Beruflich Dokumente
Kultur Dokumente
LOGO THERMODYNAMICS 1
Course books : Smith, J. M., Van Ness, H.C., Abbott, M. M. 2011. Introduction to
Chemical Engineering Thermodynamics, 6th ed., McGraw-Hill
Co., Singapore.
References books :
1. Poling, B. E., Prausnitz, J. M., O’Connell. 2001. The properties of gases and liquids
fifth edition, McGraw-Hill, New York, USA.
2. Sandler, S. I. 1999, Chemical Chemical, Biochemical, and Engineering
Thermodynamics, 5th ed., Joh Wiley and Sons, Inc., USA
3. Praustnitz, J. M., Lichtenthaler, R. N., and de Azevedo, E. G. 1999. Molecular
Thermodynamics of Fluid-Phase Equilibria, 3rd ed., Prentice Hall PTR. USA.
Course Details (cont.)
1. Thermodynamics : Definition
2. Thermodynamics : Example
3. Dimensions and Units
4. Measures of Amount or Size
5. Force
6. Temperature
7. Pressure
8. Work
9. Energy
10. Heat
Definition
Vapor-Liquid
Equilibrium
(VLE) data
Example (cont.)
Feed Extractive
Distillation Column
Preheater
Steam in
Concentrated
Evaporator
Buffer Solution
Condense out
Pump
Distillation method based on the addition Buffering-effect of TRIS on the VLE of the tert-butanol (1) +
of an entrainer (extractive distillation) water (2) system. x1' was calculated from buffer-free base :
(■), 0.05; (▲), 0.10; (●), 0.20; (___), calculated from the
(Hartanto et al, 2013)
NRTL model; (-∙∙-), smoothed results for the TRIS-free system
(Hartanto et al, 2013)
Dimensions and Units
- Dimension is recognize through our sensory perceptions and not
definable without the definition of arbitrary scales of measure,
divided into specific units of size.
m
n , m Mn
M
Total volume, divided by the mass or number of moles of the
system to yield specific or molar volume.
• Specific volume: Vt V t mV
V or
m
Vt
• Molar Volume: V or V t nV
n
Measurements of Amount and Size (cont.)
Properties in HYSYS
Force
1
1 kgf x 1 kg x 9.80665 ms 2
gc
gc 9 .80665 kg m kg f 1 s 2
dW Fdl
Vt
dW PAd
A
dW PdV t
V2t
W t PdV t
V1
Energy
1. Kinetic Energy
When a body of mass m dacted upon by a force F is displaced a distance dl during a
differential interval of time dt .
dW ma dl
Acceleration a = du / dt, where u is the velocity of the body
du dl
dW m dl m du
dt dt
Velocity u = dl / dt, the expression work becomes
dW mu du
u2
u 22 u12
W m u du m
u1 2 2
mu22 mu12 mu 2
W
2 2
2
1
Ek mu 2
2
Thank you