The question number from NEET exam are Underlined.

Below that are the reference numbers from KONALE’s

Complete Chemistry Vol-I & Vol-II along with question.

NEET - 2018 03. Which of the following oxides is most acidic

in nature ?
Set - PP (1) MgO (2) BeO
(3) BaO (4) CaO
01. A mixture of 2.3 g formic acid and 4.5 g  [Test Paper - Periodic Table &
oxalic acid is treated with conc. H2SO4. Halogen derivatives - 08-11-2017
The evolved gaseous mixture is passed Q.no - 12]
through KOH pellets. Weight (in g) of the 12. Which of the following oxides is most acidic
remaining product at STP will be in nature ?
(1) 4.4 (2) 2.8 a) BeO b) MgO c) CaO d) BaO
(3) 3.0 (4) 1.4  [Vol-1 Page No. 164 Q no. 63 similar]
 [Vol - 1 page- 16 Q.no 95 similar
concept based]
95. 1 mole of mixture of CO and CO2 requires 04. The difference between amylose and
exactly 28 g KOH in solution for complete amylopectin is
conversion of all the CO2 into K2CO3. (1) Amylopectin have 1  4 -linkage and
How much amount more of KOH will be 1  6 -linkage
required for conversion into K2CO3. If (2) Amylose have 1  4 -linkage and
one mole of mixture is completely oxidized 1  6 -linkage
to CO2 (3) Amylopectin have 1  4 -linkage and
a) 112 g b) 84 g 1  6 -linkage
c) 56 g d) 28 g (4) Amylose is made up of glucose and
galactose
 [Proper structure & Explanation is given
in class notes]
02. Nitration of aniline in strong acidic medium
also gives m-nitroaniline because
(1) In spite of substituents nitro group 05. Regarding cross-linked or network polymers,
always goes to only m-position. which of the following statements is
(2) In electrophilic substitution reactions incorrect ?
amino group is meta directive. (1) They contain covalent bonds between
(3) In absence of substituents nitro group various linear polymer chains.
always goes to m-position (2) They are formed from bi-and
(4) In acidic (strong) medium aniline is tri-functional monomers.
present as anilinium ion. (3) Examples are bakelite and melamine.
 (Test Paper - Compounds Containing (4) They contain strong covalent bonds in
Nitrogen - 29-04-2017 Q.no 27 As it is) their polymer chains.

KONALE COACHING CLASSES 1

06. In the reaction
OH
+ CHCl3 + NaOH 

the electrophile involved is
(1) dichloromethyl cation (CHCl2)
(2) formyl cation (CHO)
(3) dichloromethyl anion (CHCl2)
(4) dichlorocarbene (: CCl2)
 [Test Paper - Alcohol, Phenol, Ethers
17-07-2017 Star Batch Q. no 34]
[Vol - 1 Page no. 243 Q. no - 16]
[Vol - 2 Page no . 269 Q.no 87]
[Vol - 2 Page no . 273 Q.no 156]
OH
156. + CHCl3 + NaOH 

The electrophile involved in the above
reaction is
 (1) H3C
a) trichloromethyl anion (C Cl3 )

b) formyl cation (CHO)

c) dichloromethyl cation (CH Cl2 )
d) dichlorocarbene (: CCl2)
KONALE COACHING CLASSES
07. Carboxylic acid have higher boiling points
than aldehydes, ketones and even alcohols
O-Na+ of comparable molecular mass. It is due to
CHO their
(1) formation of intramolecular H-bonding
(2) formation of carboxylate ion
(3) more extensive association of carboxylic
acid via van der Waals force of attraction
(4) formation of intermolecular H-bonding.
 [Vol - 2 Page no. 302 Explanation given
under the heading general properties as
“Boiling points of acids increase regularly
with mol. wt. and higher than alcohols (of
comparable mol-mass) due to formation of
dimer through H-bonding”
Vol - 2 Page no. 310 Q.No. 11 Similar Type
of Question
O-Na+
CHO 08. Compound A, C8H10O, is found to react
with NaOI (produced by reacting Y with
NaOH) and yields a yellow precipitate with
characteristic smell.
A and Y are respectively.
CH2 - OH and I2
(2) CH2 - CH2 - OH and I2
CH - CH3 and I2
(3)
OH
CH3
(4) CH3 OH and I2
 [Vol-2 Page no. 290 Q. no. 36,37,38,39
Similar type of question]
2
09. The correct difference between first- and 11. Consider the change in oxidation state of
second-order reaction is that Bromine corresponding to different emf
(1) the rate of a first-order reaction does not values as shown in the diagram below:
depend on reactant concentration; the rate of
- -
a second order reaction does depend on 1.82V
BrO 4  1.5V
 BrO 3   HBrO
reactant concentrations.
(2) the half-life of a first-order reaction does Br - 
1.0652V
Br2 
1.595V

not depend on [A]0; the half-life of a Then the species undergoing
second-order reaction does depend on [A]0 disproportionation is:-
(3) a first-order reaction can be catalyzed; (1) BrO3- (2) BrO-4
a second-order reaction cannot be catalyzed. (3) Br2 (4) HBrO
(4) the rate of a first-order reaction does
depend on reactant concentrations; the rate
of a second-order reaction does not depend
on reactant concentrations 12. In which case is the number of molecules of
 [Vol - 2 Page No. 103,104 combination water maximum ?
Q.No. 28 & 33] (1) 18 mL of water
28. For a first-order reaction, the half life period (2) 0.18 g of water
is independent of (3) 0.00224 L of water vapours at 1 atm and
(a) initial concentration 273 K
(b) cube root of initial concentration (4) 10-3 mol of water
(c) first power of final concentration  [Test Paper - Some Basic Concepts of
(d) square root of final concentration Chemistry & Atomic Structure
33. Which of the following is correct for a first 14-03-18 Q.no. 31]
order reaction? 31. The number of water molecules present in a
(a) t1/2  a (b) t1/2  1/a drop of water weighing 0.018 g is
a) 6.022 x 1026 b) 6.022 x 1023
(c) t1/2  a0 (d) t1/2  1/a2
c) 6.022 x 1019 d) 6.022 x 1020
 (Test Paper - 21-02-2018 Q. no 22)
22. The Number of Water molecule is
maximum in
a) 18 molecules of water
10. Among CaH2, BeH2, BaH2, the order of
b) 1.8 g of water
ionic character is
c) 18 g of water
(1) BeH2 < CaH2 < BaH2
d) 18 moles of water
(2) CaH2 < BeH2 < BaH2
 [Test Paper - Some Basic Concepts &
(3) BeH2 < BaH2 < CaH2
Atomic Structure 24-08-2016
(4) BaH2 < BeH2 < CaH2
Q no. 31 similar]
 [Vol-1 Page no. 156 Proper Explanations is
given under the heading reaction with H2]

KONALE COACHING CLASSES 3

13. Magnesium reacts with an element (X) to 15. Which one is a wrong statement ?
form an ionic compound. If the ground state (1) Total orbital angular momentum of
electronic configuration of (X) is 1s2 2s2 electron in ‘s’ orbital is equal to zero
2p3, the simplest formula for this compound (2) An orbital is designated by three quantum
is numbers while an electron in an atom is
(1) Mg2X3 (2) MgX2 designated by four quantum numbers.
(3) Mg2X (4) Mg3X2 (3) The electronic configuration of N atom is
 [Test Paper - Periodic Table & NCB 1 1
1s 2 2px 2 p y1 2 p z
16-03-2018 Q.no 15] 2s 2

15. Predict the formulae of the binary     

compounds formed by combination of the (4) The value of m for dz2 is zero
following pairs of elements :  [Vol-1 Page No. 41 A single line is given
(i) Magnesium and nitrogen under the heading Hund’s rule of maximum
(ii) Silicon and oxygen multiplicity as “singly occupied orbitals
a) MgN2, SiO2 b) Mg3N2, SiO2 should have same spins of electrons giving
c) Mg2N3, Si2O3 d) MgN, SiO2 rise to lower energies”]
[Vol-1 Page no. 61 Q no. 74 & 81 Similar]

14. Iron exhibits bcc structure at room 16. Consider the following species :
temperature. Above 900°C, it transforms to CN+, CN-, NO and CN
fcc structure. The ratio of density of iron at Which one of these will have the highest
room temperature to that at 900°C (assuming bond order ?
molar mass and atomic radii of iron remains (1) NO (2) CN-
constant with temperature) is (3) CN+ (4) CN
3 4 3 3 3 1  [Vol-1 Page no. 118 Bond order values of
(1) (2) (3) (4) different species is given in table form]
2 3 2 4 2 2
 [Vol. - 2 Page no. 14 Q. no 26]
26. A metal crystallises into two cubic phases,
17. Which of the following statements is not true
face-centred cubic (f. c. c.) and body-centred
for halogens ?
cubic (b. c. c.) whose unit cell lengths are 3.5
o o (1) All form monobasic oxyacids.
A and 3.0 A, respectively. Calculate the ratio
(2) All are oxidizing agents.
of densities of f.c.c. and b. c. c.
(3) All but fluorine show positive oxidation
 [Page no. 20 Q.no 97 similar]
states.
97. A metal crystallizes in 2 cubic phases fcc and
o (4) Chlorine has the highest electron-gain
bcc whose unit cell lengths are 3.5 A and
o enthalpy.
3.0A respectively. The ratio of their
densities is
(a) 0.72 (b) 2.04
(c) 1.46 (d) 3.12

KONALE COACHING CLASSES 4

18. Which one of the following elements is 21. The correct order of atomic radii in group 13
unable to form MF63- ion ? elements is
(1) Ga (2) AI (3) B (4) In (1) B < Al < In < Ga < Tl
 [Test Paper - p-Block Elements (2) B < Al < Ga < In < Tl
19-01-2018 Q. no 35] (3) B < Ga < Al < Tl < In
35. The exhibition of highest co-ordination (4) B < Ga < Al < In < Tl
number depends on the availability of vacant  [Test Paper - Special Final Round - 06
orbitals in the central atom. Which of the 21-04-2018 Q. no 17]
following elements is not likely to act as 17. The increasing order of atomic radii of the
central atom in MF3-6 ? following group 13 elements is :
a) B b) Al a) Al < Ga < In < Tl
c) Ga d) In b) Ga < Al < In < Tl
c) Al < In < Ga < Tl
d) Al < Ga < Tl < In
 [Test Paper p-Block Elements - 24-12-2018
19. In the structure of ClF3, the number of lone Q no. 23 as it is]
pairs of electrons on central atom ‘Cl’ is
(1) one (2) two
(3) four (4) three
 [Test Paper - p-Block Elements 22. The correct order of N-compounds in its
20-02-2018 Q.no 24] decreasing order of oxidation states is
24. The number of lone pairs of electrons present (1) HNO3, NO, N2, NH4Cl
on central atom of ClF3 are : (2) HNO3, NO, NH4Cl, N2
(3) HNO3, NH4Cl, NO, N2
a) 0 b) 1 c) 2 d) 3
(4) NH4Cl, N2, NO, HNO3
 [Vol. - 1 Page no. 133 Q no. 137 similar]  [Vol-2 Page no. 175 Q.no 01]
01. Which of the following shows nitrogen in its
increasing order of oxidation number ?
20. Considering Ellingham diagram, which of a) N2O < NO < NO2 < NO3- < NH4+
the following metals can be used to reduce b) NH4+ < N2O < NO < NO2 < NO3-
alumina ? c) NH4+ < N2O < NO2 < NO3- < NO
(1) Fe (2) Zn (3) Mg (4) Cu d) NH4+ < NO < N2O < NO2 < NO3-
 [Vol-2 Page no. 117 Proper explanation is  [IIB - Chemistry Paper - 26-11-2017 As it is]
given in short line under Ellingham diagram] 36. Which ordering of compounds is according to the
decreasing order of the oxidation state of
nitrogen ?
1) HNO3, NO, NH4Cl, N2
2) HNO3, NO, N2, NH4Cl
3) HNO3, NH4Cl, NO, N2
4) NO, HNO3, NH4Cl, N2
 [Vol - 2 Page no. 131 Short table is given]

KONALE COACHING CLASSES 5

23. On which of the following properties does M M
c. 10 mL of HCl +90 mL of NaOH
coagulating power of an ion depend ? 10 10
(1) The magnitude of the charge on the alone M M
(2) Size of the ion alone d. 75mLof HCl + 25mLof NaOH
5 5
(3) Both magnitude and sign of the charge
the ion
25. The solubility of BaSO4 in water
(4) The sign of charge on the ion alone
2.42 × 103 gL-1 at 298 K. The value of
 [Test Paper - Mini Jumbo 03-04-2018
solubility product (Ksp) will be
Q.no - 18]
(Given molar mass of BaSO4 = 233 g mol-1)
18. The capacity of an ion to coagulate a
(1) 1.08 × 10–10 mol2 L–2
colloidal solution depends on :
(2) 1.08 × 10–12 mol2 L–2
a) its shape
(3) 1.08 × 10–14 mol2 L–2
b) the amount of its charge
(4) 1.08 × 10–8 mol2 L–2
c) the sign of the charge
 [Vol-1 Page No. 94 Q.no 60]
d) both, the amount and the sign of the
60. The solubility of BaSO4 in water is
charge
2.33 x 10-3 g L-1. Its solubility product will
 [Test Paper - State of matter - 24/01/2018
be (molecular weight of BaSO4 = 233)
Q.No.12 As it is]
a) 1 x 10-5 b) 1 x 10-10
c) 1 x 10-15 d) 1 x 10-20
24. Following solutions were prepared by
mixing different volumes of NaOH and HCl
26. Given van der Waals constant for NH3, H2
of different concentrations :
and CO2 are respectively 4.17, 0.244, 1.36
M M and 3.59, which one of the following gases is
a. 60 mL HCl + 40 mL NaOH
10 10 most easily liquefied ?
M M (1) NH3 (2) H2
b. 55 mL HCl + 45mL NaOH (3) O2 (4) CO2
10 10
 [Vol-1 Page no. 31 Q.no 65]
M M
c. 75mL HCl + 25 mL NaOH 65. The value of van waals constant ‘a’ for gases
5 5 O2, N2, NH3 and CH4 are 1.360, 1.390, 4.170
M M and 2.253 liter2 atm mol-1 respectively. The
d. 100 mL HCl +100 mL NaOH
10 10 gas which can most easily be liquefied is :
pH of which one of them will be equal to 1 ? a) O2 b) N2
(1) b (2) a c) NH3 d) CH4
(3) d (4) c  [Test Paper Some basic concept & States of
 [Test Paper - Ionic Equilibrium matter - 11-12-2016 Q no. 24 As it is]
28-02-2018 Q.no - 04]
04. Which of the following solutions will have
pH close to 1.0 ?
M M
a. 100 mL of HCl +100 mLof NaOH
10 10
M M
b. 55 mLof HCl + 45 mL of NaOH
10 10

KONALE COACHING CLASSES 6

27. The compound A on treatment with Na The compound C is
gives B, and with PCl5 gives C. B and C a) o-Bromotoluene
react together to give diethyl ether. A, B and b) m-Bromotoluene
C are in the order c) p-Bromotoluene
(1) C2H5OH, C2H6, C2H5Cl d) 3-Bromo-2, 4, 6-trichlorotoluene
(2) C2H5OH, C2H5Cl, C2H5ONa [ Jumbo Test (Girls Batch- 05-10-2017
(3) C2H5Cl, C2H6, C2H5OH Q no. 33 As it is)]
(4) C2H5OH, C2H5ONa, C2H5Cl
 (Alcohol, Phenol, Ether 02-02-18 Q.no 09) 30. Which oxide of nitrogen is not a common
09. An organic compound A reacts with sodium pollutant introduced into the atmosphere both
to give B. A also reacts with PCl5 to give C. due to natural and human activity ?
B and C react together to form diethyl ether (1) N2O5 (2) NO2 (3) N2O (4) NO
A, B and C are  [Test Paper - Hydrocarbon&Environment
a) C2H5OH, C2H5Cl, C2H5ONa 05-04-2018 Q.no 38]
b) C2H5Cl, C2H5OH, C2H5ONa 38. Which of the following is not a pollutant ?
c) C2H5OH, C2H6, C2H5Cl a) CO b) NO2
d) C2H5OH, C2H5ONa, C2H5Cl c) N2O5 d) Hydrocarbons
 [Vol-2 Page no. 267 Q.no 61 & 62
combination] 31. For the redox reaction
MnO4- + C2O42- + H+   Mn2+ + CO2 + H2O
the correct coefficients of the reactants for the
28. Hydrocarbon (A) reacts with bromine by balanced equation are
substitution to form an alkyl bromide which MnO4- C2O42- H+
by Wurtz reaction is converted to gaseous (1) 16 5 2
hydrocarbon containing less than four carbon (2) 2 5 16
atoms. (A) is (3) 2 16 5
(1) CH _= CH (2) CH2 = CH2 (4) 5 16 2
(3) CH3 – CH3 (4) CH4  [Vol. - 1 Page no. 68 Q.no 09]
 [Class book Study Material Page No. 175 09. For the redox reaction
given under the heading Wurtz reaction] MnO 4 + C2O 24 + H+  Mn2+ + CO2 + H2O
the correct coefficients of the reactants for
the balanced reaction are :
29. The compound C7H8 undergoes the
following reactions : MnO 4 C2O 24 H+
3Cl2 / 
C7 H8  Br2 /Fe
 A  Zn/HCl
 B  C a) 2 5 16
b) 16 5 2
The product ‘C’ is
c) 5 16 2
(1) m–bromotoluene
d) 2 16 5
(2) o–bromotoluene
 [Test Paper - Hydrogen & Redox Reaction
(3) 3–bromo–2,4,6–trichlorotoluene
30-03-2018 Q no. 21 As it is]
(4) p–bromotoluene
 [Test Paper - Special final round - 08
 [Vol.-2 Page no. 237 Q.no 66]
Q no. 38 25-04-2018]
66. The compound
 [Test Paper - d & f-Block elements
C7H8 
3Cl / 
2 Br /Fe
 A  2 Zn/HCl
 B   18-08-2017 Q no. 12 As it is]

KONALE COACHING CLASSES 7

32. Which one of the following conditions will
favour maximum formation of the product in
the reaction,
A2(g) + B2(g)  X2(g) rH = -X kJ ?
(1) Low temperature and high pressure
(2) Low temperature and low pressure
(3) High temperature and high pressure
(4) High temperature and low pressure
 [Vol-1 Page no. 82 Q.no 59]
59. Consider the reaction equilibrium
 2SO3 (g);
2SO2 (g) + O2 (g) 
Ho =-198 kJ
On the basis of Le Chatelier’s principle, the
condition favourable for the forward
reaction is
a) lowering of temperature as well as
pressure
b) increasing temperature as well as pressure
c) lowering the temperature and increasing
the pressure
d) any value of temperature and pressure
 [Vol - 1 Page No 80 Q no. 33 similar]
 [Test Paper - Mini Jumbo - 03-04-2018
Q no. 07 similar]
 [Test - Chemical equilibrium - 23-09-2017
Q no. 33 & 34 Similar]
 [Test Paper - Ionic & Chemical Equilibrium
24-11-2017 Q no. 39 Similar]
33. The correction factor ‘a’ to the ideal gas
equation corresponds to
(1) density of the gas molecules
(2) volume of the gas molecules
(3) electric field present between the gas
molecules
(4) forces of attraction between the gas
molecules
 [Test Paper - Some Basic Concepts & States
of matter - 09-07-2016 Qno. 16 As it is]
16 Van der Waal’s constant ‘a’ and ‘b’are related
with respectively
a) Attractive force and bond energy of
molecules
KONALE COACHING CLASSES
b) Volume and repulsive forces of molecules
c) Shape and repulsive forces of molecules
d) Attractive force and volume of the
molecules
 [Vol - 1 Page No. 22 Dark line is given under
the heading van der Waal’s equation]
34. When initial concentration of the reactant is
doubled, the half-life period of a zero order
reaction
(1) is halved (2) is doubled
(3) is tripled (4) remains unchanged
 [Vol-2 Page no.110 Q.no 09]
09. If the initial concentration is doubled, the
time for half change is also doubled, the
order of the reaction is
a) 1 b) 2 c) 0 d) 3
 [Test Paper Chemical Kinetic
06-04-2018 Q no. 38 As it is]
[Test Paper Chemical Kinetic
18-04-2017 Q no. 39 As it is]
35. The bond dissociation energies of X2, Y2 and
XY are in the ratio of 1 : 0.5 : 1. H for the
formation of XY is –200 kJ mol–1. The bond
dissociation energy of X2 will be
(1) 200 kJ mol–1 (2) 100 kJ mol–1
(3) 800 kJ mol–1 (4) 400 kJ mol–1
 [Vol-2 Page No. 54 Q.no 66]
66. AB, A2 and B2 are diatomic molecules. If the
bond enthalpies of A2, AB and B2 are in
the ratio 1:1 :0.5 and enthalpy of formation
of AB from A2 and B2 is-100 kJ mol-l.
What is the bond energy of A2 :
(a) 200 kJ mol-l (b) 100 kJ mo1-1
(c) 300 kJ mol-1 (d) 400 kJ mol-1
 [ Vol - 2 page no. 57 Q.no 113]
113. Bond enthalpies of H2, X2 and HX are in the
ratio 2:1 : 2. If enthalpy of formation of HX
is -50 kJmo1-1, the bond enthalpy of X2 is
(a) 100 kJmol-1 (b) 300 kJmo1-1
-1
(c) 200 kJmo1 (d) 400 kJmo1-1
 [Test Paper - Special final round - 04
Date : 17-04-2018 Q no. 43 Similar ]
8
36. Identify the major products P, Q and R in the 38. The type of isomerism shown by the complex
following sequence of reaction : [CoCl2(en)2] is
Anhydrous
(1) Geometrical isomerism
+ CH3CH 2CH2Cl  3 
AlCl
 P  (i) O 2
 Q + R
(ii) H O + /  3
(2) Coordination isomerism
(3) Ionization isomerism
P Q R
(4) Linkage isomerism
CH2CH2CH3 CHO  [Vol-2 Page No. 215 Q.no 176 &
Page no 208 Q.no 40 Combination of both]
(1) , , CH3CH2-OH  [test paper d & f-Block & Coordination
27-06-2017 Q no. 29 Similar]
CH2CH2CH3 CHO COOH
39. Which one of the following ions exhibits d-d
(2) , , transition and paramagnetism as well ?
(1) CrO2-4 (2) Cr2O2-7
(3) MnO-4 (4) MnO42-
CH(CH3)2 OH
 [Test Paper - d & f-block elements-Proper
(3) , , CH3CH(OH)CH3 explanation given in class notes]

OH
CH(CH3)2
40. The geometry and magnetic behaviour of the
(4) , , CH3-CO-CH3 complex [Ni(CO)4] are
(1) square planar geometry and diamagnetic
 [Test Paper - Alcohol, phenol & Ether (2) tetrahedral geometry and diamagnetic
11-04-2018 Q.no 31 & 33] (3) square planar geometry and paramagnetic
31. Cumene on air oxidation gives (4) tetrahedral geometry and paramagnetic
a) Cumene hydroperoxide b) Benzoic acid  [Coordination Compound
c) Isopropyl benzene d) Phenol 22-08-2017 Q.no 18]
33. Cumene hydroperoxide on decomposition 18. Choose the correct alternative for the
by dil. acid gives mixture of compounds :
a) phenol and acetaldehyde [Ni(CO)4] and [Ni(CN)4]2-
b) phenol and acetone
a) Tetrahedra, Tetrahedral
c) phenol and water
paramagnetic diamagnetic
d) phenol and ethyl alcohol
b) Tetrahedral, Sqaure planar,
37. Which of the following compounds can diamagnetic diamagnetic
form a zwitter ion ? c) Sqaure planar, Sqaure planar,
(1) Aniline (2) Acetanilide diamagnetic paramagnetic
(3) Benzoic acid (4) Glycine d) Trigonal Sqaure
 [Test Paper - Final Round -01 CET pyramidal pyramidal
12-04-2018 Q. no 05]  [Vol-2 Page no. 209 Q no. 53 &
05. Which of the following molecule is capable Page no. 218 Q no. 26 Both similar]
of forming zwitter ion ?
a) CH3-CHOH-NH2 b) NH2CH2COOH
c) CH3-COOH d) CCl3-NO2

KONALE COACHING CLASSES 9

41. Iron carbonyl, Fe(CO)5 is 43. Which of the following is correct with
(1) tetranuclear respect to –I effect of the substituents ?
(2) mononuclear (R = alkyl)
(3) trinuclear (1) –NH2 < – OR < – F
(4) dinuclear (2) –NR2 <–OR < – F
 [Vol -2 Page no. 206 Structure with proper (3) – NH2 > – OR > – F
explanation is given] (4) – NR2 >–OR>– F
 [Vol-1 Page no. 242 Q.no 01]
01. Which of the following is correct regarding
42. Match the metal ions given in Column I with the -I effect of the substituents ?
the spin magnetic moments of the ions given a) -NR2 < -OR < -F
in Column II and assign the correct code : b) NR2 > -OR <-F
Column I Column II c) -NR2 < -OR > - F
a. Co3+ i. 8 B.M. d) NR2 > - OR > -F
 [Class Study Material book Page no.
b. Cr3+ ii. 35 B.M. 101 Q no. 07 similar]
c. Fe3+ iii. 3 B.M.  [Test paper 12, 13, & 14
12-08-2016 Q no. 25 similar]
d. Ni2+ iv. 24 B.M.
 [Test paper Some Basic principles &
v. 15 B.M. techniques in organic chemistry 18-12-2016
a b c d Q no. 35 similar]
(1) iv v ii i  [Test paper Some Basic principles &
(2) i ii iii iv techniques in organic chemistry 22-07-2017
(3) iv i ii iii Q no. 06 similar]
(4) iii v i ii
 [Test Paper - d & f-Block Elements
18-08-2017 Q.no 02]
02. Match list-I with list-II and select the correct
answer using the codes given below ;
List - I List - II
3+
a) Cr 1. 35
2+
b) Fe 2. 30
2+
c) Ni 3. 24
2+
d) Mn 4 15
5. 8
Codes :
a) A-1, B-3, C-5, D-4
b) A-2, B-3, C-5, D-1
c) A-4, B-3, C-5, D-1
d) A-5, B-1, C-2, D-3

KONALE COACHING CLASSES 10

44. Which of the following carbocations is 45. Which of the following molecules represents
expected to be most stable ? the order of hybridisation sp2, sp2, sp, sp
from left to right atoms ?
NO2
(1) HC _= C – C _= CH
(2) CH2 = CH – C _= CH
(1) (3) CH2 = CH – CH = CH2
Y H (4) CH3 – CH = CH – CH3
 [Vol-1 Page no. 131 Q.no 104]
NO2 104. Which of the following represents the given
mode of hybridisation sp2-sp2-sp-sp from left
(2) to right ?
Y H a) H2C = CH-C  N
b) HC  C-C  CH
NO2 c) H2C=C=C=CH2
CH2
(3) H d)
H2C
Y
 [Test paper some basic principles &
NO2 Techniques in Organic chemistry
H 25-03-2018 Q no. 33 As it is]
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 [Jumbo Test - 05-06-2016 Q no. 21 As it is]
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Q no. 16 similar

KONALE COACHING CLASSES 11