5.24!07!2016 J (A) Minor Test Paper 1

Paper Code : 100 1CT1021 16013
ENGLISH
CLASSROOM CONTACT PROGRAMME

(Academic Session : 2016 - 2017)
JEE (Main + Advanced) : ENTHUSIAST COURSE

PHASE : I
Test Type : MINOR Test Pattern : JEE-Advanced
TEST DATE : 24 - 07 - 2016
Time : 3 Hours PAPER – 1 Maximum Marks : 228
READ THE INSTRUCTIONS CAREFULLY

GENERAL :
1. This sealed booklet is your Question Paper. Do not break the seal till you are told
to do so.
2. Use the Optical Response sheet (ORS) provided separately for answering the questions.
DO NOT BREAK THE SEALS WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR

3. Blank spaces are provided within this booklet for rough work.
4. Write your name, form number and sign in the space provided on the back cover of this
booklet.
5. After breaking the seal of the booklet, verify that the booklet contains 40 pages and
that all the 20 questions in each subject and along with the options are legible. If not,
contact the invigilator for replacement of the booklet.
6. You are allowed to take away the Question Paper at the end of the examination.
OPTICAL RESPONSE SHEET :

7. The ORS will be collected by the invigilator at the end of the examination.
8. Do not tamper with or mutilate the ORS. Do not use the ORS for rough work.
9. Write your name, form number and sign with pen in the space provided for this purpose
on the ORS. Do not write any of these details anywhere else on the ORS. Darken
the appropriate bubble under each digit of your form number.
DARKENING THE BUBBLES ON THE ORS :
10. Use a BLACK BALL POINT PEN to darken the bubbles on the ORS.
11. Darken the bubble COMPLETELY.
12. The correct way of darkening a bubble is as :
13. The ORS is machine-gradable. Ensure that the bubbles are darkened in the correct
way.
14. Darken the bubbles ONLY IF you are sure of the answer. There is NO WAY to erase
or "un-darken" a darkened bubble.
15. Take g = 10 m/s2 unless otherwise stated.
Please see the last page of this booklet for rest of the instructions
Target : JEE (Main + Advanced) 2017/24-07-2016/Paper-1
SOME USEFUL CONSTANTS

Atomic No. H = 1, B = 5, C = 6, N = 7, O = 8, F = 9, Al = 13, P = 15, S = 16,
Cl = 17, Br = 35, Xe = 54, Ce = 58,
Atomic masses : H = 1, Li = 7, B = 11, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24,
Al = 27, P = 31, S = 32, Cl = 35.5, Ca=40, Fe = 56, Br = 80, I = 127,
Xe = 131, Ba=137, Ce = 140,
 Boltzmann constant k = 1.38 × 10–23 JK–1

1
 Coulomb's law constant = 9 ×10 9
4 0
 Universal gravitational constant G = 6.67259 × 10–11 N–m2 kg–2
 Speed of light in vacuum c = 3 × 108 ms–1
 Stefan–Boltzmann constant  = 5.67 × 10–8 Wm–2 –K–4
 Wien's displacement law constant b = 2.89 × 10–3 m–K
 Permeability of vacuum µ0 = 4 × 10–7 NA–2
1
 Permittivity of vacuum 0 =
0 c2
 Planck constant h = 6.63 × 10–34 J–s
Space for Rough Work
E-2/40 1001CT102116013
Enthusiast Course/Phase-I/24-07-2016/Paper-1
HAVE CONTROL  HAVE PATIENCE  HAVE CONFIDENCE  100% SUCCESS
PHYSICS
BEWARE OF NEGATIVE MARKING
PART-1 : PHYSICS
SECTION–I(i) : (Maximum Marks : 24)
 This section contains SIX questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of
these four option(s) is (are) correct.
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the
ORS
 For each question, marks will be awarded in one of the following categories :
Full Marks : +4 If only the bubble(s) corresponding to all the correct option(s) is (are)
darkened.
Partial Marks : +1 For darkening a bubble corresponding to each correct option,
Provided NO incorrect option is darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : –2 In all other cases.
 for example, if (A), (C) and (D) are all the correct options for a question, darkening all these
three will result in +4 marks; darkening only (A) and (D) will result in +2 marks; and
darkening (A) and (B) will result in –2 marks, as a wrong option is also darkened
1. A bead slides on a fixed frictionless wire bent into a horizontal semicircle of radius R0 as
shown in figure. In addition to any normal forces exerted by the wire, the bead is subjected to
an external force that points directly away from origin and depends on distance r from the
2
  r 
origin according to the formula F  F0   rˆ :-
 R0 
y
v0
R0
x
v
(A) Given external force is a central force.

(B) Given external force is a conservative force.
16F0
(C) Normal reaction by wire as bead leaves the wire is .
3
16F0 R0
(D) Speed of bead as it leaves the wire is v 20  .
3m
1001CT102116013 E-3/40
2. Two particles, each of mass m, are moving inside a fixed horizontal circular tube of radius R
PHYSICS
with the same constant speed v. Figure shows their positions at time t = 0. The system
consists of particles. Mark the CORRECT statement(s) for any time t before the collision :
v v
R
x
v2  vt 
(A) Acceleration of the centre of mass is  sin   ˆj
R R
2mv2  vt 
(B) Net external force acting on the system is  sin   ˆj
R R
mv 2   vt  ˆ  vt  ˆ 
(C) force acting on left particle is  cos  R  i  sin  R  j 
R      
mv 2   vt   vt  
(D) force acting on right particle is –  cos   iˆ  sin   ˆj 
R  R R 
E-4/40 1001CT102116013
3. Two square non metallic plates of sides  are placed parallel to each other with separation d
PHYSICS
as suggested in figure. You may assume d is much less than . The plates carry uniformly
distributed static charges +Q0 and –Q0. A block of metal has width , length , and thickness
slightly less than d. It is inserted at distance x into the space between the plates. The charges
on the plates remain uniformly distributed as the block slides in. In a static situation, a metal
prevents an electric field from penetrating inside it. The metal can be thought of as a perfect
dielectric, with   .
x
 d
Q20d    x 
(A) The stored energy as a function of x is given by
 2 3
0 
Q20d
(B) The magnitude of the force that acts on the metallic block is given by to the right.
 3
0 
(C) The area of the advancing front face of the block is essentially equal to d, the stress
Q20
(force per unit area) on front face is .
2 4
0 
(D) The energy density in the electric field between the charged plates in terms of Q0, , d,
Q20
and 0 is
2 4
0 
1001CT102116013 E-5/40
4. Mark the CORRECT statement(s) :-
PHYSICS
(A) Magnitude of electric field is given by the magnitude of change in potential per unit
displacement normal to the equipotential surface at the point.
   q2
(B) Potential energy of a dipole in an external field E is  p  E  where 2a is separation
4 0  2a
between charges of dipole.
dy Ey
(C) A displacement along a field line lying in the x-y plane satisfies equation  .
dx Ex
(D) If a charge particle is released from rest in a nonuniform electric field the trajectory of
particle will be same as electric field line.
5. Consider a metal rod of length L that is given a uniform acceleration as shown in figure (a)
and an identical rod rotating with constant angular velocity in figure (b).
B

a R

A B A

Figure (a) stationary conducting
circular frame
Figure (b)
(A) If VA and VB are potential of end A and B respectively, then VA < VB in figure (a)
(B) If VA and VB are potential of end A and B respectively, then VA > VB in figure (b)
ma
(C) Electric field inside rod has magnitude in figure (a)
e
m2 r
(D) Electric field inside rod has magnitude in figure (b)
e
E-6/40 1001CT102116013
6. In the circuit shown there is steady state with the switch closed. The switch is opened at
PHYSICS
t = 0. Choose the correct option(s). (Given :  = 24V, C1 = 3F and C2 = 2F)
3
 9 C1
S
C2 6
(A) The voltage across C1 before the switch is open is 12V.

(B) The voltage across C1 after a long time after the switch is open is 12V.
(C) The voltage across C2 after a long time after the switch is open is 24V.
(D) The voltage across C2 before the switch is open is 8V.
1001CT102116013 E-7/40
SECTION–I(ii) : (Maximum Marks : 16)
PHYSICS
 This section contains TWO paragraphs.

 Based on each paragraph, there will be TWO questions
 Each question has FOUR options (A), (B), (C) and (D) ONE OR MORE THAN ONE of
these four option(s) is(are) correct.
ORS.
darkened.
Paragraph for Questions 7 and 8
Specialized bacteria can be found in oil and sewage disposal plants. A bacteria that lives
in absolutely dark and essentially homogeneous soup faces a serious navigational problem. It
must sometimes rise for oxygen and then descend for an important part of its dinner.
One class of bacteria known as Magnetostactic Bacteria has solved the problem by
incorporating an iron oxide magnet inside the cell. The magnet inside a bacteria can cause it
to rise or fall depending on the relative orientation between magnetic moment and earth's
magnetic field given by B =  – z when  and  are positive constant and z is vertical up
distance.
Because of the random thermal motion (Brownian movement) relative orientation is randomly
changed so that a bacteria can both rise for oxygen and descend for food. Actually such small
magnets of bacteria string together to form large magnets of moment M. Assume that the
formula for the field of magnetic dipole moment is valid even for small distances.
Two bacteria of magnetic moment M each align to form a chain of length d. The energy of
Brownian movement of bacteria is kT where k is boltzmann's constant and T is the absolute
temperature. This movement tends to destroy the ordering arrangement of the bacteria if
interaction energy of two bacteria becomes smaller than the Brownian movement energy.
E-8/40 1001CT102116013
7. Mark the correct statement(s) for the rise or fall of a Magnetostactic bacteria:-
PHYSICS
(A) Buoyant force due to liquid will rise or fall the bacteria (initially at rest) irrespective of
its specific weight relative to fluid.
(B) A bacteria acts as a magnetic dipole and due to uniform magnetic field it can experience
net torque resulting in its rise or fall
(C) A bacteria acts as a magnetic dipole and due to uniform magnetic field it can experience
net force resulting in its rise or fall
(D) A bacteria acts as a magnetic dipole and due to nonuniform magnetic field it can experience
net force resulting in its rise or fall
(A) Vertical magnetic force can be up or down depending on direction of dipole moment
relative to magnetic field.
 0 16M2
(B) Energy of dipole- dipole interaction in given configuration is
4 d3
(C) Force causing such a magnet to rise or fall has magnitude 2M for given field.
(D) The minimum magnetic moment inside a bacteria so that it can form the stable chain is
2kTd 3
0
1001CT102116013 E-9/40
There is an insulator rod of length L and of negligible mass with two small balls of mass m
PHYSICS
and electric charge Q attached to its ends. The rod can rotate in the horizontal plane around
a vertical axis crossing it at a L/4 distance from one of its ends. The rods are placed in a
uniform electric field as shown in the figure.
E E
Pivot Pivot
L/4 3L/4 3L/4 L/4
E E
Figure (A) Figure (B)

(A) In figure (A) rod is in unstable equilibrium
(B) In figure (B) rod is in stable equilibrium
(C) Maximum velocity attained by ball at 3L/4 when released from unstable equilibrium
9QEL
position is
5m
(D) Maximum velocity attained by ball at L/4when released from unstable equilibrium position
QEL
is
5m
10. Mark the CORRECT statement(s) :
(A) For small angular displacement  from stable equilibrium position restoring torque is
3QELsin 
2
(B) For small angular displacement  from stable equilibrium position restoring torque is
QEL sin 
2
(C) For small angular displacement  from stable equilibrium position time period of oscillation
5mL
is 
4QE
(D) For small angular displacement  from stable equilibrium position time period of oscillation
5mL
is 
QE
E-10/40 1001CT102116013
SECTION–I(iii) : (Maximum Marks : 12)
 This section contains FOUR questions.
PHYSICS
 Each question has matching lists. The codes for the lists have choices (A), (B), (C) and (D)
out of which ONLY ONE is correct
Full Marks : +3 If only the bubble corresponding to the correct option is darkened.
Negative Marks : –1 In all other cases
11. List-I shows system of charge bodies and List-II shows electric potential and electric field at
position P. Assume reference of potential at .
List-I (System of Charge Bodies) List-II (Field and Potential at P)
(P) P Q (1) V  0, E  0
Conducting shell of charge Q
Q q
(Q) P (2) V = 0, E = 0
Cavity in an earthed conductor of

charge + Q kept near a charge q.
(R) (3) E  0, v = 0
A uniformly charged dielectric sphere
Q
(S)
P (4) E = 0, V  0
Concentric spherical Cavity in a

uniformly charged dielectric sphere
Codes :
P Q R S
(A) 4 2 1 4
(B) 2 1 3 4
(C) 3 2 4 1
(D) 4 3 2 1
1001CT102116013 E-11/40
12. List-I shows charges projected in given field, list-II shows path of respective charges.
PHYSICS
List-I (Systems) List-II (Paths of charge particles)
E B
× ×
(P) × × (1) (Path in a plane)
× ×
q
The charge q is projected perpendicular
to the electric field. Then it moves through
the magnetic field.
q × ×B
(Q) × × E (2) (helical Path )
× ×
The charge is released from rest in
 
a crossed B and E

E
B q
(R) (3) (Path in a plane)
The charge is projected perpendicular to

 
E in a crossed E and B
B
v
(S) (4) (Path in a plane)
q
The charge is projected at an angle with
magnetic field
Codes :
P Q R S
(A) 2 1 4 3
(B) 3 1 4 2
(C) 4 2 1 3
(D) 3 1 2 4
E-12/40 1001CT102116013
13. List-I shows electric circuits and List-II shows equivalent resistance between A and B.
PHYSICS
List-I List-II
2R 2R
R R
(P) A B (1) R/2
R R
2R 2R
R/2
2R R
2R
(Q) R/2 (2) R/3
R R
R
A B
R
R R
(R) (3) 2R/3
R
R
B
A
R
R C
R R R R
(S) (4) 2R
A R B
Codes :
P Q R S
(A) 3 1 4 2
(B) 2 1 4 2
(C) 3 1 4 1
(D) 2 1 4 3
1001CT102116013 E-13/40
14. An isolated charged parallel plate capacitor has energy U1, u V1 is energy density, force between
PHYSICS
plates F1, electric field between plates E1 and potential difference V1. When a dielectric slab of
relative permitivity r is fully introduced, the corresponding parameters will be U2, u V2 ,F2,E2
and V2 respectively. Then :
List-I List-II
uv1
(P) is energy density (1) 1 : 1
uv2
U1
(Q) U (2) 2r :1
2
V2
(R) V (3) r : 1
1
F1
(S) F (4) 1 : r
2
Codes :
P Q R S
(A) 4 2 3 1
(B) 3 2 4 1
(C) 3 2 1 4
(D) 3 3 4 1
SECTION –II : Matrix-Match Type & SECTION –III : Integer Value Correct Type
No question will be asked in section II and III
E-14/40 1001CT102116013
SECTION–IV : (Maximum Marks : 24)
PHYSICS
 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both
inclusive.
 For each question, darken the bubble corresponding to the correct integer in the ORS.
Full Marks : +4 If only the bubble corresponding to the correct answer is darkened.
Zero Marks : 0 In all other cases.
1. Metal rod with a mass m = 10 g, and length L = 0.2 m is suspended by two light wires length
 = 1 cm in a magnetic field B which is directed vertically downwards (Figure). A capacitor of
capacitance C = 100 µF charged to a voltage of 100 V is connected as shown. The maximum
deflection (in degree) of the rod from the initial position after the switch is closed is 37°. Resistance
of wire and rod is not taken into account. What is the magntidue of magnetic field in tesla.
B
L

1001CT102116013 E-15/40
2. A thin conducting wire in the shape of a 'figure of eight' is situated with its circular loops in two
PHYSICS
planes making an angle of 120° with each other. If the current in the loop is i and the radius is
a, determine the magnetic field strength at a point of intersection of the two axes of the loops.
0 i 3
If your answer is fill the value of x.
4xa
Inward current
Outward current Topview
Loop A
60°
60°
Loop B
3. A long straight wire lies on y-axis and carries a current of 8 A in –y direction. In addition to
the magnetic field produced by the wire, a uniform magnetic field of 1.4 × 10–6 T î is also
present. What is the magnitude of net magnetic field at (1, 1, 1). Express your answer in
a
a × 10–7 T and fill in OMR sheet.
2
E-16/40 1001CT102116013
4. In Fig., the uniform-resistance wire between A and B has a total resistance R0. The contact at C
PHYSICS
can divide the wire into resistors fR0 and (1 – f)R0. Consider the ideal ammeter for any
0 < f < 1. Assume that the batteries are identical and have negligible internal resistance. For
what value of f is the ammeter reading is minimum. Fill value of 12f.
r
E E
A
fR0 (1 – f)R0
A B
C
5. In the circuit shown, all voltmeters & ammeter are ideal. The internal resistance of battery
is 20. The readings of voltmeter and ammeter are marked in the figure. What is resistance R2
R2
(in ohm)? Fill value of .
20
60V
V
R2 R3
R1
0.5A
A V
90V
120V, 20
1001CT102116013 E-17/40
6. A very long straight conductor has a circular cross-section of radius R and carries a current
PHYSICS
density J. Inside the conductor there is a cylindrical hole of radius a whose axis is parallel to
the axis of the conductor and a distance b from it. Let the z-axis be the axis of the conductor,
and let the axis of the hole be at x = b. Find the x component of magnetic field on the y–axis at
1 a2 
y = 2R. If your answer is Bx =  0 JR   2 2  fill value of |A| + |B|.
 A BR  b 
y
iin R
a
x
O C
b
E-18/40 1001CT102116013
PART-2 : CHEMISTRY
CHEMISTRY
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of
these four option(s) is (are) correct.
ORS
darkened.
1. Select the correct statements(a) about solids -
(A) Observable magnetic properties are consequence of magnetic moments associated with
individual electrons
(B) Orbital motion of electron and spin of electron around its own axis both contributes to
magnetic moment of electron
(C) Ferrimagnetic solids transform to the paramagnetic state at high temperature
(D) All seven crystal system have primitive unit cell
2. Select the correct statements
(A) In a second order reaction , if time taken for 0 to 50% completion of reaction is 't' then
time taken for 50 to 75% completion of reaction is 't/2'
(B) In a first order reaction, if time taken for 0 to 10% completion of reaction is 't' then time
taken for 10% to 20% completion of reaction is also 't'
(C) In a zero order reaction , if time taken for 0 to 50% completion of reaction is 't' then time
taken for 50 to 75 % completion of reaction is 't/2'
(D) In a zero order reaction, if time taken for 0 to 10% completion of reaction is 't' then time
taken for 10% to 20% completion of reaction is also 't'
1001CT102116013 E-19/40
3. Which of the following complexes are inner orbital ?
CHEMISTRY
(A) [Fe(CN)6]–3 (B) [Ni(en)3]+2 (C) [Fe(OH2)6]+2 (D) [NiF6]–2

4. Which of the following statement is/are INCORRECT about [Co(H2O)3F3]0 :-
(A) It is low spin complex
(B) Hybridisation of central metal is d2sp3
(C) It is paramagnetic in nature
(D) In this complex H2O responsible for the pairing of electrons
5. Select the reaction(s) correctly match with their major product :
CN CHO
(i) SnCl2 / HCl (i) Mg / Dry ether
(A) + (B) Ph–I Ph–COOH
(ii) H3O (ii) CO2
+
(iii)H
O
Zn / Hg (i) B2H6
(C) (D) (ii) H3O
+
HCl
COOH CH 2OH
6. Select the reaction(s) correctly match with their major product :
O OH
C CHO MeMgCl
Cl H2–Pd
(A) BaSO4
(B) O Cl
O
(i) Mg-Hg 1 % HgSO4
(C) (ii) H2O
(D)
dil. H2SO4
O
E-20/40 1001CT102116013
CHEMISTRY
ORS.
darkened.
Due to the difference in the spatial arrangement of the ligands within the coordination
sphere, the phenomenon of stereo-isomerism arises. In a tetrahedral structure, relative
position of each ligand is the same having the bond angle ~109° this is why, in a tetrahedral
structure, there is no geometrical isomerism. But in square planar complex and octahedral
complexes relative positions of the ligand are not equivalent so that they can show
geometrical isomerism.
The square planar complexes are generally optically inactive but octahedral complexes can
produce optical activity.
7. Which of the following complexes show geometrical isomerism but not show optical isomerism
(A) [PtBrCl(NH3)(Py)] (B) [Co(Gly)3]
(C) [Co(NH3)3(NO2)3] (D) [Co(EDTA)]–1
8. Which of the following complex have maximum number of pairs of enantiomers.
(A) [PtCl2(NH3)2(Py)2]+2 (B) [CoCl2(en)2]
(C) [CrCl2(en)(NH3)2] (D) [PtCl2(NH3)(NO2)BrI]0
1001CT102116013 E-21/40
CHEMISTRY
For the following sequence :

Br2 Mg P Na S NaI
CH3–CH3 hv
P Et2O
Q R Et2O acetone T
(excess)
9. Choose the correct option(s) ?
(A) (S) can be CH3–CH2–CH2–Br (B) (Q) is known as grignard reagent
(C) (R) is n-hexane (D) (P) is CH3–CH2–Br
10. Which of the following phenomenon / reaction is/are involved in above reaction sequence .
(A) Wurtz fittig reaction (B) Nucleophilic substitution
(C) Free radical substitution (D) Finkelstein reaction
E-22/40 1001CT102116013
CHEMISTRY
11. For the reaction A + B  product, Given : [A]0 = [B]0
List-I (Observed Rate Law) is - List-II (Graph)
Conc.
(P) r = k[A] (1)

[A]
Time
t1/2
(Q) r = k[A]1/2[B]1/2 (2)

[A]0
ln t1/2
(R) r = k[A] [B] (3) 135º

ln[A]0
ln[A]t
(S) r = k[A]0 [B]0 (4)

Time
Codes :
P Q R S
(A) 4 1 3 2
(B) 2 3 1 4
(C) 1 2 3 4
(D) 4 3 2 1
1001CT102116013 E-23/40
CHEMISTRY
12. List-I (Complexes) List-II (Correct characteristics)
(P) [Ni(CN)4]–2 (1) Tetrahedral
(Q) [Fe(H2O)5NO]+2 (2) sp3d2 hybridisation
(R) [Co(CO)4] (3)  = 0
(S) [NiCl2(NH3)2]0 (4) Sq. planar
Codes :
P Q R S
(A) 4 2 3 1
(B) 3 2 1 4
(C) 1 2 3 4
(D) 3 1 4 2
E-24/40 1001CT102116013
13. Match the reaction List-I with name of reaction in List-II :
CHEMISTRY
List-I List-II
SOCl2
(P) CH3–CH2–OH (1) Swarts reaction
AgF
(Q) CH3–CH2–Br (2) Lucas test
DMF
(R) CH3–CH2–Br CH 3–CH2ONa (3) Darzen process
(S) Ph–CH2–OH HCl (4) Williamson ether synthesis

anhyd. ZnCl2
Codes :
P Q R S
(A) 4 1 3 2
(B) 3 1 4 2
(C) 3 2 4 1
(D) 3 1 2 4
1001CT102116013 E-25/40
14. List-I List-II
CHEMISTRY
(Reaction with major product) (Reagents)
(P) (1) (i) D2 (1 eq.) / Pt ; (ii) H2 (1 eq.) / Pt
D
(Q) (2) (i) H2 (1 eq.) / Pt ; (ii) D2 (1 eq.) / Pt
D
D
SH
+
(R) D (3) (i) HS H ; (ii) Raney Ni / H2
O
(S) (4) (i) N2H4 / H2O2 ; (ii) LiAlH4 ; (iii) H+ / 
Codes :
P Q R S
(A) 4 2 1 3
(B) 3 1 2 4
(C) 4 1 2 3
(D) 3 2 1 4
E-26/40 1001CT102116013
CHEMISTRY
 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both
inclusive.
1. How many spectral lines will be obtained in emission spectrum of hydrogen in Balmer region
if electron present in 8th excited state -
Fill your answer as sum of digits (excluding decimal places) till you get the single digit
answer.
2. 1 mol He initially at 300 K are undergoing a process, T = kV2 where its volume is doubled.
Calculate |w| ( in cal) during the process.
answer.
Ea
3. Milk is pasteurised if it is heated at 67ºC for 4 hours , if, for the process is
2.303
23.8 kcal / mol then minimum how much seconds will be required for the the process at
77ºC ? [R = 2cal /k/mol]
answer.
1001CT102116013 E-27/40
4. Find the number of complexes which are paramagnetic in nature.

CHEMISTRY
[NiCl4]–2, [PtCl4]–2, [IrF6]–3, [Ag(NH3)2]+, [Fe(H2O)6]+2, [Co(H2O)6]+3
5. Find the total number of type of isomerism shown by the complex [CoCl(NH3)4(NO2)]Cl. Out
of the following :
Coordination isomerism, Linkage isomerism, Ionization isomerism, Geometrical isomerism,
Ligand isomerism, Optical isomerism.
6. In the following monobromination reaction, the number of possible achiral organic products is
CH2CH 3
Br2 (1.0 mole)
H Br
300ºC
CH3
(1.0 mole)
(enantiomerically pure)
E-28/40 1001CT102116013
PART-3 : MATHEMATICS
MATHEMATICS
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is (are) correct.
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
darkened.
three will result in +4 marks; darkening only (A) and (D) will result in +2 marks; and darkening
(A) and (B) will result in –2 marks, as a wrong option is also darkened
1.  
Tangents PA and PB are drawn from a point P 2 2,0 to the circle x2 + y2 = 4, then-
(A) Area of circumcircle of PAB is 2

(B) Area of circumcircle of PAB is 4

(C) APB 
2

(D) APB 
3
2.  
A tangent to the curve x2 + y2 = 4 at the point 1, 3 cut intercepts p and q with x and y-axis
respectively, then-
4
(A) p = 4 (B) p  (C) p  3q  0 (D) p2 + q2 = 32
3
a 1 d
3. Number of point(s) of intersection of the curves r  and  can
b sin   c cos  r e sin   ƒ cos 
y
be equal to (where a,b,c,d,e,ƒ are real numbers, x2 + y2 = r2 and tan   )
x
(A) 0 (B) 1 (C) 2 (D) 3
1001CT102116013 E-29/40
MATHEMATICS
4. Which of the following statement(s) is/are correct ?

x
 
(A) Let ƒ be a continuous function on [0,) such that lim  ƒ  x    ƒ  t  dt  exists, then
x 
 0 
lim ƒ  x   0 .
x 
ƒ x 
(B) Let ƒ be a real valued differentiable function on R such that lim exist and is finite,
x 0 x2
then ƒ'(0) = 0
1  1
(C) Let ƒ :  x1 ,x 2    ,2  be a continuous function such that ƒ  x1   and ƒ(x2) = 2, then
2  2
 
 2  1 
ƒ   ,2
 1  1   2 
x 
 1 x2 
(D) There exist no continuous monotonic function ƒ : R  R such that lim ƒ  x   1
x 
5. Let ƒ : [0,1]  R be a differentiable function with non-increasing derivative such that ƒ(0) = 0
and ƒ'(1) > 0, then
(A) ƒ(1) > ƒ'(1) (B) ƒ(1) < ƒ'(1)
1
1 ƒ 1
(C)  1  ƒ  x  dx  ƒ ' 1
0
2 (D) ƒ(x) is an increasing function on [0,1]
x   x 
  1 
6. Given ƒ  x   
0  0   x    x   dx  dx (where [.] denotes greatest integer function), then ƒ(x) is
2   
  
discontinuous at -
(A) x = 1 (B) x = 0
1
(C) x  n  ,  n  I (D) x = 2
2
E-30/40 1001CT102116013
MATHEMATICS
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS.
darkened.
three will result in +4 marks; darkening only (A) and (D) will result in +2 marks; and darkening
(A) and (B) will result in –2 marks, as a wrong option is also darkened
 
 sin 2x if 0x
6
Let ƒ  x   
ax  b if 
 x 1
 6
7. If ƒ(x) is continuous and ƒ'(x) is discontinuous then value(s) of 'a' can be-
3
(A) 0 (B) 1 (C) (D) 2
2
8. If ƒ'(x) is continuous then which of the following is/are true ?
 
(A) ƒ(x) has point of minima at x = (B) ƒ(x) has point of maxima at x =
6 6
3 3
(C) a = 1 (D) b 
6
1001CT102116013 E-31/40
MATHEMATICS
Given C1 : x2 – 2x + y2 – 3 = 0 and C2 : x2 + 2x + y2 – 3 = 0 be the equation of two circles and

'P' is a moving point on xy-plane. If PA,PB denotes length of tangent from P to the circles
C1 & C2 respectively, then
9. Angle of intersection of C1 & C2 can be-
  2 
(A) (B) (C) (D)
2 3 3 6
10. Which of the following is/are true ?
(A) A circle inscribed in the common region of C1 & C2 has radius unity.
(B) Area of largest rhombus inscribed in the common region of C1 & C2 is 2 3 sq. units
(C) If co-ordinates of P is (0,) then PA2 – PB2 is independent of  (  R)
(D) Minimum distance between C1 & C2 is 2.
E-32/40 1001CT102116013
MATHEMATICS
11. Match List-I with List-II and select the correct answer using the code given below the list.
List-I List-II
(P) A differentiable function ƒ(x) satisfies (1) 1
ƒ(1 + x) = ƒ(1– x)  x  R, then ƒ'(1) =
 1  x2 
(Q) If ƒ  x   cos1  2 
, then ƒ'(x) < 0 for x = (2) 0
1  x 
(R) ƒ : R  R be an odd twice differentiable function (3) –2
satisfying ƒ'(1) = 2, then ƒ(0) + ƒ"(0) + ƒ'(–1) =
(S) Let ƒ(x) = sgnx, g  x   1  x 2 . If  ƒ g  x  dx  Ax  B (4) 2
then A is equal to
(where sgnx denotes signum function)
Codes :
P Q R S
(A) 2 3 4 1
(B) 2 4 3 1
(C) 3 2 4 1
(D) 3 1 2 4
1001CT102116013 E-33/40
MATHEMATICS
12. Match List-I with List-II and select the correct answer using the code given below the list.
List-I List-II
2
(P) x-coordinate of a point on the curve ƒ(x) = x + 1 at (1) 2
which tangent line is parallel to the chord joining
points (–1,2) & (0,1) is
(Q) The number of critical point(s) on (2) 1
ƒ(x) = (x – 1) |x – 2| + (x – 2) |x – 1| is
(R) Least positive integral value of x for which (3) more than 2
x x
ƒ(x) = (2 – 1).(2 – 3) increases.
1
(S) Given A(x) = {|x|, x2 – 1, x2 + x + 1, n|x|}, then (4) 
2
number of function in A(x) for which Rolle's theorem
holds for the interval [–1,1].
Codes :
P Q R S
(A) 4 3 2 1
(B) 3 4 2 1
(C) 4 3 1 2
(D) 3 4 1 2
E-34/40 1001CT102116013
MATHEMATICS
n x
13. Given x dx  A 1  nƒ  x   g  x   2   C
1  n|x|
(where C is constant of integration, also g(1) = 0), then-
Match List-I with List-II and select the correct answer using the code given below the list.
List-I List-II
(P) A is equal to (1) 2
|sin x|
(Q) lim   is equal to (2) 1
 ƒ  x  
x 0
(where [.] denotes greatest integer function)
2
(R) Slope of tangent to the curve y = g(x) (3)
3
where it crosses the positive x-axis is
(S) least positive integer 'x' for which the graph of (4) 0
y = ƒ(x) – g(x) increases is
Codes :
P Q R S
(A) 3 4 1 2
(B) 3 4 2 1
(C) 3 2 4 1
(D) 4 3 2 1
1001CT102116013 E-35/40
MATHEMATICS
2x 
14. Consider the function ƒ  x   sin 1  2 
, then match List-I with List-II and select the correct
1  x 
answer using the code given below the list.
List-I List-II
(P) ƒ'(0) is equal to (1) 5
(Q) if 'n' be the number of critical points on the (2) 0
graph of ƒ(x) then (n + 2) is equal to
(R) number of positive integers where the graph of ƒ(x) (3) 4
is increasing
(S) number of points in [–10,10] where [ƒ(x)] is (4) 2
discontinuous (where [.] greatest integer function)
Codes :
P Q R S
(A) 4 1 2 3
(B) 4 2 1 3
(C) 4 3 2 1
(D) 3 4 1 2
E-36/40 1001CT102116013
MATHEMATICS
 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive.
2
 2x 3x if
1. Given ƒ  x    e x  0 . If ƒ(x) is differentiable at x = 0, then (q – 2p) is equal to
px  q if x0
n
 1
(where e  lim 1   )
n 
 n
2 sin x
e cos x  2I 
2. Given I  e sin x  sin x
dx , then   , is equal to (where [.] denotes greatest integer function)
0 e 
3. Let {Cn} be an infinite sequence of circles lying in the positive quadrant of the xy-plane, with
strictly decreasing radii and satisfying the following conditions. Each Cn touches both the
x-axis and y-axis. Further for all n > 1, the circle Cn+1 touches the circle Cn externally. If C1
m2  mn
has radius 10 c.m. and the sum of areas of all these circles is sq. c.m. then  
n 2 4 mn
is equal to (where m,n  N)
1001CT102116013 E-37/40
MATHEMATICS
2
4. For any real number 'a' let ƒ(a) denotes the maximum of the function sin x  a
3  sin x
 x R. If 'm' be the minimum value of ƒ(a), then '4m' is equal to
n
k
5. lim 
n 
k 1
 n2

ek  1 .sin
n
is equal to
6. Let ƒ : [0,1]  R be a continuous function with the property that xƒ  y   yƒ  x   1x,y  0,1 .
1

If maximum value of  ƒ  x  dx
0
is
k
, then 'k' is equal to
E-38/40 1001CT102116013
1001CT102116013 E-39/40
QUESTION PAPER FORMAT AND MARKING SCHEME :
16. The question paper has three parts : Physics, Chemistry and Mathematics.
17. Each part has two sections as detailed in the following table.
Que. No. Category-wise Marks for Each Question Maximum
Section Type of Full Partial Zero Negative Marks of the
Que. Marks Marks Marks Marks section
+4 +1 0 –2
One or more If only the bubble(s) For darkening a bubble If none In all
I(i) correct corresponding corresponding to each of the other
option(s) 6 to all the correct correct option, provided bubbles is cases 24
option(s) is(are) NO incorrect option darkened
darkened darkened
Paragraph +4 +1 0 –2
Based If only the bubble(s) For darkening a bubble If none In all
I(ii) (One or more 4 corresponding to all corresponding to each of the other 16
correct the correct option(s) correct option, provided bubbles is cases
option(s)) is(are) darkened NO incorrect option darkened
darkened
Matching +3 0 –1
Lists Type If only the bubble If none In all
I(iii) (Single 4 corresponding to — of the other 12
correct the correct option bubbles is cases
option) is darkened darkened
+4 0
Single digit If only the bubble In all
IV Integer 6 corresponding — other — 24
(0-9) to correct answer cases
is darkened
NAME OF THE CANDIDATE ................................................................................................
FORM NO. .............................................
I have read all the instructions I have verified the identity, name and Form
and shall abide by them. number of the candidate, and that question
paper and ORS codes are the same.
____________________________ ____________________________
Signature of the Candidate Signature of the invigilator
Corporate Office :  CAREER INSTITUTE, “SANKALP”, CP-6, Indra Vihar, Kota (Rajasthan)-324005
+91-744-5156100 info@allen.ac.in www.allen.ac.in
E-40/40 Your Target is to secure Good Rank in JEE 2017 1001CT102116013
Paper Code : 1001CT102116013
CLASSROOM CONTACT PROGRAMME

HINDI
(Academic Session : 2016 - 2017)
JEE (Main + Advanced) : ENTHUSIAST COURSE

PHASE : I
Test Type : MINOR Test Pattern : JEE-Advanced
TEST DATE : 24 - 07 - 2016
Time : 3 Hours PAPER – 1 Maximum Marks : 228


1. 
2. 
(ORS) 
3. 
4. 
5. 
40 
20 



6. 


7. 
8. 

9. 



:
10. 


11.  


12. 

:
13. 
14. 

15. g = 10 m/s2 
           
SOME USEFUL CONSTANTS

Atomic No. H = 1, B = 5, C = 6, N = 7, O = 8, F = 9, Al = 13, P = 15, S = 16,
Cl = 17, Br = 35, Xe = 54, Ce = 58,
Atomic masses : H = 1, Li = 7, B = 11, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24,
Al = 27, P = 31, S = 32, Cl = 35.5, Ca=40, Fe = 56, Br = 80, I = 127,
Xe = 131, Ba=137, Ce = 140,
 Boltzmann constant k = 1.38 × 10–23 JK–1
1
 Coulomb's law constant = 9 ×10 9
4 0
 Universal gravitational constant G = 6.67259 × 10–11 N–m2 kg–2
 Speed of light in vacuum c = 3 × 108 ms–1
 Stefan–Boltzmann constant  = 5.67 × 10–8 Wm–2 –K–4
 Wien's displacement law constant b = 2.89 × 10–3 m–K
 Permeability of vacuum µ0 = 4 × 10–7 NA–2
1
 Permittivity of vacuum 0 =
0 c2
 Planck constant h = 6.63 × 10–34 J–s

H-2/40 1001CT102116013
HAVE CONTROL  HAVE PATIENCE  HAVE CONFIDENCE  100% SUCCESS
PHYSICS
BEWARE OF NEGATIVE MARKING

-1 :  
–I(i) : ( : 24)
   
  
   
  
(A), (B), (C)  (D)   
      
               
       
 

   
 : +4            
 : +1              
  
 : 0         
  : –2    
          
(A), (C)  (D)       
+4  (A)
   
(D)     +2 
 
(A) 
(B)     –2       
     
1. R0 

2
  r 

r F  F0   rˆ 
:-
 R0 
y
v0
R0
x
v
(A) 
(B) 
16F0
(C) 

3
16F0 R0
(D) 
v 20  
3m

1001CT102116013 H-3/40
2. 
m 
R 
v 
PHYSICS
 t = 0 
t 

v v
R
x
2
v  vt 
(A) 
 sin   ˆj 
R R
2mv 2  vt 
(B) 
 sin   ˆj 
R R
2
mv   vt   vt  
(C)  cos   iˆ  sin   ˆj  
R  R R 
2
mv   vt   vt  
(D) 
–  cos   iˆ  sin   ˆj  
R  R R 

H-4/40 1001CT102116013
3. 
 
d 
d 

PHYSICS

+Q0 –Q0 
, 


d 
x 

  

x
 d
Q20d    x 
(A) x 
 23   
0
Q20d
(B) 
 3    0
(C) 
d 
Q20
 2 4
0  
Q20
(D) 
Q0, 
, d 
0  
24   0 

1001CT102116013 H-5/40
4. 
PHYSICS
(A) 

   q 2
(B) 
E 
p  E 
 
2a 
4 0  2a
dy Ey
(C) x-y 
 
dx Ex
(D) 

5. 
L 
(a) 
(b) 

B

a R

A B A

Figure (a) stationary conducting
circular frame
Figure (b)
(A) (a) 

VA 
VB 
A  B 
VA < VB 
(B) (b) 
VA 
VB 
A  B 
VA > VB 
ma
(C) (a) 

e
m2 r
(D) (b) 

e

H-6/40 1001CT102116013
6. 
t = 0 
PHYSICS

(
 = 24V, C1 = 3F C2 = 2F)
3
 9 C1
S
C2 6
(A) 
C1 
12V 
(B) 
C1 
12V 
(C) 
C2 
24V 
(D) 
C2 
8V 

1001CT102116013 H-7/40
–I(ii) : ( : 16)
PHYSICS
   


  
   
 
   
   
 (A), (B), (C) (D)   
      
               
         

   
 : +4            
  : +1              
  
 : 0         
  : –2    
          
(A), (C)  (D)       
  
+4  (A) 

(D)     +2 
 
(A) (B)     –2        
     
7 8   




Magnetotactic Bacteria 

 B =  – z
   z 
 ( ) 

M 



M 
 
d 
 kT k T 


H-8/40 1001CT102116013
7. Magnetotactic bacteria 
:-
PHYSICS
(A) 

(B) 

(C) 

(D) 

8. 
(A) 

 0 16M2
(B) 

4 d3
(C) 
2M 
2kTd 3
(D) 

0

1001CT102116013 H-9/40
9 10   
PHYSICS
L 
m 
Q 

L/4

E E
Pivot Pivot
L/4 3L/4 3L/4 L/4
E E
Figure (A) Figure (B)
9. 
(A) (A) 
(B) (B) 
9QEL
(C) 
3L/4 
5m
QEL
(D) 
L/4 

5m
10. 
3QELsin 
(A) 
  
2
QEL sin 
(B) 
 
2
5mL
(C) 
 
 
4QE
5mL
(D) 
 
 
QE

H-10/40 1001CT102116013
–I(iii) : (  : 12)
PHYSICS
     
 
(A), (B), (C) 
(D)  

 
 
   :
 : +3           
 : 0         
  : –1    
11.  -I 
-II 
P 


-I ( )  -II (P 
)
(P) P Q (1) V  0, E  0

Q 
Q q
(Q) P (2) V = 0, E = 0
q
+ Q 

(R) (3) E  0, v = 0

Q
(S)
P (4) E = 0, V  0


Codes :
P Q R S
(A) 4 2 1 4
(B) 2 1 3 4
(C) 3 2 4 1
(D) 4 3 2 1

1001CT102116013 H-11/40
12. 
-I 
-II 
PHYSICS
 -I () 

-II (
)
E B
× ×
(P) × × (1) (
)
× ×
q

q 


q × ×B
(Q) × × E (2) (
)
× ×
 

B 
E 


E
B q
(R) (3) (
)
 

E 
B 
E 

B
v
(S) q (4) (
)


Codes :
P Q R S
(A) 2 1 4 3
(B) 3 1 4 2
(C) 4 2 1 3
(D) 3 1 2 4

H-12/40 1001CT102116013
13. 
-I 
-II 
A B 
PHYSICS
–I –II
2R 2R
R R
(P) A B (1) R/2
R R
2R 2R
R/2
2R R
2R
(Q) R/2 (2) R/3
R R
R
A B
R
R R
(R) (3) 2R/3
R
R
B
A
R
R C
R R R R
(S) (4) 2R
A R B
Codes :
P Q R S
(A) 3 1 4 2
(B) 2 1 4 2
(C) 3 1 4 1
(D) 2 1 4 3

1001CT102116013 H-13/40
14. U
1
, 
u V 
1
F1, 
PHYSICS
E1 
V1 
r 
U2, u V ,F2, E2 
2
V2 

–I 
–II
uv1
(P) u  (1) 1 : 1
v2
U1
(Q) U (2) 2r :1
2
V2
(R) V (3) r : 1
1
F1
(S) F (4) 1 : r
2
Codes :
P Q R S
(A) 4 2 3 1
(B) 3 2 4 1
(C) 3 2 1 4
(D) 3 3 4 1

–II :  &    –III :   

II III 
H-14/40 1001CT102116013
–IV : ( : 24)
PHYSICS
   
   
    
0 9      

 
 
             
       
 

   
 : +4           
  : 0    
1. m = 10 g 
L = 0.2 m 
 = 1 cm 
B
100V 
C = 100 µF 

(
37°

B
L


1001CT102116013 H-15/40
2. 8 
120° 
PHYSICS

i 
a 
 i 3

0

x 
4xa
Inward current
Outward current Topview
Loop A
60°
60°
Loop B
3. 
y-
8 A 
–y 

1.4 × 10–6 T î 
(1, 1, 1) 
a

a × 10–7 T 

2

H-16/40 1001CT102116013
4. 
A B 
R0 
C 
fR0
PHYSICS

(1 – f)R0 
0 < f < 1 

f 
12f 
r
E E
A
fR0 (1 – f)R0
A B
C
5. 
20
R

R2 (
) 
?
2

20
60V
V
R2 R3
R1
0.5A
A V
90V
120V, 20

1001CT102116013 H-17/40
6. 
R 
J 
PHYSICS

a 
b 
z-   
x = 
b 
y  y = 2R 
x 
1 a2 
 JR
Bx = 0   2 2  
|A| + |B| 
 A BR  b 
y
iin R
a
x
O C
b

H-18/40 1001CT102116013

-2 :  
CHEMISTRY
–I(i) : ( : 24)
   
  
   
  
(A), (B), (C)  (D)  

      
               
       
 

   
 : +4            
 
: +1              
  
 : 0         
  : –2    
          
(A), (C) 
(D)       
  
+4  (A) 

(D)     +2
 
(A)
(B)     –2
      
     
1.   
- 
(A)  
(B)    

(C)   
(D)    
2.  
(A)  
0 50% 
't' 
 
50 75%  
't/2' 

(B) 
0 10% 
't' 
10 20%  't'

(C) 
0 50% 
't' 
50 75 % 
't/2' 
(D) 
0 10% 
't' 
10 20 %  't'


1001CT102116013 H-19/40
3.       ?  

CHEMISTRY
(A) [Fe(CN)6]–3 (B) [Ni(en)3]+2 (C) [Fe(OH2)6]+2 (D) [NiF6]–2
4.     [Co(H

2O)3F3]0    :- 
(A)     
(B)    
d2sp3 
(C)     

(D)    H
2
O

 
5. 
CN CHO
(i) SnCl2 / HCl (i) Mg / Dry ether
(A) + (B) Ph–I Ph–COOH
(ii) H3O (ii) CO2
+
(iii)H
O
Zn / Hg (i) B2H6
(C) (D) (ii) H3O
+
HCl
COOH CH 2OH
6. 
O OH
C CHO MeMgCl
Cl H2–Pd
(A) BaSO4
(B) O Cl
O
(i) Mg-Hg 1 % HgSO4
(C) (ii) H2O
(D)
dil. H2SO4
O

H-20/40 1001CT102116013
–I(ii) : ( : 16)
CHEMISTRY
   

  
   
 
   
   
 (A), (B), (C) (D)  

      
               
       
 

   
 : +4            
 
: +1              
  
 : 0         
  : –2    
          
(A), (C) 
(D)       
  
+4  (A) 

(D)     +2
 
(A)
(B)     –2
       
     
7 8   
      
     
~109°     


            
 
7.    
? 
(A) [PtBrCl(NH3)(Py)] (B) [Co(Gly)3]
(C) [Co(NH3)3(NO2)3] (D) [Co(EDTA)]–1
8.              
(A) [PtCl2(NH3)2(Py)2]+2 (B) [CoCl2(en)2]
(C) [CrCl2(en)(NH3)2] (D) [PtCl2(NH3)(NO2)BrI]0

1001CT102116013 H-21/40
9 10   

CHEMISTRY

Br2 Mg P Na S NaI
CH3–CH3 P Q R T

hv Et2O Et2O 
9. 
(A) (S) , CH3–CH2–CH2–Br  (B) (Q) 
(C) (R) , n- (D) (P) , CH3–CH2–Br 
10. 
(A)  (B) 
(C)  (D) 


H-22/40 1001CT102116013
–I(iii) : (  : 12)
CHEMISTRY
   
  
 
(A), (B), (C) 
(D)  

 
 
   :
 : +3           
 : 0         
  : –1    
11.  A + B  
, [A]0 = [B]0
-I (  
) - 
-II ()
Conc.
(P) r = k[A] (1)

[A]
Time
t1/2
(Q) r = k[A]1/2[B]1/2 (2)

[A]0
ln t1/2
(R) r = k[A] [B] (3) 135º

ln[A]0
ln[A]t
(S) r = k[A]0 [B]0 (4)

Time
Codes :
P Q R S
(A) 4 1 3 2
(B) 2 3 1 4
(C) 1 2 3 4
(D) 4 3 2 1

1001CT102116013 H-23/40
12. 
-I (
) 
-II ( 
)
CHEMISTRY
(P) [Ni(CN)4]–2 (1) 
(Q) [Fe(H2O)5NO]+2 (2) sp3d2 
(R) [Co(CO)4] (3)  = 0
(S) [NiCl2(NH3)2]0 (4)  

Codes :
P Q R S
(A) 4 2 3 1
(B) 3 2 1 4
(C) 1 2 3 4
(D) 3 1 4 2

H-24/40 1001CT102116013
13. 
-I 
-II 
CHEMISTRY

-I 
-II
SOCl2
(P) CH3–CH2–OH (1) 
AgF
(Q) CH3–CH2–Br
DMF
(2) 
(R) CH3–CH2–Br CH 3–CH2ONa (3) 
(S) Ph–CH2–OH HCl

anhyd. ZnCl2
(4) 
Codes :
P Q R S
(A) 4 1 3 2
(B) 3 1 4 2
(C) 3 2 4 1
(D) 3 1 2 4

1001CT102116013 H-25/40
14. 
-I 
-II
CHEMISTRY
 
O
(P) (1) (i) D2 (1 eq.) / Pt ; (ii) H2 (1 eq.) / Pt
D
(Q) (2) (i) H2 (1 eq.) / Pt ; (ii) D2 (1 eq.) / Pt
D
D
SH
H ; (ii) 
+
(R) D (3) (i) HS Ni / H2
O
(S) (4) (i) N2H4 / H2O2 ; (ii) LiAlH4 ; (iii) H+ / 
Codes :
P Q R S
(A) 4 2 1 3
(B) 3 1 2 4
(C) 4 1 2 3
(D) 3 2 1 4

–II :   &      –III :    

II III 
H-26/40 1001CT102116013
–IV : ( : 24)
CHEMISTRY
   
  
    
0 9      

 
 
             
       
 

   
 : +4           
 : 0    
1.  
8th 


   
(
   
)         

2. 300 K 1 
mol He  , T = kV2   
|w| (cal 
) 
   

(
   
)         

3. 
4 
67ºC  
Ea
, 23.8 kcal/ mol 
77ºC  
?
2.303
[R = 2cal /k/mol]
   

(
   
)         


1001CT102116013 H-27/40
4.              
CHEMISTRY
[NiCl4]–2, [PtCl4]–2, [IrF6]–3, [Ag(NH3)2]+, [Fe(H2O)6]+2, [Co(H2O)6]+3
5.       [CoCl(NH

  2)]Cl    
) (NO
3 4
 
:-

, 
, , 
, 
, 

6. 
CH2CH 3
Br2 (1.0 mole)
H Br
300ºC
CH3
(1.0 mole)
(enantiomerically pure)

H-28/40 1001CT102116013

-3 : 
MATHEMATICS
–I(i) : ( : 24)
   
  
   
  
(A), (B), (C)  (D)   
      
               
       
 

   
 : +4            
 : +1              
  
 : 0         
  : –2    
          
(A), (C)  (D)       
+4  (A)
   
(D)     +2 
 
(A) 
(B)     –2       
     
1. 
P  2 2,0  
x +y 2 2
=4 
PA 
PB 
-
(A) 
PAB 
2 
(B) 
PAB 
4 

(C) APB 
2

(D) APB 
3
2.  x2 + y2 = 4 
1, 3   
x 
y 
p
q 
-
4
(A) p = 4 (B) p  (C) p  3q  0 (D) p2 + q2 = 32
3
a 1 d
3.  r   
r e sin   ƒ cos 

a,b,c,d,e,ƒ
b sin   c cos 
y

x2 + y2 = r2 
tan   
x
(A) 0 (B) 1 (C) 2 (D) 3

1001CT102116013 H-29/40
MATHEMATICS
4. 
x
 
(A) 
[0,)  ƒ 
lim  ƒ  x    ƒ  t  dt  
lim ƒ  x   0 
x  x 
 0 
ƒ x 
(B) 
R  ƒ 
lim 
x 0 x2

ƒ'(0) = 0 
1
(C) ƒ :  x1 ,x 2    1 ,2       
ƒ  x1   
ƒ(x 2 ) = 2  
2  2
 
 2  1 
ƒ   ,2 
 1  1   2 
x 
 1 x2 
(D) 
ƒ:RR 
lim ƒ  x   1 
x 
5. ƒ : [0,1]  R 

ƒ(0) = 0 
ƒ'(1) > 0 
(A) ƒ(1) > ƒ'(1) (B) ƒ(1) < ƒ'(1)

1
1 ƒ 1 
(C)  1  ƒ  x  dx  ƒ ' 1
2 (D) [0, 1]  ƒ(x) 
0
x   x  
  1
6. ƒ x       x   x  2   dx  dx 
(
[.] 
) 
ƒ(x) 
0  0 

-
1
(A) x = 1 (B) x = 0 (C) x  n  ,  n  I (D) x = 2
2

H-30/40 1001CT102116013
–I(ii) : ( : 16)
MATHEMATICS
   

  
   
 
   
  

 (A), (B), (C) (D)   
      
               
        

   
 : +4            
 : +1              
  
 : 0         
  : –2    
   (A), (C) 
(D)  
+4 (A) 

(D) +2 (A)

(B) 
–2 
  
7 8   
 
sin 2x  0x
6
ƒ  x    

ax  b   x 1
 6
7. ƒ(x) 
ƒ'(x) 
'a' 
-
3
(A) 0 (B) 1 (C) (D) 2
2
8. ƒ'(x) 
 
(A) x =  ƒ(x) 
(B) x =  ƒ(x) 
6 6
3 3
(C) a = 1 (D) b 
6

1001CT102116013 H-31/40
9 10   

MATHEMATICS

C1 : x2 – 2x + y2 – 3 = 0C2 : x2 + 2x + y2 – 3 = 0 
'P', xy-

PA, PB 
C1 C2 
P 

9. C1 
C2 
-
  2 
(A) (B) (C) (D)
2 3 3 6
10. 
(A) C1 
C2 
(B) C1 
C2 
2 3 
(C) P 

(0,) 
PA2 – PB2,  (  R) 
(D) C1 
C2 
2 

H-32/40 1001CT102116013
–I(iii) : (  :
MATHEMATICS
12)
   
  
 
(A), (B), (C) 
(D)  

 
 
  :
 : +3           
 : 0         
  : –1    
11. 
-I  
-II               

-I 
-II
(P) ƒ(x)  ƒ(1 + x) = ƒ(1 – x)  x R (1) 1

ƒ'(1) 
 1  x2 
(Q)  ƒ  x   cos 
1
2 
 
ƒ'(x) < 0  x  (2) 0
1  x 
(R) ƒ : R  R       (3) –2
ƒ'(1) = 2 
ƒ(0) + ƒ"(0) + ƒ'(–1) 
(S) 
ƒ(x) = sgnx, g  x   1  x 2  (4) 2
  ƒ  g  x   dx  Ax  B  

A  
(
sgnx     ) 
Codes :
P Q R S
(A) 2 3 4 1
(B) 2 4 3 1
(C) 3 2 4 1
(D) 3 1 2 4

1001CT102116013 H-33/40

-I  
-II               
MATHEMATICS
12.
-I -II
(P)  ƒ(x) = x2 + 1    
x-   (1) 2
    
(–1,2) (0,1)  
   
(Q) ƒ(x) = (x – 1) |x – 2| + (x – 2) |x – 1|  (2) 1
    
(R) x        (3) 2  
ƒ(x) = (2x – 1).(2x – 3)  
1
(S) A(x) = {|x|, x2 – 1, x2 + x + 1, n|x|}  (4) 
2

A(x) 
[–1, 1] 

Codes :
P Q R S
(A) 4 3 2 1
(B) 3 4 2 1
(C) 4 3 1 2
(D) 3 4 1 2

H-34/40 1001CT102116013
MATHEMATICS
n x
13.   
 dx  A 1  nƒ  x   g  x   2   C (
C,    
g(1) = 0) 
x 1  n|x|
 
-I  
-II                
-I 
-II
(P) A   (1) 2
|sin x|
(Q) lim     (2) 1
 ƒ  x  
x 0
(
[.]    )  
2
(R)  y = g(x)        
(3)
3
x    

(S)   
'x',   y = ƒ(x) – g(x)  (4) 0
   
Codes :
P Q R S
(A) 3 4 1 2
(B) 3 4 2 1
(C) 3 2 4 1
(D) 4 3 2 1

1001CT102116013 H-35/40
MATHEMATICS
2x 
14.  
ƒ  x   sin 1  2 

-I 
-II
1  x 
      

-I 
-II
(P) ƒ'(0)   (1) 5
(Q)  'n', ƒ(x)        
(2) 0

(n + 2)  
(R) 
ƒ(x) 
(3) 4
(S)    
[–10,10] [ƒ(x)]
  (4) 2

(
[.]   
) 
Codes :
P Q R S
(A) 4 1 2 3
(B) 4 2 1 3
(C) 4 3 2 1
(D) 3 4 1 2

–II :   &      –III :    

II III 
H-36/40 1001CT102116013
–IV : ( :
MATHEMATICS
24)
   
   
    
0 9      

 
 
             
       
 


   
  : +4           
  : 0    
 x  0
2
 e2x 3x
1. 
ƒ x    
ƒ(x), x = 0 
(q – 2p) 
 px  q  x0
n
 1
(e  lim 1   )
n 
 n 
2 sin x
e cos x  2I 
2. 
I  sin x  sin x
dx 
  
(
[.] 
)
0 e e 
3. 
{Cn}, xy-
    Cn,
x- 

y-      
n > 1
Cn+1, 
Cn 
C1 
10 
2
 m   m  n  
 
  (
m,n  N)
n 2 4 mn

1001CT102116013 H-37/40
MATHEMATICS
2
4. 
'a' 
ƒ(a),  sin x   a  x R 
3  sin x

'm', ƒ(a) 
'4m'  
n
k
5. lim 
n 
k 1
 n2

ek  1 .sin
n

6. 
ƒ : [0,1]  R 
xƒ  y   yƒ  x   1, x,y   0,1 
 ƒ  x  dx  0

k 
'k' 

H-38/40 1001CT102116013

1001CT102116013 H-39/40

16. 
17. 
    
       
 
 +4 +1 0 –2
I(i)     
 6    24
   
  
 +4 +1 0 –2
I(ii)     
 4    16
    
   
I(iii)  +3 0 –1
  —  
4 12
   
   
 +4 0
IV   
—
(0-9)
6
  — 24
 
  

................................................................................................
 
.............................................

       
 
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5.24!07!2016 J (A) Minor Test Paper 1

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5.24!07!2016 J (A) Minor Test Paper 1

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Paper Code : 100 1CT1021 16013

CLASSROOM CONTACT PROGRAMME

JEE (Main + Advanced) : ENTHUSIAST COURSE

READ THE INSTRUCTIONS CAREFULLY

DO NOT BREAK THE SEALS WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR

OPTICAL RESPONSE SHEET :

11. Darken the bubble COMPLETELY.

12. The correct way of darkening a bubble is as :

SOME USEFUL CONSTANTS

 Boltzmann constant k = 1.38 × 10–23 JK–1

(A) Given external force is a central force.

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(A) The voltage across C1 before the switch is open is 12V.

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 This section contains TWO paragraphs.

L/4 3L/4 3L/4 L/4

9. Mark the CORRECT statement(s) :-

Conducting shell of charge Q

Cavity in an earthed conductor of

A uniformly charged dielectric sphere

Concentric spherical Cavity in a

List-I (Systems) List-II (Paths of charge particles)

The charge is projected perpendicular to

Space for Rough Work

Space for Rough Work

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(A) [Fe(CN)6]–3 (B) [Ni(en)3]+2 (C) [Fe(OH2)6]+2 (D) [NiF6]–2

6. Select the reaction(s) correctly match with their major product :

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For the following sequence :

9. Choose the correct option(s) ?

(A) (S) can be CH3–CH2–CH2–Br (B) (Q) is known as grignard reagent

(C) (R) is n-hexane (D) (P) is CH3–CH2–Br

(A) Wurtz fittig reaction (B) Nucleophilic substitution

(C) Free radical substitution (D) Finkelstein reaction

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(P) r = k[A] (1)

(Q) r = k[A]1/2[B]1/2 (2)

(R) r = k[A] [B] (3) 135º

(S) r = k[A]0 [B]0 (4)

12. List-I (Complexes) List-II (Correct characteristics)

(P) [Ni(CN)4]–2 (1) Tetrahedral

(Q) [Fe(H2O)5NO]+2 (2) sp3d2 hybridisation

(R) [Co(CO)4] (3)  = 0

(S) [NiCl2(NH3)2]0 (4) Sq. planar

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(R) CH3–CH2–Br CH 3–CH2ONa (3) Darzen process

(S) Ph–CH2–OH HCl (4) Williamson ether synthesis

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(Reaction with major product) (Reagents)

(P) (1) (i) D2 (1 eq.) / Pt ; (ii) H2 (1 eq.) / Pt

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Zero Marks : 0 In all other cases.

if electron present in 8th excited state -

Calculate |w| ( in cal) during the process.

77ºC ? [R = 2cal /k/mol]

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4. Find the number of complexes which are paramagnetic in nature.

[NiCl4]–2, [PtCl4]–2, [IrF6]–3, [Ag(NH3)2]+, [Fe(H2O)6]+2, [Co(H2O)6]+3

Coordination isomerism, Linkage isomerism, Ionization isomerism, Geometrical isomerism,

Ligand isomerism, Optical isomerism.

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(A) Area of circumcircle of PAB is 2