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HYDROCARBON
PROCESSING INDUSTRY
REFRACTORY SOLUTIONS
PETROCHEM
Monolithic Concept INDUSTRY
Solutions
F
Innovative Refractory Solutions for
calder
the Hydrocarbon Processing Industry REFRACTORY SOLUTIONS
applications.
The introduction of the first industrial process units created a need for dependable
refractory products to contain the hot process gases. Calderys responded with
unique monolithic refractory technology that has prevailed for many decades.
world pioneer in the development of high quality plastic and castable monolithics
for the emerging refinery and petrochemical applications. During all those years,
Calderys is aware of the present-day Each unique Calderys product has been
The Calderys team is constantly This capability assures maximum The products are specific refractory
improving their refractory service performance, reduced products which will meet all
products to meet the needs of the maintenance, and economical specific appropriate HCP standard
Calderys has earned an international The Calderys product applications The Hydrocarbon Processing
reputation for leading refractory for the Hydrocarbon Processing Industry can depend on these
technology, high quality materials, Industry are shown on the pages refractory products to meet the
and competent installation teams. indexed below. Calderys guideline of "Quality leads
to success".
Index
Crude & Vacuum Distillation Units 5 Ethylene Furnaces 13
These units are used for heating up crude oil for the refining Typical temperatures inside the furnace range from 800°C to
process. After heating the oil is transported to the distillation 1000°C. The unit can be equipped with floor and/or
column for further processing. side-wall burners. The main function of the lining is to have
The oil is transported through tubing inside the furnace. good insulating properties in order to limit energy loss.
Burner blocks
C A L D E ™ CAST F 60 C O CALDE™ CAST LW 130 C/G
C A L D E ™ CAST LM 70 CALDE™ CAST XL 106 C/G
(platformers)
A fired heater is generally used to increase the temperature workshop and erected at the job-site in a very short time
of the product anywhere in the process. These units can be due to the modular design of such units. Temperatures may
rectangular but also circular shapes are common. range from fairly low 600°C to 1000°C.
rS
FCC-Units
In the past, heavy oil residues from crude oil distillation were requires advanced refractory materials. Since the process
only used for low level applications. The search for more is in contact with the refractory, the demands are severe.
efficient use of oil reserves has lead to the development of The reaction with the catalyst, the severe erosion from
a process of cracking these residues by means of a catalyst. the catalyst against the refractory lining and the reducing
The principle is to crack the long chain residue molecules atmosphere inside someparts of the unit call for dedicated
into smaller molecules which form light high grade products materials.Calderys has developed these materials to ensure
such as propane, butane, gasoline and high octane petrol. maximum service performance, reduced maintenance and
Reactor / Regenerator
(wall, head & bottom) Reactor outer riser
wye piece
C A L D E ™ CAST LW 134 C/G
C A L D E ™ CAST M W 25 C/G CALDE™ CAST MF 55 G 4
FCC-Units
Cyclones
Specific items in the FCC unit are the cyclones and stand- consequently require a strong, severe abrasion resistant
pipes. The function of the cyclones is to remove the material. Calderys can offer the materials to resist this
catalyst from the process gasses. The conditions in this area environment.
Anchoring systems
OTÎ.
t r ^ r ^ r o o o
ÎSÎ SiS
Due to the environmental issues the need to reduce sulphur gas contains carbon dioxide, light hydrocarbons, nitrogen, etc.
in fuels as well as in flue gasses has become necessary. For each part of the equipment in this process - such as
Most refineries are equipped with a so-called sulphur burners, main chambers, mixing chambers, incinerator
recovery unit. In this type of installation, the acid gas is chambers, waste heat boilers reactors and sulphur
burned off in a furnace. Except hydrogen sulphide the flue condensers, Calderys has a proven monolithic lining concept.
Reactors
Bottom / Heads
C A L D E ™ CAST F 42
C A L D E ™ CAST LW 130 C/G
Incinerator Chambers
CALDE™ CAST 40 TR
Ethylene is the most important raw material for the Petro- products can be produced such as Polyethene, PVC, Ethylene
chemical industry. From this material, many different Glycol (Anti freeze), Styrene and many others.
Peepholes
CALDE™ CAST LW 130 C/G
CALDE™ CAST XL 140
Floors
CALDE™ CAST LW 130 C/G
Radiant section /arch
CALDE™ CAST XL 106 C/G
C A L D E ™ CAST LW 130 C/G
CALDE™ CAST LW MIX 124 C/G
C A L D E ™ CAST XL 106 C/G
C A L D E ™ CAST XL 140
Burner blocks
or Hydrogen Plants
Ammonia is an important raw material for producing process is heating of the feedstock. After heating up the
fertilizer. A similar process is also used to produce Hydrogen feedstock, it is transported through the transfer lines to the
for the Petro-chemical industry. For example, in an FCC unit, secondary reformer.
H2 is used to improve the cracking process. The process gas in this reformer is in direct contact with the
The Ammonia or Hydrogen plants have two main units: lining. Due to the composition of the process gas, the lining
primary reformer and secondary reformer which are needs to consist of very high purity material. Both low iron
connected by transfer lines. In primary reformer, the main and low silica refractory materials are therefore used.
Secondary Reformer
or Hydrogen Plants
Primary Reformer
Radiant walls
CALDE™ CAST LW MIX 124 C/G
Fluegas ducts
C A L D E ™ CAST M W 138
C A L D E ™ CAST XL 106 C/G
In a coke calciner, the final residue of the refinery process, During the process, calcination takes place in stages as
Petroleum-coke, is turned into usable carbon. This carbon is the green coke moves slowly through the progressively
a key element in the production of anodes for the aluminum increasing temperature zones from 150°C up till 1500°C.
industry. In principle, there are two types of coke calciners, In these type of installations, there is direct contact between
the rotary kiln and rotary hearth type. Described here is the the product and the refractory lining for which Calderys has
rotary hearth type. high temperature, abrasion resistant, high thermal shock
Carbon black is a high grade carbon which is used in the tire needs to consist of very high purity material. Both low iron
industry and in many other applications. Feedstock is not an and low silica refractory materials are therefore used.
oil residue but aromatic oil. O i l is injected in a tubular furnace. High temperature of
The process gas in this reformer is in direct contact with the up to 2000°C and a high velocity of the gasses make this
lining. Due to the composition of the process gas, the lining process very harsh for the refractory lining.
Reactors
C A L D E ™ CAST M W 180 C O
C A L D E ™ CAST UT 99
NOTES: CALDERYS does not warrant the accuracy, fitness for purpose or update of any information disclosed herein. The recipient shall refer t o instructions and advice
provided under any technical documentation. This d o c u m e n t and the information contained herein are the exclusive property of CALDERYS. Reproduction, alteration,
copy, release, publication or distribution, in whole or in part, is not allowed.
References, trademarks and specifications of the products may change according t o the geographical area t o be supplied. Please check the availability of the products
w i t h the sales area manager.
Castable
Tabular +0.00 +0.00 90 65
CALDE™ CAST 4 0 TR Hydraulic 1820 6 95 0.10 0.10 4.40 2.67 8 t o 10
Alumina (800°C) (1200°C) (800°C) (1200°C)
-0.55 -0.55 30 17
CALDE™ CAST F 35 Chamotte Hydraulic 1320 3 35 48 3.80 9.10 1.85 14 t o 16
(800°C) (1200°C) (800°C) (1200°C)
-0.15 -0.15 45 24
CALDE™ CAST F 42 Chamotte Hydraulic 1320 6 41 38 5 11 2 12 t o 14
(800°C) (1200°C) (800°C) (1200°C)
Insulating 1.20 -0.25 (cast) -0.75 (cast) 6.50 (cast) 3.50 (cast)
CALDE™ CAST LW 130 C/G Hydraulic 1300 5 39 39 5.50 12 3 0 t o 35 (cast)
chamotte (cast) (800°C) (1200°C) (800°C) (1200°C)
CALDE™ CAST LW 134 Chamotte 1.25* - 0 . 4 0 (gun) - 1 . 2 0 (gun) 3.50 (gun) 2.50 (gun)
Hydraulic 1340 5 42 46 1 8.50 added a t t h e nozzle
C O C/G Perlite (gun) (800°C) (1200°C) (800°C) (1200°C)
CALDE™ CAST LW M i x Insulating Chamotte -0.40 (gun) - 0 . 9 0 (gun) 3 (gun) 2.70 (gun)
Hydraulic 1140 4 24 42 9.50 15 0.94 45 t o 4 9
124 C/G Vermiculite (800°C) (1000°C) (800°C) (1000°C)
-0.05 -0.10 35 45
CALDE™ CAST UT 9 9 Tabular A l u m i n a Hydraulic 1800 6 99 0.10 0.10 0.50 3.23 4 t o 4.4
(800°C) (1200°C) (800°C) (1200°C)
-0.25 -0.70 30 16
CALDE™ G U N F 4 0 Chamotte Hydraulic 1300 6 39 45 2.40 9.20 2.14* added a t t h e nozzle
(800°C) (1200°C) (800°C) (1200°C)
-0.20 -0.70 60 45
CALDE™ G U N F 6 0 G3 Low Iron c h a m o t t e Hydraulic 1450 4 60 29 0.70 8.30 2.55 added a t t h e nozzle
(800°C) (1200°C) (800°C) (1200°C)
Ramming
Tabular -0.50 -0.65 100 120
CALDE™ PATCH PT 8 6 2CP Chemical 1650 2 87 6.50 0.20 3.1 7.3 t o 7.9 (binder)
Alumina (800°C) (1000°C) (800°C) (1000°C)
-1.25 -1.55 44 57
CALDE™ PLAST C 9 0 AB Corundum Ceramic 1750 6 90 8 0.70 2.95
(800°C) (1200°C) (800°C) (1200°C)
* Rebound included
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