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  • Poliol Lurgi Proces PDF

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    Agung Siswahyu
    73 Ansichten4 Seiten
    The document summarizes the production of PA polyester polyol from phthalic anhydride and diethylene glycol for use in polyurethane manufacturing. The process involves a two-stage esterification reaction between phthalic anhydride and diethylene glycol. This is followed by dioxane stripping and recovery of excess diethylene glycol. The typical aromatic polyester polyol product has properties suitable for production of rigid, flexible, foam and non-foam polyurethanes used in insulation, construction materials, packaging and more.

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    The document summarizes the production of PA polyester polyol from phthalic anhydride and diethylene glycol for use in polyurethane manufacturing. The process involves a two-stage esterification reaction between phthalic anhydride and diethylene glycol. This is followed by dioxane stripping and recovery of excess diethylene glycol. The typical aromatic polyester polyol product has properties suitable for production of rigid, flexible, foam and non-foam polyurethanes used in insulation, construction materials, packaging and more.

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    © All Rights Reserved
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    Markieren Sie unangemessene Inhalte
    73 Ansichten4 Seiten

    Poliol Lurgi Proces PDF

    Hochgeladen von

    Agung Siswahyu
    The document summarizes the production of PA polyester polyol from phthalic anhydride and diethylene glycol for use in polyurethane manufacturing. The process involves a two-stage esterification reaction between phthalic anhydride and diethylene glycol. This is followed by dioxane stripping and recovery of excess diethylene glycol. The typical aromatic polyester polyol product has properties suitable for production of rigid, flexible, foam and non-foam polyurethanes used in insulation, construction materials, packaging and more.

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    © All Rights Reserved
    Als PDF, TXT herunterladen oder online auf Scribd lesen
    Markieren Sie unangemessene Inhalte
    von 4

    engineering

    Lurgi Oel • Gas • Chemie

    PA Polyol from Phthalic Anhydride and


    Diethylene Glycol for Polyurethane
    PA Polyester Polyol from Phthalic Anhydride
    and Diethylene Glycol for Polyurethane Manufacture

    Production of Typical Product Properties Applications of PA Polyester Polyol


    Aromatic Polyester Polyol Acid value 2-3 ■ Polymerization with isocyanates to
    ■ Esterification of phthalic anhydride Hydroxyl value 300 - 330 polyurethanes
    with diethylene glycol Water content less than 0.1% ■ Production of rigid, flexible, foam
    1,4 dioxane content less than 1,000ppm and non-foam polyurethane qualities
    Process Steps
    ■ 2-stage esterification of phthalic Typical Consumption Data Applications of Polyurethanes
    anhydride with diethylene glycol per metric ton of PA Polyol ■ Rigid foams for thermal insulation,
    ■ Dioxane stripping Phthalic anhydride 440 kg construction and packaging
    ■ Recovery of surplus diethylene glycol Diethylene glycol 625 kg ■ Ricid material for molding car and
    ■ Optional: separation and purification Electrical energy cooler panels
    of dioxane Steam (6 bar) ■ Also suitable for: high temperature-
    Cooling water resistant foams for special industrial
    Mode of Operation insulation
    ■ Continuous or batchwise Features of the Process ■ Fexible foams for cushioning,
    ■ PA Polyol product has a decisive cost packaging and others
    Raw Materials advantage over polyether polyol
    ■ Phthalic anhydride from propylene oxide or polyester
    ■ Diethylene glycol polyol from adipic acid
    ■ Catalyst ■ Crude phthalic anhydride can
    ■ Additives (compatibilizers) be used
    ■ Heads cut and residue from PA
    distillation can be used

    STEPAN Process for Production of PA Polyol


    STEPAN Process for Production of PA Polyol

    Feed Plants Products Plants Products Applications


    (Examples)

    Butane Scrubber solution


    or Benzene MA plant MA plant
    Maleic anhydride
    Polyester

    MA recovery plant

    Fumaric acid Polyesters


    FA plant Food additives
    Feed additives

    Benzoic acid Benzoic acid


    Caprolactam
    Waste gas recovery Food conservation
    scrubber
    solution

    o-xylene PA plant Heads cut Saturated and unsaturated


    or Naphthalene alkyd resins
    Phthalic Paints
    anhydride Medicine
    Plasticizer*
    Plasticizer plant Soft PVC for
    Alcohol* cabel insulation
    Foils
    Vessel, tubes & pipes
    Polyol Forms
    Polyol plant Coatings
    Diethylene glycol Others

    Polyurethanes
    Polyurethane plant Fumiture
    Isocyanates Transportation
    Construction
    Industrial insulation
    Shoes
    Others
    * see special informationen concerning this folder
    PA = Phthalic Anhydride
    MA = Maleic Anhydride
    FA = Fumaric Acid

    Processes of the Oxidation and Hydrogenation Department


    engineering
    Lurgi Oel • Gas • Chemie

    2205e/9.99/10

    Lurgi Oel . Gas . Chemie GmbH . Lurgiallee 5 . D-60295 Frankfurt am Main


    Tel. +49 (69) 58 08-0 . Fax +49 (69) 58 08-38 88 . http://www.lurgi.com
    E-Mail: lurgi_oel_gas_chemie

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