International Journal of Ayurveda and Pharma Research Research Article
COMPARATIVE ANALYTICAL STUDY OF SAJALA AND NIRJALA NARIKEL LAVANA
Golecha Paras D1*, Kurve Siddhisha2, Sathe Ninad3, Punde Ashish4 *1M.D. Scholar, Dept. of Rasa Shastra and Bhaishajyakalpana, YMT Ayurvedic Medical College and Hospital, Navi Mumbai. 2M.D. Scholar, Dept. of Dravyaguna vidnyan, YMT Ayurvedic Medical College and Hospital, Navi Mumbai. 3Professor, 4Assistant professor, Dept. of Rasa Shastra and Bhaishajyakalpana, YMT Ayurvedic Medical College and Hospital, Navi Mumbai. ABSTRACT Advancement being the heart of development any science, Ayurveda has been no exception to this. Various basic formulations have been mentioned in the classical texts i.e. Samhitas and quite a few were added later on, by contemporary Acharyas. Lavana Kalpana is one of them. Lavana Kalpana literally denotes any pharmaceutical formulation comprising Lavana i.e. any type of salt along with other herbal ingredients. Narikel Lavana has been advised under the Rogadhikara of Parinaam Shula. Acharyas have explained two separate methods of preparation of Narikel Lavana: Sajala (retaining the water inside coconut) and Nirjala (without coconut water). Nirjala Narikel Lavana has been prepared by using Mahaputa and Sajala Narikel Lavana in Kukkutaputa. Current study is aimed at preparation, standardization and comparative study of Narikel Lavana as per two different references with the help of sophisticated analytical technique, XRF. Other methods of examination of Ayurvedic drug formulations such as organoleptic evaluation, physico- chemical tests are also employed. The differences between these values and variations in the XRF analysis have been elaborated here. Organoleptic evaluation of both the samples shows no difference, whereas minor variations are observed in the physico- chemical parameters. XRF analysis has clearly indicated the different between the elemental composition of both Sajal and Nirjala Narikel Lavana. KEYWORDS: Narikel Lavana, Sajala, Nirjala, XRF. INTRODUCTION Ayurveda is an extravagant resource where senior Ayurved practitioners in day to day clinical practice. various newly developed manufacturing methods of herbal The timely evolution in tedious manufacturing processes and mineral drugs can be explored. In most ancient and of Narikel Lavana is also evident in the classical literature. available classical texts like Bruhattrayi, a large number of The evolutionary changes can be observed in the herbo- mineral ingredients have been used to prepare the preparation methods of the same formulation, preceded by medicinal formulations. The branch of pharmaceuticals i.e. experimentation as time elapsed. Hence, it is the need of Bhaishajya-kalpana is evident since the time of Charak hour to develop a standard operating process with its Samahita. Various forms of medicines with their standardization in terms of latest sophisticated analytical manufacturing processes such as Taila, Ghrit, Avleha, techniques. Along with these methods, the age old and Ghana, Asava, Arishta etc. are available in the Ayurvedic time tested methods of evaluation of standard product classics, similarly Lavan Kalpana was also introduced in such as organoleptic characters are also studied. The the classical text later on. Lavana Kalpas are the current comparative study is aimed to develop the formulations which contain any of the five types of standard manufacturing process of Narikel Lavana with its Lavanas, especially Saindhav Lavana along with other standardization, preparation by two methods, namely herbo-mineral components. Narikel Lavana is one such Sajala (retaining the water inside coconut) and Nirjala important and commonly used Lavana Kalpa. It consists of (without coconut water). There are two separate methods Narikel along and Saindhav Lavana. Narikel Lavana is mentioned for preparation of the two types of Narikel recommended under the Rogadhikara of Parinaam Shula. Lavana. Narikel Giri (coconut meat) and Narikel Jala are one of the MATERIAL AND METHOD richest sources of essential electrolytes. It predominantly Material contains high amount of Sodium and Potassium(1). Which is Six coconuts, rock salt, fuller’s earth (Multani mitti), cotton probably why Narikel Lavana is found to be effective cloth, cow dung cakes, mortar and pestle. against Parinaam Shula and other acid peptic disorders. Saindhav Lavana is essentially Pittahara. Saindhav also has Method Sheeta veerya. With its Shamana property, Saindhav 3 batches of each Sajalaand Nirjala Narikel Lavana pacifies the vitiated Pitta. It also reduces secretion of acid were prepared as per the classical reference of in the stomach and prevents acid reflux. Saindhav is again Bhavprakash nighantu(2) and Rastarangini(3) respectively. reach in electrolytes such as Sodium, Potassium, and a. Sajala Narikel Lavan: It was prepared in the teaching Magnesium etc. Narikel Lavanais successfully used by pharmacy of department of Rasa Shastra and
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Int. J. Ayur. Pharma Research, 2016;4(6):54-57 Bhaishajya Kalpana at YMT Ayurvedic medical college, Navi mumbai and were cleaned by removing husk with the as per the reference of Bhavprakash nighantu. help of knife. Step I: 3 water containing coconuts of weight 664g, 536g, Step II: The coconut water was drained from each sample 604g respectively were procured from APMC market of in a clean SS vessel by opening the functional pore of the Navi mumbai and were cleaned by removing husk with the coconut with the help of sharp knife. help of knife. Step III: According to the selected reference, 10 Tole Step II: The coconut water from each sample was drained (125mg) rock salt was filled in each coconut, the pores in a clean SS (stainless steel) vessel by opening the were sealed and each coconut was coated by cotton cloth functional pore of each coconut with the help of sharp and wet fuller’s earth (Multani mitti).The thickness of Lepa knife and was measured batch wise. was kept up to 1 Angul (1.5cm). The samples were dried in Step III: The powdered rock salt (Saindhav) was dissolved shade (Chhayashushka). in the coconut water until saturated. The quantity of rock Step IV: Each rock salt filled, coated coconut sample was salt required for complete dissolution in the coconut water subjected to Mahaputa as per the reference of was noted batch wise. Rastarngini(5). For Mahaputa, a pit measuring 91cm X Step IV: the coconut water with dissolved rock salt was 91cm was prepared in open space around the teaching refilled in the respective coconuts with the help of glass pharmacy of the institute. The pit was filled with total funnel. The opened eyes (pores) of the coconuts were 1500 cow dung cakes. Out of which 1000 cakes were closed with the help flaps of coconut shell and were sealed arranged evenly at the base of the pit, then the coated by wet fuller’s earth (Multani mitti). coconuts were placed carefully and remaining 500 cow Step V: 3 coconuts filled with rock salt were coated with dung cakes placed above these coconuts. Finally the cow cotton cloth and fuller’s earth (Multani mitti). The dungs cakes were incinerated. Temperature of the thickness of the coating (Kapadmitti) was kept 1 Angula Mahaputa was noted at regular intervals (every 30 mins.) (1.5 cm) on each sample. Each sample was dried in shade with the help of Laser pyrometer. The samples of Nirjala (Chhayashushka) after coating with fuller’s earth (Multani Narikel Lavana were kept for self-cooling for 24h mitti). (Swangasheeta). The characteristics (Siddhilakshanas) of the processed samples were observed and noted. After Step VI: Each rock salt filled, coated coconut was subjected self-cooling, the coating and shells of the coconuts were to Kukkutputa as per the reference of Bhavprakash removed gently and each sample was rubbed in mortar nighantu. For Kukkutputa(4), 1 ft X 1 ft pit was prepared and pestle to obtain the final product from each sample. adjacent to the teaching pharmacy of institute and 42 cow Each final product was weighed and subjected to dung cakes (Upal) of size 8 inches diameter each were physicochemical analysis. arranged evenly. Each sample was incinerated in Kukkutputa in open air and temperature of each puta was OBSERVATIONS AND RESULTS noted half hourly using alaser pyrometer. The samples of Table 1: Physico- chemical parameters(6) of Sajala Sajal Narikel Lavana were kept for self-cooling up to 12h Narikel Lavana (Swangsheeta). The characteristics (Siddhilakshanas) of the Parameter Value processed samples were observed and noted. After self- pH 10.25 cooling, the coating and shells of the samples were Total Ash % 98.33 removed gently and each sample was rubbed in mortar and pestle to obtain the final product from each sample. Acid insoluble ash % 6.13 Each final product was weighed and subjected to Table 2: Physico- chemical analysis of Nirjala Narikel (6)
physicochemical analysis. Lavana
b. Nirjala Narikel Lavan: It was prepared in the teaching Parameter Value pharmacy of the department of Rasa Shastra and pH 9.21 Bhaishajya kalpanaat YMT ayurvedic medical college as Total Ash % 98.35 per the reference of Rasatarangini. Acid insoluble ash % 0.1 Step I: 3 water containing coconuts of weight 697g, 626 g, 670g respectively were procured from APMC market of Table 3: Organoleptic evaluation(7) of Narikel Lavana: Sajal NarikelLavana Nirjal Narikel Lavana Color Grayish black Grayish black Odor Pungent Pungent Taste Salty (Lavana Rasatmak) Salty (Lavana Rasatmak) Texture Rough, Fine Rough, Fine Sound Not specific Not specific XRF (X- ray fluorescence) analysis was carried out at Varsha bullion and elemental analab, Mumbai.
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Golecha Paras D et al. Comparative Analytical Study of Sajala and Nirjala Narikel lavana Table 4: Sajal Narikel Lavan XRF analysis Element Mass (%) Intensity Formula Mass (%) Na (Sodium) 8.285 0.022 Na2O 11.167 P (Phosphorus) 1.224 0.165 P2O5 2.804 S (Sulphur) 1.231 0.314 SO3 3.074 Cl (Chlorine) 72.574 9.257 Cl 72.574 K (Potassium) 6.879 0.429 K2O 8.287 Ca (Calcium) 1.410 0.109 CaO 1.972 Fe (Iron) 0.085 0.118 Fe2O3 0.122 O (Oxygen) 8.313 Table no. 5. Nirjala NarikelLavan XRF analysis Element Mass (%) Intensity Formula Mass (%) Na (Sodium) 8.481 0.014 Na2O 11.432 Si (Silicon) 0.933 0.043 SiO2 1.995 P (Phosphorus) 1.193 0.102 P2O5 2.733 S (Sulphur) 1.908 0.308 SO3 4.766 Cl (Chlorine) 63.673 5.617 Cl 63.673 K (Potassium) 5.868 0.267 K2O 7.069 Ca (Calcium) 5.117 0.287 CaO 7.159 Fe (Iron) 0.769 0.737 Fe2O3 1.100 Sr (Strontium) 0.062 0.397 SrO 0.073 O (Oxygen) 11.997 DISCUSSION The current comparative study was undertaken to Nirjala Narikel Lavana. Acid insoluble ash indicates the develop the standard manufacturing process for Narikel presence inorganic matter such as silica in the tested Lavan. Due to evolutionary changes occurred in Ayurvedic sample. pH of Sajala Narikel Lavana was slightly higher pharmaceuticals, 2 methods of preparation of Narikel (10.25) than that of Nirjala Narikel Lavana which was Lavan were observed in literary review. Bhavprakash 9.21.As per Table no. 3, Both Sajala and Nirjala Narikel nighantu has for the first time described the method of Lavana were found to have similar organoleptic preparation of Narikel Lavan in which coconut containing characters, i.e. both were grayish black in color and had a water (Sajala Narikel) was used. The method of paka characteristic pungent smell. Both were salty when tasted. (heating) was also specifically mentioned i.e. Kukkutputa The powder was smooth textured and very fine to touch. has been implemented for Sajala Narikel Lavan But the XRF analysis in table no. 4 and 5 showed preparation. As per the classical references of Kukkutputa, remarkable difference between the two samples. Mass % the samples were heated using total 42 cow dung cakes of Elemental calcium was found to be 1.410 in Sajala (Upala). In the current study, it was observed the optimum Narikel Lavana and the same was found to be 5.117 in temperature of Kukkutputa reached upto 424 oc. For the Nirjala Narikel Lavana. Elemental oxygen mass % was preparation of Sajala Narikel Lavan, comparatively low observed to be 8.313 in Sajala Narikel Lavana, whereas it heat was given i.e. 424ºC than that in case of Nirjala was 11.997 in Nirjala Narikel Lavana sample. Mass % of Narikel Lavan where Mahaputa has been implemented and elemental iron was 0.085 in the Sajal Narikel Lavana, the the maximum temperature of Mahaputa was up to same was 0.769 in Nirjala Narikel Lavana. Nirjala Narikel 1050ºC.As the coconuts were full of water in Sajal Narikel Lavana showed presence of Strontium with a mass % of Lavan, they might burst due to intolerance of high 0.062, which was absent in the Sajal Narikel Lavana. temperature. Nirjala Narikel Lavana is prepared as per the Nirjala Narikel Lavana contained elemental silicon in the reference of Rasatarangini. Hence, the coconuts which mass % of 0.933 and was absent in the Sajal Narikel were of devoid of water, were subjected to Mahaputa. Lavana. Rest all the elements such as sodium, phosphorus, These coconuts being free of water, could tolerate the high Sulphur, chlorine and potassium were found in temperature in the Mahaputa. Due to coating of fuller’s approximately similar quantities. earth (Multani mitti), the temperature rises slowly and CONCLUSION also cools very slowly which could be helpful for Narikel Lavan has been recommended under the prolonged and thorough Paka of the ingredients in the Rogadhikara of Parinaama Shula. From the above drug. As per table no.1 and 2, Physico chemical analysis of mentioned observations, it can be concluded that both Sajala and Nirjala Narikel Lavana revealed that the implementation of either of the methods for obtaining total ash values of both the samples showed no significant Narikel Lavan results in least remarkable difference in difference. Acid insoluble ash % in the Sajala Narikel majority of the physico- chemical properties. Whereas, Lavana was 6.13 whereas it was much lower i.e. 0.1 in the XRF analysis has shown that Nirjala Narikel Lavan contains Available online at: http://ijapr.in 56 Int. J. Ayur. Pharma Research, 2016;4(6):54-57 higher amount of elemental Calcium as compared to Sajala 2) Bhavaprakash, Shri Brahmashankar Mishra, Narikel Lavana. Electrolytes like Calcium and Potassium Chaukhambha Sanskrit bhawan, edi. 2012, madhyam might be responsible for the antacid property of this khanda, adhyay 30/71, 72. formulation. The pH of Sajala Narikel Lavana is higher than 3) Rasatarangini, Kashinath shastri, Motilal Banarasidas, that of Nirjala Narikel Lavana. The higher alkalinity of Revised edition 2014, Chaturdash tarang- 123- 130. Narikel Lavana may also play an important role in the 4) Rasa ratnasamucchaya, Acharya siddhinandan Mishra, therapeutic activity of this Kalpa. Final product obtained Choukhambha Orientalia, edition 2011, adhyay 10/ after both the procedures had been completely incinerated 56. and proper Paka was achieved. Preparation of Sajal 5) Rasa ratnasamucchaya, Acharya siddhinandan Mishra, Narikel Lavan required comparatively lesser heat, i.e. Choukhambha Orientalia, edition 2011, adhyay 10/ lesser amount of fuel is consumed during the entire 51. procedure as compared to Nirjala Narikel Lavana. 6) The Ayurvedic Pharmacopoeia of India, government of References India, ministry of health and family welfare, 1) The Chemical Composition and Biological Properties department of AYUSH, part- 1, volume- 1, 2.2.3, 2.2.4, of Coconut (Cocos nucifera L.) Water. Jean W. H. Yong, 3.1.3. Liya Ge, Yan Fei Ng and Swee Ngin Tan. Molecules 7) Charak Samhita, Acharya brahmanand tripathi, 2009, 14, 5144-5164; doi:10.3390/molecules Chaukhambha prakashan, vimanasthan, 8-97. 14125144.
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Golecha Paras D, Kurve Siddhisha, Sathe Ninad, Punde Ashish. Comparative Dr. Golecha Paras Analytical Study of Sajala and Nirjala Narikel lavana. International Journal of M. D. scholar, Dept. of Rasa Shastra and Ayurveda and Pharma Research. 2016;4(6):54-57. Bhaishajyakalpana, YMT ayurvedic Source of support: Nil, Conflict of interest: None Declared medical college and hospital, Navi Mumbai. Email: dr.parasd.golecha@gmail.com Cont.: 09762373730
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