Beruflich Dokumente
Kultur Dokumente
PII: S2352-1864(18)30151-2
DOI: https://doi.org/10.1016/j.eti.2018.06.015
Reference: ETI 254
Please cite this article as: Mahindrakar K.V., Rathod V.K., Utilization of banana peels for removal
of strontium (II) from water. Environmental Technology & Innovation (2018),
https://doi.org/10.1016/j.eti.2018.06.015
This is a PDF file of an unedited manuscript that has been accepted for publication. As a service to
our customers we are providing this early version of the manuscript. The manuscript will undergo
copyediting, typesetting, and review of the resulting proof before it is published in its final form.
Please note that during the production process errors may be discovered which could affect the
content, and all legal disclaimers that apply to the journal pertain.
Utilization of Banana Peels for Removal of Strontium (II) from Water.
+)(%&*!-'-&-"*!-/%+!
+--".,+*!&*$0/%+-&-"*!-/%+!
",-/)"*/+#%")& (*$&*""-&*$
)&(1'-/%+!& /)0)&"!0&*
%+*"
2
ABSTRACT
6 2 //1./1( 3$ 3. #$2"1(!$ 3'$ !(.2.1/3(.- /1."$22 ".,/ 1$# 3. -&,4(1 ,.#$+
- 341$ .% 3'$ /1."$22 $2.1/3(.- .% 231.-3(4, (.-2 %1., .!3 (-$# 6 2 !8
%(5$ "8"+$2 .% !(.2.1/3(.- -# #$2.1/3(.- (, &$2 6$1$ ".-%(1,$# 3'$
$7/+.1$2 3' 3 ,(-. '8#1.78+ " 1!.-8+ -# " 1!.78+ &1.4/2 ' # , ).1 1.+$ (-
.%231.-3(4,%1., 04$.422.+43(.-
Keywords:231.-3(4,(.2.1/3(.- - - /$$+(-$3("22.3'$1,2$2.1/3(.-
1. INTRODUCTION
!#6'4 +5 016 10.: # 5174%' 1( .+(' #0& '0'4): $76 #.51 # 70+8'45#. 51.8'06
1..76+101(9#6'4$:21+51017551.7$.'/'6#.5+5#/#66'41(76/156%10%'40616*'*'#.6*
1(.+8+0)$'+0)5*/#&'6#. 64106+7/+5#.-#.+0''#46*/'6#.#0&%*'/+%#..:
#&+1#%6+8' +51612'5 4 #0& 4 #4' /#,14 07%.'#4 (+55+10 241&7%65 24'5'06 +0 .+37+&
07%.'#4 +0&7564+#. 9#56' #0) '6 #. #&+1#%6+8' 564106+7/ +5 %#4%+01)'0+% #0&
'.'%6410+%52:416'%*0+%5/'6#..74)+%#.#0&9*'4'(14/#6+101(%'4#/+%5).#55241&7%65
2#+062+)/'065(.714'5%'06.+)*65'6%4'.'#5'5564106+7/4'#%*9#56'9#6'4*/#&2174
'6 #. $51426+10 1( 56#$.' +51612' 1( 564106+7/ %#75'5 156'121415+5
*:21/+0'4#.+;#6+10&'%4'#5'&5+;'1($10' #2#6+6'%4:56#.5*:21%#.%'/+#0*+$+6+101(
*75&'8'.12+0)#0'(('%6+8'#0&'%101/+%564106+7/%106#+0+0)9#56'9#6'464'#6/'06
*#54'%'06.:4'%'+8'&%105+&'4#$.'#66'06+10
*'4'#4'07/$'41(6'%*0+37'5#8#+.#$.'(149#56'9#6'464'#6/'06%*#-'6#.
19'8'4 )'0'4+% /'6*1&5 #4' 016 '%1(4+'0&.: #%%14&+0) 61 6*' 24+0%+2.'5 1(
)4''0 %*'/+564: #*/#0 '6 #. &51426+10 +5 10' 1( 6*' 5+/2.' #0& /156
'(('%6+8'/'6*1&59+&'.:75'&+09#56'9#6'464'#6/'06*/#&'6#. '/+4$#5
*#'/+ '6 #. 74$1)# #0& '. 0#0 #0& .6#5 7#0 '6 #.
"' '6 #. +151426+10 241%'55 *#5 *7)' 5%12' +0 9#56' 9#6'4 64'#6/'06
<471*</*+.2'*+9'1
'3/8.+9'1
(1'(('8!
4.'22'*+9
'1
'
( /47+2+*/'9/43 9+).3/6:+8 :8/3- ;'7/4:8 2/)74(+8 .';+ (++3
/484759/43(>:8/3-'-7/):19:7'1<'89+8:).'8'1243*-7++3.:11+--51'39.:112488
.2'*54:7+9'1
5+)'38.+118!.'<'(0+.+9'1
7/)+897'<(/4).'7'3-
+9'1
<+7++2514>+*947+24;+897439/:2,742<'9+7
'3'3' 51'398 '7+ ):19/;'9+* /3 247+ 9.'3 )4:397/+8 '3'3' 574*:)9/43 /3
%471* *:7/3-
<'8 ,4:3* 94 (+ '(4:9 2/11/43 2+97/) 9438 4, <./). 3*/'A8
)4397/(:9/43/8'74:3*
5'794,9.+<.41+,7+8.('3'3',7:/9/8/985++1.2'*
'3*'3/8.
.2'*'3*'3/8./39.+/77+;/+<'79/)1+7+5479+*9.+:8+4,('3'3'
5++18 /3 9.+ <'89+ <'9+7 97+'92+39 ,47 7+24;'1 4, ;'7/4:8 2+9'18 :( *
7$ / &3 + 4 : 3 *>+8 +9.>1+3+ (1:+ +9.>1
47'3-+7'3-+5+89/)/*+897'?/3+2+97>3++97/(:?/3
@*/).14745.+34=>
')+9/)')/*
@*/).14745.+34=>5745'34/)')/*'3*
@*/).14745.+34=>(:9>7/)')/*
/97/) ')/* +3?4/) ')/* '3* !'1/)>1/) ')/* /347-'3/) '3/438 '3*
7'*/43:)1/*+8".47/:2'3*#7'3/:2.2'*'3*'3/8.
'3'3'5++18)'3(+
+'8/1> '3* ).+'51> 4(9'/3+* ,742 2'70+9 51')+8 )./58 2'0/3- ,')947/+8 .49+18 .4:8+8
+9)8'3'3'5++18'7+)438/*+7+*'<'89+/98'551/)'9/43/39.+97+'92+394,.'?'7*4:8
<'89+ <'9+7 )'3 841;+ <'89+ */8548'1 574(1+2 8/3)+ /9 )'3 -+3+7'9+ -7++3.4:8+ -'8 /,
*/8548+*4,/3<+9)43*/9/438
+24;'14,897439/:2,742<'9+7(>:8/3-<'89+5.>94)4254:3*8.'8349(++3
-/;+3 2:). '99+39/43 ./8947/)'11> '3* 9.+7+ '7+ 34 7+54798 ';'/1'(1+ 43 :8+ 4, <'89+
%$0$0$ 2((.4 )13 3(/17$. 1) +$;$3'164 453105,6/ %: %,141325,10 5,.. 018 +( *1$.4 1)
23(4(05813-$3(51
56': 5+( ())(&5 1) 7$3,164 2$3$/(5(34 46&+ $4 5,/( $'413%(05 4,;( $*,5$5,10
42((' ,0,5,$. &10&(053$5,10 1) 453105,6/ ,0 4,/6.$5(' 8$45( 8$5(3 2 $0'
5(/2(3$563(
92.13('(41325,10()),&,(0&:$0'3(65,.,;$5,10&$2$&,5:1)$0'
+$3$&5(3,;($0$0$((.418'(3%:64,0* $0'
2.1. Material
+($0$0$2((.48(3(&1..(&5('$4$41.,'8$45()31/.1&$./$3-(51)$560*$,0
6/%$,0',$((.48(3(&.($0('&65,0514/$..2,(&(4<
&/$0'460'3,('5,..4
4+18('&1045$058(,*+5 +(4(/$5(3,$.48(3(&364+(',0$.$%/,9(351/$-($0'
4&3((0('8,5+4,(7(4+$7,0*4,;(3$0*(4
(&-/$0 16.5(3 1605(3 2$35,&.( 4,;( $0$.:;(3 .. &+(/,&$.4 64(' 8(3( 1) $0$.:5,&$.
*3$'(263&+$4(')31/,(',$5'6/%$,0',$!$45(8$5(38$423(2$3('%:64,0*
453105,6/0,53$5("31
#$0''(,10,;('8$5(3
)13/6.$5(' %: ',.65,0* 8,5+ '(,10,;(' 8$5(3 )31/ /* 451&- 41.65,10 1)
120-,2(3+ (, #(%%$0$,2 + "-,(" * %* 1)1 2
0.+ (, , -0!(2 * 1' )$0 %-0
2$+.$0 230$
- ,# .
!7 31(,& * ,#
5$0$ -.2(+(8$# 2- &$2 + 6(+3+ 0$"-4$07 +.*$1 -% ; 5$0$ 5(2'#0 5, %2$0
'$ +-3,2 -% 0 #1-0!$# .$0 &0 + -% ! , , .$$* .-5#$0 / 5 1 #$2$0+(,$# !7
'$0$ (1 2'$ (,(2( *120-,2(3+ (-, "-,"$,20 2(-,(, 1-*32(-, +& $ (1120-,2(3+
(-, "-,"$,20 2(-, (, 1-*32(-, %2$0 !(-1-0.2(-, +& (1 5$(&'2 -% ! , , .$$*
.-5#$0 & (1 2'$ 4-*3+$ -% +-#$* 5 12$ 5 2$0 31$# %-0 !(-1-0.2(-, /$ (1 2'$
1-*32(-, 22(+$2+&
'$ /2$4#. %(123 .1#$1 /2$4#. 2$".-# .1#$1 -# $!$1 9.11(2 *(-$3(" ,.#$+2
//+($#%.13$23(-&3'$$7/$1(,$-3 +# 3
" #$
!
" #$
04 3(.-&(5$-!8$!$1.11(2(2
"
#$
6'$1$ 0$ -# 03 1$ 3'$ ,.4-3 .% 231.-3(4, #2.1!$# /$1 &1 , .% 3
!(.2.1/3(.- 1 3$ ".-23 -32 %.1 /2$4#. %(123 -# 2$".-# .1#$1 ,.#$+2 1$2/$"3(5$+8 *
1$/1$2$-32 3'$ (-31 / 13("+$ #(%%42(.- 1 3$ ".-23 -3 -# (2 $!$1.11(2 ".-23 -3
-&,4(1 -# 1$4-#+("' ,.#$+2 6$1$ $,/+.8$# 3. #$2"1(!$ 3'$ ,$"' -(2, .%
)"%')*'#)$!*!))'"$.#" %'$%') (-%' "#)($# $($'%) $#,'
! ! "#
"#
"#
" #
' ( $##)') $# $ ' '" # # # ($!*) $# ) &* ! ' *" " & (
"$*#) $ ()'$#) *" $#( ($' %' '" $ ) &* ! ' *" " (
#"* ' $#()#) !($ !! ( #"* ' $ #) '%'(#)( $($'%) $# #)#( ).
&"- ( "- "*" "$*#) $ ()'$#) *" $#( ($' %' '" $ " # (
( $# ) ) $ )"%')*' $# ($'%) $# %'$(( ) )'"$.#"
%'")'(,'+!*)+!*($)'"$.#" %'")'(,'!*!).
*( #&*) $#(#-%'((!$,
"#
$ % $ %"#
%-*6* ) .7 8-* ).786.'98.32 (3*++.(.*28 1,1 .7 8-* .2.8.&0 786328.91 .32
(32(*286&8.32 .2 73098.32 1, * .7 786328.91 .32 (32(*286&8.32 .2 73098.32 &+8*6
'.373648.321,$.78-*:3091*3+13)*0;&78*;&8*697*)+36'.373648.32.7
;*.,-83+'&2&2&4**043;)*6, .78-*#2.:*67&0,&7(3278&28-&:.2,:&09*
/130".78-*&'73098*8*14*6&896*
.''7+6***2*6,=/130 ;*6*(&0(90&8*)'=97.2,+3003;.2,*59&8.32
*73648.32*++.(.*2(=3++36!6.327;&7(-*(/*);.8-).++*6*28730:*287
& &2) *.32.>*) %&8*6 .3736'*28 , ;.8- 1,, 3+
786328.9132.87796+&(*3'8&.2*).2'&8(-'.373648.32789)=;&78&/*2.2& 1+0&7/
&032,;.8-&/23;259&28.8=3+)*73648.3273098.32++*(83+8*14*6&896*32)*73648.32
*++.(.*2(=;&7789).*)&8 &2)
+36
1.2
36 6*97&'.0.8= *<4*6.1*287 , 3+ ;&7 &))*) .2 1 3+ 786328.91
;&7 +.08*6*) &2) 97*) +36 )*73648.32 '= &)).2, 1 3+ +8*6
)*73648.32 8-* 7&1* ;&7 6*97*) +36 '.373648.32 "-.7 7*6.*7 3+ '.373648.32 &2)
)*73648.32;&7(&66.*)3989483 (=(0*7
,21(; $1 ,21 (;&+$1*( &+520$72*5$3+< :$6 86(' 72 $6&(57$,1
75217,80 &21&(175$7,21 ,1 $48(286 62/87,21 !+( 3 0($685(0(176 :(5( '21( :,7+ $
',*,7$/ 3 0(7(5 )851,6+(' :,7+ $ &$/,%5$7(' &20%,1(' 3 */$66 (/(&752'( &$11,1*
(/(&75210,&526&23< :$686('72&+(&.7+(&+$1*(,1685)$&(0253+2/2*<2)
$)7(5%,262537,21$1''(62537,21 85)$&(0253+2/2*<2):$6678',('$7$5(62/87,21
2) # :+,/( 7+( ,0$*( 2) :$6 7$.(1 :,7+ $ 3$57,&/( 6,=( 2) 0 (5.,1
&0
72 ,'(17,)< )81&7,21$/ *52836 /2&$7(' ,1 %$1$1$ 3((/6 $1' 7+(,5 52/( ,1
%,262537,21535(66('3(//(70(7+2':$6$33/,(')256$03/(35(3$5$7,21
!,0( 5(48,5(' )25 %,262537,21 $6 :(// $6 9$5,$7,21 2) 62/87( &21&(175$7,21 :,7+
7,0($5(0$-255(48,5(0(176)25'(6,*12)%,262537,21352&(66$6('217+(7,0(678'<,7
%,262537,21 $1' $)7(5:$5'6 12 5(0$5.$%/( $8*0(17 :$6 5(&25'(' :+(1 678',(' 7,//
0,1 :,7+ 0* 5 62/87,21 '$7$ 127 6+2:1 ,0,/$5 75(1' :$6 2%7$,1(' :+(1
6,=(5$1*(%<86,1*
53063((')25
0,12)&217$&77,0(72.12:7+(())(&72),1,7,$/
675217,80,21&21&(175$7,2121(48,/,%5,807,0(2)%,262537,21,*
77+(%(*,11,1*
$6+$53,1&5($6(,15$7(2)%,262537,21:$62%6(59(':+,&+,6'8(72$%81'$17$1'5($',/<
4 (* !*$ "2(4$ !(,#(,& 1(2$1 -, (2' , (,"0$ 1$ (, 2'$ !(-1-0.2(-, 2(+$ + 11
(,"$ "-,2(,3-31 0$+-4 * -% 120-,2(3+ %0-+ 5 2$0 !7 !(-1-0.2(-, 2'$ &$21
1 230 2$# 5(2' 120-,2(3+ $,"$ (, 2'$ * 2$0 12 &$1 ,$&*(&(!*$ + 11 20 ,1%$0 ,#
!(-1-0.2(-, -""300$# , *(2$0 230$ "-..$0 ,# *$ # 5$0$ !(-1-0!$# (, +(,32$1 !7
'$.1$3#-%(012-0#$0.1$3#-1$"-,#-0#$0 ,#$!$0-00(1+-#$*15$0$31$#
2'$1$ +-#$*1 0$ 1'-5, (, !*$ '$ .1$3#-1$"-,#-0#$0 )(,$2(" +-#$* $6'(!(2$#
!$22$0 "-00$* 2(-, 5(2' 2'$ $6.$0(+$,2 * # 2 %-0 ** (,(2( * "-,"$,20 2(-,1 "-+. 0$# 2-
-2'$0 )(,$2(" +-#$*1 13&&$12(,& "'$+(" * !(-1-0.2(-, .0-"$11 "-,20-*1 2'$ !(-1-0.2(-,
'$ 4 *3$1 -% /$ ,# ) 5$0$ #$2$0+(,$# %0-+ 2'$ 1*-.$ ,# (,2$0"$.2 -00$* 2(-,
"-$%%("($,21 -!2 (,$# 5$0$ 2' 2 (1 ,$ 0*7 $/3 * 2- 2 5 1 ,-2("$# 2' 2 2'$
+&
,$ -% 2'$ (+.-02 ,2 4 0( !*$1 (,%*3$,"(,& !(-1-0.2(-, (1 2'$ 1(8$ -% !(-1-0!$,2
1'0 %$2 *
*+ $2 *
+.*$1' 4(,&+$1'1(8$
)
8( .$*2! /$! 1!-#! +-/%'! .%5! *"
8( -!.+!/%1!'4 2$!) (!.0-! 4 +-/%'! .%5!
-!(%)%)# +-(!/!-. *)./)/ .0$ . # *" %*.*-!)/ (# *)!)/-/%*) *"
.%(0'/! .*'0/%*) 7
6 /!(+!-/0-! )
-+( "*-
(%)0/!. $! 1-%/%*) *"
%*.*-+/%*) +%/4 "*- - 4 0.%)# %""!-!)/ %* .*-!)/ .%5!. %. #-+$%''4
'!.. %*.*-+/%*) +%/4 $%. %. !0.! /$! .('' .%5! +-/%'!. /!) /* !*(!
##-!#/!. 2$%$ $1! '!.. .0-"! -! "*- %*.*-+/%*) /$) %) %1% 0' +-/%'!. $!
%*.*-+/%*) +%/4 "*- 8( +-/%'! .%5! %. !//!- "*- %*.*-+/%*) #%1%)#
+%/4 .%)! /$!4 +-*1% ! '!.. .0-"! -! "*- .*-+/%*) !)! 2%/$ 8(
%.$!&! /*(%)/%)!//!-*)/-*'*1!-/$!./%--%)#+-*!..41-4%)##%//%*).+!!
-+() &!!+%)#-!(%)%)#+-(!/!-.*)./)/.0$.
8( +-/%'! .%5! -)#! "*- (%) )-!.! %) /$! -!(*1' *" - 4 %.
-!(*1'*"-4%)2/!-0+/*
-+(2%/$"0-/$!-%)-!.!%)#%//%*).+!!
7'3: -+55-' 3+4' +/ $+040315+0/ 8#4 0$4'37'& +) '44 $+040315+0/ 8#4 0$4'37'& #5
-08'3#)+5#5+0/41''&$'%#64'0(#%%6.6-#5+0/0(1#35+%-'40(8*+%**+/&'341301'3
'910463'0($+040315+0/463(#%'/5*'05*'3*#/&$+040315+0/3'.#+/4#-.045%0/45#/5
$':0/&
31.+)*.#4453#/4('33#5'8#40$4'37'&8+5*#)+5#5+0/41''&0(
31.
&6'505*')'/'3#5+0/0(1301'3563$6-'/%'8*+%*+4%0/4+&'3'&46((+%+'/5(03$+040315+0/
0(!30/(30.8#5'3'.0/'5#-
3.4. Effect of pH
7#+-#$+-+5: 0( (6/%5+0/#- )30614 #/& +0/+;#5+0/ 45#5' 0( .'5#-4 +4 3'26+3'& (03
$+040315+0/#/&+5.#+/-:&'1'/&40/10(5*'40-65+0/'%#64'1#(('%54&+440%+#5+0/
0( 5*' )30614 0/ 5*' 463(#%' 0( 5*' #/& (03.4 0( 4530/5+6. &+41'34'& +/ 8#5'3
.)
) 0( $+0403$'/5
=< 5'.1'3#563' #/&
>. 1#35+%-' 4+;' 3#/)'4 $:
64+/)
31.41''&(03.+/+)"*'$+040315+0/%#1#%+5:8#4+/%3'#4'-*'
1 +/%3'#4'& (30. 1 50 1 #5 1 8*+%* 46))'454 5*' +0/ '9%*#/)'
130%'448#4+/70-7'&60#/$'3
5-0815*'3'+4%0.1'5+5+0/$'58''/!3
#/&+0/4#-0/)8+5*5*''-'%53045#5+%3'16-4+0/#.0/)5*'!3#/&5*'104+5+7'-:
%*#3)'&#%5+7'$+040315+0/4+5'40/5*'463(#%'0(8*+%*+/*+$+545*'615#,'0(.'5#-
3'#%5+0/8*+%*%06-&0%%633'&&63+/)$+040315+0/+/#%+&+%8#5'3+4)+7'/4%*'.#5+%#--:
$'-08
4 5*' 1 8#4 +/%3'#4'& (635*'3 (30. 50 /0 3'.#3,#$-' &'%3'#4' +/ $+040315+0/
)'5')/9> <'8 4(8+7;+* 47+4;+7 '9 9./8 5 7'3-+ 897439/:2 2'/31> 57+8+39
57+*42/3'391> /3 9.+ ,472 4, $7 '3- +9 '1
'*'1' +9 '1
%.+
(/484759/43 7+')9/43 4, 897439/:2 /438 4394 9.+ !! )'3 (+ )438/*+7+* '8 ' 7+;+78/(1+
7+')9/43</9.'3+6:/1/(7/:2(+/3-2'*+(+9<++39.+9<45.'8+8'88).+2'9/)'11>8.4<3
(+14<
!!$7!!$7
$/-3/,/)'39 /25')9 <'8 349/)+* 43 897439/:2 7+24;'1 '9 '10'1/3+ 5
":'3+9'1
'8/))43*/9/43)4:1*,')/1/9'9+9.+*/8841:9/434,(/4847(+39A8
47-'3/) 2'99+7 9./8 2'> (+ 9.+ 7+'843 (+./3* 9.+ 7+*:)9/43 /3 (/484759/43 &:+ +9 '1
+3)+57'3-+4,
<'8)438/*+7+*'8459/2:2
*84759/43/849.+7224*+188:).'8'3-2:/7'3*7+:3*1/).<+7++2514>+*94
*+8)7/(+ 9.+ 2+).'3/82 4, (/484759/43 4, $7 43 9.+ !! 89/2'9+* /849.+72
5'7'2+9+78 <+7+ *+5/)9+* /3 %'(1+ %.+ (/484759/43 4, $7 4394 !! '9 */,,+7+39
)425'7/843 </9. '3-2:/7 /849.+728 <./). -';+ 14<+7 )477+1'9/43 )4+,,/)/+398 %.+
;'1:+8 4, '7+ 8++2 94 (+ /3)7+'8/3- </9. '3 /3)7+'8+ /3 9+25+7'9:7+ 8:--+89/3- 9.'9
(/484759/43 4, $7 43 !! /8 +3*49.+72/) /3 3'9:7+ /- :2(+7 4, 57+;/4:8
89:*/+8'-7++8</9.9./8+3*49.+72/)3'9:7+4,(/484759/43:7(4-''3*%+1 '3-
+9'1
+243+9'1 &++9'1 /484759/43/8,';4:7'(1+8/3)+;'1:+8
4, # 4(9'/3+* (> '3-2:/7 /849.+72 <+7+ ,'11 /3 (+9<++3 '3*
@3A +=57+88+8 9.+
".-$%-%0')%1"%25%%-!$1.0"!2%!-$").1.0"%-25()+%-)1'0%!2%02(!- 5)2()-
$%#+!0!2)4%1 .& #../%0!2)4% !$1.0/2).- 13''%12)-' 2(% 130&!#% .& ").1.0"%-2 2. "%
(%2%0.'%-%.31)--!230%+%!$)-'2./(71).1.0/2).-&!4.30!"+7!-!$!0%%2!+
(%
").1.0/2).- #!/!#)27 )-#0%!1%$ &0., ,'' 2. ,'' 5)2( !- )-#0%!1)-'
2%,/%0!230% &0.,
2.
)1% )- 2%,/%0!230% #.3+$ "% !11.#)!2%$ 5)2(
$%#0%!1%$5!2%04)1#.1)275()#(1%%,12.),/0.4%2(%,.")+)27.&0&0.,5!2%02.
5()#(%-(!-#%12(%").1.0/2).-
)' %12!"+)1(%1 2(% /+.2 .& +- $ 4%0131 0%#)/0.#!+ .& 2%,/%0!230% !-$ 2(%
.1)2)4% 4!+3% .& ; )-$)#!2%$ 2(!2 ").1.0/2).- )1 %-$.2(%0,)# /0.#%11 5()+% /.1)2)4%
; )-$)#!2%1 2(% )-#0%!1%$ 0!-$.,-%11 !2 2(% 1.+)$ !-$ 1.+32).- )-2%0&!#% $30)-'
").1.0/2).- ()1,!7"%$3%2.$%(7$0!2).-12%/2(!2)-#0%!1%12(%,.")+)27.&120.-2)3,
).-1!-$1300.3-$)-'5!2%0,.+%#3+%1)-2(%1.+32).- (%%6#(!-'%.&,.0%,.")+%).-1
/0%1%-2 .- 2(% !-$ 120.-2)3, ).-1 )1 !-.2(%0 0%!1.- 5()#( 5.3+$ #!31% /.1)2)4%
%-20./7 #(!-'% $30)-' 2(% ").1.0/2).- /0.#%11 %#0%!1% )- 2(% 4!+3%1 .& )""1 &0%%
%-%0')%1
5)2( )-#0%!1)-' 2%,/%0!230%
')4%1 &%!1)")+)27 !-$ 1/.-2!-%.31 -!230% .& /0.#%11 !-)1( %2 !+
.11!)-%2!+
30".'!!-$ %+
-!-!-$+2!1
()11%%,12./.)-2
.322(!2/(71).1.0/2).-)12(%/0%$.,)-!-2,%#(!-)1,)-2(%").1.0/2).-.&0.-2.
.-89+%8%2!+
3.6. Desorption study
'30214+0/ +3 # 120%'33 0( $+0302$'/4 2')'/'2#4+0/ %0/3+&'2'& 40 $' 0( %25%+#-
+.1024#/%'+/'%0/0.+%10+/40(6+'7'30214+0/345&97#3#%%0.1-+3*'&$9'.1-09+/)
30-6'/43 35%* #3 +42+% #%+& 5-1*52+% #%+& 9&20%*-02+% #%+& %'4+% #%+& 0&+5.
*9&208+&'#/&7#4'27*+%*7#3)+6'/
3420/4+5.
&'30214+0/ 2'31'%4+6'-9 #4 200. 4'.1'2#452' +) "3' 0( /+42+% #%+& (02
&'30214+0/*#3$''/)+6'/4*')2'#4'2&'30214+0/#.0/)4*'2'.#+/+/)30-6'/43/)-''4
#-
420/4+5. 0/ #&302$'& .#9 2'#%4 7+4* /+42+% #%+& 40 )+6' &+330-6'&
3420/4+5./+42#4'&52+/)&'30214+0/#/&4*'12'&+%4'&2'#%4+0/%#/$'
'30214+0/'((+%+'/%97#3(05/&40$'#/&
7*'/%*'%,'&$9&0+/)
&'30214+0/ '81'2+.'/43 $9 53+/) /+42+% #%+& #4 +/%2'#3'& 4'.1'2#452'3 35%* #3
#/&
2'31'%4+6'-9'/%'35%%''&+/)'81'2+.'/437'2'&0/'$953+/)/+42+%#%+
$9%0/3+&'2+/)&'30214+0/'((+%+'/%9#/&'%0/0.90(4*'120%'33
1201'24+'3 0( $+0302$'/4 7+4* *+)* 31#4+#- 2'30-54+0/ %#//+/) '-'%420/ .+%20)2#1*3 0(
+)#2'6'#-'&4*#44*'102'3#2'*+)*-9*'4'20)'/'053+22')5-#23*#1'#/&
352(#%''8*+$+43#.+%20205)*4'8452'!*+3%#/120.04'4*'#&*'2'/%'0(3420/4+5.+0/3
+/#3+.+-#27#9404*#4(05/&+//#452#-*#$+4#43'.0/'4#- #-.#'4#-
(4'2$+030214+0/#3+)/+(+%#/4%*#/)'+/4*'3425%452'0(4*'+30$3'26'&+)$
"*' #11'#34 50 *#7' 40.'8*#5 (-#,: 306)* 463(#%' 8+5* %3#5'3 -+,' 103'4 $'%#64'
5*': #3' 1#35+#--: %07'3'& $: 5*' 4530/5+6. +0/4 %*#, '5 #- # //#&63#+ '5 #-
(5'3 3'%07'3: 0( 5*' !3 (30. $: &'40315+0/ +5 %#/ $' 3'64'& (03
$+040315+0/*'/%'+5+4/'%'44#3:50456&:5*'3'64#$+-+5:%#1#%+5:0($+0403$'/5503'&6%'
5*' 07'3#-- %045 '64#$+-+5: 0( 3')'/'3#5'& $+0403$'/5 8#4 %*'%,'& 8*+%* 4*084
-+55-' &'%3'#4'
+/ $+040315+0/ %#1#%+5: #(5'3 '7'3: %:%-' 0( $+040315+0/ #/&
&'40315+0/6150%:%-'4(5'3(+(5*%:%-'5*'4#.'#%*+'7'&6150 3'.07#-0(
4530/5+6.(30. .)%0/%'/53#5'&40-65+0/-'%530/+%41'%53#0(#(5'3(+345%:%-'
0( &'40315+0/ 4*08/ +/ +) % &'1+%54 5*#5 %0/4+&'3#$-: #(('%5'& $: #-5'3+/) 5*'
463(#%'0($+0403$'/58*'/53'#5'&8+5*/+53+%#%+&.+)*5$'%*#33'&#(5'35*%:%-'
0( &'40315+0/ +) & ')'/'3#5+0/ #/& 3'64#$+-+5: 456&+'4 4*08'& 5*#5 5*'
1044'44'&105'/5+#-3'%:%-'1'3(03.#/%'
8#4%#33+'&06550+/7'45+)#5'.'%*#/+4.0($+040315+0/#/&13'4'/5'&+/+)
##/&$
%.
< 453'5%*+/) 0( #-,#/' %.
#/& < 453'5%*+/) 0(
%#3$09:-+%#%+&
%.
0('45'3#/&#/*:&3+&'
%.
$'/&+/)
'5*'3
$'/&+/)#$40315+0/(3'26'/%+'4!+)/+(+%#/5%*#/)'8#40$4'37'&+/
5*'+/5'/4+5:0(1'#,4#5
%.
8*'/ 456&+'& 5*' 41'%53# 0( #(5'3 $+040315+0/ 8*+%* +.1-+'4 5*#5
,10,<$%.( )70&6,10$. *41725 57&+ $5 $0' > 9(4( ,081.8(' ,0
&10),4/56+((:,56(0&(1)&$4%1:;.*417250,10,&*41725$4(4(52105,%.()14%,151426,10
1) &$6,10,& /(6$.5 5,0&( %$0$0$ 2((. &106$,05 .,*0,0 2(&6,0 &(..7.15( +(/,&(..7.15(5
*$.$&6174$0,&$&,'2416(,0),%4(56$4&+)$61+$2$64$(6$.
(/10(6$.
+(0(6$.
$0,5+(6$.
$
4. Conclusion
#+( /$:,/7/ %,151426,8( 4(/18$. 1) "4 %; 9$5 $&+,(8(' 9,6+
/**$6126,/,<('&10',6,10557&+$5 =/5,<(4$0*(1)
42/2$0'
6(/2(4$674( $0'
/,076(5 1) (37,.,%4,7/ &106$&6 6,/( "67',(5 1) %,151426,10
-,0(6,&5 ,0',&$6( 6+$6 6+( (:2(4,/(06$. '$6$ 9(4( )1..19(' 6+( 25(7'15(&10' 14'(4
/1'(.4(70'.,&+,516+(4//1'(.9$55+19061%($*11'),6)14$..6(/2(4$674(56(56('
,081.8(',06+(%,151426,101)"410616+(574)$&(1) #!$0'"$0$.;5,5
(56$%.,5+(5 6+( &10),4/$6,10 1) %,151426,10 (51426,10 &$2$&,6; 1) 9$5
$&&1/2.,5+('75,0*
$6 9$54(75('57&&(55)7..;)14),8(&;&.(51)
%,151426,10$0''(51426,109,6++,*+%,151426,10&$2$&,6;"44(/18$.)41/9$6(4%;
75,0* ,5$0(&101/,&$.()),&,(06$0'(08,410/(06$.)4,(0'.;241&(55)1451426,10$.
4(/18$.1)564106,7/
Acknowledgement
$.+ ':9.478 -7'9+,:11> ')034<1+*-+ 9.+ %3/;+78/9> 7'398 422/88/43 %
3*/',47574;/*/3-,/3'3)/'1'88/89'3)+/39.+7+8+'7).<470
5. References
'3*:2'3#+7;/)+8!:(1/)+'19.#+7;/)+
).'0',/*/ :'??'3/#'>'*/#'3*/
'4<)489(/4847(+39
B('3'3' 5++1C ,47 9.+ 7+24;'1 4, 5.+341/) )4254:3*8 ,742 41/;+ 2/11 <'89+<'9+7
/3+9/)'3*+6:/1/(7/:289:*/+8'?'7*'9+7 @
).'0'3*/ :'??'3/
("+24;'14,47-'3/)5411:9'398'3*3:97/+398
,74241/;+2/11<'89+<'9+7(>'8'3*,/19+73;/743'3'-+
@
.2'* $ "','9:11'. .'?'1/ #:1'/2'3 '8./2 " .2'*
"+24;'14,!+89/)/*+8,742&'9+7'3*&'89+<'9+7(>/,,+7+39*847(+398"+;/+<
3;/743#)/+'19.
@
.2'* $ "','9:11'. .'?'1/ #:1'/2'3 '8./2 "
/1 !'12
/42'88@'8+**847(+398,479.+"+24;'14,&'9+7!411:9'398A"+;/+<3;/743
#)/+'19.
@
.2'*$'3/8."','9:11'..'?'1/#:1'/2'3 '8./2"(7'./2
$.+:8+4,*'9+5'12'8'549+39/'1'*847(+39,47<'89+<'9+797+'92+39
7+;/+<3;/743#)/!411:9"+8 @
97+'92+397+;/+<3;/743'3'-+
16*-98>; )*+212 $*16*<+2 *<=*62 $ " //.,= 8/ *-<8;+.7=<
*7-,1.62,*5=;.*=6.7=<87=1.;.68?*58/<=;87=2>6/;86*:>.8><<85>=287<*C*;-
*=.;
77*->;*2 >*70 " # .. %<. 8/ ,.55>58<.+*<.- @*<=.< /8;
*-<8;9=2878/-B.</;86*:>.8><<85>=287<*C*;-*=.;
D
<1;*/ '*32- *1688- **1 (><8// 8@ ,8<=
+28<8;+.7= +*7*7* 9..5 ><* <*92.7=>6 /8; =1. ;.68?*5 8/ 1.*?B 6.=*5< #,2 ".<
<<*B
*1*; *1+>+ " *2-> " .01*;*3 < & ;.68?*5 /;86
*:>.8><<85>=287><270*58@,8<=*-<8;+.7=,82;92=1*<1:>252+;2>6*7-427.=2,<=>-B
7?2;87$.,1785778?D
*+;.;*'#1;88=.7;8.-E*.<.!".?2.@#=;87=2>6*7-
1.7 ( 270 *7 66872*2=;80.7 #8;9=287*5 !;89.;=2.< 8/ *7*7*
!..5<'*=.;7?2;87".<
.62;+*< .*?B6.=*5*-<8;9=28787=8*0;8+*<.-@*<=.6*=.;2*5<;.?2.@
*72<1*<126"+;*126"*/*=>55*11*6*-$#>5*26*7
*1*;*,=.;2C*=2878/ @88-+*<.-87*,=2?*=.-,*;+87<9;.9*;.-27
=1.9;.<.7,.8/+*<2,*,=2?*=270*0.7=<28;.<8>;,.<
*72<1 *<126 " +;*126 "*/*=>55*1 #>5*26*7 16*-$
#1*6<>CC81*16*- +#8;9=2878/899.;*7-2,4.587</;86
:>.8>< #85>=287< %<270 *5,2>6 A2-. ,=2?*=.- *=. !18.72A -*,=B52/.;* #=87.
*:+76 9=242+:2=5 26.<2, *6- %1.:57-A6*52, $<=-2.; 1.5 60 *<*
C
*62;115*-%*;125#*/2B#1*B*42$=4*25*6!2B2:704=
$
1*:*,<.:2B*<276 *6- *-;7:8<276 326.<2, ;<=-A 7/ ;=:/*,<*6< <:.*<.- 724 8*45
.58<A/:=2<+=6,1.;.;*426'*<.:%:.*<
C
4*++*; $ *6-2 .::.312; "76; .,4.:, " !=*BB*62
#.57>*4 7/ : /:75 ,1:75. <*66260 ?*;<.?*<.: +A *-;7:8<276 =;260 <?7 6*<=:*4
1*.527;<*-2%*:*01.1
1*:*,<.:2B*<276;7/;<:76<2=5
*6- +*:2=5 *-;7:8<276 /:75 *9=.7=; ;74=<276; =;260 -74752<. 87?-.: *B*:-
*-;7:8<276*B*:-*<.:
7;;*26 07 =7 ' $ 0=A.6 % &
#.57>*4 7/ ,788.:
/:75?*<.:+A*-;7:8<27676<7+*6*6*8..4*;+27;7:+.6<6<!%
): 6 7@2-." ,7587;2<. ;81.:.; *6- <1. 26>.;<20*<276 7/ $: ;7:8<276 +A
.@8.:25.6<*4-.;2061.560
;74=<27676<7:*,12;1A870*.*1=;3.;*426'*<.:%:.*<
+813<+8+'3@38/#+A+D#2+2D+.'99#//#
"3-/ =><+A,+=/. ,39-2+< ,/+.= 09< >2/ </79@+6 90 <+.39+->3@/ =><98>3?7 0<97 +;?/9?=
=96?>398#-3$9>+68@3<98 J
?9#"+<,/<#$2/</>/8>39890=><98>3?7,C=936=+=3806?/8-/.,C
:9<1+83-7+>>/<+8.=+>?<+>398-+>398=#936#-3
J
981+3.3+81/?92/8)(3+2/8 39=9<:>39890
=><98>3?7 0<97 +;?/9?= =96?>398= ,C +-366?= -/</?= 3=96+>/. 0<97 =><98>3?7
+-3/4/A=53 *?,/< %6/A3-D #9,3+89A=5+ "/79@+6 90
38/< <9-/==
;?363,<3?7538/>3-=+8.>2/<79.C8+73-=90+.73?7,39=9<:>39898>9-97:9=3>/
-23>9=+8,39=9<,/8><+,3+82/7#
#
=>+,363D+>398:98.=A3>2+8.A3>29?>7+-<9:2C>/=?8./<+<3.-637+>/'+>#-3$/-2
+<>G898DE6/D 98DE6/DG+D #?=3+6 <+H+ /<</<+/63E8
9H+"9.<G1?/D F</D /H+ "/?=/ 90 29/83B -+8+<3/8=3= :+67 0<98.
7?6-2+=,39=9<,/8>+8.+=:</-?<=9<90+->3@+>/.-+<,98=09<>2/+.=9<:>398907+D+636
38+;?/9?=:2+=/2/781
J
/798 " /798 # ! 2+81/< /798 * $?<53 66/8
2+<+->/<3D+>398 90 ,+8+8+ ://6 ,C =-+88381 /6/-><98 73-<9=-9:C +8. $"
=:/-><9=-9:C+8.3>=?=/09<-+.73?7</79@+696693.=#?<03938>/<0+-/=
E
92+77+.#27/.#+.+A3 +-97:+<+>3@/+.=9<:>398
=>?.C A3>2 .300/</8> +1<3-?6>?<+6 A+=>/ +.=9<,/8>=09< </79@+6 90 9B+7C6 :/=>3-3./
92+77+.#27/.#+.+A36/=9?53# ,->3@+>/.
+<,98 /<3@/. 0<97 1C:>3+8 +8+8+ //6= 09< "/79@+6 90 +.73?7 0<97 '+>/<
+::6630/=-338>
92+:+><+ 3=2<+ # #?>+< +8+8+ +8. 3>= ,C:<9.?-> ?>363=+>398 +8
9@/<@3/A#-38."/=8.3+
+-+<C & +<</ ) 6+=+<3 />29. 09< >2/ :</.3->398 90 8?-6/+< A+=>/
=96?>398 ./-98>+738+>398 ,C -9:</-3:3>+>398 90 =><98>3?7 398= A3>2 ,+<3?7 =?6:2+>/
?=381>2//B:/<37/8>+6.+>+9,>+38/.38898<+.39+->3@//8@3<987/8>2/781"/=
+67+98></<+=%<<+ -90<3/8.6C>/-2896913/=,+=/.98,+8+8+://6
?=/09<./-969?<3D+>39890>2/.C/381:<9-/==A+=>/A+>/<'+=>/397+==&+69<3D+>398
0<97+;?/9?==96?>39898>9>2/A+=>/=A//>637/://6=# /;?363,<3?7538/>3-=+8.
!?+8+38381$/81C?838384?!(3?=2/8)*2343+8'
#><98>3?7+8.-+6-3?7398+.=9<:>398,C796/-?6+<6C37:<38>/.2C,<3.1/62/781
"3?/81+3)2+81$ 39=9<:>39890>2/=><98>3?7398,C3<<+.3+>/.
$+--2+<97C-/=-/</@3=3+/?8./<-?6>?</-98.3>398=8@3<98#+.39+->
#+A+>92+:+><+!+5=273$2+>>+-2+<CC++8-2+8.+&
#+27+8 # ,<+23?7 ?81 ) % 3;?3. #+.39+->3@/ '+=>/=
%</+>7/8>#/@3/A'+>/<
$2+A+,5/2 # #9-5=><+A 2+.+ # 9::/< +8. =><98>3?7
+.=9<:>398,C+89@/6-+<,987+>/<3+67+8?0+->?</.0<97:/-+8=2/66=+<,98
&34+C+5?7+<#+7+6381+8!37)992+<7/8.3<+5?7+<
#/79@+690+-3..C/@396/>+8.+.=9<:>398538/>3-=79./690?=3817?=+=::A+=>/
)/ ( 3? % 3 " 3? '? * 97:+<3=98 90 =><98>3?7 +8. -+6-3?7
)?/ / /81 )? /81 ? .=9<:>398E./=9<:>398
,/2+@39<90+><+D38/98+1<3-?6>?<+6=936=38238+8@3<98$-3238+E
Figure caption
,*'-#%$("-*
'",-)&/.$)(()(...$' '$(
,-)&/.$)(()(...$' '$(
-)&/.$)(()(...$' '$(
3' $)-), (. -$2 ,*' -#%$(" -* '" , -)&/.$)(
* (
)(...$' '$(
Fig. 8: !! . )! -)&0 (.- )( -),*.$)( )! , .
3' $)-), (. -$2 ,*'
%removal
time (min.)
Fig. 1
t/qt (min.g/mg)
time (min.)
Fig. 2
%removal
BPP size ( m)
Fig.. 3
% Removal
Agitation speed ( rpm)
Fig. 4
% Removal
pH
Fig. 5
lnq
lnce
Fig. 6
ln kL
1/T
Fig. 7
% Desorption
Solvents
Fig. 8
a b
c d
Fig.. 9
Fig..10
Table 1:!&*&)'+!&%"!%+!')$+)*)&$!)%+"!%+!$&#*
!%+!
*,&!)*+&))
(#$
*$!%
*,&*&%&))
(#$
$ $!%
-!+!&%
)&))!*
Table 2:%!&$! %& &% !$$&! ! &%&$ &&"$&'$%
"$&'$
Table 3:'#%*$# &'#)'(%' %(%'&) %$%$)%
Highlights
Biosorption process complied with Freundlich and pseudo second order kinetic model.