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CHATER 1
1.1 INTRODUCTION
MAJOR PRODUCTS:
Sudarshan, is the largest pigment producer in India, has been a very prominent in the
pigment market for over 50 years, and are Major producers of the pigments. These pigments
being a color-providing component in various industries like Paints, Textiles, Dyes, Cement
Manufacturing, Rubber, Cosmetics and Leather industries. Sudarshan is uniquely placed to offer
the complete range – General Purpose Grades, High Performance, Specialist hard to make colors
and Effect Pigments. With equivalent or superior quality & consistency to the leading
international grades and provide solutions for all technical challenges, all from just one supplier.
CHAPTER 2
2.1 PLANT DESCRIPTION
The Sudarshan Chemical Limited is located at MIDC Roha. The plant is built outside the
locality surrounded by mountains. This plant spreads over 89 acres. The plant comprises of many
subunits of pigment both batch and continuous mode.
2.1.1 AZO PLANT (OPERATED IN BATCH MODE)
Azo plant operates on basis of Neutralization reaction. The Diazotization reaction is carried
out. This reaction being exothermic, ice is used as a cooling medium for reaction. The reaction needs
to be carried out at 0°c.this is done by directly adding the ice inside the Stirred Tank Reactor. This
reaction is followed by filtration, subsequent, drying (of cake), dried product is then pulverized and
blended. Product is then packed. Certain additives and reagent are added for the color, shade and
required uniformity. PH is also maintained for required shade (for yellow it is maintained 5). This
plant operates batch wise and tray dryers are used. The time for filtration is 3 to 4 hrs and the cake is
removed as soon as conductivity exceeds the prescribed value. Washing is given with water to
remove dissolved impurities.
2.1.2 AZO PLANT (OPERATED IN CONTINUOUS MODE)
In this plant the cake obtained from the plate and press filter is removed and fed to
continuous dryer. The product obtained is continuously pulverized and blended.
2.1.3 ICE PLANT
This plant operates on refrigeration cycle. The refrigerant used in liquid ammonia.
Ammonia is compresses to a high pressure at about 200 atm and condensed in a condenser using
chilled water. The condensed ammonia is then expanded using an expander valve and
temperature is decreased to a very low value. The ice maker (evaporator) is in the form of a
jacketed vessel. The water is poured on the walls of the vessel, where ammonia jacket the vessels
and water then gets converted into ice converted to ice almost instantaneously. The ice is then
scrapped by rotating scrapped and obtained ice is then converted into chip form by use of a
conveyer belt. Nearly 140 Tons of ice is produced. This ice can easily be pneumatically
conveyed instantaneously by a blower into pigment plant reciprocating compressors are used.
The water from cooled water is used for cooling the compressor. The oil separator is used in case
the oil gets mixed with the water.
Precipitin is employed, which removes the ash particles by principle of corona discharge. There
is separate ash separator for ash removal. 14 TPH and 15 TPH are also used as standby boilers.
CHAPTER 3
3.1 EFFLUENT TREATMENT PLANT
Effluent treatment plant are used to treat the industrial waste water because of it highly
acidic in nature and also it contain organic matter due to this problem we treat the waste water
and control the pH now following procedure is used to treat the waste water.
DIAZO SOLUTION
CHATER 4
4.1 PRODUCTION OF PIGMENTS
COUPLER
REACTOR
STRIKER
FILTER PRESS
TRAY DRIVER
PULVERIZER
BLENDER
PACKAGING
In a pigment products same liquid and solid chemicals are used. In liquid chemicals the
Hydrochloric acid (HCL acid) is dilute 30 % from 32 %. The Sodium Nitrate (NaNO2) is dilute
30% from 35%. The acetic acid (CH3COOH) is dilute 40-42% from 45%. The Sulphuric acid
(H2SO4) is not dilute its directly used. And the caustic soda (NaOH), Propylene Glycol, etc.
In a solid chemicals, Naphthalene, Aniline, 2, 5Dichloro-anilide etc.
dissolution and diazotization: Take 10m³ MSRL Vessel. Take a water and heat with steam.
Charge 2,5dichloro -aniline 100% and stirrer for 30 min. Heat the base slurry to 70 to 72°C to
get clear oily solution. Add HCL 30%. Then start natural cooling up to 40-45°C & stirring in 1st
gear, then cool to 0°C with Ice. Give sample to lab. Add NaNO2 30% at temp. 0-5°C Give
sample to lab. Stirror1 hrs at 0-5°C with Nitrite. pH 3.8 to 4.5
4.1.3 coupler :
Take 10 m³ vessel add water and OT-paste and AS-P paste and Stir for 30 min. Heat to 90-
95°C and add NaOH 40% dissolve completely cool immediately to 40°C. Give the sample to lab.
4.2.1 Striker :
30 m³ clean vessel. Charge ice and charge Glacial acetic acid. Transfer diazo vessel to striker
vessel remove excess of nitrite just before striking. Give the sample for checking excess nitrite
for lab. Add amido for maintained the excess conc.observed . Add now coupler in striker vessel ,
run striker vessel in 1hr -1hr 30min at 0-10°C. pH 6.3 -6.5 and Heat to 45°C & stir for 2 hrs.
Check striking ok ,if ok Give the sample of striking for checking to lab. Adjust pH 10.5-10.8
slowly with NaOH 40% Heat to 95°C and maintain at 95°C for 1hrs during heating maintain pH
10.5- 10.8 Cool to 70°C. Give F. S. Sample. And following operation as follow
4.2.3 Filtration Operation: Filter presses are sometimes called "Plate-and-Frame Filters"
which describes the style of filters developed from the 1800's onwards .Filter presses generally
work in a "batch" manner. They are loaded with slurry before completing a filtering cycle and
producing a batch of solid filtered material, called the filter "cake". The solid is removed, the
press re-loaded with slurry and the batch cycle repeated.
Often, a part of the exhausted air is recirculated with a fan located within or outside the drying
chamber. These dryers require large amount of labor to load and unload the product. Typically,
the drying times are long (10 hours). The key to successful operation is the uniform air flow
distribution over the trays as the slowest drying tray decides the residence time required.
4.3.2 Pulverization:
A pulverizer or grinder is mechanical device which is acts on the cake and it converts into the
Fine form powder it use in paint and dyes industries.
4.3.3 Blending: it means mixing the parameter which is present in the pigment aleardy
standardized but any deficiency is their so that we will add some blends to correct it such as like
pigment color ,sizing etc
CHAPTER 5
5.1 PRODUCTION OF MICA
GRINDING
SEPERATION
COATING
FILTRATION
WASHING (AIR)
DRYER
KILAN CALCINATION
BLENDING
TESTING
PACKING
where baking of mica take place at temp 850ċ and go to blending of titanium dioxide be done
and finally mica production take place after that is go for testing where any heavy material will
be present in the product so it rejected and nothing be there so it will go for packing.
5.1.1 Pumps
Centrifugal pump:
The centrifugal pump is by far the most widely used type in the chemical and petroleum
industries. It will pump liquids with very wide-ranging properties and suspensions with high
solids content including, for example, cement slurries, and may be constructed from a very wide
range of corrosion resistant materials. The whole pump casing may be constructed from plastics
such as polypropylene or it may be fitted with a corrosion resistant lining. Because it operates at
high speed, it may be directly coupled to an electric motor and it will give a high flow rate for its
size.
the engine or you can say building of pressure in the fluids, but there are used in limited
application because they require lot of maintenance. These pump are positive displacement
pumps and that is reason don’t require any type of priming for their functioning in the starting
period of the pump. Following parts of the reciprocating pump such as piston is made of mild
steel ,liner made of mild steel , inlet and out let valve is made of from steel and brass also ,motor
,shaft , relief valve , piston ring these are parts of this pump and this works same like an I.C
engine .
Working principal:
The working of this pump such first of all the piston has the function of providing the
suction force , so that the liquid can be lift up or can be sucked in with great force. After that
comes the compression part which will impart the required pressure energy to the fluids , in this
part of the phase the piston have to do a great work so that the liquid can be compressed
properly and its pressure can increased to the desired level. The inlet and the outlet valve open at
certain pressure which is set by the manufacture.
If the piston is of single acting type which means it can suck from one side and transmit
to the same side only. But we can go with double reciprocating pump too which have the
function of the giving suction and discharge simultaneously in each stroke. This pump can be
used as the compressor also but for that we have a good valve arrangement which can operate
with good frequency.
Advantages :
i. give high pressure at outlet
ii. give high suction lift
iii. they used for air also
5.1.3 Valves:
The valves used for chemical process plant can be divided into two broad classes, depending
on their primary function. A valve is a mechanical device used either to regulate the flow /
control. Flow or to stop the flow of fluid through a pipe line or in or out of the vessel.
Gate & Plug Valve: A valve selected for shut-off purposes should give a positive seal in
the closed position and minimum resistance to flow when open. Gate, plug and ball
valves are most frequently used for this purpose.
Ball Valve: Ball valve consists of a hollow spherical ball which is having a bore
diametrically.
Globe Valve: If flow control is required, the valve should be capable of giving smooth
control over the full range of flow, from fully open to close. Globe valves are normally
used, though the other types can be used.
ROUTE OF ENTRY:
Skin Contact – Yes
Skin Absorption - Yes
Eye Contact - Yes
Inhalation - Yes
HEALTH EFFECT
Eye Effects: Mild concentrations of product will cause conjunctivitis. Contact with higher
concentrations of product will cause swelling of the eyes and lesions with a possible loss of
vision.
Skin Effects: Mild concentration of product will cause dermatitis or conjunctivitis. Contact with
higher concentration of product will called caustic like dermal burns and inflammation. Toxic
level exposure may cause skin lesions resulting in early necrosis and scarring.
Inhalation effects: Corrosive and irritating to the upper respiratory system and all mucous type
tissue. Depending on the concentration inhaled, it may cause burning sensations; coughing,
wheezing, shortness of breathing, headache, nausea, with eventual collapse, inhalation of
excessive amounts affects the upper airway (larynx and bronchi) by causing caustic like burning.
Resulting in edema and chemical penumonitis. If it enters the deep lung, pulmonary edema will
result. Pulmonary edema and chemical pneumonitis are potentially fatal conditions.
Inhalation:
Prompt medical attention is mandatory in all cases of over exposure. Rescues personnel should
be equipped with self contained breathing apparatus. Conscious persons should be assisted to an
uncontaminated area and inhale fresh air. Quick removal from the contaminant area is most
important. Unconscious person should be moved to an uncontaminated area, given mouth to
mouth resuscitation and supplemental oxygen. Keep victim warm and quiet. Assure that mucus
or vomited material does not obstruct the airways by positional drainage.
HAZARDS IDENTIFICATION :
Appearance : Clear, colorless.
Flash point : 11°C.
Toxicity: Cannot be made non poisonous Causes Eye and Skin irritation may be absorbed
through intact skin. This substance has caused adverse reproductive and fatal effects in animal.
Flammable liquid and vapor harmful if inhaled may be fatal and Caused blindness if swallowed.
May cause central nervous system depression may cause digestive tract irritation with Nausea,
Vomiting and Diarrhea. Causes respiratory tract irritation, May cause Liver, Kidney and Heart
damage.
Target organs: Kidneys, Heart, Central Nervous System, Liver, Eyes.
Skin: Causes moderate skin irritation May be absorbed through the skin in harmful amount.
Prolonged and repeated contact may cause defeating of the skin and dermatitis.
Ingestion: May be fatal or cause blindness if swallowed may cause gastrointestinal irritation
with nausea, vomiting and diarrhea may cause systematic toxicity with acidosis may cause
central nervous system depression, characterized by excitement, followed by headache,
dizziness, drowsiness and nausea. Advanced stages may cause collapse, unconsciousness and
coma possible to Death due to respiratory failure may cause cardiopulmonary system effects.
Inhalation: Harmful to inhale may cause adverse central nervous system effect including
headache, convulsions and possible to Death may cause visual impairment and possible
permanent blindness causes irritation of the mucous membrane.
Chronic: Prolonged or repeated skin contact may causes dermatitis. Chronic inhalation and
ingestion may cause effects similar to those of acute inhalation and ingestion. Chronic exposure
may cause reproductive disorders and teratogenic effect. Laboratory experiments have resulted in
mutagenic effects. Prolonged exposure may cause liver, kidney and heart damage.
Sudarshan chemical India LTD. has well equipped EHS (environmental health and
safety) section. It is up-to-date according to the protocols of MPCB (Maharashtra Pollution
Control Board). All safety protocols are strictly followed in the plant. Plant is also equipped with
the fire-fighting system.
All the products must be handled wearing gloves for lens always use.
Keep accepted products in role the standard quantity decide and displayed.
Do not wear wrist watch, pen in pockets: do not wear cloths each having metal buttons
.Things may create scratches on the product.
Always use wrist and belt cover.
Product must be packed as per ISOs quantity.
Care to be taken to avoid the open product in the bin which may collect the dust.
Care to be taken at the time of packaging that hot product should not packed. It will pack
after cooling.
Do not touch moving parts of machine.
Put machine guards at proper place.
Walk through gangway only.
Thus, the company is provided with a great safety system which makes all its
employees free from danger. Apart from this, the labors and contract workers also taken
well care of. The company has always kept virtues of safety as its highest priority. The
plant runs on a principal of safety first, duty next.
5.4.3 Goggles:
These are tight fitting eye protection that completely cover the eyes, eye sockets and the
facial area immediately surrounding the eyes and provide protection from impact, dust and
splashes. Some goggles will fit over corrective lenses.
Constructed of vulcanized fiber or fiberglass and fitted with a filtered lens, welding
shields protect eyes from burns caused by infrared or intense radiant light; they also protect both
the eyes and face from flying sparks, metal spatter and slag chips produced during welding,
brazing, soldering.
Protective hats are mainly required for the protection of the head during working in the
plants as any accident may occur during the various operations.In Clariant it’s compulsory for
every worker to use all the ppe.Some other ppe’s are: hand gloves, CABA (compressed air
breathing apparatus), protective suits, etc.
CONCLUSION
It was a pleasure to perform the training of two weeks in Sudarshan Chemicals (India) Ltd.,
which is a reputed company in local area because of their work. It gives me immense pleasure
and satisfaction as I finally submit this report about the training which I underwent here for one
one month . This month of industrial training was informative period this training helped to be
more systematic and disciplined in my work During the training, I learnt to interact to different
types of people the training has not only tough me how to work with sense of responsibility and
self-confidence but also has shown me the differences between the world of theory and industrial
experiences From this training I obtained both technical and practical knowledge.
This training has certainly helped me in bridging the gap between theory and practical. It
has empowered me to see how the knowledge gained through textbook is implemented in
practice.
This training has me importance of work, culture and Teamwork I take with me successful
knowledge that I gained in period.