171808192

FIITJEE
PHYSICS, CHEMISTRY & MATHEMATICS
CPT1 - 4 PAPER - 1
SET - A
Time Allotted: 3 Hours Maximum Marks: 210
 Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
 You are not allowed to leave the Examination Hall before the end of the test.
INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer
OMR sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.
BATCHES – 1820
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Parts.
3. Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
4. Each part is further divided into two sections: Section-A & C
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
B. Filling of OMR Sheet

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on
OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment
No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All Two Parts.

(i) Section-A (01 – 10) contains 10 multiple choice questions which have one or more than one correct
answer. Each question carries +4 marks and – 2 mark for wrong answer.
(ii) Section-C (01 – 10) contains 10 Numerical based questions with single digit integer as answer,
ranging from 0 to 9 (both inclusive) and each question carries +3 marks for correct answer and – 1
mark for wrong answer.
Name of the Candidate :____________________________________________
Batch :____________________ Date of Examination :___________________
Enrolment Number :_______________________________________________

PT-4-2019(1820) (Paper-1) Set-A – PCM-2
Useful Data Chemistry:

Gas Constant = 8.314 J K1 mol1
R
= 0.0821 Lit atm K1 mol1
= 1.987  2 Cal K1 mol1
Na = 6.023  10
23
Avogadro's Number
h = 6.626  10 Js
–34
Planck’s Constant
-27
= 6.25 x 10 erg.s
1 Faraday = 96500 Coulomb
1 calorie = 4.2 Joule
-27
1 amu = 1.66 x 10 kg
-19
1 eV = 1.6 x 10 J
Atomic No : H=1, D=1, Li=3, Na=11, K=19, Rb=37, Cs=55, F=9, Ca=20, He=2, O=8,
Au=79. V = 23, Cr = 24, Co = 27, Xe = 54
Atomic Masses: He=4, Mg=24, C=12, O=16, N=14, P=31, Ar=40, Cr=52, Br=80, Cu=63.5, Fe=56,
Mn=55,
Pb=207,
Au=197, Ag=108, F=19, H=1, Cl=35.5, Sn=118.6
Useful Data Physics:
Acceleration due to gravity g = 10 m / s2
FIITJEE Ltd., Bhopal Centre, 48-A, Gurukripa Plaza, Zone – 2, M.P. Nagar, Ph. 0755-42553355, 4253455
website: www.fiitjee.com
(JEE ADV PAPER – 1 SET - A) 3
S
SEEC
CTTIIO
ONN--1
1 :: P
PHHY
YSSIIC
CSS
PART – A
(Multi Correct Choice Type)
This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONE OR MORE may be correct.
1. Initially switch is open. After some time switch is closed. Choose the correct
statements
(a) the charge flown through the switch is 54 C
(b) Point b is at higher potential than point a before the switch is closed
(c) the potential of point b is 6V w.r.t. ground, after s is closed
(d) the potential of point b is 12V, after s is closed
2. As shown in the figure find the correct statement/s :
(a) i at instant switch is closed is 2A

(b) i after long time is 2A
16
(c) charge on 4F after long time is C (when switch is closed)
3
(d) charge on 2F at instant switch is closed is 8C
3. An alpha particle enters in the region between the plates of

capacitor at an angle 60º and leaves the region at an angle
of 30º, then
(a) The ratio of speeds entering and leaving the region is

3 :1
(b) The ratio of K.E. entering and leaving the region is 1 : 3
(c) The path inside the region is circular
(d) The path inside the region is parabolic
space for rough work
PT-4-2019(1820) (Paper-1) Set-A – PCM-4
4. Three capacitors C1  2F, C2  3F and C3  4F are

separately charged with battery of potential difference 40V,
30V and 10V respectively and then disconnected. After then
they are connected to each other as shown in figure.
(a) Amount of charge flown in circuit is zero
280
(b) Final change on capacitor C3  C
13
800
(c) Final change on capacitor C2  C
13
800
(d) Final change on capacitor C1  C
13
5. A thin walled, spherical conducting shell of radius r is given charge q0. The same amount of charge is also
placed at its centre C. Which of the following statements are correct ?
q0
(a) on the outer surface of shell, the charge density is
2r 2
(b) the electric field is zero at all points inside shell
(c) At a point just outside the shell, the electric field is double the field at a point just inside the shell
(d) At any point inside shell, the electric field is inversely proportional to the square of its distance from C.
6. In the shown circuit, switch s is closed at time t = 0. Select the correct

statement
(a) Rate of increase of charge is same in both the capacitors
(b) Ratio of charge stored in capacitors C and 2C at any time t is 1:2
(c) time constant of both the capacitors are equal
(d) Steady state charge on capacitors C and 2C are in ratio 1:2
7. An electric dipole is placed at the origin O such that its equator is y-axis. At a point P far away from dipole,
the electric field direction is along y-direction. OP makes an angle  with +x-axis such that
1
(a) tan   2 (b) tan   3 (c) tan   (d) tan   1
2
8. A micrometer has a resistance of 100 and a full scale range of 50A . It can be used as a
voltmeter or as a higher range ammeter provided a resistance is added to it. Pick the correct
range and resistance combinations(s)
(a) 50V range with 10k resistance in series (b) 10V range with 200k resistance in series
(c) 5 mA range with 1 resistance in parallel (d) 10 mA range with 1 resistance in parallel
9. Two bulbs consume same power when operated at 200 V and 300 V respectively. When these bulbs
are connected in series across a d.c. source of 500 V, then :
(a) ratio of P.D. across them is 3/2
(b) ratio of P.D. across them is 4/9
(c) ratio of power consumed across them is 4/9
(d) ratio of power consumed across them is 2/3
R 10V
10. AB is a potentiometer wire of length 100 cm and its resistance is 10. It
is connected in series with a résistance R = 90 and a battery of emf
10V and negligible internal resistance. A source of unknown emf E is 30cm C
balanced by 30 cm length of the potentiometer wire, with jockey position A
B
at C. G
E
(A) the value of E is 0.30 V (B) the value of E is 0.15 V
(C) VC – VB = 0.7 V (D) VC – VB = -0.7 V
PT-4-2019(1820) (Paper-1) Set-A – PCM-6
PART – C
(Integer Type)
This section contains 10 questions. The answer to each question is a single-digit integer, ranging from 0 to 9.
The correct digit below the question number in the ORS is to be bubbled.
1. A circuit is connected as shown in the figure with the 3F 6F

X
switch S open. When the switch is closed, if total
amount of charge that flows from Y to X is Q(in C),
S
Q
then =
3 Y
3 6
9V
V(volt)
2. A battery of emf E and internal resistance r
is connected with external resistance R. 10
Resistance R can be adjusted to any value
greater than or equal to zero. Graph is
plotted between the current passing through
the resistance (I) and potential difference I(amp)
(V) across it. Internal resistance of the 2
battery ( in  ) is
3. Two identical charged spheres are suspended by strings of equal length (spheres are suspended from
same point). The strings make an angle of 30° with each other. When suspended in a liquid of density
3
800 kg/m , the angle remains the same. What is the dielectric constant of the liquid ? The density of the
3
material of the spheres is 1600 kg/m .
4. A capacitor of capacity C1 = 1.0 F withstands the maximum voltage V1 = 6kV while another capacitor of
capacitance C2 = 2 F withstands the maximum voltage V2 = 4 kV. What maximum voltage (In kV) will the
system of these two capacitors withstand if they are connected in series?
5. Potential difference across C2 in steady state is _______ V.
6. A point charge q  2c is located at the center of a thick uncharged conducting stell of inner radius 2m
and outer radius of 3m. There is a small orifice in the shell. Work done by external agent to take this
charge from center of shell to  is x × 10 , then x is
-3
7. A capacitor of capacity 4F is connected across a bettery of emf 100V. Then work done in order to
-2
double the plate separation is x × 10 Jule. Here x is
8. A sphere of radius R has uniformly distributed charge density  . There is a spherical cavity whose
centre is at C, as shown in figure. It is given that AB = d, OC = l and the angle between OC and AB
5
is 60°. The work done by field in moving a point charge q  C from A to B is:
9
(It is given that  ld  54  106  0 )
B
C
O  A
9. A capacitor C1  1F can withstand a maximum voltage V1  6 KV while C2  3 F can

withstand maximum voltage V2  4 KV . If they are connected in series, the maximum voltage this
combination can withstand is 8n KV. The value of n is:
10. VA – VB for given figure in steady state is
PT-4-2019(1820) (Paper-1) Set-A – PCM-8
S
SEEC
CTTIIO
ONN--2
2 :: C
CHHE
EMMIIS
STTR
RYY
PART– A
1. Which of the following will give yellow ppt of CHI3 when treated with NaOI.
(a) O O (b) O O
H3C C CH2 C OEt H3C C CH2 CH
(c) O (d) OH
I 3C CH O
2. Which of the following can reduce Fehling's solution

(a) Formic acid (b) 1-hydroxy-3-pentanone
(c) 1-methoxy ethanol (d) Acetaldehyde
3. Which of the following are correct for reaction?

O O
Br2 + NaOH 
CH3 H
A+B C + CO2

(a) A is Br (b) C is O O
Br
OH
Br
(c) B is O (d) C is O
- +
COO Na
4. In which of the following reaction no. of carbon atom decreases in the product.
 , CaO
(a) RCONH 2 KOH + Br2
 (b) RCOONa  
(c) RCOCl   RCOCl  
(i) NH 2 -NH 2 , (ii) NaNO 2 + HCl (i) CH 2 -N 2 , (ii) AgOH
(iii) H O/OH -
(d) (iii) H O/H +
2 2
5. B2 
Sn/HCl
 A 2 
alc AgCN
 CH3  Br 
alc KCN
 A1 
Sn/HCl
 B1
B1 and B2 can be distinguished by
(a) HNO2 (b) CHCl3 + NaOH (c) CS2 and HgCl2 (d) Hinsberg reagent
6. CH3
H Cl
H  P
NaI / acetone
H3C
Cl
Correct option(s) is/are
(a) Reaction with Br2 / CCl4 ; P will form a meso compound
(b) Reaction with Cl2 / H2O ; P will form a diastereomer pair
(c) Reaction with OsO4 / NaHSO3, P will form a recemic mixture
(d) Reaction with Baeyer Reagent, P will form a meso compound
 m     m o n o c h lo r in a te d p r o d u c ts
o n o c h lo rin a tio n
7.
Correct statement(s) about the number of products formed is/are
(a) Number of diastereomeric pairs is 4
(b) Number of optically inactive compounds formed is 2
(c) Number of enantiomeric pairs is 4
(d) Number of total monochlorinated compounds formed is 7
PT-4-2019(1820) (Paper-1) Set-A – PCM-10
8. Which of the following reactions involve hydride ion transfer?

(a) O O

OH 
2H – C – H H – C – O + CH3 – OH
(b) O
O

OH
2H3C – C – H  H3C – CH = CH – C –H
(c) O
O
Al(OEt)3
2H3C – C – H CH3 – C – O – CH2CH3
(d) R2CO + [Me2CHO]3Al 
dil . H 2 SO4
 R2CHOH + MeCOMe
9.
O O

15 OH + Br2
Ph – C – NH2 + Ph – CH2 – C – N H2 A+B
Products A and B are:
(a) 15
(b) 15 15
Ph – N H2 & Ph – CH2 N H2 Ph – CH2 N H2 & Ph – N H2
(c)
15
(d) Ph – N H2 & Ph – CH2 – NH2
Ph – CH2 N H2 & Ph – N H2
10. Which of the following will not be hydrolysed in basic medium
(a) CH3  CN (b)
O O
(c) O (d) CH3  CH2  NC
H3C C O CH2 CH3
PART – C
(Integer Type)
Benzene + acetic anhydride  (A)  (B) 

AlCl
SeO2 Conc KOH
1. 3
(P)
Degree of unsaturation present in P is ______
2. 0.344 gm of acetyl derivative of a polyhydric alcohol (Molecular Wt. of Alcohol = 92) require 0.336 gm
KOH for hydrolysis. Calculate the number of hydroxyl groups in the alcohol.
3. H H
H3C C COOH   + H3C C OH   Ester

C2 H5 C2 H5
Find the total number of esters formed.
4. HIO4
R – CH – CH – CH2OH
OHOH
How many organic products are obtained in this reaction?
5.
R number of products 

HCl
 
Br2 /CCl4
 P number of products
D D
Cold alkaline dil KMnO 4
Q number of products
Then the value of half of sum of P, Q and R is _____
PT-4-2019(1820) (Paper-1) Set-A – PCM-12
+
6. Identify the most favourable site for the attack of H .
1 O
2
3
4 N
CH3
7. The molecular formula of an amine is C5H13N. How many C–N bond(s) is/are present in its most basic
isomer(in gas phase)?
 x     C4H8Br2  [Five such products are possible]


8. Et  CH Me 
H Br2 /CCl4
| H2 o
OH
How many structure of X are possible?
9. The half of total number of N–C bonds in the compound obtained when formaldehyde reacts with
ammonia is______.
10. How many following alcohols show positive iodoform test?

HO
CH2OH OH OH
OH
, , , , ,
H2CH3C OH
OH
OH
, , ,
OH CH CH3
OH
S
SEEC
CTTIIO
ONN--3
3 :: M
MAAT
THHE
EMMA
ATTIIC
CSS
PART – A
2x 2  3  x  1 1 x
1. If  (x 2
 1)(x 2  4)
dx  alog 
 x  1   b tan 2  c , then

1 1 1 1
(a) b   (b) a  (c) b  (d) a  
2 2 2 2
3x 2  12x  1,x  [ 1,2] 

2. If f(x)    then
37 - x , x  (2,3] 
(a) f(x) is monotonic increasing in [-1, 2] (b) f(x) is continuous in [-1, 3]
(c) f(x) has the maximum value at x = 2 (d) f’(2) does not exist
x
3. If f  x   lim , then
n  x 2n  1
   
(A) f 1  f 1  0    
(B) f 1  f 1  f 1  3 / 2
(C) f  1   f  1   1
 
(D) f 1   f  1   0
 
If f '  x   g  x  x  a  where g  a   0 and g is continuous at x=a, then

2
4.
(A) f is increasing in the neighbourhood of a if g  a   0
(B) f is increasing in the neighbourhood of a if g  a   0
(C) f is decreasing in the neighbourhood of a if g  a   0
(D) f is decreasing in the neighbourhood of a if g  a   0

ln tdt
5. Integral values of x satisfying the equation 4   ln 2  0 : x  0
0 x2  t 2
ln 4
(a) 2 (b) e (c) eln 2 (d) 4
PT-4-2019(1820) (Paper-1) Set-A – PCM-14
6. Which of the following functions do not satisfy conditions of Rolle’s Theorem-

   3
(A) ex sin x, 0, (B) (x + 1)2 (2x – 3)5,  – 1,
 2   2 
1   
(C) sin |x| , [, 2] (D) sin , , 
x  2 2
 x2 
7. If h(x) = 3f   +f(3 – x2)  x  (–3, 4), where f" (x) > 0  x (–3, 4), then h (x) is -

 
3
3   3 
(A) increasing in  , 4  (B) increasing in   ,0
2   2 
 3  3
(C) decreasing in   3,   (D) decreasing in  0, 
 2  2
 
If f(x) = sin x +  sin x, –
3 2
8. <x< then-
2 2
(A) f(x) has a point of inflexion if  = 0
(B) f(x) has exactly one point of maximum & exactly one point of minimum if || < 3/2
(C) f(x) has exactly one point of maximum and exactly one point of minimum if
  (–3/2, 0)  (0, 3/2)
(D) all above
9. Let the function f(x) be defined as follows :

 x 3  x 2  10x ;  1  x  0

f(x) =  cos x ; 0  x  /2
 1  sin x ; /2  x  

Then which of the following statement(s) is/are correct
(A) Local maximum at x = 0 (B) Local maximum at x = /2
(C) Absolute maxima at x = – 1 (D) Absolute minima at x = 
10. Which of the following limits tends to unity?

sin(tan t ) sin(cos x )
(A) lim (B) lim
t0 sin t x  / 2 cos x
1 x  1 x x2
(C) lim (D) lim
x 0 x x0 x
PART – C
(Integer Type)
x5 x3
1. If f(x) = 8  (16  c )x then, the range of value of c so that function is one-one [K, ), then
5 3
integral K is ___

2. The value of  ln(1  cos x )dx = Kln2 then |[K]|
0
12  22  3 2  ....  r 2 n
  1 t r M
3. tr = and Sn = r , then find lim Sn =  then M is____
13  23  33  .....r 3 r 1
n 3
3 cos 2x  1
4. If  cos x
dx = a sin1  
3 sin x  2sin1  
b tan x  c then a + b = ____
3 2
5. The minimum positive integral value of a for which the function f(x) = ax –9x + 9x + 3 is increasing for
all real values of x is K. What is K ?
PT-4-2019(1820) (Paper-1) Set-A – PCM-16
c
6.
x 1

If lim 1  ax  bx 2  x 1
 e3 , then the value of bc is________.
a x  1 if 0  x  3
7. Let g(x) =  , if g(x) is differentiable on (0, 5) then (a + b) equals_______.
 bx  2 if 3  x  5
   2x
3
log log27 x 2 1
2 21/ 4 x
3 dy
8. Let y  and  ax  b , then the value of a + b is __________.
7 4log49 x
 x 1 dx
Let C be a curve defined by y  ea bx . The curve C passes through the point P (1, 1) and the slope of the
2
9.
tangent at P is (–2). Then the value of 2a – 3b is _______.
–1 –1
10. Number of points of non-differentiability of function f(x) = max {sin |sinx|, cos |sinx|}, 0 < x < 2 is

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PHYSICS, CHEMISTRY & MATHEMATICS

B. Filling of OMR Sheet

C. Marking Scheme For All Two Parts.

Name of the Candidate :____________________________________________

Batch :____________________ Date of Examination :___________________

Enrolment Number :_______________________________________________

Useful Data Chemistry:

Acceleration due to gravity g = 10 m / s2

2. As shown in the figure find the correct statement/s :

(a) i at instant switch is closed is 2A

3. An alpha particle enters in the region between the plates of

(a) The ratio of speeds entering and leaving the region is

(b) The ratio of K.E. entering and leaving the region is 1 : 3

(c) The path inside the region is circular

(d) The path inside the region is parabolic

space for rough work

4. Three capacitors C1  2F, C2  3F and C3  4F are

(a) Amount of charge flown in circuit is zero

6. In the shown circuit, switch s is closed at time t = 0. Select the correct

space for rough work

space for rough work

1. A circuit is connected as shown in the figure with the 3F 6F

5. Potential difference across C2 in steady state is _______ V.

space for rough work

9. A capacitor C1  1F can withstand a maximum voltage V1  6 KV while C2  3 F can

10. VA – VB for given figure in steady state is

space for rough work

2. Which of the following can reduce Fehling's solution

3. Which of the following are correct for reaction?

space for rough work

space for rough work

8. Which of the following reactions involve hydride ion transfer?

10. Which of the following will not be hydrolysed in basic medium

(a) CH3  CN (b)

space for rough work

Benzene + acetic anhydride  (A)  (B) 

H3C C COOH   + H3C C OH   Ester

R number of products 

space for rough work

 x     C4H8Br2  [Five such products are possible]

10. How many following alcohols show positive iodoform test?

space for rough work

3x 2  12x  1,x  [ 1,2] 

If f '  x   g  x  x  a  where g  a   0 and g is continuous at x=a, then

space for rough work

6. Which of the following functions do not satisfy conditions of Rolle’s Theorem-

9. Let the function f(x) be defined as follows :

10. Which of the following limits tends to unity?

space for rough work

space for rough work

space for rough work

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