𝑒𝑟𝑗𝑎 𝑎𝑘𝑡𝑢𝑎𝑙 𝑘𝑜𝑚𝑝𝑟𝑒𝑠𝑜𝑟

= 13,1217 × 262,5144

kJ
= 3444,6254
jam

1000 × 1.314
= 3444,6254 ×
3600 × 1000

= 1,2573 𝐻𝑝

Neraca Energi Total Compressor (C-01)

Komponen Aliran Masuk (kJ/jam) Aliran keluar (kJ/jam)

Q in 25965,6138
Q out 88296,7225
Q Steam 62331,1087
Total 𝟖𝟖𝟐𝟗𝟔, 𝟕𝟐𝟐𝟓 𝟖𝟖𝟐𝟗𝟔, 𝟕𝟐𝟐𝟓

16. Neraca Energi Heater (HE-06)

Qs
Q 5 in
Q 5 out
(190.2426946°C) HE-06 (230°C)
Fungsi : Untuk menaikkan temperatur produk samping menuju flash drum

Kondisi operasi : T in = 190,2426946°C (463,3926946 K)

T out = 230°C (503,15 K)

T reff = 25°C (298,15 K)

Tekanan = 10 atm

Energi Masuk Q5
Massa bahan :
laju alir BM laju alir
Komponen
masuk (kg/jam) (kg/kmol) masuk (kmol/jam)
Cl2 465,163 70,9 6,56
NOCl 429,472 65,46 6,56

Entalpi bahan masuk pada suhu 190,2426946°C (463,3926946 K)

B C D
Q Cl2 = n [(A(T − Tref)) + ( 2 ) (T 2 − Tref 2 ) + (3) (T 3 − Tref 3 ) + ( 4 ) (T 4 −
E
Tref 4 + (5) (T 5 − Tref 5 )]

= 6,56 [(27,213 (463,3926946 − 298,15)) +

0,030426
( ) (463,39269462 − 298,152 ) +
2
−0,000033353
( ) (463,39269463 − 298,153 ) +
3
1,5961 × 10−8
( ) (463,39269464 − 298,154 ) +
4
−2,7021 × 10−12
( ) (463,39269465 − 298,155 )]
5
kj
= 37670,4453 jam
B C
Q NOCl = n [(A(T − Tref)) + (2 ) (T 2 − Tref 2 ) + (3) (T 3 − Tref 3 ) +
D E
( 4 ) (T 4 − Tref 4 + (5) (T 5 − Tref 5 )]
 = 6,56 [(28,551 (463,3926946 − 298,15)) +
0,075899
( ) (463,39269462 − 298,152 ) +
2
−0,00009441
( ) (463,39269463 − 298,153 ) +
3
6,0476 × 10−8
( ) (463,39269464 − 298,154 ) +
3
−1,5054 × 10−11
( ) (463,39269465 − 298,155 )]
5

kj
= 50626,2772
jam

Q5 in total = 37670,4453 + 50626,2772

kj
= 88296,7225 jam

Energi Keluar Q5
Massa bahan :
laju alir BM laju alir
Komponen
keluar (kg/jam) (kg/kmol) keluar (kmol/jam)
Cl2 465,163 70,9 6,56
NOCl 429,472 65,46 6,56

Entalpi bahan keluar pada suhu 230°C (503,15 K)

B C D
Q Cl2 = n [(A(T − Tref)) + ( 2 ) (T 2 − Tref 2 ) + (3) (T 3 − Tref 3 ) + ( 4 ) (T 4 −
E
Tref 4 + (5) (T 5 − Tref 5 )]
0,030426
= 6,56 [(27,213 (503,15 − 298,15)) + ( ) (503,152 −
2
−0,000033353
298,152 ) + ( ) (503,153 − 298,153 ) +
3
1,5961 × 10−8 −2,7021 × 10−12
( ) (503,154 − 298,154 ) + ( ) (503,155 −
3 5

298,155 )]
 kj
= 47003,2438
jam
B C
Q NOCl = n [(A(T − Tref)) + (2 ) (T 2 − Tref 2 ) + (3) (T 3 − Tref 3 ) +
D E
( 4 ) (T 4 − Tref 4 + (5) (T 5 − Tref 5 )]
0,075899
= 6,56 [(28,551 (503,15 − 298,15)) + ( ) (503,152 −
2
−0,00009441
298,152 ) + ( ) (503,153 − 298,153 ) +
3
6,0476 × 10−8 −1,5054 × 10−11
( ) (503,154 − 298,154 ) + ( ) (503,155 −
3 5

298,155 )]
kj
= 63455,0333
jam

Q5 out total = 47003,2438 + 63455,0333

kj
= 110458,277
jam

Kebutuhan Steam

Q steam = Q output − Q input

= 110458,277 − 88296,7225
kj
= 22161,555
jam
Q steam
Massa steam = λs

kj
22161,555 jam
=
kj
674,69
kg
kg
= 32,847
jam
Neraca Energi Total Heater (HE-06)

Komponen Aliran Masuk (kJ/jam) Aliran keluar (kJ/jam)

Q in 88296,7225
Q out 110458,277
Q Steam 22161,555
Total 𝟏𝟏𝟎𝟒𝟓𝟖, 𝟐𝟕𝟕 𝟏𝟏𝟎𝟒𝟓𝟖, 𝟐𝟕𝟕

17. Flash Drum (FD-01)

Q5 T

Q5
FD-01

Q5 B

Fungsi : Untuk memisahkan senyawa Cl2 dan NOCl dari campuran

Kondisi operasi : T in = 230°C (503,15 K)

T out = 230°C (503,15 K)

T reff = 25°C (298,15 K)

Tekanan = 10 atm
Energi Masuk Q5
Massa bahan :
laju alir BM laju alir
Komponen
masuk (kg/jam) (kg/kmol) masuk (kmol/jam)
Cl2 465,163 70.9 6,56
NOCl 429,472 65,46 6,56

Entalpi bahan masuk pada suhu 230oC (503,15 K)

B C D
Q Cl2 = n [(A(T − Tref)) + ( 2 ) (T 2 − Tref 2 ) + (3) (T 3 − Tref 3 ) + ( 4 ) (T 4 −
E
Tref 4 + (5) (T 5 − Tref 5 )]
0,030426
= 6,56 [(27,213 (503,15 − 298,15)) + ( ) (503,152 −
2
−0,000033353
298,152 ) + ( ) (503,153 − 298,153 ) +
3
1,5961 × 10−8 −2,7021 × 10−12
( ) (503,154 − 298,154 ) + ( ) (503,155 −
3 5

298,155 )]
kj
= 47003.244
jam
B C
Q NOCl = n [(A(T − Tref)) + (2 ) (T 2 − Tref 2 ) + (3) (T 3 − Tref 3 ) +
D E
( 4 ) (T 4 − Tref 4 + (5) (T 5 − Tref 5 )]
0,075899
= 6,56 [(28,551 (503,15 − 298,15)) + ( ) (503,152 −
2
−0,00009441
298,152 ) + ( 3
) (503,153 − 298,153 ) +
6,0476 × 10−8 −1,5054 × 10−11
( ) (503,154 − 298,154 ) + ( ) (503,155 −
3 5

298,155 )]
kj
= 63455,033
jam

Q5 in total = 47003.244 + 63455,033

 kj
= 110458,277
jam
Energi Keluar Q5 T
Massa bahan :
laju alir BM laju alir
Komponen
keluar (kg/jam) (kg/kmol) keluar (kmol/jam)
Cl2 465,163 70.9 6,56

Entalpi bahan keluar pada suhu 230oC (503,15 K)

B C D
Q Cl2 = n [(A(T − Tref)) + ( 2 ) (T 2 − Tref 2 ) + (3) (T 3 − Tref 3 ) + ( 4 ) (T 4 −
E
Tref 4 + (5) (T 5 − Tref 5 )]
0,030426
= 6,56 [(27,213 (503,15 − 298,15)) + ( ) (503,152 −
2
−0,000033353
298,152 ) + ( ) (503,153 − 298,153 ) +
3
1,5961 × 10−8 −2,7021 × 10−12
( ) (503,154 − 298,154 ) + ( ) (503,155 −
3 5

298,155 )]
kj
= 47003.244
jam

Energi Keluar Q5 B
Massa bahan :
laju alir BM laju alir
Komponen
keluar (kg/jam) (kg/kmol) keluar (kmol/jam)
NOCl 429,472 65,46 6,56

Entalpi bahan keluar pada suhu 230oC (503,15 K)

B C
Q NOCl = n [(A(T − Tref)) + (2 ) (T 2 − Tref 2 ) + (3) (T 3 − Tref 3 ) +
D E
( 4 ) (T 4 − Tref 4 + (5) (T 5 − Tref 5 )]
 0,075899
= 6,56 [(28,551 (503,15 − 298,15)) + ( ) (503,152 −
2
−0,00009441
298,152 ) + ( ) (503,153 − 298,153 ) +
3
6,0476 × 10−8 −1,5054 × 10−11
( ) (503,154 − 298,154 ) + ( ) (503,155 −
3 5

298,155 )]
kj
= 63455,033
jam

Neraca Energi Total Flash Drum-01

Aliran Masuk (kJ/jam) Aliran Keluar (kJ/jam)

Komponen
Q5 Q5 T Q5 B
Q in 110458,277
Q out 47003.244 63455,033
Total 𝟏𝟏𝟎𝟒𝟓𝟖, 𝟐𝟕𝟕 𝟏𝟏𝟎𝟒𝟓𝟖, 𝟐𝟕𝟕

18. Neraca Energi Cooler-02

Q out pendingin

CO-02
Q5 B in Q5 B out

Q in pendingin

Fungsi : Untuk menurunkan temperatur NOCl

Kondisi operasi : T in = 230°C (503,15 K)

T out = 30°C (303,15 K)

T reff = 25°C (298,15 K)

Tekanan = 1 atm

Energi Masuk Q5 B
Massa bahan :
laju alir BM laju alir
Komponen
masuk (kg/jam) (kg/kmol) masuk (kmol/jam)
NOCl 429,472 65,46 6,56

Entalpi bahan masuk pada suhu 230oC (503,15 K)

B C
Q NOCl = n [(A(T − Tref)) + (2 ) (T 2 − Tref 2 ) + (3) (T 3 − Tref 3 ) +
D E
( ) (T 4 − Tref 4 + ( ) (T 5 − Tref 5 )]
4 5
0,075899
= 6,56 [(28,551 (503,15 − 298,15)) + ( ) (503,152 −
2
−0,00009441
298,152 ) + ( ) (503,153 − 298,153 ) +
3
6,0476 × 10−8 −1,5054 × 10−11
( ) (503,154 − 298,154 ) + ( ) (503,155 −
3 5

298,155 )]
kj
= 63455,033
jam

Energi Keluar Q5 B
Massa bahan :
laju alir BM laju alir
Komponen
keluar (kg/jam) (kg/kmol) keluar (kmol/jam)
NOCl 429,472 65,46 6,56
Entalpi bahan keluar pada suhu 30oC (303,15 K)
B C
Q NOCl = n [(A(T − Tref)) + (2 ) (T 2 − Tref 2 ) + (3) (T 3 − Tref 3 ) +
D E
( 4 ) (T 4 − Tref 4 + (5) (T 5 − Tref 5 )]
0,075899
= 6,56 [(28,551 (303,15 − 298,15)) + ( ) (303,152 −
2
−0,00009441
298,152 ) + ( ) (303,153 − 298,153 ) +
3
6,0476 × 10−8 −1,5054 × 10−11
( ) (303,154 − 298,154 ) + ( ) (303,155 −
3 5

298,155 )]
kj
= 1455,083
jam

Pendingin yang dibutuhkan

Panas yang di serap (Qs) = panas in – panas out

kj kj
= 63455,033 − 1455,083
jam jam

kj
Qs = 61999,95 jam

Entalpi pendingin masuk pada suhu 5oC (278,15 K)

B C
Cp.dT H2O = [(A(T − Tref)) + ( 2 ) (T 2 − Tref 2 ) + (3) (T 3 − Tref 3 ) +
D
( 4 ) (T 4 − Tref 4 ]
−0,039953
= [(92,053 (278,15 − 298,15)) + ( ) (278,152 −
2
−0,00021103
298,152 ) + ( ) (278,153 − 298,153 ) +
3
5,3469 × 10−7
( ) (278,154 − 298,154 )]
3

kj
= −1516,3916 kmol
Entalpi pendingin keluar pada suhu 30oC (303.15 K)

B C
Cp.dT H2O = [(A(T − Tref)) + ( 2 ) (T 2 − Tref 2 ) + (3) (T 3 − Tref 3 ) +
D
( 4 ) (T 4 − Tref 4 ]
−0,039953
= [(92,053 (303.15 − 298,15)) + ( ) (303.152 −
2
−0,00021103
298,152 ) + ( ) (303.153 − 298,153 ) +
3
5,3469 × 10−7
( ) (303.154 − 298,154 )]
3

kj
= 377,4864 kmol

Delta H = H out – H in

kj kj
= 377,4864 − (−1516,3916)
kmol kmol
kj
= 1893,878
kmol
Qs
Massa air pendingin = delta H

kj
61999,95
jam
=( kj )
1893,878
kmol

kmol
= 32,737
jam
kmol kg
= 32,737 × 18
jam kmol
kg
= 589,27
jam
Q in H2O = n × Cp dT
kmol kj
= 32,737 × (−1516,3916)
jam kmol
kJ
= −49642,1651
jam
Q out H2O = n × Cp dT
kmol kj
= 32,737 × 377,4864
jam kmol
kJ
= 12357,785
jam

Neraca Energi Total Cooler-02

Komponen Aliran Masuk (kJ/jam) Aliran Keluar (kJ/jam)

Qin 63455,033
Q out 1455,083
Q pendingin 61999,95
Total 63455,033 63455,033

19. Neraca Energi Expansion Valve (EX-01)

Q5 T in EX-01 Q5 T iout
(10 atm) (1 atm)

Fungsi : Untuk menurunkan tekanan Cl2 sebelum masuk ke tangki penyimpanan

Kondisi operasi : T in = 230°C (503,15 K)

T reff = 25°C (298,15 K)

P in = 10 atm

P out = 1 atm
Energi Masuk Q5 T
Massa bahan :
laju alir BM laju alir
Komponen
masuk (kg/jam) (kg/kmol) masuk (kmol/jam)
Cl2 465,163 70.9 6,56

Entalpi bahan masuk pada suhu 230oC (503,15 K)

B C D
Q Cl2 = n [(A(T − Tref)) + ( 2 ) (T 2 − Tref 2 ) + (3) (T 3 − Tref 3 ) + ( 4 ) (T 4 −
E
Tref 4 + (5) (T 5 − Tref 5 )]
0,030426
= 6,56 [(27,213 (503,15 − 298,15)) + ( ) (503,152 −
2
−0,000033353
298,152 ) + ( ) (503,153 − 298,153 ) +
3
1,5961 × 10−8 −2,7021 × 10−12
( ) (503,154 − 298,154 ) + ( ) (503,155 −
3 5

298,155 )]
kj
= 47003.244
jam

Menentukan Suhu Keluaran EX-01

Entalpi bahan pada suhu 25oC (298,15 K)

Cp Cl2 = A + (B × Tref) + (C × Tref 2 ) + (D × Tref 3 ) + (E × Tref 4 )
= 27,213 + (0,030426 × 298,15) + (−0,000033353 × 298,152 ) +
(1,5961 × 10−8 × 298,153 ) + (−2,7021 × 10−12 × 298,154 )
kj
= 33,7213 kmol.K
kj
R = 8,314 kmol.K²
Menghitung Nilai K

Rules of Thumb Chemical Engineer Third Edition hal 129

𝐶𝑝 𝐶𝑝
K = 𝐶𝑣 = 𝐶𝑝 −𝑅

33,7213
K = 33,7213 −8,314 = 1,3272

K-1 = 1,3272 − 1 = 0,3272

(K−1) 0,3272
= 1,3272 = 0,2466
𝐾

Menghitung 𝜟𝑯

𝑃2
𝛥𝐻 = 𝐶𝑝 𝑥 𝑇 𝑥 (1 − ((𝑃1)(𝑘−1)/𝑘 )) × 0,5
1
1
𝛥𝐻 = 33,7213 𝑥 503,15 𝑥 (1 − ((10)0,2466 )) × 0,5

kJ
𝛥𝐻 = 3674,8063
kmol

Menghitung Suhu Keluar (T2)

𝑃2 𝛥𝐻
𝑇2 = 𝑇1 𝑥 (𝑃1)(𝑘−1)/𝑘 + 𝐶𝑝

1 0,2466 3674,8063
𝑇2 = (503,15 𝑥 ((10) )) + ( )
33,7213

𝑇2 = 394,1742 𝐾

𝑇2 = 394,1742 − 273,15

𝑇2 = 121,0243°𝐶
Energi Keluar Q5 T
Massa bahan :
laju alir BM laju alir
Komponen
keluar (kg/jam) (kg/kmol) keluar (kmol/jam)
Cl2 465,163 70.9 6,56

Entalpi bahan keluar pada suhu 121,0243oC (394,174 K)

B C D
Q Cl2 = n [(A(T − Tref)) + ( 2 ) (T 2 − Tref 2 ) + (3) (T 3 − Tref 3 ) + ( 4 ) (T 4 −
E
Tref 4 + (5) (T 5 − Tref 5 )]
0,030426
= 6,56 [(27,213 (394,174 − 298,15)) + ( ) (394,1742 −
2
−0,000033353
298,152 ) + ( ) (394,1743 − 298,153 ) +
3
1,5961 × 10−8 −2,7021 × 10−12
( ) (394,1744 − 298,154 ) + ( ) (394,1745 −
3 5

298,155 )]
kj
= 21645,237
jam

Panas yang diserap

Qs = Q input − Q output
= 47003.244 − 21645,237
kj
= 25358,007
jam
Neraca Energi Total Expansion Valve-01

Komponen Aliran Masuk (kJ/jam Aliran Keluar (kJ/jam)

Q in 47003.24377
Q out 21645.23677
Qs 25358.00699
Total 47003.24377 47003.24377
20. Neraca Energi Condenser-02
Q out pendingin

Q 5T in CD-02 Q 5T out
(121,024248°C) (-50°C)

Q in pendingin

Fungsi : Untuk mengkondensasi vapor dari expansion valve hingga mengubah fasa
menjadi liquid

Kondisi operasi : T in = 121,024248°C (394,1742 K)

T out = -50°C (223,15 K)

T reff = 25°C (298,15 K)

Tekanan = 1 atm

Energi Masuk Q 5T in

Massa Bahan :

laju alir BM laju alir

Komponen
masuk (kg/jam) (kg/kmol) masuk (kmol/jam)
Cl2 465,163 70.9 6,56

Entalpi bahan masuk pada suhu 121,0243oC (394,174 K)

B C D
Q Cl2 = n [(A(T − Tref)) + ( 2 ) (T 2 − Tref 2 ) + (3) (T 3 − Tref 3 ) + ( 4 ) (T 4 −
E
Tref 4 + (5) (T 5 − Tref 5 )]
0,030426
= 6,56 [(27,213 (394,174 − 298,15)) + ( ) (394,1742 −
2
−0,000033353
298,152 ) + ( 3
) (394,1743 − 298,153 ) +
 1,5961 × 10−8 −2,7021 × 10−12
( ) (394,1744 − 298,154 ) + ( ) (394,1745 −
3 5

298,155 )]
kj
= 21645,237
jam

Energi Keluar Q 5T out

Massa Bahan :

laju alir BM laju alir

Komponen
keluar (kg/jam) (kg/kmol) keluar (kmol/jam)
Cl2 465,163 70.9 6,56

Entalpi bahan keluar pada suhu -50oC (223,15 K)

B C D
Q Cl2 = n [(A(T − Tref)) + ( 2 ) (T 2 − Tref 2 ) + (3) (T 3 − Tref 3 ) + ( 4 ) (T 4 −
E
Tref 4 + (5) (T 5 − Tref 5 )]
0,030426
= 6,56 [(27,213 (223,15 − 298,15)) + ( ) (223,152 −
2
−0,000033353
298,152 ) + ( ) (223,153 − 298,153 ) +
3
1,5961 × 10−8 −2,7021 × 10−12
( ) (223,154 − 298,154 ) + ( ) (223,155 −
3 5

298,155 )]
kj
= −16305,6955
jam

Entalpi Pengembunan Klorin Keluar pada suhu -50oC (223.15 K)

Panas pengembunan merupakan kebalikan dari panas penguapan

dH cond = (-) dH Vap

T
H Vap Cl2 = A × (1 − (Tc))n
 223,15 0,401
= 28,560 × (1 − ( ))
417,15
kj
= 21,01
kmol
dH Vap = H Vap × n Cl2 out × 1000
= 21,01 × 6,56 × 1000
kj
= 137.844,182
jam
dH cond = (-) dH Vap
kj
= −137.844,182 jam

Kebutuhan Pendingin
Qs = dH in − dH out + dH cond
kj kj kj
= 21645,237 jam − (−16305,6955 jam + (−137.844,182 jam))

kj
= 175.795,1142
jam
Entalpi pendingin masuk pada suhu 5oC (278.15 K)

B C
Cp.dT H2O = [(A(T − Tref)) + ( 2 ) (T 2 − Tref 2 ) + (3) (T 3 − Tref 3 ) +
D
( 4 ) (T 4 − Tref 4 ]
−0,039953
= [(92,053 (278.15 − 298,15)) + ( ) (278.152 −
2
−0,00021103
298,152 ) + ( ) (278.153 − 298,153 ) +
3
5,3469 × 10−7
( ) (278.154 − 298,154 )]
3

kj
= −1516,39
kmol
Entalpi pendingin keluar pada suhu 30oC (303.15 K)

B C
Cp.dT H2O = [(A(T − Tref)) + ( 2 ) (T 2 − Tref 2 ) + (3) (T 3 − Tref 3 ) +
D
( 4 ) (T 4 − Tref 4 ]
 −0,039953
= [(92,053 (303.15 − 298,15)) + ( ) (303.152 −
2
−0,00021103
298,152 ) + ( ) (303.153 − 298,153 ) +
3
5,3469 × 10−7
( ) (303.154 − 298,154 )]
3

kj
= 377,4864
kmol
Delta H = H out – H in

kj kj
= 377,4864 − (−1516,39)
kmol kmol
kj
= 1893,88
kmol
Qs
Massa air pendingin = delta H

kj
175.795,1142
jam
=( kj )
1893,88
kmol

kmol
= 92,8228
jam
kmol kg
= 92,8228 × 18
jam kmol
kg
= 1670,81
jam
Q in H2O = n × Cp dT
kmol kj
= 92,8228 × −1516,39
jam kmol
kJ
= −140.755,76
jam
Q out H2O = n × Cp dT
kmol kj
= 92,8228 × 377,4864
jam kmol
kJ
= 35.039,35
jam
Neraca Energi Total Condenser-02

Komponen Aliran Masuk (kJ/jam Aliran Keluar (kJ/jam)

Q in 21645.23677
Q out -16305.69548
Q cond -137844.182
Q pendingin 175795.1142
Total 21645.23677 21645.23677