Ecuacion de Van Der Waals

𝑛𝑅𝑇=(�+𝑛²𝑎/�²)(�−𝑛𝑏)

Procedemos a resolver el problema por los metodos de Newton-Raphson y Punto Fijo

Datos
a 1.463 bar*m⁶/(Kg*mol)²
b 0.0394 m³/Kg
P 70 Bars
R 0.08314 bar*m³/(Kg*mol*°K)
T°(K) 215 °K
Masa 1 Kg
PMCO₂ 28 Kg
n 0.0357142857 mol

Metodo de NEWTON-RAPHSON

Funcion

�(𝑉)=(�+𝑛²𝑎/�²)(�−𝑛𝑏)−𝑛𝑅𝑇 �^′ (𝑉)=P+

Hallamos un Punto Inicial

�𝑉=𝑅𝑇𝑛

�=𝑅𝑇𝑛/�=(0.08314∗215∗(1/28))/
70=0.009𝑚³

Factor Iterativo

𝑚=𝑉−(�(𝑉))/(�
′(𝑉))
Tolerancia

V m f(V) f'(V) Error

0.009 0.0081188 0.068027 77.195130
0.008119 0.0078503 0.021427 79.804583 0.034201
0.007850 0.0077548 0.007722 80.846263 0.012317
 0.007755 0.0077190 0.002908 81.252310 0.004636
0.007719 0.0077053 0.001112 81.409656 0.001773
0.007705 0.0077001 0.000428 81.470514 0.000683
0.007700 0.0076980 0.000165 81.494036 0.000263
0.007698 0.0076972 0.000064 81.503125 0.000102
0.007697 0.0076969 0.000025 81.506637 0.000039
0.007697 0.0076968 0.000010 81.507994 0.000015
0.007697 0.0076968 0.000004 81.508518 0.000006
0.007697 0.0076968 0.000001 81.508721 0.000002

Rpta: 0.0076968

Metodo de Punto Fijo

Despejamos V de la Ecuacion Donde:

nRT=(P+𝑛²𝑎/�²)(v-nb) g(V)=(𝑛𝑅𝑇/("P+"
𝑛²𝑎/�²))+nb

V=(𝑛𝑅𝑇/("P+" f(V)=V
𝑛²𝑎/�²))+nb

Tomamos como punto inicial a 0.008, esto de la grafica

Iteracion V g(V) Error Control

1 0.008 0.0078454
2 0.007845 0.0077709 0.009587 Continua
3 0.007771 0.0077340 0.004763 Continua
4 0.007734 0.0077156 0.002391 Continua
5 0.007716 0.0077063 0.001206 Continua
6 0.007706 0.0077016 0.000610 Continua
7 0.007702 0.0076992 0.000309 Continua
8 0.007699 0.0076980 0.000157 Continua
9 0.007698 0.0076974 0.000079 Continua
10 0.007697 0.0076971 0.000040 Continua
11 0.007697 0.0076969 0.000020 Continua
12 0.007697 0.0076968 0.000010 Continua
13 0.007697 0.0076968 0.000005 Fin
14 0.007697 0.0076968 0.000003 Fin
Rpta: 0.0076968
Derivada de la Funcion

�^′ (𝑉)=P+n²∗𝑎∗𝑙𝑛�+(2∗𝑛^3∗𝑎∗𝑏)/�³

V f(V) NEWTON RA
0.001 -1.4266541
0.002 -0.320318 0.2
0.003 -0.1966314
0.004 -0.1544929 0.15
0.005 -0.1187153
0.006 -0.0788242 0.1
0.007 -0.0339031
0.008 0.01533392 0.05
0.009 0.0680272
0.00001 0.010 0.12345242 0
0.002 0.004 0.006 0.0
-0.05
Iteracion Control
1 -0.1
2 Continua
3 Continua -0.15

-0.2
 -0.1

-0.15
4 Continua
5 Continua -0.2
6 Continua
7 Continua
8 Continua
9 Continua
10 Continua
11 Fin
12 Fin

0.012
V f(V) g(V)
0.000 0.000 0.001407
0.010
0.001 0.001 0.001737
/("P+"
0.002 0.002 0.002597
)+nb 0.003 0.003 0.003709 0.008
0.004 0.004 0.004828
0.005 0.005 0.005821
0.006 0.006 0.006647 0.006
0.007 0.007 0.007314
0.008 0.008 0.007845
0.004
0.009 0.009 0.008269
0.010 0.010 0.008608
0.002

0.000
0.000 0.002 0.004
 NEWTON RAPHSON

f(V)

0.004 0.006 0.008 0.010 0.012

 Punto Fijo

f(V)
g(V)

000 0.002 0.004 0.006 0.008 0.010 0.012