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A straight line joining two unmoved points defines a unique axis of rotation,
called a polar direction, unless the symmetry operations do not allow any rotation
at all, such as mirror symmetry, in which case the polar direction must be parallel
to any mirror planes.[clarification needed]
A point group with more than one axis of rotation or with a mirror plane
perpendicular to an axis of rotation cannot be polar.
When materials having a polar point group crystal structure are heated or cooled,
they may temporarily generate a voltage called pyroelectricity.
Molecular crystals that occupy[clarification needed] polar space groups may exhibit
triboluminescence.[3] A common example of this is sucrose, demonstrated by smashing
a wintergreen lifesaver in a darkened room.
References
Jeremy Karl Cockcroft, Huub Driessen, David Moss, Ian Tickle (2006). "Polar Point
Groups". University of London. Retrieved 2013-12-09.
Kasap, Safa O. (2006). Principles of electronic materials and devices. Boston:
McGraw-Hill. ISBN 9780073104645.
Zink, Jeffery (1981). "Triboluminescence-Structure Relations in Polymorphs of
Hexaphenylcarbodiphosphorane and Anthranilic Acid, Molecular Crystals, and Salts".
J. Am. Chem. Soc. 103: 1074�1079. doi:10.1021/ja00395a014.
Categories: SymmetryCrystallographyGroup theory
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