Beruflich Dokumente
Kultur Dokumente
Contents
JJ II
∗
I Wayan Warmada J I
warmada@yahoo.com
Page 1 of 39
Go Back
Full Screen
Close
Quit
∗ Laboratory of Mineral Resources, Geological Engineering, UGM
Terminology of zeolite
• The name ’zeolite’ was introduced by the
Swedish mineralogist Cronstedt in 1756 for
Home Page
certain silicate mineral in allusion to their be-
haviour on heating in a borax bread (Greek zeo Title Page
tetrahedra. Page 3 of 39
Go Back
• Application of definition: relatively easy ex-
change of extra-framework cations at rela- Full Screen
J I
• Activated carbon, activated clays, aluminum
Page 5 of 39
oxide, and silica gels are also molecular
sieves. Go Back
Full Screen
Close
Quit
Zeolite classifications
Crystal Void Volume,
Zeolite Typical Unit-Cell Formula System %
Analcime Na16(Al16Si32O96)•16H2O Cubic 18 Home Page
Quit
Specific Channel Thermal Ion-Exchange
Zeolite Gravity Dimensions, A Stability Capacity*
Analcime 2.24 – 2.29 2.6 High 4.54
Chabazite 2.05 – 2.10 3.7 × 4.2 High 3.81
Clinoptilolite 2.16 3.9 × 5.4 High 2.54 Home Page
2.8 × 4.8
Full Screen
3.3
Linde A† 1.99 4.2 High 5.48 Close
abundant. Quit
• Chabazite, clinoptilolite, erionite, mordenite,
and phillipsite are the only zeolite minerals
with commercial applications today.
cations.
Contents
Quit
• The net negative charge of the structure is
balanced by exchangeable cations, which are
loosely held within the central cavities and
surrounded by water molecules.
Home Page
Home Page
Title Page
Contents
JJ II
J I
Page 14 of 39
Go Back
Full Screen
Close
Title Page
Contents
JJ II
J I
Page 15 of 39
Go Back
a) amorphous gel-like phase; b) initial glass alteration product with Full Screen
fibrous aspect; c) acicular cluster (phillipsite?); d) phillipsite crystals
(de’Gennaro et al., 2000) Close
Quit
Home Page
Title Page
Contents
JJ II
J I
Page 16 of 39
Go Back
e) phillipsite crystals lining cavities in glass shard; f) glass shard; g) euhe- Full Screen
dral chabazite crystals; h) acicular cluster covering glass shards structure
(de’Gennaro et al., 2000) Close
Quit
Home Page
Title Page
Contents
JJ II
J I
Page 17 of 39
Go Back
Full Screen
Title Page
Contents
JJ II
J I
Page 18 of 39
Go Back
Full Screen
Close
e) opal-CD lephisphere encrusting clinoptilolite; f) encrusting opal-CT; g)
fibrous mordenite; h) adularia-like K-feldspar crystals (Cerri et al., 2001).
Quit
Home Page
Title Page
Contents
JJ II
J I
Page 19 of 39
Go Back
Full Screen
Title Page
Contents
JJ II
J I
Page 20 of 39
Go Back
Full Screen
e) subtle sedimentary structures; f) clinoptilolite cementing detrital clasts;
g) opal-CT lephispheres along with clinoptilolite crystals; h) smectite ag- Close
gregates and clinoptilolite crystals (Cerri et al., 2001).
Quit
Characterizations
• Natural zeolite minerals are identified primar-
ily by their crystal habit.
Home Page
Page 21 of 39
– X-ray Diffraction
Go Back
– Scanning Electron Microscopy
Full Screen
– Optical Microscopy
Close
– Different Thermal Analysis
Quit
• In characterizing zeolitic materials for com-
mercial uses, it is important to quantify other
physical and chemical properties required by
the specific application.
Home Page
Full Screen
Close
Quit
Zeolite characteristics
A B
Home Page
Title Page
Contents
JJ II
C D
J I
Page 23 of 39
Go Back
Full Screen
Close
Home Page
Title Page
C D Contents
JJ II
J I
Page 24 of 39
Go Back
Full Screen
Close
Home Page
Title Page
Contents
C D
JJ II
J I
Page 25 of 39
Go Back
Full Screen
A-B) chabazite in thin section, PPL and XPL; C) heulandite, XPL; D) lau-
Close
montite, XPL.
Quit
A B
Home Page
Title Page
Contents
C D JJ II
J I
Page 26 of 39
Go Back
Full Screen
Close
A) mordenite crystals, in SEM; B) clinoptilolite; C-D) mordenite and
clinoptilolite. All sample from Sidomulyo.
Quit
Home Page
Title Page
Contents
JJ II
J I
Page 27 of 39
Go Back
Full Screen
Close
1–2) chabazite; 3) phillipsite; 4) heulandite (Passaglia & Vezzalini, 1985)
Quit
Home Page
Title Page
Contents
JJ II
J I
Page 28 of 39
Go Back
Full Screen
a) acicular crystals of phillipsite; b) rhombohedral chabasite; c) phillipsite-
chabazite; d) analcime (de’Gennaro et al., 2000) Close
Quit
Zeolite applications
• The principal uses of zeolites at this time are:
Full Screen
• Aquaculture: zeolite are used in aquarium,
fish farms, and fish hatcheries to avoid the Close
Page 31 of 39
• Dimension stone: zeolitic tuffs have been used
for thousand of years as lightweight, durable Go Back
Close
Quit
Occurrences (Java Island)
West Java
• Nanggung (Bogor) Home Page
Title Page
• Bayah and Leuwidamar (Lebak)
Contents
Go Back
Central Java and Yogyakarta
Full Screen
• Trembono (Klaten)
Home Page
Contents
• G. Cagak, Wonosidi (Pacitan)
JJ II
• Slahung (Ponorogo)
J I
Go Back
• Tembarejo and Sumbermajing (Malang)
Full Screen
Close
Quit
References
• Cerri, G., Cappelletti, P., Langella, A.,
de’Gennaro, M. (2001) Zeolitization of Oligo-
Home Page
Miocene volcaniclastic rocks from Logudoro
(northern Sardinia, Italy). Contrib Mineral Title Page
Close
• Graham, I.T., Pogson, R.E., Colchester, D.M.,
Baines, A. (2003) Zeolite crystal habits, com- Quit
positions, and paragenesis; Blackhead Quarry,
Dunedin, New Zealand. Mineralogical Maga-
zine, v. 67, pp. 625–637.
JJ II
J I
Page 39 of 39
Go Back
Full Screen
Close
Quit