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INSTRUCTION TO CANDIDATES
THIS QUESTION BOOKLET CONTAINS 80 OBJECTIVE TYPE QUESTIONS (SINGLE
BEST RESPONSE TYPE) IN THE SUBJECTS OF CHEMISTRY. CANDIDATE SHOULD
CAREFULLY READ THE INSTRUCTIONS PRINTED ON THE QUESTION PAPAER
AND ANSWER SHEET AND MAKE THE CORRECT ANSWER ON THE ANSWER
SHEET. AS ANSWER SHEETS ARE DESIGNED TO SUIT THE OPTICAL MARK
READER. SPECIAL CARE SHOULD BE TAKEN TO FILL YOUR NAME, CLASS ,
SECTION AND ROLL NO. ACCURATELY.THE CANDIDATE MUST SIGN ON
THE ANSWERSHEET AND QUESTION BOOKLET.READ EACH QUESTION
CAREFULLY. DETERMINE THE CORRECT ANSWER FROM OUT OF THE FOUR
AVAILABLE OPTIONS GIVEN FOR EACH QUESTION. FILL THE APPROPRIATE
CIRCLE COMPLETELY LIKE THIS,
FOR ANSWERING THE PARTICULAR QUESTION, WITH BLACK INK BALL POINT
PEN ONLY, IN THE OMR ANSWER SHEET. EACH ANSWER WITH CORRECT
RESPONSE SHALL BE AWARDED ONE (1) MARK. IF THE EXAMINEE HAS
MARKED TWO OR MORE ANSWERS OR HAS DONE SCRATCHING AND
OVERWRITING IN THE ANSWER SHEET IN RESPONSE TO ANY QUESTION, OR
HAS MARKED THE CIRCLES INAPPROPRIATELY E.G. HALF CIRCLE, DOT, TICK
MARK, CROSS ETC, MARK/S SHALL NOT BE AWARDED FOR SUCH ANSWER/S.
IMMEDIATELY AFTER THE PRESCRIBED EXAMINATION TIME IS OVER, THE
ANSWER SHEET ARE TO BE RETURNED TO THE INVIGILATOR.
CHAPTER ONE
SOLUTION ( Grade 12 )
1. Colloids can be distinguished from true solutions by:
4. What is the molarity of a solution in which 50.0 mL of chloroform, CHCl3, are placed in a
100.0 mL volumetric flask and the flask is filled to the mark with acetone? The density of pure
CHCl3 is 1.483 g/Ml. (Molar mass of C= 12 , Cl = 35.5, H = 1 g/mol )
A. Henry's Law relates the pressure of a gas above a liquid to the concentration of dissolved gas.
B. The solubility of a substance generally increases when the temperature of solution is increased.
C. A colligative property is a physical property of a solution that depends on the number of solute
particles, and not their identity.
D. Raoult's Law relates the vapor pressure of a liquid to its mole fraction in the solution phase.
6. A solution has a mole fraction of the nonvolatile solute sucrose of 0.125. The vapor pressure of
the pure solvent is 26.0 torr at 25°C. What is the vapor pressure of the solution?
A. The entropy change upon mixing generally is a favorable factor for the formation of a solution.
B. The large crystal lattice energy of ionic solids is generally favorable to their solution formation.
C. An exothermic heat of solution would favor the formation of a solution relative to an
endothermic one.
D. One may generally say that "like dissolves like."
CHAPTER FIVE
SOME IMPORTANT ELEMENT (Grade 12 )
11. In the extraction of Zn fron ZnS, the reducing agent used and the method of refining are
14. Extraction of gold and silver involves leaching the metal with CN – ion. The metal is recovered
by ________________.
CHAPTER Four
CHEMICAL KINETICS (GRADE 11)
16. Which of the following change will increase the average kinetic energy of reactant molecules?
17. Consider the following experiments, each involving equal masses of Zinc and 10 ml of acid
Which of the following would cause the rate of the reaction to increase?
19. Which of the following compounds acts as a Brønsted-Lowry base but not as an Arrhenius
base?
A. H2O B. BF3 C. NH3 D. LiOH
21. From the following select the situation where both enthalpy and entropy favour the reaction
towards the product
A. 50 KJ B) 20 kJ C) 30 kJ D) -20 KJ
2A + B2 + C A2B + BC
|78.5230 − 77.993 |
% = × 100%
77.993
A. 6 B) 5 C) 4 D) 3
CHAPTER FIVE
CHEMICAL EQUILIBRIUM ( GRADE 11 )
28. Consider the following equilibrium;
CO( g) + ½ O2 ( g) CO2 ( g) is
A. 1 B) ( )1/2 C) RT D. ( )-1/2
Initially 0.1 mol of HBr is placed into a 2 L container. At equilibrium there are 0.04 mol of
HBr present. The equilibrium concentration of H2 is
in a closed container at equilibrium. What would be the effect of addition of CaCO3 on the
equilibrium concentration of CO2?
A. Increases C) Unpredictable
B. Decreases D) Remains unaffected
CHAPTER THREE
ELECTROMAGNETIC RADIATION (GRADE 11)
33. According to the wave-mechanical model of the atom, electrons in an atom
34. Which of these lists is arranged in order of decreasing energy per photon?
36. During a flame test, ions of a specific metal are heated in the flame of a gas burner. A
characteristic color of light is emitted by these ions in the flame when the electrons
38. Wave effects in quantum mechanics are not noticeable in the everyday world because
A. Quantum mechanics doesn’t apply to composite objects, like all everyday objects
B. Quantum effects only describe wave packets, which don’t apply to particles
C. Quantum effects are so slow that you can’t observe them
D. The wavelength is tiny compared to the size of everyday objects
39. Rutherford scattered alpha particles off of gold atoms, and discovered, to his surprise, that
A. Most of them went straight through, suggesting the atom was mostly empty space
B. The gold atoms were often knocked out, suggesting they were loosely bound
C. The electrons did little to stop them, showing that electrons were light
D. The alpha particles sometimes scattered at large angles, suggesting there was a lot of mass
and charge concentrated in the “nucleus”
A. Number of electrons.
B. Average distance of the most electron-dense regions from the nucleus.
C. Shape of the orbital
D. Spatial orientation of the orbital.
43. The work function of a particular photo-emissive material is 4.0 eV. If photons with 16 eV of
energy are incident on the material, what would be the maximum kinetic energy of the ejected
photoelectrons?
44. The graph below shows the relationship between the frequency of radiation incident on a
photosensitive surface and the maximum kinetic energy of the emitted photoelectrons What
does point P represent?
Kinetic Energy
P
Frequency (HZ)
CHAPTER THREE
CHEMICAL BONDING ( GRADE 11 )
45. Which of the following interactions are present between CO2 molecules?
I. London forces
II. Ion-dipole forces
III. Hydrogen bonding
IV. ipole-dipole attractions
B) The carbon atom has 6 electrons; 2 are core electrons and 4 are valence electrons.
C) The valence electrons in the carbon atom are all located in 2p orbitals.
D) The core electrons in the carbon atom are all located in the 1s orbital.
E) There are two unpaired electrons in the carbon atom.
A. nonpolar bonds, and is a nonpolar molecule. C) nonpolar bonds, but is a polar molecule.
B. polar bonds, and is a polar molecule. D) polar bonds, but is a nonpolar molecule.
A. The total number of molecular orbitals formed doesn’t always equal the number of atomic
orbitals in the set.
B. A bond order of zero represents a stable chemical bond.
C. Electrons placed in antibonding orbitals stabilize the ion/molecule
D. A bonding molecular orbital is of lower energy (more stable) than the atomic orbitals from
which it was formed.
49. The fact that BCl3 is a planar molecule while NCl3 is pyramidal can be explained several
different ways. Which is the best rationalization?
52. Consider the molecule below and identify the correct statement.
53. What is the maximum mass of copper that would be plated out by electrolyzing aqueous
copper CuCl2 for 16 hr at constant current of 3 ampere?
A. 28 gm B) 57 gm C) 64 gm D) 114 gm
A. Mass does not cross boundaries of the system , though energy may do so
B. Neither mass nor energy crosses the boundary of the system
C. Both mass and energy cross the boundary of the system
D. Thermodynamic reaction does not occur
55. Indicate which one of the following reactions result in a positive ΔSsys.
56. Calculate the standard heat of formation, Hfo, for FeS2(s), given the following information:
2FeS2(s) + 5O2(g) 2FeO(s) + 4SO2(g) Horxn = -1370 kJ
Hfo for SO2(g) = -297 kJ/mol
Hfo for FeO(s) = -268 kJ/mol
A. The energy released when chemical bonds are formed during a chemical reaction
B. The energy consumed when chemical bonds are broken during a chemical reaction
C. The difference between the energy released by bond formation and the energy consumed by
bond cleavage during a chemical reaction
D. The increase in disorder of the system as a reaction proceeds
60. The entropy change can be calculated by using the expression ∆S = . When water
freezes in a glass beaker, choose the correct statement amongst the following :
CHAPTER FOUR
ELECTROCHEMISTRY (GRADE 12)
61. An electrochemical cell is set up with a copper electrode in contact with 1.0 mol/L CuSO4(aq)
and a lead electrode in contact with 1.0 mol/L Pb(NO3)2(aq). The standard reduction potentials
are
Pb2+ +2e Pb E0red = - 0.13 V
Cu2+ + 2e Cu E0red = +0.34 V
At 25° C, the standard cell potential for this galvanic cell in volts is a.
62. What is the coefficient for hydroxide, and how many electrons are transferred after balancing
the reaction?
Pb(OH)42- (aq) + ClO -(aq) PbO2 (s) + Cl- (aq) ( Basic Medium )
-
A. 2 OH and 2 electrons C) 2 OH- and 4 electrons
-
B. 3 OH and 4 electrons D) 1 OH- and 2 electrons
A. Electrons flow in the external circuit toward the electrode represented by a positive sign
B. Anions move through the barrier/bridge toward the electrode where oxidation is occurring.
C. The electrode where reduction is occurring is represented by a positive sign.
D. Electrons flow in the external circuit from the cathode to the anode.
65. Which statement best describes the functions of a salt bridge in a voltaic cell?
A. Separate strong oxidizing agent from strong reducing agent; allow ions to pass through.
B. Separate strong oxidizing agent from strong reducing agent; allow electrons to pass through.
C. Allow contact between strong oxidizing agent from strong reducing agent; allow electrons to
pass through.
D. Allow contact between strong oxidizing agent from strong reducing agent; allow ions to pass
through.
66. Consider the reaction ; N2(g) + 3H2(g) 2NH3(g)
The reaction indicated above is thermodynamically spontaneous at 298 K and become non
spontaneous at higher temperature. Which of the following is true at 298 K?
CHAPTER TWO
ACID-BASE EQUILIBRIUM (GRADE 12)
70. Which of the following reactions corresponds to hydrolysis of NH4+ in water solution?
74. Potassium fluoride has a solubility of 92 g of KF in 100 g of water at 18 0C. Which of the
following mixture would form an unsaturated solution at 18 0C ?
A. Adding 35 g of KF to 25 g H2O
B. Adding 42 g of KF to 50 g H2O
C. Adding 145 g of KF to 150 g H2O
D. Adding 184 g of KF to 200 g of H2O
80. The principal source of the difference in the normal boiling points of ICl (97C; molecular
mass 162 amu) and Br2 (59C; molecular mass 160 amu) is
A. London-dispersion forces
B. dipole-dipole interactions
C. both hydrogen-bonding and dipole-dipole interactions
D. both dipole-dipole interactions and London dispersion forces
81. The following statements concern molecules that require resonance. Which is true?
) + ( ) → ( ) ∆ = − /
83. Which of the following ionic compounds has the smallest lattice energy?
84. When electrons in a molecule are not found between a pair of atoms but move throughout the
molecule, this is called
THE END
FURRA MODEL ACADEMY SCHOOL, HAWASSA
CHEMISTRY MODEL EXAMINATION FOR GRADE 12, MAY, 2011 Page 18