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Chemistry Review Series
Chem 17 1ST Long Exam

I. Modified True or False. Write TRUE if the statement

4. The concentration of Calculated order of
is correct. Otherwise, write FALSE then change the
Na2S2O3 used was one- reaction with
underlined word(s) to make the statement true.
fourth of the recorded respect to
concentration. thiosulfate
1. (LAB) The calorimeter heat capacity (Ccal) is an extensive
property. 5. Instead of 3.0 M HCl, 6 Rate of reaction
2. The higher the activation energy of a reaction, the bigger M of the said solution was
is the fraction of the energetic collisions and the slower the made to react with 0.15 M
reaction. Na2S2O3.
3. The activation energy of a reaction is the maximum
kinetic energy that molecules must bring to their collisions
for a chemical reaction to occur. III. Multiple Choice. Write the letter of your answer.
4. A reaction with a positive ∆H and negative ∆S is 1. A ____ is a step-by-step description of a chemical
spontaneous at low temperatures. reaction consisting of a series of ____.
5. A process occurring at constant temperature is called a) Reaction mechanism; elementary processes
isobaric. b) Reaction mechanism; reaction complex
6. Change in internal energy is equal to the heat flow at c) Catalysis; elementary processes
constant pressure while change in enthalpy is equal to the d) Catalysis; reaction complex
heat flow at constant volume.
7. (LAB) The reaction that drives the coupling forward was 2. Given the following data for this reaction:
extraction of carbon solid from CO2, NH4+(aq) + NO2-(aq)  N2(g) + 2H2O(l)
8. When gaseous molecules collide, it leads to a chemical
reaction when there is sufficient kinetic energy and correct EXPT [NH4+] [NO2-] RATE
orientation. 1 0.010 M 0.020 M 0.020 M/s
9. The transition state is the specie that appears in the
reaction mechanism produced by a step and used by the 2 0.015 M 0.020 M 0.030 M/s
next. 3 0.010 M 0.010 M 0.005 M/s
10. Formation of nitrogen dioxide (2NO(g) + The rate law for the reaction is:
O2(g)↔2NO2(g)) shows increased entropy.
11. At constant volume, no work is done. a) Rate = k[NH4+][NO2-]
12. (LAB) Mn2+ was the autocatalyst in the reduction of b) Rate = k[NH4+]2[NO2-]2
permanganate. c) Rate = k[NH4+]2[NO2-]
d) Rate = k[NH4+][NO2-]2
II. Cause and Effect. Identify the effect of the condition
on the indicated parameter. Write increase, decrease, no effect, or 3. A drug used to treat hypertension undergoes a
indeterminate. decomposition reaction to give an insoluble product.
Calculate the temperature at which this reaction becomes
Condition Parameter spontaneous if the enthalpy of the reaction at 298 K is 51
kJ mol-1 and the entropy of the reaction at this temperature
is 118.74 J K-1 mol-1.
1. The molarity of HCl used Time of
a) 430 K
was twice the recorded disappearance of X-
b) 2300 K
molarity. mark.
c) 0.5 K
2. 60 grams of nail was used Magnitude of d) 430oC
for the determination of the ∆Twater.
specific heat of iron nail 4. In a neutralization of strong acid with a strong base,
instead of 50 grams. reaction of H+ and OH- to form water is the essential
reaction.
3. Unknowingly, there is Calculated cFe
already water in the tumbler Two solutions of 12.0 mL each of 3 M HCl and 3 M NaOH,
before 100 mL of water is initially at 305.15 K are added to a Coffee Cup Calorimeter
added. and the reaction proceeds. The temperature rises to 327.15
K. Which of the following is the heat of reaction of the c) increase, 4
system? (Ccal = 78.2 JoC-1) d) not change
a) -82.3 kJ/mol
b) -61 kJ/mol 10. Which of the following is not an implication of a
c) -89.7 kJ/mol negative standard enthalpy of reaction?
d) -150.6 kJ/mol a) The reaction is exothermic.
b) Heat is absorbed by surroundings upon the
5. Which of the following are state functions? reaction.
I. work III. internal energy c) Enthalpy of decomposition is less than the
II. enthalpy IV. heat enthalpy of recombination.
a) I and II d) Enthalpy of decomposition is greater than the
b) II and III enthalpy of recombination.
c) II, III and IV IV. Problem Solving.
d) I and IV 1. When a 1.000 g sample of the rocket fuel hydrazine,
N2H4 (MW=32.0), is burned in a bomb calorimeter
For items 6-7, consider the pooled data below of a group containing 1500 g H2O, the temperature rises from 25.0
of students called Chemsioc. (Measured with respect to °C to 30.0 °C. If the specific heat of water is 4.18 J/g°C
surroundings of the reaction) and the Ccal of the bomb calorimeter is 670 J/ °C,
calculate:
Reaction Change in Change in (a) qreaction for combustion of a one-gram sample
volume temperature (b) qreaction for combustion of a one-mole sample of
1 Increase Decrease hydrazine.
2 Decrease Decrease 2. Wade made a bet with Francis that his proposed
3 Increase Increase mechanism for the reaction 2NO2(g) + F2(g) is plausible,
or his last name wasn’t Wilson. The problem is that he
6. In which reaction were heat absorption and work done never took Chem 17—he is now asking you to prove
by the system? this for him. The rate law is k[NO2][F2].
a) Reaction 1 Fast: NO2(g) + F2(g) NO2F2(g)
b) Reaction 2 Slow: NO2F2(g)  NO2F(g) + F(g)
c) Reaction 3 Fast: F(g) + NO2(g) NO2F(g)
d) Reactions 2 and 3 3. Determine ∆H° for the reaction: C3H4(g) + 2H2(g) →
C3H8(g) given the following:
7. In which reaction were heat release and work done by the Reaction ∆H° (kJ)
system? H2(g) + ½O2(g) → H2O(l) -285.8
a) Reaction 1 C3H4(g) + 4O2(g) → 3CO2(g) + 2H2O(l) -1937
b) Reaction 2 C3H8(g) + 5O2(g) → 3CO2(g) + 4H2O(l) -2219.1
c) Reaction 3 Does hydrogenation of C3H4(g) absorb or release heat?
d) Reactions 2 and 3 1
4. The rate of the reaction, HgCl2(aq) + 2 C2O42-(aq) 
1
8. The decomposition of carbon disulfide, CS2, to carbon Cl-(aq) + CO2(aq) + Hg2Cl2 (s) is followed by
2
monosulfide, CS, and sulfur is first order with measuring the number of moles of Hg2Cl2 that
k = 2.8 x 10-7 s-1 at 1000oC.
precipitate per liter per second. The following data are
CS2  CS + S obtained:
What is the half-life of this reaction at 1000oC?
[HgCl2] [C2O42-] Initial Rate
a) 2.5 x 106 s
(mol/L•s)
b) 5.0 x 107 s
0.10 0.10 1.3 x 10-7
c) 4.7 x 10-6 s
d) 3.8 x 105 s 0.10 0.20 5.2 x 10-7
0.20 0.20 1.0 x 10-6
9. Given: A + 3B  2C + D 0.20 0.10 2.6 x 10-7
This reaction is first order with respect to reactant A and a) What is the order of the reaction with respect
second order with respect to reactant B. If the to HgCl2, with respect to C2O42-, and overall?
concentration of A is doubled and the concentration of B b) Write the rate equation for the reaction.
is halved, the rate of the reaction would _____ by a factor c) Calculate k for the reaction.
of _____. d) When the concentrations of both mercury(II)
a) increase, 2 chloride and oxalate ion are 0.30 M, what is the
b) decrease, 2 rate of the reaction?
Answer Key:
I. True or False 4. a) rate = k [HgCl2]n x [C2O42¯]m
1. TRUE n
rate4 k[ HgCl2 ]4
n
 [ HgCl2 ]4 
2. FALSE bigger, slower  n
  
3. FALSE minimum rate1 k[ HgCl2 ]1  [ HgCl2 ]1 
4. FALSE nonspontaneous at all temperatures
2.6 x10 7  0.20 
n
5. FALSE isothermal   2 = 2n ; n = 1
6. FALSE constant volume, constant pressure 1.3x10 7  0.10 
7. FALSE oxidation of magnesium forming MgO order with respect to HgCl2 is 1. (Rate is proportional
8. TRUE
to [HgCl2].)
9. FALSE intermediate
10. TRUE m
rate2 k[ C2 O4 2  ]2 m  [ C2 O4 2  ]2 
11. TRUE   
10. TRUE rate1 k[ C2 O4 2  ]1m  [ C2 O4 2  ]1 
II. Cause and Effect
1. Decrease, higher concentration of H+ makes the reaction 5.2 x 10 7  0.20
m
  4 = 2m ; m = 2
faster. . x 10 7
13  010
. 
2. Increase, ∆Twater is directly proportional to the mass of
the metal order with respect to C2O42- is 2.
3. No effect. Starch was only used as an indicator and does Overall order is 3.
not affect the completion of the reaction.
4. No effect, the order of the reaction with respect to b) rate = k [HgCl2] [C2O42-]2
thiosulfate is zero order. c) rate = k [HgCl2] [C2O42-]2 ; 1.3 x 10-7 = k
5. Decrease. Other contaminants may be oxidized instead (0.10)(0.10)2; k = 1.3 x 10-7/0.001 = 1.3 x 10-4
of Mg d) rate = 1.3 x 10-4 x [HgCl2] [C2O42-]2; rate =
III. Multiple Choice
1. C 6. C 1.3 x 10-4 x (0.30) (0.30)2 = 3.5 x 10-6 mol/L/s
2. D 7. A
3. A 8. A
4. B 9. B
5. B 10. D
IV. Problem Solving
1. qreaction = -qcal
qreaction = -[(qwater) + (qbomb)]
qreaction = -[(ccal, water)(mwater)(∆T) + (Ccal)(∆T)]
qreaction = -[(4.18 J/g°C)(1500 g)(30°C - 25°C) + (670
J/g°C)( 30°C - 25°C)]
qreaction = -34700 J/g
qreaction = -35000 J/g = -35 kJ/g

2. [discussed in lecture]

3.
1[C3H4(g) + 4O2(g) → 3CO2(g) + 2H2O(l)] 1(-1937)
2[H2(g) + ½O2(g) → H2O(l)] 2(-285.8)
1[3CO2(g) + 4H2O(l) → C3H8(g) + 5O2(g)] 1(-2219.1)
C3H4(g) + 2H2(g) → C3H8(g) -4727.7 kJ
The reaction is highly exothermic, releases heat.