25 liters of gas A is pumped into a container at 25oC

and 760 torr with 20 liters of gas B at 25oC and 700 torr.
Calculate the total pressure when both gases are
pumped into a tank with 10 liters at 25oC.
25 liters of gas A is pumped into a container at 25oC
and 760 torr with 20 liters of gas B at 25oC and 700 torr.
Calculate the total pressure when both gases are
pumped into a tank with 10 liters at 25oC.
PV PV
nA = , n B=
RT RT

760 torr

n =
( 760 torr⋅atm −1)25 L
=1 .022
A −1 −1
( 0 . 08206 L⋅atm⋅K ⋅mol ) ( 25+273 ) K
700 torr

n =
( 760 torr⋅atm )
−1
20 L
=0 . 753
B −1 −1
( 0 . 08206 L⋅atm⋅K ⋅mol ) ( 25 +273 ) K
n total=1. 022+0 .753=1 .775

1 . 755 mol ( 0 .08206 L⋅atm⋅K −1⋅mol−1 ) ( 25+273 ) K

Ptotal= =4 .34 atm
10
KClO3 is decomposed by the following reaction:
2KClO3(s) ---> 2KCl(s) + 3O2(g)
The O2 produced was collected by the displacement of water at
22oC at a total pressure of 760 torr. The volume of gas collected
was 1.20 liters, and the vapor pressure of water at 22 oC is 21 torr.
Calculate the partial pressure of O2 in the gas collected and the
mass of KClO3 in the sample that was decomposed.
KClO3 is decomposed by the following reaction:
2KClO3(s) ---> 2KCl(s) + 3O2(g)
The O2 produced was collected by the displacement of water at
22oC at a total pressure of 760 torr. The volume of gas collected
was 1.20 liters, and the vapor pressure of water at 22 oC is 21 torr.
Calculate the partial pressure of O2 in the gas collected and the
mass of KClO3 in the sample that was decomposed.

Ptotal =PO +P H O =P O +21 torr=760 torr

2 2 2

739
PO =739 torr or atm
2 760
( 0 .972 atm ) ( 1. 2 L )
nO = −1 −1
=0 . 0482
2
( 0 . 08206 L⋅atm⋅K mol ) ( 22+273 ) K
2 mol KClO 3 122 .6 g KClO 3
g KClO 3 =0 . 0482 mol O2
( 3 mol O2 )( mol KClO 3 )
g KClO 3 =3 . 94 g
An organic compound had the following analysis (%by weight): C,
55.8%; H, 7.03%; O, 37.2%. A 1.500 g sample was vaporized and found
to occupy 530.0 mL at 100.0 C and 766 torr.

a.What is the empirical formula of the compound?

b.What is the molar mass of the compound?
c.What is the molecular formula of the compound?

a.)
gC=0 .558 (1 . 5 )=0 . 837 ⇒ 0 . 0698 moles/0 . 03488 moles= 2
gH=0 . 0703 (1 . 5 )=0 .1055 ⇒0 . 1046 moles /0 . 03488 moles= 3
gO=0 .372 ( 1 .5 )=0 . 558 ⇒ 0 . 03488 moles /0 . 03488 moles= 1
EF=C 2 H 3 O
b.)
PV ( 0.766/760 ) atm ( 0.530 L ) −2
n= = =1.75 x 10 moles
RT 0.08206 L⋅atm⋅K ⋅mol ( 373.15 K )
−1 −1

MM=1.5 g1.75 x10−2 moles=86 g/mole

a.)
gC=0 .558 (1 . 5 )=0 . 837 ⇒ 0 . 0698 moles /0 . 03488 moles= 2
gH=0 . 0703 (1 . 5 )=0 .1055 ⇒0 . 1046 moles /0 . 03488 moles= 3
gO=0 .372 ( 1 .5 )=0 . 558 ⇒ 0 . 03488 moles/0 . 03488 moles= 1
EF=C 2 H 3 O

b.)
PV ( 0.766/760 ) atm ( 0.530 L ) −2
n= = =1.75 x 10 moles
RT 0.08206 L⋅atm⋅K ⋅mol ( 373.15 K )
−1 −1

MM=1.5 g1.75 x10−2 moles=86 g/mole

c .)
EW=12 ( 2 ) +1 . 008 ( 3 ) +16=43 g/mole
MM 86
= =2
EW 43
MF :2 ( C 2 H 3 O ) =C 4 H 6 O 2
A 3.05 g sample of NH4NO3 (s) is completely decomposed at 250.0 C in an
evacuated 2.18 L flask according to the reaction: 2NH 4NO3(s)  2N2(g) +
4H2O(g) + O2(g)

a.Calculate the number of moles of each gas formed

b.Calculate the total pressure in the flask
c.Calculate the partial pressure of each gas
A 3.05 g sample of NH4NO3 (s) is completely decomposed at 250.0 C in an
evacuated 2.18 L flask according to the reaction: 2NH 4NO3(s)  2N2(g) +
4H2O(g) + O2(g)

a.Calculate the number of moles of each gas formed

b.Calculate the total pressure in the flask
c.Calculate the partial pressure of each gas
a.)
n N =( 3 . 05 /78 ) ( 2/2 )=0 .039
2

n H O =( 3 . 05/78 )( 4 /2 )=0 . 078

2

nO =( 3 . 05 /78 ) ( 1/2 )=0 . 02

2

b .)
n total =n N +n H O +nO =0 . 137
2 2 2

P total =n total RT /V=0 . 137 ( 0 . 08206 )( 523 . 15 ) /2 .18=2. 7 atm

c .)
χ N =0. 039 /0 .137=0 .28 χ H O=0 . 078/0 . 137=0 . 57 χ O =0 .02 /0 .137=0 .15
2 2 2

P N =0 . 28 ( 2 .7 )=0 .76 atm PH O=0 .57 ( 2 . 7 ) =1. 54 atm P O =0 . 15 ( 2. 7 )=0 . 405 atm
2 2 2