VIVEK HIGH SCHOOL

SECTOR 38, CHANDIGARH

NAME ______________ SUBJECT : Chemistry

2018-2019
CLASS: XI (Revision)
DATE : TOPIC: Chap1 and 2

1. An organic compound containing carbon, hydrogen and oxygen gave the following
percentage composition: C=40.68%, H=5.08%. The molecular mass of the compound is
118u. Calculate the molecular formula of the compound.
2. 0.30 mol Zn are added to 0.52 mol of hydrochloric acid .Identify the limiting reagent. How
many moles of hydrogen are produced? Calculate the amount of the reactant left unreacted.

3. Calculate the amount in grams of:

a. 2.5 atom of nitrogen
b. 3.6 moles of carbon dioxide
4. How man moles of NaOH are present in 27mL of 0.15 M oxalic acid solution?

5. A sample of NaOH weighing 0.38g is dissolved in water and the solution is made to 50.0 mL
in a volumetric flask. What is the molarity of the resulting solution.

6. If the velocity of electron in Bohr’s first orbit is 2.19m/s, calculate the de Broglie wavelength
associated with it.
7. Calculate the ratio of radius of 2nd orbit of H atom and that of 3rd orbit.
8. The ionization energy of He+ is 19.6*10 -18J per atom. Calculate the energy of first transition
state of Li 2+.
9. Calculate the uncertainty in the position of an electron if the uncertainty in its velocity is
5.7*105 m/s.
10. What is the maximum number of unpaired electrons in Cu(Z=29), Br - (Z=35), V(Z=23)?
 VIVEK HIGH SCHOOL
SECTOR 38, CHANDIGARH

NAME ______________ SUBJECT : Chemistry (Revision)

CLASS: XI TOPIC: Chap3,4 and 9
2018-2019 DATE :

1. Out of NaCl and AlCl3, which has more covalent character? Why?
2. Arrange the following in the order of increasing dipole moment.BF 3, H2S,H2O
3. Write the resonance structures of NO2 and PO43- .
4. Do BF3 and ClF3 have similar shapes? Explain.
5. Why bond angle in H2O is nearly 104.50 but that in H2S, it is nearly 900.
6. Indicate the type of hybridization of each carbon atom in the following. Also find the total number of sigma
and pi bonds:

a) CH3CHCl2 b) CH3C≡CCH3 c) CH2=C=CH2

7. Why O2 is more stable than F2? Explain on the basis of molecular orbital theory.

8. Indicate which one from O2+ and O2 2- is more stable and may exhibit paramagnetism.

9. Write the limitations of Kossel Lewis approach.

10. Describe the hybridization in case of SF4.

11. Why ethyl alcohol is completely miscible with water.

12. Explain the following.

a) 3d,4d,5d series consist of 10 elements each.

b) Mg2+ ion is smaller than O2- , though both are isoelectronic.

c) The first ionization potential of Be is higher than first ionization enthalpy of B.

13. What are the factors due which ionization enthalpy increase while electron gain enthalpy increases down a
group.

14. Explain why cations are smaller and anions larger in radii than their parent atoms.

15. Explain the following:

a) Coal gasification

b) Auto protolysis of water

16. How can hydrides be classified? Explain in detail.

17. What do you understand by temporary and permanent hardness of water? How can it be removed?

18. With the help of chemical equations explain the oxidizing and reducing action of hydrogen peroxide in
acidic medium.
 VIVEK HIGH SCHOOL SENIOR WING
SECTOR-38B (2018-2019)
CHANDIGARH

NAME:______________________________________________DATE:_____________________CLASS: XI A

Subject: CHEMISTRY Topic : Revision chap5,6

1. What do you understand by STP.

2. Out of nitrogen and ammonia molecules, which one will have greater value of van der
Waal’s constant ‘a’? Why?
3. What is the effect of temperature on a) surface tension b) viscosity c) vapour pressure of
a liquid?
4. Vapour pressures of water, ethyl alcohol and benzene at 20 C are 17.5mm, 43.0mm and
74mm respectively. Which one of the three liquids has the strongest intermolecular
forces?
5. What do you understand by boiling point?
6. Calculate the total pressure in a 10 litre cylinder which contains 0.4g of helium, 1.6g of
oxygen and 1.4g of nitrogen at 27°C. Also calculate the partial pressure of helium gas in
the cylinder. Assume ideal gas behaviour of gases. Given R= 0.082litre atmK-1 mol-1.
7. Draw and explain the isotherm for liquefaction of carbon dioxide at various temperatures.

8. Using vander waals’ equation, calculate the constant ‘a’ when two moles of gas confined
in a four litre flask exerts a pressure of 11.0 atm at a temperature of 300K. The value of
‘b’ is 0.05 litre/mol. Given R= 0.082litre atmK-1 mol-1
9. .Calculate standard enthalpy change (∆H⁰) and standard internal energy change (∆U⁰)
for the reaction
OF2(g)+ H2O(g)  O2(g)+2HF(g)
Given that standard enthalpies of formation, ∆Hf⁰ OF2(g), H2O(g), and HF(g) are 23.0,-
241.8 and -268.6kJ/mol respectively.
10. Find out whether it is possible to reduce MgO using carbon at 298K. If not,at what
temperature does it become spontaneous for the reaction,
MgO(s) + C(s)  Mg(s) + CO(g)
∆H⁰ =+ 491.18kJ/mol and ∆S⁰ =197.67J/K/mol?
11. Find the work done when 1 mole of the gas is expanded reversibly and isotermally from
5atm to 1atm at 25⁰C? (R=8.31J/K/mol, log5=0.699) (

12. The equilibrium constant for the reaction at 298K

CO2(g)+ H2(g) CO(g)+ H2O(g) is 2×107 Calculate the value of standard free
energy change,(R= 8.314 JK-1mol-1)

13. For the reaction at 298K 2A(g) + B(g)  2D(g)

∆U° = -10.5kJ and ∆S°= -44.1J/K . Calculate ∆G° for the reaction and predict
whether the reaction is spontaneous or not.
 VIVEK HIGH SCHOOL SENIOR WING
SECTOR-38B (2018-2019)
CHANDIGARH

NAME:______________________________________________DATE:_____________________CLASS: XI A

Subject: CHEMISTRY Topic : Revision Chap7,8

1. What happens to ∆G when the equilibrium is attained?

2. Why is ammonia termed as a base though it does not contain OH - ions?
3. The Ksp values of two slightly soluble salts AB and PQ2 are equal to 4.0*10-18. Which salt is more
soluble? Explain.
4. Explain why it is so?
a) High pressure is applied in the formation of ammonia
b) In the presence of Cl2, dissociation of PCl5 decreases.
c)Solubility of AgCl is more in water than in a solution of common salt.
5. In the reaction calculate H2(g)+ I2(g)----2HI(g) Calculate the equilibrium constant , if the concentrations of
H2, I2 and HI are 9.0, 3.0and 27.0 mol/l respectively.
6. Concentrations of two reactants A andB are 0.8 mol/l each. On mixing the two , the reactionsets in at a
slow rate to form C and D.A + B ----- C + D At equilibrium , concentration of C was found to be
0.60 mol/l. Calculate the equilibrium constant.
7. Hydrogen gas is obtained from the natural gas by partial oxidation with steam and is an endothermic
reaction.Write the expression for kp for the above reaction.How will the value of Kp and composition of
equilibrium mixture be effected by: i) increasing the pressure ii) increasing the temperature iii) using a
catalyst?
8. The degree of ionization of 0.1M bromoacetic acid solution is 0.132. Calculate the pH of the solution and
pKa of bromoacetic acid.
9. Calculate the pH of 0.3g of Mg(OH)2 dissolved in water to give 500mL solution.
10. Determine the oxidation number of the elements in each of the following compounds:
a. H2CO3 NO2- LiH c. Zn(OH)42-
11. Would you use an oxidizing agent or reducing agent in order for the following reactions to occur?
a. ClO3- ClO2 b. SO42- S2- b. Mn2+ MnO2 d. Zn ZnCl2
12. Write balanced equations for the following reactions:

a. Cr(OH)3 + Br2 CrO42- + Br- in basic solution

b. ClO2- ClO2 + Cl- acidic solution

13. Answer the following questions for a galvanic cell that employs the reaction

2Na(l) + S(l) -----> Na2S(s) What element is oxidized? What element is reduced? What element serves as
the anode? What element serves as the cathode?

14. A certain voltaic cell has for its cell reaction: Zn + HgO ↔ ZnO + Hg

Write the cell notation.Which is the half-reaction occurring at the anode?

15. Calculate E cell for the following reaction: 2Fe2+(aq) + Cd2+(aq) ↔ 2Fe3+(aq) + Cd(s)