QUICE REVIEW CENTER 4th Exam August 19,2019

G. Tolentino St., Sampaloc Manila Org Chem,Fluid Flow,IC

1) Pheromone is a/an a. Alkane b.Alkene c) ketone d) amine a) 45.0 hp b. 63.0 hp c) 60.3 hp d)50.3 hp
2) Identify the incorrect statement regarding the synthesis of alkenes 16) Cooling water at 22℃ flows through a 25 mm inside diameter smooth tube
a) Cracking of HC yields alkenes of length 10m. If the pressure drop throughout the pipe is 20 kN/m2. Estimate
b) The reactions are exothermic the mass flow rate of water in the pipe.
c) Zeolite catalyst helps in the synthesis of alkenes a) 1.12 kg/s b. 1.22 kg/s c) 2.11 kg/s d) 0.301 kg/s
d) The synthesis of alkenes is otherwise known as reforming 17) Over a 30 m length of 150 mm vacuum line carrying air at 293 K, the
3) What is the hybridization of H2S? pressure falls from 1kPa to 0.10 kPa. If relative roughness is 0.002, what is
a) Sp b. Sp2 c) sp3 d) sp3d the approximate flow rate?
4) Arrange the following in increasing boiling points a) 0.011 kg/s b. 0.022 kg/s c) 0.033 kg/s d) 0.044 kg/s
i) Hexane iv) 3-methylpentane 18) CH4 is to be compressed from atmospheric pressure to 30 MPa in 4 stages.
ii) 2,2-dimethylbutane v) 2,3-dimethylbutane Calculate the work required per kg of gas. Assume compression to be
isentropic and gas behaves as an ideal gas. Use gamma = 1.40
iii) 2-methylpentane
a) 711 kJ/kg b. 697 kJ/kg c) 996 kJ/kg d) 549.51 kJ/kg
a) i<ii<iii<iv<v c) v<iv<iii<ii<i
b) i<iv<iii<v<ii d) ii<v<iii<iv<i 19) Hydrogen is pumped from a reservoir at 2 MPa pressure through a clean
horizontal mild steel pipe 50 mm diameter and 500 m long. The downstream
5) The electronegativity difference between covalently bonded atoms is
pressure is also 2 MPa and the pressure of this gas is raised to 2.6 MPa by
a) Less than 0 b. 0-0.30 c) 0.30-1.70 d) over 1.7
a pump at the upstream end of the pipe. The conditions of flow are isothermal
6) Hydrolysis of an ester leads to two compounds. Which of the following and the temperature of the gas is 293 K. The viscosity of H2 at 293 K is 0.009
compounds is formed from such hydrolysis? x 10-3 Pas. What is the effective rate of working of the pump?
a) alcohol and aldehyde c. alcohol and a COOH a) 85 kW b. 113 kW c) 131 kW d) 145 kW
b) Two alcohols d. A ketone and COOH
20) Evaluate the integral of (tan(lnx))/x with respect to x
7) In nucleophilic addition reactions of alkenes with HZ in which the nucleophile a) ln cos(lnx)+C c) tan(lnx)2 +C
Z attaches to more alkyl substituted carbon and the H attaches to the carbon b) ln sec(lnx)+C d) ½ tan2(lnx) + C
that already has the greater number of H atoms, the rule being followed by
21) The motion of a particle is space from t = 0 to t = 10 seconds is defined
the reaction is
by distance in meter is ax = 0.8 t, ay = 2-0.3t, az = 5. What is the total
a) Markovnikov’s b. Knoevenagel’s c) Huckel d) Saytzeffs
distance travelled by body after 10 seconds?
8) The hydrobromination of 4-methyl-3-heptene in the presence of benzoyl a) 314.02 b. 642.26 c) 287.71 d) 298.11
peroxide yields:
22) The circle x2 + y2 =36 is revolved about the line y=14. What is the
a) 1-bromo-4-methylheptane c. 3-bromo-4-methylheptane
volume generated?
b) 2-bromo-4methylheptane d. 4-bromo-4-methylheptane
a) 9812.33 b. 8122.23 c) 9948.56 d) 1221.23
9) Ethanoic anhydride + H2O →
23) Find the volume of solid revolving about line x =-5 the region bounded
a) Acetic acid b. 2 Acetic acid c) CH4 and CH3OH d) C2H6 and O2
by the parabola x = 2y-y2 and x = y2-4
10) Methyl acetate + H2O → a) 36pi b. 42 pi c) 21pi d) 63pi
a) Formaldehyde and CH4 b. Acetic acid and HCl
24) Suppose a 2-J of work is needed to stretch a spring from its natural
c. Acetic acid and MeOH d. 2 Acetic acid
length of 30 cm to a length of 42 cm. How much work is needed to
Item 11-13. C6H6 at 100℉ is pumped through the system at the rate of 40
stretch it from 35 cm to 40 cm?
gal/min. The reservoir is at atmospheric pressure. The gauge pressure at the end
a) 10.4 J c) 25.2 J
of the discharge line is 50 psi. The discharge line is 10 ft, and the pump suction is
b) 2.04 J d) 1.04 J
4 ft above the level in the reservoir. The discharge line is 1 ½ inch schedule 40
pipe. The friction in the suction line is known to be 0.50 psia, and that in the 25) 80 ft long rope with a weight of 3 lbf/ft hangs over the edge of a building
discharge line is 5.5 psia. The mechanical efficiency of the pump is 0.60. Density that is 2000 ft high. How much work is required to pull half of the rope
= 54 lb/ft3 and its vapor pressure is 3.8 psia. to the top of the building?
a) 9600 c) 2400
11) The developed head of the pump
b) 4800 d)7200
a) 195.95 ft b. 159.95 ft c) 477.95f d) 120.13 ft
12). The total power input a) 2.86 hp b. 2.33 kW c) 1.75 kW d) 2.33 hp 26) Find the volume generated by y = x3, the line x = 0 and y=8 revolved
about the y-axis.
12) If the pump manufacturer specifies a required NPSHr of 10 ft, will the pump
a) 69pi/5 c) 32pi
be suitable for this service
b) 96pi/5 d) 72pi
a) Yes, 23.77 ft b. Yes, 17.25 ft c) No, 9.07 ft d) No, 8.64 ft
Item 14-15.It is proposed to pump 10,000 kg/hr of toluene at 114℃ and 1.1 atm 27) Find the area bounded by x = 2y2-4y+4 and x = y2-2y+4
absolute pressure from the reboiler of a distillation tower to a second distillation a) ¾ b. 4/3 c) 28/3 d) 20/3
unit without cooling the toluene before it enters the pump. If the friction loss in the Item 29-30
line between the reboiler and the pump is 7 kPa, and the density of toluene is 28) A body weighing 64 lbf is dropped from a certain height with an initial
866 kg/m3. velocity of 10 ft/s. Assume air resistance is proportional to the velocity
13) How far above the pump must the liquid level in the reboiler be maintained of the body. If the limiting velocity is known to be 128 ft/s. What is the
to give a NPSH of 2.5 m? Pv=841mmHg velocity of the body after 3 seconds?
a) 2.4 m b. 3.4 m c) 4.4 m d) 5.4 m a) 81.23 ft/s c) 84.56 ft/s
14) Calculate the power required to drive the pump if the pump is to elevate the b) 72.26 ft/s d) 106 ft/s
toluene 10m, the pressure in the second tank is atmospheric, and the 29) What is the position after 3 seconds?
friction loss in the discharge line is 35 kPa. a) 134.95 ft c) 134.95 m
a) 0.347 kW b. 0.316 kW c)0.282 k d) 0.467 kW b) 111.21 ft d) 111.21 m
15) A centrifugal fan is used to take flue gas at rest and at a pressure of 29.0
inHg and a temperature of 200℉ and discharge it at a pressure of 30.1 inHg Trust in the Lord with all your heart and lean not on your own
understanding. In all your ways acknowledge Him and He will make
and a velocity of 150 ft/s. The efficiency of the fan may be taken as 0.65 and
your paths straight. Proverbs 3:5-6
the MW = 31.3. Calculate the power needed to move the 10,000 std ft3/min
Make everyday count 
of gas.Use 378 ft3/lbmol