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PII: S0140-7007(16)00046-3
DOI: http://dx.doi.org/doi: 10.1016/j.ijrefrig.2016.02.014
Reference: JIJR 3269
Please cite this article as: Brigitte Astrid Medjo Nouadje, Paiguy Armand Ngouateu Wouagfack,
Réné Tchinda, Finite-time thermodynamics optimization of an irreversible parallel flow double-
effect absorption refrigerator, International Journal of Refrigeration (2016), http://dx.doi.org/doi:
10.1016/j.ijrefrig.2016.02.014.
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Finite-time thermodynamics optimization of an irreversible parallel
TCHINDA Réné1,2,3
1
LESEE, Department of physics, University of Yaounde I, PO Box 812, Yaounde, Cameroon
2
L2MSP, Department of physics, University of Dschang, PO Box 67, Dschang, Cameroon
3
LISIE, University Institute of Technology Fotso Victor, University of Dschang, PO Box 134, Bandjoun,
Cameroon
4
Department of Renewable Energy, Higher Technical Teachers’ Training College, University of Buea, PO Box
Page 1 of 52
Highlights
Working fluid temperatures, ECOP, specific cooling rate and entropy generation rate.
ABSTRACT
and the ecological coefficient of performance criteria has been carried out. This was done
analytically and numerically for a double-effect parallel flow absorption refrigerator with
losses of heat resistance, heat leakage and internal irreversibility. The maximum of the
coefficient of performance and the corresponding optimal conditions have been derived
parameters on the general and optimal performances on the basis of COP and ECOP functions
have been discussed. The results obtained may provide the basis for designing real double-
Page 2 of 52
Nomenclature
T: temperature (K)
a : distribution rate of the total heat reject quantity between the condenser and the absorber
b : ratio of the total heat between the HP generator and the LP generator
Symbol
Subscripts
A: absorber
Page 3 of 52
C: condenser
E: evaporator
G: generator
L: heat leakage
max: maximum
m: at maximum COP
Page 4 of 52
1. Introduction
system and the surroundings. Thus, the classical thermodynamic performance bound couldn’t
properly give the bound of absorption system (Bhardwaj et al., 2003; Kaushik et al., 2002;
Ngouateu Wouagfack and Tchinda, 2013a). For this reason, the finite-time thermodynamics
approach has been introduced to establish the performance bound of absorption system. The
finite-time thermodynamics tends to model real system in a way closer to reality. It enables to
distinguish the irreversibilities due to internal dissipation of the working fluid and that due to
the finite-rate heat transfer between the system, the external heat reservoir and heat-sink. It
tries to bridge the gap between thermodynamics and heat transfer. It deals with
systems. The applications of finite-time thermodynamics include all the processes with
thermal phenomena of all devices and systems operating with the constraints of finite-time
and finite-size. The endoreversible cycle is the fundamental physical model adopted in finite-
time thermodynamics. The finite-time thermodynamics has been first proposed by Henri B.
Reitlinger in 1929 (Vaudrey et al., 2014) and later extended to nuclear energy by Chambadal
and Novikov independently in 1957. This method has been popularized in many works
including Curzon and Ahlborn (1975), Leff and Teeters (1978), Blanchard (1980), Bejan
(1982, 1996, 1997), Andresen (1983), Feidt (1987), Sieniutycz and Salamon (1990), De Vos
(1992, 1995), Radcenco (1994), Bejan et al. (1996), Chen et al. (1997), Bejan and Mamut
(1999), Berry et al. (2000), Sieniutycz et al. (2002), Stitou et al. (2001, 2002), Zheng et al.
(2003), Stitou, Feidt (2005),Chen et al. (2011), Li et al. (2013) and Feng et al. (2015a,b,c), in
many review articles including Sieniutycz and Shiner (1994), Hoffmann et al. (1997),
Chen et al. (1999), Durmayaz et al. (2004), Feidt (2013), Qin et al. (2013) and Ngouateu
Page 5 of 52
Wouagfack and Tchinda (2013b) and in books Wu et al. (1999) and Chen and Sun (2004).
Significant results have been obtained and are provided in the literature. In the case of
absorption refrigerators, the optimal operating region of endoreversible (Yan and Chen, 1989;
Chen and Yan, 1993; Chen, 1995; Wijeysundera, 1996; Wu et al., 1997; Ng et al., 1997; Chen
et al., 1997 a, b; Chen et al., 2004, 2011, 2013) and irreversible (Chen and Schouten, 1998;
Chen, 1999; Chen et al., 2002; Zheng et al., 2003a,b, 2004; Chen et al., 2006; Qin et al., 2010;
Ngouateu Wouagfack and Tchinda, 2011a; Ngouateu Wouagfack , 2012) single effect
systems, most of the theoretically work considers the mass and energy conversion approach to
calculate the coefficient of performance of the system (Xu and Dait, 1997; Arun et al., 2000,
2001; Ezzine et al.,2004a,b, 2005; Kaushik et al., 2009; Torrella et al., 2009; Arona et al.,
2009; Gebreslassie et al., 2010; Huicochea et al., 2011; Vasilescu et al., 2011; Sedigh and
Saffari, 2011; Farshi et al., 2011, 2012; Shatata et al., 2012; Dominguez-Inzunza et al., 2014;
Li et al., 2014) and the exergy efficiencies (Gomri and Hakimi, 2008; Arona et al., 2009;
Kaushik et al., 2009; Gomri, 2010; Shahata et al., 2012; Farshi et al., 2013a,b). Chua et al.
(2000) used the process average temperature to study the impact of the various dissipative
mechanisms on the inverse of the coefficient of performance (COP-1) . Much work has yet to
refrigerators except the work of Göktun and Er (2000). They used the finite-time
refrigeration system. They did not establish the bound of the operating region of the system.
refrigerator cycle with losses of heat resistance, heat leakage and internal irreversibility are
Page 6 of 52
derived. The irreversibility parameters and heat leakage effects on the COP and on the ECOP
2. System description
Figure 1 shows the schematic illustration of a parallel flow double-effect system. It is seen in
this figure that the weak solution leaving the absorber is pumped to the low-temperature heat
exchanger (LTHE) after which it is divided into two streams. One stream flows to the HPG
through the high-temperature heat exchanger (HTHE) and the other to the low-pressure
generator (LPG) via EV4. In the LPG, the vapour refrigerant from the high-pressure generator
(HPG) is condensed and its latent heat is utilized to generate water vapour from the weak
solution in the LPG. A high-temperature heat source is used to provide heat to the HPG for
water vapour generation from the weak solution. The strong solution exiting the HPG passes
to the mixing point (P1), where it mixes with the other strong solution from the LPG. The
combined strong solution is passed to the absorber through LTHE and EV3.
3. Physical model
HPG, evaporator temperature, condenser temperature, and absorber temperature) and three-
pressure levels (low pressure in the evaporator and absorber, medium pressure in the
condenser and the low pressure generator, the high pressure in the high pressure generator).
represented in Fig. 2.
Page 7 of 52
In this model, Q H P G is the rate of heat absorbed from the heat source at temperature
T H P G to high pressure generator, Q L P G is the rate of heat absorbed from the heat source at
temperature T L P G to low pressure generator, Q C is the heat rejection rate from the condenser
to the heat-sink at temperature TC , Q A is the heat rejection rate from the absorber to the heat-
sink at temperature T A and Q E is the heat input rate from the cooling space at temperature T E
to the evaporator. The work input required by the solution pump is negligible compared to the
energy input to the high and low pressure generator. According to the first law of
Q LP G Q E Q C Q A 0 (1)
factors. We have considered the cycle of the working fluid as a three-irreversible isothermal
process and three-irreversible adiabatic process since the double-effect system is a triple
thermal system. The temperatures of the working fluid in the isothermal processes are
different from those of the external heat reservoirs such that the heat is transferred under a
In this figure, T1 and T 2 are respectively the temperatures of the working fluid in the HP
generator and LP generator. T 3 , T 4 and T5 are respectively the temperature of the working
fluid in the absorber, evaporator and condenser. We also considered the existence of heat
The heat exchanged between the working fluid and heat reservoirs obey a linear heat
transfer law, such that the equation of heat transfer can be written as:
Page 8 of 52
Q H PG U H PG AH PG T H PG T1 (2)
Q LP G U LP G ALP G T 2 T LP G (3)
Q E U E AE T E T 4 (4)
Q A U A A A T3 T A (5)
Q C U C AC T5 TC (6)
Following the idea developed by Chen and Schouten (1998), the heat-leak of a parallel flow
.
Q L K L T A T E TC T E T LP G T E (7)
where Eqs. (1)-(6) are written like Göktun and Er (2000). In equations (2)-(6), AH P G , ALP G ,
absorber and condenser respectively, U HPG , U LP G , U E ,U A and UC are the overall heat-
respectively.
The total area of heat transfer between the cycle system and the external heat reservoirs is
A AH P G ALP G AE A A AC (8)
. . . . . .
Q H P G T1 Q LP G T LP G Q E T 4 Q A IT 3 Q LP G IT 2 Q C IT 5 0 (9)
. . .
Q A T 3 Q C T5 Q LP G T 2
where I . . .
1 is the internal irreversibility parameter.
Q H P G T1 Q LP G T LP G Q E T 4
Defining the parameter a as the distribution rate of the total heat reject quantity
Page 9 of 52
. .
a Q A / QC (10)
and the parameter b as the ratio of the total heat between the HP generator and the LP
Q HPG
b (11)
Q LPG
Using Eqs. (1)-(11), we obtain the coefficient of performance, the specific cooling
load and the specific rate of entropy production of a parallel flow double-effect absorption
. . . .
. .
Q E Q L QE QL QE Q
1 L
COP 1 . (12)
. . . .
Q HPG Q HPG Q E bQ LPG
QE
where
.
1 1 1 1
b 1 a T1 1 a T LP G 1 a IT 2 a IT 3 IT 5
1
QE
(13-a)
1 1
a IT 3 IT 5 1 a T 4
. 1
Q LP G
. . .
QL 1 bQ LP G Q LP G
T A T E TC T E T LP G T E
E E 4
. . .
U T T
QE Q E U H P G T H P G T1 Q E U LP G T 2 T LP G
.
.
Q LPG Q LPG
a 1 . 1 .
QE QE
(13-b)
U A T3 T A 1 a U C T5 TC 1 a
10
Page 10 of 52
.
.
Q Q
a 1 . L P G 1 L P G
.
QE QE
T A T E TC T E T L P G T E (14)
U A T3 T A 1 a U C T5 TC 1 a
and
. . . . . .
1 Q A K L T A T E Q C K L TC T E Q L P G K L T L P G T E Q H P G Q L P G Q E K L T A T E TC T E T L P G T E
S
A TA TC TLPG TH PG TLPG TE
.
.
a 1 .
Q LPG 1 .
Q LPG
.
1 bQ L P G QE QE
.
U A T3 T A 1 a U C T5 TC 1 a
E E
U T T4
Q E U H P G T H P G T1
1
.
Q E TC 1 aT A 1 TC 1 aT A 1 1
1
T A T E TC T E T LP G T E b THPG
. TE
1 a 1 a
Q LP G
T 1 aT A 1 1
1
.
. E T A T E TC T E T LP G T E C b THPG
Q
1 a
Q LP G
T 1 aT A 1 1 TC 1 aT A 1 TC 1 aT A 1
T A TE C T A TC T E T LP G T E
1 1
TC T LP G
1 a 1 a 1 a
(15)
According to the definition of the general thermo-ecological criterion function (Ust and
Sahin, 2007; Ust, 2009; Ngouateu Wouagfack and Tchinda, 2011a,b, 2013a,b; Ngouateu
Wouagfack, 2012 and Medjo Nouadje et al., 2013, 2014) the new thermo-ecological objective
11
Page 11 of 52
. . .
1
Q Q L 1 Q E TC 1 aT A 1 1 TC
1
aT A
1
1
ECOP E b THPG TE
.
.
T env 1 a 1 a
T env Q LP G
.
.
a 1 .
Q LPG 1 .
Q LPG
. .
1 b Q LPG Q LPG QE QE
. .
U A T3 T A 1 a U C T5 TC 1 a
E E
U T T4
Q E U H P G T H P G T1 Q E U L P G T 2 T L P G
1
TC 1 aT A 1 1 TC 1 aT A 1 1
T A T E TC T E T LP G T E A E
T T T A C
T T E TC
1 a 1 a
1
1
Q T 1 aT 1 1 TC 1 aT A 1 1
E
T A T E TC T E T LP G T E C 1 a A b T H P G T T
E T
LP G LP G
1 a
Q
LP G
(16)
1 1
For the sake of convenience, let b1 1 a bT1 1 , b2 1 a IT 2 , b3 a IT 3 ,
1
b4 1 a T 4 1 and b5 IT5 . Then Eq. (12) may be written as:
1
b1 b2 b3 b5 1 a T L P G 1
COP 1 T A T E T C T E T L P G T E
b b 3 b5 b 4 U T 1 a
E E b4
b 3 b5 b 4 b 1
b b b b 1 a T
1 2 3 5 LP G
1
U
HPG THPG
1 a b
b1
1 a
U LP G T
Ib2 LP G
1
b1 b2 b4 1 a T LP G a 1
(17)
b1 b2 b3 b5 1 a T LP G
1
1 a U A a T A U C 1 TC
Ib3 Ib5
12
Page 12 of 52
We obtain the following optimal temperature of the working fluid in the HP generator ( T1 m ),
COP:
T 2 m T LP G 1 y 1 B (19)
T 3 m T A 1 z 1 B (20)
T 4 m T E 1 w 1 B (21)
T 5 m TC B (22)
where
x U C IU H P G , y U C U LP G , z U C U A , w U C IU E
1 2 1 2 1 2 1 2
1
B
az 1 z I T A 1 a U C I
1 1
T A T E TC T E T LP G T E w 1 a 1 w T E 1
1 1
B1
1
Iw TC 1 a T E z aTC T A 1 a TC U C T A T E TC T E T LP G T E 1
2 1 2 1 1
B1 1 a aI 1 w z T E 1T A 1 I 1T E 1T C 1 1 a w 1 a 1 z T C 1T A 1
2 2 2
aI
1
U C 1 a I 1 1 T A T E TC T E T L P G T E T C 1 a T E
1 1 1 1 1
TA I (23)
Substituting Eqs. (18)-(22) into Eqs. (12) and (14)-(16) give the maximum coefficient of
Numerical calculations are carried out by employing the relevant values U HPG=173500
W m-2 K-1, ULPG=171900 W m-2 K-1, UE=449000 W m-2 K-1, UA=379700 W m-2 K-1,
UC=278200 W m-2 K-1 taken from refs. (Chua et al., 2000) and THPG=443 K, TLPG=363 K
TC=303 K, TA=305 K, Tenv=300 K, TE=285 K. Maple software is used to carry out derivation
13
Page 13 of 52
and to solve polynomial equation. MATLAB software is used for numerical calculations and
Fig.4 presents the variation of the coefficient of performance with respect to the
specific cooling load for different values of internal irreversibility. We obtained a similar
curve that obtained in the case of the single effect by Chen and Yan (1989). It can also be
observed that when the internal irreversibility increases, both the maximum coefficient of
performance and the maximum specific cooling load decrease.
Fig. 5 presents the effect of the heat leakage coefficient on the maximum coefficient of
performance for different values of the internal irreversibility parameter. We can observe that
the COPmax decreases with an increase in the heat leakage coefficient. It can also be seen that
when ξ = 0, that is there is no loss due to heat leakage and when I = 1, the system is
endoreversible and COPmax ≈ 1.32. This value is closer to 1.28 obtained by Chua et al.
(2000).
performance for different values of the internal irreversibility parameter. We observe that the
COPmax decreases slightly with an increase in the parameter a, and tends to an asymptotic
value when the parameter a is large. We can conclude that the effect of the parameter a on the
performance for different value of the internal irreversibility parameter. We observe that the
COPmax decreases when the parameter b increases. So, when b 1 the maximum of the COP
is very high and this result does not reflect the reality. And when b 1 , the maximum of the
14
Page 14 of 52
Figs. 8 and 9 present the effect of the internal irreversibility on the specific entropy generation
rate and the specific cooling load at the maximum coefficient of performance respectively. As
expected, the specific entropy generation rate increases with the increase in the internal
The variations of the normalized ecop (ecop = ECOP/ECOPm) and cop (cop =
COP/COPmax) with respect to the normalized specific entropy generation rate and the
normalized specific cooling load have been plotted in Figs. 10 and 11 respectively. From
these figures, we can observe that unlike the maximum ECOP and COP for mechanical
compression refrigeration systems (Ust and Sahin, 2007; Ust, 2009) and single effect
absorption refrigeration systems (Ngouateu Wouagfack and Tchinda, 2011a, 2013b) the
maxima ecop and cop for the parallel flow double-effect absorption refrigeration systems do
not occur for the same value of normalized specific entropy generation rate and normalized
Another result from the interpretation of these figures is that there also exists a specific
T1, T2, T3, T4 and T5 that maximize the ECOP function of parallel flow double-effect
absorption refrigerators for given I and ξ values. Therefore Eq. (16) can be maximized with
respect to T1, T2, T3, T4 and T5. This optimization was done numerically.
The variations of the ecological coefficient of performance function for the parallel
flow double-effect absorption refrigerator with respect to the specific cooling load for
different values of a, b, ξ and I is given in Fig. 12. This figure reveals the optimal operating
region of an irreversible parallel flow double-effect absorption refrigerator system. Like in the
case of the single-effect absorption refrigerator, the ECOP-R characteristic curve is loop-
shape passing through the origin and divided into three parts. In positive slope part, the
15
Page 15 of 52
ecological coefficient of performance increases with the increase of the specific cooling load.
In the negative slope part, the ecological coefficient of performance increases with a decrease
in the cooling load. This is normal since the main goal of the ecological optimization consists
of cooling load for a lower entropy generation (Ngouateu Wouagfack and Tchinda, 2011b).
The variations of the ecological coefficient of performance function for the parallel
flow double-effect absorption refrigerator with respect to the specific entropy generation rate
for different values of a, b, ξ and I is given in Fig. 13. It can be observed in this figure that
the ecological coefficient of performance increases with low value of the specific entropy
generation rate and when reached it optimal value it decreases with an increase in the specific
The variations of the ecological coefficient of performance function for the parallel
flow double-effect absorption refrigerator with respect to the coefficient of performance have
been plotted in Fig.14 for different values of a, b, ξ and I. There, we observed that the
performance.
In Fig.12A, Fig.13A and Fig.14A, the ECOP decreases slightly with an increase in a.
Hence, we can see that when the parameter a tends toward infinity, its effect on the
performance of the system is negligible. We also observed that the specific cooling load (fig.
12A) and the coefficient of performance (fig. 14A) decrease slightly with an increase in a.
These relevant optimization parameters do not increase any longer when the parameter a takes
a high value. We can say that as much as the heat release at the absorber is higher than the
heat release at the condenser, the performance of the system is not influenced.
16
Page 16 of 52
In Figs. 12B, 13B and 14B, when the parameter b increases the maximum of the
ecological coefficient of performance decreases. This result is also observed in the case of the
specific cooling load (Fig. 12B) and the coefficient of performance (Fig. 14B) which decrease
with an increase in parameter b. We notice that the value of the parameter b should be near
1.23 in order to have a higher value of the system performance. For instance, when b=1.4 in
fig. 14B, the maximum of the coefficient of performance is less than 0.5 compared to the
In Figs.12C, 13C, 14C, 12D, 13D and 14D, the ECOP objective function decreases
when both heat leakage and internal irreversibility increase. Similar observations have been
made in the case of single effect absorption refrigerators (Ngouateu Wouagfack and Tchinda,
2011a,b, 2013b). The higher value of the ECOP is obtained in the endoreversible case
(Figs.12D, 13D and 14D). We also observe that as the heat-leak coefficient and the internal
irreversibility parameter increase the specific cooling load (figs. 12C and 12D) and the
5. Conclusion
absorption refrigerator system with the losses of heat resistance, heat leakage, and internal
coefficient of performance (ECOP) as objective functions has been investigated in this paper.
The five optimal temperatures of the working fluids in the main components of the system
that maximize the COP function and the corresponding ecological coefficient of performance,
specific cooling load and specific entropy production rate are investigated. Then, it has been
shown that the maxima COP and ECOP do not occur for the same operating conditions. The
effects of internal irreversibility, heat leakage, distribution rate of the total heat reject quantity
between the condenser and the absorber and ratio of the total heat between the HP generator
17
Page 17 of 52
and the LP generator on the general and optimal COP and ECOP have been investigated and
discussed.
18
Page 18 of 52
Acknowledgments
The present research work was carried out in LISIE and LESEE. All the senior researchers of
these laboratories are gratefully acknowledged for their helpful comments. We also thank the
19
Page 19 of 52
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Figure 1: parallel flow double-effect absorption refrigerator (Farshi et al., 2012).
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Figure 2: Schematic diagram of a parallel flow double-effect absorption refrigerator
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Figure 3: Schematic diagram of an irreversible parallel flow double-effect absorption
refrigerator
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Figure 4: Variations of COP function with respect to the specific cooling load for different
values of I (a=2.5, b=1.23, =0.7).
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Figure 5: Effect of the heat leakage coefficient on COPmax for different values of I (a=2.5,
b=1.23).
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Figure 6: Effect of the parameter a on COPmax for different values of I ( =0.7, b=1.23).
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Figure 7: Effect of the parameter b on COPmax for different values of I ( =0.7, a=2.5).
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Figure 8: Variations of Sm with respect to the internal irreversibility I (b=1.23, a=2.5, =0.7).
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Figure 9: Variations of Rm with respect to the internal irreversibility I (b=1.23, a=2.5, =0.7).
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Figure 10: Variations of the normalized ECOP and COP with respect to the normalized specific
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Figure 11: Variations of the normalized ECOP and COP with respect to the normalized
specific cooling load (I=1.01, b=1.23, =0.7)
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Figure 12: Variations of ECOP function with respect to the specific cooling load for different
values of (A) a (I=1.01, b=1.23, =0.7), (B) b (I=1.01, a=2.5, =0.7), (C) (I=1.01, a=2.5,
b=1.23) and (D) I (b=1.23, a=2.5, =0.7).
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Figure 13: Variations of ECOP function with respect to the specific entropy generation rate
for different values of A) a (I=1.01, b=1.23, =0.7), (B) b (I=1.01, a=2.5, =0.7), (C)
(I=1.01, a=2.5, b=1.23) and (D) I (b=1.23, a=2.5, =0.7).
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Figure 14: Variations of ECOP function with respect to the coefficient of performance for
different values of A) a (I=1.01, b=1.23, =0.7), (B) b (I=1.01, a=2.5, =0.7), (C) (I=1.01,
a=2.5, b=1.23) and (D) I (b=1.23, a=2.5, =0.7).
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