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TABLE OF CONTENTS
4. MECHANICS........................................................................................................................................................ 10
4.1 QUANTITY........................................................................................................................................................................................... 10
4.2 VELOCITY ........................................................................................................................................................................................... 10
4.3 ACCELERATION................................................................................................................................................................................. 10
4.4 LINEAR MOTION................................................................................................................................................................................ 10
4.5 FORCE (NEWTONS FIRST & SECOND LAW)................................................................................................................................ 11
4.6 SPRING FORCE (HOOKE’S LAW).................................................................................................................................................... 11
4.7 FRICTION FORCE ............................................................................................................................................................................... 11
4.8 WEIGHT................................................................................................................................................................................................ 11
4.9 MOMENTUM ....................................................................................................................................................................................... 11
4.10 WORK (SIMPLE MECHANICAL) ..................................................................................................................................................... 12
4.11 MECHANICAL ENERGY ................................................................................................................................................................... 12
4.12 POWER ................................................................................................................................................................................................. 13
5. FLUIDS.................................................................................................................................................................. 14
5.1 DENSITY .............................................................................................................................................................................................. 14
5.2 PRESSURE (ENERGY DENSITY) ..................................................................................................................................................... 14
5.3 PRESSURE (POTENTIAL ENERGY DENSITY) .............................................................................................................................. 14
5.4 PRESSURE (KINETIC ENERGY DENSITY) .................................................................................................................................... 14
5.5 BERNOULLI EQUATION (ENERGY BALANCE) ........................................................................................................................... 15
5.6 BERNOULLI EQUATION (IN LIQUID HEAD TERMS).................................................................................................................. 15
5.7 HYDRAULIC POWER (WATER)....................................................................................................................................................... 15
6. GAS LAWS............................................................................................................................................................ 16
6.1 JOULE THOMSON EXPANSION (TEMPERATURE ESTIMATION) ............................................................................................ 16
6.2 IDEAL GAS LAW (MOL).................................................................................................................................................................... 16
6.3 CALCULATION OF MOLECULAR MASS....................................................................................................................................... 17
6.4 AVOGADRO'S NUMBER ................................................................................................................................................................... 17
6.5 MOL - KG - LITRE (STP) - M3 (STP) ................................................................................................................................................. 18
6.6 STANDARD TEMPERATURE AND PRESSURE, REFERENCE CONDITIONS .......................................................................... 18
6.7 CONVERSION OF UNIVERSAL TO CHARACTERISTIC GAS CONSTANT .............................................................................. 19
6.8 IDEAL GAS LAW (MASS).................................................................................................................................................................. 19
6.9 VAN DE WAALS EQUATION ........................................................................................................................................................... 20
6.10 REAL GAS LAW (MASS) ................................................................................................................................................................... 21
6.11 CALCULATION OF COMPRESSIBILTY FACTOR......................................................................................................................... 21
6.12 COMPRESSIBILTY FACTOR LOOK UP TABLE ............................................................................................................................ 22
7. SERVICE CALCULATIONS.............................................................................................................................. 23
7.1 CALCULATION OF PIPE FILL VOLUME........................................................................................................................................ 23
7.2 AIR INCLUSION .................................................................................................................................................................................. 23
7.3 ASSESSMENT FOR PRESSURE CHANGE WITH TEMPERATURE VARIATION METHOD 1 (FRESH WATER) ................ 24
7.4 ASSESSMENT FOR PRESSURE CHANGE WITH TEMPERATURE VARIATION METHOD 2 (SEA WATER) ..................... 26
7.5 PRESSURE CORRECTION FOR ELEVATION FROM TEST DATUM OR CALCULATION OF STATIC HEAD.................... 30
7.6 PRESSURE CORRECTION FOR TIDAL CHANGE ......................................................................................................................... 30
7.7 ESTIMATION OF PRESSURE CORRECTION FOR ALTITUDE CHANGE.................................................................................. 31
7.8 DIFFERENTIAL PRESSURE TO DRIVE A PIG – RULE OF THUMB ........................................................................................... 32
7.9 DIFFERENTIAL PRESSURE TO DRIVE A PIG ............................................................................................................................... 32
7.10 CALCULATION OF FLUID VELOCITY IN PIPES .......................................................................................................................... 33
7.11 CALCULATION OF FLUID PRESSURE DROP IN PIPES .............................................................................................................. 33
7.12 CALCULATION OF REYNOLDS NUMBER .................................................................................................................................... 34
7.13 CALCULATION OF FRICTION FACTOR LAMINAR FLOW Re <2000 .................................................................................... 35
7.14 CALCULATION OF FRICTION FACTOR TURBULENT FLOW 2000< Re <108 ....................................................................... 35
7.15 CALCULATION OF PRESSURE LOSS THROUGH FITTINGS AND VALVES........................................................................... 36
1.1 PURPOSE
The purpose of this manual is to ensure that HPPS personnel work to a common set of pre-
commissioning engineering calculations, formulae and reference tables. By doing so it will
ensure that there is consistency in results from any engineering analysis carried out across
the department relevant to pre-commissioning activities. Although many of the
calculations carried out by HPPS and our sub-contractors are done using spreadsheets or
bespoke software, it is important that we promote a culture of non-reliance on software and
develop an understanding of the basic concepts behind the work we perform.
Manual calculations also acts as a check on the review and approval process to ensure that
the analysis carried out, by other means, by our own personnel and the sub-contractors are
correct and satisfactory.
The calculations are broadly presented in SI units, conversions factors are also contained
within.
1.2 SCOPE
The reference calculations, formulae and tables contained within this document are to
allow individuals to estimate key project variables such as volumes, pressures,
environmental and physical constraints and power requirements.
Accurate estimation is key to operational success. Using a standard reference will allow us
to be consistent in approach. The content adopts industry standards and practices which are
accepted by most of the legislative bodies. Many of the calculations are referred to in the
Standards, Regulations and Codes of Practice we work to on behalf of our Clients.
2. MATHEMATICAL FORMULAE
2.1 ALGEBRA
2.1.1 Expansion Formulae
(x+y)2 = x2 + 2xy + y2
(x-y)2 = x2 - 2xy + y2
Then
− b ± b 2 − 4ac
x=
2a
2.2 TRIGONOMETRY
2.2.1 Basic Ratios
O A O
sin θ = cos θ = tan θ =
H H A
H
Hypotenuse
O
Opposite
θ
A
Adjacent
θ
A
Adjacent
b 2 = a 2 + c 2 − 2ac ⋅ cos B
3.1 AREAS
Rectangle Triangle
A=ab A= ½ b h
a
h
b b
a
Parallelogram Trapezoid
A=ab A = ½ (ab) h
a h
b b
Hexagon Cone
A = 3/2 a b A = π/2 ds
b s
h
d
a
Circle Elipse
A = π d2/4 A = π2 dD/4
d d
D
Sphere
A = π d2
d
3.2 VOLUMES
Cube Cylinder
V=abc (Pipeline) V = πd2/4 L
L Vol/meter
a d
V = πd2/4
c
b
Sphere
V = πd3/6
πr 2 L ⎛ ⎛ h( 2r − h) ⎞ −1 ⎡ h ⎤ ⎞⎟
− rL⎜ (r − h ) × ⎜
L
v= ⎟ + r ⋅ sin 1 −
⎢⎣ r ⎥⎦ ⎟
2 ⎜ ⎝ r2 ⎠
⎝ ⎠
r h
Where; L = length of tank radius
liquid
r = radius of tank height
h = height of liquid
Volume of a partially filled horizontal cylindrical tank with ellipsoidal ends can be calculated as below:
πr 2 L ⎛ ⎛ h( 2r − h) ⎞ ⎡ h⎤⎞ ⎡ h⎤
v= − rL⎜ (r − h ) × ⎜ ⎟ + r ⋅ sin −1 ⎢1 − ⎥ ⎟ + πah 2 ⎢1 − ⎥
2 ⎜ ⎝ r 2
⎠ ⎣ r ⎦ ⎟⎠ ⎣ 3r ⎦
⎝
4. MECHANICS
4.1 QUANTITY
Scalar - a property described by a magnitude only e.g. Speed
Vector - a property described by magnitude and direction e.g. Velocity
4.2 VELOCITY
s
v=
t
Where:
Variable Description UNITS (Metric)
s Distance / displacement m
t Time s
v Velocity ms-1
4.3 ACCELERATION
∆v v −u
a= a=
∆t t f − t0
Where:
Variable Description UNITS (Metric)
a acceleration ms-2
∆t Time interval t f − t0 s
t0 Start Time s
4.8 WEIGHT
Weight = F = m ⋅ g
Where:
Variable Description UNITS (Metric)
F Force (Newton) N (kgms-2)
m Mass kg
g Acceleration due to Gravity (9.812ms-2 ) ms-2
4.9 MOMENTUM
p = m⋅v
Where:
Variable Description UNITS (Metric)
p momentum kgms-1
m mass kg
v velocity ms-2
4.12 POWER
P =W /t P = Q/t P = F ⋅v
Where:
Variable Description UNITS (Metric)
P Power (watt) rate of doing work W (js-1)
Q Energy (the ability to do work) J (Nm)
W Work (joule) J (Nm)
t Time interval t f − t0 s
v velocity ms-1
5. FLUIDS
5.1 DENSITY
m
ρ=
V
Where:
Variable Description UNITS (Metric)
ρ density kgm-3
m mass kg
V volume m-3
1
Initial Condition
2
Final Condition
Where:
Variable Description UNITS (Metric)
P Pressure (Pascal) Pa =(Nm-2 ) =J/m3
ρ density kgm-3
v velocity ms-1
hf Friction head Loss m
1
Initial Condition
2
Final Condition
6. GAS LAWS
∆P Change in Pressure Pa
PV = nRoT
Where:
Variable Description UNITS (Metric)
Ro Universal Gas Constant J K-1 mol-1
R = 8.314570[70] J K-1 mol-1 Universal Gas Constant
Bracketed value is 1st standard deviation
n Number of moles mol
P Absolute Pressure Pa
V Volume m3
T Temperature K
Note: 1 mol “Ideal Gas” at STP occupies 0.0224197m3 = 22.4197 L
Example
Sodium Chloride (NaCL)
M
= m.
1000 ⋅ N A
Where:
Variable Description UNITS (Metric)
NA Avogadro's number 6.02214199(47) x 1023 mol-1 mol-1
M Relative Atomic or Molecular Mass g
m Mass of individual molecule kg
n ⋅ 22.4197 = VL
n ⋅ 0.0224197 = Vm
m.⋅ 1000
n=
M
Where:
Variable Description UNITS (Metric)
n Number of moles mol;
M Relative Molar Mass (Atomic Mass) g
m Mass kg
VL Volume Litres (STP) Litre
Vm Volume m3 (STP) m3
PV = mR 'T
Where:
Variable Description UNITS (Metric)
R’ Ideal or Characteristic Gas Constant J kg-1K-1
m Mass kg
P Absolute Pressure Pa
V Volume m3
T Temperature K
PV Diagram “Water”
Equation listed for interest only and as used in Joule Thompson Expansion equation. This would be
the limit for manual calculation more accurate equations of state such as the Peng-Robinson EOS
are used in computational thermo and fluid dynamics.
PV = zmR ' T
Where:
Variable Description UNITS (Metric)
R’ Ideal or Characteristic Gas Constant J kg-1K-1
z Compressibility Factor -
m Mass kg
P Absolute Pressure Pa
V Volume m3
T Temperature K
P
Pr =
Pc
T
Tr =
Tc
Where:
Variable Description UNITS (Metric)
Pc Critical Pressure of Gas Pa
Tc Critical Temperature of Gas K
P Gas Pressure Pa
T Gas Temperature K
z Compressibility Factor from table overleaf -
Note: Compressibility factors for methane CH4 range from 1 to 0.79 depending pressure and temperature, so can have
a significant effect on calculation.
Pr
Tr 0.01 0.05 0.1 0.2 0.4 0.6 0.8 1 1.2 1.5 2 3 5 7 10
0.3 0.003 0.015 0.029 0.058 0.116 0.174 0.232 0.289 0.347 0.434 0.578 0.865 1.437 2.005 2.851
0.35 0.003 0.013 0.026 0.052 0.104 0.156 0.208 0.26 0.312 0.39 0.52 0.778 1.29 1.799 2.554
0.4 0.002 0.012 0.024 0.048 0.095 0.143 0.19 0.238 0.285 0.356 0.474 0.71 1.116 1.637 2.321
0.45 0.002 0.011 0.022 0.044 0.088 0.132 0.176 0.22 0.264 0.329 0.438 0.655 1.084 1.502 2.134
0.5 0.002 0.01 0.021 0.041 0.083 0.124 0.165 0.206 0.247 0.307 0.409 0.611 1.009 1.402 1.98
0.55 0.98 0.01 0.02 0.039 0.078 0.117 0.155 0.194 0.232 0.29 0.385 0.575 0.948 1.313 1.852
0.6 0.985 0.009 0.019 0.037 0.074 0.111 0.148 0.184 0.22 0.275 0.366 0.545 0.896 1.24 1.744
0.65 0.988 0.938 0.018 0.036 0.071 0.106 0.142 0.117 0.211 0.263 0.35 0.52 0.853 1.171 1.652
0.7 0.99 0.95 0.896 0.034 0.069 0.103 0.137 0.17 0.204 0.254 0.336 0.499 0.816 1.124 1.573
0.75 0.992 0.96 0.917 0.034 0.067 0.1 0.133 0.166 0.198 0.246 0.326 0.482 0.785 1.019 1.505
0.8 0.994 0.967 0.932 0.854 0.967 0.932 0.131 0.163 0.194 0.241 0.318 0.469 0.76 1.04 1.446
0.85 0.995 0.973 0.944 0.881 0.066 0.098 0.13 0.161 0.192 0.238 0.313 0.459 0.739 1.007 1.394
0.9 0.995 0.977 0.953 0.902 0.78 0.101 0.132 0.163 0.194 0.238 0.311 0.453 0.722 0.979 1.35
0.93 0.996 0.979 0.957 0.912 0.806 0.664 0.136 0.166 0.196 0.241 0.312 0.451 0.714 0.965 1.326
0.95 0.996 0.98 0.96 0.917 0.821 0.697 0.141 0.171 0.2 0.243 0.314 0.45 0.709 0.956 1.311
0.97 0.996 0.982 0.963 0.923 0.834 0.724 0.558 0.178 0.206 0.247 0.316 0.45 0.705 0.948 1.297
0.98 0.997 0.982 0.964 0.925 0.84 0.736 0.589 0.184 0.21 0.25 0.318 0.451 0.704 0.944 1.29
0.99 0.997 0.983 0.965 0.928 0.846 0.747 0.614 0.196 0.215 0.254 0.32 0.451 0.702 0.941 1.284
1 0.997 0.983 0.966 0.93 0.851 0.757 0.635 0.29 0.223 0.258 0.322 0.452 0.1 0.937 1.277
1.01 0.997 0.984 0.967 0.932 0.856 0.767 0.654 0.465 0.237 0.264 0.326 0.453 0.699 0.934 1.271
1.02 0.997 0.984 0.968 0.934 0.861 0.776 0.671 0.515 0.263 0.272 0.33 0.455 0.698 0.93 1.265
1.05 0.997 0.986 0.971 0.94 0.874 0.8 0.713 0.603 0.444 0.313 0.345 0.46 0.696 0.922 1.248
1.1 0.998 0.987 0.975 0.949 0.893 0.832 0.765 0.688 0.598 0.458 0.395 0.477 0.695 0.911 1.223
1.15 0.998 0.989 0.978 0.955 0.908 0.858 0.803 0.744 0.68 0.52 0.476 0.504 0.698 0.903 1.202
1.2 0.998 0.99 0.981 0.961 0.921 0.878 0.833 0.186 0.136 0.661 0.561 0.543 0.707 0.899 1.184
1.3 0.999 0.993 0.985 0.97 0.94 0.908 0.876 0.844 0.811 0.762 0.691 0.634 0.736 0.9 1.158
1.4 0.999 0.994 0.988 0.977 0.953 0.93 0.906 0.883 0.86 0.826 0.175 0.72 0.716 0.911 1.142
1.5 0.999 0.995 0.991 0.982 0.964 0.946 0.928 0.91 0.893 0.869 0.833 0.789 0.82 0.93 1.134
1.6 0.999 0.996 0.993 0.986 0.971 0.958 0.944 0.931 0.918 0.9 0.874 0.841 0.862 0.952 1.132
1.7 0.999 0.997 0.994 0.989 0.978 0.967 0.956 0.946 0.937 0.923 0.904 0.881 0.898 0.915 1.134
1.8 1 0.998 0.996 0.991 0.982 0.974 0.966 0.958 0.951 0.941 0.928 0.912 0.93 0.996 1.139
1.9 1 0.998 0.996 0.993 0.986 0.98 0.974 0.968 0.962 0.955 0.946 0.936 0.956 1.015 1.145
2 1 0.999 0.997 0.994 0.989 0.984 0.98 0.975 0.912 0.966 0.96 0.955 0.977 1.033 1.152
2.2 1 0.999 0.998 0.997 0.994 0.991 0.989 0.987 0.985 0.983 0.981 0.982 1.009 1.06 1.164
2.4 1 1 0.999 0.998 0.997 0.996 0.995 0.994 0.994 0.994 0.995 1.001 1.031 1.019 1.173
2.6 1 1 1 0.999 0.999 0.999 0.999 0.999 1 1.001 1.004 1.014 1.046 1.093 1.179
2.8 1 1 1 1 1.001 1.001 1.002 1.003 1.004 1.006 1.011 1.022 1.057 1.102 1.183
3 1 1 1 1.001 1.002 1.003 1.004 1.005 1.007 1.01 1.015 1.028 1.064 1.108 1.185
3.5 1 1 1.001 1.002 1.004 1.006 1.008 1.009 1.012 1.016 1.022 1.037 1.072 1.114 1.183
4 1 1.001 1.001 1.002 1.004 1.007 1.009 1.012 1.014 1.018 1.025 1.04 1.074 1.114 1.177
7. SERVICE CALCULATIONS
Where:
Variable Description UNITS (Metric)
D Diameter of pipe m
L Length of pipe m
Vt Fill Volume of system m3
Estimation of pipe volume based on simple cylinder, more complex shapes will require more
complex modelling, if they comprise a large percentage of the system. For instance manifolds,
wellheads.
Va =
{Sa − St} × Vp × 100
Vt 1
Where:
Variable Description UNITS (Metric)
Va Air Content (expressed as % of total fill Volume) %
To calculate St : Find the average pump strokes taken to raise the pressure by one bar between the
pressures of 25 to 35 bar. Multiply this average by 35 to obtain the theoretical
stroke figures, this figure approximates the volume to pressurise to 35 bar with no
air present in the system.
Estimation of the volume of included air, primarily this is a safety concern the secondary effect of
large volumes of included air is to increase fluid compressibility and amplify temperature response.
GRAPHICAL REPRESENTATION OF AIR CONTENT
Elastic Line
Pressure
264.7 Tf
∆P =
D / t + 100
Where:
Variable Description UNITS (Metric)
∆P is the pressure change in Bar /oC Bar /oC
The temperature factor Tf should be read from the attached graph at the mean test temperature.
∆P should be multiplied by the temperature change during the test to find the pressure correction.
Account should be taken of both ambient submerged and pipework temperature, when calculating
the pressure temperature relationship.
Note 1: It has been observed that a significant time lag may occur between a change in ambient temperature
and a corresponding change in pipe temperature.
Note 2: Chill or heat factors on exposed pipe may have an effect on pressure readings.
Estimation of temperature variation during a pressure test with fresh water as the test medium, this
is not the only method but is simpler than using fresh water coefficients in the J.C. Gray formulae
later in this document. The calculation is used to demonstrate that pressure variation can be
accounted for by temperature (in most cases we are trying to explain pressure losses, but the
calculation applies equally to pressure increases, however it is unusual for a client to request these
to be calculated).
Tf Graph
(Temperature factor)
2.5
1.5
1
Temperature Factor
0.5
0
0 5 10 15 20 25 30
-0.5
-1
Tem perature ºC
(Source: J.C.Gray)
The following formulae are used to determine the theoretical volume to pressurise a restrained or
unrestrained pipeline.
RESTRAINED
[
⎧⎪Vt Vt 1 − y 2 ID ⎫⎪
V = P×⎨ + ⎬
]
⎪⎩ k W×E ⎪
⎭
UNRESTRAINED
Where:
Variable Description UNITS (Metric)
V Volume to pressurise m3
Estimation of the required volume to pressurise a pressure test with sea water as the test medium
(fresh if C for fresh water is used), this is the J.C. Gray formulae. Other formulae have been derived
(Shell EM 065) but the results have negligible difference. Be aware of local differences in salinity
(most waters are 3.5%). Data can be produced via software for any salinity.
This formula is used to calculate any pressure changes attributed to the temperature effect on the
pipeline system under hydrostatic test.
⎧ WE[ B − 2 A] ⎫
⎪ ⎪
∆P = ⎨ ⎬
⎩⎪ { [
OD × 1 − y + WEC ⎪
2
⎭ ]}
Where:
Variable Description UNITS (Metric)
∆P Pressure change due to temperature Bar / oC
o -1
A Coefficient of expansion of pipe material C
The properties, A , E and y are constant for any one type of pipe material, the most commonly
used material being steel. The values of A , E and y for steel are listed:
A = 1.116 x 10 -5 oC-1
E = 20.7 x 105 bar
y = 0.3
The allowable pressure change attributable to environmental effects must be calculated for each °C
of the temperature change experienced over the test period and then averaged.
Estimation of temperature variation during a pressure test with sea water as the test medium, this is
the J.C. Gray formulae. Other formulae have been derived (Shell EM 065) but the results have
negligible difference. Be aware of local differences in salinity (most waters are 3.5%). Data can be
produced via software for any salinity.
C Graph
Compressibility Factor of Sea Water 3.5% Salinity
48.0E-06
3.5 % Salinity
47.0E-06
46.0E-06
45.0E-06
44.0E-06
43.0E-06
42.0E-06 1 Bar
50 Bar
100 Bar
41.0E-06
150 Bar
200 Bar
350 Bar
39.0E-06 400 Bar
450 Bar
500 Bar
38.0E-06
550 Bar
600 Bar
650 Bar
37.0E-06
700 Bar
800 Bar
36.0E-06 900 Bar
1000 Bar
1100 Bar
35.0E-06
34.0E-06
33.0E-06
32.0E-06
31.0E-06
30.0E-06
0 5 10 15 20 25 30 35 40
Temperature
Compressibility calculated from the formulae within . The Specific Volume of Seawater, Chen Tung “Arthur “ Chen & Frank J Miller.
B Graph
Expansion Coefficient of Sea Water 3.5% Salinity
450.0E-06
3.5 % Salinity
400.0E-06
350.0E-06
1 Bar
300.0E-06
50 Bar
100 Bar
150 Bar
200 Bar
Expansion Coefficient
050.0E-06
000.0E+00
0 5 10 15 20 25 30 35 40
Temperature
Expansion coefficient calculated from the formulae within. The Specific Volume of Seawater, Chen Tung “Arthur “ Chen & Frank J Miller..
h (-ve correction)
ρ×g×h
PCorrection =
100000
Test Datum (e.g. LAT)
Where:
Variable Description UNITS (Metric)
ρ Density of Test medium kg/m3
Calculation pressure due to the static head of a column of water, take care of regional differences in
density and gravity.
0.3 × ρ × g × h
LAT Datum (lowest
h
PCorrection = Time
Static
(+ve)
Astronomical Tide)
100000 Head
Seawater
Item under Test
Where:
Variable Description UNITS (Metric)
ρ Density of Seawater kg/m3
Estimation of pressure change due to changes in tidal height, note only 30% is shown to be
transferred to the pipeline contents. Other factors may shield pipe from tidal effect i.e. bundle, pipe
in pipe, heavy insulation and deep burial.
Calculations Reference Manual - 30 -
Date prepared: Prepared by: Reviewed by: Ref No:
November 2004 James MacLennan Brian McGillivray PPS-CRM-001
Ph = P0e − h / h0
Where:
Variable Description UNITS (Metric)
e 2.718281828
Estimation of pressure change due to changes in altitude, this is for operational planning lower air
pressures effectively derate the horsepower developed by engines and the efficiency of
compressors.
210
∆P =
D
Where:
Variable Description UNITS (Metric)
∆P Differential Pressure to drive pig Bar
D Internal Diameter in mm mm
Source: British Gas Spec BGC/PS/PC1
500
450
400
350
300
250
k
200
150
100
50
0
Sphere
Poly Coated
Cone Pig
Bi-Di Pig
Brush Pig
Bare Foam
Foam
K
∆P =
D
Where:
Variable Description UNITS (Metric)
∆P Differential Pressure to drive pig Bar
D Internal Diameter in mm mm
Ref: Cordell, J.L “Design of Pigs for subsea systems”, Subsea Pigging Conference, September 1986, Haugesund.
v Q&
v=
Q&
D {πD 2
4 }
Where:
Variable Description UNITS (Metric)
m3/s
Q& Fluid Flowrate
D Diameter of pipe m
f × L × v2ρ
∆P =
200000 × D
P1 P2
ρ Fluid Density D
L
Where:
Variable Description UNITS (Metric)
∆P Pressure Drop (P1-P2) Bar
D Diameter of pipe m
L Length of pipe m
vD
Re =
υ
µ
υ=
ρ
v
High Reynolds Flow
Turbulent sharper profile D
Q&
Where:
Variable Description UNITS (Metric)
Re Reynolds Number
D Diameter of pipe m
µ Dynamic Viscosity Pa s
v
Laminar Flow
Shallow Velocity D
Q&
Profile (High core flow)
Where:
Variable Description UNITS (Metric)
Re Reynolds Number
f Friction Factor
.
1325
f = 2
⎡ ⎧ e 5.74 ⎫⎤
⎢ Ln ⎨ 3.7 D + Re 0.9 ⎬⎥
⎣ ⎩ ⎭⎦
Where:
Variable Description UNITS (Metric)
Re Reynolds Number
f Friction Factor
D Pipe Diameter m
Ln Natural Logarithm
e Absolute Roughness m
Swanee and Jain (1976), Explicit formulation for the moody diagram
K f ρV 2
∆P =
200000
Where:
Variable Description UNITS (Metric)
Kf Factor from Nomographs
V ⎪⎧ P1 − Pvap ⎪⎫
t= ⋅ Ln ⎨ ⎬
C ⎪⎩ P2 − Pvap ⎪⎭
Where:
Variable Description UNITS (Metric)
V System Volume m3
Ln Natural Logarithm
Estimation of time required to reduce the pressure within a system below atmospheric using a
vacuum pump or similar device.
7.21 CONDUCTANCE
The design of high Vacuum Systems C.M. Van Atta 1960
D4
C High Pr essure = 190 ×
L
D3
C Low Pr essure = 13.6 ×
L
Where:
Variable Description UNITS (Metric)
C Conductance Litres/sec
D Diameter of Pipe cm
L Pipe Length cm
Note: Conductance is an estimation of throughput “High pressure” being viscous flow “Low Pressure” being
diffusive flow. It should be noted that final draw downs to the low millibar levels starts to enter into the diffusive
flow regime also at this stage we are on the very low throughput areas of any vacuum pump curve making
approximations of the final drawdown very difficult as any vapour evaporation event will take the system from
one regime to the other in a very short time. In general all activities are within the viscous flow regime.
Calculations within diffusive flow regimes are usually fruitless as more often than not the system is cycling from
one to the other and even different areas can be in different regimes simultaneously.
⎧⎪ wR( T + 27315 . ) ⎫⎪
t=⎨ ⎬
( )
⎪⎩ C ⋅ Pvap × 100 ⋅ M ⎪⎭
Where:
Variable Description UNITS (Metric)
w Estimated Mass of water in system ref 7.24 Kg
Estimation of time required to evaporate free water from a system using vacuum pump or similar
device.
⎧ (P × 100) ⋅ C ⋅ M ⎫
m& = ⎨ ⎬
⎩ R ⋅ (T + 273.15) ⎭
Where:
Variable Description UNITS
m& Estimated Mass removal rate Kg/hr
Estimation of water quantity removed from a system using vacuum pump or similar device.
π (D 2 − (D − 2F ) 2 )
w= × L× ρ
4
F
Where:
Variable Description UNITS (Metric)
w Estimated Mass of water Kg
D Diameter of Pipe m
L Pipe Length m
⎧ ⎫
⎪ ⎪
⎪ wR(T + 273.15) ⎪
t=⎨ ⎬
([
⎪ C ⋅ Pvap − Pgas × Pinject × 100 ⋅ M ⎪
⎪⎩ Pinject ⎪⎭
] )
Where:
Variable Description UNITS (Metric)
w Estimated Mass of water in system ref 7.24 Kg
This is the basis for calculation of an air drying duration, the variable Pinject changes along the
length of the pipeline as the drying gas expands so it is usual to calculate the pressure drop along
the pipeline, remembering this is compressible flow so the pressure drop is not linear over the
pipeline length as it would be with a liquid. The calculation can then be applied for each interval of
pipe. The total of the times being the drying duration. It should be noted that when:
t ps D t ps D t ps D
o
C mbar g/m3 o
C mbar g/m3 o
C mbar g/m3
-100 1.403x10-5 1.756x10-5 -50 39.35 38.21 0 6.108 4.847
-99 1.719 2.139 -49 44.49 43.01 1 6.566 5.192
-98 2.101 2.599 -48 50.26 48.37 2 7.055 5.559
-97 2.561 3.150 -47 56.71 54.33 3 7.575 5.947
-96 3.117 3.812 -46 63.93 60.98 4 8.129 6.360
Continued…..
t ps ρD t ps ρD
o
C mbar g/m3 o
C mbar g/m3
50 123.4 83.06 100 1013.2 597.8
51 129.7 87.01 101 1050 618.0
52 136.2 91.12 102 1088 638.8
53 143.0 95.39 103 1127 660.2
54 150.1 99.83 104 1167 682.2
95 845.3 504.5
96 876.9 522.1
97 909.4 540.3
98 943.0 558.9
99 977.6 578.1
D Diameter of Pipe m
L Pipe Length m
Note: A minimum of two slugs separated by a batching pig are required for effective dehydration.
In general this will result in approximate discharged concentrations in the first Slug of 55% MeOH
or MEG and 75% MeOH or MEG in the second slug, assuming a film thickness of 0.1mm.
-
2.00 -5.00 -8.00 11.00 -14.00 -20.00 -22.25 -24.50 -28.50 -35.00 -50.75 -60.59 -64.53 -66.50
-
3.00 -4.00 -7.00 10.00 -13.00 -19.00 -21.50 -24.00 -28.00 -34.50 -50.00 -59.69 -63.56 -65.50
4.00 -3.50 -6.50 -9.50 -12.50 -18.50 -20.75 -23.00 -27.00 -33.50 -49.00 -58.69 -62.56 -64.50
5.00 -2.50 -5.50 -8.50 -11.50 -17.50 -20.00 -22.50 -26.50 -33.00 -48.25 -57.78 -61.59 -63.50
6.00 -1.50 -4.50 -7.50 -10.50 -17.00 -19.50 -22.00 -26.00 -32.50 -47.50 -56.88 -60.63 -62.50
7.00 -0.50 -4.00 -7.00 -10.00 -16.00 -18.50 -21.00 -25.00 -31.50 -46.50 -55.88 -59.63 -61.50
8.00 0.00 -3.00 -6.00 -9.00 -15.50 -18.00 -20.50 -24.50 -31.00 -45.75 -54.97 -58.66 -60.50
9.00 1.00 -2.00 -5.25 -8.50 -14.50 -17.00 -19.50 -23.50 -30.50 -45.25 -54.47 -58.16 -60.00
10.00 2.00 -1.50 -4.50 -7.50 -14.00 -16.50 -19.00 -23.00 -29.50 -44.25 -53.47 -57.16 -59.00
11.00 3.00 -0.50 -3.50 -6.50 -13.00 -15.50 -18.00 -22.50 -29.00 -43.50 -52.56 -56.19 -58.00
12.00 4.00 0.50 -2.75 -6.00 -12.50 -15.00 -17.50 -21.50 -28.50 -42.75 -51.66 -55.22 -57.00
13.00 5.00 1.50 -1.75 -5.00 -12.00 -14.50 -17.00 -21.00 -27.50 -41.75 -50.66 -54.22 -56.00
14.00 6.00 2.00 -1.25 -4.50 -11.00 -13.50 -16.00 -20.00 -27.00 -41.00 -49.75 -53.25 -55.00
15.00 7.00 3.00 -0.25 -3.50 -10.50 -13.00 -15.50 -19.50 -26.50 -40.25 -48.84 -52.28 -54.00
16.00 8.00 4.00 0.50 -3.00 -9.50 -12.00 -14.50 -19.00 -25.50 -39.25 -47.84 -51.28 -53.00
17.00 8.50 5.00 1.50 -2.00 -9.00 -11.50 -14.00 -18.00 -25.00 -38.75 -47.34 -50.78 -52.50
18.00 9.50 6.00 2.25 -1.50 -8.00 -10.50 -13.00 -17.50 -24.00 -37.75 -46.34 -49.78 -51.50
19.00 10.50 7.00 3.25 -0.50 -7.50 -10.00 -12.50 -17.00 -23.50 -37.00 -45.44 -48.81 -50.50
20.00 11.50 7.50 4.00 0.50 -6.50 -9.25 -12.00 -16.00 -23.00 -36.25 -44.53 -47.84 -49.50
21.00 12.50 8.50 4.75 1.00 -6.00 -8.50 -11.00 -15.50 -22.00 -35.25 -43.53 -46.84 -48.50
22.00 13.50 9.50 5.75 2.00 -5.00 -7.75 -10.50 -14.50 -21.50 -34.75 -43.03 -46.34 -48.00
23.00 14.50 10.50 6.75 3.00 -4.50 -7.00 -9.50 -14.00 -21.00 -34.00 -42.13 -45.38 -47.00
24.00 15.50 11.50 7.75 4.00 -3.50 -6.25 -9.00 -13.50 -20.00 -33.00 -41.13 -44.38 -46.00
25.00 16.50 12.50 8.50 4.50 -3.00 -5.75 -8.50 -12.50 -19.50 -32.25 -40.22 -43.41 -45.00
26.00 17.00 13.00 9.25 5.50 -2.50 -5.00 -7.50 -12.00 -19.00 -31.50 -39.31 -42.44 -44.00
30.00 21.00 17.00 13.00 9.00 0.50 -2.25 -5.00 -9.00 -16.00 -28.25 -35.91 -38.97 -40.50
31.00 22.00 18.00 14.00 10.00 1.50 -1.25 -4.00 -8.50 -15.50 -27.50 -35.00 -38.00 -39.50
32.00 23.00 18.50 14.50 10.50 2.50 -0.50 -3.50 -8.00 -15.00 -27.00 -34.50 -37.50 -39.00
33.00 24.00 19.50 15.50 11.50 3.00 0.00 -3.00 -7.00 -14.00 -26.00 -33.50 -36.50 -38.00
Vgas = { Px × Vt}
Px
Vt Fill Volume
Where:
Variable Description UNITS (Metric)
Vgas Total Volume of gas required m3
Calculation of Px
Px is the total pressure required to drive the pig train this should take into account the following:
WARNING: If sizing for liquid nitrogen always ensure adequate liquid nitrogen reserves.
{
V&gas = Px × Vt m × n& pig }
Px
n& pig
V&gas
D
1m
Vtm
Where:
Variable Description UNITS (Metric)
Rate of gas required m3/s
V&gas
Fill Volume of Pipe (from 5.1) per unit metre m3/m
Vt m
n& pig Required Pig speed (0.5 to 1.0 ms-1) ms-1
Gas/
Air
Liquid Content
Where:
Variable Description UNITS (Metric)
Ph Rate of gas required Pa
HHPOutput = Q × Pi × 2.2358
Q × Pi × 2.2358
HHPPumpend =
ηp
Q × Pi × 2.2358
BHPdriver =
η p ×η e
Where:
Variable Description UNITS (Metric)
Q Flowrate m3/min
Di Inside Diameter m
Po External Pressure Pa
Pi Internal Pressure Pa
σh Hoop Stress Pa
Material SMYS Pa
API-5L-A 2.07E+08
API-5L-B 2.41E+08
API-5L-X42 2.89E+08
API-5L-X46 3.17E+08
API-5L-X52 3.58E+08
API-5L-X56 3.86E+08
API-5L-X60 4.13E+08
API-5L-X65 4.48E+08
API-5L-X70 4.82E+08
API-5L-X80 5.51E+08
API-5 CT H 40 2.76E+08
API-5 CT J 55 3.79E+08
API-5 CT K 55 3.79E+08
API-5 CT N 80 5.52E+08
API-5 CT L80 1 5.52E+08
API-5 CT L80 9 Cr 5.52E+08
API-5 CT L 80 13Cr 5.52E+08
API-5 CT C90 1,2 6.20E+08
API-5 CT C 95 6.55E+08
API-5 CT T 95 1,2 6.55E+08
API-5 CT P110 7.58E+08
API-5 CT Q 125 8.60E+08
S 30403-S 31603 1.70E+08
S 31254 3.00E+08
S other grades 2.05E+08
N 08028 2.14E+08
N 08904 2.20E+08
S 31803 4.50E+08
Measured Pressure
Gauge
Pressure
Bar G
From To
0 0
C (Celsius) F (Fahrenheit) Multiply by 1.8 and add 32
0 0
F (Fahrenheit) C (Celsius) Subtract 32multiply by .5556
0
C (Celsius) K (Kelvin) Add 273.15
0 0
F (Fahrenheit) R (Rankine) Add 459.67
0
R (Rankine) K (Kelvin Multiply by 0.5556
8. ELECTRICAL CALCULATIONS
1 1000
R ins20 = R t × ×
1 + α ( t - 20) L
Where:
Variable Description UNITS (Metric)
R ins20 Resistance at 20°, in Ω per km Ω/km
L Length of Cable m
α Ω/ Ω°C
copper 0.00393
platinum 0.00385
tungsten 0.0045
aluminum 0.0040
Where:
Variable Description UNITS (Metric)
V Electromotive Force Volt V
I Current Amperes A
R Resistance Ohms Ω
R Resistance Ohms Ω
ρ Resistivity Ωm
L Length m
a Cross sectional area of conductor m2
ρ Ωm
R1 R2 R3 Rn
RT = R1 + R2 + R3 + ..... + Rn
Where:
Variable Description UNITS (Metric)
R Resistance Ohms Ω
R1 R2 R3 Rn
1 1 1 1 1
= + + + ..... +
RT R1 R2 R3 Rn
Where:
Variable Description UNITS (Metric)
R Resistance Ohms Ω
Shorting Links
Rm12 − Rm 23 + Rm13
R1 =
1 2
R + Rm 23 − Rm13
R 2 = m12
3 2
2
Rm 23 + Rm13 − Rm12
R3 =
2
Where:
Variable Description UNITS (Metric)
R Resistance Ohms Ω
Lb Shorting
Link
La
Rm
Lc
Shorting
Link
Equivalent Circuit
R(La)
Rm 2 x R(Lc) 2 x R(Lb)
R(La)
Rm
R =
⎛ 2 Lb ⋅ 2 Lc ⎞
⎜⎜ 2 La + ⎟⎟
⎝ 2 Lb + 2 Lc ⎠
Where:
Variable Description UNITS (Metric)
R Resistance per metre Ohms Ω/m
La Length La m
Lb Length Lb m
Lc Length Lc m
Conductor
Insulator
(dielectric)
The insulator prevents the conductor from allowing current to flow to earth, everything will conduct
current to some degree “Insulators” are simply materials with very high resistances.
Lb
Shorting
Link Removed
La
Rm
Lc
Shorting
Link Removed
Equivalent Circuit
Rm
R =
⎛ La ⋅ Lb ⋅ Lc ⎞
⎜⎜ ⎟⎟
⎝ (La ⋅ Lb ) + (Lb ⋅ Lc ) + (La ⋅ Lc ) ⎠
Where:
Variable Description UNITS (Metric)
R Resistance per metre Ohms Ω/m
Rm Resistance measured Ohms Ω
La Length La m
Lb Length Lb m
Lc Length Lc m
Lb Shorting
Link Installed
La
Rm
Lc
Shorting
Link Installed
Equivalent Circuit
Rm 2R(Lc) 2R(Lb)
2R(La)
Rm
R =
⎛ 2 La ⋅ 2 Lb ⋅ 2 Lc ⎞
⎜⎜ ⎟⎟
⎝ (2 La ⋅ 2 Lb ) + (2 Lb ⋅ 2 Lc ) + (2 La ⋅ 2 Lc ) ⎠
Where:
Variable Description UNITS (Metric)
R Resistance per metre Ohms Ω/m
Rm Resistance measured Ohms Ω
La Length La m
Lb Length Lb m
Lc Length Lc m
9. PRESSURE DROPS
0 1 0.000 0 0 0
1 1 0.030 0.7 7.0 70.0
1.5 1 0.046 1.5 14.8 148.3
2 1 0.061 2.5 25.3 252.5
2.5 1 0.076 3.8 38.2 381.6
3 1 0.091 5.3 53.5 534.6
3.5 1 0.106 7.1 71.1 711.1
4 1 0.122 9.1 91.0 910.3
0 2 0.000 0.0 0.0 0.0
1 2 0.122 0.3 3.1 31.2
1.5 2 0.182 0.7 6.6 66.1
2 2 0.243 1.1 11.3 112.6
2.5 2 0.304 1.7 17.0 170.1
3 2 0.365 2.4 23.8 238.3
3.5 2 0.425 3.2 31.7 317.0
4 2 0.486 4.1 40.6 405.8
0 3 0.000 0.0 0.0 0.0
1 3 0.273 0.2 1.9 19.5
1.5 3 0.410 0.4 4.1 41.2
2 3 0.547 0.7 7.0 70.2
2.5 3 0.684 1.1 10.6 106.0
3 3 0.820 1.5 14.9 148.6
3.5 3 0.957 2.0 19.8 197.6
4 3 1.094 2.5 25.3 253.0
0 4 0.000 0.0 0.0 0.0
1 4 0.486 0.1 1.4 13.9
1.5 4 0.729 0.3 2.9 29.5
2 4 0.972 0.5 5.0 50.2
2.5 4 1.215 0.8 7.6 75.8
3 4 1.459 1.1 10.6 106.3
3.5 4 1.702 1.4 14.1 141.3
4 4 1.945 1.8 18.1 180.9
Continued…
Continued…
10.1 INTRODUCTION
As many as 50 different fluids have been developed to solve various needs within the oil and gas
market. The major types of fluids that remain at the backbone of the industry are as follows:
C=O
NH2
(CH2 CH2)n
Repeat unit of
Polyacrylamide
C=O
n=2, dimer
NH2 n=3, trimer
Example 1: Monomer and Polymer of Polyacrylamide
A monomer is sometimes referred to as a repeater unit, and whilst this is not strictly true in all
cases, the terms will be used interchangeably within this manual.
In between monomers and polymers there are many other …..mers which we refer to.
Polymers can be formed from a single type of monomer or from different types of monomer.
Types of Polymer
Natural polymers have some advantages. They are generally cheaper to prepare as nature has done
a lot of the work, and they tend to be much more marketable due to their more environmentally
friendly nature.
Man made polymers are produced in the most part by two different processes and they are
categorised in that way.
Water soluble polymers are often made by addition polymerisation. Common water soluble
addition polymers are polyacrylamide and polyvinylalcohol derivatives.
Secondary Structure
To better understand gels, it is important to understand the way the long chain molecules interact
with each other.
• Linear: Straight polymer chains lying parallel to each other with no interaction gives a non
viscous fluid with no real gel like properties. However long chain molecules tend to interact
with each other (or themselves), much like a bowl of spaghetti. Trying to lift only a couple
of strands can result in a big knot of pasta as friction and interaction binds the strands
together. The addition of more base fluid (pasta sauce) can reduce viscosity by essentially
diluting the polymer chains (or spaghetti) making the gel less viscose. Conversely the
addition of more binding agent (polymer chains or spaghetti) will increase the overall
viscosity.
• Cross-Linked: Structures based on strong covalent bonds between polymer chains which
cannot be broken by the application of heat or the addition of more base fluid. Although
more base fluid cannot break the covalent bonds, the cross linked gel may be "swollen" by
the addition of more base fluid to affect the rheological properties. To break the strong
bonds, the changing of pH or the addition of other chemicals would be required.
Simple Sugars
All simple sugars have the chemical formula C6H12O6. Their differences are due to structural
differences rather than different chemical compositions. In forming the cyclic sugar structure it is
always the carbon 1 which attacks the carbon 5 to give a 6 member ring. This cyclic form is
generally the basis for all the natural polymers we use.
CHO
CH2OH
H C OH
H C OH
OH C H O
H C OH H C H
H C OH
C C
OH C H OH
H OH
CH2OH
Simple sugar and the cyclic sugar form
A cross linked gel has actual bonds purposely formed between the individual polymer chains.
Cross linking gives rise to a 3-dimensional structure. If the base polymer units retain the affinity
for the solvent then the product will be a true gel with the typical elastic character and solvent
retention.
Calculations Reference Manual - 69 -
Date prepared: Prepared by: Reviewed by: Ref No:
November 2004 James MacLennan Brian McGillivray PPS-CRM-001
Higher cross-link density however will make the product stiffer, less elastic and more prone to the
loss of solvent as a separate fluid.
Polymer chains can be linked through physical association or interaction without being truly
chemically cross linked, giving rise to another type of gel. (e.g. XCD)
Linear gels are generally just high viscosity liquids. In order for them to attain any ridgity, high
polymer loadings are required.
The nature of cross linked gels results in a structure that has more rigid properties at relatively low
polymer loadings.
Sometimes terms such as “ringing” or “lipping” are used to describe a gel, generally “ringing”
would apply to something that resembles jelly, “lipping” would refer to a gel that when poured will
pull itself from the container from which it is poured.
The important thing to realise about Gels is that they are actually long chain polymers in solution.
10.4 HYDRATION
Hydration is the process where the long chain polymers which make up the gel become evenly
distributed though the gel solution The presence of long chains distributed throughout the solution
gives rise to a higher viscosity. Physical interactions between polymer chains, for example
hydrogen bonding or intermolecular helix formation (xanthan), increase the viscosity even more.
Rigid gels can be obtained by chemically crosslinking the chains. This generates in fact one big
molecule.
Hydration is generally pH, time and temperature dependent although it can be mechanically
accelerated in certain gels.
e.g. Xanthan will build viscosity very fast if it is sheared, however if sheared too much physical
crosslinks break down and takes some time to re-build itself.
10.5 CURING
This term is better used with gels where the bonding is a chemical reaction that slowly builds up the
gel strength.
10.6 PH CONTROL
pH is a measure of how acid or alkaline (base) a solution is. This measure is taken from the number
of hydrogen ions available in the solution. The scale goes from 0 for the most acidic to 14 for the
most base with 7 being neutral (pure water).
The pH of a solution can control how fast or slow reactions take place and as such pH control can
become very important when mixing some gels. The hydration rate and especially the ability to
cross link can all be controlled by the pH level.
For some gel recipes high pH increases the hydration rate, whilst for other recipes, low pH
will increase hydration rate.
The pH Scale
0 1 2 3 4 5 6 7 8 9 10 11 12 13 14
1 M HCl
1 M NaOH
Juice
Milk
Magnesia
Ammonia
Pure
Stomach
Acid
Lemon
Vinegar
Water
Blood
Milk of
100 10-1 10-2 10-3 10-4 10-5 10-6 10-7 10-8 10-9 10-10 10-11 10-12 10-13 10-14
Acidic [H+] Basic
Previous studies performed with these fluids have indicated that gel residue from guar fluids can be
as high as 8% to 10% by weight. The high residue content of guar gels can leave residues, if further
cleanup measures are not applied.22,23
Similar problems have been observed with linear HPG and CMHPG, though residue is not as
extreme with this type of fluid system. In both HPG and CMHPG fluids, the residue content can be
from 1% to 3% by weight. HEC fluid systems are virtually residue free and provide the cleanest of
the saccharine type materials.
The general characteristics of linear gels are poor debris transport and low fluid viscosity. Linear
gels tend to form thick filter cakes, in pipeline applications the material is so concentrated that the
work is actually being done with a filter cake.
New biopolymer gel systems have been recently added developed. These fluids feature clean,
controllable breaks and low residue gel. Some new biopolymer systems have high cost and
unfavourable shear-thinning properties.
The sediment transport capabilities of organometallic-crosslinked fluids are excellent, and can
possible be applied to leak mitigation or repair. The metallic bonds which form the crosslink
mechanism in these fluids are not reversible and do not break when exposed to conventional gel-
breaking systems. Cleanup difficulty is the major disadvantage to these types of fluids.
10.11 BREAKERS
Breakers can be used to reduce gel viscosity back to something close to the base fluids rheology. In
some applications, the use of delayed, encapsulated breakers may be desirable. However, this may
pose the additional concerns which follow:
• The encapsulated breaker may drop out of the gel if the rheology is unsuitable for
transportation.
• Delay in operations may result in untimely break of the gel.
Break testing should be performed before the job is pumped. These tests help ensure that break
times are sufficient to place the treatment, but short enough to allow the gel to break in a reasonable
amount of time. The breaker schedule should provide good fluid properties for twice the anticipated
pump time and a complete break in the required timescale
Chemical descriptions of breakers and the breaking process are presented here. Note that this article
focuses on water-based fluids and does not cover oil-gelled fluids and breakers.
To help readers optimize the fluid system for hydraulic fracturing treatments, this article covers
several aspects of fracturing fluid breakers:
Chemicals used to reduce the viscosity of gel systems are called breakers.
Water-based fracturing fluids are usually made viscous by the addition of 20 to 70 lb of guar or
derivatised guar polymer per 1000 gallons of water. Guar polymer, which is derived from the beans
of a guar plant, is referred to chemically as a galactomannan gum. A mixture of guar dissolved in
water forms a base gel, and suitable crosslinking agents are added to form a much more viscous
fluid, called a crosslinked fluid. The water-based fluids discussed here may be crosslinked with
metals, such as zirconium, titanium, or boron compounds. The viscosity of base gels are typically
20 to 50 cp; when it is crosslinked, the viscosity of the base gel is increased by 2 to 100 times
depending on the temperature, test method, and type of crosslinker used
viscosity. A single guar polymer must be cut into approximately 200 small pieces to eliminate
viscous effects.
On the other hand, crosslinking the guar increases its molecular weight to extremely high values.
The actual number of crosslinks that are possible and that actually form depends on the shear level
of the system: the total molecular weight is inversely proportional to the shear the fluid receives.
The exact number of crosslink sites is not well known, but it could be as few as one to ten. The
number of crosslinks, and thus the molecular weight of the resulting polymer, significantly alters
fluid viscosity.
Crosslinks produced by borate ion are known to be reversible and can be completely eliminated at
neutral or acidic pH. Crosslinks formed by zirconium, titanium, antimony, and aluminium
compounds, however, are not reversible and may be broken only by unconventional methods. Gel
breakers are designed to reduce guar polymer viscosity by breaking down its molecular weight.
This process can occur independent of crosslinking bonds existing between polymer chains.
The polymers used are normally water soluble: partially hydrolyzed polyacrylamides (PHPA),
thermally stabilized copolymers of PHPA, non-hydrolyzed polyacrylamide (NHPA), cationic
polyacrylamide, polyvinyl alcohol, guar, guar derivatives, xanthan, and scleroglucan. PHPA and its
copolymers are most commonly used; biopolymers have rarely positive results. Most of the
polymers start out crosslinkable, so they need to rely on the crosslinker chemistry for delay. NHPA
has no place for the crosslinkers to attach, so its crosslinking is delayed by the slow hydrolysis of
the polymer to form crosslink sites (Sydansk, 1993).
Metallic and organic crosslinkers have been used, both of which are generally pumped as "masked"
materials that are unable to interact with the polymer until their masks are removed. Metallic
"masks" are called ligands which are strongly attracted to the metal ion by ionic forces. The
stronger this attraction and larger the ligand, the longer it takes for the metal to release to crosslink
the polymer. The rate at which the metal is released can be controlled by pH or by the ligand
concentration in the system. Excess ligand can be added to the crosslinker or the
polymer/crosslinker solution to delay metal release (Lockhart and Albonico, 1992), but this often
results in weaker crosslinking interactions of the metal with the polymer. Metallic crosslinkers used
commercially include chromium acetate (Sydansk, 1992), chromium propionate (Mumallah, 1988),
zirconium lactate (Moffit et al., 1996), and aluminium citrate (Stavland and Jonsbraten, 1996).
(1) A weakly-attached organic group that is connected to the part of the crosslinker molecule
that would crosslink slowly hydrolyzes off, leaving the crosslinker molecule free to react
with the polymer (glyoxal: Zaiton et al., 1991; glutaraldehyde: Matre, 1994);
(2) Components that can slowly form the crosslinker are added to the polymer solution, rather
than a crosslinker (phenol/formaldehyde: Moradi-Araghi, 1994).
10.12.4 Foams
Generally, these materials are placed as solutions with either dissolved gas that expands after
placement, or with no gas so that it subsequently foams in product flow. Foams are not commonly
used but could be considered for water removal applications.
O G
K
R
E 1.6mm for class 150 and 300
RTJ RF 6.4mm for class 400and above
Range (litres/min)
Flowmeter size
min max
½" 2.8 27.8
¾" 7.6 55.6
1" 18.75 187.5
1½" 55.6 694.4
2" 145.8 1458.3
3" 232.6 2292
4" 375 4514
Viscosity Limits
Above these viscosities you should plan on making calibration factor adjustments. The limits are
stated as Kinematic Viscosities.
Fluid viscosity impacts turbine meter calibration factor. The amount of impact varies with flow rate
and meter size. In general, a turbine meter will have repeatable performance at a given viscosity at a
constant flow rate. Since, with our viscous fluids, we don't enjoy such a luxury during our jobs,
inventory management (tank strapping) is done to provide turbine meter calibration factor
adjustments.
Mesh Per Wire Holes per Aperture Aperture % Free No. of No. of Micron
in gauge in2 ins mm Area meshes holes per rating
SWG cm2 µm
per cm
10 23 100 0.076 1.929 58 3.93 15 1929
12 24 144 0.061 1.557 54 4.73 22 1557
16 28 256 0.047 1.211 58 6.30 40 1211
20 28 400 0.035 0.894 50 7.87 62 894
30 32 900 0.022 0.572 46 11.80 139 572
40 34 1600 0.0158 0.4013 40 15.75 248 401
60 37 3600 0.0099 0.2506 35 23.60 560 251
80 39 6400 0.0073 0.1854 34 31.50 995 185
100 41 10000 0.0056 0.1422 31 39.37 1550 142
120 43 14400 0.0047 0.1203 32 47.24 2240 120
150 45 22500 0.0039 0.0997 34 59.00 3481 100
180 47 32400 0.0036 0.0903 42 70.80 5020 90
200 47 40000 0.0030 0.0762 36 78.70 6200 76
250 48 62500 0.0024 0.0610 36 98.40 9680 61
300 48.5 90000 0.0019 0.0483 32 118.00 13924 48
12.3.2 HT-400
Neolith NP 160(Quintruplex)
0 23.09 18.29 11.60 8.80 7.29 6.00 3.56 2.97 3.03 1.97 1.51 1.15 0.72 0.43
250 14.80 11.39 9.00
500 12.00 10.19 7.80 5.85 5.10 4.39
750 8.8 7.38 6.61
1000 0 5.03 5.80 4.72 4.39 3.80 2.51 2.10 1.64 1.28
1250 0 5.00
1500 4.20 3.90 3.65 3.34
1750 2.51 3.44 3.34
2000 0 3.00 3.10 3.00 2.25 1.85 1.52 1.21 1.00
2500 1.21 2.34 2.56 0.75
3000 0 0.51 1.95 1.85 1.61 1.36 1.16 0.48
3500 0 1.20 1.70
4000 0 1.56 1.46 1.20 1.02 0.92
4500 1.29 1.29 1.15
5000 1.02 1.25 1.06 0.67 0.26
6000 0 0.93 0.97 0.89 0.82 0.41
7000 0 0.80
8000 0.48 0.72 0.70 0.59
9000 0 0.62 0.39
10000 0.44 0.61 0.52 0.25
12500 0 0.48 0.46 0.34
15000 0 0.39 0.33 0.21
20000 0 0.30 0.20
25000 0.21 0.16
30000 0 0.13
40000 0.05
50000 0
70
2” 100psi-70cfm
60
2” 75psi-60cfm
50
Head (m) 40
30
20
1” 100psi-40cfm
10
0
5 10 15 20 25
Flowrate m3/hr
0.1 10 1.0
8.0
7.0
.11 6.0
1.1
5.0 1.1
.12
4.0 1.2
.13 1.2
3.5 1.3
.14
3.0 1.4 1.3
.50.40
.15 1.5 RELATIVE
2.2
.20 5 2.0 2.2
1.7
1.9 2.65
.15 2.9 1.8
10 1.8 3.0
1.9
.25 1.7
20 2.0
1.6 4.0
30
VELOCITY AT LIMIT OF STATIONARY DEPOSIT Vsm
V sm
6.0
2.5
.1 1.4 7.0
8.0
.40 PARTICLE DIAMETER d (mm)
1.3 10 3.0
FOR GRAINS WITH Ss = 2.65 sg
0.5 3.5
1.2
20 4.0
1.1 5.0
6.0
1.0
7.0
8.0
1.5 1.0 1.0
Fig. 4.3. Nomographic chart for maximum velocity at limit of stationary deposition, from Wilson (1979).
Conversion Factors
(Factors in boldface are exact)
ACCELERATION
To convert from to Multiply by
acceleration of free fall, standard (gn) meter per second squared (m/s2) 9.806 65 E+00
2 2
foot per second squared (ft/s ) meter per second squared (m/s ) 3.048 E-01
gal (Gal) meter per second squared (m/s2) 1.0 E-02
inch per second squared (in/s2) meter per second squared (m/s2) 2.54 E-02
ANGLE
To convert from to Multiply by
acre (based on U.S. survey foot) square meter (m2) 4.046 873 E+03
2
are (a) square meter (m ) 1.0 E+02
barn (b) square meter (m2) 1.0 E-28
circular mil square meter (m2) 5.067 075 E-10
circular mil square millimeter (mm2) 5.067 075 E-04
foot to the fourth power (ft4) meter to the fourth power (m4) 8.630 975 E-03
2
hectare (ha) square meter (m ) 1.0 E+04
inch to the fourth power (in4) meter to the fourth power (m4) 4.162 314 E-07
2 2
square foot (ft ) square meter (m ) 9.290 304 E-02
square inch (in2) square meter (m2) 6.4516 E-04
2 2
square inch (in ) square centimeter (cm ) 6.4516 E+00
square mile (mi2) square meter (m2) 2.589 988 E+06
square mile (mi2) square kilometre (km2) 2.589 988 E+00
square mile (based on U.S. survey foot) (mi2) square meter (m2) 2.589 998 E+06
2
square mile (based on U.S. survey foot) (mi ) square kilometre (km2) 2.589 998 E+00
square yard (yd2) square meter (m2) 8.361 274 E-01
erg per square centimeter second [erg/(cm2 · s)] watt per square meter (W/m2) 1.0 E-03
2
watt per square centimeter (W/cm ) watt per square meter (W/m2) 1.0 E+04
watt per square inch (W/in2) watt per square meter (W/m2) 1.550 003 E+03
FORCE
To convert from to Multiply by
pound-force per foot (lbf/ft) newton per meter (N/m) 1.459 390 E+01
pound-force per inch (lbf/in) newton per meter (N/m) 1.751 268 E+02
British thermal unitIT per cubic foot (BtuIT/ft3) joule per cubic meter (J/m3) 3.725 895 E+04
3
British thermal unitth per cubic foot (Btuth/ft ) joule per cubic meter (J/m3) 3.723 403 E+04
British thermal unitIT per pound (BtuIT/lb) joule per kilogram (J/kg) 2.326 E+03
British thermal unitth per pound (Btuth/lb) joule per kilogram (J/kg) 2.324 444 E+03
calorieIT per gram (calIT/g) joule per kilogram (J/kg) 4.1868 E+03
calorieth per gram (calth/g) joule per kilogram (J/kg) 4.184 E+03
British thermal unitIT per hour square foot degree Fahrenheit [BtuIT/(h ft2 · °F)] watt per square meter kelvin [W/(m2 K)] 5.678 263 E+00
British thermal unitth per hour square foot degree Fahrenheit [Btuth/(h · ft2 · °F)] watt per square meter kelvin [W/(m2 K)] 5.674 466 E+00
2 2
British thermal unitIT per second square foot degree Fahrenheit [BtuIT/(s ft °F)] watt per square meter kelvin [W/(m K)] 2.044 175 E+04
British thermal unitth per second square foot degree Fahrenheit [Btuth/(s ft2 °F)] watt per square meter kelvin [W/(m2 K)] 2.042 808 E+04
DENSITY OF HEAT
To convert from to Multiply by
British thermal unitIT per square foot (BtuIT/ft2) joule per square meter (J/m2) 1.135 653 E+04
2
British thermal unitth per square foot (Btuth/ft ) joule per square meter (J/m2) 1.134 893 E+04
2 2
calorieth per square centimeter (calth/cm ) joule per square meter (J/m ) 4.184 E+04
langley (calth/cm2) joule per square meter (J/m2) 4.184 E+04
British thermal unitIT per square foot hour [BtuIT/(ft2 · h)] watt per square meter (W/m2) 3.154 591 E+00
British thermal unitth per square foot hour [Btuth/(ft2 · h)] watt per square meter (W/m2) 3.152 481 E+00
2 2
British thermal unitth per square foot minute [Btuth/(ft · min)] watt per square meter (W/m ) 1.891 489 E+02
British thermal unitIT per square foot second [BtuIT/(ft2 · s)] watt per square meter (W/m2) 1.135 653 E+04
2 2
British thermal unitth per square foot second [Btuth/(ft · s)] watt per square meter (W/m ) 1.134 893 E+04
British thermal unitth per square inch second [Btuth/(in 2 · s)] watt per square meter (W/m2) 1.634 246 E+06
2 2
calorieth per square centimeter minute [calth/(cm · min)] watt per square meter (W/m ) 6.973 333 E+02
calorieth per square centimeter second [calth/(cm2 · s)] watt per square meter (W/m2) 4.184 E+04
FUEL CONSUMPTION
To convert from to Multiply by
gallon (U.S.) per horsepower hour [gal/(hp · h)] cubic meter per joule (m3/J) 1.410 089 E-09
gallon (U.S.) per horsepower hour [gal/(hp · h)] liter per joule (L/J) 1.410 089 E-06
3
mile per gallon (U.S.) (mpg) (mi/gal) meter per cubic meter (m/m ) 4.251 437 E+05
mile per gallon (U.S.) (mpg) (mi/gal) kilometer per liter (km/L) 4.251 437 E-01
mile per gallon (U.S.) (mpg) (mi/gal) liter per 100 kilometer (L/100 km) divide 235.215 by number of miles per gallon
pound per horsepower hour [lb/(hp · h)] kilogram per joule (kg/J) 1.689 659 E-07
British thermal unitIT per degree Fahrenheit (BtuIT/°F) joule per kelvin (J/k) 1.899 101 E+03
British thermal unitth per degree Fahrenheit (Btuth/°F) joule per kelvin (J/k) 1.897 830 E+03
British thermal unitIT per degree Rankine (BtuIT/°R) joule per kelvin (J/k) 1.899 101 E+03
British thermal unitth per degree Rankine (Btuth/°R) joule per kelvin (J/k) 1.897 830 E+03
British thermal unitIT per hour (BtuIT/h) watt (W) 2.930 711 E-01
British thermal unitth per hour (Btuth/h) watt (W) 2.928 751 E-01
British thermal unitth per minute (Btuth/min) watt (W) 1.757 250 E+01
British thermal unitIT per second (BtuIT/s) watt (W) 1.055 056 E+03
British thermal unitth per second (Btuth/s) watt (W) 1.054 350 E+03
calorieth per minute (calth/min) watt (W) 6.973 333 E-02
calorieth per second (calth/s) watt (W) 4.184 E+00
kilocalorieth per minute (kcalth/min) watt (W) 6.973 333 E+01
kilocalorieth per second (kcalth/s) watt (W) 4.184 E+03
ton of refrigeration (12 000 BtuIT/h) watt (W) 3.516 853 E+03
British thermal unitIT per pound degree Fahrenheit [BtuIT/(lb · °F)] joule per kilogram kelvin [J/(kg · K)] 4.1868 E+03
British thermal unitth per pound degree Fahrenheit [Btuth/(lb · °F)] joule per kilogram kelvin [J/(kg · K)] 4.184 E+03
British thermal unitIT per pound degree Rankine [BtuIT/(lb · °R)] joule per kilogram kelvin [J/(kg · K)] 4.1868 E+03
British thermal unitth per pound degree Rankine [Btuth/(lb · °R)] joule per kilogram kelvin [J/(kg · K)] 4.184 E+03
calorieIT per gram degree Celsius [calIT/(g · °C)] joule per kilogram kelvin [J/(kg · K)] 4.1868 E+03
calorieth per gram degree Celsius [calth/(g · °C)] joule per kilogram kelvin [J/(kg · K)] 4.184 E+03
calorieIT per gram kelvin [calIT/(g · K)] joule per kilogram kelvin [J/(kg · K)] 4.1868 E+03
calorieth per gram kelvin [calth/(g · K)] joule per kilogram kelvin [J/(kg · K)] 4.184 E+03
THERMAL CONDUCTIVITY
To convert from to Multiply by
Britsh thermal unitIT foot per hour square foot degree Fahrenheit [BtuIT · ft/(h · ft2 · °F)] watt per meter kelvin [W/(m · K)] 1.730 735 E+00
Britsh thermal unitth foot per hour square foot degree Fahrenheit [Btuth · ft/(h · ft2 · °F)] watt per meter kelvin [W/(m · K)] 1.729 577 E+00
2
Britsh thermal unitIT inch per hour square foot degree Fahrenheit [BtuIT · in/(h · ft · °F)] watt per meter kelvin [W/(m · K)] 1.442 279 E-01
Britsh thermal unitth inch per hour square foot degree Fahrenheit [Btuth · in/(h · ft2 · °F)] watt per meter kelvin [W/(m · K)] 1.441 314 E-01
Britsh thermal unitIT inch per second square foot degree Fahrenheit [BtuIT · in/(s · ft2 · °F)] watt per meter kelvin [W/(m · K)] 5.192 204 E+02
Britsh thermal unitth inch per second square foot degree Fahrenheit [Btuth · in/(s · ft2 · °F)] watt per meter kelvin [W/(m · K)] 5.188 732 E+02
calorieth per centimeter second degree Celsius [calth/(cm · s · °C)] watt per meter kelvin [W/(m · K)] 4.184 E+02
THERMAL DIFFUSIVITY
To convert from to Multiply by
square foot per hour (ft2/h) square meter per second (m2/s) 2.580 64 E-05
THERMAL INSULANCE
To convert from to Multiply by
clo square meter kelvin per watt (m2 · K/W) 1.55 E-01
2
degree Fahrenheit hour square foot per British thermal unitIT (°F · h · ft /BtuIT) square meter kelvin per watt (m2 · K/W) 1.761 102 E-01
degree Fahrenheit hour square foot per British thermal unitth (°F · h · ft2/Btuth) square meter kelvin per watt (m2 · K/W) 1.762 280 E-01
THERMAL RESISTANCE
To convert from To Multiply by
degree Fahrenheit hour per British thermal unitIT (°F · h/BtuIT) Kelvin per watt (K/W) 1.895 634 E+00
degree Fahrenheit hour per British thermal unitth (°F · h/Btuth) Kelvin per watt (K/W) 1.896 903 E+00
degree Fahrenheit second per British thermal unitIT (°F · s/BtuIT) Kelvin per watt (K/W) 5.265 651 E-04
degree Fahrenheit second per British thermal unitth (°F · s/Btuth) Kelvin per watt (K/W) 5.269 175 E-04
THERMAL RESISTIVITY
To convert from to Multiply by
degree Fahrenheit hour square foot per British thermal unitIT inch [°F · h · ft2/(BtuIT · in)] meter Kelvin per watt (m · K/W) 6.933 472 E+00
degree Fahrenheit hour square foot per British thermal unitth inch [°F · h · ft2/(Btuth · in)] meter Kelvin per watt (m · K/W) 6.938 112 E+04
LENGTH
To convert from to Multiply by
LIGHT
To convert from to Multiply by
candela per square inch (cd/in2) candela per square meter (cd/m2) 1.550 003 E+03
footcandle lux (lx) 1.076 391 E+01
2
footlambert candela per square meter (cd/m ) 3.426 259 E+00
lambert candela per square meter (cd/m2) 3.183 099 E+03
2
lumen per square foot (lm/ft ) lux (lx) 1.076 391 E+01
phot (ph) lux (lx) 1.0 E+04
stilb (sb) candela per square meter (cd/m2) 1.0 E+04
ounce (avoirdupois) per square foot (oz/ft2) kilogram per square meter (kg/m2) 3.051 517 E-01
2
ounce (avoirdupois) per square inch (oz/in ) kilogram per square meter (kg/m2) 4.394 185 E+01
2 2
ounce (avoirdupois) per square yard (oz/yd ) kilogram per square meter (kg/m ) 3.390 575 E-02
pound per square foot (lb/ft2) kilogram per square meter (kg/m2) 4.882 428 E+00
2 2
pound per square inch (not pound force) (lb/in ) kilogram per square meter (kg/m ) 7.030 696 E+02
pound per hour (lb/h) kilogram per second (kg/s) 1.259 979 E-04
pound per minute (lb/min) kilogram per second (kg/s) 7.559 873 E-03
pound per second (lb/s) kilogram per second (kg/s) 4.535 924 E-01
ton, short, per hour kilogram per second (kg/s) 2.519 958 E-01
grain per gallon (U.S.) (gr/gal) kilogram per cubic meter (kg/m3) 1.711 806 E-02
grain per gallon (U.S.) (gr/gal) milligram per liter (mg/L) 1.711 806 E+01
3 3
gram per cubic centimeter (g/cm ) kilogram per cubic meter (kg/m ) 1.0 E+03
ounce (avoirdupois) per cubic inch (oz/in3) kilogram per cubic meter (kg/m3) 1.729 994 E+03
3
ounce (avoirdupois) per gallon [Canadian and U.K. (Imperial)] (oz/gal) kilogram per cubic meter (kg/m ) 6.236 023 E+00
ounce (avoirdupois) per gallon [Canadian and U.K. (Imperial)] (oz/gal) gram per liter (g/L) 6.236 023 E+00
ounce (avoirdupois) per gallon (U.S.) (oz/gal) kilogram per cubic meter (kg/m3) 7.489 152 E+00
ounce (avoirdupois) per gallon (U.S.) (oz/gal) gram per liter (g/L) 7.489 152 E+00
pound per cubic foot (lb/ft3) kilogram per cubic meter (kg/m3) 1.601 846 E+01
pound per cubic inch (lb/in3) kilogram per cubic meter (kg/m3) 2.767 990 E+04
3
pound per cubic yard (lb/yd ) kilogram per cubic meter (kg/m3) 5.932 764 E-01
pound per gallon [Canadian and U.K. (Imperial)] (lb/gal) kilogram per cubic meter (kg/m3) 9.977 637 E+01
pound per gallon [Canadian and U.K. (Imperial)] (lb/gal) kilogram per liter (kg/L) 9.977 637 E-02
pound per gallon (U.S.) (lb/gal) kilogram per cubic meter (kg/m3) 1.198 264 E+02
pound per gallon (U.S.) (lb/gal) kilogram per liter (kg/L) 1.198 264 E-01
slug per cubic foot (slug/ft3) kilogram per cubic meter (kg/m3) 5.153 788 E+02
3
ton, long, per cubic yard kilogram per cubic meter (kg/m ) 1.328 939 E+03
ton, short, per cubic yard kilogram per cubic meter (kg/m3) 1.186 553 E+03
pound-force foot per inch (lbf · ft/in) newton meter per meter (N · m/m) 5.337 866 E+01
pound-force inch per inch (lbf · in/in) newton meter per meter (N · m/m) 4.448 222 E+00
PERMEABILITY
To convert from to Multiply by
POWER
To convert from to Multiply by
Continued…
RADIOLOGY
To convert from to Multiply by
TEMPERATURE
To convert from to Multiply by
TEMPERATURE INTERVAL
To convert from to Multiply by
TIME
To convert from to Multiply by
foot per hour (ft/h) meter per second (m/s) 8.466 667 E-05
foot per minute (ft/min) meter per second (m/s) 5.08 E-03
foot per second (ft/s) meter per second (m/s) 3.048 E-01
inch per second (in/s) meter per second (m/s) 2.54 E-02
kilometer per hour (km/h) meter per second (m/s) 2.777 778 E-01
knot (nautical mile per hour) meter per second (m/s) 5.144 444 E-01
mile per hour (mi/h) meter per second (m/s) 4.4704 E-01
mile per hour (mi/h) kilometer per hour (km/h) 1.609 344 E+00
mile per minute (mi/min) meter per second (m/s) 2.682 24 E+01
mile per second (mi/s) meter per second (m/s) 1.609 344 E+03
revolution per minute (rpm) (r/min) radian per second (rad/s) 1.047 198 E-01
rpm (revolution per minute) (r/min) radian per second (rad/s) 1.047 198 E-01
VISCOSITY, DYNAMIC
To convert from to Multiply by
VISCOSITY, KINEMATIC
To convert from to Multiply by
acre-foot (based on U.S. survey foot) cubic meter (m3) 1.233 489 E+03
barrel [for petroleum, 42 gallons (U.S.)](bbl) cubic meter (m3) 1.589 873 E-01
barrel [for petroleum, 42 gallons (U.S.)](bbl) liter (L) 1.589 873 E+02
3
bushel (U.S.) (bu) cubic meter (m ) 3.523 907 E-02
bushel (U.S.) (bu) liter (L) 3.523 907 E+01
cord (128 ft3) cubic meter (m3) 3.624 556 E+00
3 3
cubic foot (ft ) cubic meter (m ) 2.831 685 E-02
cubic inch (in3) cubic meter (m3) 1.638 706 E-05
cubic mile (mi3) cubic meter (m3) 4.168 182 E+09
3
cubic yard (yd ) cubic meter (m3) 7.645 549 E-01
cup (U.S.) cubic meter (m3) 2.365 882 E-04
cup (U.S.) liter (L) 2.365 882 E-01
cup (U.S.) milliliter (mL) 2.365 882 E+02
3
fluid ounce (U.S.) (fl oz) cubic meter (m ) 2.957 353 E-05
fluid ounce (U.S.) (fl oz) milliliter (mL) 2.957 353 E+01
3
gallon [Canadian and U.K. (Imperial)] (gal) cubic meter (m ) 4.546 09 E-03
gallon [Canadian and U.K. (Imperial)] (gal) liter (L) 4.546 09 E+00
3
gallon (U.S.) (gal) cubic meter (m ) 3.785 412 E-03
gallon (U.S.) (gal) liter (L) 3.785 412 E+00
gill [Canadian and U.K. (Imperial)] (gi) cubic meter (m3) 1.420 653 E-04
gill [Canadian and U.K. (Imperial)] (gi) liter (L) 1.420 653 E-01
gill (U.S.) (gi) cubic meter (m3) 1.182 941 E-04
gill (U.S.) (gi) liter (L) 1.182 941 E-01
liter (L) cubic meter (m3) 1.0 E-03
3
ounce [Canadian and U.K. fluid (Imperial)] (fl oz) cubic meter (m ) 2.841 306 E-05
ounce [Canadian and U.K. fluid (Imperial)] (fl oz) milliliter (mL) 2.841 306 E+01
ounce (U.S. fluid) (fl oz) cubic meter (m3) 2.957 353 E-05
ounce (U.S. fluid) (fl oz) milliliter (mL) 2.957 353 E+01
peck (U.S.) (pk) cubic meter (m3) 8.809 768 E-03
peck (U.S.) (pk) liter (L) 8.809 768 E+00
pint (U.S. dry) (dry pt) cubic meter (m3) 5.506 105 E-04
pint (U.S. dry) (dry pt) liter (L) 5.506 105 E-01
pint (U.S. liquid) (liq pt) cubic meter (m3) 4.731 765 E-04
pint (U.S. liquid) (liq pt) liter (L) 4.731 765 E-01
quart (U.S. dry) (dry qt) cubic meter (m3) 1.101 221 E-03
quart (U.S. dry) (dry qt) liter (L) 1.101 221 E+00
3
quart (U.S. liquid) (liq qt) cubic meter (m ) 9.463 529 E-04
quart (U.S. liquid) (liq qt) liter (L) 9.463 529 E-01
3
stere (st) cubic meter (m ) 1.0 E+00
Continued…
cubic foot per minute (ft3/min) cubic meter per second (m3/s) 4.719 474 E-04
3
cubic foot per minute (ft /min) liter per second (L/s) 4.719 474 E-01
3 3
cubic foot per second (ft /s) cubic meter per second (m /s) 2.831 685 E-02
cubic inch per minute (in3/min) cubic meter per second (m3/s) 2.731 177 E-07
cubic yard per minute (yd3/min) cubic meter per second (m3/s) 1.274 258 E-02
3
gallon (U.S.) per day (gal/d) cubic meter per second (m /s) 4.381 264 E-08
gallon (U.S.) per day (gal/d) liter per second (L/s) 4.381 264 E-05
3
gallon (U.S.) per minute (gpm) (gal/min) cubic meter per second (m /s) 6.309 020 E-05
gallon (U.S.) per minute (gpm) (gal/min) liter per second (L/s) 6.309 020 E-02
Continued…
Continued…