Aspenhysys Petroleumassaysandoilcharacterizationslideshare 190305003017 PDF

Chemical Engineering Guy
www.ChemicalEngineeringGuy.com
1. Introduction
2. Hypotheticals Manager
3. Petroleum Assays 25%Theory
4. Oil Manager: Step 1 – Input Data Assay 75% Workshop
5. Oil Manager: Step 2 – Cutting & Blending

6. Oil Manager: Step 3 – Installing the Oil
7. Plotting Results: Graphs, Tables, Charts
8. Study Case – Industry Application
9. Conclusion
10. Bonus Section!
a) Why Process Simulation?
b) What is Aspen HYSYS? Required version?
c) Why Hypos, Assays and Oil Characterization?
d) Required Background and previous knowledge
 Fractionation Column
 Given conditions
 Reboiler Duty
 Crude Oil composition (LAB)
 Inlet Temperature
 Products conditions
 Model this!
 Optimize
What will happen if we change Crude Oil Composition?
Crude Oil
 Makes us easier/faster work
 Multiple and Simultaneous Simulations
 Different Real-Life Scenarios
 Change on raw/feed materials scenario
 Pricing and Costs calculation

 Raw Materials
 Plant Cost
 Utilities
 How it would behave under different conditions

 High/Low Pressure
 Humidity Changes
 Temperature change (cool/warm days/seasons)
 Mainly:
 Petrochemical
 Oil&Gas
 Other commodities such as:
 Sulfuric acids
 Chlorine/Caustic industry
 Coatings
 Ammonia
 Hydrogen Gas
 Helps us:
 Stream flow rates
 Compositions of streams
 Physical properties such as P, T, v of streams
 Unit operation operating conditions:
 Heat duty
 T, P,
 Electricity
 Efficiency
 Power…
 Preliminary equipment sizing ideas/design
 Important operational/design concerns/issues
 As any Engineering problem, we require to set some data:
 Mass & Energy balances
 Transport phenomena:
 Momentum
 Heat
 Mass
 Separation principles
 Equilibrium relationships
 Gibbs free energy
 Entropy
 thermos’s law
 DESGIN:
 Decrease in time
 Decrease or experimental requirements
 Improves Pilot Plants and Tests
 Explore proprietary/experimental process technology
 Allows Equipment design
 OPERATION:
 Helps to improve existing processes
 Set possible set of scenarios
 Determine best operational input
 Safety Analysis (Safety Regulations)
 Emissions studies (Environmental)
 Excelent for your curriculum as an engineer
 Perfect for analytical/numerical minds
 Good for debuging and fixing
.
From the website:
“Aspen HYSYS is the energy industry’s leading process simulation software that’s
used by top oil and gas producers, refineries and engineering companies for process
optimization in design and operations.”
http://www.aspentech.com/products/aspen-hysys/
 Petroluem Assay Manager
Aspen HYSYS® - Crude License
 Oil Manager
Aspen HYSYS® - Petroleum Refining

License
http://www.aspentech.com/products/aspen-hysys/
 My version V8.8 (May 2015)
 Most recent version V10 & 10.1 (Nov 2017)

 https://home.aspentech.com/en/v10
 “X” is not present in database
 “Y” is a required product, new in chemical world
X Y
X + Solvent
N/A
Solvent
 Hypos:
 Chemicals not present in database
 92 Octane Gasoline
 Diesel
 Coal
 Natural Gas
 NEW chemical components
 Non-standardized products
 Nature of chemical compounds vs. real life compounds
 Databases not 100% reliable
 Detailed material composition/modeling
 They can be still be modeled!
Crude Oil
 Assays & Oil Characterization
 Nature crude’s composition
 Naphtha
 Kerosene
 Diesels
 Fueloils
 Asphalt/residue
 Databases not 100% reliable
 Required input
 Viscosity, density, molar mass
 Paraffins CnH2n+2
 Gasses or liquids at room temperature
 Examples (methane, ethane, propane, butane, isobutane, pentane, hexane)
 Aromatics C6H5 - Y
 ringed structures with one or more rings rings contain six carbon atoms(single/double bond)
 benzene, napthalene
 Napthenes or Cycloalkanes CnH2n

 ringed structures with one or more rings rings contain only single bonds between the carbon atoms
 typically liquids
 cyclohexane, methyl cyclopentane
 Alkenes CnH2n liquid or gas 1.paraffins (15-60%)

 ethylene, butene, isobutene 2.naphthenes (30-60%)
3.aromatics (3-30%)
 Dienes and Alkynes CnH2n-2 4.asphaltics (remainder)
 liquid or gas examples
 acetylene, butadienes
 Carbon - 84%
 Hydrogen - 14%
 Sulfur - 1 to 3% (hydrogen sulfide, sulfides, disulfides, elemental sulfur)
 Nitrogen - less than 1% (basic compounds with amine groups)
 Oxygen - less than 1% (found in organic compounds such as carbon dioxide, phenols, ketones,
carboxylic acids)
 Metals - less than 1% (nickel, iron, vanadium, copper, arsenic)
 Salts - less than 1% (sodium chloride, magnesium chloride, calcium chloride)
 Coal  not present
 Gasoline 92 Octanes  not present
 Basic Chemistry, petrochemistry
 Basic knowledge in Unit Operations
 Engineering Field
 Oil / Drilling / Chemical / Petrochemical / Mechanical / Process / Industrial
Need Training?
 Please feel free to take this Course!
 You will need to know the basics of Aspen HYSYS
Use the following coupon

FREE-OILMNG
Aspen HYSYS
 Also, if you need even more training, please checkout:
www.ChemicalEngineeringGuy.com/Courses
 For my students!
 Get these FREE
 Use coupon = FREE-OILMNG
Aspen Plus Aspen HYSYS

 For my students!
 Get these for only $15 USD
 Coupon = OILMNG-15
how to setup hypothetical compounds, oil assays, blends, and petroleum characterization
using the Assays and Oil Manager of Aspen HYSYS
 Hypothetical Compounds (Hypos)

 Estimation of hypo compound data
 Use the UNIFAC Component Builder
 Basis conversion of existing components
 Petroleum Assays Manager

 Input crude oil data
 Model Crude oils
 Import existing Assays
 Plot relevant data/results
 Oil Manager
 Input of Crude Assay Data
 TBP
 ASTM (D86, D1160, D86-D1160, D2887)
 Chromatography
 Light Ends
 Density, viscosity, molecular weight based (dependent/independent)
 Plot Relevant Results
 Distillation Curves
 Viscosity
 Distribution Plots (Off Gas, Light Short Run, Naphtha, Kerosene, Light Diesel, Heavy Diesel,
Gasoil, Residue)
 Property Table/Plots
 Installing the Oil
 Cutting/Blending different assays
 Using the oil in Flowsheet
 Simulation using the Oil

 Study Case
 Fractionation of crude oil
 Compounds not present in Data Bases
 Mostly modeled/theoretical
 Select desired methods to estimate unknown properties
 Hypothetical Manager
 Possible components:
 non-library
 hypothetical
 Pure
 Defined mixtures
 Undefined mixtures
 Solids (Coals)
 You can also convert/clone HYSYS library components into hypotheticals, allowing
you to modify the library values.
 Component List > Hypo Group > Hypo Compound
 One class  One group
 Classes: Alkanes, inorganics, ketones,
 1 Comp. List = 1 Fluid Package

 Hypo Manager  Settings  Group  Class
 3 Ways to model:
 Physical + Chemical properties
 Chemical Structure
 Converting/Cloning “base” component
 NEXT  Practice each one in a Workshop!
 Typically choose 2:
 Normal Boiling Point I
n
 Molecular Weight p
u
 Liquid Density t
 Partial T/P
 Accentricity
Estimate!
 1) Generate Hypo Components
 Method = Create a Batch of Hypos
 Initial BP = 500°C
 Final BP = 900°C
 Interval = 50°C
 “ADD” to list
 2) Generate Hypo Components
 Method = Create&Edit Hypos
 NBP = 117.50°C
 MW = 150
 Density = 750 kg/m3
 Estimate unkown  Tc,Pc,Vc, Acc.
 “ADD” to list
 Use FP: Antoine
 Coefficients will be calculated
 Go to Sim. Environment
 Add stream
 T = °50, P = 101 kPa, F = 100 kmol/h
 Setup Composition
 You can now simulate the streams!
Check Course for:
*Video Lecture
*Spreadsheets
¨*Results
*Simulation/Cases
 Aspen HYSYS will model given the Structure
 Identify the “important” organic groups
 Chemical Structure + UNIFAC Component Builder
 Double click “Hypo#ID”  Button “Structure Builder”  State “UNIFAC

Structure”
1
2
1
2
 4-nonanona  Ketone
 Hypo Manager  Ketone
 Generate 1 Hypo
 UNIFAC Structure Builder
 CH3 - (sub group 1)

 CH2 - (sub group 2)
 C=O - (sub group 20)
 Choose a FP  Antoine
 Converted from another existing component
 Based on its properties
 The “base” component must be stated FIRST
 Manual/edition
 Estimation/Calculation
 Model “Benzenalike” a molecule very similar to benzene, with different propeorties,
and unkown structure
 First, Add “Benzene” to the comp. list
 Choose “Convert” from Hypo Manager
 Choose Benzene  change composition
Check Course for:
*Video Lecture
*Spreadsheets
¨*Results
*Simulation/Cases
 You can now model Benzenalike!
 A crude oil assay is the chemical evaluation of crude
oil feedstocks by petroleum testing laboratories.
 The results of crude oil assay testing provide extensive detailed hydrocarbon analysis
data for refiners, oil traders and producers.
 Assay data help refineries determine if a crude oil feedstock is compatible for a
particular petroleum refinery or if the crude oil could cause yield, quality, production,
environmental and other problems.
 Each crude oil has unique molecular and chemical characteristics
 No crude oil types are identical.
 In a refinery, a typical crude oil stream consists of the following
characteristics:
 Mixture of many naturally occurring hydrocarbons
 Boiling points ranging from -160°C (Methane) to more than 1500°C.
 Heavy fractions that are not mixtures of discretely identifiable components.
 Plus-fraction starting from C7+ to C12+
Specially  Heavy crudes!
 A proper description of the physical properties of the plus-fractions
is essential for reliable phase behavior calculations and
compositional modelling studies.
Aspen HYSYS® - Petroleum Refining License
Aspen HYSYS® - Petroleum Refining License
 Users with the HYSYS Petroleum Refining license should use the HYSYS
Petroleum Assay to model petroleum crude.
 This is an advanced form of crude oil assay supporting extensive petroleum
properties such as gravity, sulfur, nitrogen, cloud point, carbon, metals, and more.
 You can easily import existing Oil Manager assays to HYSYS Petroleum assays
from the Petroleum Assay setup pages.
 The Assay Manager lets you manage Petroleum Assay Data in
Aspen HYSYS Petroleum Refining.
 Assays can be added to the case from a variety of sources and
characterized.
 Properties required in the simulation can then be calculated
according to the specified Fluid Package.
A Fluid Package must be stated!
 Using the Petroleum Assays form, you can:
 Display the Assay Description
 Input Data / Import Assay / Download Assay
 Define cut properties
 Generate plots
 NEW Assays:
 Import Existing (Library/File)
 Manually Enter
 Characterize
 Download Assays
 Least Required
 More DATA
 Assay-1
 Define the Cuts (100°-500°)
 Assay-1
 Define the Cuts (100°-500°)
 Click “Characterize Assay”
 Assay-1
 Check out all results!
 Copy: Assay-1  Copy of Assay-1
 Add more data:
 %whole crude = 100%
 Density whole = 750 kg/m3
 Total Sulfur % = 2.5%
 Paraffin Vol = 40%
 Naphthene Vol = 25%
 Oleffins Vol = 10%
 Aromatic Vol = 15.0%
 Check results!
 Compare vs. less data
Check Course for:
*Video Lecture
*Spreadsheets
¨*Results
*Simulation/Cases
 Pre-existing Assays (600 approx.)
 By Region
 By Country
 Complete DATA!
 Import existing 
 West Texas Intermediate 1994
 Review Component List
 Verify FP = Peng Robinson (default)
 Checkout “Input Assay” Folder
 Go to “Conventional Results”
 West Texas Intermediate
Check Course for:
*Video Lecture
*Spreadsheets
¨*Results
*Simulation/Cases
 Typically, we are interested on the Assay Properties:
 Cuts
 Distillation Curve (BP vs. composition)
 Physical/Chemical Properties
 Viscosity of crude
 Viscosity of Cuts
 PNA (information of Paraffins, Napthenes, Aromatics)
1 Assay
2 or more…
 (y-axis)
 Weight
 Volume
 Mol
 (x-axis)
 %, ppm
 g/kg
 g/g (fract)
 Type:
 TBP
 D86
 D2887
 (y-axis)
 Mass
 Volume
 (x-axis)
 Temperature
 Flip Coordinates
 Selected Property
 Vs. T or V%
 Selected Property
 Vs. T or V%
 PNA represents
 Paraffin
 Naphthene
 Aromatic
 Assay  From previous Workshop (#5) Imported  West Texas Intermediate 1994
 Get all the next:
 Property Table
 Select Properties:
 Select Property
 Burning Props.  FlammabilityFlash point
 Select Property
 Cold Properties  CloudPoint
 Select Property
 Contaminants Sulfur by weight %
Check Course for:
*Video Lecture
*Spreadsheets
¨*Results
*Simulation/Cases
 The same can be done for 2
Assays or even more assays
 Excellent for crude oil comparison
 From WSK4+5  Compare our “random” assay vs. TX-Intermediate
 Repeat previous Workshop
 Get all the next:
 Select Properties:
 Select Property
 Density (kg/m3)
 Select Property
 Contaminants Sulfur by weight %
Check Course for:
*Video Lecture
*Spreadsheets
¨*Results
*Simulation/Cases
Aspen HYSYS® - Crude License
Aspen HYSYS® - Petroleum Refining
License
 Users with the HYSYS Petroleum Refining license should use the HYSYS
Petroleum Assay to model petroleum crude.
 This is an advanced form of crude oil assay supporting extensive petroleum
properties such as gravity, sulfur, nitrogen, cloud point, carbon, metals, and more.
You can easily import existing Oil Manager assays to HYSYS Petroleum assays
from the Petroleum Assay setup pages.
 Oil characterization  Oil Manager in Properties Environment
 Converts Assay Data into a series of discrete hypothetical components
 “Portion of hydrocarbons which boil from 40°C to 50°C  “NBP[0]045”
 Three steps in Oil Characterization:
1. Input assay data
2. Cut and blend assay into hypothetical components
3. Install oil information to flowsheet
 Min info. required to characterize the oil:
 Distillation data curve (*at least 2 points)
 OR/AND
 Two bulk properties (molecular weight, density, or Watson K)
More data  Better model
 Provided distillation curves are converted to other formats using built-in API
methods
API = American Petroleum Institute
 Input 1:
 (Bulk Properties)
 MW = 365 g/mol
 Density = 750 kg/m3
 Input 2:
 (Distillation Curve)
 TBP
 Point 1 (1% v/v; 0°C)
 Point 1 (99% v/v; 500°C)
Assay Types:  Bulk Properties:
 TBP (true boiling point)  Molecular Weight > 16
 Mass Density = 250 ~ 2000 kg/m3
 ASTM D86
 Watson K Factor = 8 ~ 15
 D1160 distillation  Bulk Viscosity, @ 100°F and @210°F
 D86–D1160
 ASTM D2887  Physical Property Curves:
 EFV (equilibrium flash  Molecular Weight

vaporization)  Density
 Viscosity
 Chromatographic analysis
Assay Types:
 TBP (true boiling point)  BP vs. Composition
An ASTM designation number identifies a unique
version of an ASTM standard.
 ASTM D86  https://www.astm.org/Standards/D86.htm D86 - 17

D = miscellaneous materials;
86 = assigned sequential number
 D1160 distillation 17 = year of original adoption (or, in the case of
revision, the year of last revision)
 D86–D1160
•D86 Test Method for Distillation of Petroleum Products at Atmospheric Pressure
 ASTM D2887 •ASTM D20-03(2014) Standard Test Method for Distillation of Road Tars
•D1160 Test Method for Distillation of Petroleum Products at Reduced Pressure
 EFV (equilibrium flash vaporization)

 Chromatographic analysis
 Be sure how you get the input data (specifications)
 Type (TBP, D86, etc.)…
 Are light-ends included?
 Do you have a separate light ends analysis?
TBP equipment (Crude

www.ChemicalEngineeringGuy.com Oil)DISTILLATION UNITS
AUTOMATIC TBP D2892
• Distillation Curve (v/v% vs. T°C)
 Peng Robinson %Assay Percent T(°C)
0 165
 Bulk: MW = NA D = 800 kg/m3 5 175
 Assay Data Type: ASTM D86 10 183
30 195
 Light Ends: IGNORE 50 205
70 210
90 225
95 230
98 235
Check Course for:
*Video Lecture
*Spreadsheets
¨*Results
*Simulation/Cases
0 186
 NAME = Naptha 5 220
 Bulk: D = 54.3 API-60 Watson UOPK = 11.83 10 232
20 244
 Assay Data Type: ASTM D86 30 254
40 265
 Light Ends: IGNORE
50 274
60 286
70 298
80 310
90 329
95 344
NOTE: We will use this in Blending
100 360
(Naphtha + Kerosene)
Check Course for:
*Video Lecture
*Spreadsheets
¨*Results
*Simulation/Cases
0 379
 NAME: Kerosene
5 402
 Bulk: D = 37.9 API-60 10 412
20 432
 Watson UOPK = 11.71
30 450
 T1 = 100F  V1 = 2.230 cSt
40 467
 T2 = 210F  V1 = 0.95 cSt 50 486
60 502
 Assay Data Type: ASTM D86
70 520
 Light Ends: IGNORE 80 540
90 562
95 574
100 586
NOTE: We will use this in Blending

(Naphtha + Kerosene)
Check Course for:
*Video Lecture
*Spreadsheets
¨*Results
*Simulation/Cases
 Greyson Streed Assay Basis Liquid Volume Assay Basis Molar Weight= Dependent
%Assay Percent Density (lb/ft3) Density (kg/m3)
Distillation Curve Distillation Curve 0 20.10 321.9
 Bulk: MW = 203.4 D = 52.75 lb/ft3 %Assay Percent T(°F) T(°C) 2 37.04 593.4
%Assay Percent MW
0 -4.9 -20.5 5 39.30 629.6
0 27.07 10 43.13 690.9
2 43.9 6.6
 Assay Data Type: TBP
2 62.72 15 45.01 721.1
5 96.5 35.8 5 72.15 20 46.87 750.9
10 174.3 79.1 30 48.93 783.9
10 96.77
 Light Ends: IGNORE 15 224.5 106.9
15 111.6
40 50.01 801.2
20 268.4 131.3 50 52.17 835.8
20 124.4 60 54.14 867.3
 Molecular Weight = dependent
30 345.6 174.2
40 433.8 223.2 30 150.3 70 55.75 893.1
40 185.8 80 58.11 930.9
50 529.6 276.4
 Density Curve = Dependent
90 62.22 996.8
60 631.4 333.0 50 227.8 95 67.09 1074.8
70 750.7 399.3 60 279.6 98 70.51 1129.6
80 908.3 486.8 70 350.3 10 72.95 1168.7
90 1144 617.8 80 451.8
95 1330 721.1 90 602.9
98 1548 842.2 95 689.4 See Spreadsheet
Data (WKS09)
100 1575 857.2 98 779.2
10 845.8
Check Course for:
*Video Lecture
*Spreadsheets
¨*Results
*Simulation/Cases
• Distillation Curve (v/v% vs. T°C fixed)
 Peng Robinson
 Bulk: D = 800 kg/m3 %Assay Percent T(°F) T(°F)STD T(°C)STD2
0 95 108.1 42.3
 Assay Data Type: ASTM D86
10 176 190.3 87.9
 Light Ends: IGNORE 30 289.4 305.3 151.8
 Fixed Temperature (standard) 50 336.2 352.8 178.2
70 363.2 380.2 193.4
 Extrapolation  Lagrange
90 417.2 435.0 223.9
Check Course for:
*Video Lecture
*Spreadsheets
¨*Results
*Simulation/Cases
 Light Ends are defined:
 pure components
 low boiling points
 C2 to n-C5 (propane/propylene, butanes, etc.)
 They should be replaced with discrete pure components

 This should always yield more accurate results than using hypocomponent to
represent the Light Ends portion.
 Ignore
 When the assay is prepared with the Light Ends in the sample and the Light
Ends portion is characterized using hypo components (least accurate—not
recommended)
 Also useful if it is understood there is a negligible content of lights in the assay
sample
 Input Composition:
 When the assay is prepared with Light Ends in the sample and a separate Light
Ends assay is available
 Auto Calculate
 When the assay is prepared with the Light Ends in the sample and you want to
use pure components to represent the low boiling portion of the assay
 Light Ends handling and Bulk Property fitting:
 Are Light-ends included in the input curves?
 Are Light-ends included in the bulk properties?
 Do you want to control which part of the curve is tuned to match the bulk
property?
• Distillation (v/v% vs T°C)
 Peng Robinson Assay Basis Liquid Volume
Distillation Curve
 Bulk: D = 879.8 kg/m3 %Assay Percent T(°C)
 Assay Data Type: TBP 0 -12
4 32
 Light Ends: Input (v/v% vs. T°C) 9 74
Light Ends v/v% 14 116
%Assay Percent Comp 20 154
Methane 0.0065 30 224
Ethane 0.0250 40 273
Propane 0.3200
50 327
i-Butane 0.2400
n-Butane 1.7500
60 393
i-Pentane 1.6500 70 450
n-Butane 2.2500 76 490
Water 0.0000 80 516
Check Course for:
*Video Lecture
*Spreadsheets
¨*Results
*Simulation/Cases
 Peng Robinson
 Bulk: MW = 300 D = 48.75 API-60
 Assay Data Type: TBP
 Density = dependent
 Viscosity / MW = independent
Light Ends v/v%
%Assay Percent T(°F) T(°C) INDEPENDENT
%Assay Percent Comp
0 80 27 Visc Curve 1 (use both) Kinetic 100F
Propane 0
%Assay v/v% Visc (cp)
10 255 124 i-Butane 0.19
10 0.2
20 349 176 n-Butane 0.11
30 0.75
30 430 221 i-Pentane 0.37
50 4.2
n-Butane 0.46
40 527 275 70 39
Water 0
50 635 335 90 600
60 751 399
70 915 491 %Assay v/v% Molecular Weight
INDEPENDENT
80 1095 591 0 68
Visc Curve 2 (use both) Kinetic 210F
90 1277 692 10 119
%Assay v/v% Visc (cp)
98 1410 766 20 150
10 0.1
30 182
30 0.3
Density Curve INDEPENDENT 40 225
50 0.8
%Assay v/v% API Density 50 282
70 7.5
13 63.28 60 350
90 122.3
33 54.86 70 456
57 45.91 80 585
74 38.21 90 713
91 26.01 98 838
Check Course for:
*Video Lecture
*Spreadsheets
¨*Results
*Simulation/Cases
 Peng Robinson
 Bulk: MW = 79.60 D = 0.6659 SG-60/60 api
 Assay Data Type: Chromatograph (by mol)
 Lists
 Light Ends = N2, H2S, CO2, H2O, methane to pentane
 Paraffinic = Hexane to Triconane Plus
 Aromatic = (Benzene to TMB)
 Napthenic = Cyclos
Paraffinic C# Mol Frac
Column1 Column2 Column3 Column1 Column2 Column3
Hexane (C6) 6 0.0268
Heptane (C7) 7 0.0371 Aromatic Components mol frac. Light Ends mol%
Octane (C8) 8 0.0348 N2 0.48
Nonane (C9) 9 0.0231
Benzene (C6H6) 0.0004
Decane (C10) 10 0.024 Toluene (C7H8) 0.0015 H2S 0.00
Undecane (C11) 11 0.0183 CO2 0.87
Dodecane (C12) 12 0.0142 EBZ, p+m-Xylene (C8H10) 0.0070
Tridecane (C13) 13 0.0141 o-Xylene (C8H10) 0.0028 C1 41.83
Tetradecane (C14) 14 0.0113
1,2,4 TMbenzene (C9H12) 0.0028 C2 8.87
Pentadecane (C15) 15 0.0099
Hexadecane (C16) 16 0.0074 C3 7.11
Heptadecane (C17) 17 0.0082
Naphthenic Components Mol Frac i-C4 1.47
Octadecane (C18) 18 0.0062
Nonadecane (C19) 19 0.0049 Cyclopentane (C5H10) 0.0002 n-C4 3.75
Eicosane (C20) 20 0.0046
Mclyclopentane (C6H12) 0.0106 i-C5 1.25
Heneicosane (C21) 21 0.0039
Docosane (C22) 22 0.0036 Cyclohexane (C6H12) 0.0050 n-C5 1.63
Tricosane (C23) 23 0.0032 Mcyclohexane (C7H14) 0.0156 C6 0.00
Tetracosane (C24) 24 0.0027
Pentacosane (C25) 25 0.0024
H2O 0.00
Hexacosane (C26) 26 0.0021 Total Light Ends % in Assay 67.26
Heptacosane (C27) 27 0.002
Octacosane (C28) 28 0.0018
Nonacosane (C29) 29 0.0016
Triconane Plus 30 0.0133
Check Course for:
*Video Lecture
*Spreadsheets
¨*Results
*Simulation/Cases
• Distillation (v/v% vs T°C)
 Peng Robinson
Density DEPENDENT Molecular WeightDEPENDENT Assay Basis Liquid Volume
%Assay Percent Density kg/m3 %Assay Percent MW Distillation Curve
0 321.9 0 27.1 %Assay Percent T(°C)
 Bulk: MW = 277 D = 848.1 kg/m3 2 593.4 2 62.7 0 -20.5
5 629.5 5 72.2 2 6.6
 Assay Data Type: TBP 10 690.8 10 96.8 5 35.8
15 720.9 15 111.6 10 79.1
Light Ends v/v% 20 750.8 20 124.4 15 106.9
%Assay Percent Comp 30 783.8 30 150.3 20 131.3
Methane 0.0000 40 801.0 40 185.8 30 174.3
50 835.7 50 227.8 40 223.2
Ethane 0.0150 60 867.3 60 279.6 50 276.4
Propane 0.2780 70 893.0 70 350.3 60 333.0
i-Butane 0.2080 80 930.9 80 451.8 70 399.3
90 996.7 90 602.9 80 486.8
n-Butane 1.6790
95 1075.0 95 689.4 90 617.6
i-Pentane 1.7340 98 1131.0 98 779.2 95 721.3
n-Butane 1.7930 100 1169.0 100 845.8 98 842.1
Water 0.0000 100 857.2
TOTAL 5.7070
Check Course for:
*Video Lecture
*Spreadsheets
¨*Results
*Simulation/Cases
Light Ends v/v%
 Fluid Package = Peng Robinson %Assay Percent T(°F) T(°C)
%Assay Percent Comp 0.0 15.0 -9.4
 MW = NA Methane 0.0065 4.5 90.0 32.2
Ethane 0.0225 9.0 165.0 73.9
 Density = 29.32 API-60 Propane 0.3200 14.5 240.0 115.6
i-Butane 0.2400
 Assay Data Type = TBP 20.0 310.0 154.4
n-Butane 0.8200 30.0 435.0 223.9
Water 0.0000 40.0 524.0 273.3
TOTAL 1.4090 50.0 620.0 326.7
60.0 740.0 393.3
IMPORTANT  USED
70.0 885.0 473.9
76.0 969.0 520.6
80.0 1015.0 546.1
IN FINAL WORKSHOP
85.0 1050.0 565.6
Check Course for:
*Video Lecture
*Spreadsheets
¨*Results
*Simulation/Cases
 Cutting generates the hypothetical components and
determines their compositions in the installed oil
 Types:
 Auto-cut
 User Ranges
 User Points
 Auto Cut
 Aspen HYSYS performs cuts automatically using built-in cutpoint
ranges
Cutpoint Range Boiling Point Width
IBP to 800 F 25 F per cut
800 F to 1200 F 50 F per cut
1200 F to 1650 F 100 F per cut
 HYSYS performs the cutting automatically upon selection
 User Points
 User defines the number of desired cuts for the oil
 Specified cut points are proportioned based on internal weighting scheme
Cutpoint Range Internal Weighting
IBP – 800 F 4 per 100 F
800 F – 1200 F 2 per 100 F
1200 F - FBP 1 per 100 F
 User Range
 Specify boiling point ranges and the number of cuts per range
 Grants more control over how many hypothetical components are generated
 Specifies the boiling point ranges they cover
 Choose Workshop # 13 and cut via:
 “Auto-Cut”

 “User points”

 “User Ranges”
 Blending is used to combine a number of assays and provides a general
presentation of the whole crude
Oil 1 Oil 2 Unblended Blended
NBP(20) NBP(25) NBP(20) NBP(22)
NBP(30) NBP(35) NBP(25) NBP(32)
NBP(40) NBP(45) NBP(30) NBP(42)
NBP(50) NBP(55) NBP(35) NBP(52)
NBP(60) NBP(65) NBP(40) NBP(62)
NBP(70) NBP(75) NBP(45) NBP(72)
NBP(80) NBP(85) NBP(50) NBP(82)
NBP(90) NBP(95) etc NBP(92)
8 8 16 8
 Blend Assays from:
 Workshop 10 “Naptha”
 Workshop 11 “Kerosene”
 Easiest Part!
 Click the Install Oil button after creating
the blend
 Provide the name of the target stream in
the Install Oil form and the Oil Manager
will:
 Add the hypo components to the fluid package
 Create a stream in the selected flowsheet with the
calculated composition
 Install Workshops:
 Workshop #16
 Workshop #18
 Workshop #20
 Convert Oil from Workshop #21A 
 Convert Oil from Workshop #21C 
Check Course for:
*Video Lecture
*Spreadsheets
¨*Results
*Simulation/Cases
 Table Type
 Property Plot
 Distribution Plot
 Composite Plot
 Summary Plot
 Comp Prop.
 Comp. Breakdown
 Molar Comp.
 Oil Prop.
 Oil Distrb
 Comparison between types of Assays
• Saved plots
 Now, let us USE our “installed oil”
 Did you notice that w only worked on the “Physical Properties Environment”
 THIS IS EXTRA!
 Not actually part of the course!
 Check out more material in

 Aspen HYSYS: Oil & Gas Industry
This workshop includes the following tasks:
 Goal 1 – Input Assay Data
 Goal 2 – Cut & Blend From Workshop #18
 Goal 3 – Install the Oil
 Goal 4 – Build the Flowsheet

Oil & Gas Application
 Goal 5 – Get Results
 Fluid Package = Peng Robinson Light Ends v/v% %Assay Percent T(°F) T(°C)
%Assay Percent Comp 0.0 15.0 -9.4
 Input Assay Methane 0.0065 4.5 90.0 32.2
 Density = 29.32 API-60 Ethane 0.0225 9.0 165.0 73.9
Propane 0.3200 14.5 240.0 115.6
 Assay Data Type = TBP
i-Butane 0.2400 20.0 310.0 154.4
 ENSURE v/v% n-Butane 0.8200 30.0 435.0 223.9
Water 0.0000 40.0 524.0 273.3
 Cutting TOTAL 1.4090 50.0 620.0 326.7
 User Points = 30 units 60.0 740.0 393.3
70.0 885.0 473.9
 Blending 76.0 969.0 520.6
80.0 1015.0 546.1
85.0 1050.0 565.6
 Installing Oil (Raw Crude)
 Raw Oil (Material)
 T = 450 F; P = 75 psia; Liq Flow (STD) = 1E05 Barrels/day
 PreFlash (UNIT)
 Flash Separator
 Adiabatic, Vap1 vs. Liq1
 Crude Heater (UNIT)

 Heater; Inlet = Liq1, Outelt: Hot Crude; Q = Heat Duty 1
 dP = 10 psi; T= 650F
 Mixer (UNIT)
 Inlet = Hot Crude + Vap1
 Main Steam (Material)
 T = 375 F; P = 150 psia; F = 7500 lb/h; 100% Water
 Diesel Steam (Material)

 T = 300 F; P = 50 psia; F= 3000 lb/h; 100% water
 AGO Steam (Material)

 T = 300 F; P = 50 psia; F= 2500 lb/h; 100% water
 Q-Tower in (Energy)
 N/A
 Step 1
 Add Abosrber Column
 Atm Tower (UNIT)
 No Trays = 29
 Partial Condenser Heat duty = Q-condenser;
 Off Gas = Condenser gas
 Ovhead = Naptha
 WasteWater = (check Water Draw)
 ATM Feed = stage 28
 Q-Trim = stage 28
 Main Stream = Bottom Stage Inlet
 Bottom Liquid Outlet = Residue
 Step 2
 Condenser:
 P = 19.70 psia;
 dP = 9 psi
 Bottoms
 P = 32.70 psia
 Step 3
 Optional Condenser T = 100F
 Optional Top Stage T= 250
 Optional Bottom Stage T = 600
 Step 4
 Volume Basis
 No fill
 “Done”
 Kerosene= 9300 Ba/day
 #stages= 3; Return Stage = 8; Draw Stage = 9
 STD Ideal Vol.; Config = Reboiled
 Boilup ratio = 0.75
 Draw Spec = 9300 Ba/day  INSTALL
 Diesel= 19250 Ba/day
 STD Ideal Vol.;
 Config = Steam Stripped
 Steam Feed = Diesel Stream
 AGO (Automotive Gas Oil)= 4500 Ba/day
 STD Ideal Vol.;
 Config = Steam Stripped
 Steam Feed = AGO Stream
4500 Ba/day
 Pump1
 Return stage = 1; Draw stage = 2
 1st Spec: Rate =5*10^4 Ba/d
 2nd Spec: Duty = -5.5*10^-7 Btu/h
 Pump2
 Pump3
 FracTower  Design  Specs
 Column Liquid Flow
 Name = Overflash spec
 Stage = 27
 Flow Basis = Std. Ideal Vol
 Spec Val = 3500 Ba/day
 Column Duty
 Name = Kerosene Reboiler Duty
 Energy Stream = Kerosene_Energy@Column
 Spec Val = 7.5E06 Btu/h
 Column Vapor Flow

 Name = Vap Prod Flow
 Stage = Condenser
 Flow Basis = Molar
 Spec Value = 0
 Monitor:
 Reflux Ratio
 uncheck Active; Value = 1.0
 Distillate Ratio
 ReName  Naphta Prod Rate
 Draw = Naptha @Col1
 Basis = Std. Ideal Vap
 Spec Val = 2.3*104 Ba/day
 Delete
 Reflux Rate; Vap Prod Rate; Btms Prod Rate ; Kerosene_BoilupRatio (0.75)
 Activate
 Kero Reb Duty = 7.5x10^6 Btu/h; Vap Prod Flow = 0
 Check out
 Flow rates
 Compositions
 Heat Duties
 Distillation Curve Profile
 T,P,Flow vs. Stages
Check Course for:
*Video Lecture
*Spreadsheets
¨*Results
*Simulation/Cases
 What you learnt
 What can you do now
 What’s next?
 Hypothetical Compounds (Hypos)
 Estimation of hypo compound data
 Models via Chemical Structure UNIFAC Component Builder
 Basis conversion/cloning of existing components
 Input of Petroleum Assay and Crude Oils
 Using the Petroleum Assay Manager or the Oil Manager
 Importing Assays: Existing Database
 Creating Assays: Manually / Model
 Oil Characterization
 Input:
 Typical Bulk Properties (Molar Weight, Density, Viscosity)
 Distillation curves such as TBP (Total Boiling Point)
 ASTM (D86, D1160, D86-D1160, D2887)
 Chromatography
 Light End
 Cutting: Pseudocomponent generation
 Blending of crude oils
 Installing oils into Aspen HYSYS flowsheets
 Getting Results (Plots, Graphs, Tables)
 Property and Composition Tables
 Distribution Plot
 Off Gas, Light Short Run, Naphtha, Kerosene…
 …Light Diesel, Heavy Diesel, Gasoil, Residue
 Oil Properties
 Proper
 Boiling Point Curves
 Viscosity, Density, Molecular Weight Curves
 Modeling Crude oils
 Study Case:
 Flash
 Heating
 Mixing
 Fractionation Column
Crude Oil
 Side Strippers
 Checkout more FREE and PREMIUM material at
www.ChemicalEngineeringGuy.com/Courses
 Get these FREE
 Use coupon = FREE-OILMNG
 Get these for only $15 USD
 Coupon = OILMNG-15

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5. Oil Manager: Step 2 – Cutting & Blending

b) What is Aspen HYSYS? Required version?

c) Why Hypos, Assays and Oil Characterization?

d) Required Background and previous knowledge

What will happen if we change Crude Oil Composition?

 Pricing and Costs calculation

 How it would behave under different conditions

 Other commodities such as:

 Perfect for analytical/numerical minds

 Good for debuging and fixing

Aspen HYSYS® - Crude License

Aspen HYSYS® - Petroleum Refining

 Most recent version V10 & 10.1 (Nov 2017)

 Napthenes or Cycloalkanes CnH2n

 Alkenes CnH2n liquid or gas 1.paraffins (15-60%)

Use the following coupon

Aspen Plus Aspen HYSYS

 Hypothetical Compounds (Hypos)

 Petroleum Assays Manager

 Simulation using the Oil

 1 Comp. List = 1 Fluid Package

 NEXT  Practice each one in a Workshop!

 You can now simulate the streams!

 Double click “Hypo#ID”  Button “Structure Builder”  State “UNIFAC

 CH3 - (sub group 1)

Specially  Heavy crudes!

A Fluid Package must be stated!

 Define the Cuts (100°-500°)

 Click “Characterize Assay”

 Compare vs. less data

2. Cut and blend assay into hypothetical components

3. Install oil information to flowsheet

More data  Better model

 EFV (equilibrium flash  Molecular Weight

 ASTM D86  https://www.astm.org/Standards/D86.htm D86 - 17

 EFV (equilibrium flash vaporization)

TBP equipment (Crude

NOTE: We will use this in Blending

 They should be replaced with discrete pure components

IBP to 800 F 25 F per cut

800 F to 1200 F 50 F per cut

1200 F to 1650 F 100 F per cut

 HYSYS performs the cutting automatically upon selection

Cutpoint Range Internal Weighting

IBP – 800 F 4 per 100 F

800 F – 1200 F 2 per 100 F

1200 F - FBP 1 per 100 F

 Choose Workshop # 14 and cut via:

 Choose Workshop # 15 and cut via:

 Check out more material in

 Goal 4 – Build the Flowsheet

 Crude Heater (UNIT)

 Diesel Steam (Material)

 AGO Steam (Material)

 Column Vapor Flow

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