Beruflich Dokumente
Kultur Dokumente
and Opportunities,
Editors Hans Müller-Steinhagen, M. Reza Malayeri, and A. Paul Watkinson, Engineering Conferences International, Tomar, Portugal, July 1 - 6, 2007
Department of Chemical Engineering, Pembroke Street, Cambridge CB2 3RA, UK E-mail: emi22@cam.ac.uk
http://dc.engconfintl.org/heatexchanger2007/9
Ishiyama et al.: 49
∆Ptubes). The primacy of the thermal conductivity in Eq. reported by Polley et al. (2002), Eq. (10), so that the
(1) is now evident, as δ ~ Rfλf. For crude oil fouling, λf fouling rate varies with temperature and flow rate. The
is expected to lie between that of the oil and an flow to the splitter at A is held constant while the
amorphous coke (~ 0.1-2 W/m K; Watkinson, 1988). (common) pressure drop across the exchangers is
Figure 2 shows that λf determines whether the primary increased in order to counter the hydraulic effects of
impact of fouling on an individual exchanger will be fouling. The hot stream flow and split are held constant.
hydraulic or thermal. Exchanger 2 is set to have a slightly fouled initial
condition (Rf = 0.01 m2K/kW, or Bif = 0.00463) in order
4 to differentiate the two exchangers. The characteristic
λf =0.1
3.5 operating times calculated for the thermal and the
λf =0.3 hydraulic constraints are listed in Table 1. These give a
3
rough indication of the value of λf which would shift the
2.5 heat exchanger (HE) performance limitation from thermal
λf =0.5
to hydraulic (about 0.45 W/ m K for this case).
2
Bif
dR f −E
1.5 = A f Re −0.8 Pr −0.33 exp − Cu 0.8 (10)
λf =1 dt RT
s
1
λf =2
0.5 where Af = 3.7 ×106 m2K/kW h, E = 55 kJ/mol, and
C = 3.2 ×10-7 m2/kW h Pa.
0
1 1.5 2 2.5 3 3.5
∆P/∆Pc
Fig. 2 Impact of fouling on thermal and hydraulic
performance (∆Ptubes), for different λf values. hot stream
1
200 300 psi (20.7 bar) (Shell, 2007). This energy is dissipated
across heat exchangers, piping, control valves etc. so that
150 λf=0.1 the impact of fouling on the network pressure drop is
smaller than that suggested by Eq. (7). This behaviour
100 needs to be accounted for if the throughput is to be
allowed to vary. We introduce a pressure distribution
50 HE1 factor, α, to quantify this distribution based on clean
HE2 operation at the target flow rate, viz.
0
0 100 200 300 400 500 ∆Ppiping
Time (days) α= (11)
∆PHEX , clean
(a)
The piping component in the numerator will be
4
λf =0.1
roughly ∝ m& 2 , as is the first term in Eq. (7). Practical
3.5 cases probably involve α values in the range 0.3< α < 3.
The impact of control valves, which are opened as the
3
pressure drop increases, is modelled as shown in Figure 5.
2.5 The centrifugal pump will be capable of delivering a
λf =0.5
λf =2 larger flow than the target value, m& * , until fouling causes
2
Bif
3 m*
∆P/∆Pc
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Ishiyama et al.: 51
The estimates of ∆thy and ∆tth indicate that HE3 is initial throughput, representing operation up to the design
unlikely to face thermal limitations over the 3 year limit of the exchangers.
operating period: this is confirmed by the cleaning
schedules presented later. Variable throughput requires
the hot stream mass flows to be proportional to the cold 95
stream flow rate; changes in film heat transfer coefficients 94
are also evaluated. Fouling is assumed to occur only on
93
the crude (tube) side. Calculations were performed on an
86
0 20 40 60 80 100 120 140 160
Time (weeks)
(a)
350,000
α=∞
α=3
Cumulative lost production(tonnes)
300,000
α=1
250,000 α=0.3
100,000
Figure 7 shows the performance of the network over
the 3 year period for the case where no cleaning is 50,000
performed. Excellent agreement with the original reported
results was obtained for operation at constant mass flow 0
0 20 40 60 80 100 120 140 160
rate. The plots highlight the importance of hydraulic Time (weeks)
impact, which is greatest at low α, i.e. when the pressure
drop across the exchangers dominates the total pressure (b)
drop. The reduction of throughput, by some 21,000- 235
306,000 te over 3 years, is significant: at a marginal cost
of 5 US$/bbl (Shell, 2007), this represents a lost 230
opportunity of 0.8-11.3M US$. 225
In a rigorous optimization of the cleaning schedule, The network fouling penalty function is evaluated
all exchangers would be considered at the evaluation using Eq. (16) and can be used to evaluate different
stage, with commensurate cost in computational time. scenarios, such as the benefit of instructing cleaning
The search space is therefore shrunk by using impact compared to taking no cleaning action.
criteria which denote when a unit is to be considered for tf
cleaning: a thermal impact, βΕ ( )
Obj = ∫ Q(t )C E + Clo m& target − m& (t ) dt + N c ⋅ Cc, m (16)
β E = ec − e (12) 0
CASE STUDY
and hydraulic impact, βP The PHT network in Figure 6 has parallel trains at
∆Pf the hot end of the system. Any of the exchangers can be
βP = (13) removed for cleaning. Two cost structures are
∆Pc investigated, with different energy costs and common
where the values of βι may vary from one exchanger to factors Clo - 5 US$/bbl (or 37 US$/te) and Cc - 5000
another depending on its design specification, or on $/clean: cost structure A - CE = 6.5 US$/MBtu (or 0.592
network targets such as run-down temperatures and US$/kW day); B (cheaper energy) CE -1 US$/MBtu (or
pumparound duty. A further condition to be satisfied 0.091 US$/kW day). Three scenarios are compared under
before considering a unit for cleaning is constructed by this case study, namely
estimating the financial benefit of cleaning and I. Operation without cleaning (base case)
comparing this with a threshold value, ∆G (typically a II. Operation with cleaning without flow split control
multiple of the cost of the cleaning operation). The (constant flow split)
improvement in heat transfer and throughput on cleaning III. Operation with cleaning and flow split control
is estimated and is assumed to remain constant over the (flow split control set to maximize throughput and
time horizon ∆tG following cleaning (which may be a then maximize heat recovery)
fixed period, such as 1 year, or the time left until the next
shutdown), yielding the criterion, The PHT operates continuously for a 3 year period
followed by a shutdown, with α = 1. A greedy algorithm
{C (m&
lo c ) clean
− m& f + C E β E Qmax }
∆t G > ∆ G (14) threshold value of 2000 US$ was used. Time was
discretized in one month intervals with one week sub-
where Clo is the cost of lost opportunity and CE the energy periods for cleaning: a sliding time horizon, ∆tG, of 6
cost. The transient in throughput and heat transfer during months was used and the period after shutdown of the
the cleaning period is not considered at this stage; Eq. network was not considered, i.e. as shutdown approached,
(14) simply considers the benefit in the refurbished state. ∆tG shortened. The furnace coil outlet temperature (used
Exchangers which satisfy these constraints are then to calculate the furnace duty) was set at 363°C to
compared using a detailed simulation over the horizon determine the heat duty imposed on the furnace.
and the full, integral form of the objective function, G, The results for the three case studies under two cost
Eq. (15) is evaluated. factors are summarized in Figures 8 and 9 and Table 3.
The importance of the flow split optimization is evident.
Gm period j The influence of the cost structures on throughput and the
t j+Ns scheduling of cleaning, and consequently on the entire
= ∫ {
C E Q(t ) no cleaning − Q(t ) clean m in period j dt} return, are also evident.
tj (15)
t j+N DISCUSSION
+ ∫
s
{ }
Clo m& (t ) clean m in period j − m& (t ) no cleaning dt The new simulator worked successfully, and the base
case scenario results matched those reported by Smaïli et
tj
al. The response of flow rates to the progress of fouling
− Cc, m
was represented, instead of assuming constant
throughput, thereby extending the previous work.
The time horizon is divided into intervals of equal length
The optimized schedules in Figure 9 proved to be
and the heat exchanger giving the highest positive value
very sensitive to the cost structure, in particular to the
of Gm is selected for cleaning. Only one exchanger is
relative costs of the lost profit opportunity consequent on
cleaned at a given time, in accordance with most
reduced throughput, and the energy costs incurred from
refineries’ practice between shut-downs.
sending a cooler stream to the furnace.
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Ishiyama et al.: 53
235 235
230 230
225 225
220 220
CIT (°C)
CIT (°C)
215 215
210 210
205 205
case I
case I
case II
200 case II
200 case III
case III
195 195
0 20 40 60 80 100 120 140 160 0 20 40 60 80 100 120 140 160
Time (weeks) Time (weeks)
(a-A) (a-B)
95.5 95.5
95 95
94.5 94.5
Mass flow rate (kg/s)
Mass flow rate (kg/s)
94 94
93.5 93.5
93 93
case I
case I
case II
92.5 92.5 case II
case III
case III
92 92
0 20 40 60 80 100 120 140 160 0 20 40 60 80 100 120 140 160
Time (weeks) Time (weeks)
(b-A) (b-B)
100,000 100,000
case I
case I
Cumulative lost production (tonnes)
case II
Cumulative lost production (tonnes)
case II
80,000 case III
80,000 case III
60,000 60,000
40,000
40,000
20,000
20,000
0
20 40 60 80 100 120 140 160 0
Time (weeks) 0 20 40 60 80 100 120 140 160
Time (weeks)
(c-A)
(c-B)
Fig. 8 Performance of case study PHT for scenarios I-III with cost structures A and B; (a) CIT (b) throughput, (c) cumulative
lost production.
14 14
13 13
12 12
Heat exchanger number
Under both cost structures, both scenarios II and III comparison of the schedules for individual exchangers in
show a decline in heat recovery and throughput until there Figure 9 indicates that that units 6-8 are cleaned quite
sufficient economic benefit to start cleaning. Figure 8 often, and a cleaning-based strategy may benefit from
shows that the onset of cleaning – the mitigation strategy replacing these units by two exchangers in parallel.
being considered in this work – is started at different Alternatively, an extra exchanger could be added and held
times depending on the cost structure. Cost structure A on standby to handle the duty while one of these units is
seeks to maximize energy recovery and cleaning starts off-line being cleaned.
later; cleaning also stops earlier as the period available for
recovering energy (and balancing the penalty incurred CONCLUSIONS
during the cleaning sub-period) is reduced as shutdown An analysis of the thermal and hydraulic impacts of
approaches. The latter feature is observed in most fouling has been presented. For fouling rate laws that
scheduling studies which consider fixed time horizons. incorporate the threshold fouling concept, characteristic
Cost structure B gives more emphasis to throughput and times for fouling of an exchanger were identified, based
the PHT is operated noticeably differently: cleaning is on hydraulic or thermal limitations. The importance of the
started earlier, once fouling causes the hydraulic limit to foulant thermal conductivity has been identified and the
be reached, and continues up to the shutdown in order to need for accurate values of this parameter highlighted.
maximize throughput (Figure 8(b)). The two cost The interaction between thermal and hydraulic
structures effectively demonstrate the difference between effects has been shown to give rise to thermo-hydraulic
energy- and throughput-dominated management channelling under certain conditions: the deleterious
strategies. impact of this phenomenon has been demonstrated using
Figure 9 shows that the network is cleaned often, a simple example.
which operators may view as too often. This is due to the MATLAB/Excel has been used to construct a
cost structure: an increase in Cc will reduce the frequency. highly flexible simulator intended to support the
It should also be noted that constant, linear fouling rates development of guidelines for exchanger and network
have been used in this case study and the implementation retrofitting. The code includes the characteristics
of fouling rate models sensitive to local conditions will generated by constant-speed centrifugal pumps operating
give more realistic results as the fouling rates will with control valves, and the change in throughput
generally decrease as the crude temperature decreases. resulting from saturating the control valve. The cleaning
The effect of manipulating the flow splits during and scheduling algorithm includes a filtering heuristic to
following cleaning actions is evident from comparing reduce the computational demands of the calculations,
scenarios II and III. The improvement in performance is which were performed using the ‘greedy algorithm’.
noticeable, both in terms of throughput and CIT. Flow The simulator has been tested successfully for the
split manipulation improves the attractiveness of a scheduling of cleaning operations. Simulated PHT
cleaning-based mitigation strategy, and installing performance has been improved by manipulating flow
equipment to allow flow manipulation represents a splits as fouling proceeds. The resultant cleaning
reasonably cheap retrofitting option. Furthermore,
http://dc.engconfintl.org/heatexchanger2007/9
Ishiyama et al.: 55
schedules are sensitive to the cost structure, which can be λ f thermal conductivity of the foulant layer, W/m K
simply set to favour throughput over energy recovery.
∆G greedy threshold value, US$
Acknowledgements
Funding from the EPSRC (EP/D50306X) is gratefully ∆P pressure drop, N/m2
acknowledged, as are helpful discussions with staff at ∆thy characteristic hydraulic time, day
Shell, bp, ConocoPhillips and Dr Graham Polley. ∆tth characteristic thermal time, day
∆tG sliding time horizon, day
NOMENCLATURE
a constant, kg/m3 s2 Subscripts
b constant, m4.75~5/ kg1.75~2 c clean state
A heat transfer area, m2 ends at the tube ends, headers etc.
Af constant, m2K/kW h f fouled state
Bif Biot fouling number, - i internal
C constant, m2/kW h Pa o outer
CC cost of cleaning heat exchanger, US$/clean tubes across the tubes
CE Energy cost, US$/kW
Clo Lost opportunity cost, US$/kg Superscripts
CP specific heat capacity c cold stream
CIT coil inlet temperature, °C h hot stream
dt tube internal diameter, m in inlet
e effectiveness, -
EII activation energy, J/ mol REFERENCES
Gm return on cleaning unit m, US$ Angadi, D., Hatch, C.M., Smaïli, F., Herbert, O.,
h heat transfer coefficient, W/m2 K Vassiliadis, V.S. & Wilson, D.I., 1999, ‘Optimisation of
m& mass flow rate, kg/s cleaning schedules in heat exchanger networks: Sugar
Nc number of cleaning actions, - refinery case study’, TransIChemE Part C, 77, 159-164.
NP number of periods, - Ebert, W. and Panchal, C.B., 1997, Analysis of
NS number of periods in greedy algorithm horizon, Exxon crude-oil slip stream coking data, in Fouling
dimensionless Mitigation of Industrial Heat Exchange Equipment,
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Pr Prandlt number, - Toyama, S. (eds.), Begell House, NY, 451-460.
Q furnace or exchanger heat duty, kW ESDU (Engineering Sciences Data Unit), 2000, Heat
R gas constant, J/mol K exchanger fouling in the preheat train of crude oil
Rf fouling resistance, m2K/W distillation levels, Data Item 0016, ESDU Intl., London.
RW wall resistance, m2K/W Georgiadis, M.C, Papageorgiou, L.G, and
Re Reynolds number, - Macchietto, S., 2000, ‘Optimal energy and cleaning
T temperature, K management in heat exchanger networks under fouling,
t time, day Ind. Eng. Chem. Res., 39, 441-454.
tf time at end of cleaning horizon, day Kotjabasakis, E. and Linnhoff, B., 1986, Sensitivity
TS surface temperature, K tables for the design of flexible processes. I. How much
U overall heat transfer coefficient, W/m2 K contingency in heat exchanger networks is cost-
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δ hy critical thickness (deposition) for hydraulic limit, m exchanger network (HEN) and planning the optimum
cleaning schedule, Energy Conservation and Design, Vol.
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ρ density, kg/m3
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Mitigation of fouling in refinery heat exchanger networks 2004, Mitigation of crude oil refinery heat exchanger
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concept, in Proc. Heat Exchanger Fouling and Cleaning:
λf ∆t hy a
∆tth b Rf Surface Initial
HE Uclean Area
(initial) Roughness fouling rate
Number (W/m K) (days) (days) (W/m2K) (m2)
(W/m2K) (m) (m2K/kWday)
0.1 108
0.5 22 (1) 0
1 26 463 0.000043 0.018 477
1 11 (2) 0.00001
2 5
a
∆tc,hy calculated on basis of ∆P / ∆Pclean reaching 1.1; b∆tc,th calculated on basis e decreasing by 10%.
Table 3: Summary of case study PHT performance under different operational strategies
Scenario I II III
Cost Structure A B A B A B
Average CIT (ºC) 216.0 216.0 218.6 219.0 222.0 222.7
Average throughput (kg/s) 94.0 94.0 94.4 94.6 94.8 94.9
Number of cleaning actions 0 0 8 15 15 19
Objective function (M US$) 22.2 6.3 20.6 4.3 18.3 3.2
Average heat duty delivered by the
network (MW) 40.5 40.5 41.3 41.6 42.1 42.3
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