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Guo qiang Li, Rui ping Zhou, Xiao fang Luo, Hong Zhou and Qiang Xu*
Abstract
C36 H26 N2 O4 Zn, monoclinic, C2/c (no. 15), a = 43.237(10) Å,
b = 17.201(4) Å, c = 11.271(2) Å, β = 103.009(5)°, V = 8168(3) Å3 ,
Z = 12, Rgt (F) = 0.0442, wRref (F 2 ) = 0.1530, T = 100(2) K.
The crystal structure is shown in the figure. The radii of the el-
lipsoids are drawn with an arbitrary probability. Tables 1 and
DOI 10.1515/ncrs-2017-0025 2 contain details on crystal structure and measurement con-
Received January 20, 2017; accepted July 18, 2017; available ditions and a list of the atoms including atomic coordinates
online August 5, 2017 and displacement parameters.
Source of material
The educt 1,1′-((1E,1′E)-(((ethane-1,2-diylbis(oxy))bis(2,1-
*Corresponding author: Qiang Xu, Chongqing Key Laboratory
phenylene))bis(azanylylidene))bis(methanylylidene))bis
of Environmental Materials and Remediation, Technologies,
Chongqing University of Arts and Sciences, Chongqing, 402160, (naphthalen-2-ol) (H2 L) used in the present work was
P. R. China, e-mail: 1050573038@qq.com synthesized via a standard Schiff base condensation reaction
Guo qiang Li: Chongqing Key Laboratory of Environmental Materials of 2-hydroxy-1-naphthaldehyde (0.6887 g, 4 mmol) and
and Remediation, Technologies, Chongqing University of Arts and bis(4-aminophenoxy)ethane (0.4886 g, 2 mmol) following
Sciences, Chongqing, 402160, P. R. China
a modified literature procedure [3]. All other reagents were
Rui ping Zhou and Hong Zhou: Chongqing University of Arts and
Sciences, Chongqing, 402160, P. R. China
commercially available and used without further purification.
Xiao fang Luo: Third Branch of Chongqing Academy of Metrology The title compound was prepared by a vapor diffusion
and Quality Inspection, Chongqing, 402160, P. R. China method. To a yellow MeOH solution (15 mL) of H2 L (0.552 g,
© 2017 Guo qiang Li et al., published by De Gruyter.
This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.
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with cold MeOH, and dried under vacuum over P4 O10 . The two imine nitrogen atoms with the N(1)-Zn(1)-N(2) bond angle
yellow block-shaped crystals suitable for X-ray analysis were is 163.15(12)°, and the bond length of Zn(1)-N(1), Zn(1)-N(2) are
obtained from a acetone solution of the powdered solid after 2.063(3) Å and 2.067(3) Å, respectively.
about 3 days. All bond lengths and angles in the organic ligand system
are in the expected ranges.
Experimental details
All of the hydrogen atoms were placed in the calculated posi- Acknowledgements: I acknowledge support for the pub-
tions and all the non-hydrogen atoms were refined anisotrop- lication fee by the Scientific Research Fund of Chongqing
ically. Municipal Education Commissionthe (KJ1601115), Chongqing
University of Arts and Sciences (Z2015CH02), Chongqing Uni-
versity of Arts and Sciences (XSKY2016058) and Chongqing
Discussion University of Arts and Sciences (XSKY2016067).
Schiff base is one of the oldest compound bearing the
—N=CH— functional group, which can be readily synthe- References
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