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Kultur Dokumente
CHEMISTRY
CATEGORY-B
INTERNATIONAL OLYMPIAD
PAPER – A
Time: 60 Minutes. Maximum Marks: 40
Name:....................................................................................................
Marks:
Subject: ................................................................................................
Instructions:
Attempt all questions.
This question paper has two Section-A and B. Each question of Section-A carries 2 marks
and of Section-B carries 5 marks.
Calculators and log tables are not permitted
SECTION – A
1. A sample of hydrogen gas has some atoms in one excited state and some atoms in other excited
state. It emits three different photons. When the sample was irradiated with radiations of energy
2.85eV, it emits 10 different photons, all having energy equal to or less than 13.4eV.
i) Find the principal quantum numbers of initially excited electrons
ii) Find the maximum and minimum energies of the initially emitted photons
2. 1.143 g of ferrous oxalate was dissolved in dil. H2SO4 and made up to 100 ml.
20 ml of the solution required 38% of N/10 KMnO4 for complete oxidation. On reducing the resulting
solution with SO2 and boiling off the excess of SO2. 12.7 ml of N/10 were required for re-oxidation.
Deduce the formula of the ferrous oxalate in the form Fex(C2O4)yZH2O
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FACREC-08-(IO, P1-2017-18)CHEM2
5. A dilute solution contains m mol of solute A in 1 kg of a solvent with molal elevation constant Kb; The
solute dimerises in solution as 2A A2. Show that equilibrium constant for this dimer formation is
K b (K bm Tb )
K= , where Tb is the elevation in boiling point for the given
(2Tb K bm)2
7. A basic nitrogenous compound of molecular formula C4H5N gave C4H9N on complete hydrogenation.
When the hydrogenated product is subjected to Hoffman's exhaustive methylation twice, 1,3
butadiene, trimethylamine and 2 moles of water are obtained. Explain the structure of base and
show the reaction sequence given above.
i)
Br
CH3 CH3
ii) N
N
CH3
Me
Me
10. Discuss the reaction
KOH
PhCH2CH CH2 PhCH CHMe
heat
SECTION – B
1. When a white substance A was treated with dil hydrochloric acid, a colourless gas B was
evolved, which turned moist litmus paper red. On bubbling B through lime water a precipitate
C was formed but passage of further gas resulted in a clear solution D. A small sample of A
was moistened with conc. HCl acid and placed on a platinum wire and introduced into a
Bunsen burner flame where it caused a green flame coloration. On strong heating A
decomposed, giving a white solid E which turned red litmus paper blue. 1.9735 g of A was
heated strongly and gave 1.5334 g of E. The sample of E was dissolved in water and made
up to 250 ml in a standard flask. 25 ml aliquots were titrated with acid and required 20.30 ml
of 0.0985 M HCl acid. Name the compounds A to E and give equations for all the reactions.
Calculate the gram molecular weight of A.
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FACREC-08-(IO, P1-2017-18)CHEM3
4. a) An organic compound C8H18 on monochlorination gives a single monochloride. Write the structure
of hydrocarbon.
b) Write the structures of possible major monosubstituted products formed when Br+ attacks the
following molecules justify your answer.
—COO ; — —OCH3
— — ; HO3S— —NHCOCH3
c) Which of the following has larger dipole moment. Explain 1-Butyne or 1-Butene
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