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This Section contains 10 multiple choice questions. Each question has four choices A), B), C) and
D) out of which ONLY ONE is correct. (Mark only One choice) 10 × 4 = 40 Marks
II
H IV
III
a. b. c. d.
NO2 CH3
A
Sol. Electron withdrawing group on benzene will stabilize carbon anion
3. The correct order of stability of the following carbocations is
+
+ + +
a. (CH3)2CH > (CH3)3C > Ph3C >
+
b. > Ph3C+ > (CH3)3C+ > (CH3)2CH+
+
c. Ph3C+ > > (CH3)2CH+ > (CH3)3C+
+
d. (CH3)3C+ > (CH3)2 C H > > Ph3C+
Sol. =Tropylium ion is aromatic due to positive charge, therefore most stable
4. What product results from the complete Hydration of limonene, the structure of which is given below:
Limonene
OH
OH OH
a. OH
b. OH
a. OH
b. a. OH
OH
b. OH
OH
OH OH
c. OH d.
c. HO d. c.
c. d. OH
OH
OH
OH OH
OH OH OH OH
C
HO
Hydration
OH
Sol. Markovnikoff
addition of water
5. In the reaction,
CH = CH – CH3 + HBr Product ‘X’, X is:
Br Br
B
Br
–
HBr Br
Sol. CH = CH – CH3 CH – CH2 – CH3 CH – CH2 – CH3
Stable
carbocation
6.
Formula of Zeolite is M x AlO2 SiO 2
n
x 4
ZH2O. If x = 4 and metal is Ca+2, what will be formula of
zeolite
D
Sol. Formula M x ( AlO2 ) x (SiO 2 ) y H2O
n
Negative charge on anion is equal to number of Aluminium atom. M is metal ion and ‘n’ is charge of
metal ion (M) e.g. if x = 4. Charge on anion will be 4 and number of calcium ion will be two. Correct
formula is Ca2[(AlO2)4(SiO2)y]ZH2O
7. Hydride of boron occurs as B2H6 but B2Cl6 does not exist. This is because
CH2 – CH2 – Br
a. b. c. d.
Br Br
B
Br CH2CH3 CH – CH3 HC = CH2
Br
10. Which of the following is correct match.
This Section contains 9 multiple choice questions. Each question has four choices A), B), C) and
D) out of which ONLY ONE is correct. (Mark only One choice) 9 × 4 = 36 Marks
(a) If both assertion and reason are true and reason is the correct explanation of assertion.
(b) If both assertion and reason are true and reason is not correct explanation of assertion
(c) If assertion is correct but reason is incorrect
(d) If assertion is incorrect but reason is correct
1. Assertion: 3° carbocation [(CH 3 )3 C] is more stable than 2° carbocation [(CH 3 )2 CH ] and 2°
carbocation is more stable than the 1° carbocation (CH 3 CH 2 ) .
Reason: Greater the number of hyperconjugative structures, more is the stability of carbocation.
This Section contains 2 Comprehension. Each of these questions has four choices A), B), C) and D)
out of which ONLY ONE is correct. 7 × 4 = 28 Marks
Comprehension – 1
Boron is extremely hard, low density solid with high melting point. Boron is a rare element mainly
exist as Borax. Boric acid etc. Borax is most important compound of Boron. It is sodium salt of
tetraboric acid. Boric acid is weak monobasic acid.
Comprehension – 2
The elements of group 1 describe, more clearly than any other group of elements, the effects of
increasing the size of atoms or ions on the physical and chemical properties. The chemical and
physical properties of the elements are closely related to their electronic structures and sizes. These
metals are highly electropositive and thus form very strong bases, and have quite stable oxo-salts. In
the manufacturing of sodium hydroxide, chlorine and sodium carbonate, the sodium chloride is used
as starting material.
4. Sodium hydroxide is manufacture by the electrolysis of brine solution. The reaction by-products are:
a. I, II and III only b. I, II, III and IV c. II and IV only d. I and IV only
B
6. The solubility of the fluorides and hydroxides of alkaline earth metals increases on descending the
group because the
a. lattice energy of the compounds increases more rapidly than the hydration energy
b. lattice energy of the compounds decreases more rapidly than the hydration energy
c. size of the metals decreases on descending the group
d. ionization energy of the metals increases on descending the group.
B
A B C A B C
a. CaCO3 CH4 Ca(CN)2 b. CaC2 C2H2 CaCN2
c. CaC2 C2H2 Urea d. Ca2C3 C3H4 NH3
B
(A)
CaO C CaC 2 CO
Sol.
N2
| HOH
| CH CH Ca (OH)2
CaCN 2 C
(B)
( C)
[N = C = N]–2; Cyanamide ion
It is isostere of CO2 & on hydrolysis give urea.
This Section contains 10 multiple choice questions. Each question has four choices A), B), C) and
D) out of which ONE OR MORE may be correct. 10 × 5 = 50 Marks
a. BF3 b. CCl 2 c. NH4 d. IΘ
A,B
H
|
Sol. H N H Complete octet, not electrophilic.
|
H
2. Which of the following alkane cannot be prepared by hydrogenation of alkene by Ni + H2.
CH3 CH3
| |
a. CH 3 C H CH 3 b. CH 3 C CH 3
|
CH3
CH3
|
c. CH4 d. CH 3 C H CH 2 CH 3
B,C
3. Which of the following give same alkane on decarboxylation.
a. CH 3 C H CH 2 COOH b. CH 3 C H COOH
| |
CH3 CH3
c. CH3 – CH2 – CH2COOH d. CH 3 CH CH 2 CH 2 COOH
|
CH3
B,C
Sol. Both will form propane
O O O O O O O O
N N N N
H3C CH3 I I
a. b. c. d.
H3C CH3
C,D
Sol. Steric hindrance due to larger size of – CH3 and – I.
6. Which of the following statements regarding hydrogen peroxide is(are) incorrect?
a. The two hydroxyl groups in hydrogen peroxide lie in the same plane.
b. Aqueous solution of H2O2 turns blue litmus red.
c. When H2O2 behaves as a reducing agent, the O – O bond in its molecules is not broken down.
d. Aqueous solution of H2O2 is stored in plastic bottles and some urea, phosphoric acid or glycerol
is added to that solution.
A,B
Sol. H2O2 has non-planer structure; H2O2 is stored in plastic Bottle
7. Which of the following is correct as indicated
This Section contains 3 questions. Each question has four choices (A, B, C and D) given in
Column I and five statements (p, q, r, and s) in Column II. 8 × 3 = 24 Marks
Sol. A Q; B P & R; C R; D S
3. Match the particular given in column (I) with the compound(s) in column (II).
This Section contains 8 questions. The answer to each question is a Single Digit Integer ranging
from 0 to 9. (8 × 4 = 32 Marks)
Cl2/h
1.
Find out number of monochlorinated products (including stereoisomers) which are possible in the
above reaction:
Sol. 3 Cl
Cl2
+
hv
Cl
2. Which of the following groups on Benzene ring will make it meta directing:
O
CH 3 O O
| || ||
– C N; N ; C CH 3 ; OH; C N H2 ; N H2 ; C H ;
O |
CH 3
O
||
C Cl ; – Cl;
O O O
|| || ||
Sol.6; CN, NO2, – C(CH3)3; C NH 2 ; C H; C Cl
3. How many of the following will show Geometrical Isomerism.
CH3 CH3
CH2 = CH2; C=C ;
CH3 – CH = CH – CH3; H C CH CH 3 ;
|
H3C CH3 Cl
B B BH B
HN NX HN NH XN N–X HN NH
; ; ;
HB BH H–B B–X H–B B–H HB BH
N N N N
H H H
X
5. How many of the following are Amphoteric oxides
Al2O3; BeO; GeO; SnO2; PbO2; PbO; CaO; SiO2; B2O3; CO; MgO; Li2O
Sol. 6
Al2O3; BeO; GeO; SnO2; PbO2; PbO
6. How many of the following compounds are more reactive than Benzene in electrophilic substitution
reaction.
Cl CN CH = CH2 SO3H CH3
; ; ; ;
COOH NH – C – CH3
; ;
; ; ;