Final JEE - Main Exam April,2019/10-04-2019/Morning Session

FINAL JEE–MAIN EXAMINATION – APRIL,2019

(Held On Wednesday 10th APRIL, 2019) TIME : 9 : 30 AM To 12 : 30 PM
CHEMISTRY TEST PAPER WITH ANSWER & SOLUTION

1. The major product of the following reaction 2. A bacterial infection in an internal wound
grows as N'(t) = N0 exp(t), where the time t is
is : in hours. A dose of antibiotic, taken orally,
needs 1 hour to reach the wound. Once it
OH reaches there, the bacterial population goes
( )
ethyl formate 1equiv. dN
CH3CHCH2 CH2NH2 ¾¾¾¾¾¾¾
triethylamine
® down as = –5N2. What will be the plot of
dt
N0
vs. t after 1 hour ?
N
OH
N0 N0
(1) CH3CHCH 2CH2NHCHO
N N
(1) (2)

(2) CH3CH=CH–CH2NH2

O
O

H
EN (3)
N0
N
t(h)

t(h)
(4)
N0
N
t(h)

t(h)

(3) CH3CHCH2 CH2NH2 Official Ans. by NTA (1)

LL
Sol. From 0 to 1 hour, N' = N0 et
dN
From 1 hour onwards = –5N2
dt
OH So at t = 1 hour, N' = eN0
(4) CH 3–CH –CH=CH 2 dN
= –5N2
A

dt
Official Ans. by NTA (1) N t

ò
eN 0
N -2 dN = -5ò dt
1

OH ethyl formate (1equiv. )

Sol. ¾¾¾¾¾¾¾ ® 1 1
-
CH3–CH–CH2–CH2–NH2 N eN 0 = 5(t – 1)
triethylamine

N0 1
- = 5N0 (t – 1)
N e
OH O
N0 1
CH3–CH–CH2–CH2–NH–C–H = 5N0(t – 1) +
N e

N0 æ1 ö
as NH2 is a better nucleophile than OH. = 5N0t + ç - 5N 0 ÷
N èe ø
which is following y = mx + C

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Final JEE - Main Exam April,2019/10-04-2019/Morning Session

3. The correct order of catenation is : 6. Which of the following is a condensation

(1) C > Si > Ge » Sn (2) C > Sn > Si » Ge polymer ?
(3) Ge > Sn > Si > C (4) Si > Sn > C > Ge (1) Buna - S (2) Nylon 6, 6
Official Ans. by NTA (1) (3) Teflon (4) Neoprene
Sol. As we move down the group, bond strength Official Ans. by NTA (2)
decreases, thereby decreasing the catenation Sol. Nylon-6,6 is a condensation polymer of
tendency. hexamethylene diamine and adipic acid.
Hence the order is as expected Buna-S, Teflon and Neoprene are addition
C > Si > Ge » Sn polymer.
4. The oxoacid of sulphur that does not contain
7. At 300 K and 1 atmospheric pressure, 10 mL
bond between sulphur atoms is :
of a hydrocarbon required 55 mL of O 2 for
(1) H2S 4O6 (2) H2S 2O7
complete combustion and 40 mL of CO 2 is
(3) H2S 2O3 (4) H2S 2O4
formed. The formula of the hydrocarbon is :
Official Ans. by NTA (2) (1) C4H8 (2) C4H7Cl
Sol. H2S4O6 H2S4O7 (3) C4H10 (4) C4H6
O Official Ans. by NTA (4)
O O O

HO

HO
S
O
S

H2S2O3
S
S
S

OH
S
O
OH
HO

HO
S
O
EN
O

H2S2O4
O O
S–S
S
O
OH

OH
10
æ
è

æ
è
yö
4ø

yö
10 ç x + ÷
4ø
y
Sol. CxHy + ç x + ÷ O2 ¾® xCO2 + H2O
2

10x

O æ yö
By given data, 10 ç x + ÷ = 55 .... (1)
LL
H2S2O7 does not contain bond between sulphur è 4ø
atoms. 10x = 40 .... (2)
5. Consider the statements S1 and S2 : \ x = 4, y = 6 Þ C4H6
S1 : Conductivity always increases with 8. Ethylamine (C2H5NH2) can be obtained from
decrease in the concentration of electrolyte. N-ethylphthalimide on treatment with :
S2 : Molar conductivity always incrteases with
(1) NaBH4 (2) CaH2
A

decrease in the concentration of electrolyte.

(3) H2O (4) NH2NH2
The correct option among the following is :
(1) Both S1 and S2 are correct Official Ans. by NTA (4)
(2) S1 is wrong and S2 is correct
O
(3) S1 is correct and S2 is wrong
(4) Both S1 and S2 are wrong Sol. H 2N - NH 2
N–Et ¾¾¾¾® C2H5NH2
Official Ans. by NTA (2)
Sol. On dilution, no. of ions per ml decreases so O
conductivity decreases hence S1 is wrong.
reagent is NH2–NH2 byproduct will be
1000 ´ k
ÙM = O
C
On dilution C and k both decreases but effect N–H
of C is more dominating so Ù M increases N–H
hence S2 is right. O

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 Final JEE - Main Exam April,2019/10-04-2019/Morning Session

9. The isoelectronic set of ions is : 11. Match the refining methods (Column I) with
metals (Column II).
(1) N3–, Li +, Mg 2+ and O2– Column I Column II
(2) Li+, Na+, O2– and F– (Refining methods) (Metals)
(3) F–, Li +, Na+ and Mg2+ (I) Liquation (a) Zr
(II) Zone Refining (b) Ni
(4) N3–, O2–, F – and Na+ (III) Mond Process (c) Sn
Official Ans. by NTA (4) (IV) Van Arkel Method (d) Ga
Sol. N–3 ® 1s2 2s2 2p 6 (1) (I) – (b); (II) – (c); (III) – (d); (IV) – (a)
(2) (I) – (b); (II) – (d); (III) – (a); (IV) – (c)
Li+ ® 1s2
(3) (I) – (c); (II) – (a); (III) – (b); (IV) – (d)
Mg+2 ® 1s2 2s2 2p 6 (4) (I) – (c); (II) – (d); (III) – (b); (IV) – (a)
O–2 ® 1s2 2s2 2p 6 Official Ans. by NTA (4)
Sol. Liquation is used for Sn.
F – ® 1s2 2s2 2p6
Zone refining is used for Ga.
Na+ ® 1s2 2s2 2p 6 Mond's process is used for Ni.
N–3, O–2, F – and Na+ are isoelectronic Van arkel process is used for Zr.
12. Consider the following statements
10. The species that can have a trans-isomer is :
(a) The pH of a mixture containing 400 mL of

(1) [Pt(en)Cl2]
(3) [Zn(en)Cl 2]
Official Ans. by NTA (4)

Sol. (1) Cl
Pt en
EN
(en = ethane-1, 2-diamine, ox = oxalate)
(2) [Cr(en)2(ox)]+
(4) [Pt(en)2Cl2]2+
0.1 M H2SO4 and 400 mL of 0.1 M NaOH
will be approximately 1.3.
(b) Ionic product of water is temperature dependent.
(c) A monobasic acid with K a = 10 –5 has a
pH = 5. The degree of dissociation of this
acid is 50%.
(d) The Le Chatelier's principle is not applicable
to common-ion effect.
Cl
the correct statement are :
LL
no trans isomer possible because
bidentate ligand will be co-ordinating (1) (a), (b) and (d) (2) (a), (b) and (c)
only at 90° angle in square planar complex (3) (a) and (b) (4) (b) and (c)
Official Ans. by NTA (2)
Sol. (a) H2SO4 + 2NaOH ¾® Na2SO4 + 2H2O
+ 400×.1=40 400×.1=40
en
20 0
(2) Ox Cr
A

en 20 ´ 2 1 æ 1 ö
\ [H+] = = Þ pH = –log ç ÷
no trans isomer possible 800 20 è 20 ø
\ pH = 1.3 so (a) is correct
æ Kw2 ö DH é 1 1 ù
en (b) log ç Kw ÷ = 2.303R ê T - T ú
è 1 ø ë 1 2 û
(3) Zn
so ionic product of water is temp. dependent
Cl
Cl hence (b) is correct.
3
sp hybridized so no trans possible (c) Ka = 10–5, pH = 5 Þ [H+] = 10–5
ca 2 [H + ] . a
Ka = ( Þ K =
+2 1 - a) a (1 - a )
Cl +2
en -5
10 . a 1
en Cl \ 10–5 = ( Þ 1 – a = a Þ a = = 50%
(4) Pt en Pt 1- a ) 2
Cl
Cl en so (c) is correct.
trans and cis both are possible (d) Le-chatelier's principle is applicable to
common –Ion effect so option (d) is wrong
\ correct answer (2)

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Final JEE - Main Exam April,2019/10-04-2019/Morning Session

13. Major products of the following reaction are : 15. The major product of the following reaction is :
O
( )
CHO ¾¾¾¾
HI excess
®
( i ) 50% NaOH D
+ HCHO ¾¾¾¾¾
( ii ) H3O+
®
NC O
OH I
(1) CH3OH and HCO2H (1) (2)
NC I NC OH
CH2OH COOH
OH I
(2) and
(3) (4)
NC OH NC I
COOH Official Ans. by NTA (3)
(3) CH3OH and ALLEN Ans. (1)
O
HI(excess) OH
Sol. ¾¾¾¾ D
®
CH2OH
(4) HCOOH and

Sol.
Official Ans. by NTA (4)

CHO
+ HCHO ¾¾¾¾¾
()
i 50% NaOH
( ii ) H3OÅ
®
EN NC O
Phenolic –OH does not react with HI and

16. Amylopectin is composed of :

NºC

benzylic –O– having –CN attached will react

with HI by S N2 mechanism.

(1) a-D-glucose, C1–C4 and C1–C6 linkages

(2) a-D-glucose, C1–C4 and C2–C6 linkages
I

(3) b-D-glucose, C 1–C4 and C2–C6 linkages

(4) b-D-Glucose, C 1–C4 and C1–C6 linkages
LL
This is cross cannizaro reaction so more reactive
Official Ans. by NTA (1)
carbonyl compound is oxidized and less reactive Sol. Amylopetcin is a homopolymer of a-D-glucose
where C1–C4 linkage and C1 – C6 linkage are
CH2OH present.
is reduced so answer is + HCO2H 17. Consider the hydrates ions of Ti2+, V2+, Ti3+ and
Sc 3+ . The correct order of their spin-only
magnetic moments is :
A

14. The principle of column chromatography is : (1) Sc3+ < Ti3+ < Ti2+ < V2+
(1) Capillary action. (2) Ti3+ < Ti2+ < Sc3+ < V2+
(3) Sc3+ < Ti3+ < V2+ < Ti2+
(2) Gravitational force. (4) V2+ < Ti2+ < Ti3+ < Sc3+
Official Ans. by NTA (1)
(3) Differential adsorption of the substances on Sol. Ti+2 = 1s2 2s2 2p6 3s2 3p6 3d2
the solid phase. unpaired electrons = 2.
spin only magnetic moment (µ) = 2(2 + 2)
(4) Differential absorption of the substances on = 8 B.M
the solid phase. Ti+3 = 1s2 2s2 2p6 3s2 3p6 3d1
unpaired electrons = 1
Official Ans. by NTA (3)
µ= 1(1 + 2) = 3 B.M
Sol. Main principle of column chromatography is V+2 = 1s2 2s2 2p6 3s2 3p6 3d3
differential adsorption of the substance on the µ= 3(3 + 2) = 15 B.M
solid phase. Sc+3
= 1s2 2s2 2p6 3s2 3p6
µ=0
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 Final JEE - Main Exam April,2019/10-04-2019/Morning Session
–
18. A gas undergoes physical adsorption on a 20. During the change of O2 to O2 , the incoming
surface and follows the given Freundlich electron goes to the orbital :
adsorption isotherm equation (1) s* 2P z (2) p 2P y (3) p* 2P x (4) p 2P x
Official Ans. by NTA (3)
x Sol. Molecular orbital diagram of O2 is
= kp0.5 s*2pz
m
Adsorption of the gas increases with : p2p
*
p2p
*
x y
(1) Decrease in p and decrease in T 2p 2p
(2) Increase in p and increase in T p2px p2py
(3) Increase in p and decrease in T
(4) Decrease in p and increase in T s2pz

Official Ans. by NTA (3)

x
Sol. Freundlich adsorption isotherm = Kp0.5 s*
m 2s

2s 2s
x
so on increasing pressure, increases

19. Three complexes,

[CoCl(NH3)5]2+ (I),
[Co(NH3)5H2O]3+ (II) and
m

EN
physical adsorption decreases with increase in
temperature so option (3) is correct.

1s
s

s*
1s
2s

1s

[Co(NH3)6]3+ (III)
s
LL
absorb light in the visible region. The correct 1s

order of the wavelength of light absorbed by An incoming electron will go in p*2px orbital.
them is : 21. Increasing rate of SN1 reaction in the following
(1) (III) > (I) > (II) (2) (I) > (II) > (III) compounds is :
I I
(3) (II) > (I) > (III) (4) (III) > (II) > (I) MeO
Official Ans. by NTA (2)
A

Sol. A complex having strong field ligand has

tendency to absorb light of highest energy. (A) (B)

Among the three complexes. I I

[ Co(NH3 )6 ]+3 will absorb radiation of highest

H 3C H3 CO
energy and least wavelength.
(C) (D)
(1) (A) < (B) < (C) < (D)
[ Co(NH3 )5 H 2O] +3
has field weaker than the
(2) (B) < (A) < (D) < (C)
above compound and therefore absorb radiation (3) (B) < (A) < (C) < (D)
of lesser energy and more wavelength. (4) (A) < (B) < (D) < (C)
Official Ans. by NTA (3)
[ CoCl(NH 3 )5 ] +2 has the weakest field and Sol. Rate of SN' is directly proposional to stability
of first formed carbocation so answer is
therefore will absorb light of least energy and I I I –I I
highest wavelength. MeO
> > >
Strength of ligand NH3 > H2O > Cl. CH3O H3C
+M (D) +H (C) (A) (B)

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Final JEE - Main Exam April,2019/10-04-2019/Morning Session

22. Consider the following table : 24. The graph betweeen |y|2 and r(radial distance)
is shown below. This represents :-
Gas a/(k Pa dm6 mol–1) b/(dm3 mol–1)
A 642.32 0.05196
B 155.21 0.04136
2
C 431.91 0.05196 |y|

D 155.21 0.4382
r
a and b are vander waals constant. The correct (1) 3s orbital (2) 1s orbital
statement about the gases is : (3) 2p orbital (4) 2s orbital
(1) Gas C will occupy lesser volume than gas A;
Official Ans. by NTA (4)
gas B will be lesser compressible than gas D
(2) Gas C will occupy more volume than gas A; Sol. Graph of |y 2| v/s r, touches r axis at 1 point so
gas B will be lesser compressible than gas D it has one radial node and since at r = 0, it has
(3) Gas C will occupy more volume than gas A; some value so it should be for 's' orbital.
gas B will be more compressible than gas D \ n – l – 1 = 1 where l = 0 Þ n – 1 = 1
(4) Gas C will occupy lesser volume than gas A; \ n = 2 Þ '2s' orbital

Official Ans. by NTA (3)

Sol. · Gas A and C have same value of 'b' but
EN
gas B will be more compressible than gas D

different value of 'a' so gas having higher

value of 'a' have more force of attraction so
molecules will be more closer hence
25. At room temperature, a dilute soluton of urea
is prepared by dissolving 0.60 g of urea in
360 g of water. If the vapour pressure of pure
water at this temperature is 35 mmHg,
lowering of vapour pressure will be
(molar mass of urea = 60 g mol–1):-
occupy less volume. (1) 0.027 mmHg (2) 0.028 mmHg
LL
· Gas B and D have same value of 'a' but
(3) 0.017 mmHg (4) 0.031 mmHg
different value of 'b' so gas having lesser
value of 'b' will be more compressible. Official Ans. by NTA (3)
so option (3) is correct. Sol. Lowering of vapour pressure = p0 – p = p0.xsolute
23. The increasing order of the reactivity of the
0.6 / 60
following compounds towards electrophilic \ Dp = 35 ×
0.6 360
A

aromatic substitution reactions is :- +

60 18
Cl CH3 COCH3
.01 .01
= 35 × = 35 ´
.01 + 20 20.01
(I) (II) (III) = .017 mm Hg
(1) I < III < II (2) II < I < III 26. The synonym for water gas when used in the
(3) III < I < II (4) III < II < I production of methanol is :-
Official Ans. by NTA (3) (1) natural gas (2) laughing gas
Sol. Rate of aromatic electophilic substitution is (3) syn gas (4) fuel gas
Official Ans. by NTA (3)
CH3 Cl COCH3
Sol. water gas = CO + H2
> > is also called syn gas because it is used for
synthesis of methanol.
(II) (I) (III)
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 Final JEE - Main Exam April,2019/10-04-2019/Morning Session

27. A process will be spontaneous at all

Sol. CH3–CH–CH–CH3 ¾¾¾
CH3OH
¾®?
temperatures if :-
CH3 Br
(1) DH > 0 and DS < 0

(2) DH < 0 and DS > 0 In polar protic solvent SN1 mechanism is

(3) DH > 0 and DS > 0 favourable hence reaction complete via SN1

(4) DH < 0 and DS < 0 mechanism

Official Ans. by NTA (2)

Sol. DG = DH – TDS H
CH3–CH–CH–CH3 CH3–C–CH–CH3
for spontaneous process at all temp. DG < 0 and –Br
CH3 Br CH3
it is possible when DH < 0 and DS > 0.
Hydride
28. The major product of the following reaction shift
O–CH3
is :- CH3–OH
CH3–C–CH2–CH3 CH3–C–CH2–CH3

CH3
CH3–C–CH CH3 ¾¾¾
H Br
3
¾
® CH OH EN 29.
CH3
(solvolysis)
–H
+
CH3

The regions of the atmosphere, where clouds

form and where we line respectively, are :-

(1) Stratosphere and Troposphere

CH3
LL
(2) Troposphere and Stratosphere
(1) CH3–C–CH CH3
(3) Troposphere and Troposphere
H OCH3
(4) Stratosphere and Stratosphere

Official Ans. by NTA (3)

CH3
A

(2) CH3–C–CH = CH2 Sol. Troposphere is the lowest region of atmosphere

H bounded by Earth beneath and the stratosphere
above where most of the clouds form and where
life form exists.
CH3
30. The alloy used in the construction of aircrafts
(3) CH3–C–CH2CH3
is :-
OCH3
(1) Mg – Sn (2) Mg – Mn

CH 3 (3) Mg – Al (4) Mg – Zn
(4) CH3–C = CH CH3 Official Ans. by NTA (3)

Official Ans. by NTA (3) Sol. Mg – Al alloy is used for construction of

aircrafts.