10/01/2019

MORNING

Regd. Office : Aakash Tower, 8, Pusa Road, New Delhi-110005

Ph.: 011-47623456 Fax : 011-47623472

Time : 3 hrs.
Answers & Solutions M.M. : 360

for
JEE (MAIN)-2019
(Online CBT Mode)
(Physics, Chemistry and Mathematics)

Important Instructions :
1. The test is of 3 hours duration.

2. The Test consists of 90 questions. The maximum marks are 360.

3. There are three parts consisting of Physics, Chemistry and Mathematics having 30 questions in each part
of equal weightage. Each question is allotted 4 (four) marks for each correct response.

4. Candidates will be awarded marks as stated above in Instructions No. 3 for correct response of each
question. ¼ (one-fourth) marks will be deducted for indicating incorrect response of each question. No
deduction from the total score will be made if no response is indicated for a question in the answer sheet.

5. There is only one correct response for each question.

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 JEE (MAIN)-2019 (Online)

PHYSICS

1. To mop-clean a floor, a cleaning machine presses a 3. To get output ‘1’ at R, for the given logic gate circuit
circular mop of radius R vertically down with a total the input values must be
force F and rotates it with a constant angular speed
X
about its axis. If the force F is distributed uniformly
P R
over the mop and if coefficient of friction between the Y
mop and the floor is μ, the torque, applied by the Q
machine on the mop is
FR FR (1) X = 1, Y = 1 (2) X = 0, Y = 0
(1) (2)
2 3 (3) X = 1, Y = 0 (4) X = 0, Y = 1
FR 2
(3) (4) FR Answer (3)
6 3
Answer (4) Sol. A  ⎡⎢( x  y )  xy ⎤⎥
⎣ ⎦
F
Sol. P   xyxy
R 2 dx
R A  (x  y )
F 2

R 2
∫ 2x dx x Output is 1 when x = 1, y = 0
0
4. A solid metal cube of edge length 2 cm is moving in
f  2R 3
 a positive y-direction at a constant speed of 6 m/s.
3R 2 There is a uniform magnetic field of 0.1 T in the
2 positive z-direction. The potential difference between
 FR the two faces of the cube perpendicular to the x-
3
axis, is
2. Two electric dipoles, A, B with respective dipole
  (1) 12 mV (2) 2 mV
moments d A  4qaiˆ and dB  2qaiˆ are placed
on the x-axis with a separation R, as shown in the (3) 6 mV (4) 1 mV
figure Answer (1)
R Sol. E = vB
X
A B
= 0.6 V/m
The distance from A at which both of them produce
the same potential is V = Ed
2R 2R = 0.6 × 2 × 10–2
(1) (2)
2 1 2 1 = 12 mV
R R 5. A plano convex lens of refractive index μ1 and focal
(3) (4)
2 1 2 1 length f 1 is kept in contact with another plano
Answer (2) concave lens of refractive index μ2 and focal length
f2. If the radius of curvature of their spherical faces
1
Sol. V  is R each and f1 = 2f2, then μ1 and μ2 are related
d2
as
4qa 2qa
2
 (1) 2μ1 – μ2 = 1
x (R  x )2
(2) 3μ2 – 2μ1 = 1
x
(R  x ) 
2 (3) 2μ2 – μ1 = 1

2R (4) μ1 + μ2 = 3
x
 2 1  Answer (1)

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 JEE (MAIN)-2019 (Online)

1 1 Answer (1)
Sol.   1  1
f1 R
Sol. d  2RhT  2RhR
1 1
  2  1 = 42.33 + 22.6
f2 R
d  65 km
1 1
2(1  1)   2  1 9. A block of mass m is kept on a platform which starts
R R
g
21  2  1 from rest with constant acceleration upward, as
2
6. Using a nuclear counter the count rate of emitted
shown in fig. Work done by normal reaction on block
particles from a radioactive source is measured. At
in time t is
t = 0 it was 1600 counts per second and t = 8
seconds it was 100 counts per second. The count g
rate observed, as counts per second, at t = 6 m a=—
2
seconds is close to
(1) 400 (2) 360 3m g 2 t 2 m g 2t 2
(1) (2) 
8 8
(3) 150 (4) 200
Answer (4) m g 2t 2
(3) 0 (4)
8
N ⎛ 1600 ⎞
Sol. (2)  ⎜ ⎟ Answer (1)
⎝ 100 ⎠
N=4 mg
Sol. N  mg 
2
4t = 8
3mg
t=2s N
2
1600
Count Rate  = 200 1⎛ g ⎞ 2
(2)3 S t
2 ⎜⎝ 2 ⎟⎠
7. Water flows into a large tank with flat bottom at the
3mg g 2
rate of 10–4 m3s–1. Water is also leaking out of a w  t
2 4
hole of area 1 cm2 at its bottom. If the height of the
water in the tank remains steady, then this height is 3mg 2 2
w t
(1) 5.1 cm (2) 1.7 cm 8

(3) 2.9 cm (4) 4 cm 10. A magnet of total magnetic moment 102 iˆ A-m2 is

Answer (1) placed in a time varying magnetic field, Biˆ(cos t )

dh where B = 1 Tesla and ω = 0.125 rad/s. The work
Sol.   2gh done for reversing the direction of the magnetic
dt
moment at t = 1 second, is
a 2gh  Q
(1) 0.028 J (2) 0.007 J
104 2gh  104
(3) 0.014 J (4) 0.01 J
1
h Answer (BONUS)
2g
⎛ 1⎞
h  5.1 cm Sol. v i  MB cos ⎜ ⎟
⎝8⎠
8. A TV transmission tower has a height of 140 m and
⎛ 1⎞
the height of the receiving antenna is 40 m. What is v f  MB cos ⎜ ⎟
the maximum distance upto which signals can be ⎝8⎠
broadcasted from this tower in LOS (Line of Sight) ⎛ 1⎞
w  2MB cos ⎜ ⎟
mode? (Given : radius of earth = 6.4 × 106 m) ⎝8⎠
(1) 65 km (2) 80 km = 0.0198 J
(3) 40 km (4) 48 km None of the option given is correct.

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 JEE (MAIN)-2019 (Online)

11. A train moves towards a stationary observer with 13. In a Young’s double slit experiment with slit
speed 34 m/s. The train sounds a whistle and its separation 0.1 mm, one observes a bright fringe at
frequency registered by the observer is f1. If the
speed of the train is reduced to 17 m/s, the 1
angle rad by using light of wavelength λ1. When
frequency registered is f 2. If speed of sound is 40

f1 the light of wavelength λ2 is used a bright fringe is

340 m/s, then the ratio is seen at the same angle in the same set up. Given
f2
that λ1 and λ2 are in visible range (380 nm to 740
21 nm), their values are
(1)
20 (1) 380 nm, 500 nm (2) 625 nm, 500 nm
20 (3) 380 nm, 525 nm (4) 400 nm, 500 nm
(2)
19
Answer (2)
18
(3) Sol. d = m1 1
17
d = m2 2
19
(4)
18 0.1 103
d   109 nm
Answer (4) 40
⎛ 340 ⎞ 1
Sol. f1  f0 ⎜ ⎟ d   105  25  102 nm
⎝ 340  34 ⎠ 40
⎛ 340 ⎞ d is LCM of 1 and 2
f2  f0 ⎜ ⎟
⎝ 340  17 ⎠ 1 = 625 nm and 2 = 500 nm
f1 340  17 19
  [By observation]
f2 340  34 18
14. Three Carnot engines operate in series between a
12. In the given circuit the cells have zero internal heat source at a temperature T1 and a heat sink at
resistance. The currents (in amperes) passing temperature T4 (see figure). There are two other
through resistance R1 and R2 respectively, are reservoirs at temperature T2 and T3, as shown, with
T1 > T2 > T3 > T4. The three engines are equally
efficient if
R1 20  R 2 20 
T1
– + + – 1
10 V 10 V
T2
(1) 1, 2
(2) 0, 1 2

(3) 0.5, 0 T3

(4) 2, 2 3
Answer (3) T4
Sol.
2 1/3 2 1/3
20 
(1) T2  (T1T4 ) ; T3  (T1 T4 )
20 
I2
I1
(2) T2  (T13T4 )1/4 ; T3  (T1T43 )1/4
10V 10V
10 – I1 × 20 = 0 (3) T2  (T1T4 )1/2 ; T3  (T12T4 )1/3
I1 = 0.5 A
I2 × 20 = 0 (4) T2  (T12T4 )1/3 ; T3  (T1T42 )1/3

I2 = 0 Answer (4)

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 JEE (MAIN)-2019 (Online)

T2 T T 17. If the magnetic field of a plane electromagnetic wave

Sol.   1   1 3  1 4
T1 T2 T3 is given by (The speed of light = 3 × 108 m/s)

T2  T1T3 ⎡ ⎛ x ⎞⎤
B  100  10 6 sin ⎢2  2  1015 ⎜ t  ⎟ ⎥ , then the
⎣ ⎝ c ⎠⎦
T3  T2T4
1 1
maximum electric field associated with it is
T32  T1 2 T3 2 T4
3 1
(1) 6 × 104 N/C (2) 3 × 104 N/C
T3  T1 T4
2 2
(3) 4.5 × 104 N/C (4) 4 × 104 N/C
1
T3  ⎡⎣T1T42 ⎤⎦
3
Answer (2)
Sol. Em = CBm = 3 × 108 × 100 × 10–6 = 3×104 N/C
Similarly T2  T1 T4 
1
2 3

18. A homogeneous solid cylindrical roller of radius R and

15. In the cube of side ‘a’ shown in the figure, the vector mass M is pulled on a cricket pitch by a horizontal
from the central point of the face ABOD to the force. Assuming rolling without slipping, angular
central point of the face BEFO will be acceleration of the cylinder is
z
B E F 2F
(1) (2)
2mR 3mR
a
A H F 3F
G (3) (4)
O F 3mR 2mR
y

a
Answer (2)
Sol.
D a
x
F
1 ˆ ˆ 1 ˆ ˆ
(1) a( j  i ) (2) a(i  k ) f
2 2
F – f = Ma
1 ˆ ˆ 1 ˆ ˆ
(3) a( j  k ) (4) a(k  i )
2 2 MR 2 a
fR  
Answer (1) 2 R

Sol. P.V. of G =
a  ˆ ˆ
i k  f  Ma
2 2
a 3Ma
P.V. of H =  ˆj  kˆ   F
2 2
 a 2F
GH   ˆj  iˆ   a
2 3M
16. A 2 W carbon resistor is color coded with green, 2F
black, red and brown respectively. The maximum 
3MR
current which can be passed through this resistor is
19. A satellite is moving with a constant speed v in circular
(1) 20 mA (2) 0.4 mA orbit around the earth. An object of mass ‘m’ is
(3) 100 mA (4) 63 mA ejected from the satellite such that it just escapes
Answer (1) from the gravitational pull of the earth. At the time of
Sol. G B R Br ejection, the kinetic energy of the object is

Resistance = 50 × 102 ± 1% (1) 2mv2 (2) mv2

 = I 2R 1 3
(3) mv 2 (4) mv 2
2 = 5000 × I 2 2 2
Answer (2)
4
 I2
10000 1 2
Sol. U  2  mv
2 2
I
100 In order to escape U + K = 0
I = 20 mA K = mv2
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 JEE (MAIN)-2019 (Online)

20. A charge Q is distributed over three concentric Sol. Here   7.5 × 10–12 m
spherical shells of radii a, b, c (a < b < c) such
h h
that their surface charge densities are equal to one
= 
another. The total potential at a point at distance r mv 2mK
from their common centre, where r < a, would be
h2
 K=
Q( a  b  c ) Q 2m 2
(1) (2)
4 0 (a 2  b 2  c 2 ) 4 0 (a  b  c )
(6.6  1034 )2 ev
=
Q(a2  b 2  c 2 ) Q ab  bc  ca 2  9.1 1031  (7.5  1012 )2  1.6  1019
(3) (4)
4 0 (a3  b3  c 3 ) 12 0 abc
 25 keV
Answer (1) 23. A heat source at T = 103 K is connected to another

Sol. Q  4 a  b  c 
2 2 2 heat reservoir at T = 102 K by a copper slab which
is 1 m thick. Given that the thermal conductivity of
⎡ 4 a 2 4 b 2 4 c 2 ⎤ copper is 0.1 WK–1m–1, the energy flux through it in
1
V  ⎢   ⎥ the steady state is
4 0 ⎣ a b c ⎦
(1) 200 Wm–2 (2) 65 Wm–2
1 Q a  b  c 
  2
4 0  a  b 2  c 2  (3) 120 Wm–2 (4) 90 Wm–2

21. An insulating, thin rod of length l has a linear charge Answer (4)
x
density ( x )  0 on it. The rod is rotated about Q K [T1  T2 ] 0.1 900
l Sol.    90 w/ m2
A L 1
an axis passing through the origin (x = 0) and
perpendicular to the rod. If the rod makes n rotations 24. The density of a material is SI units is 128 kg m–3.
per second, then the time averaged magnetic In certain units in which the unit of length is 25 cm
moment of the rod is and the unit of mass is 50 g, the numerical value of
density of the material is
(1) πnρl 3 (2) nρl 3
(1) 640 (2) 410
 
(3) nl 3 (4) n l 3
4 3 (3) 40 (4) 16
Answer (3) Answer (3)

Sol. dm = dxn x 2 128kg 128 1000 128

Sol.   3
 3
 3  20 = 40

m ⎛ 100 ⎞ 50 4
0 n x 3 dx ⎜ 25 ⎟
⎝ ⎠
∫ dm  ∫ 
0
25. Two guns A and B can fire bullets at speeds
3 1 km/s and 2 km/s respectively. From a point on a
0 n  4 0 n
m=   horizontal ground, they are fired in all possible
 4 4
directions. The ratio of maximum areas covered by
22. In an electron microscope, the resolution that can be the bullets fired by the two guns, on the ground is
achieved is of the order of the wavelength of
(1) 1 : 4
electrons used. To resolve a width of 7.5 × 10–12 m,
the minimum electron energy required is close to (2) 1 : 8
(1) 100 keV (3) 1 : 2

(2) 1 keV (4) 1 : 16

(3) 500 keV Answer (4)

2 2 2
(4) 25 keV A R1,max ⎛ u12 ⎞ ⎛ 1⎞ 1
Sol. 1  2
 ⎜
⎜ u2 ⎟⎟  ⎜ 4 ⎟  16
Answer (4) A2 R2,max ⎝ 2⎠ ⎝ ⎠

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26. A parallel plate capacitor is of area 6 cm2 and a  12r 12

separation 3 mm. The gap is filled with three Sol.  = 
13r L 13L
dielectric materials of equal thickness (see figure)
 12
with dielectric constants K 1 = 10, K 2 = 12 and  L '   L'
K3 = 14. The dielectric constant of a material which 2 13L
when fully inserted in above capacitor, gives same 13 L
capacitance would be  L =
24
29. A string of length 1 m and mass 5 g is fixed at both
K1 K2 K3 3 mm ends. The tension in the string is 8.0 N. The string
is set into vibration using an external vibrator of
(1) 36 (2) 14
frequency 100 Hz. The separation between
(3) 12 (4) 4 successive nodes on the string is close to
Answer (3) (1) 33.3 cm (2) 10.0 cm
Sol. C = C1 + C2 + C3 (3) 16.6 cm (4) 20.0 cm
0K A 0K1A 0K2 A 0K3 A Answer (4)
  
d 3d 3d 3d
T 8 1
K1  K 2  K 3 10  12  14 Sol. v =  = 40 m/s
 K=   12  5  103
3 3
27. A uniform metallic wire has a resistance of 18 Ω and v 40
=   0.4m
is bent into an equilateral triangle. Then, the f 100
resistance between any two vertices of the triangle is 
Separation between successive nodes =
(1) 4 Ω (2) 12 Ω 2
(3) 8 Ω (4) 2 Ω = 0.2 m  20 cm

Answer (1) 30. A piece of wood of mass 0.03 kg is dropped from

the top of a 100 m height building. At the same
12  6
Sol. RAB = 4 time, a bullet of mass 0.02 kg is fired vertically
12  6 upwards, with a velocity 100 ms–1, from the ground.
The bullet gets embedded in the wood. Then the
6 6 maximum height to which the combined system
reaches above the top of the building before falling
below is (g = 10 ms–2)
A B
6 (1) 30 m (2) 40 m
28. A potentiometer wire AB having length L and (3) 20 m (4) 10 m
resistance 12r is joined to a cell D of emf ε and internal
Answer (2)

resistance r. A cell C having emf and internal
2 1 2 2
resistance 3r is connected. The length AJ at which the Sol. 100 – 10.t  100t  5t
galvanometer as shown in fig. shows no deflection is 2
 t=1s
+D– , r
Conservation of momentum
J O
A B  90 × 02 – 10 × 03 = v × 05
+ – G
C 1.8  0.3 1.5 150
, 3r  v= =  = 30 m/s
2 0  05 0  05 5
11 11
(1) L (2) L 302 30  30
12 24 s2 =  = 45 m
2  10 2  10
5 13
(3) L (4) L
12 24  Maximum height above the building
Answer (4) = 45 – 5 = 40 m

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 JEE (MAIN)-2019 (Online)

CHEMISTRY

1. The major product of the following reaction is 3. Consider the following reduction processes:
Zn2+ + 2e– → Zn(s); Eº = –0.76 V
CH3O
CH 2Cl Ca2+ + 2e– → Ca(s); Eº = –2.87 V
(i) AlCl3 (anhyd.)

(ii) H2O
Mg2+ + 2e– → Mg(s); Eº = –2.36 V
OCH3
Ni2+ + 2e– → Ni(s); Eº = –0.25 V
CH3
(1) The reducing power of the metals increases in the
order :
CH 3O (1) Ca < Mg < Zn < Ni (2) Ni < Zn < Mg < Ca
(2) (3) Ca < Zn < Mg < Ni (4) Zn < Mg < Ni < Ca
Answer (2)

Sol. As E 2 increases, reducing power increases.

CH3O M/M
(3)
EZn/Zn2 = 0.76 V

(4) CH3O ECa/Ca2 = 2.87 V

CH3 EMg/Mg2 = 2.36 V

Answer (2)
ENi/Ni2 = 0.25 V
Sol. MeO
CH2–Cl Ca > Mg > Zn > Ni
4. Consider the given plots for a reaction obeying
AlCl3
Arrhenius equation (0°C < T < 300°C) : (k and Ea are
rate constant and activation energy, respectively)
MeO +
MeO
+

k k

MeO

Ea T(°C)
2. The chemical nature of hydrogen peroxide is I II
(1) Oxidising and reducing agent in both acidic and Choose the correct option:
basic medium (1) I is wrong but II is right
(2) Oxidising and reducing agent in acidic medium, (2) Both I and II are correct
but not in basic medium
(3) Both I and II are wrong
(3) Reducing agent in basic medium, but not in
acidic medium (4) I is right but II is wrong
(4) Oxidising agent in acidic medium, but not in Answer (2)
basic medium
Sol. K  AeEa/RT
Answer (1)
Sol. H2O2 can act as both oxidising as well as reducing So, as Ea increases, K decreases.
agent in both acidic as well as basic medium. and as T increases, K increases.

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 JEE (MAIN)-2019 (Online)

5. The electronegativity of aluminium is similar to Sol. PA° = 7 × 103

(1) Beryllium (2) Carbon PB° = 12 × 103
(3) Lithium (4) Boron XA = 0.4
Answer (1) XB = 0.6
Sol. Be and Al show diagonal relationship.
 P = (7 × 0.4 + 12 × 0.6) × 103 = 104
Kp
6. The values of for the following reactions at PA = 2.8 × 103, PB = 7.2 × 103
Kc
300 K are, respectively (At 300 K, RT = 24.62 dm3  YA = 0.28, YB = 0.72
atm mol–1) 8. If dichloromethane (DCM) and water (H2O) are used


N2(g) + O2(g) 
 2NO(g) for differential extraction, which one of the following

 statements is correct?
N2O4(g) 
 2NO2(g)

 (1) DCM and H2O will make turbid/colloidal mixture
N2(g) + 3H2(g) 
 2NH3(g)
(2) DCM and H2O will be miscible clearly
(1) 24.62 dm3 atm mol–1, 606.0 dm6 atm2 mol–2,
1.65 × 10–3 dm–6 atm–2 mol2 (3) DCM and H2O would stay as upper and lower
layer respectively in the separating funnel (S.F.)
(2) 1, 24.62 dm 3 atm mol –1 , 1.65 × 10 –3 dm –6
atm–2 mol2 (4) DCM and H2O would stay as lower and upper
layer respectively in the S.F.
(3) 1, 24.62 dm3 atm mol–1, 606.0 dm6 atm2 mol–2
Answer (4)
(4) 1, 4.1 × 10–2 dm–3 atm–1 mol, 606 dm6 atm2 mol–2
Sol. Density of dichloromethane is greater than water.
Answer (2)
So, DCM would be the lower layer and water will
KP ng form the upper layer in the separating funnel.
Sol. K  RT 
C 9. The type of hybridisation and number of lone pair(s)

 of electrons of Xe in XeOF4, respectively, are
 2NO(g), ng = 0
N2(g) + O2(g) 
(1) sp3d and 2 (2) sp3d2 and 2
KP
1 (3) sp3d2 and 1 (4) sp3d and 1
KC
Answer (3)


 2NO2(g), ng = 1
N2O4(g) 
O
KP F F
 24.62 Sol. Xe , sp3d2, Lone pair = 1
KC F F


 2NH3(g), ng = –2
N2(g) + 3H2(g)  10. Wilkinson catalyst is (Et = C2H5)
KP 1
  1.65  103 (1) [(Ph3P)3IrCl] (2) [(Ph3P)3RhCl]
K C  24.62 2
(3) [(Et3P)3IrCl] (4) [(Et3P)3RhCl]
7. Liquids A and B form an ideal solution in the entire
Answer (2)
composition range. At 350 K, the vapor pressures of
pure A and pure B are 7 × 103 Pa and 12 × 103 Pa, Sol. Wilkinson's catalyst is [Rh(PPh3)3]Cl
respectively. The composition of the vapor in
11. The metal used for making X-ray tube window is
equilibrium with a solution containing 40 mole
percent of A at this temperature is (1) Ca

(1) xA = 0.76; xB = 0.24 (2) Na

(2) xA = 0.37; xB = 0.63 (3) Mg
(3) xA = 0.28; xB = 0.72 (4) Be
(4) xA = 0.4; xB = 0.6 Answer (4)
Answer (3) Sol. Be is used in making X-ray tube windows.

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12. The major product ‘X’ formed in the following reaction 14. The total number of isotopes of hydrogen and number
is of radioactive isotopes among them, respectively, are

O O (1) 2 and 1 (2) 3 and 2

|| ||
CH2—C—OCH3 (3) 2 and 0 (4) 3 and 1
NaBH4
X Answer (4)
MeOH
Sol. There are three isotopes of H out of which only
OH tritium is radioactive.
|
CH2CH2OH
15. The increasing order of the pK a values of the
(1)
following compounds is
OH OH OH OH
OH O
| ||
CH2—C—OCH3
NO2
(2)
NO 2 OMe
A B C D
O O (1) D < A < C < B (2) B < C < D < A
|| ||
CH2—C—H (3) B < C < A < D (4) C < B < A < D
(3)
Answer (3)
Sol. Acidic strength
OH
| OH OH OH OH
CH2CH2OH
(4)
> > >
NO2
Answer (2) NO 2 OMe
(B) (C) (A) (D)
Sol. NaBH4 selectively reduces the ketone, it does not
affect alkene and ester.  pKa : B < C < A < D

O
16. The total number of isomers for a square planar
O complex [M(F)(Cl)(SCN)(NO2)] is
CH2 – C – OCH 3
NaBH 4
(1) 8 (2) 12
MeOH
(3) 4 (4) 16
O
OH
CH2 – C – OCH 3 Answer (2)
Sol. F Cl F Cl F Cl F Cl
M M M M
O2N SCN O2N NCS ONO NCS ONO SCN
13. Hall-Heroult’s process is given by
F Cl NO 2 Cl ONO Cl F Cl
M M M M
Coke, 1673K
(1) ZnO  C   Zn  CO NCS NO 2 F NCS F NCS NCS ONO
NCS Cl F Cl F Cl ONO Cl
(2) Cr2O3 + 2Al → Al2O3 + 2Cr M M M M
F NO 2 SCN NO 2 SCN ONO F SCN
(3) 2Al2O3 + 3C → 4Al + 3CO2  Answer is 12.
(4) Cu2+(aq) + H2(g) → Cu(s) + 2H+(aq) 17. Which of the following is not an example of
Answer (3) heterogeneous catalytic reaction?

Sol. Hall Heroult’s process is used in extraction of Al (1) Combustion of coal

from Alumina. (2) Ostwald’s process
Cathode : Al3+ + 3e–  Al (3) Hydrogenation of vegetable oils
Anode : C+ 2O2–  CO2 + 4e (4) Haber’s process

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Answer (1) 20. Which dicarboxylic acid in presence of a dehydrating

agent is least reactive to give an anhydride?
Sol. C + O2  CO2 No catalyst
COOH CO 2H
Ostwald process : (1) (2)
Pt/Rh
COOH CO 2H
4NH3  5O2   4NO  6H2O
O
Haber’s process CH2
CH2 COOH CH2 OH
Fe
N2  3H2   2NH3 (3) (4)
CH2 COOH CH2 OH
18. A process had ∆H = 200 Jmol–1 and S = 40 JK–1 CH2
mol–1. Out of the values given below, choose the O
minimum temperature above which the process will Answer (3)
be spontaneous. CH2 O

(1) 4 K (2) 12 K CH2 COOH 

Sol. + CO 2 + H2 O
CH2 COOH
(3) 5 K (4) 20 K
CH2
Answer (3) This compound does not form anhydride.
Sol. H = 200 J mol–1 21. Which of the graphs shown below does not
represent the relationship between incident light and
S = 40 JK–1 mol–1
the electron ejected from metal surface?
For spontaneous reaction,

H K.E.
T of e s
S

200
T 5K (1)
40
0 Energy of
So, minimum temperature is 5 K
Light
19. The major product of the following reaction is

Br Number
KOH alc (excess) of e s

Ph
Br (2)
0 Frequency of
Light
(1)
Ph
K.E.
(2) of e s
Ph

(3)
(3) 0 Intensity of
Ph LIght

(4) K.E.
Ph
of e s
Answer (2)

Br (4)
KOH alc. (excess)
Sol. Ph 
0 Frequency of
Ph
Br Light
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Answer (4)
Sol. NaNO2 (+)
NH2 CH2
Sol. hincident  h th  KE aqHCl

KE is independent of intensity and number of

photoelectrons does not depend on frequency of light. ring expansion

 KE = hincident – h th

22. Which hydrogen in compound (E) is easily OH

(+)
replaceable during bromination reaction in presence
of light?

CH3  CH2  CH  CH 25. The correct structure of product ‘P’ in the following
   
reaction is
(E)
NEt
(1) γ-hydrogen (2) α-hydrogen Asn  Ser  (CH3 CO)2 O 
3
P
(excess)
(3) δ-hydrogen (4) β-hydrogen
OCOCH 3
Answer (1) O O
|| ||
H
h
Sol. CH3 – CH2 – CH  CH2  Br2  (1) H3C N || N OH
 H O NHCOCH 3
||
CH3 – CH– CH  CH2 O
|
Br O
||
NHCOCH 3
23. Water filled in two glasses A and B have BOD O O
values of 10 and 20, respectively. The correct || ||
N
statement regarding them, is (2) H3C N || H OH
H O
(1) Both A and B are suitable for drinking OCOCH 3
(2) A is suitable for drinking, whereas B is not OCOCH 3
O O
|| H ||
(3) B is more polluted than A N
H 3C N || OH
(4) A is more polluted than B (3) H O NH2
Answer (3) ||
O
Sol. As B.O.D. increase, level of pollution in water O
increases. ||
NH 2
24. The major product formed in the reaction given below O O
|| H ||
will be N
(4) H3C N || OH
H O
NH2 NaNO 2 OCOCH 3
Aq.HCl, 0–5°C
Answer (4)

NO 2 H
OH
(1) (2) Sol. Asn  NH2 – C – CH2 – C – COOH
O NH2
OH
NO2
(3) (4) H
Ser  HO – CH2 – C – COOH
Answer (No option is correct) NH2

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Asn – Ser 28. Two pi and half sigma bonds are present in

H (1) O2 (2) O2

 NH2 – C – CH2 – C – C – N – C – CH2 – OH
(3) N2 (4) N2
O NH2 O COOH
Answer (3)

Excess(CH3CO)2O Sol. N2  1s 2  *1s 2  2s 2  *2s 2  2 p 2   2 p 2  2 p1

y x z

B.O. 2.5 = 2 bond + 0.5 bond

H H
29. Which primitive unit cell has unequal edge lengths
NH2 – C – CH2 – C – C – NH – C – CH2 – O – CO –CH3 (a ≠ b ≠ c) and all axial angles different from 90°?
O CH3CONH O COOH (1) Hexagonal (2) Monoclinic
26. The effect of lanthanoid contraction in the lanthanoid (3) Triclinic (4) Tetragonal
series of elements by and large means
Answer (3)
(1) Increase in atomic radii and decrease in ionic
Sol. For triclinic Crystal
radii
a  b  c Axial distance
(2) Decrease in atomic radii and increase in ionic
radii       90 Axial angle

(3) Decrease in both atomic and ionic radii 30. The decreasing order of ease of alkaline hydrolysis
for the following esters is
(4) Increase in both atomic and ionic radii
Answer (3) COOC 2H5
Sol. Due to lanthanoid contraction, size of atom as well
I
as ion of lanthanoid decrease
27. A mixture of 100 m mol of Ca(OH)2 and 2 g of sodium Cl COOC 2H 5
sulphate was dissolved in water and the volume was
made up to 100 mL. The mass of calcium sulphate II
formed and the concentration of OH– in resulting
solution, respectively, are (Molar mass of Ca(OH)2, O2N COOC2H5
Na2SO4 and CaSO4 are 74, 143 and 136 g mol–1,
III
respectively; Ksp of Ca(OH)2 is 5.5 × 10–6)
(1) 1.9 g, 0.14 mol L–1 (2) 13.6 g, 0.28 mol L–1 CH 3O COOC 2H 5
(3) 13.6 g, 0.14 mol L–1 (4) 1.9 g, 0.28 mol L–1
IV
Answer (4) (1) III > II > IV > I (2) IV > II > III > I

Sol. Na2SO 4  Ca  OH2  CaSO 4  2NaOH (3) II > III > I > IV (4) III > II > I > IV
Answer (4)
2  1000
mmol of Na2SO4 =  13.98 m Mol Sol. Rate of reaction  positive charge on carbonyl
143 carbon so E.W.G. increase rate while E.D.G.
mmol of CaSO4 formed = 13.98 m Mol decrease the rate.
Mass of CaSO4 formed = 13.98 × 10–3 × 136 = 1.90 g
O2N C – OC2H5 > Cl COOC2H5
mmol of NaOH = 28 mmol
O
2 –
Ca(OH)2  Ca  2OH III > II >
S 2S0.28

Value of ‘S’ will be negligible so COOC2H5 > MeO COOC2H5

0.028
[OH–] =  0.28mol L–1
0.1 I > IV

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MATHEMATICS

1. Let d  R, and Equation of tangent at A to the given circle :

3x – 4y – 7 = 0 ....(1)
⎡ 2 4d (sin )  2 ⎤
⎢
A⎢1 (sin )  2 d ⎥ The required circle is tangent to (1) at (1, –1).
⎥,
⎢⎣ 5 (2sin )  d (  sin )  2  2d ⎥⎦  (x – 1)2 + (y + 1)2 +  (3x – 4y – 7) = 0 ....(2)

  [0, 2]. If the minimum value of det(A) is 8, then (2) Passes through B(4, 0)
a value of d is  32 + 12 + (12 – 7) = 0 5 + 10 = 0   = –2

(1) –5 (2) 2( 2  1) (2) Becomes x2 + y2 – 8x + 10y + 16 = 0

(3) –7 (4) 2( 2  2)
radius =  –4 2   5 2 – 16  5
Answer (1)
Sol. 20 3
20⎛ Ci 1 ⎞ k
3. If ∑ ⎜⎜ 20 20
⎟⎟  , then k equals
–2 4d sin   2 i 1 ⎝ Ci  Ci 1 ⎠ 21
det  A   1 sin   2 d
(1) 400 (2) 100
5 2sin   d – sin   2  2d
(3) 200 (4) 50
Answer (2)
–2 4d sin   2
 1 sin   2 d Sol.
1 0 0 20 20
i !  21– i  !
Ci –1 Ci –1 20!
  
= d(4 + d) – (sin2 – 4)
20
Ci  20
Ci –1 20
Ci  i – 1!  21– i ! 21!

 det (A) = d2 + 4d + 4 – sin2 = (d + 2)2 – sin2

3
min det (A) is attained when sin2 = 1 ⎛
20 20
Ci –1⎞ 20
⎛ i ⎞
3
1 20 3
 ∑⎜ ⎟⎟  ∑ ⎜⎝ 21⎟⎠  ∑i
⎜
 (d + 2)2 –1 = 8  (d + 2)2 = 9  d + 2 = +3 i 1 ⎝
20 20
Ci  Ci –1 ⎠ i 1  213 i 1
 d = –5 or 1
2
2. If a circle C passing through the point (4, 0) touches 1 ⎛ 20  21 ⎞ 100
 
3 ⎜ ⎟  21
the circle x2 + y2 + 4x – 6y = 12 externally at the  21 ⎝ 2 ⎠
point (1, –1), then the radius of C is
(1) 5 (2) 2 5  K = 100
4. The sum of all two digit positive numbers which when
(3) 57 (4) 4
divided by 7 yield 2 or 5 as remainder is
Answer (1)
(1) 1465 (2) 1356
Sol.
(3) 1365 (4) 1256
Answer (2)
B(4,0)
A Sol.
(–2,3)
S = 16 + 23 + 30+......+93 = 654
S = 12 + 19 + 26+.....+96 = 702
Required Sum = 654 + 702
Let A = (1, –1) & B = (4, 0) = 1356

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6. Consider a triangular plot ABC with sides AB = 7 m,

dy 3 1 ⎛   ⎞
5. If  2
y 2
,x ⎜ , ⎟ and BC = 5 m and CA = 6 m. A vertical lamp-post at the
dx cos x cos x ⎝ 3 3⎠ mid point D of AC subtends an angle 30° at B. The
height (in m) of the lamp-post is
⎛⎞ 4 ⎛ ⎞
y ⎜ ⎟  , then y ⎜  ⎟ equals (1) 2 21 (2) 7 3
⎝4⎠ 3 ⎝ 4⎠
2 3
(3) 21 (4) 21
1 1 3 2
(1)  e6 (2)  e3
3 3 Answer (3)
Sol.
1 4
(3) (4)  B
3 3
5 7
Answer (1) m

Sol. C 3 D 3 A
By Appolonius Theorem,
dy
 sec 2 x 1– 3 y  ⎛ 2
dx ⎛ AC ⎞ ⎞
2 ⎜ BD 2  ⎜ ⎟ ⎟  BC 2  AB 2
⎜ ⎝ 2 ⎠ ⎟⎠
⎝
dy 2
⇒ ∫ 1– 3y   ∫ sec x dx
 
⇒ 2 m 2  32  25  9 ⇒ m  2 7

height of lamppost
1 tan30 
⇒ – ln 1– 3y  tan x  C BD
3
1 2 21
⇒ Height  2 7  
⎛⎞ 4 3 3
y⎜ ⎟ 
⎝4⎠ 3 b
7. Let I  ∫ ( x 4  2 x 2 )dx. If I is minimum then the
1  a
⇒– ln 1 – 4  tan  C
3 4 ordered pair (a, b) is

(1) (  2,0) (2) (0, 2)

1 1
⇒ – ln 3  C  1 ⇒ C  –1– ln3
3 3 (3) ( 2,  2) (4) (  2, 2)
Answer (4)
 Sol.
x
4
b

I  ∫ x 4 – 2 x 2 dx 
1 ⎛ ⎞ a
⇒ – ln 1– 3y  tan ⎜ – ⎟  C  –1  C
3 ⎝ 4⎠
dI
⇒  x 4 – 2 x 2  0 ⇒ x  0,  2
dx
1
 –1– 1– ln3
3 b
⎡ x 5 2x 3 ⎤ 3⎛x
2
2⎞
Also, I  ⎢ – ⎥  x ⎜⎜ – ⎟
⎟
 ln |1 – 3y| = 6 + ln3 ⎣⎢ 5 3 ⎥⎦
a ⎝ 5 3⎠

1 1 1 |I| is maximum when b  – 2 and a  2

⇒ ln –y 6 ⇒ – y  e6 ⇒ y   e6
3 3 3  I is minimum when (a, b)  – 2 , 2  
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8. An unbiased coin is tossed. If the outcome is a 10. If the line 3x + 4y – 24 = 0 intersects the x-axis at
head then a pair of unbiased dice is rolled and the the point A and the y-axis at the point B, then the
sum of the numbers obtained on them is noted. If the incentre of the triangle OAB, where O is the origin
toss of the coin results in tail then a card from is
a well-shuffled pack of nine cards numbered (1) (4, 3) (2) (3, 4)
1, 2, 3, ..., 9 is randomly picked and the number on
the card is noted. The probability that the noted (3) (4, 4) (4) (2, 2)
number is either 7 or 8 is Answer (4)
Sol.
13 15
(1) (2)
36 72
y
B (0, 6)
19 19
(3) (4) 6–r
36 72 6–r
8–r
Answer (4) r (r, r)
r
Sol. X
O(0,0)
8–r A (8, 0)
11 8
P (7 or 8 is the sum of two dice) =
36
8 – r + 6 – r = 10
2
P (7 or 8 is the number of card) =  2r = 4
9
 r=4
1 11 1 2  Incentre = (2, 2)
Required probability =   
2 36 2 9
11. If the third term in the binomial expansion of

1 ⎛ 11  8 ⎞ 19 (1  x log2 x )5 equals 2560, then a possible value of x


2 ⎜⎝ 36 ⎟⎠ 72
=
is

9. Consider the quadratic equation (c – 5)x2 – 2cx + 1

(1) 2 2 (2)
(c – 4) = 0, c  5. Let S be the set of all integral 4
values of c for which one root of the equation lies in
1
the interval (0, 2) and its other root lies in the interval (3) 4 2 (4)
8
(2, 3). Then the number of elements in S is
Answer (2)
(1) 11 (2) 18
(3) 12 (4) 10 Sol: Third term of (1  x log2 x )5  5C ( x log2 x )2
2

Answer (1)
given, 5C ( x log2 x )2  2560
2
Sol.
f(0).f(3) > 0 and f(0).f(2) < 0 ⇒ ( x log2 x )2  256  ( 16)2
 (c – 4) (4c – 49) > 0 and (c – 4) (c – 24) < 0
⇒ x log2 x  16 or x log2 x  16 (rejected)
⎛ 49 ⎞
 c   – , 4  U ⎜ ,  ⎟ and c   4, 24 
⎝ 4 ⎠ ⇒ x log2 x  16 ⇒ log2 x log2 x  log2 16  4

⎛ 49 ⎞ ⇒ log2 x   2 ⇒ x  22 or 22
 c  ⎜ ,24 ⎟
⎝ 4 ⎠
1
⇒ x4 or
 S = {13, 14, ......, 23} 4

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12. Let z1 and z2 be any two non-zero complex numbers

⇒ x42  x52  97 ...(2)
3z 2z
such that 3|z1| = 4|z2|. If z  1  2 then
2z2 3z1  24 x5  132  97  72 ⇒ x4 x5  36 ...(3)

5 4 9
(1) Im(z) = 0 (2) | z | (1) and (3) ⇒ x4 : x5  or
2 9 4

1 17 ⎪⎧max{| x |, x 2 }, | x |  2 ⎫⎪
(3) | z |  (4) Re(z) = 0 14. Let f ( x )  ⎨ ⎬
2 2 ⎩⎪ 8  2 | x |, 2  | x |  4 ⎭⎪
Answer (No option Matches)
Let S be the set of points in the interval (–4, 4) at
Sol: Let z1  r1e i i
and z2  r2e which f is not differentiable. Then S
(1) Equals {–2, –1, 0, 1, 2}
3 | z1 |  4 | z2 | ⇒ 3r1  4r2
(2) Equals {–2, 2}
3z1 2z2 3 r1 2 r2 i ( )
z   ei ( )  r (3) Is an empty set
2z2 3z1 2 r2 3 r1
(4) Equals {–2, –1, 1, 2}
3 4 Answer (1)
  (cos(  )  i sin(  )) 
2 3 Sol: y
2 3 y = x 2 y = x2
 [cos(  )  i sin(  )] y = 8 – 2|x|
y = 8 – 2|x|
3 4 y = |x|

⎛ 1⎞ ⎛ 1⎞
z  ⎜ 2  ⎟ cos(  )  i ⎜ 2  ⎟ sin(  ) x
⎝ 2 ⎠ ⎝ 2 ⎠ –4 –2 –1 1 2 4
25 9
 | z | cos 2(  )  sin2 (  )
4 4
Clearly, S = {–2, –1, 0, 1, 2}
34 15. Consider the statement : “P(n) : n2 – n + 41” is
  2cos 2(  )
8 prime.” Then which one of the following is true?
3 5 (1) P(5) is false but P(3) is true
  z 
2 2
(2) P(3) is false but P(5) is true
13. The mean of five observations is 5 and their variance
is 9.20. If three of the given five observations are 1, (3) Both P(3) and P(5) are false
3 and 8, then a ratio of other two observations is (4) Both P(3) and P(5) are true
(1) 4 : 9 (2) 6 : 7 Answer (4)
(3) 10 : 3 (4) 5 : 8 Sol: P(n) = n2 – n + 41
Answer (1)
 P(3) = 9 – 3 + 41 = 47
Sol: x1 + x2 + x3 + x5 = 25
P(5) = 52 – 5 + 41 = 61
x1 + x2 + x3 = 1 + 3 + 8 = 12
Both 47 and 61 are prime
 x4 + x5 = 25 – 12 = 13 ...(1)
16. A point P moves on the line 2x – 3y + 4 = 0.
5 If Q(1, 4) and R(3, –2) are fixed points, then the
∑ xi2 5
locus of the centroid of PQR is a line
i 1
5
 (5)2  9.2 ⇒ ∑ xi2  5(25  9.2) (1) Parallel to y-axis (2) With slope
3
i 1 2

= 125 + 46 = 171 2
(3) With slope (4) Parallel to x-axis
3
⇒ (1)2  (3)2  (8)2  x42  x52  171 Answer (3)

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Sol: P(h, k) ⎛ ⎞
18. The sum of all values of   ⎜ 0, ⎟ satisfying
⎝ 2⎠
3
sin2 2  cos4 2  is
G() 4

Q(1, 4) R(3, –2) 5 

(1) (2)
4 2
Let centroid G be (, )
we have 3 = 1 + 3 + h h =3 – 4 3
(3) (4) 
3 = 4 – 2 + k k = 3 – 2 8
but P(h, k) lies on 2x – 3y + 4 = 0 Answer (2)
2(3 – 4) – 3 (3 – 2) + 4 = 0
2 4 3
6 – 9 – 8 + 6 + 4 = 0 Sol: sin 2  cos 2 
4
6 – 9 + 2 = 0
Locus: 6x – 9y + 2 = 0 2 4 3
 1  cos 2  cos 2 
4
6 2
Slope  
9 3
1
 cos 2 1  cos 2  
2 2
...(1)
17. If the parabolas y2 = 4b(x – c) and y2 = 8ax have a 4
common normal, then which one of the following is
2
a valid choice for the ordered triad (a, b, c)? ⎛ cos2 2  1  cos2 2 ⎞
But  cos 21 cos 2  ⎜
2 2
⎟
⎝ 2 ⎠
⎛1 ⎞ ⎛1 ⎞
(1) ⎜ ,2,0 ⎟ (2) ⎜ ,2,3 ⎟
⎝2 ⎠ ⎝ 2 ⎠ 1
 ...(2)
(3) (1, 1, 0) (4) (1, 1, 3) 4

Answer (4) Equation (1) and (2)

Sol: Note: x-axis is a common normal. Hence all the cos22 = 1 – cos22
options are correct for m = 0.
Normal to y2 = 8ax is 1
cos22 =
y = mx – 4am – 2am3 ...(1) 2

Normal to y2 = 4b (x – c) with slope m is

1
y = m(x – c) – 2bm – bm3 ...(2) cos2 = ±
2
(1) and (2) are identical
 4am + 2am3 = cm + 2bm + bm3  3
   ,
8 8
 4a + 2am2 = c + 2b + bm2 or m = 0
 4a – c – 2b = (b – 2a) m2
 3 
Sum   
or (X-axis is common normal always) 8 8 2

4a  2b  c c
⇒ m2   2 
b  2a b  2a
19. The equation of a tangent to the hyperbola
4x2 – 5y2 = 20 parallel to the line x – y = 2 is
c c
m2  0 ⇒  2  0 ⇒ 20
b  2a b  2a (1) x – y + 7 = 0 (2) x – y + 1 = 0

(3) x – y – 3 = 0 (4) x – y + 9 = 0
c
only (1, 1, 3) satisfies 20
b  2a Answer (2)

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Sol: Slope, m = 1 = 10  45  9  3  27  2

x2 y 2 =     18
 1
5 4
a2 = 5, b2 = 4 1 5 1
 2  1 9 3  9  3  5(  3)  1(  9)
y  mx  a2m 2  b2 1  

= x 54 = 9  3  5  15    9
y=x±1
= 4  2  6
20. Let f : R  R be a function such that f(x) = x3 +
x2f (1) + xf(2) + f (3), x  R. Then f(2) equals
1 1 5
(1) 8 (2) –4 3  1 2 9  2  27    9  5    13
(3) –2 (4) 30 1 3 
Answer (3)
 for infinitely many solutions
Sol: Let f(x) = x3 + ax2 + bx + c
1 = 2 = 3 =  = 0
f(x) = 3x2 + 2ax + b f (1) = 3 + 2a + b
  = 5,  = 13   –  = 8
f(x) = 6x + 2a f(2) = 12 + 2a
f(x) = 6  f(3) = 6 ⎛3 ⎞
22. The shortest distance between the point ⎜ ,0 ⎟ and
∵ f(x) = x3 + f(1)x2 + f(2) x + f(3) ⎝2 ⎠
the curve y  x ,( x  0), is
 f(1) = a  3 + 2a + b = a  a + b = – 3 ...(1)
 f(2) = b  12 + 2a = b  2a – b = – 12 ...(2) 3 5
(1) (2)
From (1) and (2) 2 4

3a = – 15  a = – 5 b = 2
3 5
 f(x) = x3 – 5x2 + 2x + 6 (3)
2
(4)
2
 f(2) = 8 – 20 + 4 + 6 = –2
Answer (4)
21. If the system of equations
Sol.
x+y+z=5 y
y  x ⇒y2  x
x + 2y + 3z = 9
x + 3y + z = 
⎛1 t⎞
has infinitely many solutions, then  –  equals P ⎜ t2, ⎟
⎝4 2⎠
(1) 18 (2) 21
x
(3) 8 (4) 5 ⎛3 ⎞
A⎜ , 0 ⎟
Answer (3) ⎝2 ⎠

Sol.
1 1 1 Normal at P to y2 = x is
  1 2 3  2  9    3  1    5
1 3  1 1
y  tx  t  t3 ...(1)
2 4
5 1 1
1  9 2 3  5(2  9)  1(9  3)  (27  2) ⎛3 ⎞
for minimum AP, (1) passes through A ⎜ , 0 ⎟
 3  ⎝2 ⎠

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24. Let n  2 be a nutural number and 0 <  < /2.

3 t t3
 t    0 ⇒  4t  t 3  0 1
2 2 4 (sinn   sin ) n cos 
Then ∫ d  is equal to
sinn 1 
⇒ t (t 2  4)  0 ⇒ t  2, 0, 2 ∵ t  0 ⇒ t  0, 2
(where C is a constant of integration)

3 n 1
if t = 0, P(0, 0)  AP = n ⎛ 1 ⎞ n
2 (1) ⎜1  ⎟ C
n  1 ⎝ sinn 1  ⎠
2

5
if t = 2, P(1, 1)  AP = n 1
2 n ⎛ 1 ⎞ n
(2) ⎜1  ⎟ C
n 2  1 ⎝ sinn 1  ⎠
⎛3 ⎞ 5
 Shortest distance ⎜ , 0 ⎟ and y  x is
⎝2 ⎠ 2 n 1
n ⎛ 1 ⎞ n
(3) ⎜1  ⎟ C
23. In a class of 140 students numbered 1 to 140, all n 2  1 ⎝ sinn 1  ⎠
even numbered students opted Mathematics course,
those whose number is divisible by 3 opted Physics n 1
n ⎛ 1 ⎞ n
course and those whose number is divisible by 5 (4) ⎜1  ⎟ C
opted Chemistry course. Then the number of n  1⎝
2
sinn 1  ⎠
students who did not opt for any of the three courses Answer (3)
is :
Sol.
(1) 1 (2) 38
1
(3) 102 (4) 42
(sinn   sin ) n cos 
I∫ d
Answer (2) sinn 1 
Sol.
Let sin = t
cosd = dt
M
1

E G (t n  t ) n
D C I∫ dt
A t n 1
B
C
1
⎛ 1 ⎞n
P ⎜ 1  n 1 ⎟ 1
⎝ t ⎠ dt  t  n (1  t 1n ) n dt
F = ∫ ∫
tn

Let 1 – t1–n = u
–(1 – n)t–ndt = du
A = {30, 60, 90, 120}  n(A) = 4 du
t  n dt 
B = {6n: n N, 1  n  23} – A  n(B) = 19 n 1
C = {15n: n N, 1  n  9} – A  n(C) = 5 1
1 1
D = {10n: n N, 1  n  14} – A  n(D) = 10 du 1 un
I∫ un   
n 1 n 1 1 1
n(E) = 70 – n(A) – n(B) – n(D) = 70 – 33 = 37
n
n(F) = 46 – n(A) – n(B) – n(C) = 46 – 28 = 18
n 1
n(G) = 28 – n(A) – n(C) – n(D) = 28 – 19 = 9 n
= 2
u n C
n 1
 Number of required students
n 1
= 140 – (4 + 19 + 5 + 10 + 37 + 18 + 9) n ⎛ 1 ⎞ n
= 2 ⎜1  ⎟ C
= 140 – 102 = 38 n  1 ⎝ sinn 1  ⎠

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25. The plane passing through the point (4, –1, 2) and 27. For each tR, let [t] be the greatest integer less
x  2 y  2 z 1 than or equal to t. Then,
parallel to the lines   and
3 1 2
⎛x ⎞
x 2 y 3 z4 (1 | x |  sin | 1  x |)sin ⎜ [1  x ] ⎟
  also passes through the ⎝ 2 ⎠
1 2 3 lim
x 1 | 1  x | [1  x ]
point :
(1) (–1, –1, –1) (2) (–1, –1, 1) (1) Equals 0 (2) Equals 1
(3) (1, 1, 1) (4) (1, 1, –1) (3) Equals –1 (4) Does not exist
Answer (3) Answer (1)
Sol. Equation of required plane is Sol.

x  4 y 1 z  2 ⎛ ⎞
(1 | x |  sin | 1  x |)sin ⎜ [1  x ] ⎟
3 1 2 0 ⎝ 2 ⎠
lim
x 1 | 1  x | [1  x ]
1 2 3

( x  4)( 3  4)  ( y  1)(9  2)  ( z  2)(6  1)  0 (1 | 1  h |  sin | 1  1  h | sin [1  1  h]
 lim 2
h 0 | 1  1  h | [1  1  h]
7( x  4)  7( y  1)  7( z  2)  0
⎛ ⎞
x  4  y  1 z  2  0 ( h  sin h )sin ⎜  ⎟
 lim ⎝ 2⎠
x  y  z 1 0 h 0 h( 1)

 Point (1, 1, 1) lies on the plane =0

 
26. If 5, 5r, 5r2 are the lengths of the sides of a triangle, 28. Let a  2iˆ  1 ˆj  3kˆ, b  4iˆ  (3   2 ) ˆj  6kˆ and
then r cannot be equal to : 
c  3iˆ  6 jˆ  (3  1)kˆ be three vectors such that
3 7   
(1) (2) 
4 4 b  2a and a is perpendicular to c . Then a
possible value of (1, 2, 3) is :
3 5
(3) (4) (1) (1, 3, 1) (2) (1, 5, 1)
4 4
⎛1 ⎞ ⎛ 1 ⎞
Answer (2) (3) ⎜ , 4,  2 ⎟ (4) ⎜  , 4, 0 ⎟
⎝ 2 ⎠ ⎝ 2 ⎠
Sol.
Answer (4)
A
Sol. ∵ b  2a
5r2 5r

 4iˆ  (3   2 ) jˆ  6kˆ  4iˆ  21 jˆ  6kˆ

B 5 C
For ABC is possible if  3   2  21 ...(1)
5 + 5r > 5r2
∵ a is perpendicular to c
1 + r > r2
r2 – r – 1 < 0  6  61  3( 3  1)  0

⎛ 1 5 ⎞⎛ 1 5⎞ 2  21  3  1  0
⎜⎜ r   ⎟⎜ r  ⎟0
⎝ 2 2 ⎟⎜
⎠⎝ 2 2 ⎟⎠
2 1  3  1  0
⎛  5  1 5  1⎞
 r ⎜ , ⎟  3 = –21 – 1 ...(2)
⎜ 2 2 ⎟⎠
⎝
from eq (1) and (2) one of possible value of
7
 r  1
4 1   ,  2  4 and 3  0
2

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29. If the area enclosed between the curves y = kx2 and 30. Let A be a point on the line
x = ky2, (k > 0), is 1 square unit. Then k is : 
r  (1  3)iˆ  (  jˆ  (2  5)kˆ and B(3, 2, 6) be
1 a point in the space. Then the value of  for which
(1) 3 (2) 
3 the vector AB is parallel to the plane x – 4y + 3z
3 2 = 1 is :
(3) (4)
2 3 1
Answer (2) (1)
4
1 1
Sol. y2  x
k (2)
1 2
x2  y ⎛ 1 1⎞
k ⎜k,k⎟ 1
⎝ ⎠
(3)
8
1
(4) 
4
Answer (1)
Area of shaded region = 1. Sol. ∵ A be a point on given line.
1
k⎛  Position vector of
x 2⎞
 ∫ ⎜⎜ k  kx ⎟⎟ dx  1 
A  OA  r  (1  3)iˆ  (  1) jˆ  (2  5)kˆ
0⎝ ⎠
1
position vector of B  OB  3iˆ  2 jˆ  6kˆ
⎛ 3 ⎞k 1
⎜ 1 x2 ⎟ ⎛ x3 ⎞k
⎜  ⎟  ⎜⎜ k  ⎟ 1  AB  OB  OA
⎜ k 3 ⎟ ⎝ 3 ⎟⎠
0
⎝ 2 ⎠0 = (3  2)iˆ  (3   ) jˆ  (4  5)kˆ
2 1 k
 3  3 1 equation of plane is: x – 4y + 3z = 1
3 k 3k
k2 ∵ AB is parallel to plane.
2 1
2
 2 1  1(3  2)  4(3   )  3(4  5 )  0
3k 3k
3k2 = 1 3  2  12  4  12  15  0
1
k  but k > 0 2  8  0
3
1 1
 k 
3 4

  

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