K D Ambani Vidyamandir, Reliance Greens

Session 2019-2020
Chemistry – Worksheet
Topic: Solution
Name: _______________________ Date: ____________
Class: _____ Sec: ________ Roll No.: __________

Q.1 (a) Calculate the mole fraction of benzene in solution containing 30% by mass in carbon
tetrachloride.
(b) Why does chemist prefer to refer concentration of solution in terms of molality?

Q.2 (a) Two liquids say X and Y boil at 380 K and 400 K respectively. Which of them is more volatile?
Why?
(b) Why it is advised to add ethylene glycol to water in a car radiator while driving in a hill station?

Q.3 (a) The molar mass of bio molecules is determined by osmotic pressure and not by other
colligative properties. Why?
(b) What is the expected Van’t Hoff’s factor ‘i’ value for K3[Fe(CN)6] ?

Q.4 (a) Define (i) Azeotropes mixture (ii) Raoult Law (iii) Henry’s law

(b) Calculate the mass of ascorbic acid (Vitamin C, C6H8O6) to be dissolved in 75 g of acetic acid to
lower its melting point by 1.5°C. Kf = 3.9 K kg mol−1
Q.5 What is the molality of a solution containing 200 mg of urea (molar mass 60 g mol–1) dissolved
in 40 g of water ?

Q6. How many mL of 0.1 M HCl are required to react completely with 1 g mixture of Na2CO3 and
NaHCO3 containing equimolar amounts of both?
Q.7 Determine the amount of CaCl2 (i = 2.47) dissolved in 2.5 litre of water such that its osmotic
pressure is 0.75 atm at 27°C.
Q.8 Concentrated nitric acid used in laboratory work is 68% nitric acid by mass in aqueous solution.
What should be the molarity of such a sample of the acid if the density of the solution is 1.504
g mL–1?
Q.9 What is meant by positive and negative deviations from Raoult's law and how is the sign of
ΔmixH related to positive and negative deviations from Raoult's law?

Q.10 Suggest the most important type of intermolecular attractive interaction in the following pairs.
(i) I2 and CCl4
(iii) NaClO4 and water
(iv) methanol and acetone

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