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HYDROCARBON
PROCESSING INDUSTRY
REFRACTORY SOLUTIONS

PETROCHEM
Monolithic Concept INDUSTRY
Solutions

F
Innovative Refractory Solutions for
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the Hydrocarbon Processing Industry REFRACTORY SOLUTIONS

Our strategy in the industry Our worldwide presence and expertise

is to bring the best value-in-use allow us to propose the most suitable


to our customers by continuous and cost effective solutions.
improvements of our products.
Calderys has earned an international
Based on this strategy, we have
reputation for skilled engineering,
started for a long time ago, research
quality products, and competent
& development programs to
installers. Our world network
improve not only the performance
contributes new refractory
of our products, but also facilitate
formulations, efficient new installation
their placement and drying
techniques, and new solutions
properties.
to old problems.
As a consequence, we enjoy a more
Calderys refractory products are
than a hundred years successful
manufactured under stringent
activity worldwide, our offer includes
international quality controls.
a full range of monolithic refractories
They are formulated to increase the
in all applications where both alumina service life and reduce overall costs.
and silica products are needed.
Today, Calderys spans the globe and
We offer a full range of commodity
stands ready to give you the latest
and special materials meant for the
and the best in the refractory world.
maintenance of various equipment.

Additionally to the before mentioned

monolithics, Calderys offers a wide

range of prefabricated shapes for many

applications.

2 Monolithic concept solutions for Hydrocarbon Processing Industry 2


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REFRACTORY SOLUTIONS

The introduction of the first industrial process units created a need for dependable

refractory products to contain the hot process gases. Calderys responded with

unique monolithic refractory technology that has prevailed for many decades.

Calderys worked together with the Hydrocarbon Processing Industry to become a

world pioneer in the development of high quality plastic and castable monolithics

for the emerging refinery and petrochemical applications. During all those years,

Calderys has sustained a long-lasting working relationship with the Hydrocarbon

Processing Industry. They have grown together as partners in the long-term

advancement of monolithic refractory state-of-the-art.

Today Calderys continues to supplement the Hydrocarbon Processing

Industry with a fully-integrated refractory partnership that supplies

materials, technology, and installation services throughout the world.

Efficiency & quality

Calderys is aware of the present-day Each unique Calderys product has been

demands for fast and economical carefully formulated and manufactured

installation without a sacrifice of with advanced technology and quality

refractory quality. Several types assurance, controlled by ISO 9001.

of monolithic refractory products Installation, dry-out and start-up


have been developed to meet these operations are also critical to a long
criteria: refractory service life. Detailed product

• Plastic mouldables information, installation procedures

• Ramming and material safety data sheets are

• Casting (hand packing, rodding) supplied by Calderys.

• Vibration casting These critical services are furnished

• Self-flow casting by engineering and service personnel

• Gunning with years of refractory experience.

• Pumping The Hydrocarbon Processing

• Spraycasting (shotcreting) Industry can rely on the expert services

• Injection of the Calderys team who develops

• Troweling a dependable refractory product and

the solutions required to ensure a long

service life with reduced costs.

Monolithic concept solutions for Hydrocarbon Processing Industry 3


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uct Application REFRACTORY SOLUTIONS

The Calderys team is constantly This capability assures maximum The products are specific refractory

improving their refractory service performance, reduced products which will meet all

products to meet the needs of the maintenance, and economical specific appropriate HCP standard

Hydrocarbon Processing Industry. installation. Engineering specifications.

Calderys has earned an international The Calderys product applications The Hydrocarbon Processing

reputation for leading refractory for the Hydrocarbon Processing Industry can depend on these

technology, high quality materials, Industry are shown on the pages refractory products to meet the

and competent installation teams. indexed below. Calderys guideline of "Quality leads

to success".

Index
Crude & Vacuum Distillation Units 5 Ethylene Furnaces 13

Catalytic Reformer Furnaces Ammonia Plants


(platformers) 6 or Hydrogen Plants 14-15

Fired Heaters 7 Transfer Lines 16

Fluid Catalytic Cracking Units Coke Calciners 17


FCC-Units 13-9
Carbon black Reactors 18
Sulphur recovery Units/
Technical Data 19
Claus Combustion Chambers 10-12

4 Monolithic concept solutions for Hydrocarbon Processing Industry 4


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Vacuum Disti REFRACTORY SOLUTIONS

These units are used for heating up crude oil for the refining Typical temperatures inside the furnace range from 800°C to

process. After heating the oil is transported to the distillation 1000°C. The unit can be equipped with floor and/or

column for further processing. side-wall burners. The main function of the lining is to have

The oil is transported through tubing inside the furnace. good insulating properties in order to limit energy loss.

Radiant section /arch


C A L D E ™ CAST LW 130 C/G
CALDE™ CAST LW MIX 124 C/G
Convection section
C A L D E ™ CAST XL 106 C/G
C A L D E ™ CAST XL 140 CALDE™ CAST LW MIX 124 C/G

Burner blocks
C A L D E ™ CAST F 60 C O CALDE™ CAST LW 130 C/G
C A L D E ™ CAST LM 70 CALDE™ CAST XL 106 C/G

Monolithic concept solutions for Hydrocarbon Processing Industry 5


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ytic Reformer Furn REFRACTORY SOLUTIONS

(platformers)

Such a unit is used to obtain better distillation efficiency.

The product is transported through tubes inside the furnace.

Typical temperatures inside the furnace are about 1000°C.

Radiant section /arch


CALDE™ CAST LW 130 C/G
Up-takes
CALDE™ CAST LW MIX 124 C/G
Fluegas ducts
CALDE™ CAST XL 106 C/G
CALDE™ CAST LW MIX 124 C/G CALDE™ CAST XL 140

CALDE™ CAST LW 130 C/G High Duty Fire Bricks


CALDE™ CAST XL 106 C/G

6 Monolithic concept solutions for Hydrocarbon Processing Industry 6


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REFRACTORY SOLUTIONS

A fired heater is generally used to increase the temperature workshop and erected at the job-site in a very short time

of the product anywhere in the process. These units can be due to the modular design of such units. Temperatures may

rectangular but also circular shapes are common. range from fairly low 600°C to 1000°C.

New fired heaters can be completely prefabricated in the

Radiant section /roof


CALDE™ CAST LW 130 C/G
CALDE™ CAST LW MIX 124 C/G
CALDE™ CAST XL 106 C/G
Fluegas ducts CALDE™ CAST XL 140

CALDE™ CAST LW MIX 124 C/G

rS

Floors Burner blocks


CALDE™ CAST LW 130 C/G CALDE™ CAST F 6 0 C O
CALDE™ CAST XL 106 C/G CALDE™ CAST LM 70

Monolithic concept solutions for Hydrocarbon Processing Industry 7


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ic Cracking REFRACTORY SOLUTIONS

FCC-Units

In the past, heavy oil residues from crude oil distillation were requires advanced refractory materials. Since the process

only used for low level applications. The search for more is in contact with the refractory, the demands are severe.

efficient use of oil reserves has lead to the development of The reaction with the catalyst, the severe erosion from

a process of cracking these residues by means of a catalyst. the catalyst against the refractory lining and the reducing

The principle is to crack the long chain residue molecules atmosphere inside someparts of the unit call for dedicated

into smaller molecules which form light high grade products materials.Calderys has developed these materials to ensure

such as propane, butane, gasoline and high octane petrol. maximum service performance, reduced maintenance and

The unit performing this process is a FCC unit. cost-effective installation.

The FCC unit is an advanced piece of equipment that also

Reactor / Regenerator
(wall, head & bottom) Reactor outer riser
wye piece
C A L D E ™ CAST LW 134 C/G
C A L D E ™ CAST M W 25 C/G CALDE™ CAST MF 55 G 4

Reactor/ Reactor / Regeneration


Regenerator plenum primary- & secondary
cyclones
C A L D E ™ PATCH PT 86 2CP
C A L D E ™ STIX PB 85 C/G CALDE™ PATCH PT 8 6 2CP
CALDE™ STIX PB 85 C/G

Mushroom-distributor Spent catalyst


reactor inner riser standpipe
C A L D E ™ PATCH PT 86 2CP CALDE™ CAST MF 55 G 4
C A L D E ™ STIX PB 85 C/G CALDE™ G U N F 60 G 3

Main stripping &


stripper fluffing
steam ring
combustion air ring
C A L D E ™ PATCH PT 86 2CP
C A L D E ™ STIX PB 85 C/G

B Monolithic concept solutions for Hydrocarbon Processing Industry 68


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ic Cracking REFRACTORY SOLUTIONS

FCC-Units

Cyclones

Specific items in the FCC unit are the cyclones and stand- consequently require a strong, severe abrasion resistant

pipes. The function of the cyclones is to remove the material. Calderys can offer the materials to resist this

catalyst from the process gasses. The conditions in this area environment.

Inlet ducts primary- &


secondary cyclones
C A L D E ™ PATCH PT 86 2CP
C A L D E ™ STIX PB 85 C/G

Anchoring systems

OTÎ.
t r ^ r ^ r o o o
ÎSÎ SiS

Monolithic concept solutions for Hydrocarbon Processing Industry 9


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ur recovery Units REFRACTORY SOLUTIONS

Claus Combustion Chambers

Due to the environmental issues the need to reduce sulphur gas contains carbon dioxide, light hydrocarbons, nitrogen, etc.

in fuels as well as in flue gasses has become necessary. For each part of the equipment in this process - such as

Most refineries are equipped with a so-called sulphur burners, main chambers, mixing chambers, incinerator

recovery unit. In this type of installation, the acid gas is chambers, waste heat boilers reactors and sulphur

burned off in a furnace. Except hydrogen sulphide the flue condensers, Calderys has a proven monolithic lining concept.

Reactors

Bottom / Heads
C A L D E ™ CAST F 42
C A L D E ™ CAST LW 130 C/G

Main Burners/Main Combustion Chambers

C A L D E ™ PLAST C 90 AB CALDE™ CAST M W 138


C A L D E ™ PLAST F 60 AB CALDE™ PLAST C 90 AB
CALDE™ PLAST F 6 0 AB

10 Monolithic concept solutions for Hydrocarbon Processing Industry


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ur recovery Units REFRACTORY SOLUTIONS

Claus Combustion Chambers

Line Burner / Line Mixing Chamber

Line burners Line mixing chambers


— Hot section Line mixing Chambers
C A L D E ™ CAST 4 0 TR
Cold section
C A L D E ™ CAST LW 130 C/G CALDE™ CAST 40 TR
G G C A L D E ™ PLAST C 90 AB CALDE™ PLAST C 9 0 AB CALDE™ CAST LW 130 C/G (cast)

Incinerator Chambers

Hot section Mixing section


C A L D E ™ CAST 4 0 TR CALDE™ CAST 40 TR
Incineration section Tail gas inlet
C A L D E ™ CAST LW 130 C/G CALDE™ CAST LW 130 C/G
C A L D E ™ PLAST C 90 AB CALDE™ PLAST C 9 0 AB C A L D E ™ CAST F 42 CALDE™ G U N F 40

CALDE™ CAST 40 TR

11 Monolithic concept solutions for Hydrocarbon Processing Industry


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ur recovery Units REFRACTORY SOLUTIONS

Claus Combustion Chambers

Power Former Reactors Synthesis Gas Dryers

Vessel bottom / head Vessel


C A L D E ™ CAST M W 138 C A L D E ™ CAST LW 130 C/G

Tail Gas Incinerators

12 Monolithic concept solutions for Hydrocarbon Processing Industry


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REFRACTORY SOLUTIONS

Ethylene is the most important raw material for the Petro- products can be produced such as Polyethene, PVC, Ethylene

chemical industry. From this material, many different Glycol (Anti freeze), Styrene and many others.

Convection section Roof / Arch


C A L D E ™ CAST LW 130 C/G CALDE™ CAST LW 130 C/G
CALDE™ CAST LW MIX 124 C/G CALDE™ CAST XL 140

Peepholes
CALDE™ CAST LW 130 C/G
CALDE™ CAST XL 140

Floors
CALDE™ CAST LW 130 C/G
Radiant section /arch
CALDE™ CAST XL 106 C/G
C A L D E ™ CAST LW 130 C/G
CALDE™ CAST LW MIX 124 C/G
C A L D E ™ CAST XL 106 C/G
C A L D E ™ CAST XL 140

Burner blocks

Monolithic concept solutions for Hydrocarbon Processing Industry 13


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onia Plants REFRACTORY SOLUTIONS

or Hydrogen Plants

Ammonia is an important raw material for producing process is heating of the feedstock. After heating up the

fertilizer. A similar process is also used to produce Hydrogen feedstock, it is transported through the transfer lines to the

for the Petro-chemical industry. For example, in an FCC unit, secondary reformer.

H2 is used to improve the cracking process. The process gas in this reformer is in direct contact with the

The Ammonia or Hydrogen plants have two main units: lining. Due to the composition of the process gas, the lining

primary reformer and secondary reformer which are needs to consist of very high purity material. Both low iron

connected by transfer lines. In primary reformer, the main and low silica refractory materials are therefore used.

Secondary Reformer

Inlet duct Wall / cone / head


CALDE™ CAST 40 TR CALDE™ CAST 40 TR
CALDE™ CAST LW 154 C O CALDE™ CAST LW 154 C O
CALDE™ CAST M W 180 C O

14 Monolithic concept solutions for Hydrocarbon Processing Industry 14


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onia Plants REFRACTORY SOLUTIONS

or Hydrogen Plants

Primary Reformer

Radiant walls
CALDE™ CAST LW MIX 124 C/G
Fluegas ducts
C A L D E ™ CAST M W 138
C A L D E ™ CAST XL 106 C/G

Monolithic concept solutions for Hydrocarbon Processing Industry 15


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REFRACTORY SOLUTIONS

16 Monolithic concept solutions for Hydrocarbon Processing Industry 16


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REFRACTORY SOLUTIONS

In a coke calciner, the final residue of the refinery process, During the process, calcination takes place in stages as

Petroleum-coke, is turned into usable carbon. This carbon is the green coke moves slowly through the progressively

a key element in the production of anodes for the aluminum increasing temperature zones from 150°C up till 1500°C.

industry. In principle, there are two types of coke calciners, In these type of installations, there is direct contact between

the rotary kiln and rotary hearth type. Described here is the the product and the refractory lining for which Calderys has

rotary hearth type. high temperature, abrasion resistant, high thermal shock

resistant and chemical resistant materials specific to each

of the different temperature zones.

Up-take fluegas duct


Rabble roof
C A L D E ™ CAST LW 154 C O
Rabbles
C A L D E ™ PLAST C 90 AB CALDE™ PLAST C 9 0 AB
C A L D E ™ PLAST F 60 AB C A L D E ™ PATCH PT 86 2CP CALDE™ PLAST F 60 AB

Discharge table floor


/side walls Soaking pit
C A L D E ™ CAST F 60 C O CALDE™ CAST F 6 0 G 3
CALDE™ CAST LW 130 C/G

Monolithic concept solutions for Hydrocarbon Processing Industry 17


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REFRACTORY SOLUTIONS

Carbon black is a high grade carbon which is used in the tire needs to consist of very high purity material. Both low iron

industry and in many other applications. Feedstock is not an and low silica refractory materials are therefore used.

oil residue but aromatic oil. O i l is injected in a tubular furnace. High temperature of

The process gas in this reformer is in direct contact with the up to 2000°C and a high velocity of the gasses make this

lining. Due to the composition of the process gas, the lining process very harsh for the refractory lining.

Reactors
C A L D E ™ CAST M W 180 C O
C A L D E ™ CAST UT 99

NOTES: CALDERYS does not warrant the accuracy, fitness for purpose or update of any information disclosed herein. The recipient shall refer t o instructions and advice
provided under any technical documentation. This d o c u m e n t and the information contained herein are the exclusive property of CALDERYS. Reproduction, alteration,
copy, release, publication or distribution, in whole or in part, is not allowed.
References, trademarks and specifications of the products may change according t o the geographical area t o be supplied. Please check the availability of the products
w i t h the sales area manager.

Monolithic concept solutions for Hydrocarbon Processing Industry 18


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REFRACTORY SOLUTIONS

Max. Max. C h e m i c a l Analysis ( % ) Material W a t e r required Permanent Permanent


Main Binding CCS CCS
Product n a m e recomm. grain required for mixing on site linear change linear change
component system (N/mm 2 ) (N/mm 2 )
t e m p . (°C) size Al2O3 SiO2 Fe2O3 CaO (t/m3) (litres/100kg) (%) (%)

Castable
Tabular +0.00 +0.00 90 65
CALDE™ CAST 4 0 TR Hydraulic 1820 6 95 0.10 0.10 4.40 2.67 8 t o 10
Alumina (800°C) (1200°C) (800°C) (1200°C)

-0.55 -0.55 30 17
CALDE™ CAST F 35 Chamotte Hydraulic 1320 3 35 48 3.80 9.10 1.85 14 t o 16
(800°C) (1200°C) (800°C) (1200°C)

-0.15 -0.15 45 24
CALDE™ CAST F 42 Chamotte Hydraulic 1320 6 41 38 5 11 2 12 t o 14
(800°C) (1200°C) (800°C) (1200°C)

Low Iron -0.10 -0.10 50 20


CALDE™ CAST F 6 0 C O Hydraulic 1620 6 59 34 0.70 4.50 2.23 10 t o 10.40
chamotte (800°C) (1200°C) (800°C) (1200°C)

Low Iron -0.10 -0.20 50 35


CALDE™ CAST F 6 0 G3 Hydraulic 1580 4 60 30 0.80 5.70 2.14 10 t o 12
chamotte (800°C) (1200°C) (800°C) (1200°C)

High A l u m i n a -0.04 -0.09 30 32


CALDE™ CAST LM 70 Hydraulic 1650 6 70 26 0.70 1.90 2.51 6 t o 6.80
raw materials (800°C) (1200°C) (800°C) (1200°C)

Insulating Chamotte 1.40* -0.25 (gun) - 0 . 8 0 (gun) 10 (gun) 7 (gun)


CALDE™ CAST LW 116 C/G Hydraulic 1160 4 25 39 10.50 17.50 added a t t h e nozzle
Vermiculite (gun) (800°C) (1000°C) (800°C) (1000°C)

Insulating 1.20 -0.25 (cast) -0.75 (cast) 6.50 (cast) 3.50 (cast)
CALDE™ CAST LW 130 C/G Hydraulic 1300 5 39 39 5.50 12 3 0 t o 35 (cast)
chamotte (cast) (800°C) (1200°C) (800°C) (1200°C)

Insulating 1.50* -0.30 (gun) -0.85 (gun) 9 (gun) 7 (gun)


CALDE™ CAST LW 134 C/G Hydraulic 1340 5 39 40 2.80 14.5 added a t t h e nozzle
chamotte (gun) (800°C) (1200°C) (800°C) (1200°C)

CALDE™ CAST LW 134 Chamotte 1.25* - 0 . 4 0 (gun) - 1 . 2 0 (gun) 3.50 (gun) 2.50 (gun)
Hydraulic 1340 5 42 46 1 8.50 added a t t h e nozzle
C O C/G Perlite (gun) (800°C) (1200°C) (800°C) (1200°C)

Light w e i g h t -0.25 -0.10 3 4


CALDE™ CAST LW 154 C O Hydraulic 1540 5 85 0.20 0.20 14 1.12 50 t o 6 0
aggregates (800°C) (1200°C) (800°C) (1200°C)

CALDE™ CAST LW M i x Insulating Chamotte -0.40 (gun) - 0 . 9 0 (gun) 3 (gun) 2.70 (gun)
Hydraulic 1140 4 24 42 9.50 15 0.94 45 t o 4 9
124 C/G Vermiculite (800°C) (1000°C) (800°C) (1000°C)

Low Iron -0.25 -0.45 110 75


CALDE™ CAST MF 55 G 4 Hydraulic 1450 4 54 38 0.70 4.8 2.13 8 t o 9.2
chamotte (800°C) (1200°C) (800°C) (1200°C)

Insulating -0.20 -0.50 28 14


CALDE™ CAST M W 1 3 8 Hydraulic 1380 5 45 36 3 13 1.43 20 t o 24
chamotte (800°C) (1200°C) (800°C) (1200°C)

Bubble -0.20 -0.20 8.50 8


CALDE™ CAST M W 1 8 0 C O Hydraulic 1800 5 96 0.50 0.20 3 1.58 16 t o 18
alumina (800°C) (1200°C) (800°C) (1200°C)

Insulating -0.20 -0.50 10 6


CALDE™ CAST M W 2 5 C/G Hydraulic 1340 4 46 36 3 12 1.32 26 t o 30
chamotte (800°C) (1200°C) (800°C) (1000°C)

-0.05 -0.10 35 45
CALDE™ CAST UT 9 9 Tabular A l u m i n a Hydraulic 1800 6 99 0.10 0.10 0.50 3.23 4 t o 4.4
(800°C) (1200°C) (800°C) (1200°C)

0.73* -0.70 (gun) - 2 . 1 0 (gun) 1 2 0 (gun) 1 (gun)


CALDE™ CAST XL 106 C/G Vermiculite Hydraulic 1060 3 22 41 9 17.5 added a t t h e nozzle
(gun) (800°C) (1000°C) (800°C) (1000°C)

Light w e i g h t -0.05 -0.70 2 1.60


CALDE™ CAST XL 140 Hydraulic 1400 5 45 36 0.90 16 0.64 50 t o 56
aggregates (800°C) (1200°C) (800°C) (1200°C)

-0.25 -0.70 30 16
CALDE™ G U N F 4 0 Chamotte Hydraulic 1300 6 39 45 2.40 9.20 2.14* added a t t h e nozzle
(800°C) (1200°C) (800°C) (1200°C)

-0.20 -0.70 60 45
CALDE™ G U N F 6 0 G3 Low Iron c h a m o t t e Hydraulic 1450 4 60 29 0.70 8.30 2.55 added a t t h e nozzle
(800°C) (1200°C) (800°C) (1200°C)

Insulating -0.35 -0.50 65 40


CALDE™ GUN M W 148 CO HR Hydraulic 1480 3 54 35 0.60 9 2* added a t t h e nozzle
chamotte (800°C) (1200°C) (800°C) (1200°C)

Light w e i g h t -0.15 -0.70 5 4


CALDE™ G U N XL 140 C O Hydraulic 1400 5 43 38 0.70 15 0.98* added a t t h e nozzle
aggregates (800°C) (1200°C) (800°C) (1200°C)

Ramming
Tabular -0.50 -0.65 100 120
CALDE™ PATCH PT 8 6 2CP Chemical 1650 2 87 6.50 0.20 3.1 7.3 t o 7.9 (binder)
Alumina (800°C) (1000°C) (800°C) (1000°C)

-1.25 -1.55 44 57
CALDE™ PLAST C 9 0 AB Corundum Ceramic 1750 6 90 8 0.70 2.95
(800°C) (1200°C) (800°C) (1200°C)

High A l u m i n a -1.20 -1.60 33 22


CALDE™ PLAST F 6 0 AB Ceramic 1650 6 60 34 1.30 2.45
raw materials (800°C) (1200°C) (800°C) (1200°C)

-0.30 (cast) -0.65 (cast) 100 (cast) 100 (cast)


CALDE™ STIX PB 8 5 C/G Bauxite Hydraulic 1300 4 84 8 1 (P2O5) 2.30 2.85 (cast) 7.6 t o 8 . 4
(800°C) (1200°C) (800°C) (1200°C)

* Rebound included

Monolithic concept solutions for Hydrocarbon Processing Industry 19


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