SECTION A [10 MARKS]

Question 1:
A. Choose the best answers:
i. Mole is SI unit of
a) Temperature
b) Amount of substance
c) Luminous intensity
d) Current
ii. What amount of H2O produced by combustion of 32g of methane
a) 36g
b) 18g
c) 72g
d) 90g
iii. The atomic mass of an element is usually fractional because:
a) Elements are mixture of allotropes
b) Elements are mixture of isotopes
c) Elements are mixture of isobars
d) Elements contain impurities
iv. What is the empirical formula of C2H2 and C6H6?
a) C2H2
b) C6H6
c) CH
d) C3H3
v. At what conditions Gay Lussac's law of gaseous volumes is considered?
a) Same amount of all the reactants and products only.
b) Same temperature only
c) Same pressure only
d) Same temperature and pressure.

B. Match the items in Column I with relevant items in Column II. [5]
Column I Column II
Ions having positive charge +7
The sum of oxidation number of all atoms in a -1
neutral molecule
Oxidation number of hydrogen ion +1
Oxidation number of fluorine in NaF 0
Ions having negative charge Cation

Anion

SECTION B[25 MARKS]

Question 2: [2]
Differentiate between molarity and molality.

Question 3: [2]
The molecular mass of an organic compound is 90 and its %age composition is C-26.6%; O=71.1% and
H=2.2%. Determine the molecular formula of the compound.

Question 4: [2]
Write short notes on :
(a) redox reactions
(b) oxidizing agents

Question 5: [3]
1.82 g. of glucose (molar mass-180) is dissolved in 25g of water. Calculate (a) the molality (b) mole
fraction of glucose and water

Question 6: [3]
Mention oxidation, reduction, oxidising agent and reducing agent in the following reactions.
(i)FeS2+O2→Fe2O3+SO2
(ii)NH3+O2→NO+H2O
(iii)SnO2+C →Sn+CO

Question 7: [3]
The reactions given below are redox reactions. Justify the reactions.
(i) CuO(s)+H2(g)→Cu(s)+H2O(g)
(ii) Fe2O3(s)+3CO(g)→2Fe(s)+3CO2(g)
(iii)4BCl3(g)+3LiAlH4(s)→2B2H6(g)+3LiCl(s)+3AlCl3(s)

Question 8: [5]
Balance the equation by oxidation method:
KMnO4 + H2SO4 + FeSO4 → K2SO4 + MnSO4 + Fe2(SO4)3 + H2O
MnO4- + C2O42– + H+ → CO2 + Mn+2 + H2O

(OR)

Balance the equation by ion electron method:

Al + NO3- → Al(OH)4- +NH3 in alkaline medium.
Cr2O7 2-(g) + SO2(aq) → Cr3+ + SO42-(aq) (in acidic medium)

Question 9: [5]
i. Write postulates of Dalton’s atomic theory [2]
ii. Copper oxide obtained by heating copper carbonate or copper nitrate contains copper and oxygen in the
same ration by mass. Which law is illustrated by this observation? State the law. [2]
iii. Define the law of multiple proportions. Explain it with one example [1]

(OR)

i. Briefly explain the difference between precision and accuracy [2]

ii.What do mean by molarity .Calculate the molarity of NaOH in the solution prepared by dissolving its 4
g in enough water to form 250 mL of the solution. [2]
iii.Define one mole? [1]