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Accepted Manuscript

Utilization of banana peels for removal of strontium (II) from water

Komal V. Mahindrakar, Virendra K. Rathod

PII: S2352-1864(18)30151-2
DOI: https://doi.org/10.1016/j.eti.2018.06.015
Reference: ETI 254

To appear in: Environmental Technology & Innovation

Received date : 28 March 2018


Revised date : 13 June 2018
Accepted date : 30 June 2018

Please cite this article as: Mahindrakar K.V., Rathod V.K., Utilization of banana peels for removal
of strontium (II) from water. Environmental Technology & Innovation (2018),
https://doi.org/10.1016/j.eti.2018.06.015

This is a PDF file of an unedited manuscript that has been accepted for publication. As a service to
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Please note that during the production process errors may be discovered which could affect the
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Utilization of Banana Peels for Removal of Strontium (II) from Water.

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ABSTRACT

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1. INTRODUCTION

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2. MATERIALS AND METHODS

2.1. Material

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2.2. Adsorption experimental procedures

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2.4. Adsorption isotherms and Thermodynamics

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2.5. Desorption and Biosorbent Reusability study

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2.6. Analytical methods



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3. RESULTS AND DISCUSSION

3.1. Effect of contact time and Kinetic studies

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0 2$ ,#.0-4$#2'$0 .(#,$11-%0$ "2(-,(&


'+ #.-30$2 *
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'$,$2 *
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'$ 4 *3$1 -% /$ ,# ) 5$0$ #$2$0+(,$# %0-+ 2'$ 1*-.$ ,# (,2$0"$.2 -00$* 2(-,

"-$%%("($,21 -!2 (,$# 5$0$   2' 2 (1 ,$ 0*7 $/3 * 2-  2 5 1 ,-2("$# 2' 2 2'$

!(-1-0.2(-," . "(27(,"0$ 1$#%0-+  2-+&&5'$,-(,"0$ 1$#%0-+ 2- 

+&

3.2. Effect of biodsorbent size

,$ -% 2'$ (+.-02 ,2 4 0( !*$1 (,%*3$,"(,& !(-1-0.2(-, (1 2'$ 1(8$ -% !(-1-0!$,2

5'("'#$"(#$1 4 (* !*$2-2 *130% "$ 0$  ,#2'31" . "(27-%!(-1-0!$,2-11 (,$2 *


1'0 %$2 *
  *+ $2 *
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       )    8( .$*2!  /$! 1!-#! +-/%'! .%5! *"



        8( -!.+!/%1!'4 2$!) (!.0-!  4 +-/%'! .%5!

)'45!-$!.! %""!-!)/.%5!.*".(+'!.2!-!.!'!/! "*-!3+!-%(!)/.4&!!+%)#

-!(%)%)# +-(!/!-. *)./)/ .0$ .   # *" %*.*-!)/  (# *)!)/-/%*) *"

.%(0'/!  .*'0/%*) 7
6 /!(+!-/0-! ) 
 -+( "*-  (%)0/!. $! 1-%/%*) *"

%*.*-+/%*) +%/4 "*- -  4 0.%)# %""!-!)/ %* .*-!)/ .%5!. %. #-+$%''4

-!+-!.!)/! %)%# 2$%$ !.-%!./$//$!.(+'!2%/$ 8(.%5! +-/%'!..$*2! 

'!.. %*.*-+/%*) +%/4 $%. %. !0.! /$! .('' .%5!  +-/%'!. /!)  /* !*(!

##-!#/!. 2$%$ $1! '!.. .0-"! -! "*- %*.*-+/%*) /$) %) %1% 0' +-/%'!. $!

%*.*-+/%*) +%/4 "*-  8( +-/%'! .%5!   %. !//!- "*- %*.*-+/%*) #%1%)#

(3%(0(!""%%!)4(+'!.$1%)#*-.!-.%5!/$) 8('! /*'!..!-%*.*-+/%*)

+%/4 .%)! /$!4 +-*1% ! '!.. .0-"! -! "*- .*-+/%*) !)!  2%/$  8(

+-/%'!.%5!2..!'!/! "*-"0-/$!-./0 4

3.3. Effect of agitation speed

/%.-!,0%-! /*0) !-./) /$!.+!! 2$!-!/$!!3/!-)'(../-)."!--!.%./)!

%.)!#'%#%'!. .*-+/%*)%. !+!) !)/*)(../-)."!-""%4*"%*.*-+/%*)+-*!..

%.$!&! /*(%)/%)!//!-*)/-*'*1!-/$!./%--%)#+-*!..41-4%)##%//%*).+!! 

 
 

-+() &!!+%)#-!(%)%)#+-(!/!-.*)./)/.0$. 

#*"%*.*-!)/ (#*)!)/-/%*)*"(* !'2./!2/!- 7


6/!(+!-/0-!) 

 8( +-/%'! .%5! -)#! "*-  (%) )-!.! %) /$! -!(*1' *" -  4  %.

!1% !)/ /%''


 -+( / 2. *0)/!  /$/ %)-!.! %) .$&%)# .+!!  %)-!.!. /$!

-!(*1'*"-4%)2/!-0+/*
-+(2%/$"0-/$!-%)-!.!%)#%//%*).+!! 




7'3: -+55-' 3+4' +/ $+040315+0/ 8#4 0$4'37'& +) '44 $+040315+0/ 8#4 0$4'37'& #5

-08'3#)+5#5+0/41''&$'%#64'0(#%%6.6-#5+0/0(1#35+%-'40(8*+%**+/&'341301'3

'910463'0($+040315+0/463(#%'/5*'05*'3*#/&$+040315+0/3'.#+/4#-.045%0/45#/5

$':0/&
31.+)*.#4453#/4('33#5'8#40$4'37'&8+5*#)+5#5+0/41''&0(
31.

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0(!30/(30.8#5'3'.0/'5#-



3.4. Effect of pH

7#+-#$+-+5: 0( (6/%5+0/#- )30614 #/& +0/+;#5+0/ 45#5' 0( .'5#-4 +4 3'26+3'& (03

$+040315+0/#/&+5.#+/-:&'1'/&40/10(5*'40-65+0/'%#64'1#(('%54&+440%+#5+0/

0( 5*' )30614 0/ 5*' 463(#%' 0( 5*'  #/& (03.4 0( 4530/5+6. &+41'34'& +/ 8#5'3

"*'3'(03'&+(('3'/513#/)' 50 8#4456&+'&#5#/+/+5+#-4530/5+6.%0/%'/53#5+0/0(


 .) 
 ) 0( $+0403$'/5
= < 5'.1'3#563' #/&   >. 1#35+%-' 4+;' 3#/)'4 $:

64+/)
31.41''&(03 .+/+)"*'$+040315+0/%#1#%+5:8#4+/%3'#4'&#45*'

1 +/%3'#4'& (30. 1  50 1   #5 1  8*+%* 46))'454 5*' +0/ '9%*#/)'

130%'448#4+/70-7'&60#/&#3$'3 
5-0815*'3'+4%0.1'5+5+0/$'58''/!3

#/&+0/4#-0/)8+5*5*''-'%53045#5+%3'16-4+0/#.0/)5*'!3#/&5*'104+5+7'-:

%*#3)'&#%5+7'$+040315+0/4+5'40/5*'463(#%'0(8*+%*+/*+$+545*'615#,'0(.'5#-

+0/4  6#/ '5 #-



 8*+%* 3'46-5'& +/ 46113'44+0/ 0( !3  3'.07#- "*' 1044+$-'

3'#%5+0/8*+%*%06-&0%%633'&&63+/)$+040315+0/+/#%+&+%8#5'3+4)+7'/4%*'.#5+%#--:

$'-08

-  -    


 

4 5*' 1 8#4 +/%3'#4'& (635*'3 (30.  50  /0 3'.#3,#$-' &'%3'#4' +/ $+040315+0/



)'5')/9> <'8 4(8+7;+* 47+4;+7 '9 9./8 5 7'3-+ 897439/:2 2'/31> 57+8+39

57+*42/3'391> /3 9.+ ,472 4, $7  '3- +9 '1
 '*'1' +9 '1
 %.+

(/484759/43 7+')9/43 4, 897439/:2 /438 4394 9.+ !! )'3 (+ )438/*+7+* '8 ' 7+;+78/(1+

7+')9/43</9.'3+6:/1/(7/:2(+/3-2'*+(+9<++39.+9<45.'8+8'88).+2'9/)'11>8.4<3

(+14<

!!$7!!$7 

$/-3/,/)'39 /25')9 <'8 349/)+* 43 897439/:2 7+24;'1   '9 '10'1/3+ 5

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'8/))43*/9/43)4:1*,')/1/9'9+9.+*/8841:9/434,(/4847(+39A8

47-'3/) 2'99+7 9./8 2'> (+ 9.+ 7+'843 (+./3* 9.+ 7+*:)9/43 /3 (/484759/43 &:+ +9 '1


+3)+57'3-+4, <'8)438/*+7+*'8459/2:2

3.5. Isotherm and Thermodynamic studies

*84759/43/849.+7224*+188:).'8'3-2:/7'3*7+:3*1/).<+7++2514>+*94

*+8)7/(+ 9.+ 2+).'3/82 4, (/484759/43 4, $7 43 9.+ !! 89/2'9+* /849.+72

5'7'2+9+78 <+7+ *+5/)9+* /3 %'(1+  %.+ (/484759/43 4, $7  4394 !! '9 */,,+7+39

9+25+7'9:7+8<'8<+11)477+1'9+*#  ;'1:+8 ? (>7+:3*1/)./849.+7224*+1/3

)425'7/843 </9. '3-2:/7 /849.+728 <./). -';+ 14<+7 )477+1'9/43 )4+,,/)/+398 %.+

;'1:+8 4,  '7+ 8++2 94 (+ /3)7+'8/3- </9. '3 /3)7+'8+ /3 9+25+7'9:7+ 8:--+89/3- 9.'9

(/484759/43 4, $7  43 !! /8 +3*49.+72/) /3 3'9:7+ /-  :2(+7 4, 57+;/4:8

89:*/+8'-7++8</9.9./8+3*49.+72/)3'9:7+4,(/484759/43:7(4-''3*%+1 '3-

+9'1
+243+9'1 &++9'1 /484759/43/8,';4:7'(1+8/3)+;'1:+8

4, # 4(9'/3+* (> '3-2:/7 /849.+72 <+7+ ,'11 /3 (+9<++3  '3*
 @3A +=57+88+8 9.+




".-$%-%0')%1"%25%%-!$1.0"!2%!-$").1.0"%-25()+%-)1'0%!2%02(!- 5)2()-  

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(%2%0.'%-%.31)--!230%+%!$)-'2./(71).1.0/2).-&!4.30!"+7!-!$!0%%2!+
  (%

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2(%0,.$7-!,)#/!0!,%2%01 !-$ 5%0%#.,/32%$&0.,2(%1+./%!-$)-2%0#%/2

.&2(%/+.2 (%4!+3%1.&%-2(!+/7#(!-'%  ,.+ %-20./7#(!-'%  

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; )-$)#!2%1 2(% )-#0%!1%$ 0!-$.,-%11 !2 2(% 1.+)$ !-$ 1.+32).- )-2%0&!#% $30)-'

").1.0/2).- ()1,!7"%$3%2.$%(7$0!2).-12%/2(!2)-#0%!1%12(%,.")+)27.&120.-2)3,

).-1!-$1300.3-$)-'5!2%0,.+%#3+%1)-2(%1.+32).- (%%6#(!-'%.&,.0%,.")+%).-1

/0%1%-2 .- 2(%  !-$ 120.-2)3, ).-1 )1 !-.2(%0 0%!1.- 5()#( 5.3+$ #!31% /.1)2)4%

%-20./7 #(!-'% $30)-' 2(% ").1.0/2).- /0.#%11 %#0%!1% )- 2(% 4!+3%1 .& )""1 &0%%

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  ')4%1 &%!1)")+)27 !-$ 1/.-2!-%.31 -!230% .& /0.#%11 !-)1( %2 !+
 

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  ()11%%,12./.)-2

.322(!2/(71).1.0/2).-)12(%/0%$.,)-!-2,%#(!-)1,)-2(%").1.0/2).-.&0.-2.

2(%  1)-#% 0!-'% &.0 /(71)1.0/2).- )-2%04!+ )1 &0., 


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.-89+%8%2!+
 



3.6. Desorption study 

'30214+0/ +3 # 120%'33 0( $+0302$'/4 2')'/'2#4+0/ %0/3+&'2'& 40 $' 0( %25%+#-

+.1024#/%'+/'%0/0.+%10+/40(6+'7'30214+0/345&97#3#%%0.1-+3*'&$9'.1-09+/)

30-6'/43 35%* #3 +42+% #%+& 5-1*52+% #%+& 9&20%*-02+% #%+& %'4+% #%+& 0&+5.

*9&208+&'#/&7#4'27*+%*7#3)+6'/ 



 
 3420/4+5.

&'30214+0/ 2'31'%4+6'-9 #4    200. 4'.1'2#452' +) "3' 0( /+42+% #%+& (02

&'30214+0/*#3$''/)+6'/4*')2'#4'2&'30214+0/#.0/)4*'2'.#+/+/)30-6'/43/)-''4

#-
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3420/4+5./+42#4'&52+/)&'30214+0/#/&4*'12'&+%4'&2'#%4+0/%#/$'

 2   2   

'30214+0/'((+%+'/%97#3(05/&40$' #/&

7*'/%*'%,'&$9&0+/)

&'30214+0/ '81'2+.'/43 $9 53+/) /+42+% #%+& #4 +/%2'#3'& 4'.1'2#452'3 35%* #3
 #/&

2'31'%4+6'-9'/%'35%%''&+/)'81'2+.'/437'2'&0/'$953+/)/+42+%#%+&#4 

$9%0/3+&'2+/)&'30214+0/'((+%+'/%9#/&'%0/0.90(4*'120%'33

3.7. Regeneration, reusability and SEM analysis of BPP

 7#3 53'& (02 %*#2#%4'2+:+/) 352(#%' .021*0-0)9#/& (5/&#.'/4#- 1*93+%#-

1201'24+'3 0( $+0302$'/4 7+4* *+)* 31#4+#- 2'30-54+0/ %#//+/) '-'%420/ .+%20)2#1*3 0(

+)#2'6'#-'&4*#44*'102'3#2'*+)*-9*'4'20)'/'053+22')5-#23*#1'#/&

352(#%''8*+$+43#.+%20205)*4'8452'!*+3%#/120.04'4*'#&*'2'/%'0(3420/4+5.+0/3

+/#3+.+-#27#9404*#4(05/&+//#452#-*#$+4#43'.0/'4#- #-.#'4#-



(4'2$+030214+0/#3+)/+(+%#/4%*#/)'+/4*'3425%452'0(4*'+30$3'26'&+)$




"*'  #11'#34 50 *#7' 40.'8*#5 (-#,: 306)* 463(#%' 8+5* %3#5'3 -+,' 103'4 $'%#64'

5*': #3' 1#35+#--: %07'3'& $: 5*' 4530/5+6. +0/4 %*#, '5 #- # //#&63#+ '5 #-

 (5'3 3'%07'3: 0( 5*' !3  (30.  $: &'40315+0/ +5 %#/ $' 3'64'& (03

$+040315+0/*'/%'+5+4/'%'44#3:50456&:5*'3'64#$+-+5:%#1#%+5:0($+0403$'/5503'&6%'

5*' 07'3#-- %045 '64#$+-+5: 0( 3')'/'3#5'&  $+0403$'/5 8#4 %*'%,'& 8*+%* 4*084

-+55-' &'%3'#4' 
  +/ $+040315+0/ %#1#%+5: #(5'3 '7'3: %:%-' 0( $+040315+0/ #/&

&'40315+0/6150%:%-'4(5'3(+(5*%:%-'5*'4#.'#%*+'7'&6150 3'.07#-0(

4530/5+6.(30. .)%0/%'/53#5'&40-65+0/-'%530/+%41'%53#0(#(5'3(+345%:%-'

0( &'40315+0/ 4*08/ +/ +) % &'1+%54 5*#5  %0/4+&'3#$-: #(('%5'& $: #-5'3+/) 5*'

463(#%'0($+0403$'/58*'/53'#5'&8+5*/+53+%#%+&.+)*5$'%*#33'&#(5'35*%:%-'

0( &'40315+0/ +) & ')'/'3#5+0/ #/& 3'64#$+-+5: 456&+'4 4*08'& 5*#5 5*' 

1044'44'&105'/5+#-3'%:%-'1'3(03.#/%'

3.8. FTIR spectrometer analysis

"  !1'%530.'53+% %*#3#%5'3+;#5+0/ 0( 6/#&403$'& #/& 4530/5+6. -0#&'& 

8#4%#33+'&06550+/7'45+)#5'.'%*#/+4.0($+040315+0/#/&13'4'/5'&+/+)
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  %.
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%,0',0* 1) "4  ,105 ,*


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+(0(6$.

$0,5+(6$.

$

4. Conclusion

#+( /$:,/7/ %,151426,8( 4(/18$. 1) "4  %;   9$5 $&+,(8(' 9,6+


/**$6126,/,<('&10',6,10557&+$5  =/5,<(4$0*(1) 
42/2$0'

6(/2(4$674(   $0'
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-,0(6,&5 ,0',&$6( 6+$6 6+( (:2(4,/(06$. '$6$ 9(4( )1..19(' 6+( 25(7'15(&10' 14'(4

/1'(.4(70'.,&+,516+(4//1'(.9$55+19061%($*11'),6)14$..6(/2(4$674(56(56('

#+(4/1';0$/,& 2$4$/(6(45 57**(56 6+$6 %,151426,10 ,5 )($5,%.( 52106$0(175 $0'

(0'16+(4/,& ,0 0$674( 16+ &+(/,51426,10 $0' 2+;5,151426,10 /(&+$0,5/5 9(4(

,081.8(',06+(%,151426,101)"410616+(574)$&(1) #!$0'"$0$.;5,5

(56$%.,5+(5 6+( &10),4/$6,10 1) %,151426,10 (51426,10 &$2$&,6; 1)   9$5

$&&1/2.,5+('75,0* 
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%,151426,10$0''(51426,109,6++,*+%,151426,10&$2$&,6;"44(/18$.)41/9$6(4%;

75,0* ,5$0(&101/,&$.()),&,(06$0'(08,410/(06$.)4,(0'.;241&(55)1451426,10$.

4(/18$.1)564106,7/

Acknowledgement




$.+ ':9.478 -7'9+,:11> ')034<1+*-+ 9.+ %3/;+78/9> 7'398 422/88/43 %

3*/',47574;/*/3-,/3'3)/'1'88/89'3)+/39.+7+8+'7).<470

5. References

-+3)> ,47 $4=/) 8:(89'3)+8 '3* /8+'8+ "+-/897> $#"


  !:(1/) +'19.

#9'9+2+39 #97439/:2 #  


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'3*:2'3#+7;/)+8!:(1/)+'19.#+7;/)+

).'0',/*/ :'??'3/#'>'*/#'3*/
'4<)489(/4847(+39

B('3'3' 5++1C ,47 9.+ 7+24;'1 4, 5.+341/) )4254:3*8 ,742 41/;+ 2/11 <'89+<'9+7

/3+9/)'3*+6:/1/(7/:289:*/+8'?'7*'9+7  @


).'0'3*/ :'??'3/
("+24;'14,47-'3/)5411:9'398'3*3:97/+398

,74241/;+2/11<'89+<'9+7(>'8'3*,/19+73;/743'3'-+
 @


.2'* $ "','9:11'.  .'?'1/  #:1'/2'3  '8./2 " .2'* 
 

"+24;'14,!+89/)/*+8,742&'9+7'3*&'89+<'9+7(>/,,+7+39*847(+398"+;/+<

3;/743#)/+'19.

@
 

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  /1 !'12

/42'88@'8+**847(+398,479.+"+24;'14,&'9+7!411:9'398A"+;/+<3;/743

#)/+'19.
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$.+:8+4,*'9+5'12'8'549+39/'1'*847(+39,47<'89+<'9+797+'92+39

7+;/+<3;/743#)/!411:9"+8   @  

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  !7485+)98 4, ('3'3' <'89+ :9/1/?'9/43 /3 <'89+<'9+7

97+'92+397+;/+<3;/743'3'-+
  



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*=.;   

77*->;*2  >*70 " # ..     %<. 8/ ,.55>58<.+*<.- @*<=.< /8;

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%removal

  

 


 

 



    
time (min.)


Fig. 1







 




 

 
t/qt (min.g/mg)







 


    
time (min.)


Fig. 2










 




%removal













  
 
 
 

BPP size ( m)


Fig.. 3








% Removal






        
Agitation speed ( rpm)


Fig. 4










% Removal






   

pH



Fig. 5















lnq

 





     



lnce


Fig. 6







ln kL




     
1/T


Fig. 7





% Desorption











 
  


  
Solvents


Fig. 8


a b


c d




Fig.. 9







Fig..10
 



Table 1:!&*&)'+!&%"!%+!')$+)*)&$!)%+"!%+!$&#*

!%+!

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Table 2:%!&$! %& &% !$$&! ! &%&$ &&"$&'$%

"$&'$ 

  '$%!&$  $' %!&$

#(       

   
    
 
  

   
    
    

    

   
      

    
       

 
  
    
  

 



Table 3:'#%*$# &'#)'(%' %(%'&) %$%$)%

!#%" !#%" !#%"

 

           

        
          



Highlights

 Banana peels efficiently removes Sr (II) from waste water.

 BPP was characterized by SEM and FTIR spectroscopy.

 Biosorption process complied with Freundlich and pseudo second order kinetic model.

 Biosorption was endothermic and spontaneous according to thermodynamics.

 BPP’s regeneration and reusability was successfully checked upto 5 cycles.

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