ATilVAC CH EMIC/IL CORPORAT'IOII

Pagc t of t0
NUVET 2OO EC
AltlVAC |'{SDS No.: 3322

MATERIAL SAFETY DATA SHEET

I.@r LlDl1aluEledrioN
PRODLTCT NAME: NUVET 200 EC
CIIBMICAL NAME: Nor applicrblc (btend)
GENERAL USB: Emulsifiable Concentrntc insecticittc
PRODUCT DBSCRIPTION: Amber liquid
llPA tlegistration Nrrmber: Not rcgistercrl in U.S. For Bxport Onl1,.
MSDS No.: 332 2
Revision Date: 1.5 December, 2005

MANUF'ACTURER: EMBIICENCY TI,LI]PIIONB tr'UMBERS:

AMVAC CITEMICAL CORPORA'I'ION ilTANIJFACTTIRBR: 323-264-391 0
4100 E. \,trashington Blvd.
TRANSPORTATION (24 ITOURS)
l,os Angelcs, CA USA 90023-4406
Ph: J23-264-3910
CIIEl\lTReC: 800-424-9300
oTtrnR (24 nolitrs)
liAX: 321-268-1028 r\MVAC: 323-264_3910

CONIPONI'N'T
l)imr:tlryl 2,2-tliclrlorovi rrylphosphlte ( I)l)Vl,; [)i0lrlorvos)
20n,i, 62-73-1
Inelt ingredients:
80r'o
lncluclcs the follor.ving compounrJs:
I ,2-benzenedicarboxvl ic acid, dibutyl ester (Dibut1,l
phthalate) 69.',|% 84-'t4-2
Acelic arrhydride
Mixed nonionic/anioniq en4liifiers in solvenrs 0.5% I 08-24-7
oa.r\QO/
/O
_

osltA HAZARDOUS CONTpoN0NTS (29 CFII. 1910. t200) coMpoNENT

IIAZAB])

@ffi/#*r6ry,ffi
.-.-.--.-AsClig
mg/nrr 5.0 mglm' ,ro-ro-r; cNS ncpression 5 0
qdudrldC l0g:24-i\
:5nonr
ru ;;.-;"*
_ 5_-ppm
Corrosive

Exposurc Limits g lrrs. TWA

AMVAC CHEMICAL CORPORATION Psge 2 ol 10

NUVET 2OO EC AMVAC tISDS No.: 3322

Ynunt-*
EMERGENCY OVEITVIEW:

DANGER! POISON! Poisonous if sivallorved, inhalecl or absorbei ilrrough skin and eyes.
Rapidly absorbed through skin. Repeated inhalation or skin contact ntay, without
symptoms, progressively increase susceptibility to Dichlorvos (DDVP) poisoning.
CAUTION! FLAMMABLE! Keep away from sources of ignition. CAUTION! WATER
REAC'IIVE! TOXIC to fish! Do not contaminate bodies of water.
KEEP AWAY FROM CHII-DREN!

POIEI\ffir\L IIEALTI{ EFFECTS

ROUTE(S) OF ENffRY May be fatal if absorbed through thc eye or sl<in, is ingested or is inhalcd.

SIGNS OFACLffE OVEREXPOSURE: r\crrtc cholincstcr:rsc rlcprcssioo may bc cvirlcncccl bv

hcadache, nausca, vomiting, diarrhca, abdominal cramps, cxcessive sweating, salivalion and
tearing, constricted pupil.-, blurrccl vision, tightncss in chest, weakncss, musclc trvitchirrg and
confusion; irr extreme cases, unconsciousrrcss, convulsions, sevcre tespittt<;q'depression and
clcath may occur. It should also bc notcd that br:carrsc of thc prescncc oFthc othcr c()1nl)()lrcnts,
thc product may also havc thc following hcnltl.r hazards: in:iratin11 to thc skin and cvcs, mav causc
ctntral nervous system tlcprcsr;ion, ma)'catrsc skin scnsitization, amv causo harm to rn unlx;tn
tlrild, and rnny irtctcasc thc possiblc tisl< oI inrpnirccl lcttiliq'..

SIGNS OF CFIROMC OVEREXPOSURII: llcpe'atecl exlx)surcs to small closcs of Dl)V? ancl othcr
organ<lplrosplratcs nray lorvct thc cholinc"-tcrar-c to levtls tirr:rr: tlre alrovc svmpt()nrs of :rcrrtc
()vcrcxp()i^urc lrc,rbscfvctl. Irr rtltlitiorr, llrr-'rc is cvitlcrrr:c tltrt cltrrlric cxp()surc t0 thc solvr:nt rnat'
c,r, rs(: c('ntritl ilr:rv()us systcnr tlltnrtllc.

CARCINOGENICI'IY: lil)r\ untlcr its 19!X) proposcrl (iuirlclirrt's f<rr ()arcirrollcn ltisk r\sscs.rnrcrrt has
classificcl I)l)VI'!ls lravirrg "sulgcstivc cvirlcncc of carcinoecnir:ity, bLrt not sufficir:rrt t() lsscss
human carcinogcn'ic potcntial." lAlt(l lists l)I)Vl) (l)ichlorvos) as
bcing possibly carcirrog<'rric to htrrnans ((irorrJr 213). CARII SI{O[[,D BE IXI]RCISED IN
I IAM)IING I)DVP N ND TTS I()TIMT]I/\I'IONS.

MBDICALCONDITIONSAGGRAVATED BYEXPOSURE: Prcexisting conditiors rvhlch loscr

cholincstcrasc lcvcls incrcasc vulncrability to cht>lirrcstcrar-c dcprcssion,'l'hc"-c inclrrdc: (for plnsrna)
gcnetic cholincstt:tasc dc6cicrrcy; rdvalccd livr:r tliscasc; chronic alcoholisrn; nr:rlntrtritirn;
dennatomvositis; cxisting toxicity frrm exT)()i^urc to carbon disulfidc; benzalkonium salts, organic
rncrcury compounds, ciguatoxins or solanincs; and (for ltl3C) hemolytic anemias.
 \

4. FIRST AID MIIASUITES

DDVP IS A CI{OI,INESTERASE INI-III]If'OIT. A PI{\SICIAN STIOULD l]E CONIACI'ED IN ALL CASES OF
EXPOSURE TO DDVP AND N'S FOiITTLA I'IONS.

CAUTION: Pcrsons atrcnding victim should avoid clircct contact with hcavih contaminatcd clothing ot vominrs.
Rubber gkrvcs should bc wom bv the cmcrgcncy rcsJronrlcr or mc<.tic:rl pcrsrrnnci whilc washing thi pcsticiclc from skin
and harr of tht cxposcd vicrirn.

E\T'S: Immcdiatcly flush thc cycs rvith copious amolrrlts of clcirr, cool nrnnir:g rvater tirr a miniurum o[: 15 minutcs. I]old
thecyrliclsaPartduringtlrcflushingtocnsurcrinsingofthccrrtircsurfaccofthccycs and lids u.ith watcr. Contact a
physician irnmcdiatcly. I f thcrc will bc a dclay in gcttirrg rne dical rttcntitxr, rinsc thc cves for at lcast alother I 5
lr inutr:s.

INHAI-ATIO}.I:
Rcmovc vi<:tim to frcsh air. If brcnthirrg has ceasctl, clcar the victim's ainvay nnd startrnouth- to-moutll
ar:tificial rcspiration. If breathing is difFrcult, givc oxygcn. (lontact a physicinn immccliatcly.

INGESTION:
DO NOT induce vomiting. lf victim is consciorrs, adrninistcr xn I oz. glass of water containing 2 tbsp. activated
charcoal. l'Iave person lic on thr:ir left sidc to slorv down absorption of the ingested material. Ncvcr givc anvthing bv
m()uth t() An unconscious lte rs()tl- (lontact a physician immcdiatclv.

SKIN: Imnrcdiatcly flush rrll affcctcll arcrts rvith largc afir()rrnts of ciclr rvirtcr ftrr at lcist 15 nrinutcs. I{cm1rvc

pl rysi<'i:rrr ir rrrrrctlirrtt.ly.

NOIETOPFTY$CIANS:
'fhis is nn C)rgaoophttsphatc (Ol') lnsccticidc. l)o not rvait tirr laboratorv confirnation to trcar
paticnrs with
strong clinical evidencc ofpoisorring. Contact your local poison control centet for further recornmendatioos
regatding control of poisoning, emcrgency trcatment, aud other infonnation regatding the toxiciry of DD\?
(Dichlorvos)' A possible method of treatorent is given bclorv. I)o Not handle the patient rvithout the foLlowing
protective equipmeot in place chemical resistlnt gloves and apron (prcfcrably nitrile). ltcmove contamiiatcd clothing ani
do notreusc without tlrorough. cleaning with cletctgent and hot watcr. f)ispose of heavilr. c()ntalninated clot-hirrg,
including shocs, as a hazlrdous waste. Iistablish airway and oxyeenation. I lt Atropi.c s^ulf-ate is- the antidote of
cl.roicc against patasymPathetic !]ewous stimulation. If thcrc arc signs of parasymplthctic stimr:latiol, ,/\tropine
Sulfate should bc infccted at 10 minutc intcrvals in doscs of i to 2 milligrams u.rtil compl;rc atropinizarion has
occurrcd. Pralidoxime chloride (2-P,'\tr'f cliloride) mav also bc uscd as an eftective antiiote i' a.'i.lition to and rvhile
maintaining full atropinizatiot. In adults, an initial rlose of I gmm of 2-PAIVI should be injcctecl, prcferably as an
irrfusion, in250 cc of saline oveta 15 to 20 mimrte pcriocl. IFthis is notpractical,2l)r\M may bc r&rinistered slorvly
by intravcrious injection as a 59lo solution in rvatct over not lcss than 2 mirrutcs. Aftcr about an hour, a second dose
of I sram of 2- PAM rvill be inclicatcd if muscle rvcakncss has not bcen tclicvcd. For infants and chiidrcn, thc dose of 2-
I)AM is 0.25 grirms..i\voi,l morphine, aminophyllinc, phcnothiazine, reserpinc, furoscmidc ancl ethacrvnic
acid. clear chcst by postural drai'ngc. oxygcn administration nray bc neccssary.
Observe p^tient cofltinuously for 48 hours. Rcpeated exposure to cholinesterasc inhibitors may rvithout
warning cause ptolongcd susccptibiliry to vcry small doses of anv cholinestcrasc inhibitor. All,,ru no further
cxposurc until time f<rr cholincsterasc tegencration has becn attaincd as detcrmincd by a |lood tcst. Ilathe
and
sharnpoo contnminatcd skin antl hait. If irrgcstccl, crnpty stonrach. Activatcd c6atcoal is trsctirl to tlrtl.rcr
limit
absorption.
6. ACCIDBNTALRIILEASBIYIBASURIiS.-gon1't!
SMALL SPILL: Covcr with nonflanrmablc absr>rbctrt (clav, salrcl, oil city, kiny lincr, ctc..) to absorb the liquid. Srveep
into art opcn plastic tlrum. I)econtaminatc tlrc arcr rrrd cr.luipmcnt with clilutc ali<ali <>r amm6nia (iess than 570
solution) antl clctctgcnt. FIush thc arc:r rvith watcr. i\bsotb arrd -srvccp into thc sarnc opcn plastic Jmm. Close
thc dnrnr arrcl rlisposc oFas a hazardous \\'astc.

LAlt(;E SPILL: l)ikc thc spill to prcvcnt cotttitntirtatiorr of locul rvatcr s()urccs. SiJrlron thc maioritv of thc lirluitl i11t6
clrrtrrts l'rrr ust: or dislrosal, dcpcndinll on thc circrrmstanccs. (,lcan thc arca as dcscribcci f<rr a snrall spill.

T.gaNpLtNG ANp STORAGE

FIANDLING: l)rcvcnt sl<in contact. I)o not breathe fumes. Wcar approl:riatc personal protcctive ccluipmenr
(PPE, Scction 8). Wash thoroughlv aod chanse clothcs aftcr hanclling. Wash clothes .epnr"t"lv; do .,ot
rvash heavily contrminated clothint. Disposc of hcavily c()ntalninatecl clothing as a hazarclr>us rvaste.
Kccp prtxluct rrrvay fronl frlod, clrirrk, c<>sntctic"-, ancl tobacco prorlucts. Scc prodr:ct labcl firr ororc
dcttiicd harrdling proccclurcs.

of childrcn. Storc irr oriqinli containcr.

Ii. BXPOSU RIt CONTROLS/PE Ii.SONA I, PROT BCT'I ON

ENGINEEIUNGCOI\I.rIiOIS r\ wcll-vt:rrtilatctl arca is rcconrrncrrrlctl fot hanrlling NL]V;\NG) 200 I.l(1. Usc of
mcchanical or local cxbaust svstcm-s is rccomntclrclcrl. Scc labr:l ()r cont:lct vour distributr>r tbr r.norc
complctc instructions.

RESPIRATORY PITOTECTION: r\ NIOSI i/ivfSI L'\ approvr:d airlurili,ing rcspiraror ccluippccl rvith r>rganic vapgr
cartriclgcs or canir-tcts is requircd g'hcn rnvonc is workinr *,itlr or ncar opcrl colltiin;rs of this piodrct. ,\
nta;:jmtrrn usc oFcighr hours is rccommcrrclctl. llor crncrecncv arrrl otlrcr iondrtions q,hcrc. thc c,xPcisurc lintit
nray l>c grcatlv cxccctlcrl, usc an al)llr()\'ctl positivc-prt:sstrrc, scl f'-corttainctl l;rcathint1 al)p:rratlls 6r pgsitiyc-
l)rcssrtrc airlinc rvitlr atrxiliatv sc]f-contlirtt'cl rir strpplv. Scc l;rbcl ()r c()nt:tct vour,listribrrt<>. f,r. nr,r." cornpft:tc
in s lrrrctiorr s.

SKIN PnOTECIION: I)rcvcttt:rkirt c.tttitct. (lh<:rnrcrl rcsistant glovc"-(prcfcr:rblv nitrilc), covcralls iorrr-slccvcci
sllirr altrl 1t:tltt:r, rtrtl cht:tttir::t] rc'sislrurl shr,< s or llor,rs, art: ncc(-,ss:rrv t() 'r
l)r(.vcrrt skin (:(),)tlnrir):rrirl1. .\

risk oisIillrr11t'or slllrrslrirrll. l(ttrtovr: c()nt;ln);rr;rl((l r:lotlrirrt:ts s(xrn rls possilrlc. \\/lslr tii16.9r
r:onl:rrnirr:rtttl clothing scparatt.lr, tionr ofltcr r.lotirrs. \\,cirr clr:rtrr clrithcs tlailr.. Wrrslr t,cl] *ith so.rp arrcl
rr':ttcr;ttitr harrrllirt!'this Ir,rrltrct. St'r'thc lal;tl tirr rrrort.sJ.(.'cill(: irrstrur:rir,rrs.
 [!BE FIEUTLN G M II,.\sURII:5.

FI-AMMABLD PROPERTIES
Flash Point I 156 1t/65.5oO (Pensliv-l\'fartcns c,c.)
'\utoisnitiort
'['cmpcraturc: Not availablc
lilammablc l,imits: l,orvcr flammablc limit: not available
Uppcr flarnmablc limit: not availablc
. lilammability: 'l his is a nonflamnnblc liqtncl that will burn rvhcn hcatcd S',lltl?,'\ rating =1)
EXPLOSTVITY
Vapor-tirmixturcs <>f onc of thc (:()mp()ncr)ts);\cctic anhytlriclc, art: l<nt>rvtt trr bc cxplosivc rvlrcn thc ct>rnpt>uncl
is rvithin the tlarnmablc limits li--tcd abo.'e an<l thc tcmpcraturc is abovc the flaslrpoint.,\lsr>, a violent
cxgthcrmic rcrcti6n occurs rvlrcrr .\cctic arrhyrltidc rctcts rvitlt rvrtcr. ']'his hcat may bc sufficicnt trr i.O";r"
comltustiblc matcritls. r\cctjc :rnhvcl ridc is sc:nsitivc t() stxtic cl isclra rtlc.

HAZARDOUS COMBUSTION PRODI]CIS:

T'his pr6dqct will crnit toxic furncs rvhcn llurncil, irrclucling carb<ttr nronrrxidc. \rapors of thc r:nbtrrtrcd
prgduct mry also bc hazarclous. (lorltact rvith thc fumcs and vapors shottld be avoidcd bv stavirrg upu'ind
and by wearing imperviotrs clothing and positivc prcssutc sclf-containecl brcathing aPParanrs.

DCTINGUISFIINGMEDIA
Foam, dry chemical, carbon dioxide, watcr spray (fog). Usc rvatcr .x'ith caution as one of thc components.
Acctic anhydride, reacts with watcr.

FIRE FIGFITING INSTRUCITONS:

l:ivacuatc rlonessr:fltial pcrsonncl from thc arca. Kccp upwincl. Wcar self-containcd btcathing apParatus
ancl inrpenious clothing, including glovcs antl cvc protection. Clcan all clothing bcfbrc rettse. Sevcrelv
contaminatcd clotl-ring cannot bc adcquatcly dccrxrt'lrninated, :rnd rmrst be disposbd as a hazarrlous waste.
Shower rvith -soap and water nftct contact with tlris procluct.

6. ACCI
GENERAL: l;',vncuatc pcrsolurcl antl tlroroughlv vcntilafc tlrc rrcr. Usc lrlt:titrirtc vcntilatiotr anrl rtpirronrirtte
pcrsonal protcctivc e<pipnrer.rt (l)l)l:,), Scction 8). l(ccp bysturtdcrs upwind ancl arvrtv tiom thc spill.